JPH10251799A - Steel sheet for easy-open can top excellent in top openability and rivet formability, its production and easy-open can top - Google Patents

Steel sheet for easy-open can top excellent in top openability and rivet formability, its production and easy-open can top

Info

Publication number
JPH10251799A
JPH10251799A JP5778697A JP5778697A JPH10251799A JP H10251799 A JPH10251799 A JP H10251799A JP 5778697 A JP5778697 A JP 5778697A JP 5778697 A JP5778697 A JP 5778697A JP H10251799 A JPH10251799 A JP H10251799A
Authority
JP
Japan
Prior art keywords
less
lid
easy
open
steel sheet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5778697A
Other languages
Japanese (ja)
Other versions
JP3740779B2 (en
Inventor
Akio Tosaka
章男 登坂
Kazunori Osawa
一典 大沢
Masatoshi Araya
昌利 荒谷
Hideo Kukuminato
英雄 久々湊
Makoto Araya
誠 荒谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP05778697A priority Critical patent/JP3740779B2/en
Publication of JPH10251799A publication Critical patent/JPH10251799A/en
Application granted granted Critical
Publication of JP3740779B2 publication Critical patent/JP3740779B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

PROBLEM TO BE SOLVED: To obtain a steel sheet for an easy-open can cover excellent in pressure resistance, corrosion resistance, impact resistance, cover openability and revert formability by specifying the compsn. in which the contents of C, B, Al and O are regulated and composed of C, Si, Mn, S, B, Al, N, O and Fe. SOLUTION: This steel sheet for an easy-open can cover is the one having a compsn. in which the contents of C and Al are regulated, contg., by weight, <=0.02% C, <=0.05% Si, <=0.6% Mn, <=0.020% S, 0.010 to 0.020% B, <=0.010% Al, <=0.02% N and 0.010 to 0.030% O, furthermore contg., at need, prescribed amounts of Nb, Ti Cr and Mo and the balance Fe with inevitable impurities, and the average grain size of B oxides is preferably regulated to 0.1 to 20μm. This steel sheet is obtd. by subjecting a steel slab having the above componental compsn. to hot rolling at >=800 deg.C finishing temp., coiling it at 450 to 700 deg.C, executing primary cold rolling and recrystallization annealing and thereafter subjecting it to secondary cold rolling at <=30% draft.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、イージーオープン
缶の缶蓋に用いて好適な鋼板とその製造方法、および缶
蓋に関し、とくに開蓋性とリベット成形性に優れるイー
ジーオープン缶蓋用鋼板(各種のめっき、有機樹脂塗
装、有機樹脂皮膜等の表面被覆を施したものを含む)と
その製造方法、およびこの鋼板を用いて製造した缶蓋に
関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a steel plate suitable for use as a can lid of an easy-open can, a method for producing the same, and a can lid, and more particularly to a steel plate for an easy-open can lid having excellent openability and rivet forming properties. Various coatings, organic resin coatings, surface coatings such as organic resin films, etc.) and methods for producing the same, and can lids produced using this steel sheet.

【0002】[0002]

【従来の技術】缶詰の缶蓋にスコアとよばれる切れ目を
あらかじめ導入することにより、缶切りなどの特殊な道
具を用いることなしに缶を開け、缶体内部の食品や飲料
を取り出すことができる、いわゆるイージーオープン缶
蓋(イージーオープンエンド、EOE)がビール缶、炭
酸飲料ジュース缶を始めとして、各種の飲料缶および食
缶に使用されている。このような缶蓋のタイプとして
は、開蓋時にいわゆる「てこ」あるいは「把手」の役目
を果すタブが切りとり分離される「プルオフ型」のもの
と、開蓋後もタブが缶に付随した状態となる「ステイオ
ン型」に大別される。また、開蓋部の大きさで分ける
と、開口が缶径に対し部分的に行われるパーシヤルイー
ジーオープンエンドと、ほぼ全体が開蓋されるフルイー
ジーオープンエンドがあり、食缶の多くは後者である。
さて、これらのイージーオープン缶蓋の開けやすさ(以
下、「開蓋性」と略記する)に対して、前述したスコア
加工(開蓋性向上のための切れ目加工)が大きな影響を
及ぼしている。開蓋性は、スコア加工後の板厚の残存量
(スコア残厚)を小さくするほど向上することが知られ
ているが、従来の技術では、工業的に安定して加工する
ことと、内圧上昇に対する耐圧強度の維持という観点か
ら限界があった。すなわち、開蓋性を優先するあまり、
スコア残厚を減少させ過ぎると、加工の際にスコア部分
に亀裂を生じたり、運送、貯蔵などのときに、熱的な内
部圧力の増大や衝撃的な応力の負荷などによってスコア
部が破断し、内容物がもれるといった不具合を生ずる危
険性があった。
2. Description of the Related Art By introducing a cut called a score into a can lid of a can in advance, the can can be opened without using a special tool such as a can opener, and foods and beverages inside the can can be taken out. So-called easy open can lids (Easy Open End, EOE) are used for various beverage cans and food cans, including beer cans, carbonated beverage juice cans, and the like. As a type of such a can lid, there is a "pull-off type" in which a tab serving as a so-called "lever" or "handle" is cut off and separated when the lid is opened, and a state in which the tab is attached to the can after the lid is opened "Stion type". In addition, when divided according to the size of the lid opening part, there are a partial easy open end where the opening is made partially to the can diameter, and a full easy open end where almost the entire opening is opened. It is.
The above-described scoring (cutting for improving the openability) has a great effect on the ease of opening these easy-open can lids (hereinafter abbreviated as "openability"). . It is known that the openability is improved as the remaining thickness of the sheet after score processing (score remaining thickness) is reduced. There is a limit from the viewpoint of maintaining the pressure resistance against the rise. In other words, too much priority on the openability,
If the remaining score is excessively reduced, the score may crack during processing, or the score may break due to an increase in thermal internal pressure or impulsive stress during transportation or storage. However, there is a danger that a problem such as leakage of contents occurs.

【0003】ところで、これらの強度と開蓋性を両立さ
せるために、これまでにも多くの試みが行われてきた。
例えば、特開昭60−56052 号公報や特開昭62−80224 号
公報などに開示の技術がある。しかし、これらの技術で
は、いまだ十分な開蓋性が得られていない。また、開蓋
時の強度を低下させて開蓋性を向上させるために、鋼板
中にボイドの起点を発生させ、破壊クラックがより容易
に進展するように考慮した技術として、例えば特開平1
−116030号公報、特開平2−200754号公報などの方法が
ある。
By the way, many attempts have been made to achieve both the strength and the openability of the cover.
For example, there are techniques disclosed in Japanese Patent Application Laid-Open Nos. 60-56052 and 62-80224. However, with these techniques, sufficient lid opening property has not yet been obtained. Further, in order to reduce the strength at the time of opening the cover and to improve the openability, a starting point of a void is generated in the steel sheet, and a technique considered so that a fracture crack is more easily developed is disclosed in, for example,
-116030, JP-A-2-200754 and the like.

【0004】[0004]

【発明が解決しようとする課題】しかし、これらの技術
においては、Sを0.05wt%以上と極めて多量に添加する
ので、鋼が著しく脆化し、連続鋳造時の種々の割れや熱
間圧延時の割れを招き、また表面性状の劣化をも招き実
用化には至らなかった。このほか、REMを添加する技
術として、特開昭62−93345 号公報が挙げられるが、こ
の技術も同様な問題を抱えていた。しかも、これらの技
術では、Sを含む介在物が腐食の活性点となって、耐食
性を著しく低下させるという、缶材として用いる場合の
本質的な問題もあった。さらに、特開昭62−103341号公
報には、BNを鋼中に分散させることにより、開蓋性を
改善する技術が開示されている。しかし、この方法で
は、未だ開蓋性が十分でなく、さらなる改善が必要とさ
れていた。
However, in these techniques, since S is added in an extremely large amount of 0.05 wt% or more, the steel becomes extremely brittle, and various cracks during continuous casting and various problems during hot rolling. This resulted in cracking and deterioration of the surface properties, and did not lead to practical use. In addition, as a technique for adding REM, Japanese Patent Application Laid-Open No. 62-93345 is cited, but this technique also has a similar problem. In addition, in these techniques, there is also an essential problem when using as a can material, that inclusions containing S become active sites for corrosion and significantly reduce corrosion resistance. Furthermore, Japanese Patent Application Laid-Open No. Sho 62-103341 discloses a technique for improving lid opening properties by dispersing BN in steel. However, this method still has insufficient lid opening properties, and further improvement is required.

【0005】上記した技術によるこれら鉄製イージーオ
ープン缶蓋を実際に適用することを困難にしている他の
要因のひとつは、蓋を成形する際のリベット成形性 (リ
ベットは蓋本体にタブを取り付ける部分であり、蓋材に
三次元的な突起部をプレス加工で形成する) の問題であ
る。というのは、前述したように、開蓋性向上のため
に、鋼中に非金属介在物を多く残存させると、開蓋性が
向上する反面、鋼板のリベット成形性が顕著に劣化する
からである。リベット成形性が劣化すると、イージーオ
ープン缶蓋成形において重要な成形過程である、タブ取
り付けが、鋼板の破断のために困難となる。なお、リベ
ット成形の代替技術として、接着などを用いて、タブを
とりつける方法も提案されているものの、信頼性に今一
つ欠け、デザイン的な制約が大きいという問題も残って
おり採用されるまでには至っていない。
[0005] One of the other factors that makes it difficult to apply these iron easy-open can lids according to the above-described technology is the rivet forming property when forming the lid (the rivet is a part for attaching a tab to the lid body). And forming a three-dimensional projection on the cover material by press working). This is because, as described above, if a large amount of nonmetallic inclusions are left in steel to improve the lid opening property, the lid opening property is improved, but the rivet formability of the steel sheet is significantly deteriorated. is there. When the rivet formability is deteriorated, tab attachment, which is an important forming process in easy open can lid forming, becomes difficult due to breakage of the steel plate. As an alternative technique to rivet molding, a method of attaching tabs using adhesive etc. has also been proposed, but there is still a problem of lack of reliability, and there are still problems such as large design constraints, and before adoption, Not reached.

【0006】そこで、本発明の目的は、従来技術が抱え
ている上記問題点を解決し、開蓋性に優れ、しかもリベ
ット成形性にも優れるイージーオープン缶蓋用鋼板(各
種のめっき、有機樹脂塗装、有機樹脂皮膜等の表面被覆
を施したものを含む)およびその製造方法を提供するこ
とにある。本発明の他の目的は、上記イージーオープン
缶蓋用鋼板を用いて製造した開蓋性に優れた缶蓋を提供
することにある。
Accordingly, an object of the present invention is to solve the above-mentioned problems of the prior art, and to provide an easy-open can lid steel plate (various platings, organic resins, etc.) which has excellent lid opening properties and excellent rivet forming properties. Coating and surface coating such as an organic resin film) and a method for producing the same. Another object of the present invention is to provide a can lid excellent in lid opening property manufactured using the above-mentioned steel plate for an easy-open can lid.

【0007】[0007]

【課題を解決するための手段】発明者らは、上記課題を
解決するために鋭意研究を重ね、缶蓋用鋼板としての好
ましい素材を追求した。その過程で、従来技術におけ
る、素材を単純に脆くするという手法は、均一な材質に
仕上げること自体が困難であること、缶体として組み立
てた後の信頼性が不十分であることが明らかとなった。
そして、鉄の持つ優れた延性を生かしつつ、上記課題を
解決するためには、素材は次のような条件を備える必要
があるとの注目すべき知見を得た。
Means for Solving the Problems The inventors of the present invention have conducted intensive studies in order to solve the above-mentioned problems, and have pursued a preferable material as a steel plate for a can lid. In the process, it has become clear that the conventional technique of simply making a material brittle is difficult to finish to a uniform material itself and that the reliability after assembling as a can is insufficient. Was.
In addition, they have obtained a remarkable finding that the material needs to satisfy the following conditions in order to solve the above-mentioned problem while taking advantage of the excellent ductility of iron.

【0008】1)鋼板のリベット成形性を向上させるた
めには、Cの低減が有効である。 2)Bを0.01wt%以上添加して、B析出物の粒径を0.1
〜20μmの範囲に制御することにより、リベット成形性
の劣化を伴うことなく、開蓋性を顕著に向上させること
ができる。 3)BとOの含有量を適正範囲に制御することが,上記
2)の効果を達成するためには必要である。 4)この時、アルミ含有量を0.01wt%以下に規制するこ
とにより、さらに開蓋性が向上する。 5)さらに製造条件の制御も重要な条件の一つである。 6)鋼板の耐食性が、Mn、Sなどを多量に添加した場合
には劣化するのに対し、B、Oを適正量添加した場合に
は劣化しない。
1) In order to improve the rivet formability of a steel sheet, it is effective to reduce C. 2) Add B in an amount of 0.01 wt% or more to reduce the particle size of the B precipitate to 0.1%.
By controlling the thickness in the range of 2020 μm, the lid opening property can be significantly improved without deterioration of rivet forming property. 3) It is necessary to control the contents of B and O within an appropriate range in order to achieve the above-mentioned effect 2). 4) At this time, by restricting the aluminum content to 0.01 wt% or less, the lid opening property is further improved. 5) Control of manufacturing conditions is also one of the important conditions. 6) The corrosion resistance of the steel sheet deteriorates when a large amount of Mn, S, etc. is added, but does not deteriorate when B and O are added in appropriate amounts.

【0009】以上の知見に基づいて完成された本発明の
要旨構成は以下のとおりである。 (1) C:0.02wt%以下、B:0.010 〜0.020 wt%、Al:
0.010 wt%以下、O:0.010 〜0.030 wt%を含有するこ
とを特徴とする、開蓋性とリベット成形性に優れるイー
ジーオープン缶蓋用鋼板。
The gist configuration of the present invention completed on the basis of the above findings is as follows. (1) C: 0.02 wt% or less, B: 0.010 to 0.020 wt%, Al:
An easy open can lid steel sheet having excellent lid opening properties and rivet forming properties, characterized by containing 0.010 wt% or less and O: 0.010 to 0.030 wt%.

【0010】(2) C:0.02wt%以下、Si:0.05wt%以
下、Mn:0.6 wt%以下、S:0.020 wt%以下、B:0.01
0 〜0.020 wt%、Al:0.010 wt%以下、N:0.02wt%以
下、O:0.010 〜0.030 wt%を含有し、残部がFe及び不
可避的不純物の組成からなることを特徴とする、開蓋性
とリベット成形性に優れるイージーオープン缶蓋用鋼
板。
(2) C: 0.02 wt% or less, Si: 0.05 wt% or less, Mn: 0.6 wt% or less, S: 0.020 wt% or less, B: 0.01
0 to 0.020 wt%, Al: 0.010 wt% or less, N: 0.02 wt% or less, O: 0.010 to 0.030 wt%, with the balance being composed of Fe and inevitable impurities. Steel sheet for easy open can lids that excels in formability and rivet formability.

【0011】(3) C:0.02wt%以下、Si:0.05wt%以
下、Mn:0.6 wt%以下、S:0.020 wt%以下、B:0.01
0 〜0.020 wt%、Al:0.010 wt%以下、N:0.02wt%以
下、O:0.010 〜0.030 wt%を含み、かつNb:0.003 〜
0.02wt%、Ti:0.003 〜0.02wt%の1種または2種を含
有し、残部がFe及び不可避的不純物の組成からなること
を特徴とする、開蓋性とリベット成形性に優れるイージ
ーオープン缶蓋用鋼板。
(3) C: 0.02 wt% or less, Si: 0.05 wt% or less, Mn: 0.6 wt% or less, S: 0.020 wt% or less, B: 0.01
0 to 0.020 wt%, Al: 0.010 wt% or less, N: 0.02 wt% or less, O: 0.010 to 0.030 wt%, and Nb: 0.003 to 0.003 wt%
Easy open can with excellent lid openability and rivet formability, characterized in that it contains one or two kinds of 0.02 wt% and Ti: 0.003 to 0.02 wt%, and the balance is composed of Fe and inevitable impurities. Steel plate for lid.

【0012】(4) 上記(2) または(3) に記載の鋼に、さ
らに、Cu:0.20wt%以下、Ni:0.20wt%以下、Cr:0.20
wt%以下、Mo:0.20wt%以下のうちから選んだ1種また
は2種以上を含有させることを特徴とする、開蓋性とリ
ベット成形性に優れるイージーオープン缶蓋用鋼板。
(4) The steel according to the above (2) or (3), further comprising: Cu: 0.20 wt% or less, Ni: 0.20 wt% or less, Cr: 0.20 wt%
A steel sheet for an easy-open can lid having excellent lid opening properties and rivet forming properties, characterized by containing one or more kinds selected from wt% or less and Mo: 0.20 wt% or less.

【0013】(5) B酸化物の平均粒径が0.1 〜20μmで
あることを特徴とする、上記(1) 〜(4) のいずれか1つ
に記載の開蓋性とリベット成形性に優れる缶用鋼板。
(5) The B oxide has an average particle diameter of 0.1 to 20 μm, and has excellent lid opening properties and rivet forming properties as described in any one of (1) to (4) above. Steel plate for cans.

【0014】(6) 上記(1) 〜(5) のいずれか1つに記載
の鋼板の表面に、錫めっき、クロムめっき、ニッケルめ
っき、有機樹脂塗装、有機樹脂フィルムのいずれかの表
面被覆を形成したことを特徴とする、開蓋性とリベット
成形性に優れるイージーオープン缶蓋用鋼板。
(6) The surface of any one of tin plating, chrome plating, nickel plating, organic resin coating, and organic resin film is coated on the surface of the steel sheet according to any one of the above (1) to (5). An easy-open can lid steel sheet with excellent lid opening and rivet forming properties.

【0015】(7) 上記(1) 〜(6) のいずれか1つに記載
の鋼板を成形加工してなることを特徴とする、開蓋性に
優れるイージーオープン缶蓋。
(7) An easy-open can lid excellent in lid-opening property, characterized by being formed by processing the steel sheet according to any one of the above (1) to (6).

【0016】(8) C:0.02wt%以下、B:0.010 〜0.02
0 wt%、Al:0.010 wt%以下、O:0.010 〜0.030 wt%
を含有する鋼スラブを、仕上温度 800℃以上で熱間圧延
した後、450 〜700 ℃の温度範囲で巻き取り、1次冷間
圧延を経て、再結晶焼鈍を行い、次いで圧下率30%以下
で2次冷間圧延することを特徴とする開蓋性とリベット
成形性に優れるイージーオープン缶蓋用鋼板の製造方法
(8) C: 0.02% by weight or less, B: 0.010 to 0.02
0 wt%, Al: 0.010 wt% or less, O: 0.010 to 0.030 wt%
Is hot rolled at a finishing temperature of 800 ° C or higher, wound up in a temperature range of 450 to 700 ° C, subjected to primary cold rolling, recrystallized, and then reduced to a rolling reduction of 30% or less. Method of manufacturing steel plate for easy-open can lid having excellent openability and rivet formability, characterized by secondary cold rolling at room temperature

【0017】[0017]

【発明の実施の形態】以下、本発明の好ましい実施形態
について説明する。 (1) 鋼成分について; C:0.02wt%以下 Cは、0.02wt%を超えて含有すると、鋼中に存在する炭
化物の分率が増加する結果、鋼板の延性が劣化する。ま
た、下限は特に定めないが、C量が0.0005wt%以下にな
ると結晶粒の粗大化し、オレンジピール現象に似た肌荒
れ不良を発生する危険性が増大するので、0.0005wt%以
上とすることが望ましい。したがって、C量は0.02wt%
以下、好ましくは0.0005〜0.02wt%、さらに材質の安定
性と延性を高める必要がある場合には、0.0015〜0 .015
wt%の範囲が望ましい。また、さらに加工性向上の面で
は0.01wt%以下が望ましい。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will be described below. (1) Regarding steel components: C: 0.02 wt% or less If C is contained in excess of 0.02 wt%, the fraction of carbides present in the steel increases, resulting in deterioration of the ductility of the steel sheet. The lower limit is not particularly defined. However, when the C content is 0.0005 wt% or less, the crystal grains become coarse and the risk of occurrence of rough skin defects similar to the orange peel phenomenon increases. desirable. Therefore, C content is 0.02wt%
Hereinafter, it is preferably 0.0005 to 0.02 wt%, and when it is necessary to further enhance the stability and ductility of the material, 0.0015 to 0.015%.
A range of wt% is desirable. Further, from the viewpoint of further improving the workability, the content is desirably 0.01% by weight or less.

【0018】Si:0.05wt%以下 Siは、多量に含有すると、表面処理性の劣化、耐食性の
劣化等の問題を招くので、その上限は0.05wt%とする。
特に、優れた耐食性が必要な場合には、0.02wt%以下と
するのが望ましい。
Si: 0.05 wt% or less If Si is contained in a large amount, it causes problems such as deterioration of surface treatment properties and corrosion resistance. Therefore, the upper limit is set to 0.05 wt%.
In particular, when excellent corrosion resistance is required, the content is desirably 0.02% by weight or less.

【0019】Mn:0.6 wt%以下 Mnは、Sによる熱延中の赤熱脆性を防止し、結晶粒を微
細化する作用を有し、望ましい材質を確保する上で必要
な元素である。しかし、0.6 wt%を超えて添加すると耐
食性が劣化し、また鋼板が硬質化して冷間圧延性が低下
し、開蓋性が低下するので0.6 wt%以下とする。なお、
より良好な耐食性とリベット成形性が要求される用途に
は、望ましくは0.20wt%以下、さらに望ましくは0.15wt
%以下の範囲で添加するのがよい。
Mn: 0.6 wt% or less Mn has an effect of preventing red hot embrittlement during hot rolling by S and of making crystal grains fine, and is an element necessary for securing a desired material. However, if added in excess of 0.6 wt%, the corrosion resistance deteriorates, and the steel sheet becomes harder, the cold rollability decreases, and the lid opening property decreases, so the content is set to 0.6 wt% or less. In addition,
For applications requiring better corrosion resistance and rivet formability, preferably 0.20 wt% or less, more preferably 0.15 wt%
% Or less.

【0020】S:0.020 wt%以下 Sは、鋼中でMnSなどの非金属介在物として存在し、開
蓋性を改善する一方で、リベット成形性、スラブ表面性
状の低下、耐食性の劣化をもたらす有害な元素であるの
で0.020 wt%以下に制限する。リベット成形性、耐食性
をより重視する場合には、0.015 wt%以下の範囲に制限
するのが望ましい。
S: 0.020 wt% or less S exists as nonmetallic inclusions such as MnS in steel and improves the lid opening property, but also causes rivet formability, deterioration of slab surface properties, and deterioration of corrosion resistance. Since it is a harmful element, it is limited to 0.020 wt% or less. When more emphasis is placed on rivet formability and corrosion resistance, it is desirable to limit the range to 0.015 wt% or less.

【0021】B:0.010 〜0.020 wt% Bは、本発明において極めて重要な添加元素のひとつで
ある。鋼中のO量を適正範囲に制御するとともにBを0.
01wt%以上添加することにより、Bは適正な寸法の酸化
物の状態で鋼中に分散する。このB酸化物はアルミ酸化
物と異なりクラスターを形成しにくく、本発明の目的に
好ましい範囲の大きさに成長し、かつ均一に分散した状
態で存在する。また、B酸化物は比較的安定な化合物で
あるため、缶体を構成する蓋材として使用される場合も
耐食性を劣化させることがない。さらに、B酸化物は、
缶蓋の成形時に、割れを誘発することがないのに、使用
時には、開蓋に要する仕事量を低減するという、缶蓋用
素材として望ましい効果を有している。このような効果
が得られる、詳細な機構は必ずしも明らかではないが、
B酸化物の粒径、分散状態および分率などがが適正範囲
にある場合にリベット成形性と良破断性(開蓋性)い
う、通常は相反する特性が、両立するものと考えられ
る。いずれにしてもB酸化物は、従来技術で提案されて
いるBN析出物とは全く異なった効果をもたらす。以上
のように、0.010 wt%以上のBを添加することにより、
初めて顕著な開蓋性とリベット成形性に代表される成形
性の改善効果があらわれる。しかし、0.020 wt%を超え
て添加すると、鋼の顕著な脆化のためにリベット成形性
が劣化するので、Bは0.010 〜0.020 wt%の範囲で添加
する。
B: 0.010 to 0.020 wt% B is one of the extremely important additional elements in the present invention. Control the amount of O in the steel to an appropriate range and set B to 0.
By adding more than 01 wt%, B disperses in the steel in the form of oxides of appropriate dimensions. The B oxide is unlikely to form clusters unlike the aluminum oxide, grows to a size that is preferable for the purpose of the present invention, and exists in a uniformly dispersed state. In addition, since B oxide is a relatively stable compound, it does not deteriorate the corrosion resistance even when used as a lid material constituting a can. Further, B oxide is
This has a desirable effect as a material for a can lid, in that the work required for opening the lid is reduced at the time of use without causing cracking at the time of molding the can lid. Although the detailed mechanism by which such an effect is obtained is not always clear,
It is considered that when the particle size, the dispersion state, the fraction, and the like of the B oxide are in appropriate ranges, the rivet formability and the good breaking property (opening property), which are usually contradictory properties, are compatible. In any case, the B oxide has a completely different effect from the BN precipitate proposed in the prior art. As described above, by adding 0.010 wt% or more of B,
For the first time, a remarkable effect of improving formability represented by remarkable openability and rivet formability appears. However, if added in excess of 0.020 wt%, the rivet formability deteriorates due to remarkable embrittlement of the steel, so B is added in the range of 0.010 to 0.020 wt%.

【0022】Al:0.010 wt%以下 Alは、合有量が多くなると、アルミナクラスターの形成
に起因して表面性状が悪化する。また、本発明では、開
蓋性を向上させるために、鋼中のアルミナ生成量を最小
限に抑制する必要があり、Al合有量は0.010 wt%以下と
する。なお、材質の安定性という観点では0.005 wt%以
下に制限するのが望ましい。
Al: 0.010 wt% or less If the amount of Al increases, the surface properties deteriorate due to the formation of alumina clusters. Further, in the present invention, in order to improve the lid opening property, it is necessary to minimize the amount of alumina produced in the steel, and the Al content is 0.010 wt% or less. From the viewpoint of material stability, it is desirable to limit the content to 0.005 wt% or less.

【0023】N:0.02wt%以下 Nは、添加量が増すと、鋼板の強度がいたずらに増加
し、缶蓋として使用する際の開蓋性を低下させる。この
悪影響は0.02wt%以下に制限することにより、実質的な
弊害が回避できる。なお、一層の開蓋性改善効果を発揮
させるためには、0.0080wt%以下に制限することが望ま
しい。
N: 0.02 wt% or less N increases the amount of N to increase the strength of the steel sheet unnecessarily, and lowers the openability when used as a can lid. By limiting this adverse effect to 0.02 wt% or less, substantial adverse effects can be avoided. In order to achieve a further effect of improving the lid opening property, it is desirable to limit the content to 0.0080 wt% or less.

【0024】O:0.010 〜0.030 wt% Oは、本発明において上記Bとともに重要な成分であ
る。O含有量を、0.010wt%以上とすることにより、は
じめて開蓋性とリベット成形性を両立させるという改善
効果が発揮される。この効果は、破壊の起点となるに有
効な寸法の、十分な量の酸化物が鋼中に形成されること
によると考えられる。しかし、Oの含有量が0.030 wt%
を超えると、製鋼段階で表面割れ、内部割れなどのない
健全なスラブ(薄スラブを含む)を製造することが困難
となり、表面の美麗性が要求される缶材への用途には適
さなくなる。なお、より高いレベルの表面性状が要求さ
れる場合には0.025 wt%以下の範囲が望ましい。
O: 0.010 to 0.030 wt% O is an important component together with B in the present invention. When the O content is 0.010% by weight or more, the effect of improving both the openability and the rivet formability is exhibited for the first time. This effect is believed to be due to the formation of a sufficient amount of oxide in the steel of a size effective to serve as a starting point for fracture. However, the content of O is 0.030 wt%
If it exceeds 300, it becomes difficult to produce a sound slab (including a thin slab) having no surface cracks or internal cracks in the steel making stage, and it is not suitable for use in a can material requiring a beautiful surface. If a higher level of surface texture is required, the range is preferably 0.025 wt% or less.

【0025】上記基本成分に加えて、必要に応じて、さ
らにNb:0.003 〜0 .020wt%、Ti:0.003 〜0.020wt %
の1種以上または2種以上の元素、Cu:0.20wt%以下、
Ni:0.20wt%以下、Cr:0.20wt%以下、Mo:0.20wt%以
下の元素の1種以上または2種以上の元素を、単独また
は組み合わせて添加することができる。
In addition to the above basic components, if necessary, Nb: 0.003 to 0.020 wt%, Ti: 0.003 to 0.020 wt%
One or more or two or more elements of the following: Cu: 0.20 wt% or less;
One or more or two or more elements of Ni: 0.20 wt% or less, Cr: 0.20 wt% or less, and Mo: 0.20 wt% or less can be added alone or in combination.

【0026】Nb:0.003 〜0.020 wt% Nbは、鋼板の微視組織の微細化に有用な元素である。鋼
板組織の微細化により素材の強靱化がはかられ、イージ
ーオープンエンド加工後、使用時までに加えられる衝撃
的な荷重に対する信頼性が向上する。このような効果が
得られるのは、0.003 wt%以上の添加からである。しか
し、0.020 wt%を超えて添加しても、これらの効果が飽
和するうえ、再結晶温度が顕著に上昇し、焼鈍が困難に
なる。したがって、Nb添加量は0.003 〜0.020 wt%の範
囲とする。
Nb: 0.003 to 0.020 wt% Nb is an element useful for refining the microstructure of a steel sheet. The fineness of the steel sheet structure enhances the toughness of the material, and improves the reliability against the impact load applied before use after easy open end processing. Such an effect is obtained from the addition of 0.003 wt% or more. However, even if added in excess of 0.020 wt%, these effects are saturated, and the recrystallization temperature is significantly increased, making annealing difficult. Therefore, the amount of Nb added is in the range of 0.003 to 0.020 wt%.

【0027】Ti:0.003 〜0.020 wt% Tiは、Nbと同様に鋼板の微視組織の微細化に寄与する。
また、Tiは、介在物の形態制御にも有効であり、イージ
ーオープン缶蓋加工後、使用時までに加えられる衝撃的
な荷重に対する信頼性を向上させる。このような効果を
得るためには、0.003 wt%上の添加が必要である。しか
し、0.020 wt%を超えて添加しても、これらの効果が飽
和するほか、再結晶温度が上昇して、焼鈍が困難にな
る。したがって、Ti添加量は0.003 〜0.020 wt%の範囲
とする。
Ti: 0.003 to 0.020 wt% Ti contributes to the refinement of the microstructure of the steel sheet, similarly to Nb.
Further, Ti is also effective in controlling the form of inclusions, and improves the reliability against an impact load applied until the time of use after processing the easy-open can lid. In order to obtain such an effect, it is necessary to add 0.003 wt% or more. However, even if it is added in excess of 0.020 wt%, these effects are saturated, and the recrystallization temperature rises, making annealing difficult. Therefore, the content of Ti is set in the range of 0.003 to 0.020 wt%.

【0028】Cu:0.20wt%以下、Ni:0.20wt%以下、C
r:0.20wt%以下、Mo:0.20wt%以下 Cu、Ni、CrおよびMoは、延性の劣化を最小限に抑えて強
度を増加させ、また耐食性を向上させる効果を有する。
しかし、0.20wt%以上を超えて添加しても、これらの効
果が飽和するのみでなく、強度が高くなりすぎて、開蓋
性を劣化させる。したがって、Cu、Ni、CrおよびMoは、
いずれも0.20wt%以下の範囲で添加する。これらの元素
の添加効果は複合添加しても相殺されることはないが、
開蓋性確保の点から合計量で0.5 wt%以下とすることが
望ましい。また、これらの元素は各々0.01wt%以上の添
加が、添加効果を得るためには望ましい。
Cu: 0.20 wt% or less, Ni: 0.20 wt% or less, C
r: 0.20 wt% or less, Mo: 0.20 wt% or less Cu, Ni, Cr and Mo have the effect of minimizing ductility degradation, increasing strength, and improving corrosion resistance.
However, even if it is added in excess of 0.20 wt%, not only these effects are saturated, but also the strength becomes too high and the lid opening property is deteriorated. Therefore, Cu, Ni, Cr and Mo are:
All are added in a range of 0.20% by weight or less. The effect of adding these elements will not be offset by the combined addition,
From the viewpoint of ensuring openability, it is desirable that the total amount be 0.5 wt% or less. Further, it is desirable to add 0.01% by weight or more of each of these elements in order to obtain the effect of addition.

【0029】B酸化物の平均粒径:0.1 〜20μm B酸化物、すなわちBx Oy ( x:〜2、 y:〜3)の
組成で表わされる析出物、の平均粒径が0.1 〜20μmで
あることが重要である。鋼中には、この他に、炭化物、
硫化物および窒化物およびその複合したものなどの析出
物が存在するが、延性を低下させることなく、開蓋性を
改善できる析出物は、球状にかつ、孤立して存在する傾
向の強いB酸化物である。B酸化物以外の他の析出物に
起因する延性の低下などは、後述する製造条件を適用す
ることにより最低限に抑えることができる。B酸化物出
物の平均粒径が0.1 μmを下回ると、析出物による鋼板
の強化が顕著となり開蓋性の改善が不十分となる。一
方、この平均粒径が20μmを上回ると成形性の劣化が大
きくなり、蓋材の成形過程でプレス割れなどの不具合を
生ずる危険性が増す。したがって、B酸化物の平均粒径
は0.1 〜20μmとする。なお、鋼中にはB酸化物の他
に、Al2O3 、MnOなどの酸化物も存在するが、それらの
存在形態は、本発明の製造条件の範囲であれば、リベッ
ト成形性、開蓋性に大きく影響しない。また、これらの
酸化物が複合して析出している場合もこれに準ずる。上
述の鋼中析出物についての知見は、光学顕微鏡での確
認、電解抽出法により採取した残査の走査型電子顕微で
の観察および分析などによって解明したものである。な
お、析出物寸法は一義的に定まるものではなく、その調
査方法によって異なる場合がある。本発明における測定
方法は次の方法による。まず、鋼板から50g以上の重
量の試料を採取し、定電位電解したのち、凝集防止剤を
添加して粒子の凝集を防止しながら通常のニュークルポ
アフィルターでろ過して残査を抽出する (電解抽出法)
。次いで、この残査をそのまま走査型電子顕微鏡によ
り観察し、通常の画像処理(統計処理)を行って平均粒
径を求める。
Average particle size of B oxide: 0.1 to 20 μm The average particle size of B oxide, that is, a precipitate represented by the composition of BxOy (x: 22, y: 33) is 0.1 to 20 μm. This is very important. In steel, besides this, carbide,
Precipitates such as sulfides and nitrides and their composites are present, but the precipitates that can improve the openability without lowering the ductility are B oxides that tend to be spherical and isolated. Things. A reduction in ductility due to other precipitates other than the B oxide can be minimized by applying the manufacturing conditions described below. If the average particle size of the oxide B is less than 0.1 μm, the steel sheet will be strengthened by the precipitates, and the improvement of the openability will be insufficient. On the other hand, when the average particle size exceeds 20 μm, the deterioration of the moldability becomes large, and the risk of causing problems such as press cracking in the process of forming the lid material increases. Therefore, the average particle size of the B oxide is 0.1 to 20 μm. In addition, in addition to B oxides, oxides such as Al 2 O 3 and MnO also exist in the steel. However, as long as these oxides are in the range of the production conditions of the present invention, the rivet formability, openness, etc. Does not significantly affect lid properties. The same applies to the case where these oxides are precipitated in combination. The above-mentioned knowledge on the precipitates in steel has been elucidated by confirmation with an optical microscope, observation and analysis of the residue collected by the electrolytic extraction method with a scanning electron microscope, and the like. Note that the size of the precipitate is not uniquely determined, and may vary depending on the survey method. The measuring method in the present invention is based on the following method. First, a sample having a weight of 50 g or more is collected from a steel sheet, and subjected to constant potential electrolysis. After that, a coagulation inhibitor is added to prevent agglomeration of the particles, and the mixture is filtered with a normal Nuclepore filter to extract a residue ( (Electrolysis extraction method)
. Next, the residue is observed as it is with a scanning electron microscope, and ordinary image processing (statistical processing) is performed to determine the average particle diameter.

【0030】(2) 製造条件について;スラブの製造工程
は常法に従うが、成分のマクロな偏析を防止するうえで
連続鋳造法で製造することが望ましい。連続鋳造された
スラブは、一旦室温まで冷却して加熱しても、また冷却
することなくそのまま加熱炉に高温挿入してもよい。
(2) Manufacturing conditions: The slab is manufactured by a conventional method, but is preferably manufactured by a continuous casting method in order to prevent macro segregation of components. The continuously cast slab may be once cooled to room temperature and heated, or may be directly inserted into a heating furnace without cooling.

【0031】・熱間圧延 スラブ加熱につづく、熱間圧延では、仕上げ熱延温度を
800 ℃以上とする必要がある。仕上げ熱延温度を800 ℃
以上にすることにより、均一微細な熱延組織を得ること
ができ、最終製品の組織を均一微細化することができ
る。しかし、仕上げ圧延温度が950 ℃を超えると、スケ
ールに起因した庇が発生しやすくなるので、表面の健全
性が強く要求される缶用鋼板の分野では、好ましくは80
0 〜950 ℃の範囲で仕上げ圧延するのがよい。なお、材
質の均一性を重視する場合には、さらに850 〜920 ℃の
温度範囲で仕上げ圧延することが望ましい。
・ Hot rolling In the hot rolling following the slab heating, the finishing hot rolling temperature is set.
Must be at least 800 ° C. Finish hot rolling temperature 800 ℃
By doing as described above, a uniformly fine hot-rolled structure can be obtained, and the structure of the final product can be uniformly refined. However, when the finish rolling temperature exceeds 950 ° C., eaves due to scale are likely to be generated. Therefore, in the field of steel sheets for cans where surface soundness is strongly required, preferably 80 ° C.
It is preferable to perform finish rolling in the range of 0 to 950 ° C. When importance is placed on the uniformity of the material, it is desirable to further perform finish rolling in a temperature range of 850 to 920 ° C.

【0032】・熱延後の巻き取り 巻取温度は、450 〜700 ℃とする必要がある。この巻取
温度は、一般的な成形性改善のためには、通常、700 ℃
を超える高温に設定されるが、このような温度範囲で巻
き取ると、缶蓋に成形したあとの開蓋性を劣化してしま
う。また、コイルの長手方向、幅方向における材質の不
均一性も増大するようになる。発明者らの調査によれ
ば、450 〜700 ℃の巻取り温度であれば、このような成
形性の劣化を防ぎ、開蓋性の改善を図ることが可能であ
ることが明らかとなった。なお、一層の開蓋性向上を必
要とする場合には、500 〜650 ℃の範囲で巻き取ること
が望ましい。
Winding after hot rolling The winding temperature must be 450 to 700 ° C. This winding temperature is usually set to 700 ° C. for general formability improvement.
However, if the film is wound up in such a temperature range, the openability after being formed into a can lid deteriorates. Further, the non-uniformity of the material in the longitudinal direction and the width direction of the coil also increases. According to the investigation by the inventors, it has been found that if the winding temperature is 450 to 700 ° C., it is possible to prevent such deterioration of the formability and to improve the lid opening property. If it is necessary to further improve the openability of the cover, it is desirable to wind it up in the range of 500 to 650 ° C.

【0033】・酸洗および1次冷間圧延 酸洗については、格別の制限条件を設ける必要はない。
酸洗効率の上からは、通常の塩酸による酸洗が推奨され
るが、硫酸による酸洗でも材質上の問題は生じない。ま
た、1次冷間圧延についても、特にさだめる必要はない
が、通常適用される、70%以上の圧下率範囲で行うこと
が好ましい。
Pickling and primary cold rolling Pickling does not require special restrictions.
From the standpoint of pickling efficiency, pickling with ordinary hydrochloric acid is recommended, but pickling with sulfuric acid does not cause any material problems. Also, the primary cold rolling is not particularly required to be carried out, but is preferably performed in a normally applied rolling reduction range of 70% or more.

【0034】・焼鈍 蓋材の成形を安定化させるために、再結晶温度以上で焼
鈍することが、必須である。上限の温度は特に定めない
が、本発明の成分鋼ではおおむね850 ℃以下の範囲で焼
鈍することが望ましい。
Annealing In order to stabilize the formation of the lid material, it is essential to anneal at a temperature higher than the recrystallization temperature. Although the upper limit temperature is not particularly defined, it is preferable that the annealing is performed in the range of approximately 850 ° C. or less in the component steel of the present invention.

【0035】・2次冷間圧延 2次冷延の圧下率は30%以下の範囲で行う。この2次冷
延には通常スキンパス圧延と称される軽度の圧延 (おお
むね0.8 〜2.0 %) を含む。スキンパス圧延の役割は、
主として、缶蓋の成形時に、より均一な変形を与えるこ
とを可能にすることにあり、またより高圧下率での2次
冷間圧延の役割は、加工強化により、缶蓋としての強度
を増加させることにある。しかし、この圧下率が30%を
超えると、素材の延性が低下し、成形不良を生じる危険
性が増大する。したがって、2次冷間圧延は、30%以下
の圧下率範囲で目的に応じて施すものとする。
[Second Cold Rolling] The rolling reduction of the second cold rolling is performed within a range of 30% or less. This secondary cold rolling includes light rolling (generally 0.8 to 2.0%) usually called skin pass rolling. The role of skin pass rolling is
The main purpose is to provide more uniform deformation when forming the can lid. The role of secondary cold rolling at a higher reduction rate is to increase the strength of the can lid by strengthening the work. To make it happen. However, if the rolling reduction exceeds 30%, the ductility of the material is reduced, and the risk of forming defects increases. Therefore, the secondary cold rolling is performed according to the purpose within a rolling reduction range of 30% or less.

【0036】以上のようにして製造された鋼板に対し
て、表面に耐食性向上のために錫めっき、Niめっき、有
機樹脂被膜の密着性を重視してのクロムめっき、などを
行って缶蓋に供される。また、有機樹脂塗装の替わり
に、有機樹脂フィルムを熱融着(接着剤を併用するもの
も含む)したものも、同様に缶蓋に適用できる。
The steel plate manufactured as described above is subjected to tin plating, Ni plating, chromium plating with an emphasis on the adhesion of the organic resin film, etc. on the surface to improve the corrosion resistance, and is applied to the can lid. Provided. Further, instead of the organic resin coating, an organic resin film obtained by heat-sealing (including one using an adhesive together) can be similarly applied to the can lid.

【0037】[0037]

【実施例】実施例1 表1に示す種々の成分の鋼スラブを溶製し、下記条件で
缶蓋用鋼板を製造した。 スラブ加熱温度:1250℃ 仕上げ圧延温度:850 ℃ 仕上げ厚み:2.0 mm 巻取温度: 620 ℃ 1次冷間圧下率:90% 焼純:連続焼純、750 ℃−20 sec、過時効なし 2次冷間圧下率:1.5 %のスキンパス 25#ブリキ(錫目付 2.8 g/m2 ) この鋼板を用いて、長円形状のパーシヤルイージーオー
プン缶蓋(長さ40mm、半径10mmφ〜20mmφ、スコア残厚
45μm)を製造し、リベット成形性、開蓋性の調査、お
よび閉塞後の外観観察を行なった。これらの調査結果を
表2に示す。ここに、リベット成形性は、通常のタブを
取付けて、5mmφ, 1mm高さの形状に成形した際の割れ
発生の有無により判定した。また、ポップ値、ティア
値、デタッチ値は、引張試験機により引張荷重を負荷
し、荷重−変位の関係(n=20)から求めた。 ポップ値:タブを起こして初期クラックが生成されるに
必要な力(kgf) ティア値:スコア部でせん断破壊を安定して継続させる
に必要な力(kgf) デタッチ値:蓋部を缶体より切り離すに要する力(kgf)
EXAMPLES Example 1 Steel slabs of various components shown in Table 1 were melted, and steel plates for can lids were manufactured under the following conditions. Slab heating temperature: 1250 ° C Finish rolling temperature: 850 ° C Finish thickness: 2.0 mm Winding temperature: 620 ° C Primary cold reduction: 90% Purification: continuous calcination, 750 ° C-20 sec, no overaging Cold rolling reduction: 1.5% skin pass 25 # tin (2.8 g / m 2 with tinned area) Using this steel plate, oval-shaped Persian easy open can lid (length 40mm, radius 10mmφ ~ 20mmφ, score remaining thickness
45 μm), and the rivet formability, lid openability, and appearance after closure were observed. Table 2 shows the results of these investigations. Here, the rivet formability was determined by the presence or absence of cracking when a normal tab was attached and formed into a shape of 5 mmφ and 1 mm height. Further, the pop value, the tier value, and the detach value were obtained from a load-displacement relationship (n = 20) by applying a tensile load using a tensile tester. Pop value: force required to generate an initial crack by raising a tab (kgf) Tear value: force required to continue shear failure stably at the score part (kgf) Detach value: cover part from can body Force required to separate (kgf)

【0038】[0038]

【表1】 [Table 1]

【0039】[0039]

【表2】 [Table 2]

【0040】これらの実施例から、本発明を適用するこ
とにより、ポップ値、ティア値に代表される開蓋性が顕
著に向上し、またリベット成形性も改善されることが明
らかである。特に、BNが主たる析出物であるNo. 7に
比べ、本発明例は開蓋性が優れていることがわかる。
From these examples, it is clear that by applying the present invention, the openability represented by the pop value and the tier value is remarkably improved, and the rivet formability is also improved. In particular, it can be seen that the example of the present invention has an excellent lid opening property as compared with No. 7 in which BN is the main precipitate.

【0041】実施例2 表1のNo.1の鋼スラブを素材とし、表3に示す種々の条
件で表面被覆まで行った缶蓋用鋼板を製造し、実施例1
と同様の調査をおこなった。その結果を表4に示す。本
発明に従う製造条件を満たせば、リベット成形性および
開蓋性に優れた缶蓋用鋼板および缶蓋が製造できること
が明らかである。
Example 2 Using a steel slab of No. 1 in Table 1 as a raw material, a steel plate for a can lid was produced under various conditions shown in Table 3 up to surface coating.
A similar survey was conducted. Table 4 shows the results. It is clear that if the production conditions according to the present invention are satisfied, a steel plate for a can lid and a can lid excellent in rivet formability and lid openability can be produced.

【0042】[0042]

【表3】 [Table 3]

【0043】[0043]

【表4】 [Table 4]

【0044】No.2の鋼板を用いて、残厚にして40μmの
スコアを有する蓋を取り付けた、3ピース缶を製造し
た。この缶に、水を充填して加熱し、約2bar の内圧を
発生させ、その耐圧性を評価した。その結果、従来の低
炭素アルミキルド鋼連続焼鈍材により製造されたものと
同等以上の耐圧性能を有していることが確認された。ま
た、同様に準備した試料缶をコンクリート面の上に1.5
m高さから落下させて、スコア部の耐衝撃特性を調査し
た。その結果、本発明鋼板で製造した缶蓋のスコア部は
従来の低炭素アルミキルド鋼連続焼鈍材により製造され
たものと同等以上の耐衝撃特性を有していることが確認
された。すなわち、本発明によれば、従来の低炭素アル
ミキルド鋼連続焼鈍材と同等以上の、耐圧性、内容物に
対する耐衝撃保護性を有しながら、リベット成形性、開
蓋性のいずれをも顕著に向上させることが可能であるこ
とがわかった。
Using a No. 2 steel plate, a three-piece can was manufactured with a lid having a residual thickness of 40 μm. The can was filled with water and heated to generate an internal pressure of about 2 bar, and its pressure resistance was evaluated. As a result, it was confirmed that it had a pressure resistance equal to or higher than that of a conventional low carbon aluminum killed steel continuous annealed material. Also, place the prepared sample can on a concrete surface for 1.5
After dropping from a height of m, the impact resistance characteristics of the score portion were investigated. As a result, it was confirmed that the score portion of the can lid manufactured from the steel sheet of the present invention had impact resistance equal to or higher than that of the conventional low carbon aluminum killed steel continuously annealed material. That is, according to the present invention, the rivet forming property and the lid opening property are both remarkable while having pressure resistance and impact resistance to the contents, which are equal to or higher than those of the conventional low carbon aluminum killed steel continuous annealing material. It was found that it could be improved.

【0045】0.010 wt%C−0.01wt%Si−0.15wt%Mn−
0.010 wt%S−0.005 wt%Al−0.0030wt%N鋼をベース
に材とし、O含有量を0 .0150 wt%に制御し、Bを幅広
く変化させ、同様にして缶蓋を製造し、開蓋性((ポッ
プ値+ティア値)/2)と缶蓋のリベット成形時の割れ
不具合の発生率について調査(n=30)した。その結果
を図1に示す。図1から、B、Oの含有量を適正範囲に
制御することにより当初の課題が達成できることがわか
る。
0.010 wt% C-0.01 wt% Si-0.15 wt% Mn-
Based on 0.010 wt% S-0.005 wt% Al-0.0030 wt% N steel, the O content is controlled to 0.0150 wt%, B is varied widely, and the can lid is manufactured and opened in the same manner. The lid property ((pop value + tear value) / 2) and the incidence of cracking during rivet forming of the can lid were investigated (n = 30). The result is shown in FIG. From FIG. 1, it can be seen that the initial problem can be achieved by controlling the B and O contents in appropriate ranges.

【0046】[0046]

【発明の効果】以上、説明したように、本発明によれ
ば、従来はアルミ材で多く製造されていた缶蓋材に替わ
って鉄材を適用するにあたり、鉄材の課題であった、開
蓋性とリベット成形性を大幅に向上できるので、安価で
リサイクルが容易なイージーオープン缶蓋としての使途
が期待される。しかも、本発明によれば、上記特性に加
えて、優れた耐圧性と、良好な耐食性と耐衝撃性をも付
与したイージーオープン缶蓋を提供することが可能とな
る。
As described above, according to the present invention, when the iron material is applied in place of the can lid material which has been conventionally made of aluminum material in many cases, the problem of the openability has been a problem of the iron material. It is expected to be used as an easy-open can lid that is inexpensive and easy to recycle because the rivet formability can be greatly improved. Moreover, according to the present invention, it is possible to provide an easy-open can lid that has excellent pressure resistance, good corrosion resistance and impact resistance in addition to the above-mentioned characteristics.

【図面の簡単な説明】[Brief description of the drawings]

【図1】開蓋性とリベット成形性に及ぼすB含有量の影
響を示す図である。
FIG. 1 is a diagram showing the effect of the B content on the openability and rivet formability.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 荒谷 昌利 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社技術研究所内 (72)発明者 久々湊 英雄 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社千葉製鉄所内 (72)発明者 荒谷 誠 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社千葉製鉄所内 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Masatoshi Araya 1 Kawasaki-cho, Chuo-ku, Chiba City, Chiba Prefecture Inside the Technical Research Institute of Kawasaki Steel Co., Ltd. (72) Inventor Makoto Aratani 1 Kawasaki-cho, Chuo-ku, Chiba-shi, Chiba Prefecture Kawasaki Steel Corporation Chiba Works

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 C:0.02wt%以下、B:0.010 〜0.020
wt%、Al:0.010 wt%以下、O:0.010 〜0.030 wt%を
含有することを特徴とする、開蓋性とリベット成形性に
優れるイージーオープン缶蓋用鋼板。
1. C: 0.02% by weight or less, B: 0.010 to 0.020
An easy open can lid steel sheet having excellent openability and rivet formability, characterized by containing wt%, Al: 0.010 wt% or less, and O: 0.010 to 0.030 wt%.
【請求項2】 C:0.02wt%以下、Si:0.05wt%以下、
Mn:0.6 wt%以下、S:0.020 wt%以下、B:0.010 〜
0.020 wt%、Al:0.010 wt%以下、N:0.02wt%以下、
O:0.010 〜0.030 wt%を含有し、残部がFe及び不可避
的不純物の組成からなることを特徴とする、開蓋性とリ
ベット成形性に優れるイージーオープン缶蓋用鋼板。
2. C: 0.02% by weight or less, Si: 0.05% by weight or less,
Mn: 0.6 wt% or less, S: 0.020 wt% or less, B: 0.010-
0.020 wt%, Al: 0.010 wt% or less, N: 0.02 wt% or less,
O: A steel sheet for an easy-open can lid having excellent openability and rivet formability, comprising 0.010 to 0.030 wt%, with the balance being composed of Fe and inevitable impurities.
【請求項3】 C:0.02wt%以下、Si:0.05wt%以下、
Mn:0.6 wt%以下、S:0.020 wt%以下、B:0.010 〜
0.020 wt%、Al:0.010 wt%以下、N:0.02wt%以下、
O:0.010 〜0.030 wt%を含み、かつNb:0.003 〜0.02
wt%、Ti:0.003〜0.02wt%の1種または2種を含有
し、残部がFe及び不可避的不純物の組成からなることを
特徴とする、開蓋性とリベット成形性に優れるイージー
オープン缶蓋用鋼板。
C: 0.02% by weight or less, Si: 0.05% by weight or less,
Mn: 0.6 wt% or less, S: 0.020 wt% or less, B: 0.010-
0.020 wt%, Al: 0.010 wt% or less, N: 0.02 wt% or less,
O: 0.010 to 0.030 wt%, and Nb: 0.003 to 0.02
Easy open can lid excellent in openability and rivet formability, characterized in that it contains one or two kinds of wt%, Ti: 0.003 to 0.02 wt%, and the balance is composed of Fe and inevitable impurities. For steel plate.
【請求項4】 請求項2または3に記載の鋼に、さら
に、Cu:0.20wt%以下、Ni:0.20wt%以下、Cr:0.20wt
%以下、Mo:0.20wt%以下のうちから選んだ1種または
2種以上を含有させることを特徴とする、開蓋性とリベ
ット成形性に優れるイージーオープン缶蓋用鋼板。
4. The steel according to claim 2, further comprising Cu: 0.20 wt% or less, Ni: 0.20 wt% or less, Cr: 0.20 wt%.
% Or less, Mo: 0.20 wt% or less, characterized by containing one or more kinds selected from the group consisting of:
【請求項5】 B酸化物の平均粒径が0.1 〜20μmであ
ることを特徴とする、請求項1〜4のいずれか1項に記
載の開蓋性とリベット成形性に優れる缶用鋼板。
5. The steel sheet for cans according to claim 1, wherein the B oxide has an average particle diameter of 0.1 to 20 μm.
【請求項6】 請求項1〜5のいずれか1項に記載の鋼
板の表面に、錫めっき、クロムめっき、ニッケルめっ
き、有機樹脂塗装、有機樹脂フィルムのいずれかの表面
被覆を形成したことを特徴とする、開蓋性とリベット成
形性に優れるイージーオープン缶蓋用鋼板。
6. The steel sheet according to claim 1, wherein a surface coating of any one of tin plating, chromium plating, nickel plating, organic resin coating, and organic resin film is formed. A characteristic steel plate for easy-open can lids that features excellent openability and rivet formability.
【請求項7】 請求項1〜6のいずれか1項に記載の鋼
板を成形加工してなることを特徴とする、開蓋性に優れ
るイージーオープン缶蓋。
7. An easy-open can lid excellent in lid-opening properties, characterized by being formed by processing the steel sheet according to any one of claims 1 to 6.
【請求項8】 C:0.02wt%以下、B:0.010 〜0.020
wt%、Al:0.010 wt%以下、O:0.010 〜0.030 wt%を
含有する鋼スラブを、仕上温度 800℃以上で熱間圧延し
た後、450 〜700 ℃の温度範囲で巻き取り、1次冷間圧
延を経て、再結晶焼鈍を行い、次いで圧下率30%以下で
2次冷間圧延することを特徴とする開蓋性とリベット成
形性に優れるイージーオープン缶蓋用鋼板の製造方法。
8. C: 0.02% by weight or less, B: 0.010 to 0.020
A steel slab containing wt%, Al: 0.010 wt% or less, and O: 0.010 to 0.030 wt% is hot-rolled at a finishing temperature of 800 ° C or more, and then wound up in a temperature range of 450 to 700 ° C, and then subjected to primary cooling. A method for producing a steel sheet for an easy-open can lid having excellent openability and rivet formability, comprising performing recrystallization annealing after cold rolling, and then performing secondary cold rolling at a rolling reduction of 30% or less.
JP05778697A 1997-03-12 1997-03-12 Steel plate for easy open can lid excellent in openability and rivet formability, manufacturing method thereof, and easy open can lid Expired - Fee Related JP3740779B2 (en)

Priority Applications (1)

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JP05778697A JP3740779B2 (en) 1997-03-12 1997-03-12 Steel plate for easy open can lid excellent in openability and rivet formability, manufacturing method thereof, and easy open can lid

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JPH10251799A true JPH10251799A (en) 1998-09-22
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