JPH1060615A - Wire rod plating device - Google Patents

Wire rod plating device

Info

Publication number
JPH1060615A
JPH1060615A JP23470296A JP23470296A JPH1060615A JP H1060615 A JPH1060615 A JP H1060615A JP 23470296 A JP23470296 A JP 23470296A JP 23470296 A JP23470296 A JP 23470296A JP H1060615 A JPH1060615 A JP H1060615A
Authority
JP
Japan
Prior art keywords
gas
wire rod
wire
plating
plating apparatus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP23470296A
Other languages
Japanese (ja)
Other versions
JP3109992B2 (en
Inventor
Naohisa Tatsumi
尚久 辰巳
Hirobumi Matsumoto
博文 松本
Tomio Kizuwa
富夫 木津和
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kokoku Steel Wire Ltd
Osaka Gas Co Ltd
Original Assignee
Kokoku Steel Wire Ltd
Osaka Gas Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kokoku Steel Wire Ltd, Osaka Gas Co Ltd filed Critical Kokoku Steel Wire Ltd
Priority to JP08234702A priority Critical patent/JP3109992B2/en
Publication of JPH1060615A publication Critical patent/JPH1060615A/en
Application granted granted Critical
Publication of JP3109992B2 publication Critical patent/JP3109992B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Electroplating Methods And Accessories (AREA)
  • Coating With Molten Metal (AREA)

Abstract

PROBLEM TO BE SOLVED: To attain the remarkable cost reduction as compared with the case of gaseous nitrogen by using a heat generating type atmospheric gas in which moisture is absorbed to a specified dew point as a nonoxidizing gas to be fed to the face of a plating bath in the rising part of a wire rod. SOLUTION: At the time of immersing a steel wire 1 in a galvanizing tank 2, executing galvanizing and taking up the steel wire 1 from the plating tank 2, through the gas throttling part, the bath face is covered with a nonoxidizing atmospheric gas to prevent the oxidation of the bath face, and the sticking of oxide to the wire rod 1 is prevented. As a nonoxidizing gas source therefor, the one using city gas or natural gas as the raw material, refrigerated till the dew point of <=-40 deg.C by a heat generating type gas generating device 4, and with moisture absorbed is used. Furthermore, the heat generating gas, e.g. has a compsn. composed of, by vol., 9% CO2 , 4 to 5% CO, 4 to 5% H2 and 80% N2 . In this way, easily applicable heat generating type gas can be used, by which the product capable of the remarkable reduction of the cost and moreover having a plated surface excellent in luster can be obtd.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は無酸化性ガスにより
メッキ絞りを行う方式の線材メッキ装置に関するもので
ある。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wire plating apparatus of a type in which plating is drawn with a non-oxidizing gas.

【0002】[0002]

【従来の技術】図3は従来のこの種の亜鉛メッキ装置を
示したもので、鉄線又は鋼線1を溶融亜鉛のメッキ浴2
に浸漬して引き上げる際に、メッキ浴面の線材立ち上が
り部分に線材1を囲むチャンバ3を設けて、該チャンバ
3に浴面の酸化を防止するための無酸化性ガスを供給す
るようにしたガス絞り部3が設けられており、このメッ
キ絞り用ガスとしては複数の窒素ボンベを順次切り替え
るようにしたガス源4から窒素ガスが供給されるように
なっていた。なおガス絞り部3は複数併設されて、同時
に多数本の線材1がメッキ処理されるようになってお
り、ガス絞り部3を出た線材は,水冷装置5によって冷
却されたのち、トップローラ6を通って引き取られる。
2. Description of the Related Art FIG. 3 shows a conventional galvanizing apparatus of this kind, in which an iron wire or steel wire 1 is coated with a hot-dip galvanizing bath 2.
When dipping and pulling up, a chamber 3 surrounding the wire 1 is provided at a rising portion of the wire on the plating bath surface, and a non-oxidizing gas is supplied to the chamber 3 to prevent oxidation of the bath surface. A throttle unit 3 is provided, and a nitrogen gas is supplied from the gas source 4 that sequentially switches a plurality of nitrogen cylinders as the plating throttle gas. A plurality of gas throttles 3 are provided in parallel, and a large number of wires 1 are plated at the same time. After the wires coming out of the gas throttles 3 are cooled by a water cooling device 5, a top roller 6 is cooled. Picked up through.

【0003】[0003]

【発明が解決しようとする課題】従来のメッキ装置にお
いては、メッキ絞り用ガスとして、上述のように窒素ガ
スを使用するか、あるいはプロパン、ブタン等の炭化水
素系燃料ガスを使用していた。しかし窒素ガスは通常ボ
ンベあるいはタンクに入れて運搬あるいは保管する必要
があるために取り扱いが面倒である上に、高価であると
いう問題があり、また燃料ガスはガス絞り用チャンバの
上端開口部で燃焼処理を行う必要があるために、多量の
すすが発生する上に、その炎のために線材の温度が上が
り過ぎて垂れ落ちを生じ易くなり、特に厚メッキには不
適であるという欠点があった。そこで本発明の第一の目
的は、絞り用ガスとして欠点の多い燃料ガスを直接使用
したり、あるいは高価で取り扱いの面倒な窒素ガスを用
いる方式に代え、都市ガスやプロパンガス等を燃焼させ
ることによりメッキ絞り用無酸化性ガスを安価に生成す
ることができるこの種の線材メッキ装置を提供すること
にある。
In a conventional plating apparatus, nitrogen gas is used as described above, or a hydrocarbon-based fuel gas such as propane or butane is used as a gas for plating. However, nitrogen gas usually has to be transported or stored in cylinders or tanks, so it is troublesome to handle and expensive, and fuel gas is burned at the upper opening of the gas throttle chamber. Due to the necessity of the treatment, a large amount of soot is generated, and the temperature of the wire is too high due to the flame, so that the wire is apt to droop, which is not suitable especially for thick plating. . Therefore, a first object of the present invention is to use city gas or propane gas instead of directly using a fuel gas having many defects as a restricting gas or using a method of using an expensive and cumbersome nitrogen gas. Accordingly, it is an object of the present invention to provide a wire plating apparatus of this kind that can generate an inoxidizing gas for plating squeezing at low cost.

【0004】またガス絞り部3を通過した線材1は、上
方で水冷装置5によって急冷されるが、メッキ層が凝固
する前に水冷を行うと形状が崩れてしまって品質が低下
するために、従来は絞り部3から水冷装置5までの間は
空気中で自然に放熱させていた。しかし自然放熱の場合
は、水冷装置5に達するまでに液垂れを起こし易いため
に、メッキ層の肉厚を大きくすることができないという
欠点があった。また厚メッキを目的として、ガス絞り部
3と水冷装置5との中間部で線材1に、エアを吹き付け
るという方法も試みられたが、この部分は未だメッキ層
の溶融金属が凝固しておらず、またエアは線材1と交わ
る方向に吹き付けられるために、エアによってメッキ層
が偏肉を起こし、線材の外観を損ない易いという問題が
あった。そこで本発明の第二の目的は、線材の外観を維
持しながらメッキ厚をもっと大きくすることができるよ
うなこの種のメッキ装置を提供することにある。
[0004] The wire rod 1 passing through the gas throttle unit 3 is rapidly cooled by a water-cooling device 5 above. However, if water-cooling is performed before the solidification of the plating layer, the shape of the wire rod is lost and the quality deteriorates. Conventionally, heat was naturally radiated in the air from the throttle unit 3 to the water cooling device 5. However, in the case of natural heat radiation, there is a drawback that the thickness of the plating layer cannot be increased because liquid dripping easily occurs before reaching the water cooling device 5. Further, for the purpose of thick plating, a method of blowing air to the wire 1 at an intermediate portion between the gas throttle unit 3 and the water cooling device 5 has also been tried, but in this portion, the molten metal of the plating layer has not yet solidified. In addition, since air is blown in a direction intersecting with the wire 1, there is a problem that the plating layer is uneven in thickness due to the air, and the appearance of the wire is easily impaired. Therefore, a second object of the present invention is to provide a plating apparatus of this kind which can increase the plating thickness while maintaining the appearance of the wire.

【0005】[0005]

【課題を解決するための手段】請求項1及び2の発明
は、図1に示すように、線材立ち上がり部のメッキ浴面
に無酸化性ガスを供給して、浴面の酸化を防止するガス
絞り部3を備えた線材メッキ装置において、上記無酸化
性ガスとして、露点が−40℃以下になるまで吸湿した
発熱型雰囲気ガスを使用するようにしたものであり、都
市ガス等の供給を受けて連続的に絞り用ガスを生成する
ことができるために、ボンベやタンク等が不要となり大
幅なコストダウンと取り扱いの簡略化を図ることができ
る上に、窒素ガスや燃料ガスを用いる方式に比し、水素
ガスや一酸化炭素による還元性を有するために、メッキ
表面の光沢を向上し得る点に特徴を有するものである。
According to the first and second aspects of the present invention, as shown in FIG. 1, a non-oxidizing gas is supplied to a plating bath surface at a rising portion of a wire to prevent oxidation of the bath surface. In the wire rod plating apparatus provided with the squeezing section 3, a heat-generating atmosphere gas that has absorbed moisture until the dew point becomes -40 ° C or less is used as the non-oxidizing gas. Can continuously generate the gas for squeezing, eliminating the need for cylinders and tanks, greatly reducing costs and simplifying handling. In addition, since it has a reducing property with hydrogen gas or carbon monoxide, it is characterized in that the gloss of the plating surface can be improved.

【0006】また請求項3及び4の発明は、上記ガス絞
り部3を備えると共に、このガス絞り部3の上方に線材
1を急速冷却するための水冷装置5を備えた線材メッキ
装置において、上記ガス絞り部3と水冷装置5との中間
部に、線材と平行な空気流により線材の溶融メッキ層を
凝固点近くまで冷却する強制空冷装置8を備えたもので
あって、メッキ層が偏肉しないように周囲から均等に空
冷することによって、メッキ絞り部3と水冷装置5との
間のメッキ層の流動性を下げ、外観を損なうことなくメ
ッキ厚を大きくし得る点に特徴を有するものである。
Further, the invention according to claims 3 and 4 is a wire rod plating apparatus comprising the gas throttle section 3 and a water cooling device 5 for rapidly cooling the wire 1 above the gas throttle section 3. A forced air cooling device 8 is provided at an intermediate portion between the gas throttle unit 3 and the water cooling device 5 to cool the hot-dip coating layer of the wire to near the solidification point by an air flow parallel to the wire, so that the plating layer is not uneven in thickness. As described above, by uniformly cooling from the periphery, the fluidity of the plating layer between the plating throttle unit 3 and the water cooling device 5 is reduced, and the plating thickness can be increased without impairing the appearance. .

【0007】[0007]

【発明の実施の形態】図1は本発明の一実施例を示した
もので、鋼線1を溶融亜鉛メッキ浴2に浸漬して亜鉛メ
ッキを行うものであり、ガス絞り部3では、鋼線1をメ
ッキ槽2から引き上げる際に、浴面を無酸化性の雰囲気
ガスで覆って浴面の酸化を防止し、酸化物が線材1に付
着するのを防止している。この無酸化性ガス源4とし
て、都市ガスあるいは天然ガスを原料とする発熱型ガス
発生装置が設けられている。なお発熱型雰囲気ガスと
は、理論混合比よりもやや少ない空気比の混合ガスを燃
焼させて得られる雰囲気ガスで、加熱及び触媒を通じて
得られる吸熱型とは異なり、外から熱を加えなくても燃
焼が継続するものである。本実施例ではこの発熱型ガス
の組成として、例えばCO2 :9%,CO:4〜5%,
H2 :4〜5%,N2:80%とし、露点が−40℃以
下になるまで冷凍して吸湿したものであり、入手の容易
な都市ガスあるいはプロパンガス等を燃焼することによ
り生成することができるので、大幅なコストダウンが図
ることができ、更に絞り用ガスが還元性を有するため
に、窒素ガス等を用いる方式に比し、メッキ表面の光沢
の遥かに優れた製品を得ることができる。
FIG. 1 shows an embodiment of the present invention, in which a steel wire 1 is immersed in a hot-dip galvanizing bath 2 to perform galvanization. When the wire 1 is lifted from the plating tank 2, the bath surface is covered with a non-oxidizing atmosphere gas to prevent the bath surface from being oxidized and to prevent the oxide from adhering to the wire 1. As the non-oxidizing gas source 4, a heating type gas generator using city gas or natural gas as a raw material is provided. Note that the heat-generating atmosphere gas is an atmosphere gas obtained by burning a mixed gas having an air ratio slightly smaller than the theoretical mixing ratio, and unlike an endothermic gas obtained through heating and catalyst, without applying heat from outside. Combustion continues. In the present embodiment, the composition of the exothermic gas is, for example, CO2: 9%, CO: 4 to 5%,
H2: 4-5%, N2: 80%, frozen and absorbed until the dew point becomes -40 ° C or less, and can be produced by burning easily available city gas or propane gas. As a result, the cost can be significantly reduced, and since the drawing gas has a reducing property, a product having a much more excellent gloss on the plating surface can be obtained as compared with a method using nitrogen gas or the like. .

【0008】ガス絞り部3の上方には、線材1に両側か
ら水をかけて急速冷却するための水冷装置5が設けられ
ており、凝固点付近まで温度低下したメッキ層を急冷す
ることによって、厚み方向の温度差によるしわの発生を
防止している。またガス絞り部3と水冷装置5との中間
部には、線材のメッキ層を凝固点近くまで冷却するため
の強制空冷装置8が設けられている。この強制空冷装置
8は、フラスコ状の圧力室11と、その上端開口部に連
設された通風筒12とで構成されており、圧力室11に
は中心軸に沿って線材1が通過する内筒9が貫設される
と共に、側壁に加圧空気供給管10が接続されている。
また圧力室11の上端開口部には内筒9と外周壁との間
に放射状に複数の整流板13が設けられており、圧力室
11から通風筒12へ吹き込まれた空気流が、この整流
板13を通過して整流され、線材1の溶融メッキ層の外
形を乱すことなく周囲から均等に冷却し、溶融金属の垂
れ落ちを防止する。なお通風筒12の下端部はネジソケ
ットとなっており、圧力室11の上端外周のネジ部に螺
着されている。
A water-cooling device 5 is provided above the gas narrowing section 3 for rapidly cooling the wire 1 by spraying water from both sides. The generation of wrinkles due to the temperature difference in the direction is prevented. A forced air cooling device 8 for cooling the plating layer of the wire rod to near the solidification point is provided at an intermediate portion between the gas throttle unit 3 and the water cooling device 5. The forced air cooling device 8 includes a flask-shaped pressure chamber 11 and a ventilation tube 12 connected to an upper end opening of the pressure chamber 11. The wire 1 passes through the pressure chamber 11 along a central axis. A cylinder 9 is penetrated, and a pressurized air supply pipe 10 is connected to a side wall.
A plurality of rectifying plates 13 are provided radially between the inner cylinder 9 and the outer peripheral wall at the upper end opening of the pressure chamber 11, and the air flow blown from the pressure chamber 11 into the ventilation cylinder 12 is rectified by the rectifying plate 13. The flow is rectified through the plate 13 and is uniformly cooled from the surroundings without disturbing the outer shape of the hot-dip plating layer of the wire 1 to prevent the molten metal from dripping. The lower end of the ventilation tube 12 is a screw socket, and is screwed to a screw portion on the outer periphery of the upper end of the pressure chamber 11.

【0009】[0009]

【発明の効果】請求項1乃至2の発明によれば、メッキ
絞り用ガスとして発熱型雰囲気ガスを使用することがで
きるので、入手の容易な都市ガスあるいは天然ガスを利
用して現地で生成することができ、従ってボンベで運搬
保管していた窒素ガスに比し大幅なコストダウンが図れ
る上に、ボンベの交換作業が不要となるなど、取り扱い
を著しく簡便化できるという利点があり、また特にCO
2 及びH2 の含有量をそれぞれ4%以上として還元性を
付与すれば、窒素ガス等に比しメッキ表面の光沢の優れ
た製品を得ることができるという利点がある。更に請求
項3乃至4の発明によれば、凝固点に達するまでの溶融
メッキ層の流動性を下げることにより、溶融金属の垂れ
落ちを防止することができる上に、軸方向の空気流によ
って線材を周囲から均等に冷却することができ、従って
線材の引き上げ速度を大きくすることができるので、外
観を平滑に維持しながら厚肉のメッキ層を形成すること
ができるという利点がある。
According to the first and second aspects of the present invention, a heat-generating atmosphere gas can be used as a gas for plating squeezing, so that it is generated locally using city gas or natural gas which is easily available. Therefore, there is an advantage that the cost can be significantly reduced as compared with nitrogen gas transported and stored in a cylinder, and the handling can be remarkably simplified, such as eliminating the need for replacing cylinders.
If the content of 2 and H2 is set to 4% or more to provide reducibility, there is an advantage that a product having excellent gloss on the plating surface can be obtained as compared with nitrogen gas or the like. Further, according to the third and fourth aspects of the invention, the flowability of the hot-dip coating layer until the solidification point is reached is reduced, so that the dripping of the molten metal can be prevented. Since it is possible to cool the wire uniformly from the surroundings and to increase the pulling speed of the wire, there is an advantage that a thick plating layer can be formed while keeping the appearance smooth.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明の一実施例を示す概略系統図。FIG. 1 is a schematic system diagram showing one embodiment of the present invention.

【図2】 同上に用いる強制空冷装置の縦断面図。FIG. 2 is a longitudinal sectional view of a forced air cooling device used in the above.

【図3】 従来例の概略系統図。FIG. 3 is a schematic system diagram of a conventional example.

【符号の説明】[Explanation of symbols]

1 線材 2 メッキ槽 3 ガス絞り部 4 無酸化ガス源あるいは発熱形ガス発生装置 5 水冷装置 6 トップローラ 7 シンカーローラ 8 強制空冷装置 9 内筒 10 加圧空気供給管 11 圧力室 12 通風筒 13 整流板 DESCRIPTION OF SYMBOLS 1 Wire rod 2 Plating tank 3 Gas throttle part 4 Non-oxidizing gas source or heat generating gas generator 5 Water cooling device 6 Top roller 7 Sinker roller 8 Forced air cooling device 9 Inner cylinder 10 Pressurized air supply pipe 11 Pressure chamber 12 Ventilation cylinder 13 Rectification Board

フロントページの続き (72)発明者 木津和 富夫 東京都中央区京町二丁目15番1号 興国鋼 線索株式会社内Continuation of front page (72) Inventor Tomio Kizu 2-15-1, Kyomachi, Chuo-ku, Tokyo

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 線材立ち上がり部のメッキ浴面に無酸化
性ガスを供給して、浴面の酸化を防止するガス絞り部を
備えた線材メッキ装置において、上記無酸化性ガスとし
て、露点−40℃以下まで吸湿した発熱型雰囲気ガスを
使用するようにして成る線材メッキ装置。
1. A wire rod plating apparatus provided with a gas throttle unit for supplying a non-oxidizing gas to a plating bath surface at a rising portion of a wire rod to prevent oxidation of the bath surface, wherein the non-oxidizing gas has a dew point of -40. A wire rod plating apparatus that uses a heat-generating atmosphere gas that has absorbed moisture up to a temperature of less than or equal to ° C.
【請求項2】 上記発熱型雰囲気ガスの一酸化炭素及び
水素成分をそれぞれ4容積%以上として成る請求項1記
載の線材メッキ装置。
2. The wire rod plating apparatus according to claim 1, wherein the carbon monoxide and hydrogen components of the heat-generating atmosphere gas are each at least 4% by volume.
【請求項3】 線材立ち上がり部のメッキ浴面に無酸化
性ガスを供給して、浴面の酸化を防止するガス絞り部を
備えると共に、ガス絞り部の上方に線材を急速冷却する
ための水冷装置を備えた線材メッキ装置において、上記
ガス絞り部と水冷装置との中間部に、線材と平行な空気
流により線材の溶融メッキ層を凝固点近くまで冷却する
強制空冷装置を備えて成る線材メッキ装置。
3. A gas cooling portion for supplying a non-oxidizing gas to a plating bath surface at a rising portion of a wire to prevent oxidation of the bath surface, and water cooling for rapidly cooling the wire above the gas narrowing portion. In a wire rod plating apparatus provided with a device, a wire rod plating apparatus comprising a forced air cooling device for cooling a hot-dip layer of a wire rod to near a solidification point by an air flow parallel to the wire rod in an intermediate portion between the gas narrowing unit and the water cooling device. .
【請求項4】 上記強制空冷装置として、中央に線材が
通過する内筒が貫設され、側壁に加圧空気供給口を備え
た圧力室の上端に、中心軸に沿って線材が通過する通風
筒を連接することにより、通風筒内に線材と平行な空気
流を形成して成る請求項3記載の線材メッキ装置。
4. A forced air cooling device, wherein an inner cylinder through which a wire passes is provided at the center, and a ventilation passage through which a wire passes along a central axis at an upper end of a pressure chamber having a pressurized air supply port on a side wall. The wire rod plating apparatus according to claim 3, wherein an air flow parallel to the wire rod is formed in the ventilation cylinder by connecting the cylinders.
JP08234702A 1996-08-17 1996-08-17 Wire plating equipment Expired - Fee Related JP3109992B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP08234702A JP3109992B2 (en) 1996-08-17 1996-08-17 Wire plating equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP08234702A JP3109992B2 (en) 1996-08-17 1996-08-17 Wire plating equipment

Publications (2)

Publication Number Publication Date
JPH1060615A true JPH1060615A (en) 1998-03-03
JP3109992B2 JP3109992B2 (en) 2000-11-20

Family

ID=16975066

Family Applications (1)

Application Number Title Priority Date Filing Date
JP08234702A Expired - Fee Related JP3109992B2 (en) 1996-08-17 1996-08-17 Wire plating equipment

Country Status (1)

Country Link
JP (1) JP3109992B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020043699A (en) * 2000-12-02 2002-06-12 이구택 Manufacturing Method of Molten Zinc Plated Steel Sheet with good Property and Defiecient of Dross and Zinc Dust
WO2003060176A1 (en) * 2001-12-27 2003-07-24 Sakuratech Co., Ltd. Wire material plating equipment
JP2007332450A (en) * 2006-06-19 2007-12-27 Nippon Steel Corp Hot-dipped wire, and cooling device therefor
JP2010095750A (en) * 2008-10-15 2010-04-30 Mitsubishi Cable Ind Ltd Apparatus and method of plating wire, and plated wire
JP2014040656A (en) * 2012-07-26 2014-03-06 Nisshin Steel Co Ltd MANUFACTURING APPARATUS AND MANUFACTURING METHOD OF Al PLATED STEEL WIRE

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020043699A (en) * 2000-12-02 2002-06-12 이구택 Manufacturing Method of Molten Zinc Plated Steel Sheet with good Property and Defiecient of Dross and Zinc Dust
WO2003060176A1 (en) * 2001-12-27 2003-07-24 Sakuratech Co., Ltd. Wire material plating equipment
US7220316B2 (en) 2001-12-27 2007-05-22 Sakuratech Co. Ltd. Wire material plating equipment
CN1332059C (en) * 2001-12-27 2007-08-15 樱泰科有限公司 Wire material plating equipment
JP2007332450A (en) * 2006-06-19 2007-12-27 Nippon Steel Corp Hot-dipped wire, and cooling device therefor
JP2010095750A (en) * 2008-10-15 2010-04-30 Mitsubishi Cable Ind Ltd Apparatus and method of plating wire, and plated wire
JP2014040656A (en) * 2012-07-26 2014-03-06 Nisshin Steel Co Ltd MANUFACTURING APPARATUS AND MANUFACTURING METHOD OF Al PLATED STEEL WIRE

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