JPH09263807A - Method for injecting pulverized coal into blast furnace - Google Patents

Method for injecting pulverized coal into blast furnace

Info

Publication number
JPH09263807A
JPH09263807A JP7261496A JP7261496A JPH09263807A JP H09263807 A JPH09263807 A JP H09263807A JP 7261496 A JP7261496 A JP 7261496A JP 7261496 A JP7261496 A JP 7261496A JP H09263807 A JPH09263807 A JP H09263807A
Authority
JP
Japan
Prior art keywords
pulverized coal
burner
combustion
temp
blast furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP7261496A
Other languages
Japanese (ja)
Inventor
Koichi Takashima
光一 高島
Yukio Tomita
幸雄 富田
Yasuo Okamoto
泰夫 岡本
Akiyoshi Sugano
晃由 菅野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Nisshin Co Ltd
Original Assignee
Nisshin Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nisshin Steel Co Ltd filed Critical Nisshin Steel Co Ltd
Priority to JP7261496A priority Critical patent/JPH09263807A/en
Publication of JPH09263807A publication Critical patent/JPH09263807A/en
Withdrawn legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To prevent ash content from being stuck to a combustion branched pipe at the tip part of a tuyere, to improve the combustion ratio of pulverized coal and to obtain the stable operation of a blast furnace by comparing the previously obtd. fusing temp. of the ash content in the pulverized coal and the combustion temp. of the pulverized coal and deciding the position of the tip part of a burner at the time of injecting the pulverized coal. SOLUTION: At the time of injecting the pulverized coal from the burner 6 passing through the side wall 1a of a blasting branched tube 1 and projecting inward, a first process for previously obtaining the fusing temp. of the ash content contained in the injected pulverized coal, a second process for obtaining the combustion temp. of the injected pulverized coal and a third process for comparison-calculating the fusing temp. and the combustion temp. of the pulverized coal are provided. The tip part of the burner 6 is advanced/retreated so that the result of arithmetic operation based on the third process becomes lower than the fusing temp. of the ash content. Then, as a combustion temp. detecting means 3 of the pulverized coal injected from the burner 6, an optical temp. measuring means is used, and a hydraulic driving means 8 is preferably used for the advance/retreat of the burner 6.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、高炉の羽口から微
粉炭を吹き込む方法に関するものである。
TECHNICAL FIELD The present invention relates to a method for blowing pulverized coal from tuyere of a blast furnace.

【0002】[0002]

【従来の技術】一般に、多くの高炉では羽口からコーク
スの代替燃料である微粉炭を多量に吹き込んでいる。こ
の吹き込み量を増やすことができればできるほどコーク
ス使用量が減りコークスを製造するコークス炉の負担を
低減する事ができる。さらにコークスと微粉炭との単価
差を考えると大幅な製造コストの低減を図る事ができ
る。ただし、微粉炭は重油や天然ガスなどの補助燃料に
比べて燃焼性が低く、燃焼しないで残る灰分を多量に含
有するといった欠点がある。そのため羽口先で未燃焼の
微粉炭が発生し、その未燃焼の微粉炭が高炉炉内に蓄積
しそのため、高炉の安定操業に支障が生じる。さらに微
粉炭中に含まれる灰分の融着物が羽口や送風支管に付着
堆積し、送風支管を閉鎖させてしまい、これも高炉の安
定操業を阻害する一因となる。
2. Description of the Related Art Generally, in many blast furnaces, a large amount of pulverized coal, which is an alternative fuel for coke, is blown from the tuyere. The more the blow-in amount can be increased, the smaller the amount of coke used and the less the burden of the coke oven for producing coke. Further, considering the unit price difference between coke and pulverized coal, it is possible to significantly reduce the manufacturing cost. However, pulverized coal has a disadvantage that it has a lower combustibility than auxiliary fuels such as heavy oil and natural gas, and contains a large amount of ash that remains without being combusted. Therefore, unburned pulverized coal is generated at the tuyere, and the unburned pulverized coal is accumulated in the blast furnace, which hinders stable operation of the blast furnace. Further, the ash deposits contained in the pulverized coal adhere to and accumulate on the tuyere and the blast branch pipe, closing the blast branch pipe, which also contributes to the hindered stable operation of the blast furnace.

【0003】微粉炭は吹き込みバーナーの先端から送風
支管内に吹き出されてすぐ周囲の温度により昇温され、
ある一定温度になると着火する。着火後石炭中の揮発分
の燃焼が一気に進み、それと同時に固体の炭素の燃焼が
緩やかに進むことが知られている。図2にはバーナーの
先端から吹き出された微粉炭の燃焼温度分布と燃焼効率
を試験燃焼炉を用いて測定した燃焼試験結果を示す。微
粉炭はバーナー先端から約100mmの噴出した所から
急激に燃焼温度が上昇し400〜600mm付近で最高
に達し、燃焼率も100mm付近から急激に上昇するこ
とが解る。図2の現象から、高炉へ熱風を送り込む熱風
支管の側面の壁を貫通し、その内側に突出するバーナー
の先端から微粉炭を吹き込む際に、バーナーの先端位置
をどの位置に配置するかによって高炉内に吹き込まれる
未燃焼の微粉炭量は大きく変化することが推察される。
この未燃焼微粉炭の減少を図るための公知の技術として
は特公昭60−53081号公報がある。この公報の方
法によるとバーナーの先端位置を送風支管と羽口の境界
から100〜350mm以上の上流の送風支管側に位置
させて行う方法が開示されている。
The pulverized coal is blown out from the tip of the blowing burner into the blast branch pipe and immediately heated by the ambient temperature.
It ignites when it reaches a certain temperature. It is known that after ignition, the combustion of volatile matter in coal proceeds at once, and at the same time, the combustion of solid carbon proceeds gradually. FIG. 2 shows the combustion test results obtained by measuring the combustion temperature distribution and the combustion efficiency of the pulverized coal blown from the tip of the burner using a test combustion furnace. It is understood that the combustion temperature of pulverized coal rapidly rises from a point of about 100 mm ejected from the tip of the burner, reaches the maximum in the vicinity of 400 to 600 mm, and the combustion rate also sharply increases in the vicinity of 100 mm. From the phenomenon of Fig. 2, when the pulverized coal is blown from the tip of the burner that penetrates the side wall of the hot air branch pipe that sends hot air to the blast furnace and projects inward, it depends on the position of the tip of the burner. It is presumed that the amount of unburned pulverized coal blown inside changes greatly.
As a known technique for reducing the amount of unburned pulverized coal, there is Japanese Patent Publication No. 60-53081. According to the method disclosed in this publication, there is disclosed a method in which the tip of the burner is positioned on the side of the blast branch pipe which is 100 to 350 mm or more upstream from the boundary between the blast branch pipe and the tuyere.

【0004】前記したように燃焼状態を良好に保つに
は、バーナーの先端位置をできるだけ高炉の炉内から遠
ざけ送風支管から羽口までの間で微粉炭の燃焼を進行さ
せることが望ましい。一方、微粉炭の燃焼温度により溶
融した灰分が羽口及び送風支管内壁に付着・再凝結する
が、この微粉炭の燃焼により溶融した灰分が羽口や送風
支管に付着するのを防止するにはできるだけバーナーの
先端を炉内側に位置させる必要がある。
As described above, in order to maintain a good combustion state, it is desirable to keep the tip position of the burner as far away from the furnace of the blast furnace as possible so that the combustion of pulverized coal proceeds from the blow branch pipe to the tuyere. On the other hand, the ash content melted by the combustion temperature of the pulverized coal adheres and re-condenses on the tuyere and the inner wall of the blast branch pipe, but to prevent the ash content melted by the combustion of the pulverized coal from adhering to the tuyere and the blast branch pipe. The tip of the burner should be located inside the furnace as much as possible.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、高炉へ
吹き込む微粉炭の灰分の組織は、吹き込む微粉炭の銘柄
によって変化するため、この灰分の付着を防止すること
は極めて困難であった。また、高炉へ安定的に微粉炭を
吹き込み燃焼させ、かつ高炉の羽口先や燃焼支管に燃焼
した灰分を付着させることなく微粉炭の燃焼効率を最大
にすることが要望されていた。
However, since the ash structure of the pulverized coal blown into the blast furnace changes depending on the brand of the pulverized coal blown in, it is extremely difficult to prevent this ash deposit. Further, it has been demanded that the pulverized coal is stably blown into the blast furnace for combustion, and that the combustion efficiency of the pulverized coal is maximized without adhering the burned ash to the tuyere tip and the combustion branch pipe of the blast furnace.

【0006】本発明は、以上のような課題を解決するた
めになされたもので、特に、高炉の操業条件が変化して
も灰分が付着するバーナー先端位置を特定することによ
り、灰分の付着をなくし、かつ、微粉炭の燃焼率を最大
限上昇させるようにした高炉への微粉炭吹き込み方法を
提供することを目的とする。
The present invention has been made in order to solve the above problems, and in particular, by identifying the burner tip position where the ash adheres even if the operating conditions of the blast furnace change, the ash adhesion can be prevented. It is an object of the present invention to provide a method for blowing pulverized coal into a blast furnace that eliminates pulverized coal and maximizes the combustion rate of pulverized coal.

【0007】[0007]

【課題を解決するための手段】本発明による高炉への微
粉炭吹き込み方法は、高炉へ熱風を送り込む送風支管の
側面の壁を貫通し、その壁の内側に突出させるバーナー
から微粉炭を吹き込む方法において、予め前記高炉に吹
き込む前記微粉炭に含まれる灰分の溶融温度を求めてお
く第1工程と、前記バーナーから吹き込んだ前記微粉炭
の燃焼温度を求める第2工程と、前記微粉炭の灰分の溶
融温度と前記燃焼温度を比較演算する第3工程と、前記
第3工程による演算結果が前記灰分の溶融温度より低く
なるように前記バーナーの先端を進退させる方法であ
る。
A method for blowing pulverized coal into a blast furnace according to the present invention is a method in which pulverized coal is blown from a burner which penetrates a side wall of a blast branch pipe for feeding hot air into the blast furnace and projects inside the wall. In the first step, the melting temperature of the ash contained in the pulverized coal blown into the blast furnace is determined in advance, the second step of determining the combustion temperature of the pulverized coal blown from the burner, and the ash content of the pulverized coal is determined. A third step of comparing and calculating a melting temperature and the combustion temperature, and a method of moving the tip of the burner forward and backward so that the calculation result of the third step is lower than the melting temperature of the ash.

【0008】さらに詳細には、前記バーナーから吹き込
んだ前記微粉炭の燃焼温度を求める手段として光学的な
温度計測手段を用いる方法である。
More specifically, it is a method of using an optical temperature measuring means as a means for obtaining the combustion temperature of the pulverized coal blown from the burner.

【0009】さらに詳細には、油圧を用いて前記バーナ
ーを進退させる方法である。
More specifically, it is a method of moving the burner forward and backward by using hydraulic pressure.

【0010】[0010]

【発明の実施の形態】以下、図面と共に本発明による高
炉への微粉炭吹き込み方法の好適な実施の形態について
述べる。図1において符号1で示されるものは、筒状の
送風支管であり、この送風支管1の側面に形成された第
1孔5には、バーナー6が挿入して設けられていると共
に、第2孔5aには温度計3が挿入され、この温度計3
の先端は送風支管1の羽口2を横切り、測定範囲4を形
成している。なお、温度計3としては、周知の光学的な
温度計測手段を用いている。この温度計3は第1孔5の
バーナー6から噴射する微粉炭の燃焼した火炎の光のエ
ネルギーから温度を計測する光学式の放射温度計であ
る。この温度計3での温度の計測範囲は、第2孔5aの
炉内側への延長線が羽口2の内面に重なるように配置さ
れて、測定範囲4においては炉内からの光を温度計3が
捕らえないように配置してある。また、前述のバーナー
6は、バーナー保持部7の油圧シリンダー8によって出
入自在に設けられ、その先端を自在に出入できる。
BEST MODE FOR CARRYING OUT THE INVENTION Preferred embodiments of the method for blowing pulverized coal into a blast furnace according to the present invention will be described below with reference to the drawings. A reference numeral 1 in FIG. 1 denotes a tubular blower branch pipe, and a burner 6 is provided by being inserted into a first hole 5 formed on a side surface of the blower branch pipe 1, and a second blower pipe is provided. The thermometer 3 is inserted into the hole 5a, and the thermometer 3
Of the air blower traverses the tuyere 2 of the blower branch pipe 1 to form a measurement range 4. A well-known optical temperature measuring means is used as the thermometer 3. The thermometer 3 is an optical radiation thermometer that measures the temperature from the energy of the light of the flame of the pulverized coal burned from the burner 6 of the first hole 5. The temperature measuring range of the thermometer 3 is arranged so that the extension line of the second hole 5a to the inside of the furnace overlaps the inner surface of the tuyere 2. In the measuring range 4, the light from the inside of the furnace is measured by the thermometer. It is arranged so that 3 is not caught. Further, the above-mentioned burner 6 is provided so as to be able to move in and out by the hydraulic cylinder 8 of the burner holding portion 7, and its tip can be freely moved in and out.

【0011】次に動作について述べる。前記微粉炭の燃
焼温度を温度計3で測定した結果と、現在高炉にバーナ
ー6を介して吹込んでいる微粉炭の灰分の溶融温度とを
比較する。比較して燃焼温度が高ければバーナー6の先
端を送風支管1の内側に侵入するように操作を行う。ま
た、バーナー6を出入駆動させる場合、バーナー保持部
7に設けた油圧シリンダー8でバーナー6を予め設定し
たピッチで進退させ、1ピッチ移動したときに、再び温
度計3で温度を測定して最適なバーナー先端位置を決め
る。
Next, the operation will be described. The result of measuring the combustion temperature of the pulverized coal with the thermometer 3 is compared with the melting temperature of the ash content of the pulverized coal currently blown into the blast furnace through the burner 6. In comparison, if the combustion temperature is high, the operation is performed so that the tip of the burner 6 enters the inside of the blower branch pipe 1. When the burner 6 is driven in and out, the hydraulic cylinder 8 provided in the burner holding portion 7 advances and retracts the burner 6 at a preset pitch, and when the burner 6 moves one pitch, the temperature is measured again by the thermometer 3 to optimize the operation. Determine the burner tip position.

【0012】[0012]

【実施例】次の表1の第1表には測定を行なった操業条
件と微粉炭の物性値を示す。第1表にはA,B,C3種
類の微粉炭の物性値を示し、この物性値の異なる微粉炭
を用いて高炉の操業条件、微粉炭吹き込み比を80〜1
55kg/t、風湿が25〜35g/Nm3、酸素富化
率を1.5〜3.5%、熱風温度を1160〜1220℃
の4条件で実操業を行なった。このときの灰分の羽口や
支管内壁への付着状況を羽口後方の覗孔より目視で観察
した。
EXAMPLES Table 1 in Table 1 below shows the operating conditions measured and the physical properties of pulverized coal. Table 1 shows the physical property values of three types of pulverized coal of A, B, and C. The operating conditions of the blast furnace and the pulverized coal blowing ratio are 80 to 1 using the pulverized coal having different physical property values.
55 kg / t, air humidity 25-35 g / Nm 3 , oxygen enrichment rate 1.5-3.5%, hot air temperature 1160-1220 ° C.
The actual operation was performed under the following four conditions. At this time, the ash content adhering to the tuyere and the inner wall of the branch pipe was visually observed through a peephole behind the tuyere.

【0013】[0013]

【表1】 [Table 1]

【0014】図3、4、5は前述の第1表に示した微粉
炭A,B,Cをバーナー6から高炉(図示せず)へ吹き
込んだ際の羽口2の先端とバーナー6の先端との距離と
温度計3にて燃焼温度を測定した結果を示している。微
粉炭Aを用いた図3の操業条件(1)では灰分を付着させ
ない距離はバーナーを羽口先より640mm引っ込めた
位置で、操業条件(4)では同じく580mm地点であ
る。図4の微粉炭の銘柄Bでは操業条件(7)では570
mmより内側で行えば灰分の付着は回避できる事を示し
ている、図5の微粉炭銘柄Cの操業条件(9)では670
mmである。このように、微粉炭の灰分融点と操業条件
によって、バーナー6の先端位置を制御することにより
羽口2の先や送風支管1の溶融した灰分の付着を防ぐこ
とができる。なお、前述の高炉への微粉炭吹き込み方法
をまとめると次の通りである。すなわち、高炉へ熱風を
送り込む送風支管1の側面の壁1aを貫通し、その壁1
aの内側に突出させるバーナー6から微粉炭を吹き込む
方法において、予め前記高炉に吹き込む前記微粉炭に含
まれる灰分の溶融温度を求めておく第1工程と、前記バ
ーナーから吹き込んだ前記微粉炭の燃焼温度を求める第
2工程と、前記微粉炭の灰分の溶融温度と前記燃焼温度
を比較演算する第3工程と、前記第3工程による演算結
果が前記灰分の溶融温度より低くなるように前記バーナ
ーの先端を進退させると共に、前記バーナー6から吹き
込んだ前記微粉炭の燃焼温度を求める手段として光学的
な温度計測手段を用い、油圧を用いて前記バーナーを進
退させている。
3, 4 and 5 show the tip of tuyere 2 and the tip of burner 6 when the pulverized coal A, B and C shown in Table 1 is blown from burner 6 into a blast furnace (not shown). The result of measuring the combustion temperature with the distance and the thermometer 3 is shown. In the operating condition (1) of FIG. 3 using the pulverized coal A, the distance where ash is not deposited is the position where the burner is retracted 640 mm from the tuyere, and the operating condition (4) is also the 580 mm point. For the pulverized coal brand B in FIG. 4, the operating condition (7) is 570.
It is shown that ash adhesion can be avoided if done inside mm, 670 under operating conditions (9) of pulverized coal brand C in FIG.
mm. Thus, by controlling the tip position of the burner 6 according to the ash melting point of the pulverized coal and the operating conditions, it is possible to prevent the molten ash from adhering to the tip of the tuyere 2 or the blower branch pipe 1. The method of blowing pulverized coal into the blast furnace is summarized as follows. That is, the side wall 1a of the blast branch pipe 1 for sending hot air into the blast furnace penetrates through the wall 1a.
In the method of blowing pulverized coal from the burner 6 which is projected to the inside of a, the first step of previously determining the melting temperature of the ash contained in the pulverized coal to be blown into the blast furnace, and the combustion of the pulverized coal blown from the burner The second step of obtaining the temperature, the third step of comparing and calculating the melting temperature of the ash of the pulverized coal and the combustion temperature, and the burner of the burner so that the calculation result of the third step is lower than the melting temperature of the ash. While moving the tip forward and backward, an optical temperature measuring means is used as a means for obtaining the combustion temperature of the pulverized coal blown from the burner 6, and the burner is moved forward and backward using hydraulic pressure.

【0015】[0015]

【発明の効果】本発明による高炉への微粉炭吹き込み方
法は、以上のように構成されているため、次のような効
果を得ることができる。すなわち、従来は、灰分の付着
制御のためにバーナー先端位置を過度に高炉炉内側にせ
ざるを得なかったが、本発明により灰分が付着するバー
ナーの先端位置が正確に把握できるので付着をさせない
範囲で、微粉炭の燃焼量を最大限上昇させることが可能
となる。
Since the method of blowing pulverized coal into the blast furnace according to the present invention is configured as described above, the following effects can be obtained. That is, conventionally, the burner tip position had to be excessively inside the blast furnace for ash deposition control, but since the burner tip position to which ash deposits can be accurately grasped by the present invention, the range in which deposition does not occur is prevented. Thus, the combustion amount of pulverized coal can be maximized.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明による高炉への微粉炭吹き込み方法の実
施形態を示す概念図である。
FIG. 1 is a conceptual diagram showing an embodiment of a method for blowing pulverized coal into a blast furnace according to the present invention.

【図2】微粉炭の燃焼状態を説明する図である。FIG. 2 is a diagram illustrating a combustion state of pulverized coal.

【図3】羽口先端とバーナー先端との距離と測定温度の
関係を示す図である。
FIG. 3 is a diagram showing the relationship between the distance between the tuyere tip and the burner tip and the measured temperature.

【図4】羽口先端とバーナー先端との距離と測定温度の
関係を示す図である。
FIG. 4 is a diagram showing the relationship between the distance between the tuyere tip and the burner tip and the measured temperature.

【図5】羽口先端とバーナー先端との距離と測定温度の
関係を示す図である。
FIG. 5 is a diagram showing the relationship between the distance between the tuyere tip and the burner tip and the measured temperature.

【符号の説明】 1 送風支管 1a 壁 2 羽口 3 温度計 4 測定範囲 5 第1孔 5a 第2孔 6 バーナー 7 バーナー保持部 8 油圧シリンダー[Explanation of symbols] 1 blower branch pipe 1a wall 2 tuyere 3 thermometer 4 measurement range 5 first hole 5a second hole 6 burner 7 burner holder 8 hydraulic cylinder

───────────────────────────────────────────────────── フロントページの続き (72)発明者 菅野 晃由 広島県呉市昭和町11番1号 日新製鋼株式 会社呉製鉄所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Akiyoshi Sugano 11-1 Showa-cho, Kure City, Hiroshima Prefecture Nisshin Steel Co., Ltd. Kure Steel Works

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 高炉へ熱風を送り込む送風支管(1)の側
面の壁(1a)を貫通し、その壁(1a)の内側に突出させるバ
ーナー(6)から微粉炭を吹き込む方法において、予め前
記高炉に吹き込む前記微粉炭に含まれる灰分の溶融温度
を求めておく第1工程と、前記バーナーから吹き込んだ
前記微粉炭の燃焼温度を求める第2工程と、前記微粉炭
の灰分の溶融温度と前記燃焼温度を比較演算する第3工
程と、前記第3工程による演算結果が前記灰分の溶融温
度より低くなるように前記バーナーの先端を進退させる
ことを特徴とする高炉への微粉炭吹き込み方法。
1. A method of blowing pulverized coal from a burner (6) which penetrates a side wall (1a) of a blast branch pipe (1) for feeding hot air into a blast furnace and projects inside the wall (1a). A first step of determining the melting temperature of the ash contained in the pulverized coal blown into the blast furnace, a second step of determining the combustion temperature of the pulverized coal blown from the burner, a melting temperature of the ash content of the pulverized coal and the above A method for injecting pulverized coal into a blast furnace, which comprises advancing and retracting a tip of the burner so that a calculation result of the combustion temperature is compared and a calculation result of the third step is lower than a melting temperature of the ash.
【請求項2】 前記バーナー(6)から吹き込んだ前記微
粉炭の燃焼温度を求める手段として光学的な温度計測手
段を用いることを特徴とする請求項1記載の高炉への微
粉炭吹き込み方法。
2. The method for injecting pulverized coal into a blast furnace according to claim 1, wherein an optical temperature measuring means is used as a means for obtaining a combustion temperature of the pulverized coal blown from the burner (6).
【請求項3】 油圧を用いて前記バーナー(6)を進退さ
せることを特徴とする請求項1記載の高炉への微粉炭吹
き込み方法。
3. The method for injecting pulverized coal into a blast furnace according to claim 1, wherein the burner (6) is advanced and retracted using hydraulic pressure.
JP7261496A 1996-03-27 1996-03-27 Method for injecting pulverized coal into blast furnace Withdrawn JPH09263807A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7261496A JPH09263807A (en) 1996-03-27 1996-03-27 Method for injecting pulverized coal into blast furnace

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7261496A JPH09263807A (en) 1996-03-27 1996-03-27 Method for injecting pulverized coal into blast furnace

Publications (1)

Publication Number Publication Date
JPH09263807A true JPH09263807A (en) 1997-10-07

Family

ID=13494451

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7261496A Withdrawn JPH09263807A (en) 1996-03-27 1996-03-27 Method for injecting pulverized coal into blast furnace

Country Status (1)

Country Link
JP (1) JPH09263807A (en)

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WO2014020965A1 (en) * 2012-08-03 2014-02-06 三菱重工業株式会社 Blast-furnace-blow-in charcoal and method for producing same
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