JPH09194321A - Antiseptic for cosmetics - Google Patents

Antiseptic for cosmetics

Info

Publication number
JPH09194321A
JPH09194321A JP8007486A JP748696A JPH09194321A JP H09194321 A JPH09194321 A JP H09194321A JP 8007486 A JP8007486 A JP 8007486A JP 748696 A JP748696 A JP 748696A JP H09194321 A JPH09194321 A JP H09194321A
Authority
JP
Japan
Prior art keywords
tourmaline
cosmetics
antiseptic
water
fine powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8007486A
Other languages
Japanese (ja)
Inventor
Keisuke Matsuyama
圭佑 松山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HADA CORP KK
Original Assignee
HADA CORP KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HADA CORP KK filed Critical HADA CORP KK
Priority to JP8007486A priority Critical patent/JPH09194321A/en
Publication of JPH09194321A publication Critical patent/JPH09194321A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain an antiseptic for cosmetics capable of manifesting remarkably high antiseptic and bactericidal effects by using fine powder of a specific mineral and its action to enhance surface activities of water, alcohol, etc. SOLUTION: In this antiseptic for cosmetics, fine powder of a material called tourmaline is used. Tourmaline is a silicate mineral containing boron and belongs to a trigonal or a hexagonal hemimorphic hemihedral form which is asymmetric in above and below. Its chemical formula is complicated and the typical one is expressed by the formula (X is Mg, Fe, Li, etc.). Tourmaline is more excellent in chemical resistances against acids, alkalies, etc., than silica. Thus, when mixed in cosmetics, no chemical reaction occurs with the acids and the alkalies included in the cosmetic components. When tourmaline is brought into contact with water, it is electrolyzed by its action as permanent electrodes and has a function to emulsify and disperse an oil component in water as hydroxyl ions formed by the electrolysis which exhibit a surface activity. The fine particles have preferably <=10μm particle size.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、電気石あるいはト
ルマリンと称される物質の微粉末を用いた化粧品の防腐
剤に関する。
TECHNICAL FIELD The present invention relates to a preservative for cosmetics using fine powder of a substance called tourmaline or tourmaline.

【0002】[0002]

【従来の技術】化粧品は、その内容が、皮膚の分泌物
(皮脂膜)の作用を補う役割を持っているところから、
微生物の栄養源になり易く、増殖の場となることもあ
る。
2. Description of the Related Art Since cosmetics have a role of supplementing the action of skin secretions (sebum membranes),
It can easily serve as a nutrient source for microorganisms and can be a place of growth.

【0003】微生物に汚染された化粧品は、変臭、変
質、カビの発生等、品質の低下を来すのでこれを防止す
る措置を講ずる必要がある。
Cosmetics contaminated with microorganisms cause deterioration in quality such as odor, deterioration, and generation of mold, and it is necessary to take measures to prevent this.

【0004】このため、ほとんどの化粧品には、防腐、
防バイの目的で防腐・殺菌剤を配合し、経時的な汚染防
止に努めている。
Therefore, most cosmetics have antiseptic,
Antiseptic and bactericidal agents are added for the purpose of anti-vibration to prevent pollution over time.

【0005】上記のような防腐剤として一般的に使用さ
れているものは、比較的毒性が強く、いろいろな化粧品
から各種の防腐剤を摂取することは好ましくなく、各防
腐剤毎に使用基準が薬事法等により定められている。化
粧品に使用が認められている防腐・殺菌剤は、安息香
酸、安息香酸塩類、サルチル酸、サルチル酸塩類、ソル
ビン酸及びその塩類、フェノール類等がある。
The above-mentioned preservatives generally used are relatively toxic, and it is not preferable to ingest various preservatives from various cosmetics. It is defined by the Pharmaceutical Affairs Law. Antiseptics and bactericides approved for use in cosmetics include benzoic acid, benzoates, salicylic acid, salicylates, sorbic acid and its salts, and phenols.

【0006】[0006]

【発明が解決しようとする課題】上記のように、これら
の防腐剤は、化粧品の保存性を高める反面、その毒性が
強いために人体に悪影響を及ぼす恐れがあり、最近で
は、防腐剤無添加のいわゆる自然化粧品に対する需要が
高まっている。
As described above, while these preservatives enhance the shelf life of cosmetics, they are highly toxic and may adversely affect the human body. Recently, no preservatives have been added. Demand for so-called natural cosmetics is increasing.

【0007】しかしながら、このような自然化粧品は、
冷蔵を必要としたり、又製造から短期日内で使用しなけ
ればならないので、流通過程に乗り難く、且つコスト高
となる問題点がある。
However, such natural cosmetics are
Since it requires refrigeration or has to be used within a short period of time after production, there are problems that it is difficult to get into the distribution process and the cost is high.

【0008】この発明は、上記従来の問題点に鑑みてな
されたものであって、人体に無害の物質により、化粧品
の防腐・殺菌効果を得ることができるようにした化粧品
の防腐剤を提供することを目的とする。
The present invention has been made in view of the above-mentioned conventional problems, and provides a cosmetic preservative capable of obtaining a cosmetic antiseptic / sterilizing effect by a substance harmless to the human body. The purpose is to

【0009】[0009]

【課題を解決するための手段】この発明は、電気石の微
粉末からなる化粧品の防腐剤により上記目的を達成する
ものである。
The present invention achieves the above object by a cosmetic preservative comprising fine tourmaline powder.

【0010】即ち、本発明者は、電気石が例えば特公平
7−38987号公報に説明されているように、永久電
極による反応により界面活性を持つ水を作る機能に着目
したものであり、これが、水のみでなく、化粧品成分で
あるアルコール類、油脂類にも同様の作用を及ぼすこ
と、及び、従来の化学化合物の防腐剤に代わるものとし
て使用できることを確認したものである。
That is, the present inventor has paid attention to the function of tourmaline for producing water having surface activity by a reaction with a permanent electrode, as described in Japanese Patent Publication No. 7-38987, for example. It was confirmed that not only water, but also alcohols and fats and oils which are cosmetic ingredients have a similar effect, and that it can be used as an alternative to the preservatives of conventional chemical compounds.

【0011】電気石は、硼素を含む珪酸塩鉱物であり、
三方又は六方の異極反面像族に属し、この異極像は上下
非対称であり、化学式は複雑で、その代表的なものは、
次式に示される。
Tourmaline is a silicate mineral containing boron,
Belonging to the trigonal or hexagonal heteropolar image family, this heteropolar image is vertically asymmetric, its chemical formula is complicated, and its typical one is
It is shown in the following formula.

【0012】3{NaX3 Al6 (BO3 3 Si6
16(OHF)4 } (X=Mg,Fe,Li等)
3 {NaX 3 Al 6 (BO 3 ) 3 Si 6 O
16 (OHF) 4 } (X = Mg, Fe, Li, etc.)

【0013】このような電気石の結晶は、記号Xで示さ
れる金属の種類によって若干変わるが、酸、アルカリ等
の耐薬品性は石英よりも優れている。従って、化粧品中
に混合されても、化粧品成分中の酸あるいはアルカリに
より化学変化を生じることがない。
Such tourmaline crystals are slightly different depending on the kind of the metal indicated by the symbol X, but are more resistant to chemicals such as acids and alkalis than quartz. Therefore, even if it is mixed into cosmetics, chemical changes do not occur due to acids or alkalis in the cosmetic ingredients.

【0014】かかる電気石は、前述の特公平7−389
7号公報にも開示されるように、磁石のような永久電極
を有し、その反応により界面活性を持つ水を作り、ある
いは、炭化水素の鎖を電極反応によって分断、分解して
低分子量にさせる機能を有している。
Such tourmaline is described in Japanese Patent Publication No. 7-389.
As disclosed in Japanese Patent Publication No. 7, a permanent magnet-like electrode is provided, and water having surface activity is produced by the reaction, or a hydrocarbon chain is fragmented and decomposed by an electrode reaction to obtain a low molecular weight. It has the function of

【0015】特に、水が電気石と接触すると、該電気石
の永久電極の作用により、電気分解され、水素イオンH
+ が水分子と結合してH3 O+ (ヒドロニウムイオン)
を形成し、又他方の電極からは、OH- 又はH3 2 -
(ヒドロキシルイオン)が形成される。そして、ヒドロ
ニウムイオンを形成するH+ はその移動速度がヒドロキ
シルイオンよりも速いので、電極面で比較的容易に放
電、析出してH2 になり、ガスとして放出されていく。
一方、ヒドロキシルイオンは、界面活性を示し、油成分
を水の中に乳化、分散させる。
In particular, when water comes into contact with tourmaline, it is electrolyzed by the action of the permanent electrode of the tourmaline to generate hydrogen ions H.
+ Combines with water molecule to form H3 O + (hydronium ion)
From the other electrode and OH or H 3 O 2
(Hydroxyl ion) is formed. Since the moving speed of H + forming hydronium ions is faster than that of hydroxyl ions, it is relatively easily discharged and deposited on the electrode surface to become H 2 and released as gas.
On the other hand, hydroxyl ions exhibit surface activity and emulsify and disperse an oil component in water.

【0016】電気石は、これらの界面活性作用の他に、
水のpH値を中性に向かって移動させたり、弱い還元作
用を示すという作用がある。
Tourmaline, in addition to these surface-active effects,
It has the effects of shifting the pH value of water toward neutrality and exhibiting a weak reducing action.

【0017】従って、電気石微粉末を化粧品に混合する
と、上記機能により、該化粧品の腐敗及び細菌の増殖を
抑制することができる。
Therefore, when tourmaline fine powder is mixed with cosmetics, it is possible to suppress the decay of the cosmetics and the growth of bacteria due to the above function.

【0018】又、電気石微粉末は、例えば歯磨等の研磨
剤としての機能を要求される場合を除き、皮膚にざらつ
き感を与えないためには、その粒径が10μ以下である
ことが望ましい。更には、電気石としての上述のような
機能を発揮するためには、その粒径をより小さくするこ
とが望ましく、微粒子化の技術的な限界である0.1μ
程度まで小さくするとよい。
In addition, the tourmaline fine powder preferably has a particle size of 10 μm or less in order to prevent the skin from being roughened, except when the function as an abrasive such as toothpaste is required. . Furthermore, in order to exert the above-mentioned function as tourmaline, it is desirable to make the particle diameter smaller, which is a technical limit of atomization of 0.1 μm.
It is good to make it small.

【0019】更に、人体、特に皮膚に対する影響につい
て、電気石は、例えばその粉末を布地や繊維に固定した
衣類が近年大量に販売されているが、全く無害であるの
みでなく皮膚の生理効果を増大させ、ひいては健康を増
進させるという機能さえもある。
Regarding the influence on the human body, especially on the skin, as for tourmaline, for example, clothing in which the powder is fixed to cloth or fibers has been sold in large quantities in recent years, but it is not only harmless at all, but also has a physiological effect on the skin. It even has the function of increasing and thus improving health.

【0020】又、いわゆるMRSAと称されるメシチリ
ン耐性黄色葡萄状球菌については、非常に良好な抗菌効
果が確認されている。
A very good antibacterial effect has been confirmed for mesitillin-resistant Staphylococcus aureus so-called MRSA.

【0021】本発明の電気石微粉末の製造は次のように
する。
The production of tourmaline fine powder of the present invention is as follows.

【0022】まず、電気石鉱床から高含有量(99%以
上)の電気石鉱石を掘り出し、適宜の大きさに砕いて洗
浄し、更に3〜数段階程度で、徐々に小さく粉砕し、最
終的には1μ以下、望ましくは0.1μ以下の粒子径と
する。
First, a tourmaline ore having a high content (99% or more) is excavated from the tourmaline deposit, crushed into an appropriate size and washed, and further crushed into small pieces in about 3 to several steps, and finally. The particle size is 1 μm or less, preferably 0.1 μm or less.

【0023】化粧品に対する電気石の混合割合は、その
化粧品の種類によって異なる。
The mixing ratio of tourmaline to cosmetics varies depending on the type of cosmetics.

【0024】又、同じ種類の化粧品でも、要求される粘
性、含有される油性成分、他の粉末成分によっても異な
るが、防腐剤としての機能を得るためには、重量比で1
%以下で十分である。
Further, even in the same kind of cosmetics, the weight ratio is 1 in order to obtain the function as a preservative, though it depends on the required viscosity, contained oily component and other powder component.
% Or less is sufficient.

【0025】例えば歯磨に利用する場合、電気石の硬度
が研磨剤としての機能も十分果たすことができるので、
通常の歯磨に要求される10〜20μの粒径の粉末がよ
い。
For example, when it is used for toothbrushing, the hardness of tourmaline can sufficiently function as an abrasive,
A powder having a particle size of 10 to 20 μ which is required for ordinary toothpaste is preferable.

【0026】特に、電気石は、そのモース硬度が7.0
〜7.5でかなり硬いので、煙草のヤニを取り、歯を白
くするような歯磨には最適であり、且つ大目に(5〜1
0%程度)を混合させるとよい。
Particularly, tourmaline has a Mohs hardness of 7.0.
It's fairly hard at ~ 7.5, so it's perfect for brushing your teeth by removing cigarette tar and whitening your teeth.
0%) is preferably mixed.

【0027】[0027]

【発明の効果】本発明は上記のように、人体に全く無害
で、場合によっては皮膚の活性を高める電気石微粉末を
防腐剤として用いているので、その水あるいはアルコー
ル等の界面活性を高めることにより、極めて高い防腐・
殺菌効果を得ることができるという優れた効果を有す
る。
INDUSTRIAL APPLICABILITY As described above, the present invention uses tourmaline fine powder, which is completely harmless to the human body and enhances the activity of the skin in some cases, as a preservative, and thus enhances the surface activity of water or alcohol. Therefore, extremely high antiseptic
It has an excellent effect that a bactericidal effect can be obtained.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】電気石の微粉末からなる化粧品の防腐剤。1. A preservative for cosmetics comprising tourmaline fine powder.
JP8007486A 1996-01-19 1996-01-19 Antiseptic for cosmetics Pending JPH09194321A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8007486A JPH09194321A (en) 1996-01-19 1996-01-19 Antiseptic for cosmetics

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8007486A JPH09194321A (en) 1996-01-19 1996-01-19 Antiseptic for cosmetics

Publications (1)

Publication Number Publication Date
JPH09194321A true JPH09194321A (en) 1997-07-29

Family

ID=11667107

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8007486A Pending JPH09194321A (en) 1996-01-19 1996-01-19 Antiseptic for cosmetics

Country Status (1)

Country Link
JP (1) JPH09194321A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999045901A1 (en) * 1998-03-13 1999-09-16 Color Access, Inc. Tourmaline in cosmetic cleansing compositions
EP1100434A1 (en) 1999-05-26 2001-05-23 Color Access, Inc. Cosmetic compositions containing fluorescent minerals
KR100382078B1 (en) * 2000-10-07 2003-04-26 안상기 Fungicides comprising tourmalines
KR20030064193A (en) * 2002-01-24 2003-07-31 안상기 diseases of cure, comprising tourmaline

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999045901A1 (en) * 1998-03-13 1999-09-16 Color Access, Inc. Tourmaline in cosmetic cleansing compositions
US6036965A (en) * 1998-03-13 2000-03-14 Color Access, Inc. Tourmaline in cosmetic cleansing compositions
EP1100434A1 (en) 1999-05-26 2001-05-23 Color Access, Inc. Cosmetic compositions containing fluorescent minerals
EP1100434B1 (en) * 1999-05-26 2013-08-14 Color Access, Inc. Cosmetic compositions containing fluorescent minerals
KR100382078B1 (en) * 2000-10-07 2003-04-26 안상기 Fungicides comprising tourmalines
KR20030064193A (en) * 2002-01-24 2003-07-31 안상기 diseases of cure, comprising tourmaline

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