JPH10201694A - Method and device for washing and sterilizing dishes - Google Patents

Method and device for washing and sterilizing dishes

Info

Publication number
JPH10201694A
JPH10201694A JP9022197A JP2219797A JPH10201694A JP H10201694 A JPH10201694 A JP H10201694A JP 9022197 A JP9022197 A JP 9022197A JP 2219797 A JP2219797 A JP 2219797A JP H10201694 A JPH10201694 A JP H10201694A
Authority
JP
Japan
Prior art keywords
water
washing
diaphragm
sterilizing
pipe
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9022197A
Other languages
Japanese (ja)
Inventor
Yoshiya Okazaki
良弥 岡崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
OMUKO KK
TANIKOO SENJO SYST KK
Original Assignee
OMUKO KK
TANIKOO SENJO SYST KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by OMUKO KK, TANIKOO SENJO SYST KK filed Critical OMUKO KK
Priority to JP9022197A priority Critical patent/JPH10201694A/en
Publication of JPH10201694A publication Critical patent/JPH10201694A/en
Pending legal-status Critical Current

Links

Landscapes

  • Washing And Drying Of Tableware (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

PROBLEM TO BE SOLVED: To efficiently wash and sterilize dishes by electrolyzing a chloride salt aqueous solution with a diaphragm electrolytic cell to generate strong acidic water and strong alkaline water having specified pH values, performing the washing with the strong alkaline water, and then performing the sterilization with a hypochlorous acid sterilizing water obtained by diluting the strong acidic water. SOLUTION: An aqueous solution having a relatively high concentration which contains a chloride salt such as sodium chloride, potassium chloride or the like is electrolyzed in a diaphragm electrolytic cell to generate a strongly alkaline water of pH 10.5 or more and a strongly acidic water of pH1-3.5. The strongly alkaline water is diluted with tap water and regulated to a strongly alkaline water of pH10.5-13.5, and the strongly acidic water is diluted with tap water and regulated to a hypochlorous acid sterilizing water having pH4-8 which has high sterilizing force but is nontoxic to human body. The thus regulated sternly alkaline water of pH10.5-13.5 is sprayed to dishes, preferably, in shower form to remove oil and wash the dishes, and the dishes are then sterilized with the hypochlorous acid sterilizing water of pH4-8, whereby washing and sterilization of the dishes can be efficiently performed.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は食器類の洗浄・殺菌
方法及び装置に関し、特に、塩化ナトリウムなどの塩化
物塩の水溶液を電解して得た強アルカリ水と強酸性水を
使用して、強アルカリ水による食器類の油落し洗浄と次
亜塩素酸殺菌水による殺菌を行うようにした食器の洗浄
方法及び装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method and an apparatus for cleaning and sterilizing tableware, and more particularly, to a method and a method using strong alkaline water and strong acid water obtained by electrolyzing an aqueous solution of a chloride salt such as sodium chloride. The present invention relates to a dishwashing method and apparatus for performing degrease cleaning of tableware with strong alkaline water and sterilization with hypochlorous acid sterilized water.

【0002】[0002]

【従来の技術】塩化ナトリウム、塩化カリウムなどの塩
化物塩を含む水を、例えば有隔膜電解槽でアルカリ水と
酸性水に電解するとpHの高い強アルカリ水が得られ、
このアルカリ水は食器の油落しなどの洗浄に適してい
る。他方、上記の塩化物塩を含む水を無隔膜電解槽で電
解した水は次亜塩素酸を多く含み、殺菌水としてきわめ
て有効である。従って、上記のアルカリ水で食器の一次
洗浄を行うとともに、次亜塩素酸殺菌水で二次洗浄を行
うと効率の良い食器の洗浄・殺菌を行うことができる。
2. Description of the Related Art When water containing chloride salts such as sodium chloride and potassium chloride is electrolyzed into alkaline water and acidic water in, for example, a diaphragm electrolyzer, a strong alkaline water having a high pH is obtained.
This alkaline water is suitable for washing grease on tableware. On the other hand, water obtained by electrolyzing the above-mentioned water containing a chloride salt in a diaphragm-free electrolytic cell contains a large amount of hypochlorous acid and is extremely effective as sterilizing water. Therefore, when the primary cleaning of the tableware is performed with the above-described alkaline water and the secondary cleaning is performed with the sterilized water of hypochlorous acid, efficient cleaning and sterilization of the tableware can be performed.

【0003】[0003]

【発明が解決しようする課題】ところが、強アルカリ水
と次亜塩素酸水をそれぞれ独立の電解装置を用いて別個
に生成するとコストが高くなり、装置も大型になる。し
かも電解生成水のみで所望のpHの強アルカリ水と次亜
塩素酸水を調整しようとすると、pHの調整が難しく、
電解槽の電解効率が比較的に劣る。また、有隔膜電解槽
は強アルカリ水のみを使用し、酸性水は捨ててしまうた
め水が無駄になっていた。
However, if strong alkaline water and hypochlorous acid water are separately produced using independent electrolytic devices, the cost increases and the device becomes large. Moreover, if it is attempted to adjust the strong alkaline water and hypochlorous acid water at the desired pH with only the electrolyzed water, it is difficult to adjust the pH,
The electrolysis efficiency of the electrolyzer is relatively poor. Further, the diaphragm electrolytic cell uses only strong alkaline water, and the acidic water is discarded, so that the water is wasted.

【0004】従って、本発明の第1の目的は食器類を効
率良く洗浄・殺菌する方法を提供することにあり、特に
pH調整が容易で電解効率が良く、しかも無駄水が少な
い食器類の洗浄・殺菌方法を提供することにある。
Accordingly, a first object of the present invention is to provide a method for efficiently cleaning and disinfecting tableware, and in particular, for cleaning tableware which is easy to adjust pH, has good electrolysis efficiency, and has little waste water. -To provide a sterilization method.

【0005】本発明の第2の目的は上記の食器洗浄・殺
菌方法を実施するための装置を提供することにある。
[0005] A second object of the present invention is to provide an apparatus for performing the above-described dishwashing / sterilizing method.

【0006】上記第1の目的を達成するために、本発明
の請求項1による食器類の洗浄・殺菌方法は、塩化物塩
水溶液を有隔膜電解槽で電解してpH1〜3.5の強酸
性水と強アルカリ水とを生成し、前記強アルカリ水を水
で希釈してpH10.5〜13.5の強アルカリ水に調
整するとともに、前記強酸性水を水で希釈してpH4〜
8の次亜塩素酸殺菌水に調整し、前記pH10.5〜1
3.5の強アルカリ水で食器類を洗浄した後、該食器類
を前記次亜塩素酸殺菌水で殺菌することを特徴とする。
In order to achieve the first object, a method for cleaning and sterilizing tableware according to the first aspect of the present invention is to provide a method for electrolyzing a chloride salt aqueous solution in a diaphragm electrolyzer to obtain a strong acid having a pH of 1 to 3.5. A strong water and a strong alkaline water are produced, and the strong alkaline water is diluted with water to adjust to a strong alkaline water having a pH of 10.5 to 13.5, and the strong acidic water is diluted with water to a pH of 4 to
8 adjusted to hypochlorous acid sterilized water,
After washing the dishes with 3.5 alkaline water, the dishes are sterilized with the hypochlorous acid sterilizing water.

【0007】また、上記第1の目的を達成するために、
本発明の請求項2による食器類洗浄・殺菌方法は、塩化
物塩水溶液を有隔膜電解槽で電解してpH1〜3.5の
強酸性水と強アルカリ水を生成し、前記強アルカリ水を
水で希釈してpH10.5〜13.5の強アルカリ水に
調整するとともに、他方、塩化物塩水溶液を無隔膜電解
槽で電解した電解処理水又はその希釈水溶液を前記有隔
膜電解により生成した強酸性水に混合してpH4〜8の
次亜塩素酸殺菌水に調整し、前記pH10.5〜13.
5の強アルカリ水で食器類を洗浄した後、該食器類を前
記次亜塩素酸殺菌水で殺菌することを特徴とする。
In order to achieve the first object,
In the dishwashing / sterilizing method according to claim 2 of the present invention, a chloride salt aqueous solution is electrolyzed in a diaphragm electrolyzer to generate strongly acidic water and strongly alkaline water having a pH of 1 to 3.5, and the strong alkaline water is produced. It was diluted with water to adjust to a strong alkaline water having a pH of 10.5 to 13.5, and on the other hand, electrolytically treated water obtained by electrolyzing a chloride salt aqueous solution in a non-diaphragm electrolytic cell or a diluted aqueous solution thereof was produced by the above-mentioned diaphragm electrolysis. Mix with strongly acidic water to adjust to hypochlorite sterilized water having a pH of 4 to 8, and adjust the pH to 10.5 to 13.
After washing the dishes with strong alkaline water of No. 5, the dishes are sterilized with the hypochlorous acid sterilizing water.

【0008】さらに、上記第1の目的を達成するため
に、本発明の請求項3による食器類洗浄・殺菌方法は、
塩化物塩水溶液を有隔膜電解槽で電解してpH10.5
〜13.5の強アルカリ水とpH1〜3.5の強酸性水
に調整するとともに、前記pH1〜3.5の強酸性水又
は前記pH1〜3.5の強酸性水と塩化物塩水溶液の混
合水を無隔膜電解槽で電解してpH4〜8の次亜塩素酸
殺菌水に調整し、前記pH10.5〜13.5の強アル
カリ水で食器類を洗浄した後、該食器類を前記次亜塩素
酸殺菌水で殺菌することを特徴とする
Further, in order to achieve the first object, a dishwashing / sterilizing method according to claim 3 of the present invention comprises:
An aqueous chloride salt solution is electrolyzed in a diaphragm electrolyzer to adjust the pH to 10.5.
The pH is adjusted to 13.5 to 13.5 and the pH is 1 to 3.5, and the pH is 1 to 3.5 or the pH is 1 to 3.5. The mixed water is electrolyzed in a non-diaphragm electrolytic cell to adjust to hypochlorite sterilized water having a pH of 4 to 8, and the dishes are washed with strong alkaline water having a pH of 10.5 to 13.5. Disinfected with hypochlorous acid sterilized water

【0009】いずれの場合も、さらに、有隔膜電解槽で
電解したpH1〜3.5の強酸性水の一部を、前記食器
洗浄に供した強アルカリ水の中和及び/又は強アルカリ
水洗浄により食器に付着したカルシウム及び渋の溶解除
去に使用するようにしてもよい。
In each case, a part of the strongly acidic water having a pH of 1 to 3.5 electrolyzed in the diaphragm electrolyzer is further neutralized and / or washed with the strong alkaline water used for washing the dishes. May be used for dissolving and removing calcium and astringent attached to tableware.

【0010】上記第2の目的を達成するために、本発明
の請求項5による食器類洗浄・殺菌装置は、pH10.
5〜13.5の強アルカリ水とpH4〜8の次亜塩素酸
殺菌水を同時に生成する洗浄水調整装置と、この洗浄水
生成装置で生成した前記強アルカリ水と次亜塩素酸水を
各別に給水する洗浄水供給管路と、各々の洗浄水供給管
路に通ずるノズルを備えた食器洗浄槽と、を具備し、前
記洗浄水調整装置が、電解隔膜を介して陰極室と陽極室
に仕切った有隔膜電解槽の一側に塩化物塩水溶液の給水
管回路を有するとともに、他側に陰極室側排出管と陽極
室側排出管を有し、給水管回路から供給される塩化物塩
水溶液を電解して陰極室側排出管から強アルカリ水を排
出し、陽極室側排出管から次亜塩素酸と塩素ガスを含む
強酸性水を排出する有隔膜電解整水装置と;陰極室側排
出管の強アルカリ水に原水を供給して希釈する希釈水給
水管と;陽極室側排出管に原水を供給して希釈する希釈
水供給管と;を具備することを特徴とする。
[0010] In order to achieve the second object, a dishwashing and sterilizing apparatus according to claim 5 of the present invention has a pH of 10.
A washing water adjusting device for simultaneously producing a strong alkaline water of 5 to 13.5 and a hypochlorous acid sterilizing water having a pH of 4 to 8, and the strong alkaline water and the hypochlorous acid water generated by the washing water generating device; A washing water supply pipe for separately supplying water, and a dishwashing tank provided with a nozzle communicating with each washing water supply pipe, and the washing water adjusting device is provided with a cathode chamber and an anode chamber via an electrolytic diaphragm. One side of the partitioned electrolytic cell has a water supply pipe circuit of a chloride salt aqueous solution, and the other side has a cathode chamber side discharge pipe and an anode chamber side discharge pipe, and the chloride salt supplied from the water supply pipe circuit. Electrolyzed aqueous solution to discharge strongly alkaline water from the cathode chamber side discharge pipe, and discharge strong acid water containing hypochlorous acid and chlorine gas from the anode chamber side discharge pipe; A dilution water supply pipe for supplying and diluting raw water to the strongly alkaline water of the discharge pipe; and an anode chamber side Characterized by comprising a; and diluting water supply pipe for dilution by supplying raw water to the exit pipe.

【0011】また、上記第2の目的を達成するために、
本発明の請求項6の食器類洗浄殺菌装置は、pH10.
5〜13.5の強アルカリ水とpH4〜8の次亜塩素酸
殺菌水を同時に生成する洗浄水調整装置と、この洗浄水
調整装置で生成した前記強アルカリ水と次亜塩素酸水を
各別に給水する洗浄水供給管路と、各々の洗浄水供給管
路に通ずるノズルを備えた食器洗浄槽を具備し、前記洗
浄水調整装置が、電解隔膜を介して陰極室と陽極室に仕
切った有隔膜電解槽の一側に塩化物塩水溶液の給水管回
路を有するとともに、他側に陰極室側排出管と陽極室側
排出管を有し、給水管回路から供給される塩化物塩水溶
液を電解して陰極室側排出管から強アルカリ水を排出
し、陽極室側排出管から次亜塩素酸と塩素ガスを含む強
酸性水を排出する有隔膜電解装置と;陰極室側排出管の
強アルカリ水に原水を供給して希釈する希釈水給水管
と;無隔膜電解槽の一側に塩化物塩水溶液の給水管を有
し、この給水管から供給される塩化物塩水溶液を電解し
て排出管から排水する無隔膜電解整水装置と;前記有隔
膜電解整水装置の陽極室側排水回路から前記無隔膜電解
整水装置の水回路に接続され、有隔膜電解槽から生成さ
れる強酸性水の一部を、無隔膜電解整水装置の排水回路
又は給水回路に供給してpH及び次亜塩素酸濃度を調整
するpH・濃度調整管路とを具備することを特徴とす
る。
In order to achieve the second object,
The dishwashing and sterilizing apparatus according to claim 6 of the present invention has a pH of 10.
A washing water adjusting device for simultaneously producing a strong alkaline water of 5 to 13.5 and a hypochlorous acid sterilizing water of pH 4 to 8, and the strong alkaline water and the hypochlorous acid water generated by the washing water adjusting device are each A washing water supply pipe for separately supplying water and a dishwashing tank provided with a nozzle communicating with each washing water supply pipe were provided, and the washing water adjusting device was partitioned into a cathode chamber and an anode chamber via an electrolytic diaphragm. One side of the diaphragm electrolyzer has a water supply pipe circuit of a chloride salt aqueous solution, and the other side has a cathode chamber side discharge pipe and an anode chamber side discharge pipe, and the chloride salt aqueous solution supplied from the water supply pipe circuit is supplied with water. Electrolyzed to discharge strongly alkaline water from the cathode chamber side discharge pipe, and to discharge strongly acidic water containing hypochlorous acid and chlorine gas from the anode chamber side discharge pipe; A dilution water supply pipe for supplying and diluting raw water to alkaline water; And a non-diaphragm electrolysis water conditioning apparatus for electrolyzing a chloride salt aqueous solution supplied from the water supply pipe and draining it from a discharge pipe; and an anode chamber of the diaphragm electrolysis water conditioning apparatus A part of the strong acid water generated from the diaphragm electrolyzer is connected to the water circuit of the non-diaphragm electrolysis water conditioning device from the side drainage circuit and supplied to a drainage circuit or a water supply circuit of the non-diaphragm electrolysis water conditioning device. a pH / concentration adjusting conduit for adjusting the pH and the concentration of hypochlorous acid.

【0012】上記第2の目的を達成するために、本発明
の請求項7の食器類洗浄殺菌装置は、pH10.5〜1
3.5の強アルカリ水とpH4〜8の次亜塩素酸殺菌水
を同時に生成する洗浄水調整装置と、この洗浄水調整装
置で生成した前記強アルカリ水と次亜塩素酸水を各別に
給水する洗浄水供給管路と、各々の洗浄水供給管路に通
ずるノズルを備えた食器洗浄槽を具備し、前記洗浄水調
整装置が、電解隔膜を介して陰極室と陽極室に仕切った
有隔膜電解槽の一側に塩化物塩水溶液の給水管回路を有
するとともに、他側に陰極室側排出管と陽極室側排出管
を有し、給水管回路から供給される塩化物塩水溶液を電
解して陰極室側排出管から強アルカリ水を排出し、陽極
室側排出管から次亜塩素酸と塩素ガスを含む強酸性水を
排出する有隔膜電解整水装置と;この有隔膜電解整水装
置で調整した強酸性水又はこの強酸性水と塩化物塩水溶
液の混合水を電解して次亜塩素酸殺菌水を生成する無隔
膜電解整水装置と;を具備することを特徴とする食器の
洗浄・殺菌装置
In order to achieve the second object, the apparatus for cleaning and sterilizing dishes according to claim 7 of the present invention has a pH of 10.5-1.
A washing water conditioner for simultaneously producing 3.5 strongly alkaline water and a hypochlorite disinfecting water having a pH of 4 to 8; and separately supplying the strong alkaline water and hypochlorous acid solution produced by the washing water conditioner. A washing water supply pipe, and a dishwashing tank provided with a nozzle communicating with each of the washing water supply pipes, wherein the washing water adjusting device separates a cathode chamber and an anode chamber through an electrolytic membrane. One side of the electrolytic cell has a water supply pipe circuit for a chloride salt aqueous solution, and the other side has a cathode chamber side discharge pipe and an anode chamber side discharge pipe to electrolyze the chloride salt aqueous solution supplied from the water supply pipe circuit. A diaphragm electrolyzer for discharging strongly alkaline water from a discharge pipe on the cathode chamber side and discharging strongly acidic water containing hypochlorous acid and chlorine gas from a discharge pipe on the anode chamber side; Electrolyte the strongly acidic water prepared in Step 2 or a mixture of this strongly acidic water and the aqueous solution of chloride salt. Cleaning and sterilizing apparatus for dishes, characterized by comprising; a diaphragm-free electrolytic water conditioner apparatus for generating hypochlorous acid sterilizing water Te

【0013】無隔膜電解整水装置を併用する場合は、さ
らに、無隔膜電解槽の排水管に希釈水給水管を接続して
もよい。
When a non-diaphragm electrolysis water conditioning apparatus is used together, a diluting water supply pipe may be further connected to a drain pipe of the non-diaphragm electrolysis tank.

【0014】いずれの場合も、さらに、前記洗浄水調整
装置は、有隔膜電解槽の陽極室側排出管から分岐させた
強酸性水分岐排水管を有するとともに、この分岐排水管
と前記食器洗浄槽間に強酸性水供給管路を設け、有隔膜
電解槽の陽極室側排出管の強酸性水の一部が前記食器洗
浄槽に給水されるようにしてもよい。
In any case, the washing water adjusting device further includes a strong acid water branch drain pipe branched from the anode chamber side discharge pipe of the diaphragm electrolyzer, and the branch drain pipe and the dishwashing tank. A strongly acidic water supply pipe may be provided between the two, and a part of the strongly acidic water in the anode chamber side discharge pipe of the diaphragm electrolyzer may be supplied to the dishwashing tank.

【0015】[0015]

【発明の実施の形態】次に、本発明の実施の形態を説明
する。本発明による食器類の洗浄・殺菌方法の第1の形
態は、塩化ナトリウム、塩化カリウムなどの塩化物塩を
含む比較的高濃度の水溶液を有隔膜電解槽で電解し、p
H10.5以上の強アルカリ水とpH1〜3.5の強酸
性水を生成する。次いで、前記有隔膜電解により生成し
た強アルカリ水を水道水などの原水で希釈してpH1
0.5〜13.5の強アルカリ水に調整するとともに、
前記有隔膜電解により生成したpH1〜3.5の強酸性
水を水道水などの原水で希釈してpH4〜8の次亜塩素
酸殺菌水に調整する。ここで、「比較的高濃度」の塩化
物塩水溶液とは、電解処理のみで目的の洗浄用強アルカ
リ水を生成するときの塩化物水溶液よりも高濃度である
ことを意味している。このように、比較的高濃度の塩化
物塩水溶液を電気分解するため、電気電導率が高く、電
解効率が良い。
Next, an embodiment of the present invention will be described. In a first embodiment of the method for cleaning and sterilizing tableware according to the present invention, a relatively high concentration aqueous solution containing a chloride salt such as sodium chloride or potassium chloride is electrolyzed in a diaphragm electrolyzer.
Produces a strong alkaline water of H10.5 or more and a strongly acidic water of pH 1 to 3.5. Next, the strong alkaline water produced by the above-mentioned diaphragm electrolysis is diluted with raw water such as tap water to adjust the pH to 1
While adjusting to a strong alkaline water of 0.5 to 13.5,
The strongly acidic water having a pH of 1 to 3.5 generated by the diaphragm electrolysis is diluted with raw water such as tap water to adjust to a hypochlorite sterilized water having a pH of 4 to 8. Here, the “relatively high concentration” of the chloride salt aqueous solution means that the concentration is higher than that of the chloride aqueous solution when the intended strong alkaline water for cleaning is generated only by the electrolytic treatment. As described above, since the relatively high concentration aqueous chloride salt solution is electrolyzed, the electric conductivity is high and the electrolysis efficiency is good.

【0016】pH10.5〜13.5、好ましくは、p
H12以上の強アルカリ水は食器等の油落し洗浄にきわ
めて有効であるが、塩化物塩水溶液を有隔膜電解槽で電
解してpH10.5〜13.5あるいはそれ以上の強ア
ルカリ水を得ようとすると有隔膜電解槽の陽極室から生
成される強酸性水はpH1〜3.5になり、このpHの
強酸性水は塩素ガスを含み有害である。そこで、本発明
による食器類の洗浄・殺菌方法の上記第1の形態は、上
記pH1〜3.5の強酸性水を原水で希釈することによ
り、殺菌力が強く、人体に無害なpH4〜8の次亜塩素
酸水に調整するものである。
PH 10.5-13.5, preferably p
Strong alkaline water of H12 or more is extremely effective for cleaning grease from tableware, etc., but electrolyze a chloride salt aqueous solution in a diaphragm electrolyzer to obtain strong alkaline water having a pH of 10.5 to 13.5 or more. Then, the strongly acidic water generated from the anode compartment of the diaphragm electrolyzer has a pH of 1 to 3.5, and the strongly acidic water at this pH contains chlorine gas and is harmful. Therefore, the first embodiment of the method for washing and sterilizing tableware according to the present invention is characterized in that strong acidic water having a pH of 4 to 8 which is strong and has no harm to the human body is obtained by diluting the strongly acidic water having a pH of 1 to 3.5 with raw water. Is adjusted to a hypochlorous acid aqueous solution.

【0017】このようにして調整したpH10.5〜1
3.5の強アルカリ水を食器類に、好ましくは、シャワ
ー状に吹き付けて食器類の油落し洗浄を行った後、前記
pH4〜8の次亜塩素酸殺菌水で前記食器類の殺菌を行
うことで効率の良い食器類の洗浄・殺菌が行われる。
The pH adjusted in this manner is 10.5-1.
After 3.5 g of strong alkaline water is sprayed on the dishes, preferably in the form of a shower, the dishes are drained and washed, and then the dishes are sterilized with the hypochlorous acid sterilized water having a pH of 4 to 8. As a result, efficient washing and sterilization of tableware is performed.

【0018】本発明による食器洗浄・殺菌方法の第2の
形態は、前記と同様に塩化物塩水溶液を有隔膜電解槽で
pH10.5以上の強アルカリ水とpH1〜3.5の強
酸性水を生成するとともに、この強アルカリ水を水道水
などの水で希釈してpH10.5〜13.5の強アルカ
リ水に調整し、この強アルカリ水で食器類の油落し洗浄
を行う。他方、塩化ナトリウム、塩化カリウムなどの塩
化物塩水溶液を無隔膜電解し、得られた電解処理水又は
この電解処理水に原水を混合希釈した水を、前記有隔膜
電解によって生成した陽極室側のpH1〜3.5の強酸
性水に混合してpH4〜8の次亜塩素酸殺菌水に調整
し、この次亜塩素酸殺菌水で食器の殺菌を行う。すなわ
ち、本発明による洗浄・殺菌方法の第2の形態は、塩化
物塩水溶液を無隔膜電解して得たpH値の高い電解処理
水を前記pH1〜3.5の強酸性水に混合してpH4〜
8の次亜塩素酸水に調整するものである。
A second embodiment of the dishwashing / sterilizing method according to the present invention is the same as described above, except that a chloride salt aqueous solution is treated in a diaphragm electrolyzer with strongly alkaline water having a pH of 10.5 or more and strongly acidic water having a pH of 1 to 3.5. And diluting the strong alkaline water with water such as tap water to adjust the pH to a strong alkaline water having a pH of 10.5 to 13.5, and washing the dishes with the strong alkaline water. On the other hand, a chloride salt aqueous solution such as sodium chloride and potassium chloride is subjected to diaphragm-free electrolysis, and the obtained electrolyzed water or water obtained by mixing and diluting raw water with the electrolyzed water is used for the anode chamber side generated by the above-mentioned diaphragm electrolysis. It is mixed with strongly acidic water of pH 1 to 3.5 to adjust to hypochlorite sterilized water of pH 4 to 8, and the tableware is sterilized with the hypochlorous acid sterilized water. That is, the second embodiment of the cleaning / sterilizing method according to the present invention is to mix electrolytically treated water having a high pH value obtained by subjecting a chloride salt aqueous solution to non-diaphragm electrolysis with the strongly acidic water having a pH of 1 to 3.5. pH 4 ~
The hypochlorous acid water of No. 8 is adjusted.

【0019】本発明による食器洗浄・殺菌方法の第3の
形態は、塩化物塩水溶液を有隔膜電解槽でpH10.5
〜13.5の強アルカリ水とpH1〜3.5の強酸性水
に電解し、水で希釈しないpH10.5〜13.5の強
アルカリ水で食器類の油落し洗浄を行う。他方、pH4
〜8の次亜塩素酸殺菌水は、前記有隔膜電解によって生
成した強酸性水又は、該強酸性水と塩化ナトリウムなど
の塩化物塩水溶液の混合水を無隔膜電解して調整し、食
器の殺菌を行うものである。
A third embodiment of the dishwashing / sterilizing method according to the present invention is a method of washing a chloride salt aqueous solution with a pH of 10.5 in a diaphragm electrolyzer.
Electrolyze strong alkaline water of 1313.5 and strongly acidic water of pH 1-3.5, and wash dishes with strong alkaline water of pH 10.5-13.5 which is not diluted with water. On the other hand, pH 4
Hypochlorous acid sterilized water of ~ 8 is prepared by strongly electrolyzing the strongly acidic water or the mixed water of the strongly acidic water and an aqueous solution of a chloride salt such as sodium chloride by diaphragm-free electrolysis. It sterilizes.

【0020】上記のように、塩化ナトリウムなどの塩化
物塩水溶液を電解して得たpH10.5〜13.5の強
アルカリ水で食器の油落し洗浄を行うと、強アルカリ水
の洗浄後に析出したカルシウムが食器に付着することが
あり、また、洗浄に供したアルカリ水はpH値が高いの
でそのままドレン等に捨てることは好ましくない。そこ
で、本発明による食器洗浄・殺菌方法の第3の形態は、
上記第1及び第2の方法に加えて、さらに、塩化物塩水
溶液を有隔膜電解して得たpH1〜3.5の強酸性水の
一部をそのまま、食器洗浄槽に供給し、強アルカリ水で
洗浄した食器のカルシウムの溶解用洗浄水として利用し
たり、洗浄に供した強アルカリ水の中和剤として利用す
ることにより上記の問題を解決している。
As described above, when dishwashing is performed with strong alkaline water having a pH of 10.5 to 13.5 obtained by electrolyzing an aqueous solution of a chloride salt such as sodium chloride, precipitation occurs after washing with strong alkaline water. Calcium may adhere to tableware, and alkaline water used for washing has a high pH value, so it is not preferable to discard it as it is in a drain or the like. Therefore, a third embodiment of the dishwashing / sterilizing method according to the present invention comprises:
In addition to the above first and second methods, a part of the strongly acidic water having a pH of 1 to 3.5 obtained by electrolyzing a chloride salt aqueous solution with a diaphragm is directly supplied to a dishwashing tank, The above problem is solved by using as washing water for dissolving calcium in tableware washed with water or as a neutralizing agent for strong alkaline water used for washing.

【0021】次に、本発明による食器洗浄・殺菌装置の
実施例を添付の図面に基づいて説明する。図のように、
本発明の食器洗浄・殺菌装置は、食器、台所用品などの
食器類を入れて洗浄を行う食器洗浄槽1と、この洗浄槽
で使用する水を生成する洗浄・殺菌水調整装置2と、殺
菌水調整装置で生成した洗浄用あるいは殺菌用の水を洗
浄槽1に給水する洗浄水供給手段3から構成されてい
る。
Next, an embodiment of a dishwashing / sterilizing apparatus according to the present invention will be described with reference to the accompanying drawings. As shown
The dishwashing / sterilizing apparatus according to the present invention includes a dishwashing tank 1 for holding dishes such as tableware and kitchen utensils for washing, a washing / sterilizing water adjusting device 2 for generating water used in the washing tank, and a sterilizing apparatus. The washing water supply means 3 supplies washing water or sterilization water generated by the water adjusting device to the washing tank 1.

【0022】洗浄・殺菌水調整装置2は油落し洗浄用の
pH10.5〜13.5の強アルカリ水と、殺菌用のp
H4〜8の次亜塩素酸水と、必要に応じて、上記強アル
カリ水と次亜塩素酸水の他にさらにpH1〜3.5の強
酸性水を同時に生成するものである。
The washing / sterilizing water adjusting device 2 comprises a strong alkaline water having a pH of 10.5 to 13.5 for oil removal washing and a sterilizing p-water.
H4 to H8, and if necessary, strongly acidic water having a pH of 1 to 3.5 in addition to the strong alkaline water and the hypochlorous acid water.

【0023】[0023]

【発明の実施の形態】図1の装置の洗浄・殺菌水調整装
置2は、対向配置した陰電極4と陽電極5間を電解隔膜
6によって陰極室7と陽極室8に仕切った有隔膜電解槽
9を有し、この有隔膜電解槽9は下部給水部に、水道水
などの原水と塩化ナトリウムなどの塩化物塩溶液を供給
する給水管回路10を有するとともに、上部に陰極室側
排出管11と陽極室側排出管12を有し、全体として連
続通水式の電解整水装置を構成している。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A cleaning / sterilizing water adjusting apparatus 2 of the apparatus shown in FIG. 1 has a diaphragm electrode in which a cathode electrode 7 and an anode chamber 8 are partitioned by an electrolytic diaphragm 6 between a negative electrode 4 and a positive electrode 5 which are arranged opposite to each other. The diaphragm electrolyzer 9 has a water supply pipe circuit 10 for supplying raw water such as tap water and a chloride salt solution such as sodium chloride to a lower water supply section, and a cathode chamber side discharge pipe at an upper part. 11 and an anode-chamber-side discharge pipe 12, and constitutes a continuous water-flow type electrolytic water regulator as a whole.

【0024】有隔膜電解槽9の給水口に塩化ナトリウム
などの塩化物塩水溶液を供給する図1の給水管回路10
は、原水給水本管13から分岐した管路14と、この管
路14から供給される原水の一部を塩化物塩と混合して
塩化物塩水溶液を製造するタンク15と、このタンク1
5の塩化物塩水溶液に前記管路14からの水の一部を混
合して1〜5%、好ましくは2〜3%塩化物塩水溶液に
調整するタンク16と、このタンク16の水を電解槽9
の給水口に導く管路17を備え、所定濃度に調整した塩
化物塩水溶液を定量ポンプ18及び流量比率調整弁19
を介して有隔膜電解槽9の電極室7、8に供給するよう
になっている。
A water supply pipe circuit 10 shown in FIG. 1 for supplying an aqueous solution of a chloride salt such as sodium chloride to a water supply port of a diaphragm electrolyzer 9.
Is a pipe 14 branched from a raw water supply main pipe 13, a tank 15 for producing a chloride salt aqueous solution by mixing a part of the raw water supplied from the pipe 14 with a chloride salt,
A tank 16 for mixing a part of the water from the pipe line 14 with the aqueous chloride salt solution 5 to adjust the aqueous solution to 1 to 5%, preferably 2 to 3% chloride salt aqueous solution; Tank 9
A pipe 17 leading to a water supply port of the apparatus is provided.
Is supplied to the electrode chambers 7 and 8 of the diaphragm electrolyzer 9 through the electrode.

【0025】上記のように構成された電解整水装置は給
水管回路10から供給される塩化物塩水溶液を電解槽9
で電解し、陰極室7にpH11以上の強アルカリ水を生
成して陰極室側排出管11から送り出すとともに、陽極
室8に次亜塩素酸と塩素ガスを含む強酸性水を生成して
陽極室側排出管12を通して送り出すようになってい
る。図は省略したが、陰極室側排出管11と陽極室側排
出管12に流量バルブなどの流量調整手段を設けてもよ
い。
The electrolytic water conditioner configured as described above uses the aqueous chloride salt solution supplied from the water supply pipe circuit
To produce a strong alkaline water having a pH of 11 or more in the cathode chamber 7 and send it out from the cathode chamber side discharge pipe 11, and generate a strong acid water containing hypochlorous acid and chlorine gas in the anode chamber 8 to produce the anode chamber. It is sent out through the side discharge pipe 12. Although illustration is omitted, the cathode chamber side discharge pipe 11 and the anode chamber side discharge pipe 12 may be provided with a flow rate adjusting means such as a flow valve.

【0026】陰極室側排出管11には該排出管11の強
アルカリ水を希釈して増量させるための希釈水給水管2
0aが流量制御弁21、フロースイッチ22を介して接
続されており、陰極室側排出管11の強アルカリ水に希
釈水給水管20aからの原水を混合することにより、p
H10.5〜13.5にpH調整され、且つ、増量され
た強アルカリ水が強アルカリ水管路Aから排出されるよ
うになっている。
A diluted water supply pipe 2 for diluting and increasing the strong alkaline water of the discharge pipe 11 is provided on the cathode chamber side discharge pipe 11.
0a is connected via a flow control valve 21 and a flow switch 22. By mixing raw water from a dilution water supply pipe 20a with strong alkaline water in a cathode chamber side discharge pipe 11, p
The pH is adjusted to H10.5 to 13.5 and the increased amount of strong alkaline water is discharged from the strong alkaline water pipe A.

【0027】他方、陽極室側排出管12にも同様に希釈
水給水管20bが流量制御弁23、フロースイッチ24
を介して接続されており、陽極室側排出管12から送り
出される次亜塩素酸・塩素ガスを含有する強酸性水と、
希釈水給水管20bから供給される水が混合されるよう
になっている。この場合の強酸性水と希釈水の混合は、
強酸性水中の塩素ガスと希釈水を反応させて次亜塩素酸
(HClO)を発生させ、水中の次亜塩素酸の量を増加
させるとともに強酸性水を希釈して増量させ、pH4〜
8、濃度2〜200ppmの次亜塩素酸水にするためで
ある。従って、陽極室側排出管12と希釈水給水管20
bの接続部下流側はpH4〜8、濃度2〜200ppm
の次亜塩素酸水排水管路Bとなる。
On the other hand, the dilution water supply pipe 20b is also provided with a flow control valve 23 and a flow switch 24 in the anode chamber side discharge pipe 12.
And a strong acidic water containing hypochlorous acid / chlorine gas sent out from the anode chamber side discharge pipe 12;
The water supplied from the dilution water supply pipe 20b is mixed. Mixing of strongly acidic water and dilution water in this case
The hypochlorite (HClO) is generated by reacting the chlorine gas in the strongly acidic water with the dilution water to increase the amount of hypochlorous acid in the water and dilute the strongly acidic water to increase the pH.
8. This is to make the aqueous solution of hypochlorous acid having a concentration of 2 to 200 ppm. Therefore, the anode chamber side discharge pipe 12 and the dilution water supply pipe 20
The downstream side of the connection point of b is pH4-8, concentration 2-200ppm
Is a hypochlorous acid water drainage pipe B.

【0028】図の実施例では、強アルカリ水の希釈水給
水管20aと強酸性水の希釈水給水管20bは、給水本
管13から分岐した希釈水本管20を二股にして形成さ
れている。また、希釈水給水管20a、20bに介装さ
れているフロースイッチ22、24は水の流れを検出し
て電解槽9の電解ON、OFF制御信号として使用され
るものである。
In the embodiment shown in the figure, the dilution water supply pipe 20a for strong alkaline water and the dilution water supply pipe 20b for strong acid water are formed by bifurcating the dilution water main pipe 20 branched from the water supply main pipe 13. . The flow switches 22, 24 provided in the dilution water supply pipes 20a, 20b detect the flow of water and are used as an electrolysis ON / OFF control signal for the electrolytic cell 9.

【0029】図1の実施例は、上記の構成により、給水
管回路10から給水される所定濃度の塩化物塩水溶液を
有隔膜電解槽9に供給して電解することにより、陰極室
側排出管11からpH10.5以上の強アルカリ水が排
出され、この強アルカリ水に希釈水給水管20aからの
原水が混合されてpH10.5〜13.5の強アルカリ
水に調整されるとともに、他方、陽極室側排出管12か
ら強酸性水が排出され、この強酸性水に希釈水給水管2
0bからの原水が混合されてpH4〜8の次亜塩素酸殺
菌水が排出される。尚、次亜塩素酸殺菌水の濃度は塩化
物水溶液あるいは希釈水の混合量等により、好ましくは
2〜200ppmに調整する。
In the embodiment of FIG. 1, the above-described structure supplies an aqueous chloride salt solution of a predetermined concentration supplied from the water supply pipe circuit 10 to the diaphragm electrolysis tank 9 for electrolysis, thereby forming the cathode chamber side discharge pipe. The strong alkaline water having a pH of 10.5 or more is discharged from 11 and the raw water from the dilution water supply pipe 20a is mixed with the strong alkaline water to adjust to a strong alkaline water having a pH of 10.5 to 13.5. Strongly acidic water is discharged from the anode chamber side discharge pipe 12, and the strongly acidic water is diluted with a dilution water supply pipe 2.
The raw water from Ob is mixed and the hypochlorite sterilized water having a pH of 4 to 8 is discharged. The concentration of the hypochlorous acid sterilizing water is preferably adjusted to 2 to 200 ppm depending on the mixing amount of the aqueous chloride solution or the dilution water.

【0030】本発明は陽極室側排出管12の水に原水を
希釈してpH4〜8の次亜塩素酸殺菌水を生成するもの
であるが、これと並行して陰極室側排出管11の希釈前
または希釈後の前記強アルカリ水の一部を、陽極室側排
出管12の希釈水混合前または混合後の水に混合して次
亜塩素殺菌水のpHを最終的にpH4〜8に調整しても
よい。このため、図1の実施例では希釈後の陰極室側排
出管11’に強アルカリ水タンク25を介装するととも
に、このタンク25から希釈後の陽極室側排出管12’
に管路26を接続し、ポンプ27により強アルカリ水の
一部を希釈後の陽極室側排出管12’の水に混合するよ
うにしてある。
According to the present invention, the raw water is diluted with the water in the anode chamber side discharge pipe 12 to produce sterilized hypochlorous acid water having a pH of 4-8. A part of the strong alkaline water before or after the dilution is mixed with the water before or after the mixing of the dilution water in the anode chamber side discharge pipe 12 to finally adjust the pH of the hypochlorite water to pH 4 to 8. It may be adjusted. For this reason, in the embodiment of FIG. 1, a strong alkaline water tank 25 is interposed in the cathode chamber side discharge pipe 11 ′ after dilution, and the anode chamber side discharge pipe 12 ′ after dilution from this tank 25.
And a part of the strong alkaline water is mixed with the diluted water of the anode chamber side discharge pipe 12 ′ by the pump 27.

【0031】陽極室側排出管12から排出される水はp
Hが低いときは塩素ガスを含む。このため、図1の実施
例では希釈後の陽極室側排出管12にガス吸収槽28を
介装してある。また、好ましい実施例として陽極室側排
出管12’に次亜塩素酸の濃度検出装置29を設けてあ
る。
The water discharged from the anode chamber side discharge pipe 12 is p
When H is low, chlorine gas is included. For this reason, in the embodiment of FIG. 1, the gas absorption tank 28 is interposed in the anode chamber side discharge pipe 12 after dilution. As a preferred embodiment, a hypochlorous acid concentration detector 29 is provided in the anode chamber side discharge pipe 12 '.

【0032】前記陽極室側排出管12から排水される強
酸性水はその所定量を所定量の希釈水と混合して目的の
pH及び目的の流量の次亜塩素酸殺菌水に生成するもの
であるが、そのために必要な強酸性水は陽極室8から生
成される量の一部で足る場合があり、この場合は残りの
強酸性水は系外に排水する必要がある。このため、図の
装置では、より好ましい実施例として、陽極室側排水管
12の強酸性水の一部を系外に排水する分岐排水管30
を設けてある。この分岐排水管30は陽極室側排水管1
2から切換弁31を介して分岐されており、強酸性水排
水管路Cとなる。
The strongly acidic water discharged from the anode chamber side discharge pipe 12 is mixed with a predetermined amount of a predetermined amount of dilution water to produce a hypochlorite sterilizing water having a desired pH and a desired flow rate. However, the strongly acidic water required for this may be a part of the amount generated from the anode chamber 8, and in this case, the remaining strongly acidic water needs to be drained out of the system. For this reason, in the apparatus shown in the drawing, as a more preferred embodiment, a branch drain pipe 30 for draining a part of the strongly acidic water of the anode chamber drain pipe 12 out of the system.
Is provided. The branch drain pipe 30 is connected to the anode chamber side drain pipe 1.
It is branched from 2 via a switching valve 31, and becomes a strongly acidic water drainage pipe C.

【0033】分岐排水管30から排水される強酸性水に
は次亜塩素酸や塩素ガスが含まれているのでそのまま排
水することは好ましくない。そこで本発明のさらに他の
実施形態は分岐排水管30の系に、該分岐排水管30を
通る強酸性水、または、分岐排水管30から排水された
強酸性水の次亜塩素酸と塩素ガスを還元して塩酸に変え
るための還元装置32が設けられている。
Since the strongly acidic water drained from the branch drain pipe 30 contains hypochlorous acid and chlorine gas, it is not preferable to drain it as it is. Therefore, still another embodiment of the present invention relates to a system of the branch drainage pipe 30 in which a strong acid water passing through the branch drainage pipe 30 or a strong acid water drained from the branch drainage pipe 30 is hypochlorous acid and chlorine gas. Is provided with a reducing device 32 for reducing the hydrogen to hydrochloric acid.

【0034】還元装置32の好ましい第1の実施例(還
元装置32a)としては、図2に参照記号32aで示す
ように、強酸性水が通る管路(図の実施例では分岐排水
管30)に反応槽33と白金族などの触媒34を配設す
るとともに、この反応槽33に水素ガスを送る水素ガス
供給管35を接続した構成になり、触媒の存在下で強酸
性水中の次亜塩素酸と塩素ガスを水素ガス供給管35か
らの水素ガスと反応させることにより、次亜塩素酸と塩
素ガスを還元させ、塩酸化するものである。すなわち、
強酸性水中の次亜塩素酸(HClO)と塩素ガス(Cl
2)は水素ガス(H2)と反応して塩酸(HCl)にな
る。
As a preferred first embodiment of the reduction device 32 (reduction device 32a), as shown by reference numeral 32a in FIG. 2, a pipeline through which strongly acidic water passes (a branch drain pipe 30 in the illustrated embodiment). A reaction tank 33 and a catalyst 34 such as a platinum group are disposed in the reaction tank 33, and a hydrogen gas supply pipe 35 for sending hydrogen gas is connected to the reaction tank 33. By reacting the acid and chlorine gas with the hydrogen gas from the hydrogen gas supply pipe 35, the hypochlorous acid and the chlorine gas are reduced and oxidized. That is,
Hypochlorous acid (HClO) and chlorine gas (Cl
2 ) reacts with hydrogen gas (H 2 ) to form hydrochloric acid (HCl).

【0035】本発明による前記装置の陰極室側排出管1
1を通る強アルカリ水には水素ガスが含まれるので、よ
り好ましくは、該陰極室側排出管11に強アルカリ水中
の水素ガスを取り出すための水素ガス分離部36を設け
るとともに、この水素ガス分離部36から反応槽33に
水素ガス供給管35を配管し、ポンプ37を介して強ア
ルカリ水中の水素ガスを利用して送り込むようにする。
この構成では還元のための水素ガスを自給できるので合
理的である。
The cathode tube side discharge pipe 1 of the device according to the present invention
Since the strong alkaline water passing through 1 contains hydrogen gas, more preferably, the cathode chamber side discharge pipe 11 is provided with a hydrogen gas separating portion 36 for extracting hydrogen gas from the strong alkaline water, A hydrogen gas supply pipe 35 is piped from the section 36 to the reaction tank 33, and is fed through a pump 37 using hydrogen gas in strong alkaline water.
This configuration is reasonable because hydrogen gas for reduction can be self-supplied.

【0036】還元装置32の好ましい第2の実施例(還
元装置32b)は、図2のように、分岐排水管30から
の強酸性水を受入れる貯水槽38内に、紫外線灯39の
近傍を白金族などの触媒40のカバーで囲んだ紫外線照
射装置41を配設するとともに、この紫外線照射装置4
1を通して貯水槽38内の水を循環させ、水面上方から
霧状(シャワー状)に放出させる循環路42を設けた構
成になっている。
As shown in FIG. 2, the second preferred embodiment of the reduction device 32 (reduction device 32b) is a platinum storage device for receiving strongly acidic water from the branch drain 30 in the vicinity of an ultraviolet lamp 39. And an ultraviolet irradiation device 41 surrounded by a cover of a catalyst 40 such as an aromatic group.
1 is provided with a circulation path 42 for circulating the water in the water storage tank 38 and discharging the water in the form of a mist (shower) from above the water surface.

【0037】この構成の還元装置32bは、強酸性水に
紫外線を照射すると、触媒40下の紫外線のエネルギー
によって強酸性中の次亜塩素酸が還元され塩酸に変ると
ともに、塩素ガスは前記循環路42のシャワー放水によ
って液中に溶け込み次亜塩素酸となった後、前記のよう
に、触媒40下の紫外線エネルギーによって還元され、
塩酸になる。この場合、塩素ガスを液中に効率良く溶け
込ませるために、給水パイプ43から貯水槽38に水を
給水するようにしてもよい。図において破線で示すよう
に、この給水パイプ43は本発明の装置の原水給水本管
13から配管してもよい。さらに、貯水槽38の上蓋に
活性炭等を使用したガス抜き装置44を設け、塩素成分
を除去したガスを外部に放出するようにしてもよい。な
お、図中、参照記号45は水位センサである。
When the strongly acidic water is irradiated with ultraviolet light, the energy of the ultraviolet light under the catalyst 40 reduces the hypochlorous acid in the strongly acidic water to convert it into hydrochloric acid. After being dissolved into the liquid by the shower water discharge of 42 to become hypochlorous acid, it is reduced by the ultraviolet energy below the catalyst 40 as described above,
It becomes hydrochloric acid. In this case, water may be supplied from the water supply pipe 43 to the water storage tank 38 in order to efficiently dissolve the chlorine gas into the liquid. As shown by the broken line in the figure, the water supply pipe 43 may be connected from the raw water supply main pipe 13 of the apparatus of the present invention. Further, a gas venting device 44 using activated carbon or the like may be provided in the upper lid of the water storage tank 38 to discharge the gas from which the chlorine component has been removed to the outside. In the drawing, reference numeral 45 is a water level sensor.

【0038】還元装置32の他の実施例(還元装置32
c)としては、L−アスコルビン酸、エチルアルコー
ル、メチルアルコールなどの還元剤水溶液46をポンプ
で送って被還元処理水に添加もしくはシャワー状に吹き
付ける装置を使用することもできる。また。還元剤水溶
液46は貯水槽38内の処理水に混合してもよく、さら
には、図のように貯水槽38の排水管47の水に添加し
てもよい。
Another embodiment of the reduction device 32 (reduction device 32
As the device c), a device may be used in which a reducing agent aqueous solution 46 such as L-ascorbic acid, ethyl alcohol, methyl alcohol or the like is pumped and added to the water to be reduced or sprayed in a shower. Also. The reducing agent aqueous solution 46 may be mixed with the treated water in the water storage tank 38, or may be added to the water in the drain pipe 47 of the water storage tank 38 as shown in the figure.

【0039】上記の各還元装置32a、32b、32c
は、それぞれ一種を単独に使用してもよく、また、いず
れか二つ以上を組合わせて使用してもよい。図2の実施
例は上記三通りの還元装置32a、32b、32cを組
合わせており、この場合は還元剤水溶液46は前記第
1、第2の還元装置32a、32bで還元処理した水に
添加して排水する組合せでもよく、また、前記第1の還
元装置32aの反応槽33と触媒34は貯水槽38の循
環路42に介装してもよい。また、図1及び後述の図
3、図4の各装置に図2と同様の還元装置32a、32
b、32cを使用してもよい。
Each of the above reduction devices 32a, 32b, 32c
May be used alone or in combination of two or more. The embodiment of FIG. 2 combines the above three types of reduction devices 32a, 32b, and 32c. In this case, the reducing agent aqueous solution 46 is added to the water reduced by the first and second reduction devices 32a and 32b. Alternatively, the reaction tank 33 and the catalyst 34 of the first reduction device 32a may be interposed in the circulation path 42 of the water tank 38. Further, the same reduction devices 32a, 32 as in FIG.
b, 32c may be used.

【0040】図1、図2の実施例の洗浄・殺菌水調整装
置2は、原水給水本管13からの原水の一部を高濃度の
塩化物塩水溶液にして電解し、生成された強アルカリ水
と強酸性水を原水給水本管13からの原水で希釈するも
のであるが、原水給水本管13の原水の全量を比較的低
濃度の塩化物塩水溶液にして電解し、生成された電解水
を希釈しないで陰極室側排出管11からpH10.5〜
13.5の強アルカリ水を排出し、陽極室側排出管12
からpH4〜8の次亜塩素酸殺菌水を排出することもで
きるようにしてある。
The washing / sterilizing water adjusting device 2 of the embodiment shown in FIGS. 1 and 2 converts a part of the raw water from the raw water supply main pipe 13 into a high-concentration chloride salt aqueous solution and electrolyzes the strong alkaline water. The water and the strongly acidic water are diluted with the raw water from the raw water supply main 13, and the whole amount of the raw water in the raw water supply main 13 is electrolyzed into a relatively low-concentration chloride salt aqueous solution, and the electrolysis generated is performed. Without diluting water, pH 10.5-
13.5 strong alkaline water is discharged, and the anode chamber side discharge pipe 12 is discharged.
From which hypochlorite sterilized water having a pH of 4 to 8 can be discharged.

【0041】このため、希釈水給水管20から切換弁4
8を介して有隔膜電解槽9の給水側に管路49を接続
し、切換弁48の切換操作により希釈水給水管20へ流
れる原水が有隔膜電解槽9の給水側に流れ、給水本管1
3からの原水の全量が塩化物塩水溶液として有隔膜電解
槽9で電解されるようになっている。この管路49には
好ましくは流量制御弁50及びフロースイッチ51を設
ける。
For this reason, the switching valve 4 is connected to the dilution water supply pipe 20.
A pipe 49 is connected to the water supply side of the diaphragm electrolyzer 9 via the pipe 8, and the raw water flowing to the dilution water supply pipe 20 by the switching operation of the switching valve 48 flows to the water supply side of the diaphragm electrolyzer 9, and the water supply main pipe 1
The entire amount of raw water from No. 3 is electrolyzed in the diaphragm electrolyzer 9 as a chloride salt aqueous solution. This line 49 is preferably provided with a flow control valve 50 and a flow switch 51.

【0042】図3は他の洗浄・殺菌水調整装置を使用し
た本発明の洗浄・殺菌装置であって、図1、図2と同じ
参照記号は同一の部材を示している。このものは、有隔
膜電解槽9の一側に塩化物塩水溶液の給水管回路10を
有し、他側に陰極室側排出管11と陽極室側排出管12
を有する連続通水式の有隔離膜電解装置9と、無隔膜電
解槽52の一側に塩化物塩水溶液の給水管53を有し、
他側に電解水排出管54を有する連続通水式の無隔膜電
解整水装置55を備えている。
FIG. 3 shows a cleaning / sterilizing apparatus according to the present invention using another cleaning / sterilizing water adjusting device. The same reference numerals as those in FIGS. 1 and 2 denote the same members. This has a water supply pipe circuit 10 for a chloride salt aqueous solution on one side of a diaphragm electrolyzer 9 and a cathode chamber side discharge pipe 11 and an anode chamber side discharge pipe 12 on the other side.
A continuous-flow type isolated membrane electrolysis device 9 having: and a water supply pipe 53 of a chloride salt aqueous solution on one side of a non-diaphragm electrolysis tank 52;
A continuous flow-type non-diaphragm electrolysis water conditioning device 55 having an electrolysis water discharge pipe 54 on the other side is provided.

【0043】有隔膜電解槽9の陰極室側排出管11には
前記と同様に希釈水給水管20aが接続されており、陰
極室側排出管11から排水される強アルカリ水を希釈水
給水管20aから給水される原水で希釈してpH10.
5〜13.5の強アルカリ水に調整するものである。ま
た、図3では陽極室側排出管12にも前記と同様に希釈
水給水管20bが接続されているが、これは必ずしも必
須のものではない。
A diluted water supply pipe 20a is connected to the cathode chamber side discharge pipe 11 of the diaphragm electrolyzer 9 in the same manner as described above, and the strong alkaline water discharged from the cathode chamber side discharge pipe 11 is diluted water supply pipe. Diluted with raw water supplied from 20a to pH10.
It is adjusted to a strong alkaline water of 5 to 13.5. In FIG. 3, the dilution water supply pipe 20b is also connected to the anode chamber side discharge pipe 12 in the same manner as described above, but this is not necessarily essential.

【0044】他方、無隔膜電解整水装置55の電解水排
出管54に希釈水給水管20cが接続されており、無隔
膜電解槽52で生成された次亜塩素酸水が原水で希釈さ
れるようになっている。
On the other hand, the diluted water supply pipe 20c is connected to the electrolyzed water discharge pipe 54 of the diaphragmless electrolysis water conditioning apparatus 55, and the hypochlorous acid water generated in the diaphragmless electrolytic tank 52 is diluted with raw water. It has become.

【0045】図3の実施例の装置は、さらに、有隔膜電
解槽9の陽極室側排出管12から排水される強酸性水を
前記無隔膜電解整水装置55の水回路、すなわち、無隔
膜電解槽52からの排出管54、又は、無隔膜電解槽5
2への給水管53に供給・混合することにより、無隔膜
電解槽52から排水される電解処理水をpH4〜8の次
亜塩素酸殺菌水に調整するとともに、この次亜塩素酸殺
菌水の次亜塩素酸濃度を所定の値(2〜200ppm)
に調整するためのpH・濃度調整管56を具備してい
る。
The apparatus of the embodiment shown in FIG. 3 further uses the acidic circuit discharged from the anode chamber side discharge pipe 12 of the diaphragm electrolyzer 9 for the water circuit of the diaphragmless electrolysis water conditioning apparatus 55, that is, the diaphragmless membrane. Discharge pipe 54 from electrolytic cell 52 or non-diaphragm electrolytic cell 5
2 is supplied to and mixed with the water supply pipe 53 to adjust the pH of the electrolyzed water discharged from the non-diaphragm electrolytic cell 52 to hypochlorous acid disinfecting water having a pH of 4 to 8; Hypochlorous acid concentration at a specified value (2-200 ppm)
And a pH / concentration adjusting tube 56 for adjusting the pH.

【0046】このため、図3では陽極室側排出管12か
ら無隔膜電解整水装置55の排出管54に前記pH・濃
度調整管56を接続している。このpH・濃度調整管5
6は図3のようにタンク73に貯水した強酸性水の適量
を定量ポンプを介して供給する管路でもよく、また、陽
極室側排出管12を流れる水を切換弁57とpH・濃度
調整管56を用いて供給する管路でもよい。もちろん図
3のように、両者を併用してもよい。また、図は省略し
たが、このpH・濃度調整管56は無隔膜電解槽52の
排出管54に接続する場合に限らず、無隔膜電解槽52
の給水管53に接続し、無隔膜電解槽52に給水される
塩化物塩水溶液に有隔膜電解槽9の前記強酸性水の適量
を添加することにより、無隔膜電解槽52から排水され
る次亜塩素酸水のpH・濃度を調整するようにしてもよ
い。
Therefore, in FIG. 3, the pH / concentration adjusting pipe 56 is connected from the anode chamber side discharge pipe 12 to the discharge pipe 54 of the non-diaphragm electrolysis water regulator 55. This pH / concentration adjusting tube 5
Reference numeral 6 may be a conduit for supplying an appropriate amount of strong acid water stored in the tank 73 through a metering pump as shown in FIG. A pipe supplied by using the pipe 56 may be used. Of course, both may be used together as shown in FIG. Although illustration is omitted, the pH / concentration adjusting tube 56 is not limited to being connected to the discharge tube 54 of the diaphragm-free electrolytic cell 52,
Is added to the aqueous chloride salt solution supplied to the diaphragm-free electrolytic cell 52 by adding an appropriate amount of the strong acid water in the diaphragm-containing electrolytic cell 9 to drain the water from the diaphragm-free electrolytic cell 52. The pH and concentration of the aqueous chlorite solution may be adjusted.

【0047】図3の実施例の装置も前記図1、図2の装
置と同様に通常は高濃度の塩化物塩水溶液を電解し、原
水給水本管13の水で電解後の水を希釈して所望のpH
に調整しながら増量させるものであるが、所望により原
水給水本管13の原水の全量を塩化物塩水溶液と共に給
水して電解し、電解後の水を希釈しないで目的の強アル
カリ水と次亜塩素酸殺菌水を生成することができるよう
に構成されている。
The apparatus of the embodiment shown in FIG. 3 is also generally similar to the apparatus shown in FIGS. Desired pH
If necessary, the entire amount of the raw water in the raw water supply main pipe 13 is supplied together with a chloride salt aqueous solution to perform electrolysis, and the desired strong alkaline water and hypochlorous water are diluted without diluting the water after the electrolysis. It is configured so that chloric acid sterilizing water can be generated.

【0048】このため、図3の装置は、前記希釈水給水
管20a、20b、20cと共通の給水本管13から有
隔膜電解槽9と無隔膜電解槽52の各々の給水側にそれ
ぞれ原水給水管58、59を接続するとともに、これら
原水給水管58、59と希釈水給水管20a、20b、
20cのそれぞれに、選択的に開閉する開閉制御弁機構
60、61、62、63、64を具備している。図3の
実施例ではこれらの開閉制御弁機構60〜64はソレノ
イド弁で例示されているが、これに限定されるものでは
ない。
For this reason, the apparatus shown in FIG. 3 is connected to the diluting water supply pipes 20a, 20b, 20c from the common water supply main pipe 13 to the respective water supply sides of the diaphragm electrolyzer 9 and the non-diaphragm electrolyzer 52. The pipes 58, 59 are connected, and the raw water supply pipes 58, 59 and the dilution water supply pipes 20a, 20b,
Each of the opening / closing control valve mechanisms 60, 61, 62, 63, and 64 selectively opens and closes. In the embodiment of FIG. 3, these opening / closing control valve mechanisms 60 to 64 are exemplified by solenoid valves, but are not limited thereto.

【0049】かくして、原水給水管58、59の開閉制
御弁機構60、61を閉じ、希釈水給水管20a、20
b、20cの開閉制御弁機構62、63、64を開くと
高濃度の塩化物塩水溶液が、有隔膜電解槽と無隔膜電解
槽で電解され、各々の電解水が希釈水給水管20a、2
0b、20cからの原水によって希釈される。
Thus, the open / close control valve mechanisms 60 and 61 of the raw water supply pipes 58 and 59 are closed, and the dilution water supply pipes 20a and 20a are closed.
When the opening / closing control valve mechanisms 62, 63, 64 of b, 20c are opened, a high-concentration aqueous chloride salt solution is electrolyzed in the diaphragm electrolyzer and the non-diaphragm electrolyzer, and each electrolyzed water is diluted with the dilution water feed pipes 20a, 20b.
Ob, diluted by raw water from 20c.

【0050】他方、原水給水管58、59の開閉制御弁
機構60、61を開き、希釈水給水管20a、20b、
20cの開閉制御弁機構62、63、64を閉じると電
解水は希釈されず、給水本管13の水の全量が塩化物塩
水溶液に混合されて電解される。
On the other hand, the opening / closing control valve mechanisms 60, 61 of the raw water supply pipes 58, 59 are opened, and the dilution water supply pipes 20a, 20b,
When the opening / closing control valve mechanism 62, 63, 64 of 20c is closed, the electrolyzed water is not diluted, and the whole amount of water in the water supply main pipe 13 is mixed with the chloride salt aqueous solution to be electrolyzed.

【0051】同様にして前記の各開閉制御弁機構60〜
64の開閉制御を組合わせることによって、例えば、無
隔膜電解槽52については塩化物塩水溶液に原水給水管
59の水を合流して電解し、電解水は希釈せず、他方、
有隔膜電解槽9は高濃度の塩化物塩水溶液を電解して強
アルカリ水だけを希釈するなど、多種の電解整水運転が
可能になる。尚、原水給水管59と希釈水給水管20c
に配置されているフロースイッチ65、66は無隔膜電
解槽52をON、OFF制御するスイッチとして使用す
ることができる。
Similarly, each of the opening / closing control valve mechanisms 60 to 60
By combining the opening / closing control of 64, for example, in the non-diaphragm electrolytic cell 52, the water of the raw water supply pipe 59 is combined with the aqueous solution of chloride salt for electrolysis, and the electrolyzed water is not diluted.
The diaphragm electrolyzer 9 can perform various kinds of electrolyzing operations such as electrolyzing a high concentration aqueous chloride salt solution to dilute only strong alkaline water. The raw water supply pipe 59 and the dilution water supply pipe 20c
Can be used as switches for controlling ON and OFF of the diaphragm-free electrolytic cell 52.

【0052】図4は、有隔膜電解整水装置と無隔膜電解
整水装置を使用したさらに別の洗浄・殺菌水調整装置2
で洗浄用及び殺菌用の水を調整する場合の実施形態を示
すもので、このものは、有隔膜電解槽9の陽極室側排出
管12を無隔膜電解整水装置55の給水管53に接続
し、有隔膜電解槽9で生成したpH1〜3.5の強酸性
水又はこの強酸性水と塩化ナトリウムなどの塩化物塩水
溶液の混合水を無隔膜電解槽52で電解してpH4〜8
の次亜塩素酸殺菌水を調整するようになっている。ま
た、図4の装置は、有隔膜電解槽9の陰極室7からpH
10.5〜13.5の強アルカリ水を生成し、原水で希
釈しないでそのまま食器の油落し洗浄水として供給する
構造になっている。その他は図1乃至図3の装置と同様
の構造にすることができる。
FIG. 4 shows another washing / sterilizing water conditioning device 2 using a diaphragm electrolysis water conditioning device and a non-diaphragm electrolysis water conditioning device.
This shows an embodiment in which water for cleaning and sterilization is adjusted by connecting the anode chamber side discharge pipe 12 of the diaphragm electrolyzer 9 to the water supply pipe 53 of the diaphragmless electrolysis water regulator 55. Then, strongly acidic water having a pH of 1 to 3.5 or a mixed water of the strongly acidic water and an aqueous solution of a chloride salt such as sodium chloride produced in the diaphragm electrolytic cell 9 is electrolyzed in the non-diaphragm electrolytic cell 52 to obtain a pH of 4 to 8.
The hypochlorite sterilizing water is adjusted. In addition, the apparatus shown in FIG.
It has a structure in which a strong alkaline water of 10.5 to 13.5 is generated, and is supplied as it is to the dishwashing water without dilution with raw water. Otherwise, the structure can be the same as that of the apparatus shown in FIGS.

【0053】図1、図2の有隔膜電解槽9は陰極室7に
析出するカルシウムを溶解洗浄するために、電極の極性
を逆転して逆電洗浄を行う型式の電解槽を示している。
このため、陰極室側排出管11から切換弁67を介して
陽極室側排出管12に合流管路68を接続するととも
に、分岐排水管30から切換弁69を介してドレン70
へ排水される排水管路71を設けてある。従って、切換
弁67を介して陰極室側排出管11を陽極室側排出管1
2に連通させるとともに、切換弁31を介して陽極室側
排出管12を分岐排水管30に連通させ、さらに切換弁
69を介してドレン70へ連通させると、電解槽9の洗
浄水はすべてドレン70へ排水される。
The diaphragm electrolyzer 9 shown in FIGS. 1 and 2 is a type of electrolyzer in which the polarity of the electrode is reversed to perform reverse electrolysis in order to dissolve and wash calcium precipitated in the cathode chamber 7.
Therefore, the merging conduit 68 is connected from the cathode chamber side discharge pipe 11 to the anode chamber side discharge pipe 12 via the switching valve 67, and the drain 70 is connected via the switching valve 69 from the branch drain pipe 30.
There is provided a drain pipe 71 for draining water. Accordingly, the cathode chamber side discharge pipe 11 is connected to the anode chamber side discharge pipe 1 through the switching valve 67.
2, the anode chamber side discharge pipe 12 is connected to the branch drain pipe 30 via the switching valve 31, and further connected to the drain 70 via the switching valve 69. Drained to 70.

【0054】他方、図3及び図4の有隔膜電解槽9は所
定時間毎に電極の極性を逆転して電解整水を行うことに
より析出したカルシウムを溶解洗浄するもので、この電
解槽は電極の極性が変わっても強アルカリ水と強酸性水
の取出管路に影響しないように、陰極室側排出管11と
陽極室側排出管12間に電極の極性転換に連動して切換
わる流路切換弁装置72が設けられている。前記洗浄水
回路については図3の装置の構造を図1、図2の装置に
応用してもよく、また、図1、図2の装置の構造を図3
の装置に応用してもよい。
On the other hand, the diaphragm electrolyzer 9 shown in FIGS. 3 and 4 reverses the polarity of the electrode at predetermined time intervals to perform electrolytic water adjustment, and dissolves and cleans the precipitated calcium. The flow path which is switched between the cathode chamber side discharge pipe 11 and the anode chamber side discharge pipe 12 in conjunction with the polarity change of the electrode so that the polarity of the electrolyte does not affect the extraction pipes of the strong alkaline water and the strong acid water. A switching valve device 72 is provided. For the washing water circuit, the structure of the apparatus of FIG. 3 may be applied to the apparatus of FIGS. 1 and 2, and the structure of the apparatus of FIGS.
May be applied to the above-mentioned device.

【0055】尚、図中記号Pは定量ポンプ、Mはモータ
バルブ、SOLはソレノイド弁を示している。
In the figure, symbol P indicates a metering pump, M indicates a motor valve, and SOL indicates a solenoid valve.

【0056】かくして、図1乃至図4の実施例に示す食
器洗浄・殺菌装置の洗浄・殺菌水調整装置2はいずれも
pH10.5〜13.5の強アルカリ水を調整して排水
管路Aからアルカリ水タンク74に貯留するとともに、
pH4〜8の次亜塩素酸殺菌水を調整して排水管路Bか
ら次亜塩素酸水タンク75に貯留し、さらに、pH1〜
3.5の強酸性水を調整し、排水管路Cから強酸性水タ
ンク76に貯留するようになっている。
Thus, the washing / sterilizing water adjusting device 2 of the dishwashing / sterilizing device shown in the embodiment of FIGS. 1 to 4 adjusts the pH of strong alkaline water of 10.5 to 13.5 and discharges the drainage line A. And stored in an alkaline water tank 74 from
Hypochlorous acid sterilized water having a pH of 4 to 8 is adjusted and stored in a hypochlorous acid water tank 75 from a drainage pipe B.
The highly acidic water of 3.5 is adjusted and stored in the strongly acidic water tank 76 from the drainage pipe C.

【0057】洗浄水調整装置2で調整されたpH10.
5〜13.5の強アルカリ水とpH4〜8の次亜塩素酸
水とpH1〜3.5の強酸性水は各々の供給管路77、
78、79を通してポンプ等で食器洗浄槽1へ給水され
る。
PH adjusted by washing water adjusting device 2
The strong alkaline water having a pH of 5 to 13.5, the hypochlorous acid water having a pH of 4 to 8 and the strong acid water having a pH of 1 to 3.5 are supplied to respective supply pipes 77,
Water is supplied to the dishwashing tank 1 through pumps 78 and 79.

【0058】食器洗浄槽1は内部に収納した食器80に
前記各種の洗浄・殺菌水を散布して洗浄・殺菌を行う槽
であり、図の実施例では、食器80を載せて移動させる
ベルトコンベア等の搬送手段81を有するとともに、前
記三種の水の供給管路77、78、79の各々の噴射ノ
ズル82、83、84が搬送手段81上の食器80に向
くようにして組み付けられている。
The dishwashing tank 1 is a tank for performing washing and sterilization by spraying the above various kinds of washing and sterilizing water on the tableware 80 stored therein. In the embodiment shown in the drawing, a belt conveyor on which the tableware 80 is placed and moved. Etc., and the nozzles 82, 83, 84 of the three types of water supply pipes 77, 78, 79 are assembled so as to face the tableware 80 on the conveying means 81.

【0059】食器80の洗浄は、強アルカリ水による油
落し洗浄の後、次亜塩素酸水による殺菌がなされるよう
に強アルカリ水の噴射ノズル82を次亜塩素酸水の噴射
ノズル83の上流側に向くようにする。pH10.5〜
13.5の強アルカリ水で食器の油落し洗浄を行うと洗
浄水から析出したカルシウムが食器80の表面に付着す
る。強酸性水供給管路の噴射ノズル84からの散水はこ
のカルシウムを溶解して洗い流すためのものであるか
ら、噴射ノズル84は強アルカリ水の噴射ノズル82と
次亜塩素酸水の噴射ノズル83の間に配置する。
The washing of the tableware 80 is performed by removing the jet nozzle 82 of the strong alkaline water upstream of the jet nozzle 83 of the hypochlorous acid water so that after the oil is washed off with the strong alkaline water and sterilized with the hypochlorous acid solution, the tableware 80 is cleaned. Face to the side. pH 10.5 ~
When dishwashing is performed with 13.5 strong alkaline water, calcium precipitated from the washing water adheres to the surface of the tableware 80. Since the water spray from the injection nozzle 84 of the strongly acidic water supply line is for dissolving and washing away this calcium, the injection nozzle 84 is formed by the injection nozzle 82 of the strong alkaline water and the injection nozzle 83 of the hypochlorous acid water. Place between.

【0060】食器洗浄槽1は各々の噴射ノズル82、8
3、84の下方を各洗浄・殺菌水に対応する強アルカリ
水受槽85、強酸性水受槽86及び次亜塩素酸水受槽8
7に仕切られているとともに、各受槽85、86、87
からオーバーフローした水は、好ましくは、合流槽88
に合流させて中和させた後ドレン89へ排水されるよう
になっている。
The dishwashing tank 1 is provided with respective spray nozzles 82, 8
A strong alkaline water receiving tank 85, a strongly acidic water receiving tank 86, and a hypochlorous acid water receiving tank 8 corresponding to each washing / sterilizing water are provided below the lower parts 3, 84.
7 and each receiving tank 85, 86, 87
The water overflowing from the
And then neutralized, and then drained to a drain 89.

【0061】強アルカリ水供給管路77から供給される
強アルカリ水の一部は管路を介して強アルカリ水受槽8
5の下流側貯水部に供給されるようになっている。また
強アルカリ水受槽85の下流側貯水部の水は食器の油落
し洗浄能力を保持しているので、図の実施例では循環路
90を介して強アルカリ水の噴射ノズル82に供給でき
るようにしてある。
A part of the strong alkaline water supplied from the strong alkaline water supply pipe 77 is supplied to the strong alkaline water receiving tank 8 through the pipe.
5 is supplied to the downstream water storage section. Further, since the water in the downstream water storage portion of the strong alkaline water receiving tank 85 retains the drainage cleaning ability of tableware, in the embodiment shown in the drawing, the water can be supplied to the strong alkaline water injection nozzle 82 via the circulation path 90. It is.

【0062】尚、食器洗浄槽1は洗浄の最終段階として
食器80に蒸気又は温水を噴射するノズル91を備えて
いる。このノズル91は原水給水管路13から分岐した
管路92に連通しており、この管路92には加熱部93
が介装されている。
The dishwashing tank 1 is provided with a nozzle 91 for injecting steam or hot water into the dishware 80 as a final stage of washing. The nozzle 91 communicates with a pipe 92 branched from the raw water supply pipe 13, and the pipe 92 has a heating unit 93.
Is interposed.

【0063】本発明ではかくして食器洗浄槽1内の食器
80はpH10.5〜13.5の強アルカリ水で油落し
洗浄をした後、pH1〜3.5の強酸性水でカルシウム
を洗い流し、pH4〜8の次亜塩素酸水で殺菌した後、
蒸気又は温水を散布して食器洗浄槽1から送り出され
る。
In the present invention, the tableware 80 in the dishwashing tank 1 is thus washed with greasy water having a pH of 10.5 to 13.5 and then washed with strong acidic water having a pH of 1 to 3.5 to remove calcium, and then washed with a pH of 4 to 3.5. After sterilizing with ~ 8 hypochlorous acid water,
Steam or hot water is sprayed and sent out from the dishwashing tank 1.

【0064】[0064]

【効果】本発明は一つの洗浄水調整装置で強アルカリ
水、次亜塩素酸殺菌水、強酸性水の複数種の洗浄水を同
時に生成し、食器の第一次油落し洗浄と第二次殺菌洗浄
をラインに沿って連続的に行うことができるので食器類
の洗浄・殺菌効率が著しく向上する。
[Effect] The present invention simultaneously produces a plurality of types of washing water of strong alkaline water, hypochlorous acid sterilizing water, and strongly acidic water with a single washing water adjusting device, and performs primary degreasing and secondary washing of tableware. Since the sterilization and washing can be continuously performed along the line, the efficiency of washing and sterilizing tableware is remarkably improved.

【0065】特に、強アルカリ水、次亜塩素酸水を調整
するに際し、相対的に少量の高濃度塩化物塩水溶液を電
解して強アルカリ水と次亜塩素酸水を生成し、希釈水の
混合によって強アルカリ水と次亜塩素酸水を増量させる
ので、電解槽が相対的に小容量のもので足り、コストの
低減をはかることができる。また、希釈水の混合調整で
pH、濃度を微妙に調整することができる。さらに高濃
度の水溶液を電解するので電導度が高くなり、電解効率
が著しく向上する。
In particular, when adjusting the strong alkaline water and the hypochlorous acid water, a relatively small amount of a high-concentration chloride salt aqueous solution is electrolyzed to generate strong alkaline water and hypochlorous acid water, and the dilution water is used. Since the amount of strong alkaline water and hypochlorous acid water is increased by mixing, a relatively small capacity of the electrolytic cell is sufficient, and the cost can be reduced. Further, the pH and concentration can be finely adjusted by adjusting the mixing of the dilution water. Further, since the high-concentration aqueous solution is electrolyzed, the conductivity is increased, and the electrolysis efficiency is significantly improved.

【0066】また、従来、ドレンへ捨てていた水を利用
してpH、濃度等を調整できるので無駄水が少なくな
り、pH、濃度の調整が一層容易になる。
Further, since the pH, concentration, etc. can be adjusted by using the water conventionally discarded to the drain, waste water is reduced, and the adjustment of pH, concentration is further facilitated.

【0067】余分の強酸性水は塩酸に還元されるので安
全である。
The extra strongly acidic water is safe because it is reduced to hydrochloric acid.

【0068】高濃度水溶液の電解と原水の全量電解に装
置を使い分けることができるので目的に応じた多様の利
用が可能になる。
Since the apparatus can be selectively used for electrolysis of a high-concentration aqueous solution and electrolysis of the entire amount of raw water, various uses can be made according to the purpose.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の実施例による装置の概略構成図FIG. 1 is a schematic configuration diagram of an apparatus according to an embodiment of the present invention.

【図2】本発明の他の実施例による装置の概略構成図FIG. 2 is a schematic configuration diagram of an apparatus according to another embodiment of the present invention.

【図3】本発明の他の実施例による装置の概略構成図FIG. 3 is a schematic configuration diagram of an apparatus according to another embodiment of the present invention.

【図4】本発明の他の実施例による装置の概略構成図FIG. 4 is a schematic configuration diagram of an apparatus according to another embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1…食器洗浄槽 2…洗浄・殺菌水調整装置 3…洗浄水供給手段 4…陰電極 5…陽電極 6…電解隔膜 7…陰極室 8…陽極室 9…有隔膜電解槽 10…給水管回路 11、11’…陰極室側排出路 12、12’…陽極室側排出路 13…原水給水本管 14…管路 15…タンク 16…タンク 17…管路 18…定量ポンプ 19…流量比率調整弁 20a、20b、20c…希釈水給水管 21、23…流量制御弁 22、24…フロースイッチ 25…強アルカリ水タンク 26…管路 27…ポンプ 28…ガス吸収槽 29…濃度検出装置 30…分岐排水管 31…切換弁 32、32a、32b、32c…還元装置 33…反応槽 34…触媒 35…水素ガス供給管 36…水素ガス分離部 37…ポンプ 38…貯水槽 39…紫外線灯 40…触媒 41…紫外線照射装置 42…循環路 43…給水パイプ 44…ガス抜き装置 45…水位センサ 46…還元剤水溶液 47…排水管 48…切換弁 49…管路 50…流量制御弁 51…フロースイッチ 52…無隔膜電解槽 53…給水管 54…電解水排出管 55…無隔膜電解整水装置 56…pH・濃度調整管 57…切換弁 58、59…原水給水管 60〜64…開閉制御弁機構 65、66…フロースイッチ 67、69…切換弁 68…合流管路 70…ドレン 71…排水管路 72…流路切換装置 73…強酸性水タンク 74…強アルカリ水タンク 75…次亜塩素酸水タンク 76…強酸性水タンク 77、78、79…供給管路 80…食器 81…搬送手段 82、83、84…噴射ノズル 85…強アルカリ水受槽 86…強酸性水受槽 87…次亜塩素酸水受槽 88…合流槽 89…ドレン 90…循環路 91…ノズル 92…管路 93…加熱部 DESCRIPTION OF SYMBOLS 1 ... Dishwashing tank 2 ... Washing / sterilization water adjustment apparatus 3 ... Washing water supply means 4 ... Negative electrode 5 ... Positive electrode 6 ... Electrolytic membrane 7 ... Cathode chamber 8 ... Anode chamber 9 ... Separated membrane electrolytic tank 10 ... 11, 11 '... Cathode chamber side discharge path 12, 12' ... Anode chamber side discharge path 13 ... Raw water supply main pipe 14 ... Pipe line 15 ... Tank 16 ... Tank 17 ... Pipe line 18 ... Metering pump 19 ... Flow rate ratio regulating valve 20a, 20b, 20c: Dilution water supply pipe 21, 23 ... Flow control valve 22, 24 ... Flow switch 25 ... Strong alkaline water tank 26 ... Pipe line 27 ... Pump 28 ... Gas absorption tank 29 ... Concentration detection device 30 ... Branch drainage Pipe 31 ... Switching valve 32, 32a, 32b, 32c ... Reducing device 33 ... Reaction tank 34 ... Catalyst 35 ... Hydrogen gas supply pipe 36 ... Hydrogen gas separation unit 37 ... Pump 38 ... Water tank 39 ... Ultraviolet light 40 ... Catalyst 41 ... External line irradiation device 42 ... Circulation path 43 ... Water supply pipe 44 ... Degassing device 45 ... Water level sensor 46 ... Reducing agent aqueous solution 47 ... Drain pipe 48 ... Switching valve 49 ... Pipe line 50 ... Flow control valve 51 ... Flow switch 52 ... No diaphragm Electrolyzer 53 ... Water supply pipe 54 ... Electrolyzed water discharge pipe 55 ... Non-diaphragm electrolytic water conditioning apparatus 56 ... pH / concentration adjustment pipe 57 ... Switching valve 58, 59 ... Raw water supply pipe 60-64 ... Opening / closing control valve mechanism 65, 66 ... Flow switches 67, 69 Switch valve 68 Merging line 70 Drain 71 Drainage line 72 Flow path switching device 73 Strong acid water tank 74 Strong alkaline water tank 75 Hypochlorous acid water tank 76 Strong acid Aqueous water tank 77, 78, 79 ... supply line 80 ... tableware 81 ... conveying means 82, 83, 84 ... injection nozzle 85 ... strong alkaline water receiving tank 86 ... strong acidic water receiving tank 87 ... hypochlorous acid water Bath 88 ... merging tank 89 ... Drain 90 ... circulation path 91 ... nozzle 92 ... conduit 93 ... heating section

Claims (9)

【特許請求の範囲】[Claims] 【請求項1】塩化物塩水溶液を有隔膜電解槽で電解して
pH1〜3.5の強酸性水と強アルカリ水とを生成し、
前記強アルカリ水を水で希釈してpH10.5〜13.
5の強アルカリ水に調整するとともに、前記強酸性水を
水で希釈してpH4〜8の次亜塩素酸殺菌水に調整し、
前記pH10.5〜13.5の強アルカリ水で食器類を
洗浄した後、該食器類を前記次亜塩素酸殺菌水で殺菌す
ることを特徴とする食器類の洗浄・殺菌方法
1. An electrolysis of a chloride salt aqueous solution in a diaphragm electrolyzer to produce strongly acidic water and strongly alkaline water having a pH of 1 to 3.5,
The strong alkaline water is diluted with water to have a pH of 10.5 to 13.
While adjusting to 5 strong alkaline water, the strong acid water is diluted with water to adjust to pH 4 to 8 hypochlorous acid sterilized water,
A method for washing and sterilizing tableware, comprising washing tableware with the strong alkaline water having a pH of 10.5 to 13.5 and then sterilizing the tableware with the hypochlorite sterilized water.
【請求項2】塩化物塩水溶液を有隔膜電解槽で電解して
pH1〜3.5の強酸性水と強アルカリ水を生成し、前
記強アルカリ水を水で希釈してpH10.5〜13.5
の強アルカリ水に調整するとともに、他方、塩化物塩水
溶液を無隔膜電解槽で電解した電解処理水又はその希釈
水溶液を前記有隔膜電解により生成した強酸性水と混合
してpH4〜8の次亜塩素酸殺菌水に調整し、前記pH
10.5〜13.5の強アルカリ水で食器類を洗浄した
後、該食器類を前記次亜塩素酸殺菌水で殺菌することを
特徴とする食器類の洗浄・殺菌方法
2. An aqueous solution of a chloride salt is electrolyzed in a diaphragm electrolyzer to produce strongly acidic water and strongly alkaline water having a pH of 1 to 3.5, and the strongly alkaline water is diluted with water to have a pH of 10.5 to 13. .5
And an aqueous electrolyzed chloride salt solution in a non-diaphragm electrolytic cell or a dilute aqueous solution thereof mixed with the strongly acidic water generated by the electrolysis with a diaphragm to adjust the pH to 4-8. Adjust to chlorite sterilized water and adjust the pH
A method for washing and sterilizing tableware, comprising washing tableware with strongly alkaline water of 10.5-13.5, and then sterilizing the tableware with the hypochlorous acid sterilized water.
【請求項3】塩化物塩水溶液を有隔膜電解槽で電解して
pH10.5〜13.5の強アルカリ水とpH1〜3.
5の強酸性水に調整するとともに、前記pH1〜3.5
の強酸性水又は前記pH1〜3.5の強酸性水と塩化物
塩水溶液の混合水を無隔膜電解槽で電解してpH4〜8
の次亜塩素酸殺菌水に調整し、前記pH10.5〜1
3.5の強アルカリ水で食器類を洗浄した後、該食器類
を前記次亜塩素酸殺菌水で殺菌することを特徴とする食
器類の洗浄・殺菌方法
3. An aqueous chloride salt solution is electrolyzed in a diaphragm electrolyzer to form a strong alkaline water having a pH of 10.5 to 13.5 and a pH of 1 to 3.
5 and a pH of 1 to 3.5.
Of strongly acidic water or a mixture of strongly acidic water having a pH of 1 to 3.5 and an aqueous solution of a chloride salt in a non-diaphragm electrolytic cell to have a pH of 4 to 8
Adjusted to the hypochlorous acid sterilized water, and the pH of 10.5 to 1
A method of washing and sterilizing tableware, comprising washing dishes with strongly alkaline water of 3.5, and then sterilizing the tableware with the hypochlorous acid sterilized water.
【請求項4】有隔膜電解槽で電解したpH1〜3.5の
強酸性水の一部を、前記食器洗浄に供した強アルカリ水
の中和及び/又は強アルカリ水洗浄後に食器に付着した
カルシウム及び渋の溶解除去に使用することをさらに特
徴とする請求項1、2又は3記載の食器類の洗浄・殺菌
方法
4. A part of strongly acidic water having a pH of 1 to 3.5 electrolyzed in a diaphragm electrolyzer adheres to dishes after neutralization of strong alkaline water and / or washing with strong alkaline water used for washing the dishes. 4. The method for washing and sterilizing tableware according to claim 1, further comprising dissolving and removing calcium and astringent.
【請求項5】pH10.5〜13.5の強アルカリ水と
pH4〜8の次亜塩素酸殺菌水を同時に生成する洗浄水
調整装置と、この洗浄水調整装置で生成した前記強アル
カリ水と次亜塩素酸水を各別に給水する洗浄水供給管路
と、各々の洗浄水供給管路に通ずるノズルを備えた食器
洗浄槽と、を具備し、前記洗浄水調整装置が、電解隔膜
を介して陰極室と陽極室に仕切った有隔膜電解槽の一側
に塩化物塩水溶液の給水管回路を有するとともに、他側
に陰極室側排出管と陽極室側排出管を有し、給水管回路
から供給される塩化物塩水溶液を電解して陰極室側排出
管から強アルカリ水を排出し、陽極室側排出管から次亜
塩素酸と塩素ガスを含む強酸性水を排出する有隔膜電解
整水装置と;陰極室側排出管の強アルカリ水に原水を供
給して希釈する希釈水給水管と;陽極室側排出管に原水
を供給して希釈する希釈水供給管と;を具備することを
特徴とする食器類の洗浄・殺菌装置
5. A washing water adjusting device for simultaneously producing a strong alkaline water having a pH of 10.5 to 13.5 and a hypochlorous acid sterilizing water having a pH of 4 to 8, and the strong alkaline water produced by the washing water adjusting device. A washing water supply line for separately supplying hypochlorous acid water, and a dishwashing tank provided with a nozzle communicating with each washing water supply line, and the washing water adjusting device is provided through an electrolytic diaphragm. A water supply pipe circuit for a chloride salt aqueous solution is provided on one side of the diaphragm electrolytic cell partitioned into a cathode compartment and an anode compartment, and a cathode compartment side discharge pipe and an anode compartment side discharge pipe are provided on the other side. Electrolytes the chloride salt solution supplied from the furnace and discharges strongly alkaline water from the discharge pipe on the cathode chamber side, and discharges strongly acidic water containing hypochlorous acid and chlorine gas from the discharge pipe on the anode chamber side. A water device; a diluent for supplying and diluting raw water to strong alkaline water in the cathode chamber side discharge pipe Water supply pipe and; cleaning and sterilizing apparatus for tableware, characterized by comprising; a diluting water supply pipe for dilution by supplying raw water to the anode chamber side exhaust pipe
【請求項6】pH10.5〜13.5の強アルカリ水と
pH4〜8の次亜塩素酸殺菌水を同時に生成する洗浄水
調整装置と、この洗浄水調整装置で生成した前記強アル
カリ水と次亜塩素酸水を各別に給水する洗浄水供給管路
と、各々の洗浄水供給管路に通ずるノズルを備えた食器
洗浄槽を具備し、前記洗浄水調整装置が、電解隔膜を介
して陰極室と陽極室に仕切った有隔膜電解槽の一側に塩
化物塩水溶液の給水管回路を有するとともに、他側に陰
極室側排出管と陽極室側排出管を有し、給水管回路から
供給される塩化物塩水溶液を電解して陰極室側排出管か
ら強アルカリ水を排出し、陽極室側排出管から次亜塩素
酸と塩素ガスを含む強酸性水を排出する有隔膜電解整水
装置と;陰極室側排出管の強アルカリ水に原水を供給し
て希釈する希釈水給水管と;無隔膜電解槽の一側に塩化
物塩水溶液の給水管を有し、この給水管から供給される
塩化物塩水溶液を電解して排出管から排水する無隔膜電
解整水装置と;前記有隔膜電解整水装置の陽極室側排水
回路から前記無隔膜電解整水装置の水回路に接続され、
有隔膜電解槽から生成される強酸性水の一部を、無隔膜
電解整水装置の排水回路又は給水回路に供給してpH及
び次亜塩素酸濃度を調整するpH・濃度調整管路とを具
備することを特徴とする食器類の洗浄・殺菌装置
6. A washing water adjusting device for simultaneously producing a strong alkaline water having a pH of 10.5 to 13.5 and a hypochlorous acid sterilizing water having a pH of 4 to 8, and the strong alkaline water generated by the washing water adjusting device. A washing water supply pipe for separately supplying hypochlorous acid water, and a dishwashing tank provided with a nozzle communicating with each washing water supply pipe, wherein the washing water adjusting device is provided with a cathode through an electrolytic diaphragm. A water supply pipe circuit for the aqueous solution of chloride salt is provided on one side of the diaphragm cell separated into a chamber and an anode chamber, and a discharge pipe on the cathode chamber side and an anode chamber side discharge pipe are provided on the other side. Electrolyzed chloride salt solution to discharge strong alkaline water from the discharge pipe on the cathode chamber side and discharge strong acid water containing hypochlorous acid and chlorine gas from the discharge pipe on the anode chamber side And dilution water for supplying and diluting raw water to the strong alkaline water in the discharge pipe on the cathode chamber side A water pipe; a non-diaphragm electrolysis water conditioning apparatus having a water supply pipe for a chloride salt aqueous solution on one side of a non-diaphragm electrolytic cell, electrolyzing a chloride salt aqueous solution supplied from the water supply pipe, and draining it from a discharge pipe; Connected to the water circuit of the diaphragmless electrolysis water conditioning device from the anode chamber side drainage circuit of the diaphragm electrolysis water conditioning device,
A part of strong acid water generated from the diaphragm electrolyzer is supplied to a drainage circuit or a water supply circuit of a non-diaphragm electrolyzer for adjusting pH and concentration of hypochlorous acid. Tableware washing / sterilizing apparatus characterized by comprising
【請求項7】pH10.5〜13.5の強アルカリ水と
pH4〜8の次亜塩素酸殺菌水を同時に生成する洗浄水
調整装置と、この洗浄水調整装置で生成した前記強アル
カリ水と次亜塩素酸水を各別に給水する洗浄水供給管路
と、各々の洗浄水供給管路に通ずるノズルを備えた食器
洗浄槽を具備し、前記洗浄水調整装置が、電解隔膜を介
して陰極室と陽極室に仕切った有隔膜電解槽の一側に塩
化物塩水溶液の給水管回路を有するとともに、他側に陰
極室側排出管と陽極室側排出管を有し、給水管回路から
供給される塩化物塩水溶液を電解して陰極室側排出管か
ら強アルカリ水を排出し、陽極室側排出管から次亜塩素
酸と塩素ガスを含む強酸性水を排出する有隔膜電解整水
装置と;この有隔膜電解整水装置で調整した強酸性水又
はこの強酸性水と塩化物塩水溶液の混合水を電解して次
亜塩素酸殺菌水を生成する無隔膜電解整水装置と;を具
備することを特徴とする食器の洗浄・殺菌装置
7. A washing water adjusting device for simultaneously producing a strong alkaline water having a pH of 10.5 to 13.5 and a hypochlorite disinfecting water having a pH of 4 to 8, and the strong alkaline water generated by the washing water adjusting device. A washing water supply pipe for separately supplying hypochlorous acid water, and a dishwashing tank provided with a nozzle communicating with each washing water supply pipe, wherein the washing water adjusting device is provided with a cathode through an electrolytic diaphragm. A water supply pipe circuit for the aqueous solution of chloride salt is provided on one side of the diaphragm cell separated into a chamber and an anode chamber, and a discharge pipe on the cathode chamber side and an anode chamber side discharge pipe are provided on the other side. Electrolyzed chloride salt solution to discharge strong alkaline water from the discharge pipe on the cathode chamber side and discharge strong acid water containing hypochlorous acid and chlorine gas from the discharge pipe on the anode chamber side And strongly acidic water prepared by this diaphragm electrolysis water conditioning apparatus or this strongly acidic water Cleaning and sterilizing apparatus for dishes, characterized by comprising; by electrolytic mixing water product salt solution and the diaphragm-free electrolytic water conditioner apparatus for generating hypochlorous acid sterilizing water
【請求項8】無隔膜電解槽の排水管に希釈水給水管を接
続したことをさらに特徴とする請求項6又は7記載の食
器類の洗浄・殺菌装置
8. The apparatus for cleaning and sterilizing tableware according to claim 6, wherein a dilution water supply pipe is connected to a drain pipe of the non-diaphragm electrolytic cell.
【請求項9】前記洗浄水調整装置が、有隔膜電解槽の陽
極室側排出管から分岐させた強酸性水分岐排水管を有す
るとともに、この分岐排水管と前記食器洗浄槽間に強酸
性水供給管路を設け、有隔膜電解槽の陽極室側排出管の
強酸性水の一部が前記食器洗浄槽に給水されるようにし
たことをさらに特徴とする請求項5、6、7又は8記載
の食器類の洗浄・殺菌装置
9. The washing water adjusting device has a strong acid water branch drain pipe branched from an anode chamber side discharge pipe of a diaphragm electrolyzer, and a strong acid water between the branch drain pipe and the dishwashing tank. The supply line is provided, and a part of the strongly acidic water in the discharge pipe on the anode chamber side of the diaphragm electrolytic cell is supplied to the dishwashing tank. Tableware cleaning and sterilizing equipment
JP9022197A 1997-01-21 1997-01-21 Method and device for washing and sterilizing dishes Pending JPH10201694A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9022197A JPH10201694A (en) 1997-01-21 1997-01-21 Method and device for washing and sterilizing dishes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9022197A JPH10201694A (en) 1997-01-21 1997-01-21 Method and device for washing and sterilizing dishes

Publications (1)

Publication Number Publication Date
JPH10201694A true JPH10201694A (en) 1998-08-04

Family

ID=12076078

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9022197A Pending JPH10201694A (en) 1997-01-21 1997-01-21 Method and device for washing and sterilizing dishes

Country Status (1)

Country Link
JP (1) JPH10201694A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003230524A (en) * 2002-02-07 2003-08-19 Sanyo Electric Co Ltd Dishwasher and washer
JP2011240318A (en) * 2010-05-21 2011-12-01 Sakura Seiki Kk Cleaning method and cleaning apparatus
WO2015094122A1 (en) * 2013-12-20 2015-06-25 K-One Industries Pte. Ltd. Industrial dishwasher
JP2015196152A (en) * 2014-04-02 2015-11-09 株式会社中西製作所 Nozzle pipe unit and cleaner using the same
JP2016101583A (en) * 2010-06-30 2016-06-02 エコラボ ユーエスエー インコーポレイティド Control system and method of use for controlling concentrations of electrolyzed water in cip applications
CN111164253A (en) * 2017-10-05 2020-05-15 伊莱克斯家用电器股份公司 Washing machine

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003230524A (en) * 2002-02-07 2003-08-19 Sanyo Electric Co Ltd Dishwasher and washer
JP2011240318A (en) * 2010-05-21 2011-12-01 Sakura Seiki Kk Cleaning method and cleaning apparatus
JP2016101583A (en) * 2010-06-30 2016-06-02 エコラボ ユーエスエー インコーポレイティド Control system and method of use for controlling concentrations of electrolyzed water in cip applications
WO2015094122A1 (en) * 2013-12-20 2015-06-25 K-One Industries Pte. Ltd. Industrial dishwasher
CN105979843A (en) * 2013-12-20 2016-09-28 K-One工业私人有限公司 Industrial dishwasher
EP3082553A4 (en) * 2013-12-20 2017-09-06 K-One Industries PTE. Ltd. Industrial dishwasher
JP2015196152A (en) * 2014-04-02 2015-11-09 株式会社中西製作所 Nozzle pipe unit and cleaner using the same
CN111164253A (en) * 2017-10-05 2020-05-15 伊莱克斯家用电器股份公司 Washing machine

Similar Documents

Publication Publication Date Title
US6357454B1 (en) Method for washing and sterilizing beer supply pipe
JPH10140384A (en) Device for simultaneously generating strongly alkaline water and hypochlorous acid sterilizing water by electrolysis
US20050126927A1 (en) Water supply system for an aircraft
EP1945575A1 (en) Electrolytic sterilizing apparatus for ship ballast water
KR20090052892A (en) Method of sterilization and sterilizer apparatus
KR102111199B1 (en) A washing method using the electrolyted water of nano bubble and apparatus thereof
KR101768458B1 (en) Hand Sterilizer of Electrolytic Water Disinfection
JP2007209859A (en) Wastewater treatment method and wastewater treatment equipment of medical purpose cleaning and sterilizing device
JPH10201694A (en) Method and device for washing and sterilizing dishes
KR101873940B1 (en) Sterilizing treatment-apparatus for storage reservoir
KR101371616B1 (en) Naocl dilution structure of generation-system for antiseptic solution including chlorine
JPH09299953A (en) Electrolytic water generator
JP2576033B2 (en) Endoscope cleaning method and apparatus
JPH1076270A (en) Method for simultaneous generation of strongly alkaline water and hypochlorous acid sterilizing water by electrolysis
JPH09173359A (en) Dental drainage and system for purifying piping for sucking drainage as well as method for purifying the same
JPH10182325A (en) Device for reinforcing sterilization powder of sodium hypochlorite
JP3747337B2 (en) Tableware cleaning and sterilization method and apparatus
JP3802888B2 (en) Electrolytic sterilization apparatus and method
JP3359661B2 (en) Method for cleaning / sterilizing a continuous electrolytic water regulator and an electrolytic water regulator provided with a mechanism for performing the method
KR100602058B1 (en) Electrolysis and electro-coagulation treatment apparatus of wastewater
CN217679447U (en) Integrated water tank
KR100922866B1 (en) Electrolysis method for water treatment
JP3733476B2 (en) Cleaning method for continuous electrolyzed water generating device and continuous electrolyzed water generating device provided with mechanism for carrying out this method
CN217679444U (en) Integrated water tank
CN215479921U (en) Water treatment equipment

Legal Events

Date Code Title Description
A521 Written amendment

Effective date: 20040217

Free format text: JAPANESE INTERMEDIATE CODE: A523

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040311

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20060516

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20061128