JPH09297114A - Method of judging plastic material, and device therefor - Google Patents

Method of judging plastic material, and device therefor

Info

Publication number
JPH09297114A
JPH09297114A JP11339196A JP11339196A JPH09297114A JP H09297114 A JPH09297114 A JP H09297114A JP 11339196 A JP11339196 A JP 11339196A JP 11339196 A JP11339196 A JP 11339196A JP H09297114 A JPH09297114 A JP H09297114A
Authority
JP
Japan
Prior art keywords
plastic
temperature
measured
infrared
infrared ray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP11339196A
Other languages
Japanese (ja)
Inventor
Yuji Inagaki
裕治 稲垣
Naokazu Takeuchi
直和 竹内
Seiji Andou
精持 安藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP11339196A priority Critical patent/JPH09297114A/en
Publication of JPH09297114A publication Critical patent/JPH09297114A/en
Withdrawn legal-status Critical Current

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  • Investigating Or Analyzing Materials Using Thermal Means (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

PROBLEM TO BE SOLVED: To easily, quickly and continuously perform a material judgment by emitting an infrared ray to plastics, thereby causing a plastic surface temperature difference because the absorptivity of infrared ray is differed between materials, and measuring the temperature difference by a temperature measuring device. SOLUTION: An infrared ray emitting device 1 and a temperature measuring device 2 are arranged above a transfer device 3. A plastic 4 to be measured is placed on the transfer device 3 and transferred. A sorting device 6 is arranged on the downstream side of the transfer device 3. When the plastic 4 is passed through the infrared ray emitting zone by the infrared ray emitting device 1 for a fixed time, a fixed infrared ray is emitted thereto, and the plastic 4 shows a temperature rise according to the absorptivity of the respective materials by the natural infrared ray absorptivity. A judgment device 5 compares the measured temperature of the plastic 4 measured by the temperature measuring device 2 with a known data to judge the material of the plastic 4.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、プラスチック材質
判別法及びその装置に関する。詳しくは、清涼飲料水等
のプラスチックボトル、食品のプラスチック包装袋等の
各種のプラスチック廃棄物の処理或いはリサイクルを実
施するに当たり、プラスチック廃棄物を選別するのに好
適に使用できるプラスチックの材質判別方法及びその装
置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a plastic material discriminating method and its device. Specifically, when processing or recycling various plastic wastes such as plastic bottles such as soft drinks and plastic packaging bags for foods, etc. Regarding the device.

【0002】[0002]

【従来の技術】清涼飲料水等のプラスチックボトルや食
品のプラスチック包装包袋を始めとして、各種のプラス
チックが使用後ゴミとして大量に廃棄されている。近
年、世界的な環境問題と資源の有効利用の観点から、種
々の産業分野において、廃棄物等の再利用が望まれてい
る。
2. Description of the Related Art A large amount of various plastics such as soft drinks and other plastic bottles and food packaging bags are discarded as waste after use. In recent years, from the viewpoint of global environmental problems and effective use of resources, reuse of wastes and the like is desired in various industrial fields.

【0003】清涼飲料水等のプラスチックボトルでは、
ポリエチレンテレフタレート(以下PETと略す)製ボ
トルのリサイクルが事業化されつつある。廃PETボト
ルのリサイクルにおいては、異種材質ボトルの混在する
回収廃ボトルの中から、PETボトルを選別する技術が
重要である。
For plastic bottles such as soft drinks,
The recycling of bottles made of polyethylene terephthalate (hereinafter abbreviated as PET) is being commercialized. In the recycling of waste PET bottles, it is important to have a technique of selecting PET bottles from collected waste bottles in which different material bottles are mixed.

【0004】ボトル材質としては、PET以外には、ポ
リエチレン(以下PEと略す)、ポリプロピレン(以下
PPと略す)、ポリスチレン(以下PSと略す)、ポリ
塩化ビニル(以下PVCと略す)等がある。
Other than PET, bottle materials include polyethylene (hereinafter abbreviated as PE), polypropylene (hereinafter abbreviated as PP), polystyrene (hereinafter abbreviated as PS), polyvinyl chloride (hereinafter abbreviated as PVC), and the like.

【0005】材質の判別法としては、比重よる方法、X
線透過量を測定する方法(実開昭60−187711
号)、赤外線或いは近赤外線の吸収スペクトルを測定
し、既知データと比較し判別する方法(特開平6−12
3701号、特開平6−210632号等)及びレーザ
ビーム照射により材料温度を上昇させ、反射する赤外線
を測定することにより、熱拡散率を計算し、既知データ
と比較し、判別する方法(特開平5−312742
号)。
As a method of discriminating the material, a method based on specific gravity, X
Method for measuring the amount of linear transmission (Shokai Sho 60-187711)
No.), a method of measuring the absorption spectrum of infrared rays or near-infrared rays and comparing it with known data to make a discrimination (JP-A-6-12).
No. 3701, JP-A-6-210632, etc.) and a method of calculating the thermal diffusivity by raising the material temperature by laser beam irradiation and measuring infrared rays reflected, and comparing with known data to make a distinction (Japanese Patent Laid-Open Publication No. HEI-HEI). 5-312742
issue).

【0006】[0006]

【発明が解決しようとする課題】しかしながら、上述し
た従来の判別法には次のような問題点があった。比重に
よる判別では、PETと比重差の大きい、PE,PP,
PS等は分別可能であるが、PETと比重差の小さいP
VCでは判別が困難である。また、X線透過量を測定す
る方法は、放射線を利用することから来る安全性や方等
の問題に加え、ボトルの形状差や潰れよる重なり等によ
り誤認する不都合がある。
However, the above-mentioned conventional discrimination method has the following problems. In the discrimination by specific gravity, PE, PP, which has a large specific gravity difference from PET,
PS, etc. can be separated, but P with a small difference in specific gravity from PET
It is difficult to identify with VC. Further, the method of measuring the amount of X-ray transmission has a problem that it is mistakenly recognized due to the difference in the shape of the bottles, the overlapping due to crushing, etc.

【0007】更に、赤外線或いは近赤外線の吸収スペク
トルを利用する方法では、ボトルの潰れによる重なりや
廃ボトルの内面の汚れにより吸収スペクトルの測定が困
難な場合がある。また、吸収スペクトルを測定し、既知
データと比較し判別するため、処理速度の高速化に限界
がある。
Further, in the method of utilizing the absorption spectrum of infrared rays or near infrared rays, there are cases where it is difficult to measure the absorption spectrum due to overlapping due to crushing of bottles and dirt on the inner surface of the waste bottle. In addition, since the absorption spectrum is measured and compared with known data to make a distinction, there is a limit in increasing the processing speed.

【0008】一方、レーザビームを照射し熱拡散率を計
算する方法では、レーザ照射装置のような特殊装置が必
要であることに加え、温度上昇度から熱拡散率の計算に
は、被測定物の厚さが寄与するため、廃ボトルの材質判
別等の形状不均一な被測定物には適さない。
On the other hand, in the method of irradiating a laser beam to calculate the thermal diffusivity, a special device such as a laser irradiating device is required, and in addition, the thermal diffusivity is calculated from the temperature rise degree. Is not suitable for the object to be measured, which has a non-uniform shape such as the material discrimination of waste bottles.

【0009】また、レーザビームを微少スポットに照射
し、同一点での赤外線の検出を行うため、被測定物は固
定されている必要があり、ライン上でのボトル判別等の
連続処理が困難である。
Further, since the laser beam is applied to a minute spot to detect infrared rays at the same point, the object to be measured needs to be fixed, and continuous processing such as bottle discrimination on the line is difficult. is there.

【0010】[0010]

【課題を解決するための手段】本発明のプラスチック材
質判別法は、材質が未知のプラスチックに赤外線を照射
することにより、前記プラスチックの表面温度を上昇さ
せ、その温度を測定し、材質を判別することを特徴とす
る。
In the plastic material discrimination method of the present invention, the surface temperature of the plastic is raised by irradiating the plastic of unknown material with infrared rays, and the temperature is measured to discriminate the material. It is characterized by

【0011】また、上記目的を達成する本発明のプラス
チック材質判別装置は、材質が未知のプラスチックに赤
外線を照射する赤外線照射装置と、プラスチック表面の
温度測定を行う温度測定装置と、測定したプラスチック
表面温度により材質を判定する判別器とを備えたことを
特徴とする。
Further, the plastic material discriminating apparatus of the present invention which achieves the above object, is an infrared irradiating device for irradiating plastic of unknown material with infrared rays, a temperature measuring device for measuring the temperature of the plastic surface, and a measured plastic surface. And a discriminator that determines the material based on the temperature.

【0012】[0012]

【発明の実施の形態】本発明は、プラスチックに赤外線
を照射することにより、材質間で赤外線の吸収率に差が
あることから、プラスチック表面温度差が生じ、その温
度差を温度測定装置で測定することにより、プラスチッ
クの材質判定ができる。
BEST MODE FOR CARRYING OUT THE INVENTION According to the present invention, when plastics are irradiated with infrared rays, there is a difference in the absorption rate of the infrared rays among the materials, so that a plastic surface temperature difference occurs and the temperature difference is measured by a temperature measuring device. By doing so, the plastic material can be determined.

【0013】[0013]

【実施例】以下、本発明について、図面に示す実施例を
参照して詳細に説明する。本発明の一実施例に係るプラ
スチック材質判別装置を図1に示す。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail with reference to embodiments shown in the drawings. FIG. 1 shows a plastic material discriminating apparatus according to an embodiment of the present invention.

【0014】同図に示すように、移送装置3の上方に
は、赤外線照射装置1、温度測定装置2が配設される一
方、移送装置3上には被測定プラスチック4が載置され
矢印方向に移送される。移送装置3の下流側には、分別
装置6が配置され、移送された被測定プラスチック4は
分別装置6へ到達する。
As shown in the figure, an infrared irradiation device 1 and a temperature measuring device 2 are arranged above the transfer device 3, while a plastic 4 to be measured is placed on the transfer device 3 in the direction of the arrow. Be transferred to. A sorting device 6 is arranged on the downstream side of the transfer device 3, and the transferred measured plastic 4 reaches the sorting device 6.

【0015】赤外線照射装置1としては、赤外線波長領
域の光線を発生する装置を広く採用することができ、例
えば、赤外線ヒータ等が利用できる。赤外線照射装置1
に、赤外線照射強度を調節する可変調節器又は多段式調
節器を備えることにより、被測定プラスチック4の昇温
速度を制御できる。
As the infrared irradiating device 1, a device for generating light rays in the infrared wavelength region can be widely adopted, and for example, an infrared heater or the like can be used. Infrared irradiation device 1
In addition, by providing a variable controller or a multi-stage controller that adjusts the infrared irradiation intensity, the rate of temperature rise of the measured plastic 4 can be controlled.

【0016】温度測定装置2としては、検出器として、
真空熱電対、焦電赤外センサ又は放射温度計を用いるこ
とができる。温度測定装置2は、一定の赤外線を照射さ
れた後の被測定プラスチック4の温度を計測し、計測し
た温度を判別器5へ送る。
As the temperature measuring device 2, as a detector,
Vacuum thermocouples, pyroelectric infrared sensors or radiation thermometers can be used. The temperature measuring device 2 measures the temperature of the measured plastic 4 after being irradiated with a constant infrared ray, and sends the measured temperature to the discriminator 5.

【0017】移送装置3としては、被測定プラスチック
4を連続走行又は間欠送り移送させるものを用いること
ができる。被測定プラスチック4としては、材質が未知
のものに適用され、特に、成形品で形状及び厚さが同一
のものに適用されることが望ましい。
As the transfer device 3, a device for continuously traveling or intermittently transferring the measured plastic 4 can be used. As the plastic 4 to be measured, it is preferable to use a material whose material is unknown, and in particular, a molded product having the same shape and thickness.

【0018】判別器5は、温度測定装置2により測定さ
れた被測定プラスチック4の測定温度を既知データと比
較することにより、被測定プラスチック4の材質を判別
する。
The discriminator 5 discriminates the material of the measured plastic 4 by comparing the measured temperature of the measured plastic 4 measured by the temperature measuring device 2 with known data.

【0019】ここで、被測定プラスチック4は、赤外線
照射装置1による赤外線照射ゾーンを一定時間通過する
際に、一定の赤外線が照射され、固有の赤外線吸収率に
より、それぞれの材質の吸収率に応じた温度上昇を示
す。その具体例を図2に示す。図2は、PETボトルと
PVCボトルを赤外線ヒータを用いて赤外線を照射し、
赤外線放射温度計により表面温度を計測した例である。
図2中、横軸が赤外線照射時間、立軸がボトルの表面温
度である。
Here, the measured plastic 4 is irradiated with a certain amount of infrared light when passing through the infrared irradiation zone by the infrared irradiation device 1 for a certain time, and the infrared absorption rate peculiar to each plastic material causes the absorption rate of each material to vary. Shows a rise in temperature. A specific example is shown in FIG. FIG. 2 shows that a PET bottle and a PVC bottle are irradiated with infrared rays using an infrared heater,
This is an example of measuring the surface temperature with an infrared radiation thermometer.
In FIG. 2, the horizontal axis is the infrared irradiation time and the vertical axis is the surface temperature of the bottle.

【0020】図2に示すように、PETボトルとPVC
ボトルとは、赤外線吸収率の差により、温度上昇の差が
生じ、PETボトルがPVCボトルに比較して、赤外線
照射初期から約20℃だけ高温である。
As shown in FIG. 2, PET bottle and PVC
The difference in temperature between the bottle and the bottle occurs due to the difference in infrared absorption rate, and the PET bottle is higher than the PVC bottle by about 20 ° C. from the initial stage of infrared irradiation.

【0021】そのため、判別器5が、プラスチックの表
面温度を予め材質毎に設定した基準値と比較し、或い
は、基準材料と異種材料間での測定温度差により、材質
を判定することができ、分別装置6が、判別器5の結果
により、被測定プラスチック4を分別でき、上記例で
は、PETボトルとPVCボトルとを分別できるのであ
る。
Therefore, the discriminator 5 can determine the material by comparing the surface temperature of the plastic with a reference value set in advance for each material, or by the difference in the measured temperature between the reference material and different materials. The sorting device 6 can sort the plastics 4 to be measured based on the result of the discriminator 5, and in the above example, the PET bottle and the PVC bottle can be sorted.

【0022】このように説明したように、本実施例で
は、プラスチック材料が固有の赤外線吸収率を有してい
ることを利用し、材質が未知のプラスチックに一定の赤
外線を照射し、材質により異なる温度上昇を計測し、測
定温度或いは測定温度と基準値との比較、或いは異種材
質間の温度差により、プラスチック材料を判別すること
ができる。
As described above, in the present embodiment, the fact that the plastic material has a unique infrared absorption rate is used to irradiate the plastic of unknown material with a certain amount of infrared rays, and it varies depending on the material. The plastic material can be discriminated by measuring the temperature rise and comparing the measured temperature or the measured temperature with a reference value or the temperature difference between different materials.

【0023】また、本実施例では、照射光として一般的
を赤外線を利用することにより、簡便、迅速且つ連続し
てプラスチックの材料を判別することができる。尚、本
実施例では、所定時間赤外線を照射した後、赤外線照射
装置1の下流側で温度計測を行っていたが、移送装置3
を用いずに、所定時間赤外線を照射した後、その場所で
温度を計測するようにしても良いし、或いは、赤外線照
射と同時に温度を測定しても良い。
Further, in this embodiment, by using infrared rays as the irradiation light, it is possible to discriminate the plastic material easily, rapidly and continuously. In this embodiment, the temperature was measured on the downstream side of the infrared irradiation device 1 after the infrared irradiation for a predetermined time.
Instead of using, the temperature may be measured at the place after the infrared irradiation for a predetermined time, or the temperature may be measured at the same time as the infrared irradiation.

【0024】[0024]

【発明の効果】以上、実施例に基づいて具体的に説明し
たように、本発明は、赤外線照射装置によって被測定プ
ラスチックに一定の赤外線を照射した後、被測定プラス
チック表面の温度を温度測定装置で測定することによ
り、材質判別を簡便、迅速且つ連続して行うことができ
る。
As described above in detail with reference to the embodiments, the present invention irradiates the plastic to be measured with infrared rays by the infrared irradiation device and then measures the temperature of the surface of the plastic to be measured by the temperature measuring device. The material determination can be performed easily, quickly, and continuously by measuring with.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例に係るプラスチック材料判別
装置の構造図である。
FIG. 1 is a structural diagram of a plastic material discriminating apparatus according to an embodiment of the present invention.

【図2】赤外線照射時間とボトルの表面温度の関係を示
すグラフである。
FIG. 2 is a graph showing the relationship between infrared irradiation time and bottle surface temperature.

【符号の説明】[Explanation of symbols]

1 赤外線照射装置 2 温度計測装置 3 移送装置 4 被測定プラスチック 5 判別器 6 分別装置 1 Infrared irradiation device 2 Temperature measurement device 3 Transfer device 4 Plastic to be measured 5 Discriminator 6 Sorting device

Claims (9)

【特許請求の範囲】[Claims] 【請求項1】 材質が未知のプラスチックに赤外線を照
射することにより、前記プラスチックの表面温度を上昇
させ、その温度を測定し、材質を判別することを特徴と
するプラスチック材質判別法。
1. A method for determining a plastic material, which comprises irradiating infrared rays to a plastic of an unknown material to raise the surface temperature of the plastic and measuring the temperature to determine the material.
【請求項2】 前記プラスチックは、成形品で形状及び
厚さが同一のものに適用されることを特徴とする請求項
1記載のプラスチック材質判別法。
2. The plastic material discrimination method according to claim 1, wherein the plastic is a molded product having the same shape and thickness.
【請求項3】 材質が未知のプラスチックに赤外線を照
射する赤外線照射装置と、プラスチック表面の温度測定
を行う温度測定装置と、測定したプラスチック表面温度
により材質を判定する判別器とを備えたことを特徴とす
るプラスチック材質判別装置。
3. An infrared irradiation device for irradiating a plastic of unknown material with infrared rays, a temperature measuring device for measuring the temperature of the plastic surface, and a discriminator for judging the material based on the measured plastic surface temperature. Characteristic plastic material identification device.
【請求項4】 前記プラスチックは、成形品で形状及び
厚さが同一のものに適用されることを特徴とする請求項
3記載のプラスチック材質判別装置。
4. The plastic material discrimination device according to claim 3, wherein the plastic is a molded product having the same shape and thickness.
【請求項5】 前記判別器は、前記プラスチックの表面
温度を予め材質毎に設定した基準値と比較することによ
り、材質を判定することを特徴とする請求項3又は4記
載のプラスチック材質判別装置。
5. The plastic material discriminating apparatus according to claim 3 or 4, wherein the discriminator judges the material by comparing the surface temperature of the plastic with a reference value preset for each material. .
【請求項6】 前記判別器は、前記プラスチックの表面
温度を基準材料と異種材料間での測定温度差とを比較す
ることにより、材質を判定することを特徴とする請求項
3又は4記載のプラスチック材質判別装置。
6. The material according to claim 3, wherein the discriminator judges the material by comparing the surface temperature of the plastic with a reference material and a measured temperature difference between different materials. Plastic material identification device.
【請求項7】 前記プラスチックは、連続走行又は間欠
送り走行されることを特徴とする請求項3,4,5又は
6記載のプラスチック材質判別装置。
7. The plastic material discriminating apparatus according to claim 3, 4, 5 or 6, wherein the plastic is continuously or intermittently fed.
【請求項8】 前記プラスチックは、所定時間赤外線を
照射した後温度を計測されること、或いは、赤外線照射
と同時に温度を測定されることを特徴とする請求項3,
4,5又は6記載のプラスチック材質判別装置。
8. The temperature of the plastic is measured after being irradiated with infrared rays for a predetermined time, or the temperature is measured at the same time when the plastic is irradiated with infrared rays.
The plastic material discrimination device according to 4, 5, or 6.
【請求項9】 前記プラスチックは、所定時間赤外線を
照射した後温度計測を、赤外線照射装置の下流側で行う
ことを特徴とする請求項3,4,5又は6記載のプラス
チック材質判別装置。
9. The plastic material discriminating apparatus according to claim 3, wherein the temperature of the plastic is irradiated with infrared rays for a predetermined time and then the temperature is measured on the downstream side of the infrared irradiation apparatus.
JP11339196A 1996-05-08 1996-05-08 Method of judging plastic material, and device therefor Withdrawn JPH09297114A (en)

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Application Number Priority Date Filing Date Title
JP11339196A JPH09297114A (en) 1996-05-08 1996-05-08 Method of judging plastic material, and device therefor

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Publication number Priority date Publication date Assignee Title
US6522149B2 (en) 2000-05-15 2003-02-18 Nec Corporation Method and apparatus for identifying plastics
US7799835B2 (en) * 2003-03-13 2010-09-21 Next-Tec, Ltd. Recycling and reduction of plastics and non-plastics material
JP2010536025A (en) * 2007-08-08 2010-11-25 セミ−コンダクター ディバイセズ − アン エルビット システムズ−ラファエル パートナーシップ System and method for detection of counterfeit medicines based on thermography
CN102288372A (en) * 2011-09-08 2011-12-21 洛阳兰迪玻璃机器有限公司 Vacuum glass sealing performance on-line detection method and device thereof
US9008408B2 (en) 2009-02-05 2015-04-14 D.I.R. Technologies (Detection Ir) Ltd. Method and system for determining the quality of pharmaceutical products
CN109100391A (en) * 2018-08-08 2018-12-28 广东永和建设集团有限公司 A kind of concrete infrared detection method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6522149B2 (en) 2000-05-15 2003-02-18 Nec Corporation Method and apparatus for identifying plastics
US7799835B2 (en) * 2003-03-13 2010-09-21 Next-Tec, Ltd. Recycling and reduction of plastics and non-plastics material
JP2010536025A (en) * 2007-08-08 2010-11-25 セミ−コンダクター ディバイセズ − アン エルビット システムズ−ラファエル パートナーシップ System and method for detection of counterfeit medicines based on thermography
US8586928B2 (en) 2007-08-08 2013-11-19 Semi-Conductor Devices—An Elbit Systems-Rafael Partnership Thermography based system and method for detecting counterfeit drugs
KR101510911B1 (en) * 2007-08-08 2015-04-10 세미-컨덕터 디바이스-언 엘벗 시스템즈-라파엘 파트너쉽 Thermography based system and method for detecting counterfeit drugs
US9008408B2 (en) 2009-02-05 2015-04-14 D.I.R. Technologies (Detection Ir) Ltd. Method and system for determining the quality of pharmaceutical products
CN102288372A (en) * 2011-09-08 2011-12-21 洛阳兰迪玻璃机器有限公司 Vacuum glass sealing performance on-line detection method and device thereof
CN109100391A (en) * 2018-08-08 2018-12-28 广东永和建设集团有限公司 A kind of concrete infrared detection method
CN109100391B (en) * 2018-08-08 2021-06-15 广东永和建设集团有限公司 Concrete infrared detection method

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