JPH1035085A - Transfer sheet for curable resin decorative material and curable resin decorative material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To improve water resistance of a curable resin decorative material such as polyester resin decorative laminate or the like. SOLUTION: For a curable resin decorative material 20, adhesion of a curable resin layer to a pattern layer is improved by making a layer of the pattern layer 20 come in contact with its curable resin layers 24, 26, and an easily adhesive layer or the like, by a layer having carboxyl modified vinyl chloride- vinyl acetate copolymer as a binder. Further, a layer of the pattern layer 25 or the like is formed of a transfer sheet. In the transfer sheet, a layer in contact with at least a material to be transferred of the transfer has the carboxyl modified vinyl chloride-vinyl acetate copolymer as the binder thereof.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a curable resin decorative material such as a melamine decorative panel, a polyester decorative panel, and the like, which are used for building interiors, fittings, furniture, kitchen tools, light electrical equipment cabinets, vehicle interiors, and the like. The present invention relates to a transfer sheet used for manufacturing.

[0002]

2. Description of the Related Art Conventionally, in a curable resin decorative material such as a decorative polyester board, a resin used for a pattern layer in contact with the curable resin layer, an easy-adhesion layer, etc. is a cellulose resin such as nitrocellulose, an acrylic resin. Resins, vinyl chloride-vinyl acetate copolymer resins, polystyrene resins and the like have been used. For example, the curable resin decorative plate of JP-A-6-64122 has a pattern layer as a transfer layer, and is obtained by using a transfer sheet in which a fine embossed concavo-convex pattern is formed on the transfer layer. A polyester veneer comprising two curable resin layers having the shine of natural wood is disclosed. According to the decorative board of the same publication, a concealing layer made of titanium paper is laminated on a base material for a decorative board such as a plywood via an adhesive, and the first curing with an unsaturated polyester resin is further performed thereon in order. A curable resin layer, a pattern layer transferred and formed on the curable resin layer with the transfer sheet, and a second curable resin layer made of an unsaturated polyester resin, and the inner interface of the second curable resin layer has the fine irregularities. There is disclosed a curable resin decorative material having a configuration having the following.

[0003]

However, in a conventional curable resin decorative material, the adhesion between the pattern layer provided in contact with the curable resin layer and the curable resin layer may be insufficient. Was. For example, when a severe test such as a water resistance test is performed, water resistance such as peeling between the curable resin layer and the pattern layer may be poor. In particular, there is a problem in water resistance such as warm water resistance and hot water resistance in applications used around water such as a wash basin and a bathroom.

[0004]

Therefore, in order to solve the above-mentioned problems, the curable resin decorative material of the present invention includes a decorative layer which is in contact with the curable resin layer, that is, a layer such as a pattern layer or an easily adhesive layer. By forming the layer as a layer using a carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder, the adhesion between the curable resin layer and the pattern layer was improved. In addition, the adhesiveness of the other layers such as the other pattern layers (not using the specific binder) laminated on the curable resin layer was improved by the easy-adhesion layer. Further, the transfer sheet for forming the pattern layer of such a curable resin decorative material has a structure in which at least a layer of the transfer layer which is in contact with the transfer target is made of a carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder.

[0005]

Embodiments of the present invention will be described below in more detail with reference to the drawings.

The transfer sheet for a curable resin decorative material of the present invention is a transfer sheet used for imparting various functions such as painting of a curable resin decorative material such as a decorative polyester sheet, and is transferred from the transfer sheet. At least, in the transfer layer, at least the layer in contact with the curable resin layer of the transfer-receiving member uses a carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder. FIG. 1 is a sectional view showing one embodiment of the transfer sheet of the present invention. As shown in FIG.
Reference numeral 0 denotes a transfer layer 2 having a transfer layer 2 on a releasable support 1. The transfer layer 2 may be, for example, a pattern layer formed by printing or coating, an adhesive layer provided on the pattern layer as needed. There is. The transfer layer 2 also includes a transparent resin layer forming a transparent layer. Further, as described above, the transfer layer may have an uneven surface. Then, the transfer layer is transferred to the curable resin layer side, and becomes a decorative layer of the curable resin decorative material.

The releasable support 1 is not particularly limited as long as it has an appropriate releasability from the transfer layer 2 and can withstand heat or the like when using heat in the transfer process. For example, polyethylene terephthalate, polyethylene-terephthalate-isophthalate copolymer, polyester film such as polybutylene terephthalate, polyolefin film such as polypropylene film, vinylon film, resin film such as polyvinylidene chloride film, or paper such as polyolefin coated paper. And other supports such as metal foil, among which a thickness of 10 to 10 can be used.
A biaxially stretched polyethylene terephthalate film of about 0 μm is suitable. In addition to the case where the above-mentioned support is used alone, a transfer layer of the above-mentioned support is formed as the releasable support 1 (not shown) for the purpose of improving the releasability from the transfer layer 2 in addition to the case where the support is used alone. A release support having a release layer on its surface may be used. The release layer, a fluorine-based resin, various waxes, a known vehicle, for example, a release agent such as a silicone resin, for example, an acrylic resin, a cellulose resin, to form a coating film of a paint obtained by adding a vinyl resin, Releasable resin, for example,
It is formed by applying a fluorine resin, a silicone resin, a melamine resin, a polyolefin resin, an ionizing radiation-curable acrylic resin, or the like, or by using an extrusion coating, and usually has a thickness of about 0.1 to 3 μm. . When a release layer is provided, the surface of the release layer is matted by mixing inorganic or organic fine particles in the release layer, or fine unevenness is formed by a line pattern by embossing or the like. In this case, the transfer layer may have an uneven surface, and an uneven pattern may be formed on the outer surface of the transfer layer after being transferred to the transfer target. The release layer is peeled and removed integrally with the support during transfer. That is, peeling occurs at the interface between the release layer and the transfer layer.

The pattern layer as the transfer layer 2 has a pattern shape,
The entire surface is solid, or a layer of a combination thereof is formed by a known printing means such as gravure printing, offset printing, letterpress printing, silk screen printing, or a known coating means such as gravure coating. When the pattern layer is configured to be the outermost surface of the transfer layer, that is, a layer that comes into contact with the transfer target, it is preferable to use a carboxyl-modified vinyl chloride-vinyl acetate copolymer as the binder to improve the adhesion to the transfer target. It is preferred in that respect. The ink or coating liquid that forms the pattern layer uses the above-mentioned carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder, and if necessary, mixes various additives such as coloring materials and extender pigments as necessary. Used.

The carboxyl-modified vinyl chloride-vinyl acetate copolymer is a resin having a carboxyl group introduced into the copolymer during or after polymerization of the vinyl chloride-vinyl acetate copolymer. For example, it is a resin obtained by copolymerizing a vinyl monomer having a carboxyl group such as acrylic acid, methacrylic acid, maleic acid, fumaric acid, and itaconic acid together with a vinyl chloride monomer and a vinyl acetate monomer as a copolymer monomer. Further, those obtained by introducing a carboxyl group by various carboxylation reactions or the like after polymerization of the copolymer may be used. Here, the weight ratio of carboxyl groups is 0.3 to 7 of the whole resin.
% By weight is preferred. By forming a layer in contact with a curable resin layer such as a polyester resin layer using the above-mentioned carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder, in particular, the water-resistant adhesion such as hot water resistance and hot water resistance is improved. This has the effect of significantly improving.

The coloring material used for the pattern layer includes, for example, inorganic pigments such as titanium white, zinc white, red iron oxide, vermilion, ultramarine, cobalt blue, titanium yellow, graphite, carbon black, isoindolinone, Hansa Yellow A Organic pigments (including dyes) such as quinacridone, permanent red 4R, phthalocyanine blue, indathrene blue RS, and aniline black; metal pigments such as aluminum and brass; titanium dioxide-coated mica; and basic lead carbonate and other foil powders. A conventionally known coloring pigment such as a pearlescent (pearl) pigment may be used.
The extender pigment to be added is, for example, calcium carbonate,
Use silica, alumina, barium sulfate, or the like.

The patterns of the pattern layer include, for example, a wood pattern, a stone pattern, a cloth pattern, a leather pattern, a character, a geometric figure, a symbol,
It is a line drawing, a pattern pattern such as various abstract patterns, or a solid pattern on the entire surface. On the entire surface, in addition to the transparent colored layer, a colored concealing layer may be used, or a known coating method may be used. Of course, the pattern pattern may be combined with the entire solid pattern. For example, when the pattern layer has a stone pattern such as marble and a wood-based decorative material base is used as the curable resin decorative material, a whitish background-colored stone pattern may be used, and When the color of the system interferes, if the color hiding layer of the white system is provided as a part of the pattern layer together with the pattern of the stone pattern, the influence of the color blur of the ground color of the decorative board substrate And a pattern layer having a stable color tone can be formed by transfer. Similarly, for example, in the case of forming a brown woodgrain pattern layer on a gray base material such as a concrete base material, a tea-based colored concealing layer may be provided as a part of the pattern layer. .

Further, even when the pattern layer is provided with an adhesive layer using the specific resin as a binder without using the specific resin as a binder of the pattern layer, the transfer layer has a two-layer structure and the number of steps is small. Although this increases, the adhesive layer acts as an easy-adhesion layer, and the adhesion to the curable resin layer can be improved. In this case, as the binder of the pattern layer, a conventionally known resin such as a vinyl acetate, a vinyl chloride-vinyl acetate copolymer, a thermoplastic resin such as a cellulose resin, or a room temperature or thermosetting resin such as a polyurethane. May be used. Although the adhesive layer is provided on the entire surface, a similar configuration in that the adhesive layer is provided on the entire surface is a configuration in which the above-described colored concealing layer is used in combination as a part of the pattern layer. Therefore, the colored concealing layer may be constituted by the binder of the specific resin, and the other part of the pattern layer thereunder (on the side of the releasable support) may be constituted by a pattern layer using another resin as a binder. Needless to say, both may be constituted by the binder of the specific resin.

When a binder of the above-mentioned specific resin is used for the adhesive layer, the pattern layer does not form a layer from the resin binder, and a metal thin film can be used. Alternatively, a layer using a resin binder and a metal thin film are used in combination. For example,
Using a metal such as aluminum, chromium, gold, silver, or copper, a metal thin film formed by a method such as vacuum evaporation or sputtering may be laminated in a whole or in part in a pattern. In addition,
To form a pattern, a removal layer is formed in a desired pattern with a water-soluble ink on an unnecessary portion of the metal thin film, a metal thin film is formed on the entire surface by vapor deposition or the like, and then washed with water and immediately above the removal layer. A known method such as removal of the metal thin film.

The transfer sheet for a curable resin decorative material of the present invention as described above can be used for decoration of various curable resin decorative materials. The transfer layer (decorative layer) may be transferred to the curable resin layer on the transfer sheet of the present invention even after the curable resin layer is completely cured, but is preferably uncured before full curing or a half-curing process such as a so-called B stage. Performing in the cured state is excellent in the effect of improving adhesion. As a typical example of this,
In this case, a decorative plywood is formed by forming a decorative layer on the surface of a wood plywood by transfer, applying an unsaturated polyester resin paint on the decorative layer, and curing the coating. In addition, the transfer layer is not directly transferred to the curable resin layer, but is transferred to another layer, and the curable resin layer is cured by coating the curable resin layer on another layer to which the transfer layer has been transferred. A curable resin decorative material having a configuration in contact with the curable resin layer can also be used. Note that, in this case, at least the outer layer of the transfer layer after transfer uses a transfer sheet using the specific resin as a binder, but if the transfer layer is only a pattern layer, the outer layer is also the same. There is no problem because it is a layer composed of a binder of

Using the transfer sheet of the present invention as described above,
In order to obtain the curable resin decorative material of the present invention described below, various production methods conventionally known as curable resin decorative materials such as thermosetting resin decorative boards can be used according to the layer structure and materials. For example, a laminate molding method used for a polyester decorative board or the like. In addition, BMC (Bulk Molding Compoun
d) Molding method, SMC (Sheet Molding Compound) molding method,
FRP (Fiber Reinforced
Plastics) various molding methods, or injection molding methods,
RIM (Reaction Injiction Molding), and the like.

Next, the curable resin decorative material of the present invention will be described. First, the decorative material referred to in the present invention includes both a so-called decorative plate as a flat or curved plate material and a so-called decorative material which is attached to a base material via an adhesive or the like as a surface material of the base material. . The shape of such a decorative material is arbitrary, such as a flat plate, a curved surface, and a three-dimensional shape. When the decorative material is used in combination with other members to form a single product, or the shape of the decorative material itself is a target. There is a case where the present cosmetic material has high strength and strength or the present cosmetic material is combined with each other to form one product.

The curable resin decorative material of the present invention comprises at least two layers: a curable resin layer and a decorative layer in contact with the layer. For example, if the curable resin layer itself is one in which the decorative material satisfies the mechanical strength required by the application, the curable resin layer and the decorative layer (pattern layer or the like) in contact with the curable resin layer may be used. It is a cosmetic material. In the case where the mechanical strength required for the decorative material cannot be obtained by the curable resin layer itself, for example, a layer other than the curable resin layer such as a resin layer or a wood layer may be laminated or used as another member. By fixing, a curable resin decorative material having mechanical strength suitable for the intended use can be obtained.
The other layer may be laminated with a transparent resin layer or the like to provide a protective function or other decorative effect. When the adhesion is insufficient when the other layer is laminated on the curable resin layer, the above-mentioned carboxyl-modified vinyl chloride-vinyl acetate copolymer is used, depending on the material of the other layer. If the used easy-adhesion layer is used as a layer in contact with the curable resin layer, the adhesion can be improved. For example, there is a case where a thermoplastic resin sheet is laminated as another layer. The curable resin layer may be a single layer or a multilayer such as two layers.
For example, a configuration in which a pattern layer using the above specific resin as a binder is provided between hardening resin layers of the same quality.

As described above, the layer structure of the curable resin decorative material of the present invention may have various forms. FIG. 2 shows a decorative material base material as the lowermost layer as one form of the curable resin decorative material of the present invention. It is sectional drawing which shows the structure using. The curable resin decorative material 20 shown in the figure includes an adhesive layer 22, a colored concealing layer 23, a first curable resin layer 24, a pattern layer 25, and a second curable resin layer 26 on a decorative material base 21. It is a laminated structure. The second curable resin layer is a colorless or colored transparent layer because it is an upper layer of the pattern layer 25. In various embodiments of the present invention, for example, the first curable resin layer is located immediately below the pattern layer 25, and thus may be a colored concealing layer for concealing the color of the decorative material base 21 and the like. In this case, the colored concealing layer 23 can be omitted as appropriate. Further, the first and second curable resin layers may be made of the same unsaturated polyester resin layer or the like, for example, and may be made of different layers in addition to the same layers. Further, the second curable resin layer may be a thermoplastic resin layer.

Hereinafter, the constituent materials of each layer will be described with reference to FIG.

The decorative material base material 21 is appropriately used for imparting mechanical strength for maintaining the shape of the decorative material, such as particle board, MDF (Mid Density).
Wood board such as Fiber Board), wood veneer, wood plywood, etc., glass, ceramics such as ceramics, plate material such as cement board such as ALC, plate material such as polypropylene, phenolic resin, metal such as iron and aluminum A plate or a three-dimensional article made of these various materials, such as resin molding, is used. For example, a wood fiber board such as a particle board having a thickness of about 5 to 30 mm is used.

The adhesive layer 22 is for fixing a fibrous base material such as titanium paper as a colored concealing layer 23 thereon to a decorative board base material. For the adhesive layer, an appropriate material suitable for the decorative material base 21 and the colored concealing layer 23 is used. Conventionally known curable adhesives such as urethane resins, acrylic resins, polyester resins, and vinyl chloride-vinyl acetate resins, thermoplastic adhesives, and the like are used. In addition, the colored concealing layer 23 has a background color or the like of the surface of the base material to which the decorative material is applied if the decorative material substrate is not laminated on the decorative plate substrate or the decorative material itself.
This is a layer for hiding so as not to adversely affect the color and pattern of the cosmetic material. As a colored concealing layer, titanium paper containing titanium oxide having a strong concealing property is a preferable one.

The curable resin layers 24 and 26 are formed of a curable resin such as a melamine resin, a diallyl phthalate resin, an acrylic resin, a guanamine resin, an unsaturated polyester resin, an epoxy resin, a polyurethane resin, and, if necessary, a polymerization initiator, It is a resin layer obtained by curing a composition to which a crosslinking agent, a filler such as an extender pigment, a coloring agent, and the like are added, by heat or the like, and appropriately crosslinking. The curable resin layer is a thermosetting resin layer by its curing mechanism, or radical polymerization or polymerization such as cationic polymerization by ionizing radiation such as ultraviolet rays,
It also includes a curable resin layer cured by other than heat.

For example, when the curable resin layer is an unsaturated polyester resin layer, the unsaturated polyester resin liquid is cured. The unsaturated polyester resin liquid is generally obtained by mixing a composition of an uncured unsaturated polyester resin prepolymer and a polymerization initiator with a polymerization accelerator and various other known additives as needed. As the polymerization initiator, for example, peroxides such as methyl ethyl ketone peroxide, benzoyl peroxide and hydroperoxide, radical polymerization initiators such as azobisisobutyronitrile and the like are appropriately selected and used. The amount of the polymerization initiator to be added is generally 0.1 to the resin.
5 to 3% by weight. As the polymerization accelerator, for example, a cobalt compound such as cobalt naphthenate, a metal compound such as a vanadium compound or a manganese compound, or an amine compound such as dimethyl nitrile is preferably added in an amount of 0.1 to 2% by weight based on the resin. Used in quantity. Further, a vinyl monomer having a vinyl group such as a styrene monomer is added to the resin in an amount of 1% in order to adjust the viscosity by crosslinking the resin.
You may add in the ratio of 0-40 weight%.

The curable resin layer has a fibrous material in the curable resin layer so as to have mechanical strength and the like as a decorative material.
Alternatively, a filler such as an inorganic powder can be contained. Examples of fibers include organic fibers such as acrylic, nylon, polyester, polyethylene, polypropylene, rayon, acetate, vinyl chloride, cellulose, vinylon, and pulp, glass fibers, asbestos, potassium titanate fibers, alumina fibers, silica fibers, and carbon fibers. And other inorganic fibers. These fibrous materials may be contained in a resin solution for forming a curable resin layer as short fibers, such as chopped strand glass fibers, or, for mats, nonwoven fabrics, woven fabrics, pulp, etc., titanium paper, Japanese paper, etc. A sheet-like fibrous base material such as paper is formed, and the fibrous base material is impregnated with a curable resin liquid by coating or the like to form a curable resin layer composed of a composite with a curable resin. Examples of fillers such as inorganic powders include extenders such as calcium carbonate, silica, alumina, and barium sulfate.

The curable resin decorative material of the present invention is a laminate having at least one curable resin layer and a decorative layer in contact with the layer. The curable resin layer may be a multilayer of two or more layers. Alternatively, a laminate of one or more curable resin layers and another resin layer such as thermoplastic or another material layer may be used. The resin layer such as the curable resin layer or another resin layer may be a colorless or colored transparent layer, or a colorless or colored opaque layer when it is located below the pattern layer. The coloring material to be contained in the resin layer such as the curable resin layer for coloring includes inorganic pigments such as titanium white, zinc white, red iron oxide, vermilion, ultramarine, cobalt blue, titanium yellow, graphite, and carbon black. , Isoindolinone, Hansa Yellow A, quinacridone, permanent red 4R, phthalocyanine blue, indathrene blue RS, aniline black and other organic pigments (or dyes), aluminum, brass and other metal pigments, titanium dioxide coated mica, base A known coloring material such as a pearlescent (pearl) pigment made of a foil powder such as a conductive lead carbonate can be used.

In the curable resin decorative material of the present invention, the transfer sheet of the present invention described above can be used for laminating a pattern layer in contact with the curable resin layer. However, the pattern layer in contact with the curable resin layer, or the pattern layer as a configuration not in contact with the curable resin layer, other than the transfer printing method using the transfer sheet or the like, may be formed directly by printing or coating on the curable resin layer. . When the curable resin layer is in a liquid state before complete curing, it is limited in that it cannot be directly formed.However, even in the direct printing method, if the curable resin layer is in a solid state before complete curing, or after complete curing. Then, a pattern layer can be formed.

Accordingly, the curable resin decorative material of the present invention can be used as a flat decorative plate having a flat or curved surface, or a three-dimensional decorative material, such as a ceiling, a floor, a wall around a kitchen, a bathroom or the like.
Other interior materials for buildings such as walls, furniture such as window frames, doors, handrails, furniture such as desks, wash basins, kitchen utensils, cabinets for light electric / OA equipment, vehicle interior materials such as cars, trains, aircraft, etc. , Window glass and the like.

[0028]

EXAMPLES Hereinafter, the present invention will be described more specifically with reference to Examples.

<< Examples and Comparative Examples 1-4 >> A polyethylene terephthalate film having a thickness of 50 µm (T-100 manufactured by Diafoil Hoechst Co., Ltd.) as a releasable support.
Then, a pattern layer to be a transfer layer was formed by gravure printing with a wood grain pattern using inks of various binder resin systems shown in Table 1 to obtain transfer sheets of Examples and Comparative Examples. And, using a waterproof plywood with a thickness of 10 mm as a decorative material base material,
On top of this, a white titanium paper was adhered as a colored concealing layer with a vinyl acetate emulsion adhesive, and from above, 99 parts of an unsaturated polyester resin (manufactured by Showa Polymer Co., Ltd., Rigolac) was applied to a curing agent (Showa Kako). A curable resin solution to which 1 part of Kayamake (manufactured by Kagaku Co., Ltd.) was added was applied and impregnated into titanium paper. The application of the curable resin liquid is such that the resin liquid remains as a layer on the titanium paper even after the impregnation, and further covers the resin liquid surface on the titanium paper so that the pattern layer as a transfer layer is in contact with the transfer sheet obtained above, After leaving at room temperature for 1 hour, the release support of the transfer sheet was peeled off, and the wood-grain pattern layer was transferred to a curable resin layer on titanium paper before complete curing to form a decorative layer. Next, a curable resin liquid of the same unsaturated polyester resin as described above is applied to the entire surface of the curable resin layer on which the transfer layer is formed, to form another (transparent) curable resin layer. The flat curable resin decorative plates of Examples and Comparative Examples having two curable resin layers were obtained.

<< Evaluation of Performance >> The performance of the curable resin decorative board obtained above was evaluated with respect to warm water resistance and hot water resistance.
The hot water resistance was evaluated after immersion in hot water at 80 ° C. for 24 hours, and the hot water resistance was evaluated after immersion in boiling water for 1 hour. The evaluation criteria are as follows: ○ if there is no peeling or change in appearance between layers (between the pattern layer and the curable resin layer) after immersion; Δ if partial blistering or whitening has occurred between layers; The sample that was peeled was evaluated as x. As a result, as shown in Table 1, the decorative material in which the pattern layer was formed as a layer in contact with the curable resin layer using the carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder was excellent in both warm water resistance and hot water resistance. High durability.

[0031]

[Table 1]

In Table 1, * 1, * 2 is abbreviation of vinyl chloride-vinyl acetate copolymer. * 1 The binder resin has a copolymerization ratio of vinyl chloride / vinyl acetate / maleic acid = 81/1
7/2 (weight ratio), carboxyl group content = 1.6% by weight. * 2 The binder resin has a copolymerization ratio of vinyl chloride / vinyl acetate = 81/19 (weight ratio).

[0033]

According to the present invention, in a curable resin decorative material such as a polyester resin decorative plate, a specific resin is used as a binder of a layer such as a pattern layer in contact with the curable resin layer. It is possible to obtain a curable resin decorative material having excellent adhesion between the resin and the curable resin layer, and particularly excellent in interlayer adhesion in water resistance such as warm water resistance and boiling water resistance.

[Brief description of the drawings]

FIG. 1 is a cross-sectional view showing one embodiment of a transfer sheet for a curable resin decorative material of the present invention.

FIG. 2 is a cross-sectional view showing one embodiment of the curable resin decorative material of the present invention.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Release support 2 Transfer layer 10 Transfer sheet for curable resin decorative materials 20 Curable resin decorative material 21 Decorative material base material 22 Adhesive layer 23 Color hiding layer 24 First curable resin layer 25 Pattern layer (decoration layer) ) 26 Second curable resin layer

Claims (2)

[Claims] 1. A transfer sheet for a curable resin decorative material, wherein at least a layer of the transfer layer which is in contact with the transfer object uses a carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder. 2. A curable resin comprising a curable resin layer and a decorative layer, wherein at least a layer of the decorative layer in contact with the curable resin layer comprises a layer containing a carboxyl-modified vinyl chloride-vinyl acetate copolymer as a binder. Resin cosmetics.