JPH10279457A - Perfume stabilizing composition - Google Patents
Perfume stabilizing compositionInfo
- Publication number
- JPH10279457A JPH10279457A JP9844697A JP9844697A JPH10279457A JP H10279457 A JPH10279457 A JP H10279457A JP 9844697 A JP9844697 A JP 9844697A JP 9844697 A JP9844697 A JP 9844697A JP H10279457 A JPH10279457 A JP H10279457A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- acid ester
- keto acid
- present
- ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、香料安定化組成物
に関する技術分野に属する。より詳細には、光に対して
不安定な、その構造中にケト酸エステルを有する有香物
質を組成物中に含む場合に、この有香物質と長波長紫外
線吸収能を有する紫外線吸収剤を組み合わせて配合する
ことにより、この有香物質の安定性を向上させた香料安
定化組成物に関する技術分野に属する発明である。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention belongs to the technical field of perfume stabilizing compositions. More specifically, when the composition contains a scented substance which is unstable to light and has a keto acid ester in its structure, the scented substance and an ultraviolet absorber having a long-wavelength ultraviolet absorption ability are used. This is an invention belonging to the technical field related to a perfume stabilizing composition in which the stability of this scented substance is improved by being combined and combined.
【０００２】[0002]
【従来の技術】香料は、様々な理由から様々な態様で用
いられている。例えば、化粧品においては、化粧品に
豊かな香りをもたせ、それを使う人の魅力を引出す、
化粧品基剤原料等固有のにおいのマスキング、香りに
よる心理面，生理面の高揚等を目的として香料が配合さ
れている。この香料が有する香りは、原則として経時的
に一定であることが理想的であるが、残念ながら熱や光
に対して不安定な有香物質が多いことも現実である。BACKGROUND OF THE INVENTION Fragrances are used in various ways for various reasons. For example, in cosmetics, cosmetics have a rich aroma and bring out the appeal of those who use it.
Fragrances are blended for the purpose of masking the odor inherent in cosmetic base materials and the like, enhancing psychological and physiological aspects by fragrance, and the like. Ideally, the fragrance of this fragrance is ideally constant over time, but unfortunately, there are many fragrant substances that are unstable to heat and light.
【０００３】[0003]
【発明が解決しようとする課題】そこで、本発明が解決
すべき課題は、経時的に不安定な有香物質の安定化手段
を提供することにある。SUMMARY OF THE INVENTION An object of the present invention is to provide a means for stabilizing a fragrant substance which is unstable with time.
【０００４】[0004]
【課題を解決するための手段】本発明者は、この課題の
解決に向けて検討を重ねた結果、その構造中にケト酸エ
ステルを有する有香物質は特に光に対して不安定である
ことを見出し、その安定化手段について、さらに鋭意検
討を行った。その結果、これらの有香物質と長波長紫外
線吸収能を有する紫外線吸収剤とを共存させることによ
り、これらの有香物質による光による変質を防ぎ、経時
的安定性を飛躍的に向上させ得ることを見出し本発明を
完成した。すなわち、本発明者は本願において以下の発
明を提供する。Means for Solving the Problems As a result of repeated investigations toward solving this problem, the present inventor has found that a scented substance having a keto acid ester in its structure is particularly unstable to light. Were found, and further studies were made on the stabilizing means. As a result, by coexistence of these odorants and an ultraviolet absorber having a long-wavelength ultraviolet absorption ability, deterioration by light due to these odorants can be prevented, and the stability over time can be dramatically improved. And completed the present invention. That is, the present inventor provides the following invention in the present application.
【０００５】請求項１において、その構造中にケト酸エ
ステルを有する有香物質と長波長紫外線吸収能を有する
紫外線吸収剤とを含んでなる香料安定化組成物を提供す
る。[0005] In the first aspect, there is provided a fragrance-stabilizing composition comprising a scented substance having a keto acid ester in its structure and an ultraviolet absorber having a long-wavelength ultraviolet absorption ability.
【０００６】請求項２において、その構造中にケト酸エ
ステルを有する有香物質が、アセト酢酸エチル，ピルビ
ン酸エチル，ピルビン酸イソアミル及びレプリン酸エチ
ルからなる群の有香物質のいずれかの有香物質である前
記請求項１記載の香料安定化組成物を提供する。[0006] In claim 2, the scented substance having a keto acid ester in its structure is any of scented substances of the group consisting of ethyl acetoacetate, ethyl pyruvate, isoamyl pyruvate and ethyl replate. 2. A perfume stabilizing composition according to claim 1 which is a substance.
【０００７】請求項３において、その構造中にケト酸エ
ステルを有する有香物質が、アセト酢酸エチルである前
記請求項１記載の香料安定化組成物を提供する。According to a third aspect of the present invention, there is provided the fragrance-stabilizing composition according to the first aspect, wherein the scented substance having a keto acid ester in its structure is ethyl acetoacetate.
【０００８】請求項４において、長波長紫外線吸収能を
有する紫外線吸収剤が、４−tert−ブチル−４’−メト
キシジベンゾイルメタンである前記請求項１乃至請求項
３のいずれかの請求項記載の香料安定化組成物を提供す
る。[0008] In claim 4, the ultraviolet absorber having a long-wavelength ultraviolet absorption ability is 4- tert -butyl-4'-methoxydibenzoylmethane. Perfume stabilizing composition.
【０００９】[0009]
【発明の実施の形態】以下、本発明の実施の形態につい
て説明する。本発明組成物における安定化の対象となる
「その構造中にケト酸エステルを有する有香物質」は、
この化学構造の有香物質（香料の原料となり得る香りを
発生する物質）である限り特に限定されるものではな
い。Embodiments of the present invention will be described below. The subject of stabilization in the composition of the present invention "a scented substance having a keto acid ester in its structure"
It is not particularly limited as long as it is a scented substance having this chemical structure (a substance that generates a scent that can be a raw material of a fragrance).
【００１０】例えば、下記式で表されるアセト酢酸エチ
ル（甘くラム様の香気を有する無色の液体で，様々な果
実フレーバー，ウイスキーのエッセンス，フローラル系
調合香料に用いられている）：For example, ethyl acetoacetate represented by the following formula (a colorless liquid having a sweet and rum-like scent, which is used in various fruit flavors, whiskey essences, and floral compound flavors):
【００１１】[0011]
【化１】 Embedded image
【００１２】下記式で表されるピルビン酸エチル（甘い
カラメル様香気を有する無色の液体で，ラム等のフレー
バーとして用いられている）：Ethyl pyruvate represented by the following formula (a colorless liquid having a sweet caramel-like odor and used as a flavor of rum and the like):
【００１３】[0013]
【化２】 Embedded image
【００１４】下記式で表されるピルビン酸イソアミル
（カラメル様香気を有する無色の液体で，メープル，ラ
ム等のフレーバーに用いられている）：Isoamyl pyruvate represented by the following formula (a colorless liquid having a caramel-like odor and used for flavors such as maple and rum):
【００１５】[0015]
【化３】 Embedded image
【００１６】下記式で表されるレブリン酸エチル（甘く
ラム様のフルーティな香気を有する無色の液体で、様々
な果実フレーバー等に用いられている）：Ethyl levulinate represented by the following formula (a colorless liquid having a sweet, lamb-like fruity aroma and used in various fruit flavors, etc.):
【００１７】[0017]
【化４】 等を例示することができる。Embedded image And the like.
【００１８】これらの有香物質のうち、特にアセト酢酸
エチルは光による劣化が顕著であり、本発明の対象とな
る有香物質としては特に好適である。Of these odorants, ethyl acetoacetate, in particular, is remarkably deteriorated by light, and is particularly suitable as the odorant to be used in the present invention.
【００１９】上記の「その構造中にケト酸エステルを有
する有香物質」と共に本発明組成物中に配合する長波長
紫外線吸収能を有する紫外線吸収剤も、この長波長紫外
線（ＵＶ−Ａ）吸収能がある限りにおいて特に限定され
ず、例えばオキシベンゾン，ジオキシベンゾン，オキシ
ベンゾンスルホン酸，メキセノン，２−（４−フェニル
ベンゾイル）安息香酸２−エチルヘキシル等のベンゾフ
ェノン誘導体；４−tert−ブチル−４’−メトキシジベ
ンゾイルメタン、１−（４−tert−ブチルフェニル−３
−（４−メトキシフェニル）プロパン−１，３−ジオ
ン、１−ｐ−クメニル−３−フェニルプロパン−１，３
−ジオン、１，３−ビス（４−メトキシフェニル）プロ
パン−１，３−ジオン等のジベンゾイルメタン；アント
ラニル酸メチル、Ｎ−アセチルアントラニル酸ホモメン
チル等のアントラニル酸誘導体等を広く選択することが
できる。The long-wavelength ultraviolet ray (UV-A) absorbing agent, which is used in the composition of the present invention together with the above-mentioned "fragrant substance having a keto acid ester in its structure", has a long-wavelength ultraviolet ray absorbing ability. Benzophenone derivatives such as oxybenzone, dioxybenzone, oxybenzonesulfonic acid, mexenone, 2-ethylhexyl 2- (4-phenylbenzoyl) benzoate; 4- tert -butyl-4'-methoxy Dibenzoylmethane, 1- (4- tert -butylphenyl-3)
-(4-methoxyphenyl) propane-1,3-dione, 1-p-cumenyl-3-phenylpropane-1,3
Dibenzoylmethane such as -dione and 1,3-bis (4-methoxyphenyl) propane-1,3-dione; and anthranilic acid derivatives such as methyl anthranilate and homomenthyl N-acetylanthranilate can be widely selected. .
【００２０】なお、本発明において選択され得るＵＶ−
Ａ吸収剤は、所望するＵＶ−Ａ吸収能さえ有していれ
ば、中波長紫外線（ＵＶ−Ｂ）吸収能があるか否かは問
題とはならない。It should be noted that UV-UV which can be selected in the present invention is
It does not matter whether or not the A-absorbent has medium-wavelength ultraviolet (UV-B) absorption as long as it has the desired UV-A absorption.
【００２１】上記のＵＶ−Ａ吸収剤の中で、特に４−te
rt−ブチル−４’−メトキシジベンゾイルメタンは、上
記有香物質と組み合わせた場合の光変質防御効果が高
く、選択するのに好ましいＵＶ−Ａ吸収剤である。Among the above UV-A absorbers, in particular, 4- te
rt -Butyl-4'-methoxydibenzoylmethane is a UV-A absorber which has a high photo-alteration protection effect when combined with the above-mentioned odorant and is a preferable UV-A absorber for selection.
【００２２】本発明組成物における有香物質とＵＶ−Ａ
吸収剤との配合比率は、重量比で有香物質１に対してＵ
Ｖ−Ａ吸収剤が０．１〜１０．０の範囲であり、同ＵＶ
−Ａ吸収剤が０．５〜５．０の範囲が好ましく、さらに
同ＵＶ−Ａ吸収剤が２．０〜３．０の範囲が特に好まし
い。また、上記のＵＶ−Ａ吸収剤は、単独で本発明組成
物中に配合することができることは勿論であるが、２種
以上を組み合わせて配合することも可能である。The odorant and UV-A in the composition of the present invention
The compounding ratio with the absorbent is such that the weight ratio of U
The VA absorber is in the range of 0.1 to 10.0, and the UV
-A absorber is preferably in the range of 0.5 to 5.0, and the UV-A absorber is particularly preferably in the range of 2.0 to 3.0. The UV-A absorber described above can be used alone in the composition of the present invention, but may be used in combination of two or more.
【００２３】上記のごとく、その構造中にケト酸エステ
ルを有する有香物質とＵＶ−Ａ吸収能を有する紫外線吸
収剤とを含んでなる本発明組成物は、この有香物質の光
による変質を排除することが可能である。よって、本発
明組成物が化粧品等に配合する前段階の形態をとる場合
は、主にその光に対する管理を簡略化することが可能で
ある。そして、化粧品や香水等の形態を採る場合におい
ては、同様に管理を簡略化することが可能であるばかり
ではなく、その香りに経時的な安定性を付与することが
可能である。As described above, the composition of the present invention, which comprises a scented substance having a keto acid ester in its structure and an ultraviolet absorber having UV-A absorption ability, is capable of preventing the scented substance from being altered by light. It is possible to eliminate. Therefore, when the composition of the present invention is in a form before being incorporated into cosmetics or the like, it is possible to mainly simplify the management of the composition for light. And when taking the form of cosmetics, perfume, etc., not only can the management be similarly simplified, but also the fragrance can be given stability over time.
【００２４】本発明組成物の具体的形態は、「その構造
中にケト酸エステルを有する有香物質」を用いる限り特
に限定されず、この有香物自体，化粧品等の皮膚外用
剤，香水，食品，芳香剤等に広く用いることができる。The specific form of the composition of the present invention is not particularly limited as long as "a scented substance having a keto acid ester in its structure" is used. The scented substance itself, an external preparation for skin such as cosmetics, perfume, It can be widely used for foods, fragrances, etc.
【００２５】よって、これらの形態に応じた他の成分
を、本発明の所期の効果を損なわない限り本発明組成物
中に配合し得ることは勿論可能である。その具体的形態
については、後述する実施例において記載する。Therefore, it goes without saying that other components according to these forms can be incorporated into the composition of the present invention as long as the desired effects of the present invention are not impaired. The specific form will be described in Examples described later.
【００２６】[0026]
【実施例】以下、本発明を実施例により、さらに具体的
に説明するが、この実施例により本発明の技術的範囲が
限定されるべきものではない。EXAMPLES Hereinafter, the present invention will be described more specifically with reference to examples, but the technical scope of the present invention should not be limited by these examples.
【００２７】〔試験例〕本発明組成物の光に対する安定
性の検討 本試験例においては、ＵＶ−Ａ吸収剤として，４−tert
−ブチル−４’−メトキシジベンゾイルメタン（以下，
パルソール１７８９という）及び２−ヒドロキシ−４−
メトキシ−ベンゾフェノン（以下，オキシベンゾンとい
う）を用いた。また、ＵＶ−Ｂ吸収剤として，ジパラメ
トキシケイ皮酸−モノ−２−エチルヘキサン酸グリセリ
ル（以下，サンガードＢという）を用いた。[Test Example] Investigation of the stability of the composition of the present invention to light In this test example, 4- tert.
-Butyl-4'-methoxydibenzoylmethane (hereinafter, referred to as "
Parsol 1789) and 2-hydroxy-4-
Methoxy-benzophenone (hereinafter referred to as oxybenzone) was used. Glyceryl diparamethoxycinnamate-mono-2-ethylhexanoate (hereinafter, referred to as Sunguard B) was used as a UV-B absorber.
【００２８】これらの紫外線吸収剤とアセト酢酸エチル
を、下記第１表に示す配合比率で混合して、これらの組
成物を試験品として、キセノンランプ〔キセノンロング
ライフ・フェードメーター（型式：ＦＡＬ−２５ＸＬ型
（スガ試験機株式会社製）〕を光源とする紫外線を、６
０時間又は９０時間照射して（１時間当り１MJ/m2 ）試
験品の変臭の度合いを，以下の基準による官能試験を行
って評価した。These ultraviolet absorbers and ethyl acetoacetate were mixed at the compounding ratios shown in Table 1 below, and these compositions were used as test articles, and tested with a xenon lamp [xenon long life fade meter (model: FAL- 25XL type (manufactured by Suga Test Instruments Co., Ltd.)]
Irradiation was performed for 0 hour or 90 hours (1 MJ / m 2 per hour), and the degree of unpleasant odor of the test product was evaluated by performing a sensory test according to the following criteria.
【００２９】変臭の度合い ○：全く変臭していない △：やや変臭している ×：変臭しているDegree of unpleasant odor ：: No odor at all △: Slightly odor x: Slight odor
【００３０】この試験に結果等を第１表に示す。Table 1 shows the results of the test.
【表１】 ＊：重量比でアセト酢酸エチル（有香物質）１．０に対
して，ＵＶ吸収剤を１．０の割合で混ぜたものを，メタ
ノールに１．０％の割合で溶かしたもの ＊＊：重量比でアセト酢酸エチル（有香物質）１．０に
対して，ＵＶ吸収剤を２．０の割合で混ぜたものを，エ
タノールに１．０％の割合で溶かしたもの[Table 1] *: Ethyl acetoacetate (scented substance) 1.0 in weight ratio, mixed with UV absorber at a ratio of 1.0, and dissolved in methanol at a ratio of 1.0% **: Ethyl acetoacetate (scented substance) 1.0 by weight ratio, UV absorber mixed at a ratio of 2.0, dissolved in ethanol at a ratio of 1.0%
【００３１】この結果より、ＵＶ−Ａ吸収剤を上記有香
物質とを組み合わせることにより、紫外線により惹起さ
れる有香物質の変臭を非常に有効に防止し得ることを見
出した（ＵＶ−Ｂ吸収剤であるサンガードＢと組み合わ
せた試験品においては変臭を防御することができなかっ
た）。また、ＵＶ−Ａ吸収剤の中でもパルソール１７８
９を選択することが特に好ましいことが明らかになっ
た。From these results, it has been found that by combining the UV-A absorber with the above-mentioned odorant, it is possible to very effectively prevent the smell of the odorant caused by ultraviolet rays (UV-B The test article in combination with SunGard B, which is an absorbent, could not protect against odor.) Also, among the UV-A absorbers, Parsol 178 is used.
It has been found that the choice of 9 is particularly preferred.
【００３２】以下、様々な形態の本発明組成物を例示す
る。なお、これらの本発明組成物は全て、ＵＶ−Ａ吸収
剤を配合しない比較例と比べると上記試験において、変
臭の度合いは少なく、評価は「○」であった。Hereinafter, various forms of the composition of the present invention will be exemplified. In addition, all of the compositions of the present invention had a lower degree of unpleasant odor in the above test than the comparative example in which the UV-A absorber was not blended, and the evaluation was “○”.
【００３３】まず、下記の配合成分を混合して香料組成
物ａ）を調製した。 香料組成物ａ） （配合成分） 重量％ パルーソール１７８９ ３０．０ Ｌｉｍｏｎｅｎｅ ２０．０ Triethyl Citrate ２０．０ Ethylene brassylate ２０．０ （Musk T) アセト酢酸エチル １０．０ ─────── １００．０First, a perfume composition a) was prepared by mixing the following ingredients. Perfume composition a) (Ingredients)% by weight Parousole 1789 30.0 Limonene 20.0 Triethyl Citrate 20.0 Ethylene brassylate 20.0 (Musk T) Ethyl acetoacetate 10.0 ─────── 100.0
【００３４】この香料組成物ａ）を下記の組成の本発明
組成物中に配合した。 〔実施例１〕 香水 （配合成分） 重量％ エタノール ９８．０ 黄色５号 ０．００００３ 黄色２０３号 ０．００００７ 精製水 ０．９９９９ 香料組成物ａ） １．０ ─────── １００．０ この組成の香水を常法により調製した。This fragrance composition a) was incorporated into the present composition having the following composition. [Example 1] Perfume (components)% by weight Ethanol 98.0 Yellow 5 0.00003 Yellow 203 0.00007 Purified water 0.9999 Perfume composition a) 1.0 組成 100. 0 A perfume of this composition was prepared by a conventional method.
【００３５】 〔実施例２〕 クリーム （配合成分） 重量％ ステアリン酸 ８．０ ステアリルアルコール ４．０ ステアリン酸ブチル ６．０ プロピレングリコール ５．０ モノステアリン酸グリセリン ２．０ 水酸化カリウム ０．４ 精製水 ７４．１ 香料組成物ａ） ０．５ ─────── １００．０ この組成のクリームを常法により調製した。Example 2 Cream (Ingredients) Weight% Stearic Acid 8.0 Stearyl Alcohol 4.0 Butyl Stearate 6.0 Propylene Glycol 5.0 Glycerin Monostearate 2.0 Potassium Hydroxide 0.4 Purification Water 74.1 Fragrance composition a) 0.5───────100.0 A cream of this composition was prepared in a conventional manner.
【００３６】 〔実施例３〕 化粧水 （配合成分） 重量％ １，３−ブチレングリコール ６．０ グリセリン ４．０ オレイルアルコール ０．１ ソルビタンモノラウリン酸エステル ０．５ ラウリルアルコールエーテル ０．５ 精製水 ８８．８ 香料組成物ａ） ０．１ ─────── １００．０ この組成の化粧水を常法により調製した。[Example 3] Lotion (Blending component)% by weight 1,3-butylene glycol 6.0 Glycerin 4.0 Oleyl alcohol 0.1 Sorbitan monolaurate 0.5 Lauryl alcohol ether 0.5 Purified water 88 0.8 Fragrance composition a) 0.1 100.0 A lotion of this composition was prepared by a conventional method.
【００３７】[0037]
【発明の効果】本発明により、光に対して不安定な、そ
の構造中にケト酸エステルを有する有香物質の安定性を
向上させた香料安定化組成物が提供される。According to the present invention, there is provided a fragrance-stabilized composition in which the stability of a scented substance which is unstable to light and has a keto acid ester in its structure is improved.
Claims (4)
物質と長波長紫外線吸収能を有する紫外線吸収剤とを含
んでなる香料安定化組成物。1. A fragrance-stabilizing composition comprising a scented substance having a keto acid ester in its structure and an ultraviolet absorber having an ability to absorb long-wavelength ultraviolet rays.
物質が、アセト酢酸エチル，ピルビン酸エチル，ピルビ
ン酸イソアミル及びレプリン酸エチルからなる群の有香
物質のいずれかの有香物質である請求項１記載の香料安
定化組成物。2. A scented substance having a keto acid ester in its structure is one of the scented substances of the group consisting of ethyl acetoacetate, ethyl pyruvate, isoamyl pyruvate and ethyl replate. A perfume stabilizing composition according to claim 1.
物質が、アセト酢酸エチルである請求項１記載の香料安
定化組成物。3. The fragrance-stabilizing composition according to claim 1, wherein the scented substance having a keto acid ester in its structure is ethyl acetoacetate.
が、４−tert−ブチル−４’−メトキシジベンゾイルメ
タンである請求項１乃至請求項３のいずれかの請求項記
載の香料安定化組成物。4. The fragrance stabilizer according to claim 1, wherein the ultraviolet absorber having a long-wavelength ultraviolet absorption ability is 4- tert -butyl-4′-methoxydibenzoylmethane. Composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9844697A JPH10279457A (en) | 1997-03-31 | 1997-03-31 | Perfume stabilizing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9844697A JPH10279457A (en) | 1997-03-31 | 1997-03-31 | Perfume stabilizing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH10279457A true JPH10279457A (en) | 1998-10-20 |
Family
ID=14219974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9844697A Withdrawn JPH10279457A (en) | 1997-03-31 | 1997-03-31 | Perfume stabilizing composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH10279457A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1994921A1 (en) * | 2007-05-21 | 2008-11-26 | L'Oreal | Fragrance composition comprising the combination of one filter A hydroxyaminobenzophenone, one filter B cinnamate and of one compound C piperidinole, benzotriazole or dibenzoylmethane |
| FR2916347A1 (en) * | 2007-05-21 | 2008-11-28 | Oreal | Perfume composition, useful e.g. as stabilizing agent of organoleptic property of composition against external aggression, comprises substance, hydroxy aminobenzophenone filter, cinnamate filter and compound comprising e.g. piperidinol |
| FR2916346A1 (en) * | 2007-05-21 | 2008-11-28 | Oreal | Perfume composition, useful e.g. as stabilizing agent of organoleptic property of composition against external aggression, comprises substance, hydroxy aminobenzophenone filter, cinnamate filter and compound comprising e.g. piperidinol |
| WO2009059872A1 (en) * | 2007-11-09 | 2009-05-14 | L'oreal | Fragrancing composition comprising a combination of a benzotriazole compound, a uva screening agent of the dibenzoylmethane type and a particular uvb screening system |
| FR2923386A1 (en) * | 2007-11-09 | 2009-05-15 | Oreal | Composition, useful e.g. for perfuming keratin materials e.g. skin, comprises perfume substance, benzotriazole compound, and UV filter of dibenzoylmethane and alkyl beta,beta'-diphenylacrylate/alkyl alpha-cyano-beta,beta'-diphenylacrylate |
| FR2923385A1 (en) * | 2007-11-09 | 2009-05-15 | Oreal | Composition, useful e.g. for perfuming human keratin materials e.g. skin, lips and integument, comprises perfume substance, benzotriazole compound, cinnamate type UV filter, dibenzoylmethane type UV filter and salicylate type UV filter |
| JP2010013424A (en) * | 2008-07-07 | 2010-01-21 | Kao Corp | Perfume composition for skin cosmetic |
| KR101400355B1 (en) * | 2012-09-03 | 2014-05-27 | 주식회사 사임당화장품 | Composition having improved light stability of natural materials |
| WO2023247298A1 (en) * | 2022-06-21 | 2023-12-28 | Firmenich Sa | Compositions for preventing, reducing, or ameliorating malodorous aldehydes and ketones, and uses thereof |
-
1997
- 1997-03-31 JP JP9844697A patent/JPH10279457A/en not_active Withdrawn
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1994921A1 (en) * | 2007-05-21 | 2008-11-26 | L'Oreal | Fragrance composition comprising the combination of one filter A hydroxyaminobenzophenone, one filter B cinnamate and of one compound C piperidinole, benzotriazole or dibenzoylmethane |
| FR2916347A1 (en) * | 2007-05-21 | 2008-11-28 | Oreal | Perfume composition, useful e.g. as stabilizing agent of organoleptic property of composition against external aggression, comprises substance, hydroxy aminobenzophenone filter, cinnamate filter and compound comprising e.g. piperidinol |
| FR2916346A1 (en) * | 2007-05-21 | 2008-11-28 | Oreal | Perfume composition, useful e.g. as stabilizing agent of organoleptic property of composition against external aggression, comprises substance, hydroxy aminobenzophenone filter, cinnamate filter and compound comprising e.g. piperidinol |
| WO2009059872A1 (en) * | 2007-11-09 | 2009-05-14 | L'oreal | Fragrancing composition comprising a combination of a benzotriazole compound, a uva screening agent of the dibenzoylmethane type and a particular uvb screening system |
| FR2923386A1 (en) * | 2007-11-09 | 2009-05-15 | Oreal | Composition, useful e.g. for perfuming keratin materials e.g. skin, comprises perfume substance, benzotriazole compound, and UV filter of dibenzoylmethane and alkyl beta,beta'-diphenylacrylate/alkyl alpha-cyano-beta,beta'-diphenylacrylate |
| FR2923385A1 (en) * | 2007-11-09 | 2009-05-15 | Oreal | Composition, useful e.g. for perfuming human keratin materials e.g. skin, lips and integument, comprises perfume substance, benzotriazole compound, cinnamate type UV filter, dibenzoylmethane type UV filter and salicylate type UV filter |
| JP2010013424A (en) * | 2008-07-07 | 2010-01-21 | Kao Corp | Perfume composition for skin cosmetic |
| KR101400355B1 (en) * | 2012-09-03 | 2014-05-27 | 주식회사 사임당화장품 | Composition having improved light stability of natural materials |
| WO2023247298A1 (en) * | 2022-06-21 | 2023-12-28 | Firmenich Sa | Compositions for preventing, reducing, or ameliorating malodorous aldehydes and ketones, and uses thereof |
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