JPH10207009A - Silver halide color photo-graphic sensitive material - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide the photosensitive material small in fluctuation of color development even in the case of using different kinds of printers and stable in finish and superior in image storage stability by incorporating a nondecolorizable yellow dye to increase the absorbency ratio in a specified wavelength after color development of the photosensitive material in a medium amount of exposure. SOLUTION: This color photographic sensitive material has blue-, green-, and red-sensitive silver halide emulsion layers and contains the nondecolorizable yellow dye to increase the absorbance ratio S430/D470 in comparison with that without using it after color development of the photosensitive material in a medium amount of exposure, where each of D430 and D470 is the absorbance in the wavelength of 430 and 470nm. This photosensitive material, preferably, contains a coupler represented by formula I and/or II in which each of X<1> and X<1> is an alkyl or aryl group or the like; X3 is an organic group necessary to form an N-containing geterocyclic group together with the >N- group; Y is an aryl or heterocyclic group; and Z is an H atom or a group to be released by reaction of this coupler with the oxidation product of a color developing agent.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a silver halide color photographic light-sensitive material having a dyed layer, and relates to a yellow dye which is photochemically inert, non-diffusible and not decolored by development. The present invention relates to a silver halide color photographic light-sensitive material which contains an improved hue and has a small change in the tint of a print between different types of printers.

[0002]

2. Description of the Related Art The performance requirements of color photographic light-sensitive materials (hereinafter also referred to as "light-sensitive materials" or "light-sensitive materials") are high. It is required to satisfy high-level performance in all aspects such as storability and image storability.

The yellow, magenta and cyan dyes formed from couplers do not necessarily have ideal absorption characteristics. They have side absorption depending on each skeleton, and main absorption itself depends on the type of coupler. different.

In recent years, when printing on color paper using a color negative film, it has been found that the color tone of the finished color print is shifted between the light-sensitive materials depending on the type of printing equipment used. This not only causes problems such as a decrease in the print yield in a developing laboratory and complicated setting of printing conditions, but also makes it difficult to adjust the color.
Another problem is that poorly finished prints are produced.

As a yellow coupler for forming a color photographic image, an acylacetanilide type coupler having an active methylene (methylene) group is generally known (TH James, “Theory of the.
Photographic Process, 4th Edition, 354-35
6), these dyes had the disadvantage that the color density was low and the dye formation rate was low. In particular, when these couplers are used as so-called DIR couplers, they must be used in large amounts because of their low activity, and the color image fastness, color reproducibility, sharpness, desilvering properties, rapid processing suitability are not sufficient, and The cost was high and it was a problem.

As a malondianilide-type coupler similar to the yellow coupler represented by formula (I) or (II), for example, US Pat. Nos. 4,149,886, 4,095,984, and 4 No. 4,477,563 or British Patent No. 1,204,680. These couplers are known to have image storability,
In particular, the wet and heat fastness was low, which was a problem.

The use of a yellow coupler represented by the general formula (I) or (II) can significantly improve image storability, but the dye obtained therefrom has a longer spectral absorption than a conventional yellow coupler. In this case, there is a problem that the variation in the color tone of the finish between different types of printers is deteriorated.

Investigations have been made to solve this problem, and it has been found that one of the causes is a difference in hue between the light-sensitive materials.

[0009] EP 0742202A describes that a residual color of a sensitizing dye occurs in an inverse imagewise manner with respect to the exposure level of a light-sensitive material, and that the yellow hue becomes longer in a lower density portion. A technique for improving the hue by using a yellow coupler has been reported.

However, in this method, the hue density dependency is certainly reduced, but the hue becomes longer in the entire density region with respect to the original hue of the main coupler. It was insufficient to eliminate variations in print finish.

[0011]

SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to firstly provide a photographic material which can be stably produced with little change in color tone even when a different kind of printer is used, and secondly, it is excellent in image storability. Provided is a photosensitive material.

[0012]

The above objects have been achieved by the silver halide color photographic light-sensitive materials described below.

(1) At least one of each
In a silver halide color photographic light-sensitive material having a blue-sensitive, green-sensitive and red-sensitive silver halide emulsion layer, a non-bleachable yellow dye is mixed with an absorbance ratio D430 / after color development processing of the light-sensitive material at an intermediate exposure dose. A silver halide color photographic light-sensitive material characterized in that D470 is contained so as to increase as compared with the case where no yellow dye is contained.

D430: Absorbance at a wavelength of 430 nm D470: Absorbance at a wavelength of 470 nm (2) It contains a coupler represented by the following general formula (I) and / or a coupler represented by the following general formula (II). The silver halide color photographic light-sensitive material according to (1) above.

Formula (I)

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Embedded image General formula (II)

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Embedded image (Wherein, X ¹ and X ² each represent an alkyl group, an aryl group or a heterocyclic group, X ³ represents an organic residue forming a nitrogen-containing heterocyclic group with> N—, and Y represents an aryl group or a heterocyclic group. Represents a ring group, and Z represents a hydrogen atom or a group which is released when the coupler represented by the formula is reacted with an oxidized developing agent.) The yellow dye used in the present invention will be described.

The yellow dye used in the present invention (hereinafter also referred to as "dye") is non-bleachable, photochemically inert, non-diffusible, and 400-47 in methanol solution.
Any dye having a maximum absorption at 0 nm may be used.
Species or a combination of two or more species may be used.

In the present invention, the term "non-bleachable" means that the added dye has an absorption even after the development processing, and the spectral absorption does not substantially change from that before the processing. Substantially no change means that the average optical density in the 400 to 500 nm region is 80% or more of that before processing.

In the present invention, being photochemically inactive means that it does not substantially react with an oxidized developing agent. The term "substantially no reaction" means that the gradation at the intermediate exposure is preferably changed by 10% or more when a dye of 1/5 mol of the total coupler amount is added to the fourth layer of Example 1 described later. I will not do it. The yellow dye used in the present invention does not enclose so-called colored couplers.

In the present invention, non-diffusion is preferably the following case. Sample 1 described in Example 1 below
A light-sensitive material containing a dye in an amount equivalent to that of the dye No. 05 is prepared, exposed to sensitometry, and subjected to the development processing described in Example 1. Samples stored under a forced deterioration condition of 50 ° C. and 80% before exposure are simultaneously subjected to development processing, and the sensitivity of the blue-sensitive layer is compared with that of a sample not stored under the forced deterioration condition. In this case, it is preferable that a decrease in sensitivity due to storage under forced deterioration conditions of a sample containing no dye is 0.06 or less.

The method of adding the dye to the target layer includes a method of directly dyeing gelatin, a method of dispersing the dye in oil-in-water as described below, that is, a method of adding a high-boiling organic solvent having a boiling point at normal pressure of 175 ° C. or higher. Boiling point 50 ° C or higher and 160 ° C if necessary
Dissolving also using the following organic solvent, a method of adding what is emulsified and dispersed in a gelatin aqueous solution containing a surfactant,
International Patent Patent Publication No. WO88 / 4974, Tokuhei Hei 1-502
912 and EP-A-456,148, a method of adding a so-called solid dispersion, or a method of preventing the diffusion of a dye via a polymer mordant. Representative polymer mordants include, for example,
88548. In the present invention, any of these methods can be used, but addition by an oil-in-water dispersion method is particularly preferred because it does not desensitize the emulsion layer. Therefore, oil-soluble dyes are preferred as the dyes used in the present invention.

In the present invention, the dye is used in the form of an absorbance ratio D430 / D after color development processing of the photosensitive material at an intermediate exposure amount.
470 is added so as to increase as compared with the case where no dye is contained. Here, the term “intermediate exposure amount” refers to an exposure amount at which the yellow density at the time of white light exposure gives fog + 1.

In the present invention, the preferable addition amount of the dye is such that the average optical density in the range of 400 to 500 nm in the dry film is 0.1.
It is an amount to be from 0.5 to 0.3. The method of measuring this concentration is
The dye was coated on a transparent support together with gelatin and dried, and the average optical density was determined from the integrated value obtained by measuring the density of the sample at 400 to 500 nm using a spectrophotometer.

The amount of dye applied is such that the absorbance ratio D430 / D470 after color development of the light-sensitive material at the intermediate exposure amount is:
May be an amount which increases as compared with the case of not containing a ^{dye, 0.015g / m 2 ~0.10g / m} 2 is preferred.

The dye which can be used in the present invention may be added to any photographic constituent layer in the light-sensitive material, but is preferably added to a green-sensitive layer having the highest sensitivity or a layer closer to the support than the green-sensitive layer. May be added to any of the photosensitive and non-photosensitive photographic constituent layers, but is preferably added to the non-photosensitive intermediate layer.

Dyes are disclosed in JP-A-63-40143, EP
O434,026A1, benzylidene dyes described in JP-A-2-165135, oxonol dyes described in JP-B-59-50973, and azo dyes described in USSR 1359289A. Specific examples of the dye used in the present invention are shown below, but the present invention is not limited to these.

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Embedded image Next, the couplers represented by formulas (I) and (II) will be described in detail.

When X ¹ and X ² represent an alkyl group, it is a straight-chain, branched, cyclic, saturated, unsaturated, substituted or unsubstituted alkyl group having 1 to 30, preferably 1 to 20 carbon atoms. Examples of the alkyl group include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, cyclopropyl, allyl, t-octyl, dodecyl, and 2-hexyldecyl.

When X ¹ and X ² each represent a heterocyclic group, it has 1 to 20 carbon atoms, preferably 1 to 10 carbon atoms and contains at least one nitrogen atom, oxygen atom or sulfur atom as a hetero atom, and has 3 to 12 members. A ring, preferably a 5- or 6-membered, saturated or unsaturated, substituted or unsubstituted, monocyclic or condensed heterocyclic group. Examples of the heterocyclic group include 3-pyrrolidinyl, 1,2,4-triazol-3-yl, 2-pyridyl, 4-pyrimidinyl,
-Pyrazolyl, 2-pyrrolyl, 2,4-dioxo-1,
3-imidazolidin-5-yl or pyranyl and the like.

When X ¹ and X ² represent an aryl group,
Represents a substituted or unsubstituted aryl group having 6 to 20, preferably 6 to 10 carbon atoms. Representative examples of the aryl group include phenyl and naphthyl.

When X ³ represents a nitrogen-containing heterocyclic group formed with> N—, the heterocyclic group has 1 to 20 carbon atoms, preferably 1 to 15 carbon atoms, and in addition to a nitrogen atom as a hetero atom,
For example, it may contain an oxygen atom or a sulfur atom, and
It is a 2-membered, preferably 5- or 6-membered, substituted or unsubstituted, saturated or unsaturated, monocyclic or fused-ring heterocyclic group. Examples of this heterocyclic group include pyrrolidino, piperidino, morpholino, 1-piperazinyl,
-Indolinyl, 1,2,3,4-tetrahydroquinolin-1-yl, 1-imidazolidinyl, 1-pyrazolyl, 1-pyrrolinyl, 1-pyrazolidinyl, 2,3-dihydro-1-indazolyl, 2-isoindolinyl, 1
-Indolyl, 1-pyrrolyl, 4-thiazine-S, S-
Dioxo-4-yl or benzoxazin-4-yl.

When X ¹ and X ^{2 each} represent a substituted alkyl, an aryl or a heterocyclic group, and the nitrogen-containing heterocyclic group formed by X ³ together with> N— has a substituent. The following are examples of such substituents. Halogen atom (for example, fluorine atom, chloro atom), alkoxycarbonyl group (C 2-30,
Preferably 2-20. For example, methoxycarbonyl, dodecyloxycarbonyl, hexadecyloxycarbonyl), acylamino group (2-30 carbon atoms, preferably 2
~ 20. For example, acetamide, tetradecaneamide, 2
-(2,4-di-t-amylphenoxy) butanamide, benzamide), a sulfonamide group (having 1 to 3 carbon atoms)
0, preferably 1-20. For example, methanesulfonamide, dodecanesulfonamide, hexadecylsulfonamide, benzenesulfonamide), carbamoyl group (having 1 to 30 carbon atoms, preferably 1 to 20; for example, N-butylcarbamoyl, N, N-diethylcarbamoyl), N-
A sulfonylcarbamoyl group (1 to 30 carbon atoms, preferably 1 to 20; for example, N-mesylcarbamoyl, N-dodecylsulfonylcarbamoyl); a sulfamoyl group (1 to 30 carbon atoms, preferably 1 to 20; for example, N-butylsulfa) Moyl, N-dodecylsulfamoyl, N-hexadecylsulfamoyl, N-3- (2,4-di-t
-Amylphenoxy) butylsulfamoyl, N, N-
Diethylsulfamoyl), alkoxy group (1 to 1 carbon atoms)
30, preferably 1-20. For example, methoxy, hexadecyloxy, isopropoxy), aryloxy group (C6-20, preferably 6-10. For example, phenoxy, 4-methoxyphenoxy, 3-t-butyl-4-hydroxyphenoxy, naphthoxy), aryl An oxycarbonyl group (C7-21, preferably 7-11; e.g. phenoxycarbonyl), an N-acylsulfamoyl group (C2-30, preferably 2-20; e.g. N
-Propanoylsulfamoyl, N-tetradecanoylsulfamoyl), sulfonyl group (1 to 30 carbon atoms, preferably 1 to 20; for example, methanesulfonyl, octanesulfonyl, 4-hydroxyphenylsulfonyl, dodecanesulfonyl), alkoxy Carbonylamino group (1 to 30, preferably 1 to 20 carbon atoms; for example, ethoxycarbonylamino), cyano group, nitro group, carboxyl group, hydroxyl group, sulfo group, alkylthio group (1 to 30 carbon atoms, preferably 1 to 30 carbon atoms) 20. For example, methylthio,
Dodecylthio, dodecylcarbamoylmethylthio), a ureido group (1 to 30 carbon atoms, preferably 1 to 20; for example, N-phenylureido, N-hexadecylureido), an aryl group (6 to 20 carbon atoms, preferably 6 to 1 carbon atom)
0. For example, phenyl, naphthyl, 4-methoxyphenyl), a heterocyclic group (C1-20, preferably 1-1)
0. A monocyclic ring or a condensed ring of a 3 to 12-membered ring, preferably a 5- or 6-membered ring containing at least one nitrogen atom, oxygen atom or sulfur atom as a hetero atom. For example, 2-pyridyl, 3-pyrazolyl, 1-pyrrolyl, 2,
4-dioxo-1,3-imidazolidin-1-yl, 2
Benzoxazolyl, morpholino, indolyl), alkyl groups (C1-30, preferably C1-20, linear, branched, cyclic, saturated, unsaturated, e.g. methyl, ethyl, isopropyl, cyclopropyl, t -Pentyl, t
-Octyl, cyclopentyl, t-butyl, s-butyl, dodecyl, 2-hexyldecyl), an acyl group (1 to 30, preferably 2 to 20 carbon atoms, for example, acetyl, benzoyl), an acyloxy group (2 to 30 carbon atoms) And preferably 20 to 20. For example, propanoyloxy and tetradecanoyloxy), an arylthio group (6 to 20 carbon atoms, preferably 6 to 10; for example, phenylthio and naphthylthio), and a sulfamoylamino group (0 to 30 carbon atoms). And preferably 0 to 20. For example, N-butylsulfamoylamino, N-dodecylsulfamoylamino, N-phenylsulfamoylamino) or N-sulfonylsulfamoyl group (1 to 30 carbon atoms, preferably 1 to 30 carbon atoms) -20, for example N-mesylsulfamoyl, N-ethanesulfamoyl, N-dodecane E acylsulfamoyl, N- hexadecane sulfonylsulfamoyl) and the like.
Preferred substituents among the above are an alkoxy group, a halogen atom, an alkoxycarbonyl group, an acyloxy group,
Examples include an acylamino group, a sulfonyl group, a carbamoyl group, a sulfamoyl group, a sulfonamide group, a nitro group, an alkyl group, and an aryl group. The above substituents may further have a substituent. Examples of the substituent include the substituents mentioned here.

When Y in the general formulas (I) and (II) represents an aryl group, it has 6 to 20 carbon atoms, preferably 6 to 20 carbon atoms.
And 10 substituted or unsubstituted aryl groups. For example, a phenyl group and a naphthyl group are typical examples.

In formulas (I) and (II), when Y represents a heterocyclic group, it has the same meaning as described when X ¹ or X ² represents a heterocyclic group.

When Y represents a substituted aryl group or a substituted heterocyclic group, examples of the substituent include the aforementioned X ¹
Examples of the substituent when has a substituent include the substituents listed above. Preferred examples of the substituent for Y include:
One after the substitution is halogen atom, alkoxycarbonyl group, sulfamoyl group, carbamoyl group, sulfonyl group, N-sulfonylsulfamoyl group, N-acylsulfamoyl group, alkoxy group, acylamino group, N-sulfonylcarbamoyl group, When it is a sulfonamide group or an alkyl group.

The group represented by Z in formulas (I) and (II) may be any of a hydrogen atom and a conventionally known coupling-off group. Preferred Z is a nitrogen-containing heterocyclic group, an aryloxy group, an arylthio group, a heterocyclic oxy group, a heterocyclic thio group, an acyloxy group, a carbamoyloxy group, an alkylthio group, or a halogen atom bonded to the coupling position with a nitrogen atom. No.

These leaving groups may be a non-photographic useful group or a photographically useful group or a precursor thereof (for example, a development inhibitor, a development accelerator, a desilvering accelerator, a fogging agent, a dye, a hardener, a coupler, Oxidized developer scavenger, fluorescent dye, developing agent or electron transfer agent).

When Z is a photographically useful group, conventionally known groups are useful. For example, U.S. Pat.
8,962, 4,409,323, 4,43
8,193, 4,421,845, 4,61
8,571, 4,652,516, 4,86
1,701, 4,782,012, 4,85
7,440, 4,847,185, 4,47
7,563, 4,438,193, 4,62
Nos. 8,024, 4,618,571, 4,74
1,994, EP-A-193389A
Or a leaving group (for example, a timing group) for releasing the photographically useful group described in JP-A Nos. 148139A or 272573A.

When Z represents a nitrogen-containing heterocyclic group bonded to the coupling position by a nitrogen atom, it preferably has 1 to 1 carbon atoms.
15, preferably 1 to 10, 5- or 6-membered, substituted or unsubstituted, saturated or unsaturated, monocyclic or fused-ring heterocyclic groups. The hetero atom may include an oxygen atom or a sulfur atom in addition to the nitrogen atom.
Preferred specific examples of the heterocyclic group include 1-pyrazolyl,
1-imidazolyl, pyrrolino, 1,2,4-triazol-2-yl, 1,2,3-triazol-3-yl,
Benzotriazolyl, benzimidazolyl, imidazolidine-2,4-dione-3-yl, oxazolidine-
2,4-dione-3-yl, 1,2,4-triazolidine-3,5-dione-4-yl, 2-imidazolinone-
Examples include 1-yl, 3,5-dioxomorpholino or 1-indazolyl. When these heterocyclic groups have a substituent, examples of the substituent include the substituents listed as the substituents that the group represented by X ¹ may have. As a preferred substituent, one of the substituents is an alkyl group, an alkoxy group, a halogen atom, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylthio group, an acylamino group, a sulfonamide group, an aryl group, a nitro group, a carbamoyl group, or a sulfonyl group It is when.

When Z represents an aryloxy group, it is preferably a substituted or unsubstituted aryloxy group having 6 to 10 carbon atoms. Particularly preferred is a substituted or unsubstituted phenoxy group. When it has a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ¹ may have. Among them, preferred substituents are those in which at least one substituent is an electron-withdrawing substituent, such as a sulfonyl group, an alkoxycarbonyl group, a sulfamoyl group,
Examples include a halogen atom, a carboxyl group, a carbamoyl group, a nitro group, a cyano group, and an acyl group.

When Z represents an arylthio group, it is preferably a substituted or unsubstituted arylthio group having 6 to 10 carbon atoms. Particularly preferred is a substituted or unsubstituted phenylthio group. When it has a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ¹ may have. Among them, at least one substituent is preferably an alkyl group, an alkoxy group, a sulfonyl, an alkoxycarbonyl group, a sulfamoyl group, a halogen atom, a carbamoyl group, or a nitro group.

When Z represents a heterocyclic oxy group, the part of the heterocyclic group has 1 to 20, preferably 1 to 10 carbon atoms and contains at least one nitrogen atom, oxygen atom or sulfur atom as a hetero atom. It is a 3- to 12-membered, preferably 5- or 6-membered, substituted or unsubstituted, saturated or unsaturated, monocyclic or condensed heterocyclic group. Examples of the heterocyclic oxy group include a pyridyloxy group,
A pyrazolyloxy group or a furyloxy group. When it has a substituent, examples of the substituent include the aforementioned X
^The substituents listed as the substituents that the group represented by ¹ may have are mentioned as examples. Among the preferred substituents, one of the substituents is an alkyl group, an aryl group,
It is a carboxyl group, an alkoxy group, a halogen atom, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylthio group, an acylamino group, a sulfonamide group, a nitro group, a carbamoyl group, or a sulfonyl group.

When Z represents a heterocyclic thio group, the part of the heterocyclic group has 1 to 20, preferably 1 to 10 carbon atoms and contains at least one nitrogen atom, oxygen atom or sulfur atom as a hetero atom. It is a 3- to 12-membered, preferably 5- or 6-membered, substituted or unsubstituted, saturated or unsaturated, monocyclic or condensed heterocyclic group.
Examples of the heterocyclic thio group include a tetrazolylthio group,
3,4-thiadiazolylthio group, 1,3,4-oxadiazolylthio group, 1,3,4-triazolylthio group, benzimidazolylthio group, benzothiazolylthio group, or 2-pyridylthio group . When it has a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ¹ may have. Among them, preferred substituents are those in which at least one of the substituents is an alkyl group, an aryl group, a carboxyl group, an alkoxy group, a halogen atom, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkylthio group, an acylamino group, a sulfonamide group, or a nitro group. Group, carbamoyl group, heterocyclic group or sulfonyl group.

When Z represents an acyloxy group, it is preferably a monocyclic or condensed, substituted or unsubstituted aromatic acyloxy group having 6 to 10 carbon atoms, or 2 carbon atoms.
To 30 and preferably 2 to 20 substituted or unsubstituted aliphatic acyloxy groups. When these have a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ¹ may have.

When Z represents a carbamoyloxy group,
An aliphatic, aromatic, heterocyclic, substituted or unsubstituted carbamoyloxy group having 1 to 30, preferably 1 to 20 carbon atoms. Examples include N, N-diethylcarbamoyloxy, N-phenylcarbamoyloxy, 1-imidazolylcarbonyloxy or 1-pyrrolocarbonyloxy. When these have a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ¹ may have.

When Z represents an alkylthio group, it has 1 to 30 carbon atoms, preferably 1 to 20 carbon atoms, linear, branched, cyclic,
It is a saturated, unsaturated, substituted or unsubstituted alkylthio group. When it has a substituent, examples of the substituent include the substituents listed as the substituent which the group represented by X ¹ may have.

Next, particularly preferred ranges of the couplers represented by formulas (I) and (II) will be described below.

The group represented by X ¹ in the general formula (I) is preferably an alkyl group. The number of carbon atoms in the alkyl group, specific examples are the same as those listed as the group represented by X ^1. Particularly preferred is an alkyl group having 1 to 10 carbon atoms.

The group represented by X ² in the general formula (I) is preferably an alkyl group or an aryl group, and particularly preferably a phenyl group.

In formula (I), X ³ is preferably a group which forms a nitrogen-containing heterocyclic ring with> N, and 1-indolinyl is particularly preferable as the heterocyclic ring.

The group represented by Y in formulas (I) and (II) is preferably an aryl group. Particularly preferred is a phenyl group having at least one substituent at the ortho position. The description of the substituent includes those described as the substituent which may be possessed when Y is an aryl group. The description of the preferred substituent is the same.

The group represented by Z in formulas (I) and (II) is preferably a 5- to 6-membered nitrogen-containing heterocyclic group, an aryloxy group, which is bonded to the coupling position by a nitrogen atom.
Examples thereof include a 5- to 6-membered heterocyclic oxy group and a 5- to 6-membered heterocyclic thio group.

Preferred couplers in formulas (I) and (II) are represented by the following formulas (III), (IV) or (V).

Formula (III)

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Embedded image General formula (IV)

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Embedded image General formula (V)

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Embedded image In the formula, Z represents the same meaning as described in the general formula (I), X ⁴ represents an alkyl group, X ⁵ represents an alkyl group or an aryl group, and Ar has at least one substituent on an ortho group. X ⁶ represents an organic residue which forms a nitrogen-containing ring group (monocyclic or condensed ring) together with —C (R ¹ R ² ) —N <, and X ⁷ represents —C
An organic residue forming a nitrogen-containing heterocyclic group (monocyclic or condensed ring) together with (R ³ ) = C (R ⁴ ) -N <;
¹ , R ² , R ³ and R ⁴ represent a hydrogen atom or a substituent.

In the general formulas (III) to (V), X ^{4 to} X
The detailed description and preferred range of the groups represented by ⁷ , Ar and Z have the same meanings as those described in the corresponding ranges in the description of general formulas (I) and (II). When R ^{1 to} R ⁴ represent a substituent, those exemplified as the substituent which X ¹ may have may be mentioned as examples.

Particularly preferred couplers in the above formula are those represented by formula (IV) or (V).

The couplers represented by the general formulas (I) to (V) can be prepared by divalent or higher groups represented by X ^{1 to} X ⁷ , Y, Ar, R ^{1 to} R ⁴ and Z. Dimers or higher multimers (eg, telomers or polymers) may be formed which bind to each other. In this case, the number of carbon atoms may be out of the specified range for each substituent.

The couplers represented by the general formulas (I) to (V) are preferred examples when they are diffusion-resistant couplers.
The diffusion-resistant type is a coupler having a group in the molecular weight that sufficiently increases the molecular weight in order to immobilize the layer to which the molecule is added. Usually, an alkyl group having 8 to 30 carbon atoms, preferably 10 to 20 carbon atoms, or an aryl group having 4 to 20 carbon atoms as a substituent is used. These non-diffusible groups may be substituted in any of the molecules, and may have a plurality.

Specific examples of the couplers represented by formulas (I) to (V) are shown below, but the present invention is not limited thereto.

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Embedded image The coupler of the present invention represented by the formula (I) or (II) is
It is preferably added to a light-sensitive silver halide emulsion layer in a light-sensitive material or a layer adjacent thereto, and particularly preferably added to a light-sensitive silver halide emulsion layer.

The couplers of the formula (I) or (II) of the present invention can be used alone or in combination of two or more. When two or more kinds are added, they may be added to the same layer or different layers, but are preferably added to the same layer.

The coupler of the formula (I) or (II) of the present invention can be used in combination with other yellow couplers. There is no particular limitation on the maximum absorption wavelength of the coupler used in combination.

The coupler of the formula (I) or (II) of the present invention is preferably used for a blue-sensitive layer when the leaving group Z does not contain a photographically useful group component.

The total amount of the coupler of the formula (I) or (II) of the present invention added to the light-sensitive material is 0.0001 to 0.80 g when the leaving group Z contains a photographically useful group component. / M ²
(Sensitive material), preferably 0.0005 to 0.50 g
/ M ² , more preferably 0.02 to 0.30 g / m ² . When the leaving group Z does not contain a photographically useful group component, its addition amount is 0.001-1.20 g / m ^2.
By weight, preferably 0.01~1.00g / m ^2, more preferably 0.10~0.80g / m ^2.

The coupler of the present invention can be added in the same manner as a usual coupler.

Synthesis Example (1) Synthesis of Illustrative Coupler (1) The coupler was synthesized according to the following synthesis route.

[0095]

Embedded image Step (1) The mixture of (a) in a mixed solvent of 100 ml of N, N-dimethylformamide and 100 ml of acetonitrile.
5 g and 13 g of (b) were dissolved. At room temperature, 40 ml of an acetonitrile solution in which 6 g of N, N'-dicyclohexylcarbodiimide was dissolved was added dropwise to this solution. After reacting for 2 hours, the precipitated N, N'-dicyclohexylurea was separated by filtration. The filtrate was poured into 500 ml of water, and ethyl acetate 50 was added.
Extracted with 0 ml. After transferring to a separating funnel and washing with water, the oil layer was separated. The solvent was distilled off under reduced pressure, and hexane was added to the residue for crystallization. 16.1 g of (c) were obtained.

16 g of step (2) (c) were mixed with 150 ml of dichloromethane. A solution of 4.8 g of bromine in 10 ml of dichloromethane was added dropwise under ice cooling (5 ° C. to 10 ° C.). After reacting for 10 minutes, the mixture was transferred to a separating funnel and washed with water. The oil layer (including (d)) was taken and this solution was used in the next step.

Step (3) 8.2 g of (c) and 8.8 ml of triethylamine were added to N, N-dimethylformamide 1
Added to 60 ml. The dichloromethane solution of (d) obtained above was added dropwise to this solution at room temperature. After reacting for 1 hour, 500 ml of ethyl acetate was added, and the mixture was transferred to a separating funnel and washed with water.
After neutralization with dilute hydrochloric acid, washing was performed again with water. The oil layer was separated and the solution was distilled off under reduced pressure. The residue was separated and purified by column chromatography. Silica gel was used as a filler, and ethyl acetate / hexane (1/1) was used as an eluent. The fraction containing the desired compound is collected, and the solvent is distilled off under reduced pressure to give a wax-like coupler (1).
6.3 g were obtained. Synthesis Example (2) Synthesis of Exemplary Coupler (2) Synthesis was performed in the same manner as in Synthesis Example (1). However, the above (b)
In place of (f) and (e), the following (g) was replaced with an equimolar amount, respectively, and the same procedure was repeated, except that 15.4 g of a waxy target coupler (2) was obtained. .

[0098]

Embedded image

[0099]

Embedded image Synthesis Example (3) Synthesis of Illustrative Coupler (6) The coupler was synthesized by the reaction shown in the following scheme.

[0100]

Embedded image Compound (i) was added to 50 ml of N, N-dimethylformamide.
Was added, and triethylamine (1.87 g) was added thereto, followed by stirring for 10 minutes. This solution is added at room temperature with methylene chloride 2
A solution in which 6.23 g of the compound (h) was dissolved in 0 ml was added dropwise over 15 minutes. After reacting for 1 hour at room temperature,
The reaction solution was poured onto water and extracted with ethyl acetate. The organic layer was dried over magnesium sulfate, the desiccant was removed by filtration, and the solvent was distilled off under reduced pressure. Purification by silica gel column chromatography gave 4.7 g of the desired exemplified coupler (6) as a white powder.

The light-sensitive material of the present invention may have at least one light-sensitive layer provided on a support. A typical example is a silver halide photographic light-sensitive material having at least one light-sensitive layer comprising a plurality of silver halide emulsion layers having substantially the same color sensitivity but different sensitivities on a support. It is. The photosensitive layer is a unit photosensitive layer having color sensitivity to any of blue light, green light, and red light, and in a multilayer silver halide color photographic material, the arrangement of the unit photosensitive layers is generally A red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer are provided in this order from the support side. However, depending on the purpose, the order of installation may be reversed, or the order of installation may be such that different photosensitive layers are sandwiched between layers of the same color sensitivity. A non-light-sensitive layer may be provided between the silver halide light-sensitive layers and as the uppermost layer and the lowermost layer. These may contain a coupler, a DIR compound, a color mixing inhibitor and the like described below. As described in DE 1,121,470 or GB 923,045, a plurality of silver halide emulsion layers constituting each unit light-sensitive layer are formed by sequentially exposing two layers of a high-speed emulsion layer and a low-speed emulsion layer toward a support. It is preferable to arrange them so that the degree is low. Also, JP-A-57-112751, 62-200350, 62-2
As described in JP-A Nos. 06541 and 62-206543, a low-speed emulsion layer may be provided on the side farther from the support, and a high-speed emulsion layer may be provided on the side closer to the support.

As a specific example, from the side farthest from the support,
Low sensitivity blue photosensitive layer (BL) / High sensitivity blue photosensitive layer (BH) / High sensitivity green photosensitive layer (GH) / Low sensitivity green photosensitive layer (GL) / High sensitivity red photosensitive layer (RH) / In the order of the low-sensitivity red photosensitive layer (RL), or in the order of BH / BL / GL / GH / RH / RL, or BH / BL / GH /
They can be installed in the order of GL / RL / RH.

As described in JP-B-55-34932, the blue-sensitive layer / GH /
They can be arranged in the order of RH / GL / RL. Also, JP-A-56
As described in -25738 and 62-63936, the layers may be arranged in the order of blue-sensitive layer / GL / RL / GH / RH from the side farthest from the support.

As described in JP-B-49-15495, the upper layer is a silver halide emulsion layer having the highest sensitivity, the middle layer is a silver halide emulsion layer having a lower sensitivity, and the lower layer is a layer having a lower sensitivity than the middle layer. An example is an arrangement in which a silver halide emulsion layer having a low sensitivity is arranged and three layers having different sensitivities are sequentially reduced in sensitivity toward a support. Even when such a three-layer structure having different photosensitivity is used,
As described in JP-A-59-202464, in the same color-sensitive layer, the layers may be arranged in the order of medium-speed emulsion layer / high-speed emulsion layer / low-speed emulsion layer from the side away from the support.

In addition, a high-speed emulsion layer / low-speed emulsion layer / medium-speed emulsion layer, or a low-speed emulsion layer / medium-speed emulsion layer / high-speed emulsion layer may be arranged in this order.

Also, in the case of four or more layers, the arrangement may be changed as described above.

In order to improve color reproducibility, US Pat. No. 4,663,27
1, 4,705,744, 4,707,436, JP-A-62-160448,
It is preferable to arrange a donor layer (CL) having a multilayer effect having a different spectral sensitivity distribution from that of the main photosensitive layer such as BL, GL, and RL described in the specification of JP-A-63-89850, adjacent to or close to the main photosensitive layer. .

The preferred silver halide used in the present invention is silver iodobromide, silver iodochloride, or silver iodochlorobromide containing about 30 mol% or less of silver iodide. Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mol% to about 10 mol% silver iodide.

The silver halide grains in the photographic emulsion include those having regular crystals such as cubic, octahedral and tetradecahedral, those having irregular crystalline forms such as spherical and plate-like,
It may have a crystal defect such as a twin plane or a composite form thereof.

The silver halide may be fine grains having a grain size of about 0.2 μm or less or large grains having a projected area diameter of about 10 μm, and may be a polydisperse emulsion or a monodisperse emulsion.

The silver halide photographic emulsion usable in the present invention is, for example, Research Disclosure (hereinafter referred to as RD).
No. 17643 (December 1978), pages 22 to 23, "I. Emulsion preparation and types", and No. 18716 (November 1979), page 648, No. 307105 (1989
Nov., pp. 863-865, and Grafkid, "Physics and Chemistry of Photography", published by Paul Montell (P. Glafkides, Chimie)
et Phisique Photographiques, Paul Montel, 1967),
Duffin, Photographic Emulsion Chemistry, Focal Press (GF Duffin, Photographic Emulsion Chemistry, Foc)
al Press, 1966), "Production and Coating of Photographic Emulsions", by Zelikman et al., Published by Focal Press (VL Zelikman, et a
l., Making and Coating Photographic Emulsion, Foca
l Press, 164).

US 3,574,628, US 3,655,394 and GB 1,4
Monodisperse emulsions described in 13,748 are also preferred.

Tabular grains having an aspect ratio of about 3 or more can also be used in the present invention. Tabular grains are described in Gutoff, Photographic Science and Engineering (Gutoff, Photographic Science and E).
ngineering), Vol. 14, pp. 248-257 (1970); US 4,43.
It can be easily prepared by the methods described in 4,226, 4,414,310, 4,433,048, 4,439,520 and GB 2,112,157.

The crystal structure may be uniform, the inside and the outside may be composed of different halogen compositions, or may have a layered structure. Silver halides having different compositions may be joined by epitaxial joining, or may be joined to a compound other than silver halide, such as, for example, silver rhodanate or lead oxide. Also, a mixture of particles of various crystal forms may be used.

The above emulsion may be either a surface latent image type in which a latent image is mainly formed on the surface, an internal latent image type in which a latent image is formed inside a grain, or a type having a latent image on both the surface and the inside. Type emulsion. Among the internal latent image type emulsions, core / shell type internal latent image type emulsions described in JP-A-63-264740 may be used.
-133542. The thickness of the shell of this emulsion varies depending on the development process and the like, but is preferably 3 to 40 nm, and 5 to 40 nm.
-20 nm is particularly preferred.

As the silver halide emulsion, usually, those subjected to physical ripening, chemical ripening and spectral sensitization are used. Additives used in such a process are RD No. 17643 and RD No. 187.
16 and No. 307105, and the relevant portions are summarized in the table below.

The light-sensitive material of the present invention comprises a light-sensitive silver halide emulsion having a grain size, a grain size distribution, a halogen composition,
Two or more emulsions differing in at least one characteristic of grain shape and sensitivity can be mixed and used in the same layer.

The silver halide grains having a fogged surface described in US Pat. No. 4,082,553, US Pat. No. 4,626,498, JP-A-59-214852.
It is preferable to apply the silver halide grains and colloidal silver having the inside of the grains described in (1) to the light-sensitive silver halide emulsion layer and / or the substantially light-insensitive hydrophilic colloid layer. The term "silver halide particles having a fogged interior or surface" refers to silver halide grains that can be uniformly (non-imagewise) developed regardless of unexposed portions and exposed portions of the photosensitive material. , Its preparation method is described in US Pat.
It is described in 214852. The silver halide forming the internal nucleus of the core / shell type silver halide grain having the inside of the grain fogged may have a different halogen composition. As the silver halide having the inside or surface of the grain fogged, any of silver chloride, silver chlorobromide, silver iodobromide and silver chloroiodobromide can be used. The average grain size of these fogged silver halide grains is 0.01 to 0.75 μm, particularly 0.05
~ 0.6 μm is preferred. The grains may be regular grains or polydisperse emulsions, but may be monodisperse (at least 95% of the weight or the number of silver halide grains has a grain size within ± 40% of the average grain size). Is preferable.

In the present invention, it is preferable to use non-photosensitive fine grain silver halide. Non-photosensitive fine grain silver halide is silver halide fine grains that are not exposed during imagewise exposure to obtain a dye image and are not substantially developed in the developing process, and are preferably not fogged in advance. . The fine grain silver halide has a silver bromide content of 0 to 100 mol%, and may contain silver chloride and / or silver iodide as needed. Preferably, it contains 0.5 to 10 mol% of silver iodide. Fine grain silver halide, average grain size (average value of projected area equivalent circle diameter)
Is preferably 0.01 to 0.5 μm, more preferably 0.02 to 0.2 μm.

The fine silver halide grains can be prepared in the same manner as in the case of ordinary light-sensitive silver halide. The surface of the silver halide grains does not need to be optically sensitized, and no spectral sensitization is required. However, before adding this to the coating solution, a triazole-based, azaindene-based,
It is preferable to add a known stabilizer such as a benzothiazolium-based or mercapto-based compound or a zinc compound. Colloidal silver can be contained in the layer containing fine silver halide grains.

The coated silver amount of the light-sensitive material of the present invention was 6.0 g / m 2.
² or less, and most preferably 4.5 g / m ² or less.

The photographic additives which can be used in the present invention are also described in RD, and the relevant portions are shown in the following table.

Types of Additives RD17643 RD18716 RD307105 Chemical sensitizer page 23, page 648, right column, page 866 2. 2. Sensitivity enhancer, page 648, right column 3. Spectral sensitizer, pages 23 to 24, page 648, right column, pages 866 to 868 Super sensitizer, page 649, right column Brightener page 24 page 647 page right column page 868 5. 5. Light absorbers, pages 25 to 26, page 649, right column, page 873 Filters, page 650, left column, dyes, ultraviolet absorbers Binder page 26 page 651 left column pages 873 to 874 7. 7. Plasticizer, page 27 page 650, right column, page 876 Lubricant Coating aid, pages 26 to 27, page 650, right column, pages 875 to 876 Surfactant 9. Static 27 pages 650 pages right column pages 876-877 Inhibitors 10. Matting Agents, pages 878 to 879 Various dye-forming couplers can be used in the light-sensitive material of the present invention, but the following couplers are particularly preferred.

Yellow coupler: Formula (I) of EP 502,424A,
Coupler represented by (II); Formulas (1) and (2) of EP 513,496A
(Especially Y-28 on page 18); EP 568,037A
A coupler of the formula (I) of claim 1 of US Pat.
6,576, column 45, line 45 to 55, couplers represented by the general formula (I); JP-A-4-74425, paragraph 0008, couplers represented by the general formula (I); EP 498,381 A1, page 40, claim 1 Couplers (especially D-35 on page 18); EP 447,969A1-4
Couplers represented by the formula (Y) on the page (especially Y-1 (page 17), Y-54
(Page 41)); US Pat. No. 4,476,219, column 7, lines 36 to 58, formula (II)
~ (IV) (especially II-17,19 (column 1
7), II-24 (column 19)).

Magenta coupler; JP-A-3-39737 (L-57 (1
L-68 (lower right of page 12), L-77 (lower right of page 13); EP 456,
257, [A-4] -63 (p. 134), [A-4] -73, -75 (p. 139); EP 486,
965 M-4, -6 (p. 26), M-7 (p. 27); EP 571, 959A M-45 (19
(M-1) of JP-A-5-204106 (page 6); M-22 of paragraph 0237 of JP-A-4-32631.

Cyan coupler: CX-1, described in JP-A-4-04843
3,4,5,11,12,14,15 (pages 14 to 16); JP-A 4-43345 C-
7,10 (p. 35), 34, 35 (p. 37), (I-1), (I-17) (pp. 42-43);
A coupler represented by the general formula (Ia) or (Ib) according to claim 1 of JP-A-6-67385. Polymer coupler: JP-A-2-44345
P-1, P-5 (page 11).

Examples of couplers in which the coloring dyes have an appropriate diffusibility include US Pat. No. 4,366,237, GB 2,125,570, EP 96,873B,
Those described in DE 3,234,533 are preferred. Couplers for correcting unnecessary absorption of color-forming dyes are yellow colored cyan couplers represented by the formulas (CI), (CII), (CIII), and (CIV) described on page 5 of EP 456,257A1 (especially on page 84). YC-86), the EP
Yellow colored magenta coupler ExM-7 (202
), EX-1 (page 249), EX-7 (page 251), US 4,833,069
Magenta colored cyan coupler CC-9 (column
8), CC-13 (column 10), (2) of US 4,837,136 (column 8),
Colorless masking couplers of formula (A) in claim 1 of WO 92/11575 (especially the exemplified compounds on pages 36 to 45) are preferred.

Examples of the compounds (including couplers) which release a photographically useful compound residue by reacting with an oxidized developing agent include the following. Development inhibitor releasing compound:
Compounds of the formulas (I), (II), (III) and (IV) described on page 11 of EP 378,236A1 (especially T-101 (page 30), T-104 (page 31), T-11
3 (page 36), T-131 (page 45), T-144 (page 51), T-158 (page 58)), EP43
Compounds represented by the formula (I) described on page 7 of 6,938A2 (particularly D-49 (page 51)), compounds represented by the formula (1) of EP 568,037A (particularly (23) (page 11)), Compounds of the formulas (I), (II) and (III) described on pages 5 to 6 of EP 440,195 A2 (especially on page 29)
I- (1)); Bleaching accelerator releasing compounds: compounds represented by the formulas (I) and (I ′) on page 5 of EP 310,125A2 (especially (60) and (6) on page 1)
1)) and the compound represented by formula (I) of claim 1 of JP-A-6-59411 (particularly (7) (page 7)); Ligand releasing compound: US
A compound represented by LIG-X described in claim 1 of 4,555,478 (especially a compound on line 21 to 41 of column 12); a leuco dye-releasing compound: compound 1 of column 3 to 8 of US 4,749,641
~ 6; Fluorescent dye releasing compound: Claim 4, C of US 4,774,181
Compound represented by OUP-DYE (especially compounds 1 to 11 in columns 7 to 10); Development accelerator or fogging agent releasing compound: US
4,656,123, the compounds of formulas (1), (2) and (3) in column 3 (especially (I-22) in column 25) and EP 450,637A2
ExZK-2, p. 75, lines 36-38; Compound which releases a group which becomes a dye only when it is cleaved: Formula (I) of claim 1 of US 4,857,447
(Especially Y-1 to Y-19 in columns 25 to 36)
.

The following are preferred as additives other than the coupler.

Dispersion medium for oil-soluble organic compound: JP-A-62-215
272 P-3,5,16,19,25,30,42,49,54,55,66,81,85,86,93
Latex for impregnating oil-soluble organic compound: Latex described in US Pat. No. 4,199,363; Oxidized developing agent scavenger: Compound represented by formula (I) in column 2, lines 54 to 62 of US 4,978,606 Especially I-, (1), (2), (6), (12)
(Columns 4-5), formulas in rows 5-10 of column 2 of US 4,923,787 (especially compound 1 (column 3); stain inhibitor: EP
Formulas (I) to (III) on page 4, lines 30 to 33 of 298321A, especially I-47, 72,
III-1, 27 (pages 24 to 48); Anti-fading agent: A-6 of EP 298321A,
7,20,21,23,24,25,26,30,37,40,42,48,63,90,92,94,164
(Pp. 69-118), II-5-II of columns 25-38 of US 5,122,444
I-23, especially III-10, I-1 to III- on pages 8 to 12 of EP 471347A
4, especially II-2, US 5,139,931 columns 32 to 40, A-1 to 48,
In particular, A-39, 42; a material that reduces the amount of a color-enhancing agent or color-mixing inhibitor used: EP 411324A, pages 5 to 24, I-1 to II-15,
Especially I-46; Formalin Scavenger: 24 of EP 477932A
SCV-1 to 28 on page 29, especially SCV-8; hardener: JP-A 1-21
4845, page 17, H-1,4,6,8,14, US 4,618,573, columns 13-
Compounds (H-1 to 54) represented by formulas (VII) to (XII) of 23, compounds represented by the formula (6) at the lower right of page 8 of JP-A-2-214852 (H
-1 to 76), especially compounds described in claim 1 of H-14, US Pat. No. 3,325,287; development inhibitor precursors: disclosed in JP-A-62-168139.
P-24, 37, 39 (pages 6 to 7); compounds described in claim 1 of US Pat. No. 5,019,492, in particular, 28, 29 of column 7;
US 4,923,790, columns 3-15, I-1 to III-43, especially II-
1,9,10,18, III-25; stabilizer, antifoggant: US 4,923,
793 columns 6 to 16 I-1 to (14), especially I-1,60, (2), (13),
Compounds 1-65, especially 3 in columns 25-32 of US 4,952,483
6: Chemical sensitizer: triphenylphosphine selenide, compound 50 of JP-A-5-40324; dye: 15-1 of JP-A-3-156450
A-1 to b-20 on page 8, especially a-1,12,18,27,35,36, b-5,27 to 2
V-1 to 23 on page 9, especially FI on page 33 to 55 of V-1, EP 445627A
-1 to F-II-43, especially FI-11, F-II-8, 17 to 2 of EP 457153A
III-1 to 36 on page 8, especially III-1,3, 8 to 26 in WO 88/04794
A microcrystalline dispersion of Dye-1 to 124, compounds 1 to 22 on pages 6 to 11 of EP 319999A, in particular compounds D-1 to 87 (compounds 1 and 519306A represented by formulas (1) to (3)). (Pages 3 to 28), US 4,2
Compounds 1 to 22 represented by the formula (I) of 68,622 (columns 3 to
10), compounds (1) to (4) of the formula (I) of US Pat.
(31) (Columns 2 to 9); UV absorber: Formula of JP-A-46-3335
Compounds (18b) to (18r), 101 to 427 (6 to
9), and the compounds (3) to (6) represented by the formula (I) in EP 520938A.
6) (Pages 10 to 44) and compound HBT-1 represented by formula (III)
~ 10 (page 14), a compound represented by formula (1) in EP 521823A
(1) to (31) (columns 2 to 9).

The present invention is preferably applied to color negative films for general use, and is disclosed in JP-B-2-32615, JP-B-3-3978.
It is suitable for the film unit with lens described in 4.

Suitable supports that can be used in the present invention include, for example, the aforementioned RD. No. 17643, page 28, RD. No. 18716, page 647 right column to page 648 left column, and RD. No. 307105, page 879. It is described in.

In the light-sensitive material of the present invention, the total thickness of all the hydrophilic colloid layers on the side having the emulsion layer is preferably 28 μm or less, more preferably 23 μm or less, further preferably 18 μm or less, and more preferably 16 μm or less. Particularly preferred. Further, the film swelling speed T _1/2 is preferably 30 seconds or less, more preferably 20 seconds or less. T _1/2 is the time required for the film thickness to reach 1/2 when the saturated film thickness is 90% of the maximum swelled film thickness reached when the color developing solution is processed at 30 ° C. for 3 minutes and 15 seconds. Is defined.
The film thickness means a film thickness measured under humidity control at 25 ° C. and a relative humidity of 55% (2 days), and T _1/2 is a value obtained by A. Green et al. In Photographic Science and Engineering. (Photogr. Sci. Eng.), Vol. 19, pp. 2,124-129, which can be used for measurement. T _1/2 can be adjusted by adding a hardening agent to gelatin as a binder or by changing the aging conditions after coating. The swelling ratio is preferably from 150 to 400%. The swelling ratio can be calculated from the maximum swelling film thickness under the conditions described above by the following formula: (maximum swelling film thickness-film thickness) / film thickness.

In the light-sensitive material of the present invention, a hydrophilic colloid layer (referred to as a back layer) having a total dry film thickness of 2 μm to 20 μm is preferably provided on the side opposite to the side having the emulsion layer.
In this back layer, the above-mentioned light absorber, filter dye,
It is preferable to contain an ultraviolet absorber, an antistatic agent, a hardener, a binder, a plasticizer, a lubricant, a coating aid, and a surfactant. The swelling ratio of this back layer is 150 ~ 500
% Is preferred.

The light-sensitive material of the present invention is obtained by using the above-mentioned RD.
No. 18716, No. 18716, 651 left column to right column, and No. 18716
No. 307105, pages 880 to 881 can be used for development.

Next, the processing solution for a color negative film used in the present invention will be described.

The compounds described in JP-A-4-21739, page 9, upper right column, line 1 to page 11, lower left column, line 4 can be used in the color developer used in the present invention. As a color developing agent for particularly rapid processing, 2-methyl-4-
[N-ethyl-N- (2-hydroxyethyl) amino]
Aniline, 2-methyl-4- [N-ethyl-N- (3-
Hydroxypropyl) amino] aniline, 2-methyl-
4- [N-ethyl-N- (4-hydroxybutyl) amino] aniline is preferred.

These color developing agents are used in an amount of preferably 0.01 to 0.08 mol, more preferably 0.015 to 0.06 mol, and further preferably 0.02 to 0.05 mol, per liter of the color developing solution. The replenisher of the color developing solution preferably contains a color developing agent having a concentration of 1.1 to 3 times, more preferably 1.3 to 2.5 times the concentration.

As a preservative of the color developing solution, hydroxylamine can be used in a wide range. If higher preservation is required, substitution with an alkyl group, a hydroxyalkyl group, a sulfoalkyl group, a carboxyalkyl group, or the like is required. A hydroxylamine derivative having a group is preferable, and specifically, N, N-di (sulfoethyl) hydroxylamine, monomethylhydroxylamine, dimethylhydroxylamine, monoethylhydroxylamine, diethylhydroxylamine, N, N-di (carboxyethyl) Hydroxylamines are preferred. Among the above, N, N-di (sulfoethyl) hydroxylamine is particularly preferred. These may be used in combination with hydroxylamine, but it is preferable to use one or more of them instead of hydroxylamine.

The preservative is preferably used in the range of 0.02 to 0.2 mol per liter, particularly preferably 0.03 to 0.15 mol, more preferably 0.04 to 0.1 mol. As in the case of the color developing agent, the replenisher preferably contains a preservative at a concentration of 1.1 to 3 times the concentration of the mother liquor (processing tank solution).

In the color developing solution, sulfite is used as an anti-tarring agent for the oxide of the color developing agent. The sulfite is preferably used in the range of 0.01 to 0.05 mol per liter, particularly preferably in the range of 0.02 to 0.04 mol.
The replenisher is preferably used at a concentration 1.1 to 3 times the above.

The pH of the color developing solution is preferably in the range of 9.8 to 11.0, particularly preferably 10.0 to 10.5, and the replenisher is set to a higher value in the range of 0.1 to 1.0 from these values. Preferably. In order to stably maintain such a pH, a known buffer such as carbonate, phosphate, sulfosalicylate, and borate is used.

The replenishment amount of the color developing solution is preferably from 80 to 1300 ml / m ² of the light-sensitive material, but is preferably smaller from the viewpoint of reducing environmental pollution load, specifically from 80 to 600 ml, more preferably from 80 to 600 ml. 80-400 ml are preferred.

The bromide ion concentration in the color developing solution is usually from 0.01 to 0.06 mol per liter. However, fog is suppressed while maintaining sensitivity, discrimination is improved, and graininess is improved. For this purpose, it is preferably set to 0.015 to 0.03 mol per liter. When the bromide ion concentration is set in such a range, the replenisher may contain bromide ions calculated by the following formula. However, when C becomes negative, it is preferred that the replenisher does not contain bromide ions.

C = A−W / V C: Bromide ion concentration in the color developing replenisher (mol / liter) A: Target bromide ion concentration in the color developing solution (mol / liter) W: 1 m ² exposure When the material is color-developed, the amount of bromide ion eluted from the light-sensitive material into the color-developing solution (mol) V: The replenishment amount of the color-developing replenisher for 1 m ² of the light-sensitive material (liter) In addition, when a high bromide ion concentration is set, 1-phenyl-3-pyrazolidone or 1-phenyl-2-methyl-2 may be used as a method for increasing sensitivity.
It is also preferable to use a development accelerator such as pyrazolidones represented by -hydroxymethyl-3-pyrazolidone and thioether compounds represented by 3,6-dithia-1,8-octanediol.

The compounds and processing conditions described in JP-A-4-125558, page 4, lower left column, line 16 to page 7, lower left column, line 6 can be applied to the processing solution having bleaching ability in the present invention. .

The bleaching agent preferably has an oxidation-reduction potential of 150 mV or more, and specific examples thereof are described in JP-A-5-72694 and JP-A-5-72694.
Preferred are those described in 5-173312, and in particular, 1,3-diaminopropanetetraacetic acid, and specific example 1 on page 7 of JP-A-5-73312.
Are preferred.

In order to improve the biodegradability of the bleaching agent, JP-A-4-251845, JP-A-4-268552, EP588,289, and 591,
934, a compound ferric complex salt described in JP-A-6-208213 is preferably used as a bleaching agent. The concentration of these bleaching agents is preferably 0.05 to 0.3 mol per liter of a liquid having bleaching ability, and particularly preferably 0.1 mol to 0.15 mol for the purpose of reducing the amount discharged to the environment. When the bleaching solution is a bleaching solution, it preferably contains 0.2 to 1 mol of bromide per liter, particularly preferably 0.3 to 0.8 mol.

The replenisher of the solution having the bleaching ability basically contains the concentration of each component calculated by the following formula. Thereby, the concentration in the mother liquor can be kept constant.

C _R = C _T × (V ₁ + V ₂ ) / V ₁ + C _P C _R : concentration of component in replenisher C _T : concentration of component in mother liquor (treatment tank solution) C _P : during treatment Concentration of consumed components V ₁ : Replenishment amount of replenisher having bleaching ability for photosensitive material of 1 m ² (milliliter) V ₂ : Amount brought in from prebath by photosensitive material of 1 m ² (milliliter) Preferably contains a pH buffer, particularly preferably a dicarboxylic acid having a low odor, such as succinic acid, maleic acid, malonic acid, glutaric acid, and adipic acid. Also, JP-A-53-95630, RDN
It is also preferable to use known bleaching accelerators described in O. 17129, US 3,893,858.

The bleaching solution contains 50 to ¹⁰ per m ² of the light-sensitive material.
It is preferred to replenish 00 ml of bleach replenisher, especially 80-500 ml, even 100-300
It is preferred to make up for milliliters. Further, it is preferable to perform aeration on the bleaching solution.

The processing solution having a fixing ability is disclosed in
The compounds and processing conditions described on page 7, lower left column, line 10 to page 8, lower right column, line 19 of 4-125558 can be applied.

In particular, in order to improve the fixing speed and the preservation, a processing solution having a fixing ability by using the compounds represented by the general formulas (I) and (II) of JP-A-6-301169, alone or in combination. Is preferably contained. In addition to the use of p-toluenesulfinic acid salts, the use of sulfinic acids described in JP-A-1-224762 is also preferable from the viewpoint of improving the preservation.

It is preferable to use ammonium as a cation in the solution having the bleaching ability or the solution having the fixing ability from the viewpoint of improving the desilvering property. However, from the viewpoint of reducing environmental pollution, ammonium is reduced or reduced to zero. Is more preferred.

In the bleaching, bleach-fixing and fixing steps, it is particularly preferable to carry out jet stirring described in JP-A-1-309590.

The replenishment rate of the replenisher in the bleach-fixing or fixing step is from 100 to 1000 ml, preferably from 150 to 700 ml, particularly preferably from 200 to 600 ml, per m ² of the photographic material.

In the bleach-fixing and fixing steps, it is preferable to install various silver recovery devices in-line or off-line to recover silver. By installing in-line, the processing can be carried out with a reduced silver concentration in the solution, so that the replenishment amount can be reduced. It is also preferable to recover silver off-line and reuse the remaining liquid as a replenisher.

The bleach-fixing step and the fixing step can be constituted by a plurality of processing tanks, and it is preferable that each tank is cascaded to form a multistage countercurrent system. From the balance with the size of the developing machine, a two-tank cascade configuration is generally efficient, and the ratio of the processing time in the former tank and the latter tank is preferably in the range of 0.5: 1 to 1: 0.5. In particular, the range of 0.8: 1 to 1: 0.8 is preferable.

It is preferable that a free chelating agent not forming a metal complex is present in the bleach-fixing solution or the fixing solution from the viewpoint of improvement in preservation. These chelating agents are described in connection with the bleaching solution. Preferably, a biodegradable chelating agent is used.

Regarding the washing and stabilizing steps, see JP-A-4-125558, page 12, lower right column, line 6 to page 13, lower right column, line 16
The contents described in the line can be preferably applied. In particular, EP 504,60 replaces formaldehyde in stabilizers.
9. Use of the azolylmethylamines described in 519,190 and N-methylolazoles described in JP-A-4-362943, and the use of an interface free of image stabilizers such as formaldehyde by dimerizing a magenta coupler. It is preferable to use a liquid of the activator from the viewpoint of preserving the working environment.

In order to reduce the adhesion of dust to the magnetic recording layer applied to the light-sensitive material, a stabilizer described in JP-A-6-289559 can be preferably used.

The amount of washing and replenishment of the stabilizing solution can be adjusted according to the photosensitive material 1
m is preferably ² per 80 to 1,000 ml, particularly 1
The range of from 00 to 500 ml, and more preferably from 150 to 300 ml, is a preferable range in terms of both securing a washing or stabilizing function and reducing waste liquid for environmental protection. In the treatment carried out with such a replenishing amount, a known method such as thiabendazole, 1,2-benzisothiazolin-3-one and 5-chloro-2-methylisothiazolin-3-one is used to prevent the growth of bacteria and fungi. It is preferable to use water deionized with an antifungal agent, an antibiotic such as gentamicin, or an ion exchange resin. It is more effective to use a combination of deionized water and a bactericide or antibiotic.

Further, the liquid in the washing or stabilizing liquid tank is
JP-A-3-46652, JP-A-3-53246, JP-A-355542, JP-A-3-12144
8, it is also preferable to reduce the replenishment amount by performing the reverse osmosis membrane treatment according to 3-126030, the reverse osmosis membrane in this case,
Preferably, it is a low pressure reverse osmosis membrane.

In the process of the present invention, it is particularly preferable to carry out the correction of evaporation of the processing solution disclosed in Hatsumei Kyokai Disclosure No. 94-4992. In particular, a method of performing correction using temperature and humidity information of a developing machine installation environment based on (Equation 1) on page 2 is preferable. The water used for evaporation correction is preferably collected from a replenishment tank for washing,
In that case, it is preferable to use deionized water as the washing replenishing water.

As the treating agent used in the present invention, those described in the above-mentioned published technical report from page 3, right column, line 15 to page 4, left column, line 32 are preferable. In addition, as a developing machine used for this,
The film processor described on page 3, right column, lines 22 to 28 is preferred.

Specific examples of preferred processing agents, automatic developing machines, and evaporation correction methods for carrying out the present invention are described in the above-mentioned published technical report, from page 5, right column, line 11 to page 7, right column, last line. Have been.

The supply form of the treating agent used in the present invention is as follows.
It may be in any form, such as a liquid preparation in the form of a liquid used or a concentrated form, or granules, powders, tablets, pastes, and emulsions. As an example of such a treating agent, JP-A-63-1
7453 discloses a liquid agent contained in a container having low oxygen permeability,
19655, 4-230748, vacuum-packed powders or granules, 4-221951, granules containing a water-soluble polymer,
JP-A-51-61837 and JP-A-6-102628 describe tablets and JP-A-57-5
Discloses a paste-like treating agent, which can be preferably used, but from the viewpoint of simplicity at the time of use,
It is preferable to use a liquid that has been prepared in advance in a concentration for use.

[0168] Polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, nylon or the like is used alone or as a composite material for the container for storing these treating agents. These are selected according to the required level of oxygen permeability. For an easily oxidizable liquid such as a color developing solution, a material having low oxygen permeability is preferable, and specifically, a polyethylene terephthalate or a composite material of polyethylene and nylon is preferable. These materials are used in containers having a thickness of 500 to 1500 μm, and preferably have an oxygen permeability of 20 ml / m ² · 24 hrs · atm or less.

Next, the processing solution for the color reversal film used in the present invention will be described.

Regarding the processing for the color reversal film,
Aztec Co., Ltd. No. 6 (April 1, 1991), page 1, line 5 to page 10, line 5, and page 15, line 8 to line 24
It is described in detail in line 2 of the page, and any of the contents can be preferably applied. In processing a color reversal film, the image stabilizer is contained in a conditioning bath or a final bath. Such image stabilizers include, in addition to formalin, sodium formaldehyde sodium bisulfite and N-methylolazole, and from the viewpoint of working environment, sodium formaldehyde sodium bisulfite or N-methylolazole is preferable, and N-methylol is preferred. As the azoles, N-methyloltriazole is particularly preferred.
In addition, the contents regarding the color developing solution, bleaching solution, fixing solution, washing water, etc. described in the processing of the color negative film,
It can be preferably applied to the processing of a color reversal film.

A preferred color reversal film treating agent having the above-mentioned content is Eastman Kodak E-6.
Examples of the treating agent include CR-56 treating agent manufactured by Fuji Photo Film Co., Ltd.

Next, the magnetic recording layer used in the present invention will be described.

The magnetic recording layer used in the present invention is obtained by coating a support with an aqueous or organic solvent-based coating liquid in which magnetic particles are dispersed in a binder.

The magnetic particles used in the present invention are γFe ₂
Ferromagnetic iron oxide such as O _3, Co deposited γFe ₂ O _3, Co coated magnetite ,, Co-containing magnetite, ferromagnetic chromium dioxide, ferromagnetic metal, ferromagnetic alloy, hexagonal system Ba ferrite, Sr ferrite, Pb ferrite, Ca ferrite, etc. can be used. Co-coated ferromagnetic iron oxide, such as Co-coated γFe ₂ O _3, is preferred. The shape may be any of needle shape, rice grain shape, spherical shape, cubic shape, plate shape and the like. 20 in S _BET for specific surface area
m is preferably not less than ² / g, and particularly preferably equal to or greater than 30 m ² / g.
The saturation magnetization (σs) of the ferromagnetic material is preferably 3.0 × 10 ⁴ to
3.0 × 10 ⁵ A / m, particularly preferably 4.0 × 10 ⁴ to 2.
It is 5 × 10 ⁵ A / m. The ferromagnetic particles are made of silica and / or
Alternatively, a surface treatment with alumina or an organic material may be performed. Further, the surface of the magnetic particles may be treated with a silane coupling agent or a titanium coupling agent as described in JP-A-6-161032. JP-A-4-259911, 5-
Magnetic particles having a surface coated with an inorganic or organic substance described in No. 81652 can also be used.

The binder used for the magnetic particles may be a thermoplastic resin, a thermosetting resin, a radiation-curable resin, a reactive resin, an acid, an alkali or a biodegradable polymer, or a natural material described in JP-A-4-219569. Combinations (cellulose derivatives, sugar derivatives, etc.) and mixtures thereof can be used. The above resin has a Tg of -40 ° C to 300 ° C and a weight average molecular weight of 2,000 to 1,000,000. Examples thereof include vinyl copolymers, cellulose diacetate, cellulose triacetate, cellulose derivatives such as cellulose acetate propionate, cellulose acetate butyrate, and cellulose tripropionate, acrylic resins and polyvinyl acetal resins, and gelatin is also preferable. Particularly, cellulose di (tri) acetate is preferable. The binder can be cured by adding an epoxy-based, aziridine-based, or isocyanate-based crosslinking agent. Examples of the isocyanate-based crosslinking agent include isocyanates such as tolylene diisocyanate, 4,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate, and xylylene diisocyanate, and reaction products of these isocyanates with polyalcohol (for example, 3mol of isocyanate and 1m of trimethylolpropane
ol reaction product), and polyisocyanates formed by condensation of these isocyanates.
For example, it is described in JP-A-6-59357.

As a method for dispersing the above-mentioned magnetic substance in the binder, a kneader, a pin type mill, an annular type mill and the like are preferably used, as in the method described in JP-A-6-35092. Dispersants described in JP-A-5-088283 and other known dispersants can be used. The thickness of the magnetic recording layer is 0.1 μm to 10 μm, preferably 0.2 μm to 5 μm.
m, more preferably 0.3 μm to 3 μm. The weight ratio between the magnetic particles and the binder is preferably 0.5: 100 to 60: 100.
And more preferably from 1: 100 to 30: 100.

The coating amount of the magnetic particles was 0.005 to 3 g / m ² ,
Preferably 0.01~ 2g / m ^2, more preferably 0.02 to
0.5 g / m ² . The transmission yellow density of the magnetic recording layer is
0.01 to 0.50 is preferable, 0.03 to 0.20 is more preferable, and 0.
04-0.15 is particularly preferred. The magnetic recording layer can be provided on the entire back surface of the photographic support by coating or printing, or in a stripe shape. Methods for applying the magnetic recording layer include air doctor, blade, air knife, squeeze, impregnation, reverse roll, transfer roll, gravure, kiss, cast, spray, dip, bar,
Extrusion and the like can be used, and the coating liquid described in JP-A-5-341436 is preferable.

In the magnetic recording layer, lubricity improvement, curl control,
It may have functions such as antistatic, antiadhesion, and head polishing, or may provide another functional layer to provide these functions. At least one of the particles has a Mohs hardness of 5 or more. Abrasives of the above non-spherical inorganic particles are preferred. As the composition of the non-spherical inorganic particles, oxides such as aluminum oxide, chromium oxide, silicon dioxide, titanium dioxide and silicon carbide, carbides such as silicon carbide and titanium carbide, and fine powders such as diamond are preferable. These abrasives may have their surfaces treated with a silane coupling agent or a titanium coupling agent. These particles may be added to the magnetic recording layer, or may be overcoated (for example, a protective layer, a lubricant layer, etc.) on the magnetic recording layer. As the binder used at this time, the above-mentioned binders can be used, and the same binder as the binder for the magnetic recording layer is preferable. For photosensitive materials having a magnetic recording layer, see US Pat.
5,229,259, 5,215,874 and EP 466,130.

Next, the polyester support used in the present invention will be described. For details including sensitizing materials, treatments, cartridges and examples described later, see Japanese Patent Publication No. 94-6023 (Invention Association; .15.).
The polyester used in the present invention is formed by using a diol and an aromatic dicarboxylic acid as essential components, and 2,6-, 1,5-, 1,4-, and 2,7 as aromatic dicarboxylic acids.
-Naphthalenedicarboxylic acid, terephthalic acid, isophthalic acid, phthalic acid, diethylene glycol as diol,
Examples include triethylene glycol, cyclohexanedimethanol, bisphenol A, and bisphenol.
Examples of the polymer include homopolymers such as polyethylene terephthalate, polyethylene naphthalate, and polycyclohexanedimethanol terephthalate. Particularly preferred are polyesters containing 50 to 100 mol% of 2,6-naphthalenedicarboxylic acid. Among them, polyethylene 2,6-naphthalate is particularly preferred. Average molecular weight ranges from about 5,000 to
200,000. The Tg of the polyester of the present invention is 50 ° C. or higher, preferably 90 ° C. or higher.

Next, the polyester support is heat-treated at a heat treatment temperature of 40 ° C. or more and less than Tg, more preferably Tg−20 ° C. or more and less than Tg, in order to make it difficult to form a curl. The heat treatment may be performed at a constant temperature within this temperature range, or may be performed while cooling. The heat treatment time is 0.1 to 1500 hours, more preferably 0.5 to 200 hours. The heat treatment of the support may be performed in the form of a roll, or may be performed while transporting the support in the form of a web.
Surface irregularities may be imparted (for example, conductive inorganic fine particles such as SnO ₂ or Sb ₂ O ₅ may be applied) to improve the surface state. It is also desirable to take measures such as applying knurls to the ends and raising the ends only slightly to prevent cut-out of the core. These heat treatments may be performed at any stage after the formation of the support, after the surface treatment, after the application of the back layer (antistatic agent, slip agent, etc.), and after the application of the undercoat. Preferably after application of the antistatic agent.

An ultraviolet absorbent may be kneaded into the polyester. In order to prevent light piping, the purpose can be achieved by kneading dyes or pigments commercially available for polyesters such as Diaresin manufactured by Mitsubishi Kasei and Kayaset manufactured by Nippon Kayaku.

Next, in the present invention, it is preferable to perform a surface treatment in order to bond the support and the light-sensitive material constituting layer. Chemical treatment, mechanical treatment, corona discharge treatment, flame treatment, ultraviolet treatment, high frequency treatment, glow discharge treatment, active plasma treatment,
Surface activation treatments such as laser treatment, mixed acid treatment, ozone oxidation treatment and the like can be mentioned. Among the surface treatments, ultraviolet irradiation treatment, flame treatment, corona treatment, and glow treatment are preferable.

Next, the undercoating method will be described. It may be a single layer or two or more layers. As the binder for the undercoat layer, vinyl chloride, vinylidene chloride, butadiene, methacrylic acid, acrylic acid, itaconic acid, including copolymers starting from monomers selected from maleic anhydride, as a starting material, Examples include polyethyleneimine, epoxy resin, grafted gelatin, nitrocellulose, and gelatin.
Compounds that swell the support include resorcinol and p-chlorophenol. In the undercoat layer, as a gelatin hardener, chromium salt (chromium alum, etc.), aldehydes (formaldehyde, glutaraldehyde, etc.), isocyanates, active halogen compounds (2,4-dichloro-6) are used.
-Hydroxy-S-triazine), epichlorohydrin resin, active vinyl sulfone compound and the like. SiO ₂ , TiO ₂ , inorganic fine particles or polymethyl methacrylate copolymer fine particles (0.01 to 10 μm) may be contained as a matting agent.

In the present invention, an antistatic agent is preferably used. Examples of such antistatic agents include polymers containing carboxylic acid and carboxylate and sulfonate, cationic polymers, and ionic surfactant compounds.

The most preferred antistatic agent is Z
_{nO, TiO 2, SnO 2,} Al 2 O 3, In 2 O 3, SiO 2, M
The volume resistivity of at least one selected from gO, BaO, MoO ₃ and V ₂ O ₅ is 10 ⁷ Ω · cm or less, more preferably 10 ⁷ Ω · cm or less.
⁵ Ωcm or less particle size 0.001 to 1.0 μm crystalline metal oxide or their composite oxide (Sb, P, B, In,
(S, Si, C, etc.), and fine particles of a sol-like metal oxide or a composite oxide thereof.

The content in the light-sensitive material is 5 to 500 mg / m ²
And particularly preferably 10 to 350 mg / m ² . The ratio of the amount of the conductive crystalline oxide or its composite oxide to the binder is preferably 1/300 to 100/1, more preferably 1/1.
00 to 100/5.

The light-sensitive material of the present invention preferably has a slip property. The slip agent-containing layer is preferably used on both the photosensitive layer surface and the back surface. A preferable slip property is a dynamic friction coefficient of 0.
It is 25 or less and 0.01 or more. The measurement at this time represents the value when transported at 60 cm / min against a stainless steel ball with a diameter of 5 mm (25
° C, 60% RH). In this evaluation, even if the surface of the photosensitive layer is replaced as the partner material, the values are almost the same level.

The sliding agents usable in the present invention include polyorganosiloxanes, higher fatty acid amides, metal salts of higher fatty acids, esters of higher fatty acids and higher alcohols, and the like, and polyorganosiloxanes include polydimethylsiloxane and polydiethylsiloxane. Siloxane, polystyrylmethylsiloxane, polymethylphenylsiloxane, or the like can be used. The additional layer is preferably the outermost layer of the emulsion layer or the back layer. Particularly, polydimethylsiloxane or an ester having a long-chain alkyl group is preferable.

The light-sensitive material of the present invention preferably contains a matting agent. The matting agent may be on either the emulsion side or the back side, but is particularly preferably added to the outermost layer on the emulsion side.
The matting agent may be soluble in the processing solution or insoluble in the processing solution, and preferably both are used in combination. For example, polymethyl methacrylate, poly (methyl methacrylate / methacrylic acid = 9/1 or 5/5 (molar ratio)), polystyrene particles and the like are preferable. The particle size is preferably 0.8 to 10 μm, and the particle size distribution is preferably narrow, and the average particle size is 0.9 to 10 μm.
It is preferable that 90% or more of the total number of particles is contained during 1.1 times. It is also preferable to simultaneously add fine particles having a size of 0.8 μm or less in order to enhance the matting property. For example, polymethyl methacrylate (0.2 μm), poly (methyl methacrylate / methacrylic acid = 9/1 (molar ratio), 0.3 μm)), Polystyrene particles (0.25μm), colloidal silica (0.03μm)
m).

Next, the film cartridge used in the present invention will be described. The main material of the patrone used in the present invention may be metal or synthetic plastic.

Preferred plastic materials are polystyrene, polyethylene, polypropylene, polyphenyl ether and the like. Further, the patrone of the present invention may contain various antistatic agents, and carbon black, metal oxide particles, nonionic, anionic, cationic and betaine surfactants or polymers can be preferably used. These antistatic patrones are disclosed in
37, 1-312538. Particularly, the resistance at 25 ° C. and 25% RH is preferably 10 ¹² Ω or less. Usually, a plastic patrone is manufactured using a plastic into which carbon black, a pigment, or the like is kneaded in order to impart light shielding properties. The size of the patrone may be the same as the current 135 size, and it is effective to reduce the diameter of the current 135 size 25 mm cartridge to 22 mm or less in order to reduce the size of the camera.
The volume of a cartridge case, 30cm ³ or less, preferably 25
It is preferably set to not more than cm ³ . The weight of plastic used for patrone and patrone case is 5g ~
15 g is preferred.

Further, a patrone for rotating the spool and feeding the film may be used in the present invention. Further, a structure may be employed in which the leading end of the film is housed in the cartridge body, and the leading end of the film is sent out from the port of the cartridge by rotating the spool shaft in the film sending direction. These are disclosed in US Pat. Nos. 4,834,306 and 5,226,613. The photographic film used in the present invention may be a so-called raw film before development or a photographic film that has been subjected to development processing. Also, raw film and developed photographic film may be stored in the same new patrone,
A different patrone may be used.

The color photographic light-sensitive material of the present invention is also suitable as a negative film for an advanced photo system (hereinafter referred to as an AP system), and NEXIA A manufactured by Fuji Photo Film Co., Ltd. (hereinafter referred to as Fuji Film). NEXI
Films processed into the AP system format such as AF and NEXIA H (in order, ISO 200/100/400) and stored in a special cartridge can be mentioned. These APs
The cartridge film for a system is used by being loaded into a camera for an AP system such as an EPION series (EPION 300Z, etc.) manufactured by FUJIFILM Corporation. Further, the color photographic light-sensitive material of the present invention is also suitable for a film with a lens such as a super slim, which is a Fujicolor photograph run made by FUJIFILM.

The film photographed by the above is printed through the following steps in the minilab system. (1) Reception (exposed cartridge film received from customer) (2) Detach process (transfer film from cartridge to intermediate cartridge for development process) (3) Film development (4) Retouch process (developed negative (Return the film to the original cartridge.) (5) Print (continuous automatic printing of C / H / P 3 type prints and index prints on color paper (preferably SUPER FA8 made by FUJIFILM)) (6) Verification and shipment (The cartridge and index print are collated by ID number and shipped together with the print.) These systems include Fujifilm Minilab Champion Super FA-298 / FA-278 / FA-258 / FA-238 and Fujifilm Digital Lab System Frontier. preferable. FP922AL / FP562B / FP562B, AL / FP362B / FP362B, AL are examples of minilab champion film processors, and the recommended treatment chemical is Fujicolor Justit CN-1.
6L and CN-16Q. As a printer processor,
PP3008AR / PP3008A / PP1828AR / PP1828A / PP1258AR / PP1258A
/ PP728AR / PP728A, and the recommended treatment chemicals are Fujicolor Justit CP-47L and CP-40FAII. Frontier System, Scanner & Image Processor
SP-1000 and laser printer & paper processor
LP-1000P or laser printer LP-1000W is used. The detacher used in the detaching step and the rear toucher used in the rear attaching step are preferably DT200 / DT100 and AT200 / AT100 of Fujifilm, respectively.

The AP system can also be enjoyed by a photo joy system centered on the Fuji Film Aladdin 1000 digital image workstation. For example, you can directly load a developed AP system cartridge film into the Aladdin 1000, or transfer image information from negative film, positive film, and print to a 35mm film scanner FE.
The digital image data obtained by inputting using the -550 or PE-550 flat head scanner can be easily processed and edited. The data are stored in a digital color printer NC-550AL using a light fixing type thermal color printing system and a pictograph 3000 using a laser exposure thermal development transfer system.
Or as prints with existing lab equipment through a film recorder. The Aladdin 1000 can also transfer digital information directly to a floppy disk, Zip disk, or via a CD writer.
You can also output to CD-R.

On the other hand, at home, the developed AP system cartridge film is transferred to a Fujifilm photo player AP.
You can enjoy photos on TV just by loading it in -1,
By loading it onto a Fujifilm AS-1 photo scanner, image information can be continuously and rapidly captured on a personal computer. To enter a film, print, or three-dimensional object into a computer, use Fujifilm PhotoVision FV-10 / FV.
-5 is available. Furthermore, image information recorded on a floppy disk, Zip disk, CD-R, or hard disk can be variously processed and enjoyed on a personal computer using Fujifilm's application software Photo Factory. In order to output high-quality prints from a personal computer, a digital color printer NC-2 / NC-2D manufactured by Fujifilm of a light fixing type thermal color print system is suitable.

In order to store the developed AP system cartridge film, the Fuji Color Pocket Album AP-5 POP L, AP-1 POP L, AP-1 POP KG or the cartridge file 16 is preferable.

[0198]

EXAMPLES The present invention will be described in more detail with reference to the following Examples, but it should not be construed that the invention is limited thereto.

Example 1 On an undercoated cellulose triacetate film support,
Sample 101, which is a multilayer color photographic material composed of each layer having the following composition, was prepared. The amount coated amount (Composition of photosensitive layer) is represented in units of g / m ² of silver for silver halide and colloidal silver, also couplers, the amount for the additives and gelatin, expressed in units of g / m ^2, The sensitizing dyes are shown in terms of moles per mole of silver halide in the same layer. The symbols indicating the additives have the following meanings. However, when there is more than one utility, only one of them is listed as a representative.

UV; UV absorber; Solv; high boiling organic solvent; ExF; dye; ExS; sensitizing dye; ExC: cyan coupler, ExM; magenta coupler, ExY; yellow coupler, Cpd; Inhibiting layer) Black colloidal silver 0.15 Gelatin 1.61 UV-1 1.9 × 10 ^-2 UV-2 4.7 × 10 ^-2 UV-3 8.6 × 10 ^-2 ExF-3 5.0 × 10 ^-3 ExM-3 6.7 × 10 ^-2 Solv-1 0.16 Solv-2 0.10 Second layer (intermediate layer) Gelatin 0.65 Polyethyl acrylate latex 2.6 × 10 ^-1 ExC-7 7.5 × 10 ^-2 Third layer (low-sensitivity red-sensitive emulsion layer) Silver iodobromide emulsion A Silver coating amount 0.24 Silver iodobromide emulsion B Silver coating amount 0.55 Gelatin 1.75 ExS-16 ^{.9 × 10 -4 ExS-2 4.0} × ^{0 -4 ExS-5 6.7 × 10} -4 ExS-7 1.4 × 10 -5 ExC-1 3.0 × 10 -1 ExC-5 2.0 × 10 -1 ExC-9 2.2 × 10 ^-2 Cpd-4 5.3 × 10 ^-2 ExC-4 6.1 × 10 ^-2 Fourth layer (medium sensitivity red-sensitive emulsion layer) Silver iodobromide emulsion C Silver coating amount 0.30 Gelatin 0.40 ExS-1 3.5 × 10 ^-4 ExS-2 2.0 × 10 ^-4 ExS-5 3.4 × 10 ^-4 ExS-7 6.9 × 10 ^-6 ExC-1 1.3 × 10 ^-1 ExC-2 0.5 × 10 ^-2 ExC-4 4.6 × 10 ^-2 ExC-5 8.6 × 10 ^-2 ExC-6 1.1 × 10 ^-2 ExC-7 4.6 × 10 ^-2 Cpd-4 2.1 × 10 ^-2 Fifth layer (high-sensitivity red-sensitive emulsion layer) Silver iodobromide emulsion D Silver coating amount 0.63 Gelatin 0.68 ExS-1 3.2 × 10 ^-4 ExS-2 1.8 × 10 ^-4 ExS-5 3.1 ^{10 -4 ExS-7 4.8 × 10} -5 ExC-1 5.1 × 10 -2 ExC-3 0.2 × 10 -2 ExC-6 9.0 × 10 -3 ExC-4 2.0 × 10 ⁻² ExC-8 0.3 × 10 ⁻² ExC-9 1.0 × 10 ⁻² Cpd-4 2.1 × 10 ⁻³ Cpd-7 2.2 × 10 ⁻² Solv-1 0.08 Solv -2 0.04 6th layer (intermediate layer) Gelatin 0.62 Cpd-1 0.08 Polyethyl acrylate latex 4.1 × 10 ^-2 Solv-1 4.0 × 10 ^-2 7th layer (low sensitivity green Sensitive emulsion layer) Silver iodobromide Emulsion E Silver coated 0.35 Gelatin 0.49 ExS-8 5.7 × 10 ^-5 ExS-4 9.0 × 10 ^-4 ExS-5 1.8 × 10 ^-4 ExM-1 0.26 Cpd-7 3.3 × 10 -2 Solv-1 0.15 Solv-3 7.0 × 10 -3 eighth layer (middle sensitivity green-sensitive emulsion layer) Silver bromide emulsion F silver coverage 0.20 iodobromide emulsion E silver coverage 0.05 Gelatin ^{0.14 ExS-8 4.3 × 10 -5} ExS-4 6.8 × 10 -4 ExS-5 ^{1.3 × 10 -4 ExM-1 5.5} × 10 -2 ExM-7 1.5 × 10 -2 ExY-1 5.0 × 10 -3 Solv-1 3.3 × 10 -2 Solv-3 1.5 × 10 ⁻³ Ninth layer (high-sensitivity green-sensitive emulsion layer) Silver iodobromide emulsion G Silver coating amount 0.30 Gelatin 0.30 ExS-4 5.0 × 10 ⁻⁴ ExS-5 9.9 × 10 ^-5 ExS-8 3.2 × 10 ^-5 ExM-7 2.0 × 10 ^-2 ExM-6 0.4 × 10 ^-2 ExM-5 0.5 × 10 ^-2 ExM-1 5.5 × 10 ^-2 ExY-1 3.5 × 10 ^-2 ExC-1 6.0 × 10 ^-3 ExC-4 8.0 × 10 ^-3 Cpd-6 8.0 × 10 ^-3 Solv-1 0.12 Solv-2 0. 06 Solv-3 6.0 × 10 ^-3 Tenth layer (intermediate layer) Gelatin 0.39 UV-2 1.4 × 10 ^-2 UV-3 1.6 × 10 ^-2 UV-5 4.2 × 10 ^-2 Cpd-1 2.6 × 10 ^-2 Polyethyl acrylate latex 1.4 × 10 ^-2 Solv-1 2.8 × 10 ^-2 Eleventh layer (donor layer of multilayer effect on red-sensitive layer) Silver Emulsion H Silver coated amount 0.80 Silver iodobromide Emulsion I Silver coated 0.20 Gelatin 1.61 ExS-3 6.4 × 10 ^-4 ExM-2 2.4 × 10 ^-1 ExM-1 ^{0 × 10 -2 ExM-4 4.8} × 10 -2 ExM-7 1.7 × 10 -2 ExY-2 2.0 × 10 -2 Cpd-7 1.0 × 10 -2 Solv-1 0. 50 Solv-5 0.05 12th layer (yellow filter layer) yellow colloidal silver 7.0 × 10 ^-2 gelatin 0.61 Cpd-1 4. ^{× 10 -2 Cpd-2 7.9 ×} 10 -2 Cpd-5 1.0 × 10 -3 Solv-1 4.7 × 10 -2 13th layer (low sensitivity blue-sensitive emulsion layer) Silver iodobromide emulsion J Silver coated amount 0.70 Gelatin 2.8 ExS-9 8.8 × 10 ^-4 ExY-2 2.4 × 10 ^-1 ExY-3 1.10 ExY-4 0.10 ExC-9 6.3 × 10 ^-2 ExC-1 3.0 × 10 ^-2 ExC-10 8.4 × 10 ^-2 Cpd-7 2.9 × 10 ^-3 Solv-1 0.33 14th layer (high-sensitivity blue-sensitive emulsion layer) Silver iodobromide emulsion K Silver coated amount 0.06 Silver iodobromide emulsion L Silver coated amount 0.07 Silver iodobromide emulsion M Silver coated amount 0.12 Gelatin 0.35 ExS-6 4.4 × 10 ^-4 ExY-3 7.5 × 10 ^-2 ExY-6 1.0 × 10 ^-2 ExC-1 1.2 × 10 ^-3 ExC-10 1.3 × 10 ^-3 Solv-1 1.7 × 10 ^-1 No. 5 layers (first protective layer) fine silver iodobromide emulsion N silver coverage 0.06 Gelatin ^{0.51 UV-2 4.0 × 10 -2} UV-3 4.9 × 10 -2 UV-4 0. 04 UV-5 0.12 Cpd-3 0.10 ExF-4 2.1 × 10 ⁻³ ExF-5 6.3 × 10 ⁻³ Solv-4 2.0 × 10 ⁻² Polyethyl acrylate latex 9.0 × 10 ^-2 16th layer (second protective layer) fine silver iodobromide emulsion N silver coverage 0.18 gelatin 0.84 B-1 (diameter 2.0 .mu.m) 8.0 × 10 ^-2 B-2 ( 8.0 × 10 ^-2 B-3 3.5 × 10 ^-2 W-5 1.8 × 10 ^-2 H-1 0.18 In addition to the above samples, 1,2-benzisothiazolin-3-one (average 2
00 ppm), n-butyl-p-hydroxybenzoate (about 1,000 ppm), and 2-phenoxyethanol (about 10,000 ppm). Further, W-1 may be suitably added to each layer in order to improve the storability, processability, pressure resistance, fungicide / antibacterial properties, antistatic properties and coatability.
To W-6, B-1 to B-6, F-1 to F-17 and iron, lead, gold, platinum, iridium and rhodium salts.

[0201]

[Table 1] In Table 1, (1) Emulsions A to M were subjected to reduction sensitization during the preparation of grains using thiourea dioxide and thiosulfonic acid according to the examples of JP-A-2-191938.

(2) Emulsions A to M are described in JP-A-3-2374.
According to the example of No. 50, gold sensitization, sulfur sensitization and selenium sensitization were performed in the presence of the spectral sensitizing dye described in each photosensitive layer and sodium thiocyanate.

(3) The preparation of tabular grains is described in
According to the example of 58 426, low molecular weight gelatin is used.

(4) Dislocation lines as described in JP-A-3-237450 were observed in tabular grains and normal crystal grains having a grain structure using a high-pressure electron microscope.

(5) Emulsions A to M H. Carro
ll, Photographic Science an
d Engineering, 24, 265 (198
0) etc., the particles contain iridium inside.

[0206]

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[0207]

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[0219]

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[0218]

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[0219]

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[0220]

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[0221]

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[0222]

Embedded image To the sample 101, an emulsion of a yellow dye was added.
Samples 102 to 113 were prepared as shown in Table 2 according to the method of preparing Sample 101 except that ExY-2 of the layer was replaced with the compounds of the general formulas (I) and (II) of the present invention. When the yellow dye emulsion was added, the amount of gelatin applied to the layer was corrected so as to be the same as that of Sample 101.

The yellow dye emulsion of the above sample 101 was dissolved by heating the following solutions A and B, respectively, and after mixing the solutions A and B, the mixture was emulsified and dispersed by a household mixer.

[0224]

[0225]

[Table 2] The sample prepared in this manner was subjected to ISO 1007: 199
A 135-size magazine (cartridge) that was processed to 135 size (36 shots) in accordance with 5 (E) and was also prepared in accordance with ISO 1007: 1995 (E).
Stored in. It was loaded into a 35 mm compact camera "Cardia Mini Tiara", photographed with a Macbeth color checker, and subjected to the following development processing. (Processing method) Process Processing time Processing temperature Color development 3 minutes 15 seconds 38 ° C. Bleaching 3 minutes 00 seconds 38 ° C. Water washing 30 seconds 24 ° C. Fixing 3 minutes 00 seconds 38 ° C. water washing (1) 30 seconds 24 ° C. water washing ( 2) 30 seconds 24 ° C. Stability 30 seconds 38 ° C. Drying 4 minutes 20 seconds 55 ° C. Next, the composition of the processing solution is described. (Color developing solution) (Unit g) Diethylenetriaminepentaacetic acid 1.0 1-Hydroxyethylidene-1,1-diphosphonic acid 2.0 Sodium sulfite 4.0 Potassium carbonate 30.0 Potassium bromide 1.4 Potassium iodide 5 mg hydroxylamine sulfate 2.4 4- [N-ethyl-N- (β-hydroxyethyl) amino] -2-methylaniline sulfate 4.5 Add water and add 1.0 liter pH (potassium hydroxide and sulfuric acid) 10.05 (Bleaching solution) (unit g) Sodium ferric ethylenediaminetetraacetate trihydrate 100.0 Disodium ethylenediaminetetraacetate 10.0 3-Mercapto-1,2,4-triazole 0.0 03 Ammonium bromide 140.0 Ammonium nitrate 30.0 Ammonia water (27%) 6.5 ml Add water 1.0 liter pH (adjusted with aqueous ammonia and nitric acid) 6.0 (fixing solution) (unit g) Ethylenediaminetetraacetic acid disodium salt 0.5 ammonium sulfite 20.0 aqueous ammonium thiosulfate (700 g / liter) 295.0 Milliliter acetic acid (90%) 3.3 1.0 liter by adding water pH (adjusted with ammonia water and acetic acid) 6.7 (stabilized solution) (unit: g) p-nonylphenoxypolyglycidol (glycidol average polymerization degree 10) ) 0.2 ethylenediaminetetraacetic acid 0.05 1,2,4-triazole 1.3 1,4-bis (1,2,4-triazol-1-ylmethyl) piperazine 0.75 hydroxyacetic acid 0.02 hydroxyethylcellulose 0 .1 (Daicel Chemical HEC SP-2000) 1,2-benzisothiazoline Using printer A for adding 3-one 0.05 1.0 liter of water pH 8.5 the obtained treated samples were generated print sample 101A～113A.

D430 and D470 of the processed sample were obtained as follows. The sample exposed to white light (4800 ° K) is subjected to the above-described development treatment, and the hue at the point where the yellow density gives fog +1.0 is determined by HITACHI U-3500 S
Measured with a spectrophotometer, wavelength 430 nm, 470
It was determined by reading the absorbance at nm.

Next, print samples 101B to 113B were prepared in the same manner as the printer A using the printer B having a different detector in the blue region.

Printer A: FUJI AUTOMAT
IC COLOR PRINTERFAP-3500 Printer B: KODAK 3510 COLOR P
RINTER However, FUJI COLOR SUPER G ACE is used as a standard photographic material regardless of whether printer A or B is used.
Using 400, printer conditions were set such that the gray color of this standard photosensitive material was appropriate, and prints of samples 101 to 113 were created under the same conditions.

The density of the gray plate of the produced print was measured using a yellow filter, and the density difference between the case of using the printer A and the case of using the printer B was shown as a relative value to the standard photosensitive material. The closer this value is to 0, the closer the variation in color between different printers is to the standard photographic material, which is preferable.

The evaluation of the color image storability was performed by subjecting a raw sample to development processing after exposure to a wedge, storing it at 50 ° C. and 70% RH for 4 months, and determining the color image residual ratio at an initial density of 2.0. .

From Table 2, it can be seen that the light-sensitive material of the present invention having a yellow dye so that D430 / D470 is increased is preferable because the color variation between different types of printers is small. Further, a light-sensitive material having a coupler represented by the formula (I) or (II) is more preferable because it has improved color image storability.

(Example 2) 1) Support The support used in this example was prepared by the following method.

100 parts by weight of polyethylene-2,6-naphthalate polymer and Tinuvin as an ultraviolet absorber
P. 326 (manufactured by Ciba-Geigy) and 2 parts by weight, and then melted at 300 ° C.
It is extruded from the mold die, stretched 3.3 times at 140 ° C., then stretched 3.3 times at 130 ° C., and heat-set at 250 ° C. for 6 seconds to obtain a PEN film having a thickness of 90 μm. Obtained. The PEN film has a blue dye, a magenta dye and a yellow dye (Publication Technical Report: I-1, I-4, I-6, I-6 described in Kokai No. 94-6023).
-24, I-26, I-27, II-5) were added in an appropriate amount. Further, the support was wound around a stainless steel winding core having a diameter of 20 cm to give a heat history of 110 ° C. and 48 hours, thereby providing a support that was not easily curled.

2) Coating of Undercoat Layer The support was subjected to a corona discharge treatment, a UV discharge treatment, and a glow discharge treatment on both surfaces, and then gelatin 0.1 g / m ² and sodium α- Suruhoji-2-ethylhexyl succinate 0.01 g / m ^2, salicylic acid 0.04g / m ^2, p- chlorophenol 0.2 g /
m ² , (CH ₂ ＣＨCHSO ₂ CH ₂ CH ₂ NHCO) ₂
CH ^₂ 0.012g / m _2, polyamide - epichlorohydrin polycondensate was coated an undercoat solution ^{0.02g / m 2 (10cc / m} 2, a bar coater used), an undercoat layer hotter side at the time of stretching Was. Drying was performed at 115 ° C. for 6 minutes (all rollers and transport devices in the drying zone were at 115 ° C.).

3) Coating of Back Layer An antistatic layer having the following composition, a magnetic recording layer, and a sliding layer were formed as a back layer on one surface of the support after the undercoating. 3-1) Coating of antistatic layer Tin oxide-antimony oxide composite having an average particle diameter of 0.005 μm has a specific resistance of 5 Ω · cm, a dispersion of fine particle powder (secondary aggregated particle diameter of about 0.08 μm). .2g / m ^2, gelatin _{^{0.05g / m 2 (CH 2 =}} CHSO 2 CH 2 CH
₂ NHCO) ₂ CH ₂ 0.02 g / m ² , poly (degree of polymerization 10) oxyethylene-p-nonylphenol 0.00
Coated with 5 g / m ² and resorcin.

3-2) Coating of Magnetic Recording Layer Cobalt-γ-iron oxide coated with 3-poly (degree of polymerization 15) oxyethylene-propyloxytrimethoxysilane (15% by weight) (specific surface area 43 m ²⁾ / G, major axis 0.14 μm, single axis 0.03 μm, saturation magnetization 89 emu
/ G, Fe ^{+ 2} / Fe ⁺³ = 6/94, surface treated with silicon oxide aluminum oxide at 2% by weight of iron oxide) 0.06
g / m ² of diacetyl cellulose 1.2 g / m ² (dispersion of iron oxide was carried out by an open kneader and a sand mill), and C ₂ H ₅ C (CH ₂ OCONH-C
0.3 g / m ² of ₆ H ₃ (CH ₃ ) NCO) ₃ was applied with a bar coater using acetone, methyl ethyl ketone and cyclohexanone as a solvent to obtain a 1.2 μm-thick magnetic recording layer. Silica particles (0.3μ
m) and 3-poly (degree of polymerization 15) oxyethylene-propyloxytrimethoxysilane (15% by weight) treated and coated with aluminum oxide (0.15 μm) as an abrasive to be 10 mg / m ^2. did. 115 for drying
C., 6 minutes (115 ° C. for all rollers and conveyors in the drying zone). X- write saturation magnetization moment of the magnetic recording layer of the D color density increment of about 0.1 of ^B or magnetic recording layer, in (blue filter) is 4.2 emu / g,
The coercive force was 7.3 × 10 ⁴ A / m, and the squareness ratio was 65%.

3-3) Preparation of Sliding Layer Diacetylcellulose (25 mg / m ² ), C ₆ H ₁₃ C
H (OH) C ₁₀ H ₂₀ COOC ₄₀ H ₈₁ (Compound a, 6 mg
/ M ² ) / C ₅₀ H ₁₀₁ O (CH ₂ CH ₂ O) ₁₆ H (compound b, 9 mg / m ² ) mixture was applied. Note that this mixture is composed of xylene / propylene monomethyl ether (1
/ 1) was melted at 105 ° C. and poured into and dispersed in propylene monomethyl ether (10-fold amount) at room temperature to prepare
The dispersion was added in acetone (average particle size: 0.01 μm) and then added. Silica particles (0.3μm) as matting agent
And 3-poli (degree of polymerization 15) oxyethylene-propyloxytrimethoxysilane (aluminum oxide (0.15 μm) coated with 15% by weight) of 15 mg /
m ² . Drying was performed at 115 ° C. for 6 minutes (all rollers and transport devices in the drying zone were 115 ° C.).
° C). The sliding layer has a dynamic friction coefficient of 0.06 (stainless hard ball of 5 mmφ, load of 100 g, speed of 6 cm / min), a static friction coefficient of 0.07 (clip method), and a kinetic friction coefficient of 0.12 between an emulsion surface and a sliding layer described later. Excellent characteristics.

4) Coating of Photosensitive Layer Next, on the opposite side of the back layer obtained above, the same photosensitive layer as that of the sample 101 of Example 1 was applied by multi-layer coating.
7: 1995 (E), processed into 135 size (24 shots), which was also ISO 1007: 1995
It was stored in a 135-size magazine (cartridge) prepared according to (E). This is designated as Sample 201.

A sample prepared by introducing a yellow dye and a coupler of the formula (I) or (II) into Sample 201
Samples 202 to 2 were prepared according to
13. When evaluation was carried out in the same manner as in Example 1 using these, the light-sensitive material of the present invention having a yellow dye showed favorable performance in that there was little variation between different types of printers as in the results shown in Example 1, and Formula (I) or (I
The light-sensitive material having the coupler (I) had a high residual ratio of a color image, and showed more preferable results.

(Example 3) Samples 201 to 21 of Example 2
3 and 1 according to ISO732: 1991 (E).
Processed to 20 size, provided light-shielding paper,
O732: Samples 301 to 313 were prepared in the same manner as Samples 201 to 213, except that they were wound around a spool prepared according to 1991 (E). When these sample films were loaded into a medium-sized camera “Fuji GW690III Professional” and the same evaluation as in Example 1 was performed,
The same results as in Example 1 were obtained.

[0241]

According to the present invention, it is possible to provide a silver halide color photographic light-sensitive material which has a small change in tint and can be stably finished even when a different kind of printer is used.

Claims (2)

[Claims] In a silver halide color photographic material having at least one blue-sensitive, green-sensitive and red-sensitive silver halide emulsion layer on a support, a non-bleachable yellow dye is added at an intermediate exposure dose. A silver halide color photographic light-sensitive material, characterized in that the light-sensitive material contains a light-absorbing ratio D430 / D470 after color development processing so as to increase as compared with the case where no yellow dye is contained. D430: Absorbance at 430 nm wavelength D470: Absorbance at 470 nm wavelength 2. The silver halide color photographic light-sensitive material according to claim 1, which contains a coupler represented by the following general formula (I) and / or a coupler represented by the following general formula (II). material. General formula (I) General formula (II) (Wherein, X ¹ and X ² each represent an alkyl group, an aryl group or a heterocyclic group, X ³ represents an organic residue forming a nitrogen-containing heterocyclic group with> N—, and Y represents an aryl group or a heterocyclic group. And Z represents a hydrogen atom or a group which is released when the coupler represented by the formula is reacted with an oxidized developing agent.)