JPH0938191A - Antibacterial deodorizing sheet - Google Patents
Antibacterial deodorizing sheetInfo
- Publication number
- JPH0938191A JPH0938191A JP7195572A JP19557295A JPH0938191A JP H0938191 A JPH0938191 A JP H0938191A JP 7195572 A JP7195572 A JP 7195572A JP 19557295 A JP19557295 A JP 19557295A JP H0938191 A JPH0938191 A JP H0938191A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- titanium dioxide
- antibacterial
- antibacterial deodorizing
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 40
- 230000001877 deodorizing effect Effects 0.000 title claims abstract description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 84
- 239000012790 adhesive layer Substances 0.000 claims abstract description 12
- 239000002344 surface layer Substances 0.000 claims abstract description 12
- 239000004408 titanium dioxide Substances 0.000 claims description 40
- 239000002781 deodorant agent Substances 0.000 claims description 22
- 239000010409 thin film Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229920002050 silicone resin Polymers 0.000 claims description 4
- 238000010030 laminating Methods 0.000 claims description 2
- 238000007740 vapor deposition Methods 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 abstract description 11
- 244000005700 microbiome Species 0.000 abstract description 8
- 230000001699 photocatalysis Effects 0.000 abstract description 6
- 241000208125 Nicotiana Species 0.000 abstract description 3
- 235000002637 Nicotiana tabacum Nutrition 0.000 abstract description 3
- 239000000779 smoke Substances 0.000 abstract description 3
- 230000003292 diminished effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 10
- 239000010408 film Substances 0.000 description 9
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 239000004065 semiconductor Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 230000003287 optical effect Effects 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000011941 photocatalyst Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 239000010779 crude oil Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004332 deodorization Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000012784 inorganic fiber Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl Chemical compound [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
Description
【０００１】[0001]
【発明の技術分野】本発明は二酸化チタンの薄膜からな
る光触媒反応を利用した抗菌脱臭シートに関するもので
ある。TECHNICAL FIELD The present invention relates to an antibacterial deodorant sheet utilizing a photocatalytic reaction composed of a thin film of titanium dioxide.
【０００２】[0002]
【従来の技術】近年、二酸化チタンＴｉＯ2 に代表され
る光半導体の微粒子による光触媒作用、特にその強い酸
化触媒作用に高い注目が集められている。即ち、二酸化
チタン等の光半導性を有する粒子状物質をそのバンドキ
ャップエネルギ以上の光（二酸化チタンの場合は４００
ｎｍ以下の光、即ち、紫外線）で照射すると、価電子帯
の電子が光励起されて伝導帯に移り、伝導帯には自由電
子が生成すると共に、価電子帯には正の電荷を帯びた粒
子（正孔）が生成する。これらの正孔と電子とは半導体
粒子内部を運動し、時間の経過と共に再結合して消滅す
る。しかしその粒子表面に空気または水、或いはそれら
の正孔や電子よりもエネルギの低い空順位を有する化合
物やイオンが存在すると、その粒子表面を通してそれら
の正孔と電子が化合物やイオンに移動し、その結果、正
孔は粒子表面に接触する化合物やイオンを直接酸化し、
或いは活性酸素の１つである水酸基ラジカルを生成す
る。 2. Description of the Related Art In recent years, much attention has been paid to the photocatalytic action of fine particles of an optical semiconductor represented by titanium dioxide TiO 2 , and particularly to its strong oxidation catalytic action. That is, a particulate matter having a light semiconducting property such as titanium dioxide is converted into light having a band cap energy equal to or more than that (in the case of titanium dioxide,
When irradiated with light having a wavelength of nm or less, that is, ultraviolet rays, electrons in the valence band are photoexcited and move to the conduction band, free electrons are generated in the conduction band, and particles having a positive charge in the valence band. (Hole) is generated. These holes and electrons move inside the semiconductor particles and recombine with time to disappear. However, if air or water, or a compound or ion having a lower vacancy than the holes or electrons exists on the particle surface, those holes and electrons move to the compound or ion through the particle surface, As a result, the holes directly oxidize compounds and ions that come into contact with the particle surface,
Alternatively, a hydroxyl radical, which is one of active oxygen, is generated.
【０００３】また、電子による還元反応は主に酸素の還
元であり、電子が付加された酸化性のある酸素種が生成
される。こうして、光半導体微粒子は光が照射されるこ
とによって酸化性の活性表面を形成し、有機化合物の分
解等に触媒として作用する（「季刊 化学総説 『光が
関わる触媒化学』Ｎｏ．２３，１９９４）。このような
光半導体微粒子による酸化触媒作用は、光半導体の中で
も二酸化チタンが特に高い。また、二酸化チタンは安定
性や安全性にも優れている。そして、この二酸化チタン
の微粉末を薄膜として基体表面に担持して光触媒を形成
し、紫外線照射時のその高い酸化力を有機化合物等の分
解に利用した種々の応用が既に知られている。Further, the reduction reaction by electrons is mainly reduction of oxygen, and oxidative oxygen species to which electrons are added are generated. In this way, the photo-semiconductor fine particles form an oxidative active surface when irradiated with light, and act as a catalyst for decomposition of organic compounds, etc. Among the optical semiconductors, titanium dioxide is particularly high in the oxidation catalytic action by such optical semiconductor fine particles, and titanium dioxide is also excellent in stability and safety. Various applications have already been known in which a photocatalyst is formed by supporting it on the surface of a substrate, and its high oxidizing power during irradiation of ultraviolet rays is utilized for decomposing organic compounds and the like.
【０００４】例えば、二酸化チタンの薄膜からなる光触
媒をコーティングした中空のガラスビーズは海上に流出
した原油の分解剤として知られている。すなわち、ガラ
スビーズ表面に付着した原油は太陽光中の紫外線によっ
て活性化された二酸化チタンの強い酸化触媒作用によっ
て分解される。また最近では、室内空気の脱臭または消
臭、殺菌（抗菌）、タバコのヤニや油膜等の汚れの分解
にもその応用が試みられ、自然光または蛍光灯の光に含
まれる紫外線を利用してその光触媒を活性化させ、それ
の酸触媒反応によって接触するメルカブタン等の臭気化
合物、或いはタバコのヤニ等の有機物を分解し、また
は、細菌等の微生物を死滅させ、またはその繁殖を抑え
るものである。For example, hollow glass beads coated with a photocatalyst consisting of a thin film of titanium dioxide are known as a decomposing agent for crude oil that has flowed out to the sea. That is, the crude oil attached to the surface of the glass beads is decomposed by the strong oxidation catalytic action of titanium dioxide activated by ultraviolet rays in sunlight. Recently, its application has been tried for deodorization or deodorization of indoor air, sterilization (antibacterial), and decomposition of stains such as tars and oil slicks of cigarettes, using ultraviolet light contained in natural light or fluorescent light. It activates a photocatalyst and decomposes an odorous compound such as mercaptan or an organic substance such as tobacco tar that is brought into contact by its acid-catalyzed reaction, or kills microorganisms such as bacteria, or suppresses the growth thereof.
【０００５】[0005]
【発明が解決しようとする課題】空調が一般化したこと
もあり、事務所、公共施設さらには個人住宅においても
外気から隔離された空間が増えている。このような隔離
された空間では、空気の入れ替えが少なく、煙草の煙、
食物の臭気等が壁等に付着して残ったり、湿気のあると
ころで黴が発生したりする。With the generalization of air conditioning, offices, public facilities, and even private houses are increasing in space isolated from the outside air. In such an isolated space, there is little replacement of air, tobacco smoke,
The odor of food adheres to and remains on walls, etc., and mold develops in humid places.
【０００６】本発明はかかる不都合を解消するもので、
手軽に利用できかつ空気の浄化、黴等の微生物の繁殖を
抑える二酸化チタンの光触媒作用を利用した抗菌脱臭シ
ートを提供するものである。The present invention eliminates such inconveniences.
The present invention provides an antibacterial deodorizing sheet that can be easily used and uses the photocatalytic action of titanium dioxide that suppresses the purification of air and the growth of microorganisms such as mold.
【０００７】[0007]
【課題を解決するための手段】本発明の抗菌脱臭シート
は、表面に二酸化チタンが表出したシート本体と、該シ
ート本体の裏面に積層された粘着層と、を具備すること
を特徴とする。本発明の抗菌脱臭シートは、紫外線照射
を受ける炊事場、風呂場、洗面所等の壁とか、家具に張
り付け、周囲の空気を浄化するとともに、黴等の発生を
抑えるものである。The antibacterial deodorizing sheet of the present invention comprises a sheet body having titanium dioxide exposed on the surface and an adhesive layer laminated on the back surface of the sheet body. . The antibacterial deodorant sheet of the present invention is attached to a wall of a kitchen, a bathroom, a washroom, or the like that is irradiated with ultraviolet rays, or furniture to purify the surrounding air and suppress the generation of mold and the like.
【０００８】本発明の抗菌脱臭シートは、シート本体と
粘着層とで構成されている。シート本体はその表面に二
酸化チタンが表出している。二酸化チタンは強力な酸化
触媒として機能する。このため二酸化チタンの近くにあ
る有機物は強力な酸化作用を被る。この二酸化チタンに
よる酸化作用に耐えるため、二酸化チタンを保持結合す
るマトリックス、バインダーは高耐酸化性の物質である
ことが望ましい。かかる見地から、二酸化チタンを保持
する物質としては、フッ素樹脂、シリコン樹脂等の合成
樹脂、シリケート、フォスフェート等の無機接着剤が好
ましい。従って、シート本体を二酸化チタンが混入され
たフッ素樹脂、シリコン樹脂等の合成樹脂、シリケー
ト、フォスフェート等の無機接着剤で構成するのが好ま
しい。The antibacterial deodorant sheet of the present invention comprises a sheet body and an adhesive layer. Titanium dioxide is exposed on the surface of the sheet body. Titanium dioxide acts as a strong oxidation catalyst. For this reason, organic substances in the vicinity of titanium dioxide undergo a strong oxidizing action. In order to withstand the oxidizing action of titanium dioxide, it is desirable that the matrix and binder that holds titanium dioxide to be a binder be a material having high oxidation resistance. From this point of view, as the substance that holds titanium dioxide, synthetic resins such as fluororesins and silicone resins, and inorganic adhesives such as silicates and phosphates are preferable. Therefore, it is preferable that the sheet main body is made of a synthetic resin such as fluororesin or silicon resin mixed with titanium dioxide, or an inorganic adhesive such as silicate or phosphate.
【０００９】抗菌脱臭機能を期待するのはシート本体の
表面のみであることを考慮すると、シート本体を基材シ
ートとこの基材シートの表面に積層される二酸化チタン
の粉末を含むシリコン樹脂あるいはフッ素樹脂さらには
無機物の表層とから構成することも可能である。この場
合には、基材シートには二酸化チタンの強い酸化作用が
作用しない。このため基材シートとして通常のシート材
として知られている、ポリエステルフィルム、塩化ビニ
ルフィルム、ポリオレフィンフィルム等の通常のフィル
ムを採用できる。Considering that the antibacterial deodorizing function is expected only on the surface of the sheet body, the sheet body is formed of a base sheet and a silicone resin or a fluorine containing titanium dioxide powder laminated on the surface of the base sheet. It is also possible to comprise a resin and a surface layer of an inorganic material. In this case, the strong oxidizing action of titanium dioxide does not act on the base sheet. Therefore, as the base sheet, a normal film known as a normal sheet material such as a polyester film, a vinyl chloride film, or a polyolefin film can be adopted.
【００１０】表層は、二酸化チタンの粉末を練り混んだ
フッ素樹脂、シリコン樹脂等の合成樹脂で、基材シート
の表面に一体的に薄い層として形成できる。また、基材
シートの上に、二酸化チタンの粉末を無機バインダーで
固定したものでも良い。二酸化チタンは物理的蒸着法あ
るいは化学的蒸着法で薄いフィルム状とすることができ
る。かかる場合には、バインダーを必要としない。しか
し、二酸化チタンの蒸着膜を保持する基材シートには高
い耐酸化性を必要とする。このような場合には、基材シ
ートをフッ素樹脂あるいはシリコン樹脂で形成し、その
表面に二酸化チタンの蒸着膜を形成することによりシー
ト本体を得ることができる。また、特に強い耐酸化性を
必要とする場合には、ガラス繊維等の無機繊維で編んだ
り織ったりした無機繊維布を基材シートとして使用でき
る。この基材シートに二酸化チタンの蒸着膜とか二酸化
チタンの粉末を練り混んだフッ素樹脂、シリコン樹脂の
表層を形成することにより、シート本体を得ることがで
きる。The surface layer is made of a synthetic resin such as fluororesin or silicon resin in which titanium dioxide powder is kneaded and can be formed as a thin layer integrally on the surface of the base sheet. Alternatively, titanium dioxide powder may be fixed on the base sheet with an inorganic binder. Titanium dioxide can be formed into a thin film by physical vapor deposition or chemical vapor deposition. In such a case, no binder is needed. However, a base sheet holding a vapor deposited film of titanium dioxide requires high oxidation resistance. In such a case, the sheet body can be obtained by forming the base material sheet with a fluororesin or a silicone resin and forming a vapor deposition film of titanium dioxide on the surface thereof. When particularly strong oxidation resistance is required, an inorganic fiber cloth knitted or woven with inorganic fibers such as glass fibers can be used as the base sheet. A sheet body can be obtained by forming a vapor-deposited film of titanium dioxide or a surface layer of fluororesin or silicon resin in which titanium dioxide powder is kneaded and mixed on this base sheet.
【００１１】粘着層はシート本体の裏面に設けられるも
のである。粘着層としては、従来より知られている粘着
物質で粘着層を形成できる。具体的には、未加硫のゴム
材料、熱可塑性エラストマー、酢酸ビニル樹脂等で粘着
層を形成できる。なお、使用していない時の粘着層の機
能を抑えるために、粘着層に離型紙を張り付け、使用時
に離型紙を分離して本発明の抗菌脱臭シートを所定表面
に粘着させるのが好ましい。The adhesive layer is provided on the back surface of the sheet body. As the adhesive layer, the adhesive layer can be formed of a conventionally known adhesive substance. Specifically, the adhesive layer can be formed of an unvulcanized rubber material, thermoplastic elastomer, vinyl acetate resin, or the like. In order to suppress the function of the pressure-sensitive adhesive layer when not in use, it is preferable that a release paper is attached to the pressure-sensitive adhesive layer and the release paper is separated at the time of use to adhere the antibacterial deodorant sheet of the present invention to a predetermined surface.
【００１２】なお二酸化チタンはその粒子径が十分に小
さいほど「量子サイズ効果」等によって光触媒作用が高
い。そのため、二酸化チタンはコロイド状とするのがこ
のましい。そして二酸化チタンは、一般に０．３μｍ以
下、好ましくは０．２μｍ以下の膜厚の透明な薄膜とし
て、またはそのような薄膜を多層化した薄膜として形成
するのが好ましい。また、物理的蒸着法（ＰＶＤ）や化
学的蒸着法（ＣＶＤ）等の方法によって形成することも
できる。The smaller the particle size of titanium dioxide, the higher the photocatalytic action due to the "quantum size effect" and the like. Therefore, it is preferable to make titanium dioxide in a colloidal form. Titanium dioxide is preferably formed as a transparent thin film having a thickness of generally 0.3 μm or less, preferably 0.2 μm or less, or as a thin film obtained by laminating such a thin film. It can also be formed by a method such as physical vapor deposition (PVD) or chemical vapor deposition (CVD).
【００１３】本発明の抗菌脱臭シートを有効に機能させ
るためには、紫外線を必要とする。太陽光線中にも本発
明の抗菌脱臭シートに有効な紫外線が含まれている。ま
た、紫外線を放射する殺菌灯のような蛍光灯にも紫外線
が含まれている。また、最近開発された発光ダイオード
にも紫外線を照射するものもある。例えば、ｐｎ接合さ
れた窒化ガリウム（ＧａＮ）系光半導体の結晶体で構成
した発光ダイオードは、波長３６０〜４００ｎｍの光
（電磁波）、即ち、紫外線を放射する。したがって、他
に適当な紫外線光源存在しない場合、ｐｎ接合された窒
化ガリウム（ＧａＮ）系光半導体の結晶体で構成した発
光ダイオードを使用することができる。Ultraviolet rays are required for the antibacterial deodorant sheet of the present invention to function effectively. The sun rays also contain ultraviolet rays effective for the antibacterial deodorant sheet of the present invention. Further, a fluorescent lamp such as a germicidal lamp that emits ultraviolet rays also contains ultraviolet rays. In addition, there are some recently developed light emitting diodes that irradiate with ultraviolet rays. For example, a light emitting diode made of a pn-junction gallium nitride (GaN) optical semiconductor crystal emits light (electromagnetic waves) having a wavelength of 360 to 400 nm, that is, ultraviolet rays. Therefore, when there is no other suitable ultraviolet light source, a light emitting diode composed of a pn-junction gallium nitride (GaN) -based optical semiconductor crystal can be used.
【００１４】本発明の抗菌脱臭シートは部屋の壁、家具
の表面、扇風機のファンの表面等に張りつけて使用する
ことができる。The antibacterial deodorizing sheet of the present invention can be used by being attached to a wall of a room, a surface of furniture, a surface of a fan of a fan, or the like.
【００１５】[0015]
【作用】本発明の抗菌脱臭シートは、手軽に壁、家具等
に張りつけて使用できる。そして紫外線の照射を受けて
強力な酸化作用をする。このため空気中に含まれている
臭い成分、煙草等の煙成分を分解除去する。また、強い
酸化作用により微生物の活動を抑える。このため本発明
の抗菌脱臭シートが張りつけられた所は悪臭が無くな
り、空気が浄化され、付近の微生物も少なくなる。The function of the antibacterial deodorant sheet of the present invention can be easily applied to a wall, furniture or the like. Then, it is irradiated with ultraviolet rays and has a strong oxidizing action. Therefore, odorous components and smoke components such as cigarettes contained in the air are decomposed and removed. In addition, it suppresses the activity of microorganisms due to its strong oxidizing action. Therefore, the place where the antibacterial deodorizing sheet of the present invention is attached has no bad odor, the air is purified, and the microorganisms in the vicinity are reduced.
【００１６】[0016]
【実施例】以下、本発明の実施例を説明する。 （第一実施例）図１は本発明の第一実施例の抗菌脱臭シ
ートの断面を示す。この抗菌脱臭シートは、フッ素樹脂
フィルム出形成された基材シート１と、フッ素樹脂エマ
ルジョンに二酸化チタン粉末を混合し、基材シート１の
表面に塗布、乾燥して形成した表層２と、基材シート１
の裏面に設けられた未加硫ゴムからなる粘着層３とで構
成されている。基材シート１と表層２シート本体１０が
形成される。Embodiments of the present invention will be described below. (First Embodiment) FIG. 1 shows a cross section of an antibacterial deodorant sheet according to a first embodiment of the present invention. This antibacterial deodorant sheet is composed of a base material sheet 1 formed with a fluororesin film, a surface layer 2 formed by mixing a fluororesin emulsion with titanium dioxide powder, coating the surface of the base material sheet 1, and drying the mixture. Sheet 1
And an adhesive layer 3 made of unvulcanized rubber provided on the back surface of the. The base sheet 1 and the surface layer 2 sheet body 10 are formed.
【００１７】この抗菌脱臭シートは表層２に含まれる二
酸化チタンの光触媒作用により、抗菌および脱臭機能を
もつ。また、基材シート１を採用しているため機械的強
度が高く、破損しにくいため使用に便利である。 （第二実施例）図２は本発明の第二実施例の抗菌脱臭シ
ートの断面を示す。この抗菌脱臭シートは、フッ素樹脂
フィルム出形成された基材シート１および基材シート１
の表面に物理的蒸着法により形成された二酸化チタンの
薄膜５で形成されたシート本体１０と、基材シート１の
裏面に設けられた未加硫ゴムからなる粘着層３とで構成
されている。This antibacterial deodorizing sheet has antibacterial and deodorizing functions by the photocatalytic action of titanium dioxide contained in the surface layer 2. Further, since the base material sheet 1 is adopted, it has high mechanical strength and is not easily damaged, which is convenient for use. (Second Embodiment) FIG. 2 shows a cross section of an antibacterial deodorant sheet according to a second embodiment of the present invention. This antibacterial deodorant sheet is composed of a base sheet 1 and a base sheet 1 on which a fluororesin film is formed.
A sheet body 10 formed of a titanium dioxide thin film 5 formed on the surface of the base material by a physical vapor deposition method, and an adhesive layer 3 made of unvulcanized rubber provided on the back surface of the base material sheet 1. .
【００１８】この抗菌脱臭シートは表層２の二酸化チタ
ン薄膜の光触媒作用により、抗菌および脱臭機能をも
つ。表層２が二酸化チタン薄膜からなる蒸着膜であるた
め、光沢に富む綺麗な表面を持ち、装飾的効果もある。 （第三実施例）図３は本発明の第三実施例の抗菌脱臭シ
ートの断面を示す。この抗菌脱臭シートは、フッ素樹脂
エマルジョンに二酸化チタン粉末を混合して厚く成形し
て形成したシート本体１０と、シート本体１０の裏面に
設けられた未加硫ゴムからなる粘着層３とで構成されて
いる。This antibacterial deodorizing sheet has antibacterial and deodorizing functions by the photocatalytic action of the titanium dioxide thin film of the surface layer 2. Since the surface layer 2 is a vapor-deposited film made of a titanium dioxide thin film, it has a beautiful glossy surface and also has a decorative effect. (Third Embodiment) FIG. 3 shows a cross section of an antibacterial deodorant sheet according to a third embodiment of the present invention. This antibacterial deodorant sheet is composed of a sheet body 10 formed by mixing titanium dioxide powder into a fluororesin emulsion to form a thick body, and an adhesive layer 3 made of unvulcanized rubber provided on the back surface of the sheet body 10. ing.
【００１９】この抗菌脱臭シートは実施例１の抗菌脱臭
シートよりシートとしての性能は低いが、抗菌および脱
臭機能については同じように高い性能をもつ。Although this antibacterial deodorant sheet has lower performance as a sheet than the antibacterial deodorant sheet of Example 1, it has similarly high antibacterial and deodorant functions.
【００２０】[0020]
【発明の効果】本発明の抗菌脱臭シートは貼付して紫外
線に当てるだけで強い酸化作用をする。このためこの抗
菌脱臭シートが貼付された所は、空気が浄化され、付近
の微生物の活動を抑制する。このため環境が良くなる。The antibacterial deodorant sheet of the present invention has a strong oxidizing action only by being attached and exposed to ultraviolet rays. Therefore, air is purified at the place where this antibacterial deodorizing sheet is attached, and the activity of microorganisms in the vicinity is suppressed. This improves the environment.
【図１】 図１は本発明の第一実施例の抗菌脱臭シート
の断面図である。FIG. 1 is a sectional view of an antibacterial deodorizing sheet according to a first embodiment of the present invention.
【図２】 図２は本発明の第二実施例の抗菌脱臭シート
の断面図である。FIG. 2 is a sectional view of an antibacterial deodorant sheet according to a second embodiment of the present invention.
【図３】 図３は本発明の第三実施例の抗菌脱臭シート
の断面図である。FIG. 3 is a sectional view of an antibacterial deodorant sheet according to a third embodiment of the present invention.
１：基材シート ２：表層 ３：粘着層 ５：二酸化チタンの薄膜 １０：シート本体 1: Base material sheet 2: Surface layer 3: Adhesive layer 5: Titanium dioxide thin film 10: Sheet body
───────────────────────────────────────────────────── フロントページの続き (72)発明者 田牧 真人 愛知県西春日井郡春日町大字落合字長畑１ 番地 豊田合成株式会社内 (72)発明者 酒井 和宏 愛知県西春日井郡春日町大字落合字長畑１ 番地 豊田合成株式会社内 (72)発明者 山口 寿夫 愛知県西春日井郡春日町大字落合字長畑１ 番地 豊田合成株式会社内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Masato Tamaki 1 Ochiai, Nagahata, Kasuga-cho, Nishikasugai-gun, Aichi Toyoda Gosei Co., Ltd. Inside Toyoda Gosei Co., Ltd. (72) Inventor Toshio Yamaguchi No. 1 Nagahata, Ochiai, Kasuga-cho, Nishikasugai-gun, Aichi Prefecture Inside Toyoda Gosei Co., Ltd.
Claims (4)
と、 該シート本体の裏面に積層された粘着層と、 を具備することを特徴とする抗菌脱臭シート。1. An antibacterial deodorizing sheet, comprising: a sheet body having titanium dioxide exposed on the surface thereof; and an adhesive layer laminated on the back surface of the sheet body.
トの表面に積層された前記二酸化チタンの粉末を含むシ
リコン樹脂あるいはフッ素樹脂の表層とからなる請求項
１記載の抗菌脱臭シート。2. The antibacterial deodorant sheet according to claim 1, wherein the sheet body comprises a base sheet and a surface layer of a silicon resin or a fluororesin containing the powder of titanium dioxide laminated on the surface of the base sheet.
トの表面に積層された前記二酸化チタンの粉末を無機接
着剤で固めた表層とからなる請求項１記載の抗菌脱臭シ
ート。3. The antibacterial deodorant sheet according to claim 1, wherein the sheet body comprises a base sheet and a surface layer obtained by laminating the powder of titanium dioxide laminated on the surface of the base sheet with an inorganic adhesive.
ッ素樹脂で形成された基材シートと該基材シートの表面
に蒸着して形成された前記二酸化チタンの薄膜からなる
請求項１記載の抗菌脱臭シート。4. The antibacterial deodorant sheet according to claim 1, wherein the sheet body is composed of a base sheet made of a silicone resin or a fluororesin and a titanium dioxide thin film formed by vapor deposition on the surface of the base sheet. .
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7195572A JPH0938191A (en) | 1995-07-31 | 1995-07-31 | Antibacterial deodorizing sheet |
| US08/687,667 US5919422A (en) | 1995-07-28 | 1996-07-26 | Titanium dioxide photo-catalyzer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7195572A JPH0938191A (en) | 1995-07-31 | 1995-07-31 | Antibacterial deodorizing sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0938191A true JPH0938191A (en) | 1997-02-10 |
Family
ID=16343363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7195572A Withdrawn JPH0938191A (en) | 1995-07-28 | 1995-07-31 | Antibacterial deodorizing sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0938191A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09313887A (en) * | 1996-05-28 | 1997-12-09 | Agency Of Ind Science & Technol | Photocatalyst sheet |
| JPH10217383A (en) * | 1996-12-03 | 1998-08-18 | Achilles Corp | Decorative sheet and production thereof |
| JPH1110802A (en) * | 1997-06-26 | 1999-01-19 | Achilles Corp | Laminated sheet |
| JPH1176375A (en) * | 1997-09-12 | 1999-03-23 | Toto Ltd | Bathroom member, coating composition for bathroom member and sheet for bathroom member |
| JP2000320026A (en) * | 1999-05-07 | 2000-11-21 | Ykk Architectural Products Inc | Gas adsorption panel for construction |
| JP2018044036A (en) * | 2016-09-12 | 2018-03-22 | 株式会社ニトムズ | Adhesive sheet |
| US10464055B2 (en) | 2014-03-11 | 2019-11-05 | Nitto Denko Corporation | Photocatalytic element |
| KR20210060785A (en) * | 2019-11-19 | 2021-05-27 | 고경찬 | Sheet with air purification function |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62164384U (en) * | 1986-04-09 | 1987-10-19 | ||
| JPS62166235U (en) * | 1986-04-10 | 1987-10-22 | ||
| JPH04284851A (en) * | 1991-03-14 | 1992-10-09 | Japan Storage Battery Co Ltd | Photo-catalyst body |
| JPH05253544A (en) * | 1992-03-13 | 1993-10-05 | Toto Ltd | Production of plate-shape member having deodorizing function |
| JPH07171408A (en) * | 1993-06-28 | 1995-07-11 | Ishihara Sangyo Kaisha Ltd | Photocatalytic body and its production |
-
1995
- 1995-07-31 JP JP7195572A patent/JPH0938191A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62164384U (en) * | 1986-04-09 | 1987-10-19 | ||
| JPS62166235U (en) * | 1986-04-10 | 1987-10-22 | ||
| JPH04284851A (en) * | 1991-03-14 | 1992-10-09 | Japan Storage Battery Co Ltd | Photo-catalyst body |
| JPH05253544A (en) * | 1992-03-13 | 1993-10-05 | Toto Ltd | Production of plate-shape member having deodorizing function |
| JPH07171408A (en) * | 1993-06-28 | 1995-07-11 | Ishihara Sangyo Kaisha Ltd | Photocatalytic body and its production |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09313887A (en) * | 1996-05-28 | 1997-12-09 | Agency Of Ind Science & Technol | Photocatalyst sheet |
| JPH10217383A (en) * | 1996-12-03 | 1998-08-18 | Achilles Corp | Decorative sheet and production thereof |
| JPH1110802A (en) * | 1997-06-26 | 1999-01-19 | Achilles Corp | Laminated sheet |
| JPH1176375A (en) * | 1997-09-12 | 1999-03-23 | Toto Ltd | Bathroom member, coating composition for bathroom member and sheet for bathroom member |
| JP2000320026A (en) * | 1999-05-07 | 2000-11-21 | Ykk Architectural Products Inc | Gas adsorption panel for construction |
| US10464055B2 (en) | 2014-03-11 | 2019-11-05 | Nitto Denko Corporation | Photocatalytic element |
| JP2018044036A (en) * | 2016-09-12 | 2018-03-22 | 株式会社ニトムズ | Adhesive sheet |
| KR20210060785A (en) * | 2019-11-19 | 2021-05-27 | 고경찬 | Sheet with air purification function |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4695700B2 (en) | Photocatalyst and method for producing the same | |
| JP2008229624A (en) | Photocatalytic composition | |
| JP3658800B2 (en) | Light emitting diode | |
| JPH09940A (en) | Photocatalytst device and its application device | |
| JPH0938191A (en) | Antibacterial deodorizing sheet | |
| JPH11267519A (en) | Photocatalyst powder for purifying environment, polymer composition containing the powder and its molding, and production of these | |
| JP3912806B2 (en) | Photocatalytic device | |
| JP3689939B2 (en) | Photocatalytic device | |
| JP4112661B2 (en) | Photocatalyst and its use | |
| JPH0938189A (en) | Fan having air cleaning function | |
| JP6328527B2 (en) | UV sterilizer | |
| JP4621859B2 (en) | Method for producing porous photocatalyst | |
| JPH10202110A (en) | Flexible photocatalyst body | |
| JP2006089858A (en) | Photocatalytic wallpaper and porous photocatalytic wallpaper derived from the same | |
| JP3674987B2 (en) | Antibacterial deodorization box | |
| JPH0938192A (en) | Air cleaner | |
| JPH09299456A (en) | Photocatalyst apparatus | |
| JP3952238B2 (en) | Removal method of harmful substances by photocatalyst | |
| US20100200891A1 (en) | Led structure | |
| JP2558923Y2 (en) | Deodorant toilet | |
| JP2000014607A (en) | Vacuum cleaner and its manufacture | |
| JPH10165812A (en) | Novel catalyst and material with addition of novel catalyst | |
| JP2000317312A (en) | Photocatalytic reaction method, data recording method and member such as filter or the like utilizing photocatalytic reaction | |
| JP4347925B2 (en) | Photocatalyst and method for producing the same | |
| JPH0938487A (en) | Air conditioner with air purifying function |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20040302 |
|
| A761 | Written withdrawal of application |
Free format text: JAPANESE INTERMEDIATE CODE: A761 Effective date: 20040326 |