JPH08339070A - Apparatus for processing photographic sensitive material - Google Patents

Abstract

PURPOSE: To execute quality control high in photographic characteristics and accuracy in a processing solution. CONSTITUTION: The density of the exposed and nonexposed parts of a color paper 16P processed in a processing bath 10N is measured by a densitometer 22. When the density of the nonexposed part exceeds the upper limit of a prescribed range, it is judged in the following order whether a processing amount of the color paper 16P per a unit time, the accuracy of the feed rate of a replenishing solution, and pH, specific gravity, and an addition amount of water of the processing solution are abnormal or not, and the cause of exceeding the limit is assumed and a countermeasure against thus cause is executed.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a photographic light-sensitive material processing apparatus, and more particularly to a photographic light-sensitive material processing apparatus for processing a photographic light-sensitive material by passing it through a processing liquid.

[0002]

2. Description of the Related Art Conventionally, control of the processing liquid state in a photographic light-sensitive material processing apparatus is generally performed by a control stop process. This Control Stops process is performed with constant light intensity, constant exposure time,
Also, the photographic light-sensitive material (control strips) that has been exposed under standard exposure conditions of a certain light quality is developed, the density of the developed control strips is measured with a densitometer, and the processing solution is based on the measurement results. It is a work to check the state of. Such work is a troublesome work for the user and requires a densitometer separately, which is economically burdensome and needs to be improved.

In view of the above facts, a reference exposure portion for exposing a photosensitive material under the above-mentioned reference exposure conditions for producing control strips, and a photosensitive material exposed in the reference exposure portion and developed in the developing portion (control A film developing apparatus for providing a densitometer for measuring the density of strips), calculating the state of the processing liquid from the measurement result of the densitometer, and displaying the calculated state of the processing liquid on the display unit (JP-A-6-23).
No. 0543), or by exposing the photosensitive material by irradiating light in the exposure section under the standard exposure conditions, and measuring the density of the standard exposed and developed photosensitive material in the development processing section with a densitometer,
A photographic printing processing apparatus (Japanese Patent Laid-Open No. 6-236018) has been proposed which calculates the state of the processing liquid from the measurement result and displays the calculated state of the processing liquid on the display unit.

[0004]

However, in this film developing apparatus and photographic printing developing processing apparatus, only the abnormality of the photographic characteristics is detected, and the cause of the abnormality is not found at the time of abnormality, and therefore, the error is erroneous. Process control may be performed.

The present invention has been made in view of the above facts, and an object of the present invention is to provide a photographic light-sensitive material processing apparatus capable of highly precise quality control of photographic characteristics and processing solutions.

[0006]

In order to achieve the above object, the invention according to claim 1 is a density measuring means for measuring a specific density of a processed photographic light-sensitive material which has been processed by passing through a processing solution. A physical quantity detecting means for detecting a plurality of different physical quantities each having an influence on the photographic characteristics of the processed photographic light-sensitive material,
Judgment means for judging whether or not the specific density measured by the density measuring means is out of a predetermined range including a predetermined density, and the measured specific density is out of the predetermined range. When it becomes a value, it is configured to include a cause estimation unit that determines the physical quantity in a predetermined order and estimates the cause that the measured specific concentration becomes a value outside the predetermined range. There is.

According to a second aspect of the invention, in the first aspect of the invention, the physical quantity detecting means detects the state of the processing liquid as one of the physical quantities.

According to a third aspect of the present invention, in the first aspect of the invention, the physical quantity detection means replenishes at least a processing amount of the photographic light-sensitive material per unit time as the physical quantity and a replenishing solution for replenishing the processing solution. I try to detect the accuracy.

According to a fourth aspect of the present invention, in the invention according to any one of the first to third aspects, the predetermined order is the upper limit of the predetermined range of the measured specific concentration. The case where the value is larger than the value and the case where the value is smaller than the lower limit of the predetermined range are different.

The invention according to claim 5 is the invention according to any one of claims 1 to 4, wherein the control condition is determined according to the physical quantity and the processing liquid is maintained in an appropriate state. Based on the maintenance means for maintaining the treatment liquid in an appropriate state based on the cause, the control condition is changed so that the specific concentration measured based on the cause estimated by the cause estimating means becomes a value within the predetermined range. Change means to
Is further included.

According to a sixth aspect of the present invention, in the invention according to any one of the first to fifth aspects, the density measuring means measures at least the density of an unexposed portion of the processed photographic light-sensitive material. It is something that is done.

[0012]

As the specific density measured by the density measuring means of the present invention, any one of the density, the standard density, the maximum density and the minimum density of a predetermined portion of the processed photographic light-sensitive material is used. can do.

The density of the predetermined portion has a constant reproduction characteristic and a predetermined exposure condition (predetermined light intensity,
Exposure of the context after processing an undeveloped photographic light-sensitive material [control strip (hereinafter referred to as "context")], which has been exposed at a predetermined one or more points for a predetermined exposure time) with a processing solution. The concentration of the site that has been treated can be used. Incidentally, the photographic light-sensitive material processing apparatus of the present invention is provided with an exposing means for exposing a predetermined one or a plurality of points of the unexposed photographic light-sensitive material under the above-mentioned predetermined exposure conditions, and the exposing means is used to expose when necessary. You may make it like this and create a const.

As the maximum density, the density of the exposed portion of the photographic light-sensitive material or the maximum density of a pictorial image can be used.

As the minimum density, the density of the unexposed portion of the processed photographic light-sensitive material can be used, and the unexposed portion of the processed photographic light-sensitive material which has been processed with the processing liquid and exposed with a pictorial image (for example, , The area between the frame images) or the density of the processed photographic light-sensitive material that has been processed with the processing liquid and the frame image has not been exposed. Alternatively, the minimum density of a pictorial image may be used as the minimum density.

The standard density is obtained by exposing the photographic light-sensitive material to the standard density.

The different physical quantities which have an influence on the photographic characteristics of the processed photographic light-sensitive material detected by the physical quantity detecting means include the processing amount of the photographic light-sensitive material, the replenishment accuracy of each processing solution, and the residual quantity in the processed photographic light-sensitive material. The residual silver amount, the state of the processing solution, and the exposure time (or exposure amount) are average values. The state of each treatment liquid includes the temperature of each treatment liquid, the hydrogen ion exponent pH (or hydrogen ion concentration) of each treatment liquid, the specific gravity of each treatment liquid, the electrical conductivity (electric conductivity) of each treatment liquid, and There is an evaporation correction amount for each processing liquid.

It is preferable that the physical quantity detecting means detects at least the processing quantity per unit time and the replenishing accuracy of the replenisher for replenishing the processing solution as the physical quantity that affects the photographic characteristics of the processed photographic light-sensitive material.

The determining means determines whether or not the specific concentration measured by the concentration measuring means has become a value outside a predetermined range including a predetermined concentration, and the cause estimating means measures by the concentration measuring means. When the specified specific density is out of the predetermined range, the physical quantity is judged in a predetermined order to estimate the reason why the specific density is out of the predetermined range.

The above order will be described below. This order is
The cause of each concentration being outside the predetermined range determined according to each concentration, which was obtained from a number of experiments conducted for each of the above specific concentrations (minimum concentration, standard concentration, and maximum concentration) It is determined in consideration of the degree of association with the physical quantity. That is, the occurrence frequency of a physical quantity that is out of a predetermined range for a certain cause is determined, and the order is determined by associating the physical quantity with a high occurrence frequency with this cause with high relevance.

If the minimum density exceeds the upper limit value of a predetermined range that is predetermined so as to include the minimum density of the processed photographic light-sensitive material when it is processed with a processing solution of suitable performance, then the following steps 1 to Each physical quantity is determined in the order of 4. The minimum density does not fall below the lower limit of this allowable range. Step 1: Processing amount of photosensitive material Step 2: Accuracy of replenishing at least one of rinsing water and stabilizing solution Step 3: Accuracy of replenishing other processing solution Step 4: Other physical quantity Standard concentration is processed with processing solution of suitable performance When the value is below the lower limit of a predetermined range that is predetermined so as to include the standard density of the processed photographic light-sensitive material, each physical quantity is determined in the order of the following steps 1 to 4. Step 1: Accuracy of replenishment of developing solution Step 2: Processing amount of photosensitive material Step 3: At least one of pH and specific gravity of developing solution Step 4: Other physical quantity Processing when standard concentration is processed by processing solution of appropriate performance If the upper limit of a predetermined range that includes the standard density of the processed photographic light-sensitive material is exceeded, the following steps 1 to
Each physical quantity is determined in the order of step 4. Step 1: Processing amount of photosensitive material Step 2: Accuracy of replenishment of developing solution Step 3: At least one of pH and specific gravity of developing solution Step 4: Other physical quantity Processing when maximum concentration is processed by processing solution of suitable performance When the physical quantity is less than the lower limit value of the predetermined range that is predetermined so as to include the maximum density of the processed photographic light-sensitive material, each physical quantity is determined in the order of the following steps 1 to 6. Step 1: Replenishment accuracy of developing solution Step 2: Throughput of photosensitive material Step 3: At least one of pH and specific gravity of developing solution Step 4: Accuracy of replenishing at least one of bleaching solution and bleach-fixing solution Step 5: Bleaching solution and bleaching At least one of the pH and / or the specific gravity of at least one of the fixing solutions: Other physical quantity: The maximum concentration is predetermined to include the maximum concentration of the processed photographic light-sensitive material when processed with the processing solution of suitable performance. When exceeding the upper limit of the range, each physical quantity is determined in the order of the following steps 1 to 6. Step 1: Accuracy of replenishing bleaching solution Step 2: Amount of residual silver Step 3: pH of each processing solution Step 4: Electric conductivity of at least one of washing water and stabilizing solution Step 5: Temperature of each processing solution Step 6: Other Physical quantity Since the degree of association between the cause and the physical quantity changes depending on at least one of the type of photosensitive material and the type of processing liquid,
It is preferable to change according to these. In addition, it was confirmed from a number of experiments that at least one of the processing amount of the photosensitive material and the replenishment accuracy of the processing solution is highly related to all the causes. It is preferable to give priority to the judgment. Also,
Since the degree of relevance between the cause and the physical quantity differs between the region that exceeds the upper limit of the predetermined range and the region that is less than the lower limit of the predetermined range, this order is used when the specific concentration is higher than the upper limit of the predetermined range and when the lower limit of the predetermined range is reached. It is efficient to make it different for smaller cases.

The processing amount of the photographic light-sensitive material may be measured every unit time (period), for example, every day, every week, and every month. It is preferable to measure every predetermined period of one week to one month because the fluctuation of the treatment amount is small in a short period of about one day or two days, and the fluctuation of the treatment amount appears after a certain long period. That is, the processing amount for one week to the processing amount for one month, the processing amount per week (average value) to the processing amount per month (average value) in the integrated value for a plurality of days of the processing amount for one day, It is preferable to use.

Then, the range of the processing amount of one or a plurality of steps based on the ideal processing amount (ideal processing amount) capable of maintaining the state of the processing liquid in an ideal state (a state in which the photographic light-sensitive material can be appropriately processed) is set. It is set in advance, and it is determined whether the processing amount of the photographic light-sensitive material per unit time corresponds to the set one or a plurality of ranges.

Generally, 1/2 to 2 of the designated standard processing amount
It is preferable to define the double range as the allowable throughput.

The replenishment accuracy of each processing solution may be the replenishment accuracy of a developing solution, a bleaching solution, a fixing solution, a bleach-fixing solution, a rinsing solution, a stabilizing solution or the like. It can be calculated from the theoretical replenishment amount determined based on the amount of material processed and the actually replenished amount. For example, when the unit replenishing amount of the replenishing liquid per unit processing amount of the photographic light-sensitive material is set and the replenishing liquid is replenished at the replenishment timing,
The replenishment accuracy is based on the ideal replenishment amount calculated based on the integrated value of the processing amount up to the replenishment timing (the value obtained by dividing the integrated value of the processing amount by the unit processing amount by the unit replenishment amount),
The ideal replenishment amount and the actual replenishment amount actually replenished (can be calculated based on the liquid level in the replenisher tank that stores the replenisher liquid, or can be calculated with an integrating flowmeter that integrates the replenisher liquid flow rate). It is possible to obtain it by the ratio of the difference with (good). Note that this difference may be used instead of the replenishment accuracy, or the ratio of the actual replenishment amount to the ideal replenishment amount may be used.

Then, the first normal value which is preset
(For example, within ± 5%), a second range that is a dangerous area (for example, a range that is greater than ± 5% and ± 10% or less), and a third range that is an abnormal area (for example,
A plurality of ranges such as (a range larger than ± 10%) are set, and it is determined which of the predetermined ranges the replenishment accuracy corresponds to.

The replenishment accuracy of each processing solution may be recorded for each unit time, for example, for one week, preferably for each day, but it is stored as time series data over the past week or more, preferably over one month. Is preferred.

The amount of residual silver is determined by irradiating the maximum density portion or exposed portion of the pictorial image of the processed photographic light-sensitive material with infrared rays, for example, at the exit of the processing portion, and passing through the processed photographic light-sensitive material. Infrared rays reflected from the photographic light-sensitive material can be detected and the amount of infrared rays detected can be measured. The residual silver amount may be detected every unit time, for example, one week, preferably one day, but it is preferable to store it as time series data over the past one week or more, preferably one month or more.

If the treatment performance of the treatment liquid is good (within the standard range) or slightly good (standard limit range),
And if it is defective (outside of the standard limit), set multiple ranges,
It is to be decided which of the plurality of set ranges the residual silver amount falls into. For example, the standard range is 5
[Μg / cm ² ] or less, the standard limit range is 5
[[Mu] g / cm ^2] greater than 10 [[mu] g / cm ^2] or less of the range, as the outside specification limits 10 [[mu] g / cm ^2]
Larger ranges can be set.

As the temperature of each processing solution, the temperature for each of a plurality of processing solutions such as a developing solution, a bleaching solution, a fixing solution, a bleach-fixing solution, a rinsing solution (washing water) and a stabilizing solution can be used.
Then, a temperature range of one or a plurality of stages based on an ideal temperature (ideal temperature) capable of maintaining the treatment liquid in an ideal state is set, and the temperature of each treatment liquid is set to one or a plurality of the set temperatures. Be sure to determine which of the above ranges applies.

The pH, specific gravity and electric conductivity of the above processing solutions include the pH, specific gravity and electric conductivity of the processing solutions such as developing solution, bleaching solution, fixing solution, bleach-fixing solution, rinse solution and stabilizing solution. Although it is possible to use the measured value of the degree, it is preferable to use the pH and the specific gravity of the bleaching solution, the fixing solution, and the bleach-fixing solution for the pH and the specific gravity from the viewpoint of excellent measurement accuracy. It is preferable to use the electric conductivity of each of the rinse liquid and the stabilizing liquid. The pH, specific gravity, and electric conductivity of each treatment solution may be detected every unit time, for example, for one week, preferably for each day, but it is time series data over the past week or more, preferably over one month. It is preferable to remember.

Then, based on the standard pH, specific gravity and electric conductivity which can maintain the treatment liquid in an ideal state,
Or, the ranges of pH, specific gravity and electric conductivity of a plurality of stages are set respectively, and which of the above-mentioned set one or a plurality of ranges the detected pH, specific gravity and electric conductivity correspond to? Try to judge.

As the amount of evaporation correction of each processing solution, the amount of water added to correct the amount of evaporation of each processing solution such as a developing solution, a bleaching solution, a fixing solution, a bleach-fixing solution, a rinse solution and a stabilizing solution is used. be able to. This amount of water is calculated based on the amount of evaporation of the processing liquid obtained from the environmental temperature, the environmental humidity, the operating state of the photographic light-sensitive material processing apparatus, and the like, and is the amount of water supplied to the processing liquid. The temperature, the environmental humidity, the operating state of the photographic light-sensitive material processing apparatus, and the like may be stored at the same time. This evaporation correction amount is preferably recorded every day, but may be recorded as time series data for the past week or more, preferably for one month or more.

As the average value of the exposure time (or exposure amount), the light amount (exposure amount) received by the photographic light-sensitive material during printing or the image density of the photographic light-sensitive material can be used. That is, it is possible to use a value (average value) per image frame of the integrated value of the exposure amount and the image density of a plurality of image frames. Then, the range of the exposure amount and the image density of one or a plurality of steps based on the ideal ideal exposure amount and the ideal image density capable of maintaining the processing liquid in an ideal state is set, and the average value is set to this value. It is to be determined which of the above-mentioned one or a plurality of ranges is applicable. The number of frames of the plurality of image frames is at least 100 frames,
It is preferably about 500 to 5000 frames. The image density of the photographic light-sensitive material is obtained from the average density on the image surface.
This image plane average density includes the large area transmission density [LATD
(Large Area Transmittance
Desmity)] and image surface density average. Also,
The exposure amount of the photographic light-sensitive material and the image of the photographic light-sensitive material at the time of printing are preferably for a predetermined specific print size. It is particularly preferable that the predetermined specific print size is a general-purpose size (for example, E size or L size).

The maintaining means maintains the treatment liquid in the proper state based on the control condition which is determined according to the physical quantity and maintains the treatment liquid in the proper state. Such control conditions include a replenishment amount replenished at the replenishment timing and a set temperature for controlling the temperature of the processing liquid to a standard state.

The changing means changes the control condition so that the specific concentration becomes a value within a predetermined range based on the cause estimated by the cause estimating means.

The photographic light-sensitive material processing apparatus of the present invention is
For example, a photographic film processing device that processes photographic film, a photographic paper processing device that processes photographic paper (paper such as color paper), or a photographic film processing unit that processes photographic film and a photographic paper processing unit that processes photographic paper. It may be any of the photographic processing devices provided in the same casing. As described above, if the photographic processing apparatus is provided with the photographic film processing section and the photographic paper processing section in the same casing, more information can be obtained, and the specific density measured by the density measuring means falls within a predetermined range. This is a preferable mode because the cause of the outside can be accurately estimated.

As described above, when the specific concentration measured by the concentration measuring means becomes a value outside the predetermined range including the predetermined concentration, the physical quantity is judged in a predetermined order to measure the concentration. If the cause of the specific concentration measured by the means is out of the predetermined range is estimated, and the control condition is changed so that the specific concentration becomes a value within the predetermined range based on the estimated cause, Control conditions can be changed to suitable control conditions for maintaining the processing liquid in an appropriate state in a short time,
As a result, the processing performance of the processing liquid can be controlled within an allowable range, and photographic characteristics and quality control of the processing liquid with high accuracy become possible.

Further, when the specific concentration measured by the concentration measuring means is out of a predetermined range including a predetermined concentration, the physical quantity is judged in a predetermined order and the specific concentration measured by the concentration measuring means is determined. Since the cause of the concentration being out of the predetermined range is estimated, the cause can be specified quickly and efficiently. Therefore, if the control conditions are changed so that the specific concentration becomes a value within a predetermined range based on the identified cause, even if the processing performance of the processing liquid is out of the allowable range, the allowable range can be quickly set. It is possible to maintain the excellent photographic characteristics of the light-sensitive material.

Examples of the above-mentioned processing solutions include color developing solutions, black-and-white developing solutions, bleaching solutions, adjusting solutions, reversing solutions, fixing solutions, bleach-fixing solutions, stabilizing solutions and rinsing solutions.

The color developing solution is preferably an alkaline aqueous solution containing an aromatic primary amine type color developing agent as a main component. Although aminophenol compounds are also useful as the color developing agent, p-phenylenediamine compounds are preferably used, and a typical example thereof is 3
-Methyl-4-amino-N, N-diethylaniline, 4
-Amino-N-ethyl-N-β-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-β-
Hydroxyethylaniline, 3-methyl-4-amino-
N-ethyl-N-β-methanesulfonamide ethylaniline, 3-methyl-4-amino-N-ethyl-N-β-
Methoxyethylaniline, 3-methyl-4-amino-N
-Ethyl-N- [delta] -hydroxybutylaniline and their sulphates, hydrochlorides or p-toluenesulphonates. Two or more kinds of these compounds may be used in combination depending on the purpose.

The color developer is an alkali metal carbonate,
It generally contains a pH buffering agent such as borate or phosphate, a bromide salt, an iodide salt, a development control agent such as a benzimidazole, a benzothiazole or a mercapto compound, or an antifoggant. is there. Also, if necessary, various preservatives such as hydroxylamine, N, N-di (sulfoethyl) hydroxylamine, diethylhydroxylamine, sulfite, hydrazines, phenylsemicarbazides, triethanolamine, and catecholdisulfonic acids, ethylene glycol. , Organic solvents such as diethylene glycol, benzyl alcohol, polyethylene glycol, quaternary ammonium salts, development accelerators such as amines, dye-forming couplers, competitive couplers,
Fogging agent such as sodium boron hydride, 1
An auxiliary developing agent such as -phenyl-3-pyrazolidone,
Various chelating agents represented by viscosity imparting agents, aminopolycarboxylic acids, aminopolyphosphonic acids, alkylphosphonic acids, phosphonocarboxylic acids, for example, ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid. , Hydroxyethyliminodiacetic acid, carboxyethyliminodiacetic acid, 1-hydroxyethylidene-1,1-diphosphonic acid, nitrilo-N, N, N-trimethylenephosphonic acid, ethylenediamine-N, N, N ', N'- Tetramethylenephosphonic acid, ethylenediamine di (o-hydroxyphenylacetic acid) and their salts can be mentioned as representative examples.

The pH of these color developers is generally 9 to 12. The replenishing amount of these developing solutions depends on the color photographic light-sensitive material to be processed, but is generally 1 liter or less per square meter of the light-sensitive material, and 400 ml or less by reducing the bromide ion concentration in the replenishing solution. You can also do it. Preferably from 30 ml
It is 300 ml / m ² . When the replenishment rate is reduced, it is preferable to prevent evaporation of the liquid and air oxidation by reducing the contact area of the processing tank with the air. Further, the amount of replenishment can be reduced by using means for suppressing the accumulation of bromide ions in the developing solution.

The photographic emulsion layer after color development is usually bleached. The bleaching process may be performed simultaneously with the fixing process (bleach-fixing process), or may be performed individually. Further, in order to speed up the processing, a processing method of bleach-fixing processing after bleaching processing may be used. Further, treatment with two continuous bleach-fixing baths, fixing treatment before the bleach-fixing treatment, or bleaching treatment after the bleach-fixing treatment can be optionally carried out. Examples of bleaching agents include iron (III) and cobalt
(III), chromium (VI), compounds of polyvalent metals such as copper (II),
Peracids, quinones, nitro compounds and the like are used. Typical bleaching agents are ferricyanide: dichromate: iron
(III) or cobalt (III) organic complex salts, such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, ethylenediaminedisuccinic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, 1,3-diaminopropanetetraacetic acid, glycol etherdiaminetetraacetic acid, Aminopolycarboxylic acids such as carboxyethyliminodiacetic acid or complex salts such as citric acid, tartaric acid and malic acid: persulfates: bromates: permanganates: nitrobenzenes can be used. Of these, aminopolycarboxylic acid iron (III) complex salts including ethylenediaminetetraacetic acid iron (III) complex acid and persulfates are preferable from the viewpoint of rapid treatment and prevention of environmental pollution. Further, aminopolycarboxylic acid iron (II
The I) complex salt is particularly useful in both the bleaching solution and the bleach-fixing solution. The pH of a bleaching solution or a bleach-fixing solution containing these aminopolycarboxylic acid iron (III) complex salts is usually 4.5.
~ 8 but lower pH for faster processing
It can also be processed with.

If necessary, a bleaching accelerator can be used in the bleaching solution, the bleach-fixing solution and their pre-bath.
Specific examples of useful bleaching accelerators are described in the following specifications: US Pat. No. 3,893,858, West German Patent 1,290,812, JP-A-53-95630, Research. Disclosure No. 17129 (19
Compounds having a mercapto group or a disulfide bond described in, for example, July 1978); thiazolidine derivatives described in JP-A No. 50-140129; US Pat.
The thiourea derivative described in Japanese Patent No. 561;
35, iodide salt; West German Patent 2,748,43
Polyoxyethylene compounds described in No. 0; JP-B-45
A polyamine compound described in -8836; bromide ion or the like can be used. Among them, a compound having a mercapto group or a disulfide group is preferable from the viewpoint of a large accelerating effect, and particularly described in US Pat. No. 3,893,858, West German Patent No. 1,290,812, and JP-A-53-95630. Compounds are preferred. Further, U.S. Pat. No. 4,552,
The compounds described in No. 834 are also preferable. These bleaching accelerators may be added to the light-sensitive material. These bleaching accelerators are particularly effective when bleach-fixing a color photographic material for photography.

Examples of the fixing agent include thiosulfates, thiocyanates, thioether compounds, thioureas, and a large amount of iodide salts. The use of thiosulfates is common, especially ammonium thiosulfate. Is the most widely used. As a preservative for the bleach-fix solution, sulfite, bisulfite, benzenesulfinic acid or carbonyl bisulfite adduct is preferable.

Further, after the desilvering treatment, washing and / or stabilizing steps are generally performed. The amount of washing water in the washing process is
Characteristics of photosensitive material (for example, depending on materials used such as couplers),
It can be set in a wide range depending on the use, the washing water temperature, the number of washing tanks (the number of stages), the replenishment system such as countercurrent and forward flow, and various other conditions. Of these, the relationship between the number of washing tanks and the amount of water in the multi-stage countercurrent system is described in the Journal of the Society of
Motion Picture and Television Engineers Volume 64,
It can be determined by the method described in P248-253 (May 1955 issue).

According to the multistage countercurrent method described in the above-mentioned document,
Although the amount of washing water can be greatly reduced, the increase in the residence time of water in the tank causes problems such as bacteria breeding and adhered floating substances produced to the photosensitive material. In the processing of the color light-sensitive material of the present invention, as a solution to such a problem, the method of reducing calcium ion and magnesium ion described in JP-A-62-288838 can be used very effectively. Also, Japanese Patent Application Laid-Open No.
No. 8542, isothiazolone compounds, siabendazoles, chlorinated germicides such as chlorinated sodium isocyanurate, and other benzotriazoles, etc. Hiroshi Horiguchi, "Chemistry of Antibacterial and Antifungal Agents," Sanitary Technology Society, "Microorganisms" Sterilization of
The sterilizing agents described in "Sterilization and Antifungal Technology" and "Encyclopedia of Antibacterial and Antifungal Agents" edited by Japan Society for Antibacterial and Antifungal Agents can also be used.

The pH of washing water in the processing of the light-sensitive material of the present invention is 4 to 9, preferably 5 to 8. The washing water temperature and the washing time can be set variously depending on the characteristics of the light-sensitive material, the use, etc., but generally 15 to 45 ° C. for 20 seconds to 10 minutes,
A range of 30 seconds to 5 minutes at 25 to 40 ° C is preferably selected. Further, in the photographic light-sensitive material processing apparatus of the present invention, instead of the above-mentioned washing with water, processing can be directly carried out with a stabilizing solution.
In such stabilization treatment, Japanese Patent Laid-Open No. 57-854
3, JP-A-58-14834, JP-A-60-220.
All known methods described in No. 345 can be used.

Various chelating agents and antifungal agents can also be added to this stabilizing bath. The overflow solution that accompanies the washing with water and / or the supplement of the stabilizing solution can be reused in other steps such as the desilvering step.

Next, the photographic light-sensitive material that can be used in the present invention will be described. The present invention can be applied to any photosensitive material, but is preferably applied to a color negative film and a color paper.

The silver halide emulsion and other materials (additives and the like) and photographic constituent layers (layer arrangement and the like) applied in the present invention, and processing methods and processing additions applied to process the light-sensitive material. As the agent, the following patent publications, particularly European Patent EPO, 355,660A2 (Japanese Patent Application No.
Those described in No. 107011) are preferably used.

[0053]

[Table 1]

[0054]

[Table 2]

[0055]

[Table 3]

[0056]

[Table 4]

[0057]

[Table 5]

The silver halide emulsion used in the present invention is
Silver iodobromide, silver iodochloride, silver iodochlorobromide, silver chlorobromide, silver bromide,
Emulsions of various halogen compositions such as silver chloride can be used. Particularly, in the case of a color negative film, it is preferable to have a layer containing a silver iodobromide emulsion, and it is preferable to use an emulsion having an iodine content of about 0.1 to 10 mol%. Further, in the case of color paper, it is preferable to have at least one emulsion layer containing silver halide grains of which silver chloride is 90 mol% or more. More preferably 95 to 99.9 mol% or more, still more preferably 98 to 9
It is particularly preferable that the emulsion is 9.9 mol% or more of silver chloride, and the total layer is a silver chlorobromide emulsion of 98 to 99.9 mol% or more of silver chloride. As the coating amount of silver is not particularly limited, 2g~10g / m ² approximately in the case of color negative film, preferably it may contain about 0.2 to 0.9 g / m ² in the case of color paper .

The light-sensitive material used in the present invention may contain various couplers, the details of which are shown in Table 2.

Further, as a cyan coupler, JP-A-2-
In addition to the diphenylimidazole-based cyan coupler described in JP-A-33144, European Patent EPO, 333,185A2
3-Hydroxypyridine cyan couplers (especially the couplers (42) listed as specific examples, which are 4-equivalent couplers with a chlorine leaving group to make them 2-equivalent, couplers (6) and (9) Is particularly preferable) and cyclic active methylene cyan couplers described in JP-A-64-32260 (coupler examples 3, 8, and 34 listed as specific examples are particularly preferable) are also preferably used.

In the light-sensitive material according to the present invention, a hydrophilic colloid layer is added to the photosensitive colloid layer for the purpose of improving the sharpness of an image and the like, as described in European Patent EPO, 337,490A2.
A dye which can be decolorized by treatment (among others, an oxonol dye) described on page 76 is added so that the optical reflection density at 680 nm of the light-sensitive material is 0.70 or more,
It is preferable that the water-resistant resin layer of the support contains 12% by weight or more (more preferably 14% by weight or more) of titanium oxide surface-treated with a divalent to tetravalent alcohol (eg, trimethylolethane).

Further, the color photographic light-sensitive material according to the present invention, together with the coupler, has a European patent EPO, 277,589.
It is preferable to use a color image keeping improving compound as described in A2. In particular, it is preferably used in combination with a pyrazoloazole coupler.

That is, the compound (F) and // which chemically bond with the aromatic amine developing agent remaining after the color development processing to form a chemically inactive and substantially colorless compound.
Alternatively, the compound (G) which chemically bonds with an oxidized product of an aromatic amine color developing agent remaining after the color developing treatment to form a chemically inactive and substantially colorless compound is used simultaneously or alone. However, it is preferable to prevent the occurrence of stains and other side effects due to the formation of a coloring dye due to the reaction of the residual color developing agent in the film or the oxidant thereof with the coupler during storage after processing.

In order to prevent various molds and bacteria which propagate in the hydrophilic colloid layer and deteriorate the image, the light-sensitive material according to the present invention has an anti-mold property as described in JP-A-63-271247. It is preferable to add an agent.

In the present invention, it is preferable that the dry film thickness of the silver halide color photographic light-sensitive material, excluding the support, is 25 μm or less in order to reduce the carryover amount and increase the silver recovery rate. Particularly, in the case of a color negative film, about 13 to 23 μm is preferable, and in the case of car paper, about 7 to 12 μm is preferable.

The reduction of these film thicknesses is caused by the amount of gelatin, the amount of silver,
This can be achieved by reducing the amount of oil, the amount of coupler, etc., but it is most preferred that the amount of gelatin is reduced.
Here, the film thickness can be measured by an ordinary method after allowing the sample to stand at 25 ° C. and 60 RH% for 2 weeks.

In the silver halide color photographic light-sensitive material used in the present invention, the film swelling degree of the photographic layer is from 1.5 to
A value of 4.0 is preferable from the viewpoint of improving stain and improving image storability. Particularly, in the range of 1.5 to 3.0, a further effect can be obtained. The degree of swelling in the present invention means a value obtained by dividing the film thickness of the photographic layer after immersing the color light-sensitive material in distilled water at 33 ° C. for 2 minutes by the film thickness of the dried photographic layer.

The term "photographic layer" as used herein refers to a laminated hydrophilic colloid group layer containing at least one photosensitive silver halide emulsion layer and having a water-permeable relationship with this layer. The back layer provided on the opposite side of the support from the photographic photosensitive layer is not included. The photographic layer is usually formed of a plurality of layers involved in photographic image formation, and in addition to the silver halide emulsion layer, an intermediate layer, a filter layer, an antihalation layer, a protective layer and the like are included.

Any method may be used to adjust the degree of swelling. For example, the amount and type of gelatin used in the photographic film, the amount and type of hardener, or the drying conditions after coating the photographic layer. And can be adjusted by changing the aging condition. It is advantageous to use gelatin for the photographic layer, but more hydrophilic colloids can be used. For example, gelatin derivatives, graft polymers of gelatin and other polymers, proteins such as albumin and casein, cellulose derivatives such as hydroxyethyl cellulose, carboxymethyl cellulose, cellulose sulfates, sugar derivatives such as sodium alginate and starch derivatives; polyvinyl alcohol. Use of various synthetic hydrophilic polymer substances such as single or copolymers of polyvinyl alcohol partial acetal, poly-N-vinylpyrrolidone, polyacrylic acid, polymethacrylic acid, polyacrylamide, polyvinylimidazole and polyvinylpyrazole. You can

As the gelatin, in addition to lime-processed gelatin, acid-processed gelatin may be used, and gelatin hydrolyzate and gelatin enzyme-decomposed product may also be used. As the gelatin derivative, various compounds such as acid halides, acid anhydrides, isocyanates, bromoacetic acid, alkane sultones, vinyl sulfonamides, maleinimide compounds, polyalkylene oxides, epoxy compounds are added to gelatin. What is obtained by reaction is used.

As the gelatin-graft polymer, a homopolymer or a copolymer of vinyl monomers such as acrylic acid, methacrylic acid, derivatives thereof such as esters and amides, acrylonitrile and styrene are grafted onto gelatin. What was made to use can be used. In particular, a graft polymer with a polymer having a certain degree of compatibility with gelatin, for example, a polymer such as acrylic acid, methacrylic acid, acrylamide, methacrylamide, or hydroxyacyl methacrylate is preferable.
Examples of these are U.S. Pat. Nos. 2,763,625 and 2,8.
31, 767, 2,956, 884 and the like. Typical synthetic hydrophilic polymer substances are, for example, West German patent application (OLS) 2,312,708, US Pat.
No. 620,751, No. 3,879,205, Japanese Patent Publication No. 4
No. 3-7561.

Examples of hardening agents include chromium salts (chromium alum, chromium acetate, etc.), aldehydes (formaldehyde, glyoxal, glitalaldehyde, etc.), N-methylol compounds (dimethylol urea, methylol dimethylhydantoin, etc.), dioxane. Derivatives (2,3-dihydroxydioxane, etc.), active vinyl compounds (1,3,5-triacryloyl-hexahydro-s-triazine, bis (vinylsulfonyl) methyl ether, N, N'-methylenebis- [β- (vinyl Sulfonyl) propionamide] etc.), active halogen compounds (2,4-dichloro-6-hydroxy-s-triazine etc.), mucohalogen acids (mucochloric acid, mucophenoxycycloric acid etc.), isoxazoles, dialdehyde starch, 2-chlor And 6-hydroxy triazinyl gelatin can be used alone or in combination.

Particularly preferred hardeners are aldehydes, active vinyl compounds and active halogen compounds.

As the support used in the light-sensitive material according to the present invention, a white polyester support for display or a layer containing a white pigment is provided on the support having the silver halide emulsion layer. A support may be used. Further, in order to improve the sharpness, it is preferable to apply an antihalation layer on the silver halide emulsion layer coated side or the back side of the support. In particular, the transmission density of the support is 0.3 so that the display can be viewed with both reflected and transmitted light.
It is preferably set in the range of 5 to 0.8.

The light-sensitive material according to the present invention may be exposed to visible light or infrared light. The exposure method may be low-illuminance exposure or high-illuminance short-time exposure, and in the latter case, a laser scanning exposure method in which the exposure time per pixel is shorter than 10 ⁻⁴ seconds is preferable.

In the exposure, US Pat. No. 4,880,72
It is preferable to use the band stop filter described in No. 6. As a result, light color mixture is removed, and color reproducibility is significantly improved.

The present invention relates to various light-sensitive materials, that is, color negative flume, color negative paper, color reversal paper,
Auto positive paper, color reversal film, negative film for movie, positive film for movie, X-ray film,
A plate-making film such as a squirrel film, a black-and-white negative film, and the like can be mentioned, but application to a color negative film or a color negative paper is particularly preferable.

[0078]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A first embodiment of the present invention will be described below in detail with reference to the drawings. As shown in FIG. 1, a printer processor 10 as a photographic light-sensitive material processing apparatus of the present invention includes a light source unit 12 including a light control filter including C, M and Y filters, a reflection mirror and a halogen lamp, and a photographic light-sensitive material. And a paper magazine section 17 for accommodating color paper 16p having a size different from that of the color paper 16P.

The light emitted from the light source section 12 is exposed through the negative film N loaded in the negative carrier 18 to the exposure section 1.
4 is illuminated. In addition, a color paper 16P (color paper 16
It may be p. In the following, only the color paper 16P will be described as an example. ), The image of the negative film N is printed in the exposure unit 14, and the processor unit 10N
Be transported inside.

The processor section 10N includes a color development processing tank 10N1, a bleach-fix processing tank 10N2, and a rinse processing tank 1.
Each of the processing tanks 0N3 to 10N6 and the drying unit 10N7 are configured. A color development processing solution is stored in the color development processing tank 10N1, a bleach-fixing processing solution is stored in the bleach-fixing processing tank 10N2, and a rinsing processing solution is stored in each of the rinse processing tanks 10N3 to 10N6. As a result, the color paper 16P developed in the color development processing tank 10N1 is fixed in the bleach-fixing processing tank 10N2 and then rinsed in the rinsing processing tank 10.
A color print is created by washing with N3 to 10N6 and drying in a drying unit 10N7. This color print is placed on the sorter unit 10N8.

The printer processor 10 includes a display panel 72 on the upper part of the printer processor 10 (upper side of FIG. 1), a code reading sensor 55 for reading the bar code and DX code recorded on the negative film N on the negative carrier 18. And the reflection mirror 14N1 of the exposure unit 14.
Scanners 14N3 for detecting the amount of exposure (corresponding to the negative density) by detecting the light transmitted through the image of the negative film N via the lens 14N2 are installed on the reflection side of the. In addition, this printer processor 10
A densitometer 22 that measures the density of the image on the color paper 16P that has been conveyed into the density measuring unit 22N is installed therein. Further, an environmental temperature sensor 54 that detects an environmental temperature and an environmental humidity sensor 56 that detects an environmental humidity are installed at locations where the drying section 10N7 and the exposure section 14 are not affected by heat.

When the printer processor 10 is connected to another film processor having an environmental temperature sensor, a code reading sensor and an environmental humidity sensor by a communication line, the environmental temperature detected by the film processor, You may make it take in the information of environmental humidity, a barcode, and a DX code. In this case, the code reading sensor 55, the environmental temperature sensor 54, and the environmental humidity sensor 56 of the printer processor 10 can be omitted. The printer processor 10 is provided with a control unit 60 that performs various controls.

As shown in FIG. 2B, on the upstream side of the color development processing tank 10N1 in the conveying direction of the color paper 16P, an infrared emitting portion 32N and a detecting portion 34N are arranged to face each other with a predetermined gap. Photo sensor is provided. As shown in FIG. 2A, the infrared radiation unit 32N
Is a plurality (six (in this embodiment, not limited to six) infrared emitting elements (infrared emitting diodes) 3)
2N1 to 32N6 in the conveying direction X of the color paper 16P
The detector 34N is arranged in a direction (width direction of the color paper) that intersects with the infrared radiation element 32.
Detection elements (photodiodes) 34N1 to 34N6 for respectively detecting the infrared rays emitted from N1 to 32N6 are arranged in a direction intersecting the transport direction X of the color paper 16P. In addition, the infrared radiation elements 32N1 to 32N1
32N6 and the detection elements 34N1 to 34N6 are the control unit 60.
(See FIG. 7).

Next, each of the processing tanks 10N1 to 10N6 will be described. Since the color development processing tank 10N1 and the bleach-fixing processing tank 10N2 have the same configuration, only the color development processing tank 10N1 will be described.
The description of 2 is omitted. The color development processing tank 10N1 is shown in FIG.
As shown in FIG. 1, a processing tank 1 for storing a color development processing solution
0M, sub tank 10M in communication with processing tank 10M
S, a replenishment tank 44M that stores a replenishment liquid to be replenished in the sub tank 10MS, and a water replenishment tank 45M that stores water to be replenished in the sub tank 10MS.

The sub tank 10MS is connected to the replenishment tank 44M via the replenishment nozzle 42 and the replenishment pump 44N so as to replenish the replenishment liquid, and the replenishment nozzle 4
2 and the replenishment pump 48L so as to replenish water with the water replenishment tank 45M.

The replenishment tank 44M includes a replenishment tank 44M.
An ultrasonic level meter 46N for detecting the level of the replenisher is provided. The water supply pipe connected to the water replenishment tank 45M is provided with a water flow meter 48N that detects the amount of water supplied via the replenishment pump 48L.

The sub-tank 10MS has a temperature sensor 40N for detecting the temperature of the color development processing solution in the sub-tank 10MS, a pH sensor 38N for detecting the pH of the color development processing solution, and a specific gravity for detecting the specific gravity of the color development processing solution. 36 in total
A level detector 34 for detecting the levels of N and the color developing solution is provided.

Reference numeral 32 is an outlet for overflowing the color developing solution. The color development processing tank 10N1 includes a processing tank 10M and a sub tank 10M.
A circulation device 30 that circulates the color development processing solution stored in S in the direction indicated by the broken line is provided. The circulation device 30 includes a circulation pump 30N1, a cooling fan 30N2, a heater 30N3, a circulation flow meter 51, and a filter mounting rod 3.
0N5 and a circulation filter 30N4. By the circulation device 30, temperature control (feedback control) is performed so that the temperature of the color development processing liquid becomes a set temperature (a temperature for appropriately processing the color paper 16P (for example, 35 [° C.])). There is.

Next, the rinse treatment tanks 10N3 to 10N5 will be described. Since they have the same configuration, the rinse treatment tank 10N3 will be described and the other rinse treatment tanks 10N will be described.
The description of 4, 10N5 is omitted. Rinse treatment tank 10N3
As shown in FIG. 4, the color development processing tank 1 shown in FIG.
Since the configuration is substantially the same as that of 0N1, the description thereof will be omitted by assigning the same reference numerals to the portions corresponding to those of FIG. 3, but the pH sensor 38N and the pycnometer 36N provided in the sub tank 10MS of the color development processing tank 10N1 are omitted. The color development processing tank 10N1 is different from the color development processing tank 10N1 in that it does not include a sensor corresponding to.

As shown in FIG. 5, the final rinse treatment tank 10N6 has substantially the same structure as that of the rinse treatment tank 10N3 shown in FIG. 4, but the piping from the circulation filter 30N4 to the inlet of the circulation pump 30N1. The rinsing tank 10N3 is different in that a coil-type electric conductivity meter 50 is additionally provided.

As shown in FIGS. 6A and 6B, the hydrometer 36N is composed of a measuring unit 62 and a detecting unit 68, and the detecting unit 68 has an oscillator 64H for oscillating ultrasonic waves and an ultrasonic wave. The receiver 66H for receiving the signal is provided as a pair. The oscillator 64H and the receiver 66H are supported by the support member 52 so as to be opposed to each other with the treatment liquid interposed therebetween. The oscillator 64H of the detection unit 68 is composed of a piezoelectric element such as piezoelectric ceramics, and oscillates a predetermined ultrasonic wave when a predetermined voltage is applied from the oscillation circuit 72 of the measurement unit 62. Further, the receiver 66 outputs a predetermined signal when receiving the ultrasonic wave oscillated from the oscillator 64H.

The measuring section 62 includes an oscillator circuit 72 connected to an oscillator 64H and a receiver circuit 7 connected to a receiver 66H.
4, a time measuring circuit 76 connected to the oscillator circuit 72 and the receiving circuit 74, and an arithmetic circuit 78 connected to the time measuring circuit 76. In this measuring unit 62,
The oscillator circuit 72 causes the oscillator 64H to generate ultrasonic waves, and when the receiver 66H receives the ultrasonic waves, the receiving circuit 74 outputs a reception signal. The time measuring circuit 76 measures the time until the ultrasonic wave oscillated from the oscillator 64H is received by the receiver 66H, and outputs the measured time to the arithmetic circuit 78. In the arithmetic circuit 78, the time required for the ultrasonic waves stored in advance to propagate through the support member 52 (oscillator 64
The time required for the ultrasonic wave to propagate through the support member 52 by the distance obtained by subtracting the inner diameter D ₂ of the support member 52 from the distance D ₁ between the H and the receiver 66H) is subtracted from the time input from the time measuring circuit 76. Then, the time required for the ultrasonic waves to propagate in the color developing solution (distance D ₂ ) is determined, and the propagation speed at which the ultrasonic waves propagate in the color developing solution is calculated from the determined time and the distance D ₂ . An output value [mV] proportional to the propagation velocity is output to the control unit 60.

The control section 60 controls the color paper 1 which will be described later.
A map (see FIG. 17) corresponding to the processing amount of 6P is selected, and the specific gravity is calculated based on the selected map and the output value [mV] proportional to the input propagation velocity.

Next, the control unit 60 will be described. As shown in FIG. 7, the control unit 60 includes a CPU 62, a ROM 64,
It is configured by a microcomputer including a RAM 66, an input / output port 68, and a bus 70 that connects these to each other. Note that subscripts 1 to 6 attached to the reference numerals in FIG.
Are, in order, a color developing tank 10N1 and a bleach-fixing processing tank 10N.
2, the elements provided in the rinse treatment tanks 10N3 to 10N6 are represented. That is, the input / output port 68 is connected to the environmental temperature sensor 54 and the environmental humidity sensor 5.
6, infrared radiation elements 32N1 to 32N6, detection element 34
N1～34N6, the temperature sensor 40N ₁ ~40N _6, ultrasonic level meter 46N ₁ ~46N _6, conductance meter 50 _6,
pH sensors 38N ₁ and 38N ₂ , specific gravity meters 36N ₁ and 36
The N ₂ , the replenishment flowmeters 48N _{1 to} 48N ₆ , the densitometer 22, and the code reading sensor 55 are connected. Also,
The input / output port 68 includes a display panel 72 and a replenishment pump 44.
N ₁ ~44N _6, is connected to a replenishing pump 48L ₁ ~48L ₆ and circulating pump 30N1 ₁ ~30N1 _6,.
The input / output port 68 is not shown,
A transport system for transporting the light source unit 12, the exposure unit 14, and the color paper 16P is also connected.

Next, the operation of this embodiment will be described. Here, when the power is turned on, the printer processor 10
Controls the temperature control of each processing liquid. After that, when the negative film N is loaded, the image frames recorded on the negative film N are printed and exposed on the color paper 16P, and the color paper 16P that has been printed and exposed is developed, fixed and washed with water. The state in which the power is turned on and the color paper 16P is not processed is called a standby state, and the state in which the power is turned on and the color paper 16P is processed is called a drive state. Then, the power supply is turned off and the temperature control is stopped on a rest day or at night. This state is called a stopped state. In this example,
The case where there is at least a standby state and a stopped state every day will be described as an example.

First, the processing performance management processing routine for managing the processing performance of the processing liquid of this embodiment will be described with reference to FIG.

When it is determined that the temperature of the processing liquid has reached the set temperature because the printer processor 10 has changed from the stopped state to the standby state, it is drawn out from the photosensitive material magazine 16 using the ND filter incorporated in the printer processor 10. Paper 16P reaching the exposure unit 14 by
Is exposed to a standard density, and the exposed color paper 16P is conveyed by a conveying roller, and each processing tank 10N
1 to 10N6 to pass through each treatment solution to be treated,
It passes through the drying unit 10N7. When the color paper 16P reaches the installation position of the densitometer 22 after passing through the drying unit 10N7 and the transport path is switched to the density measuring unit 22N by a switching unit (not shown), a paper detection sensor (not shown) scans the color paper 16P. To detect. By this detection, the density is fetched from the densitometer 22 in step 102 of the routine of FIG. The processing for capturing the density will be described with reference to FIG.

First, in step 132, the exposed portion (the portion exposed so as to have the standard density) is measured, and step 13
In step 4, the three primary color signals of R, G, and B obtained by photometry are captured, and in step 136, the captured three primary color signals are converted into R,
The density of each color of G and B is converted and stored.

In step 138, the unexposed portion (the portion other than the portion exposed to the standard density) is measured, and in step 140 the three primary color signals of R, G, B obtained by the photometry are fetched, and in step 142 Then, the fetched three primary color signals are converted into densities of R, G, and B colors and stored, and the routine proceeds to step 104 (see FIG. 8).

By the above processing, color paper 16P
The densities (standard density and minimum density D _min ) of the three primary colors of R, G, and B in the exposed and unexposed areas of are taken.

In step 104, it is judged whether or not there is an abnormality in the densities of the three primary colors of R, G, B of the exposed and unexposed areas that have been taken in. It should be noted that this judgment is made for each of the densities of the three primary colors of R, G, B of the exposed and unexposed areas that have been taken in,
The exposed area and the unexposed area captured by comparing the allowable range including the standard densities of the three primary colors of R, G, and B and the allowable range including the minimum density of the three primary colors of R, G, and B. If the densities of the three primary colors of R, G, and B are outside the allowable range, it is determined that there is an abnormality. Note that it may be determined whether or not there is an abnormality in the density of either the exposed portion or the unexposed portion.

If the determination in step 104 is negative, the processing liquid has appropriate performance, so this processing is terminated. If the determination in step 104 is positive, the processing performance of the processing liquid is abnormal. In order to estimate the cause of the abnormality, in step 106, the physical quantity that affects the photographic characteristics of the color paper 16P is determined.

This determination process will be described in detail with reference to FIG. In step 146, the variable i is initialized to 0,
In step 148, the variable i is incremented by 1.

At step 150, it is checked (determined) whether or not the check item i is abnormal. The check item is a physical quantity that affects the photographic characteristics of the color paper 16P, and this physical quantity is identified by the variable i. If the determination in step 104 of FIG. 8 is affirmative, the R, G, and B of at least one of the exposed portion and the unexposed portion that have been taken in are 3
There is an abnormality in the density of the primary colors. In addition, the density abnormality is that the density of the unexposed area (minimum density) exceeds the upper limit value of the allowable range, the density of the exposed area (standard density) is lower than the lower limit value of the allowable range, and the standard density is There are three modes in which the upper limit of the allowable range is exceeded, and the order of check items i is determined for each mode. This order is obtained from a number of experiments and is determined in order of increasing relevance to the cause of abnormal concentration. The check order and details of the check process will be described later.

If the determination in step 150 is negative, the process returns to step 148 and the above processing (step 14
8 and step 150) are repeated. On the other hand, step 1
If the determination in 50 is affirmative, in step 152,
The abnormality content (check item that is abnormal and the content thereof) is stored, and in step 154, it is determined whether the cause of the abnormal concentration can be specified from the stored abnormality content. In other words, if the checked check item is abnormal, it is possible to directly identify the cause of the abnormal concentration based on the abnormal check item, and if the concentration is abnormal based on the combination of multiple abnormal check items. In some cases, it is possible to specify the cause of the abnormality, and in this embodiment, the abnormal check item pattern and the cause of the abnormal concentration are stored in association with each other. Therefore,
In step 154, the stored abnormality content is compared with the abnormal check item pattern, and it is determined whether or not the cause of the abnormal concentration can be identified.

If the determination in step 154 is negative, it is determined in step 156 whether or not the variable i has exceeded the total number i ₀ of check items i determined for each mode. Judge whether or not the item is judged.

If the determination in step 156 is negative, there is an item that has not been checked, so the process returns to step 148 and the above-described processing (step 148-
Repeat step 156).

If the determination in step 156 is negative, all the check items have been checked but the cause could not be specified. Therefore, in step 158, it is stored that the determination is not possible, and step 108 in FIG. move on.

On the other hand, if the cause of the abnormal concentration can be identified from the abnormality content stored in step 152, the determination in step 154 is affirmative and the routine proceeds to step 108 in FIG.

Next, the order of the check items i will be described for each mode. If the density of the unexposed area (minimum density) exceeds the upper limit of the allowable range, the processing amount of the color paper 16P, the replenishment accuracy of the rinse tank, the replenishment accuracy of other processing tanks, and other physical quantities may be abnormal in this order. Check if there is. Other physical quantities include, in the order of check, electric conductivity of washing water, temperature of each processing solution, pH of color development processing solution and bleach-fix processing solution, specific gravity of color development processing solution and bleach-fix processing solution,
There is the amount of water added to each processing solution.

When the density of the exposed area (standard density) is below the lower limit of the permissible range, the replenishment accuracy of the color developing tank, the processing amount of the color paper 16P, the pH and / or the specific gravity of the color developing processing solution, and It is checked whether or not there is an abnormality in the order of other physical quantities. The order of other physical quantities can be determined in the same manner as above.

When the density (standard density) of the exposed area exceeds the upper limit of the allowable range, the processing amount of the color paper 16P, the replenishing accuracy of the color developing tank, the pH and specific gravity of the color developing solution, and other It is checked whether or not there is an abnormality in the order of physical quantities. The order of the other physical quantities can be determined in the same manner as above.

If it is determined in step 104 that there are a plurality of abnormal density states, the check items are checked in the above order for each aspect. Then, the cause of the abnormal concentration is estimated for each mode, and it is determined whether the estimated causes are the same. It should be noted that the order of determining the abnormal mode may be arbitrary.

Tables 6 and 7 below show examples of the relationship between the check item pattern and the cause.

When the density of the unexposed area (minimum density) exceeds the upper limit of the allowable range

[0116]

[Table 6]

[0117]

When the density (standard density) of the exposed area is below the lower limit of the allowable range

[0119]

[Table 7]

The relationship between the check item pattern and the cause when the density (standard density) of the exposed portion exceeds the upper limit of the allowable range can be determined in the same manner as above.

Next, the check processing of each check item will be described. Checking the throughput of color paper 16P
As will be described later, in this embodiment, the color paper 16P is used.
The processing amount of is stored in time series for each week and one month. Therefore, the latest processing amount of the color paper 16P for each week and each month stored in this time series is taken in and taken in for one week. And the amount of processing per month is within an allowable range (a range of the amount of the color paper 16P to be processed in order to maintain the photographic characteristics of the color paper 16P within the allowable range).

The replenishment accuracy of each processing tank is checked, as will be described later, because the replenishment accuracy based on the processing amount of the color paper 16P for one week is stored. The latest replenishment accuracy based on the processing amount of the color paper 16P is fetched, and it is determined by judging whether the fetched replenishment accuracy is within an allowable range (range in which replenishment accuracy is good).

In this embodiment, if the replenishment accuracy of each processing tank is out of the range of ± 5%, that fact is stored, but the replenishment accuracy of each processing tank is ± 5%. It may be possible to determine whether or not it is outside the two ranges, that is, a range within (first allowable range) and a range within ± 10% and a range exceeding ± 5% (second allowable range).

As will be described later, the electrical conductivity of the rinse liquid in the final rinse treatment tank 10N6 is stored in time series, so that the electrical conductivity of the rinse liquid stored in this time series is checked. The conductivity is taken in, and the taken electric conductivity is based on the ideal electric conductivity of the rinse liquid in the final rinse treatment tank 10N6 for keeping the photographic characteristics of the color paper 16P within the allowable range. It is performed by judging whether it is within the allowable range).

As will be described later, the temperature of each processing liquid is checked in time series because the temperature of each processing liquid is stored in time series.
Taking in the temperature of each processing liquid stored in this time series,
This is performed by determining whether the temperature of each of the processing liquids taken in is within a permissible range based on the set temperature.

As will be described later, the pH of the development processing solution and the bleach-fixing processing solution is checked in the time series, so that the pH of the development processing solution and the bleach-fixing processing solution are stored in time series. The pH of the development processing solution and the bleach-fixing processing solution that have been taken in is within an allowable range (the ideal pH of the development processing solution and the bleach-fixing processing solution for maintaining the photographic characteristics of the color paper 16P within the allowable range). It is performed by judging whether it is within the allowable range based on

As to the specific gravity check, since the specific gravities of the development processing solution and the bleach-fixing processing solution are stored in time series as described later, the development processing solution and the bleach-fixing processing solution stored in this time series are stored. The specific gravity of the development processing solution and the bleach-fixing processing solution that have been taken in is within an allowable range (ideal specific gravity of the development processing solution and the bleach-fixing processing solution for keeping the photographic characteristics of the color paper 16P within the allowable range). It is performed by judging whether it is within the allowable range based on

As to the check of the amount of water added, as will be described later, the amount of actual water added and the theoretical amount of water added for each treatment liquid are stored in time series. The amount of water added is taken in and it is determined whether or not the amount of actual water added is within an allowable range (an allowable range from the theoretical amount of water for maintaining the photographic characteristics of the color paper 16P within the allowable range).

Next, the routine for detecting the processing amount, the temperature of the processing liquid, the replenishment accuracy and the like will be described in detail.

A processing amount detection routine for detecting the processing amount of the color paper 16P will be described with reference to FIG.

As described above, the color paper 16 on which the image of the negative film N is printed in the exposure section 14
P is carried into the processor unit 10N. At this time, the color paper 16P includes the infrared radiation unit 32N and the detection unit 3
It passes between 4N (see FIG. 2B). On the other hand, since the infrared radiating elements 32N1 to 32N6 constantly radiate infrared rays, the color paper 16P is not radiated by the infrared radiating section 32N.
And the detection unit 34N, the color paper 1
Infrared rays are blocked by 6P.

When the infrared rays from any of the infrared radiating elements 32N1 to 32N6 are cut off, the detecting elements 34N1 to 34N1 to 34N1 to 34N3 are cut off.
A cutoff signal is input to the control unit 60 from 4N6. When this cut-off signal is input from any of the detection elements 34N1 to 34N6, the determination in step 162 is affirmative, that is, it is determined that the leading edge of the color paper 16P has passed, and step 164 starts timing, 166
Then, the width of the color paper 16P is detected from the number of detection elements that output the cutoff signal. That is, the infrared radiation elements 32N1 to 32N6 and the detection elements 34N1 to 34N6.
Are arranged in a direction intersecting the transporting direction X of the color paper 16P, as described above, so that when the color paper 16P passes between the infrared radiation unit 32N and the detection unit 34N, the width of the color paper 16P becomes smaller. The cutoff signals are output from the corresponding detection elements 34N2 to 34N5, and the color paper 16 is calculated based on the number of detection elements that output the cutoff signals.
The width of P can be detected.

In the next step 168, color paper 1
It is determined whether or not the rear end of the color paper 16P has passed by determining whether or not the blocking of infrared rays by 6P has been released. When the passage of the rear end of the color paper 16P is detected, the determination in step 168 is affirmed, and in step 170, the time measurement is ended. As described above, the time required for the color paper 16P to pass between the infrared emitting section 32N and the detecting section 34N is measured.

At the next step 172, the total area of the continuously processed color paper 16P is calculated as the processing amount of the color paper 16P. That is, since the transport speed of the color paper 16P is determined in advance, the length of the color paper 16P can be detected from this transport speed and the time measured, and this length and the width of the color paper 16P detected in step 146 can be detected. From color paper 16P
The total area of can be calculated.

As described above, every time the color paper 16P is processed, the total area (processing amount) of the processed color paper 16P is integrated, and one day, one week, one month, and the processing liquid is in a fresh state (color paper). The processing amount of each color paper 16P from the state where 16P is not processed is stored in a time series together with the date data (year, month, day).

A temperature detection routine for detecting the temperature of each processing liquid will be described with reference to FIG. This routine is executed by an interrupt process when it is determined that the printer processor 10 has changed from the stopped state to the standby state and the temperature of the processing liquid has reached the set temperature, and in step 176, the temperature of each processing liquid is detected by the temperature sensor 40N _1. uptake from ~40N _6, the temperature taken to store along with the date data.

A replenishment accuracy detection routine for detecting the replenishment accuracy of the processing tank will be described with reference to FIG. It should be noted that this routine is executed every week, for example, when it is determined that the printer processor 10 is stopped on Sunday,
In step 182, the ultrasonic level meter 46N _{1 of} each processing tank
The level of each replenisher (current level) is fetched from .about.46N ₆ , and in step 184, the previous level, that is, the level of each replenisher one time before the execution of this routine (one week ago) is fetched. In step 186, the actual replenishment amount (replenishment amount) is calculated from the current level, the previous level, and the shape data (for example, the bottom area) of the replenishment liquid storage portion of each replenishment tank 44M. .

At step 188, the current level (the level fetched at step 182) and the calculated actual replenishment amount are stored together with the date data.

In step 190, the processing amount of the color paper 16P for one week from the execution of this routine last time by referring to the date data is taken in, and in step 192, the ideal replenishment amount Is calculated.
That is, in this embodiment, the replenishing liquid is supplied to V (for example, 50) each time the processing amount of the color paper 16P reaches the predetermined value S1.
[Ml]) I try to replenish. Therefore, the total processing amount S0 that processed the color paper 16P within the past week
The ideal replenishment amount H for is obtained from the following equation (1).

[0140]

## EQU1 ## H = (S0 / S1) × V (1) In step 194, the replenishment accuracy of each processing tank, that is, the error of the actual replenishment amount from the ideal replenishment amount is calculated, and step 1
At 96, the calculated replenishment accuracy of each processing tank is stored together with the date data.

The process of storing the electrical conductivity of the rinse liquid in the final rinse treatment tank 10N6 in time series is the same as the temperature detection routine, and therefore its explanation is omitted.
When the temperature detection routine ends, it is executed by interrupt processing. The reason why only the electrical conductivity of the rinse liquid in the final rinse treatment tank 10N6 is detected is that the electrical conductivity can be detected more accurately as the concentration of the treatment liquid is smaller. The electric conductivity of the rinse liquid other than the final rinse tank may be detected.

The process for storing the pH values of the developing treatment solution and the bleach-fixing treatment solution in time series is the same as the above temperature detection routine, so the description thereof will be omitted. However, in this processing, the processing for detecting the electric conductivity is omitted. It is executed by interrupt processing when it is finished. The reason why only the pH of the development processing solution and the bleach-fixing processing solution is detected is that the higher the concentration of the processing solution, the more accurately the pH can be detected. The pH of a processing solution other than the developing processing solution and the bleach-fixing processing solution may be detected.

A specific gravity detection routine for detecting the specific gravity of the developing treatment liquid will be described with reference to FIG. First, the principle of specific gravity detection in this embodiment will be described. For example, the density when the composition of the solution is one component such as caustic soda (NaOH) can be determined if the propagation velocity of ultrasonic waves in the solution can be detected. That is, when the propagation velocity of the ultrasonic waves in the solution is V and the bulk modulus of the solution is E, the density ρ of the solution is obtained from the following equation (2).

[0144]

## EQU2 ## ρ = E / V ² (2) If the density of the solution is obtained in this way, the specific gravity of the solution can also be obtained from this density.

However, since the treatment liquid is composed of multiple components as described above, the bulk elastic modulus E of the treatment liquid changes depending on the type of chemical component and the ratio of the components.
Even if the propagation velocity of ultrasonic waves in the treatment liquid and the treatment liquid are detected,
The specific gravity cannot be obtained accurately.

On the other hand, the inventors of the present invention sampled the processing liquids of a plurality of film processors of the same type (3 units will be described as an example for convenience of explanation) and dilute each processing liquid with water. Meanwhile, the propagation velocity of ultrasonic waves propagating in the treatment liquid at that time was measured, and at the same time, the specific gravity was measured by a specific gravity meter serving as a reference. The results are shown in FIG. 15 and FIG.
6 is shown. FIG. 15 shows the relationship between the output value [mV] proportional to the propagation velocity of ultrasonic waves propagating in the bleaching solution of each film processor and the measured specific gravity.
6 shows the relationship between the measured specific gravity and the output value [mV] proportional to the propagation velocity of the ultrasonic wave propagating in the fixing solution of each film processor. As can be understood from these figures, different processors have different specific gravities even with the same propagation speed. In addition, these specific gravities were obtained by using a hydrometer such as a float type or a pendulum type.

It is considered that the reason why the specific gravities are different when the processors are different even if the propagation speed is the same is that the processing amounts of the negative films N processed by the respective film processors are different. This is because when the negative film N is treated with the treatment liquid, a predetermined component is eluted from the negative film N into the treatment liquid, and the larger the treatment amount is, the larger the elution amount is, and the composition of the treatment liquid changes accordingly. . That is, the amount of change in the composition of the treatment liquid is determined according to the treatment amount. On the contrary, even if the specific gravity is the same, if the treatment amount is different, the composition of the solution is different, which causes the ultrasonic wave propagation velocity to be different.

Therefore, when the relationship between the propagation velocity of ultrasonic waves propagating in the processing liquid of a large number of film processors and the measured specific gravity is investigated together with the processing amount of the negative film N while the processing liquid is diluted with water, , The relationship shown in FIG. 17 was obtained. That is, FIG. 17A shows the relationship between the propagation velocity and the measured specific gravity when the bleaching solution is in a fresh state (a state in which the negative film N is not yet treated). FIG. 17B shows the relationship between the propagation velocity of ultrasonic waves propagating in the bleaching solution and the measured specific gravity when the processing amount of the negative film N is a certain processing amount K. FIG. 17
(C) shows the relationship between the propagation velocity and the measured specific gravity when the fixer is in a fresh state. FIG. 17
(D) shows the relationship between the propagation velocity of ultrasonic waves propagating in the fixing solution and the measured specific gravity when the processing amount of the negative film N is a certain processing amount K. In addition, this treatment liquid is
The processing liquid "CN-16X" (trade name) for color negative film of Fuji Film Co., Ltd. was used.

As described above, even if the processing liquids of the same type of film processors have different processing amounts of the negative film N, the relationship between the propagation velocity and the specific gravity of the processing liquids is different.
When the throughput is the same, the relationship between the propagation velocity and the specific gravity is the same.

By the way, the film processor has been described above, but the same can be said for the printer processor.

Therefore, in this embodiment, a map similar to that shown in FIG. 17 is stored for each predetermined processing amount of the relationship between the propagation velocity of ultrasonic waves in the processing liquid and the specific gravity. In FIG. 17,
The relationship in the fresh state and the relationship when the treatment amount is K is shown for each treatment liquid, but each map is shown for a plurality of treatment amounts that are defined in the range of the treatment amount between 0 and K and beyond K. Has been defined. Further, regarding the relationship between the propagation velocity and the specific gravity, the inclination of the straight line showing the relationship between the propagation velocity and the specific gravity tends to increase as the processing amount increases.

Incidentally, a map showing the relationship between the propagation velocity of ultrasonic waves in the processing liquid and the specific gravity may not be stored, but a similar data table may be stored, or the processing liquid corresponding to the processing amount may be stored. You may make it memorize | store the arithmetic expression which shows the relationship between the propagation velocity of the ultrasonic wave in it, and specific gravity. Note that a map or the like depending on the temperature may be stored. That is,
As described above, in the present embodiment, the temperature of the processing liquid is controlled to the set temperature. However, a plurality of set temperatures of the processing liquid are prepared, and the set temperature is selected when the predetermined condition is satisfied. When controlling to the selected set temperature, a map showing the relationship between the propagation velocity of ultrasonic waves in the processing liquid and the specific gravity according to this temperature (map for each range of predetermined processing amount)
To remember. As a result, the temperature of the specific gravity is corrected.

This routine (see FIG. 14) starts when the process of storing the pH values of the developing treatment solution and the bleach-fixing treatment solution in time series is completed.

First, at step 202, the total processing amount of the color paper 16P from the fresh state is taken in, and at step 204, the map (the map similar to FIG. 17) having the closest processing amount to the total processing amount taken in is selected. .

[0155] At step 206, ultrasound as described above color developing solution (the distance D ₂₎ color developing solution which is calculated from the time required for propagation and the distance D ₂ of the ultrasound propagates An output value [mV] proportional to the propagation velocity is taken in, in step 208, a specific gravity is calculated from the output value [mV] based on the selected map, and in step 210,
The calculated specific gravity is stored together with the date data.

A routine for detecting the amount of water added to each treatment liquid will be described with reference to FIG. This routine is executed when the printer processor 10 changes from the stopped state to the standby state.

That is, the printer processor 10
At every predetermined time, the environmental temperature sensor 54 fetches the environmental temperature and the environmental humidity sensor 56 fetches the environmental humidity, and the ambient humidity is stored and the time when the printer processor 10 is in each of the stopped state, the standby state, and the drive state is recorded. I remember.

Therefore, in step 212, each process from the time when the ambient temperature, the ambient humidity, and the operating state are stored in this way to the time when this routine is executed last time until this time is executed (one day). The evaporation amount (theoretical water amount) of water from the liquid is calculated, and in step 214, the replenishment pump 48
L ₁ ~48L ₆ a is driven to supply water only this theory amount of water, at step 216, the replenishment flow meter 48N ₁ ~48N
_The amount of water added (actual amount of water) actually supplied to each treatment liquid is taken in from step 6, and in step 218 the theoretical amount of water and the actual amount of water added are stored together with date data.

If the physical quantity data stored as described above is deleted from old data that has passed a predetermined time limit (for example, one month), the data can be effectively stored. .

After the physical quantity is determined as described above, in step 108 (see FIG. 8), the abnormal item is displayed on the display panel 72. For example, color paper 16P
If the processing amount for 1 week is outside the allowable range, it is displayed that the processing amount for 1 week of the color paper 16P is outside the allowable range.

At step 110, step 15 of FIG.
The cause identified in 4 is displayed. If the cause cannot be identified and the determination result is stored, the determination result is displayed.

In the next step 112, a countermeasure is proposed based on the estimated cause of abnormality (a countermeasure for setting the density of the three primary colors R, G, B of the captured exposed portion and unexposed portion to values within an allowable range). (Plan), the estimated countermeasure plan is displayed in step 114, and the estimated countermeasure plan is executed in step 116.

Incidentally, when the cause of the abnormality is specified in this way, the countermeasure plan is also specified.
Countermeasure plans are also stored in correspondence with the cause of this abnormality.

Here, in the case where the replenishment solution is insufficiently replenished, for example, the replenishment solution replenishment accuracy in the rinse tanks 10N3 to 10N6 is below the allowable range, that is, the replenishment pump 44N ₃
When the amount of the replenisher replenished by driving .about.44N ₆ is less than the set value by a predetermined amount, the set value is increased by a predetermined amount, for example, 5 [ml] as a countermeasure. Also, failure or replenishment pump 44N ₃ ~44N ₆ of rinsing tank 10N3～10N6, rinsing tank 10N3~10
When it is determined that the circulation filters 30N4 _{3 to} 30N4 _{6 of} N6 are not filled (the abnormal items do not become normal despite the correction of the replenishment amount), the replenishment pumps 44N _{3 to} 44N ₆ are taken as a countermeasure. exchange, the displays on the circulation filter 30N4 ₃ ~30N4 ₆ drink display panel 72 instruction information Mari removal without the further, when the printer processor is connected to the headquarters of the host computer in communication lines, Division Is displayed on the monitor of the printer processor 10 for instructing replacement of the replenishment pumps 44N _{3 to} 44N ₆ of the printer processor 10. If the determination cannot be made, the data of the abnormal concentration mode and the check item that is abnormal may be transmitted to the host computer of the headquarters.

In step 118, it is displayed that it is necessary to reconfirm whether the densities of the exposed portion and the unexposed portion of the color paper 16P described above are within a permissible range after a predetermined time has passed, and in step 120. Then, it is determined whether or not a fixed time has elapsed, and in step 122, it is again determined whether or not the densities of the exposed portion and the unexposed portion of the color paper 16P are within the permissible range. If it is determined that the value is not within the allowable range, in step 124,
Information indicating that the cause analysis should be instructed is displayed on the display panel 72, the present process is terminated, and when the determination in step 126 is positive, that is, the densities of the exposed and unexposed portions of the color paper 16P described above. Is within the allowable range, in step 126, the display indicating that it should be determined whether the densities of the exposed and unexposed parts of the color paper 16P are within the allowable range is stopped, This process ends.

As described above, when the processing performance of the processing liquid is abnormal, the cause can be specified, and based on the specified cause, R of the exposed portion and the unexposed portion,
Since measures are taken to set the densities of the three primary colors G and B to values within the allowable range, the density of the color paper can be set to a value within a predetermined range when the measures are taken. The processing performance of the processing liquid can be set within an allowable range.

When the density of at least one of the unexposed area and the exposed area is abnormal, the physical quantity is determined in a predetermined order according to the mode, and the density of at least one of the unexposed area and the exposed area is determined. Since the cause of the abnormality is specified, the cause can be specified quickly and efficiently, and based on the specified cause, the density of the exposed and unexposed parts taken in is within the allowable range. By taking the measures for the above, it is possible to quickly bring the value within the allowable range even if the density of the color paper becomes abnormal.

The inventors of the present invention have used, as the printer processor of the above embodiment, a printer processor PP125 for a small photo lab (minilab) manufactured by Fuji Photo Film Co., Ltd.
5V (trade name) is used, and CP-47 manufactured by the same company is used as the processing liquid.
L (trade name) was used. The processing steps of this printer processor "P1255V" are the development processing (45
Second), bleach-fixing treatment (45 seconds), rinse treatment (90
Seconds) and a drying process (60 seconds).

Further, this printer processor "PP1
255V ”to expose a predetermined portion of the color paper 16P to a standard density, and the density of the exposed and unexposed portions of the color paper 16P exposed to a standard density using this filter (blue ( (B), green (G) and red (R) three colors minimum density)
It has a built-in densitometer for detecting the above and various sensors described above.

Further, this printer processor "PP
1255V ”, so that the present embodiment can be applied to the past 1
A function is provided to record the amount of treatment for the week and the past month, and to compare the amount of treatment for the past week and the amount recorded for the past month with the allowable amount of treatment. Further, a function of recording the temperature of each treatment liquid, a function of comparing the recorded temperature of each treatment liquid with an allowable temperature, and a function of recording the replenishment accuracy of each treatment liquid were provided.
As the replenishment accuracy, the replenishment accuracy based on the throughput in the past week is recorded. Further, the function of measuring the electric conductivity of the final rinse water of the rinse tank and comparing the measured electric conductivity with the allowable range, and the p of the developing solution and the bleach-fixing solution.
Measuring H and specific gravity and the measured pH and specific gravity,
A function of comparing with each allowable range and a function of recording the amount of water added to each treatment liquid and comparing the recorded amount of water with the allowable range were provided.

Then, the printer processor "PP12
55V ”is switched from the stopped state to the standby state, and when it is determined that the temperature of each processing liquid has reached the set temperature, the color paper 16P exposed to the standard density using the above filter is processed in the above processing step. Then, the unexposed portion and the exposed portion of the color paper 16P were measured by the densitometer and converted into yellow, cyan, and magenta densities and sampled, and the yellow density (BL
The sampling value of D _min ) is as shown in FIG. That is, the sampling values SP _{5 to} SP ₃ from 5 days to 3 days before the density of yellow in the unexposed portion of the color paper 16P processed in the above processing step are the standard density g _y10.
Although it was a value close to, it gradually increased from 2 days ago (see sampling values SP ₂ and SP ₁ ), and this sampling value SP ₀ is the upper limit value g _y11 (+0.03) of the allowable range.
Over.

Since there is such a sample value SP ₀ , the reason why the yellow density (BLD _min ) of the unexposed portion exceeds the upper limit is the order of increasing relevance, that is, the processing amount of color paper and the rinse. Each physical quantity was determined in the order of tank replenishment accuracy, electrical conductivity of the final rinse water in the rinse tank, temperature of each processing solution, pH and specific gravity of color developing solution and bleach-fix solution, and amount of water added to each processing solution. .

As a result, each sample value of the total processing amount of the color paper 16P for one week was within the allowable range including the ideal processing amount k ₁₀ , as shown in FIG. In addition,
k ₁₁ is an upper limit value and k ₁₂ is a lower limit value.

Since the total treatment amount of the color paper 16P for one week was within the permissible range as described above, the replenishment accuracy based on the treatment amount of the rinse treatment water in the rinse treatment tank for one week was detected by the method described above. did. The result of this sample is shown in Figure 2.
As shown in 1, the ideal replenishment accuracy h ₁₀ began to fall below the sampling value SP ₁₃ four weeks ago, and the current sampling value SP ₁₀ fell below the lower limit value h ₁₂ (-10%) of the allowable range. The cause could not be identified at this stage.

Next, the final rinse water in the rinse tank is washed.
The electrical conductivity of was detected by the above method. This sampling
As shown in Fig. 22, the results are the sampling values 4 days before.
SP _{twenty four}To ideal electrical conductivity n_TenStarted crossing the previous day and now
Sampling value SP of times_{twenty one}, SP₂₀Is the upper limit of the allowable range
Value n₁₁(× 1.5 times) exceeded.

As a result of checking up to this point, it can be assumed that the cause of the abnormality is a decrease in the replenishing amount of the rinse water in the rinse treatment tank, so the check of the physical quantity scheduled later is omitted. When this process was completed, I checked the other physical quantities that were scheduled later.The temperature of each processing solution in the color development processing tank, bleach-fixing processing tank, and rinse processing tank, the color development processing solution and the bleaching The pH and specific gravity of the fixing treatment liquid and the amount of water added to each treatment liquid were within the permissible range.

As described above, the replenishing accuracy of the rinse treatment water to the rinse treatment water was below the lower limit of the allowable range, and the electric conductivity of the final rinse treatment tank 10N6 exceeded the upper limit of the acceptable range. "Reduction of water replenishment accuracy" and "Increase in electric conductivity of final rinse treatment tank 10N6 for washing water" are displayed on the display panel 72.

Then, the replenishment amount of the rinse treatment tank was increased by a predetermined amount. Then, after one week, the density of the unexposed portion of the color paper 16P exposed with the standard density was measured, and the result was in the allowable range.

Further, the inventors of the present invention have made the above-mentioned printer processor PP1255V (treatment liquid CP-47L, developing treatment (45 seconds), bleach-fixing treatment (45 seconds), rinsing treatment (90 seconds), drying treatment (60 seconds). In the processing step of)), the processing amount for the past week and the past month is recorded, the function for comparing the recorded treatment amount for the past week and the past month with the allowable range, and the replenishment accuracy of each treatment liquid are set. The function to record is provided. This replenishment accuracy was recorded as the replenishment accuracy based on the throughput for 3 days.

As a result, the color paper 1 exposed to the standard density by using the filter built in the printer
When 6P was processed in the above-mentioned processing step and the unexposed area and the standard exposed area were measured by a densitometer and sampled, the magenta and cyan density sampling values of the standard exposed area are shown in FIGS. 23 and 24, respectively. It became so.

That is, the density of magenta in the exposed portion of the color paper 16P processed in the above processing step _{gradually falls} below the standard density g _{m10 of} magenta from the sampling value SP ₃₅ 5 days before, and the current sampling value SP ₃₀ becomes , The value was close to the lower limit g _m12 (−0.10) of the allowable range.
Further, the density of cyan in the exposed portion of the color paper 16P processed in the above processing step is the sampling value SP ₄₃ 3 days before.
, The standard density of cyan g _c10 begins to drop greatly, and the current sampling value SP ₄₀ is the lower limit g of the allowable range.
It became _c12 (-0.10).

As described above, since the magenta and cyan sampling values of the exposed portion of the color paper 16P became the lower limit of the allowable range, the processing amount of the color paper per unit time and the replenishing solution replenished to each processing solution When only the replenishing amount was detected and sampled, the replenishing amount of the replenishing liquid replenished to each treatment liquid was within the allowable range, but as shown in FIG. 25, the past one week, the past two weeks to the past one week. Sampling value SP ₅₀ , S of the processing amount of each color paper 16P for the past 1 week, the past 3 weeks to the past 2 weeks, and the past 4 weeks to the past 3 weeks
P ₅₁ , SP ₅₂ , and SP ₅₃ were within the allowable range, but were all close to the lower limit value K _{w 12} (1/2) of the allowable range.
In this way, since the throughput of each week is small for the past 4 weeks, as shown in FIG. 26, the sampling value SP ₆₀ of the throughput of the past month is the lower limit K of the allowable range.
It was below _m12 (1/2).

Thus, the color paper 16 for one month
Since the processing amount of P was below the lower limit value K _{m1 2} of the allowable range, it was displayed as "processing amount lower limit".

The cause is presumed to be that the developing activity is lowered because the processing amount becomes the lower limit value. Therefore, the replenishment amount of the color development processing solution was increased by a predetermined amount. Then, after one week, the density of the exposed portion was measured so as to be the standard density of the color paper 16P, and the result was in the allowable range.

Next, a second embodiment of the present invention will be described.
As shown in FIG. 27, the film processor as the photographic light-sensitive material processing apparatus of the present embodiment includes a loading unit 11 for loading the negative film N. The loading section 11 is exposed by opening a lid (not shown) and is loaded with the negative film N on which an image is exposed by photographing, and then the loaded negative film N is transported into the processor section 10P. The loading section 11 has the same code reading sensor 55 and infrared radiation section 32N as those of the first embodiment.
And a photo sensor configured by the detection unit 34N. On the upper side of the loading section 11, the display panel 72 similar to that of the first embodiment described above, and on the lower side of the loading section 11,
The environmental temperature sensor 54 and the environmental humidity sensor 56 described above are provided.

The processor section 10P includes a color development processing tank 10A, a bleaching tank 10B, a bleach-fixing tank 10C, and a fixing tank 10.
D, super rinsing tank 10E, stabilizing tanks 10F, 10G are arranged in order, and a color developing processing solution, a bleaching processing solution, a bleach-fixing processing solution, a fixing processing solution, a rinsing processing water, and a stabilizing processing are provided in each processing tank. Liquid is stored. Further, each processing tank is provided with an upper roller and a lower roller to form a transport path between and within each processing tank, and the negative film N passes through each processing tank by the upper roller and the lower roller. At the same time, it is dipped in each processing solution and processed.

A drying section 10H is arranged next to the processor section 10P. The drying unit 10H dries the negative film N by blowing air heated by a heater (not shown) with a fan while reciprocating the negative film N in the vertical direction. Then, the negative film N is conveyed in the film leader stacking unit 10I arranged on the downstream side of the outlet 10HE of the drying unit 10H, and the leader adhered to the tip of the negative film N is hung on a hanger (not shown). As the negative film N is conveyed, the rear end portion of the negative film N is stored in the storage box 2
It is housed in 2N. And in the film processor,
A control unit 60 that performs various controls is provided.

The color developing tank 10A is the same as the color developing tank 10N1 in the first embodiment described above, and the bleaching tank 1 is used.
0B, the bleach-fixing processing tank 10C is the bleach-fixing tank 10N2 and the super rinse tank 10E in the first embodiment described above.
And the stabilizing tank 10F is the rinse tank 10 in the first embodiment.
N3 and the stabilizing tank 10G have the same structure as the final rinse tank 10N6 in the first embodiment.

The film reader integrated section 10I includes
An infrared sensor unit 120V and a densitometer 22 are provided.

Next, the infrared sensor unit 120V
Will be described in detail with reference to FIG. The infrared sensor unit 120V includes infrared emitting diodes (hereinafter, referred to as emitting diodes) 12A, 12B, 12.
Equipped with C. These radiating diodes 12A, 12B,
A liquid phase epitaxial radiating diode using gallium arsenide (GaAs) can be used for 12C. Note that carbon dioxide gas (C
It is also possible to use an O ₂ ) laser, a carbon monoxide (CO) laser, or the like.

The radiating diodes 12A, 12B, 12
Photodiodes 14A, 14B, and 14C as photovoltaic photoelectric conversion elements are arranged so as to face C. A phototransistor other than a photodiode can be used for this photovoltaic photoelectric conversion element.

Sensor 124A composed of radiating diode 12A and photodiode 14A, radiating diode 1
Sensor 12 composed of 2B and photodiode 14B
4B, radiating diode 12C and photodiode 14C
Each of the sensors 124C constituted by
The light is shielded by A, the light shielding box 20B, and the light shielding box 20C.

The upstream side of the sensor 124A in the negative film N transport direction, between the sensors 124A and 124B, between the sensors 124B and 124C, and between the sensors 124.
On the downstream side of C in the negative film N transport direction, a pair of transport rollers 16A, 16B, 16 each including a pair of rollers.
C and 16D are provided, and the negative film N is configured to pass between the radiation diode 12A and the photodiode 14A, between the radiation diode 12B and the photodiode 14B, and between the radiation diode 12C and the photodiode 14C. The sensor 124A and the sensor 1
24B and the sensor 124C are arranged at equal intervals.

Further, the photodiodes 14A, 14B, 1
Amplifiers 18A, 18B, and 18C are connected to 4C, respectively. The amplifiers 18A, 18B, 1
Each of 8C is composed of a resistor, a capacitor, and an operational amplifier.

As shown in FIG. 29, the control unit 60 of this embodiment has the same structure as the control unit of the first embodiment described above. The input / output port 68 of the control unit 60 is provided with radiating diodes 12A, 12B, 12C and amplifiers 18A, 18B, 18C in addition to the components connected to the input / output port 68 of the first embodiment described above. Photodiode 1
4A, 14B and 14C are connected.

Here, the radiation diodes 12A, 12B,
The infrared rays emitted from 12C will be described. Infrared rays radiated from the radiating diodes 12A, 12B, and 12C have substantially the same spectral distribution of radiated energy but different radiant energy. That is, the spectral distribution of each radiating diode is as shown in FIG.
The peak portion is 0.95 [μm]. Also,
As shown in FIG. 32, the radiant energy of infrared rays (hereinafter, referred to as radiant amount) is radiated by the radiant amount W1
The radiation diode 12B has a radiation amount W2 (a value smaller than W1), and the radiation diode 12C has a radiation amount W3.
(A value smaller than W2).

The radiation amount W1 is such that the amount of silver remaining in the negative film N treated with each treatment solution is 10 [μg / cm ² ].
It is the amount that passes through this negative film N even at a higher level,
The radiation amount W2 is the amount that passes through the negative film N when the amount of silver remaining in the negative film N treated with each processing solution is 10 [μg / cm ² ] or less, and the radiation amount W3 is the radiation amount W3. The amount of silver remaining in the negative film N treated with the solution is 5
[Μg / cm ² ] It is the amount that is transmitted through the negative film N when it is not more than.

When the amount of silver remaining in the negative film N processed with each processing solution is more than 10 [μg / cm ² ], it can be judged that the desilvering performance of the processing solution is poor. Further, when the amount of silver remaining in the negative film N treated with each processing solution is 5 [μg / cm ² ] or less, it can be judged that the desilvering performance of the processing solution is good. Then, the amount of silver remaining in the negative film N treated with each treatment liquid is 5
More than [μg / cm ² ] and 10 [μg / c
m ² ], it can be judged that the desilvering performance of the processing liquid is somewhat poor.

The spectral sensitivity characteristics of the photodiodes 14A, 14B and 14C are 0.85 [μ] as shown in FIG.
m] is the peak.

The processing performance management processing routine of this embodiment is
Although not shown because it is substantially the same as the above-described first embodiment, the processing performance management processing routine of this embodiment is different from the processing performance management processing routine (see FIG. 8) of the first embodiment described above. , Step 102 and step 106 are different.

Further, the processing performance management processing routine in this embodiment starts when the transportation of the contents is started. This composition is exposed under different reference exposure conditions, and areas of an unexposed portion (D _min portion), a standard density portion (LD portion), and a high density portion (HD portion) are formed.

In the density acquisition process of step 102,
As shown in FIG. 33, in step 222, the D _min portion is measured, and in step 224, R, G, and
The three B primary color signals are fetched, and in step 226, the fetched three primary color signals are converted into densities of R, G, and B colors.

Similarly, steps 228 to 232
In step 234 to step 238, the LD portion is measured and converted into the densities of R, G, and B colors.
The area D is measured, the densities of the colors R, G, and B are converted, and this routine is ended.

Through the above processing, the densities of the three primary colors of R, G and B of the D _min portion, LD portion and HD portion of the control strip are captured.

In this embodiment, the screen of the first embodiment described above is used.
Step 146-in Step 106 (see FIG. 8)
This is the same as performing the same processing as step 158 (see FIG. 10).
To D _minItems depending on the abnormality of the laser and LD sections
The order of is similar to that of the first embodiment.

In this embodiment, the order of the check items to be checked according to the abnormal state of the HD section is predetermined as follows.

When the density of the HD portion is below the lower limit of the allowable range, at least one of the replenishment accuracy of the color developing tank, the processing amount of the negative film N, the pH and the specific gravity of the color developing solution,
The replenishment accuracy of at least one of the bleaching tank and the bleach-fixing tank, the pH and / or the specific gravity of at least one of the bleaching solution and the bleach-fixing solution, and other physical quantities are checked in this order.

When the density of the HD part exceeds the upper limit of the permissible range, the replenishment accuracy of the bleaching tank, the amount of residual silver remaining in the negative film N, the pH of each processing solution, the rinsing solution and the stabilizing solution are at least one. The electrical conductivity, the temperature of each processing solution, and other physical quantities are checked in this order. In addition, in other physical quantities,
In order, there are the specific gravity of each processing solution, the amount of water added to each processing solution, the processing amount of the negative film N, and the replenishment accuracy of a processing tank other than the bleaching tank.

Tables 8 and 9 below show examples of the relationship between the check item patterns and causes similar to those in the first embodiment.

When the density of HD part (maximum density) is below the lower limit of the allowable range

[0211]

[Table 8]

[0212]

When the density of HD part (maximum density) exceeds the upper limit of the allowable range

[0214]

[Table 9]

Regarding the D _min section and the LD section, the first
It is similar to the embodiment.

As for checking the amount of silver remaining in the negative film N, the amount of silver remaining in the processed negative film N is stored in time series as will be described later. Therefore, the negative film N stored in this time series is stored. Incorporate the latest amount of silver remaining in, and determine whether the amount of silver captured is within the allowable range.

Now, a silver amount detecting routine for detecting the amount of silver remaining on the negative film N will be described with reference to FIG. When the negative film N is loaded, the loading unit 11 transports the loaded negative film N into the processor unit 10P, and the negative film N transported in the processor unit 10P.
Is a color development processing tank 10A, a bleaching tank 10B, a bleach-fixing tank 10C, and a fixing tank 1 depending on the upper roller and the lower roller.
0D4, super rinse tank 10E, stabilizing tank 10F, 10
After passing through G in that order, each processing tank is dipped in each processing solution of a developing solution, a bleaching solution, a bleach-fixing solution, washing water, and a stabilizing solution for processing. The negative film N treated with each treatment liquid is the drying unit 1
After being guided to 0H and reciprocating in the drying section 10H in the vertical direction, the leading end of the negative film (see FIG. 35) reaches the infrared sensor unit 120V which constantly radiates infrared rays.

Therefore, when the leading end of the negative film N passes between the radiation diode 12A and the photodiode 14A, the amount of infrared rays detected by the photodiode 14A that receives the infrared rays emitted from the radiation diode 12A changes.

When it is detected that the detected amount has changed, this silver amount detecting routine is started, and in step 252, it is judged whether or not a predetermined time has elapsed. This predetermined time corresponds to the time required for the leading end NB of the negative film N to reach between the radiating diode 12B and the photodiode 14B.
When this predetermined time has elapsed, the tip end NB has reached the area where the infrared rays emitted from the emission diode 12B can be irradiated, and therefore in step 254, the emission diode 12B emits infrared rays.

At step 256, it is judged whether or not the detection signal B is inputted. That is, when the desilvering performance of the processing liquid is slightly poor or good, the infrared rays emitted from the radiation diode 12B pass through the tip portion NB of the negative film N and are detected by the photodiode 14B. In this case, a signal is output from the photodiode 14B,
It is amplified by the amplifier 18B and input as the detection signal B. Therefore, the determination at step 256 is affirmative, and the routine proceeds to step 260.

On the other hand, when the desilvering performance of the processing liquid is poor, the infrared rays emitted from the radiation diode 12B are almost totally reflected by the silver present in the negative film N, and the infrared rays do not pass through the negative film N. Therefore, the detection amount of infrared rays emitted from the emission diode 12B of the photodiode 14B becomes extremely small, and the detection signal B is not output.

Therefore, in this case, the determination at step 256 is denied, and at step 258, it is stored that the detection signal B has not been input and the routine proceeds to step 260.

At step 260, it is determined whether or not a predetermined time has elapsed, and it is determined whether or not the leading end NB of the negative film N has reached between the radiating diode 12C and the photodiode 14C. If this predetermined time has passed,
Since the tip portion NB has reached the area where the infrared rays emitted from the emission diode 12C can be irradiated, the emission diode 12C emits infrared rays in step 262.

When the desilvering performance of the processing liquid is good, the infrared rays radiated from the radiation diode 12C pass through the negative film N and are detected by the photodiode 14C. Therefore, the detection signal C is output from the photodiode 14C. Then, the determination in step 264 is affirmed, and step 268 is performed.
Proceed to.

On the other hand, if the desilvering performance of the processing liquid is not good, the infrared rays emitted from the emitting diode 12C are
Since the negative film N is not transmitted and the detection signal C is not output from the photodiode 14C, the determination in step 264 is negative, and it is stored in step 266 that the detection signal C is not input, and the process proceeds to step 268.

At step 268, as shown in FIG. 36, the residual silver amount is estimated based on the map storing the residual silver amount corresponding to the combination of the presence or absence of the input of the detection signal B and the detection signal C. When the detection signal B and the detection signal C are input, it is estimated that the amount of silver remaining on the negative film is 5 [μg] or less per 1 [cm ² ]. In addition, the detection signal B
Is input but the detection signal C is not input, the amount of silver remaining on the negative film is 5 [μ per 1 cm ² ].
g] is estimated larger than that at 10 [μg] Hereinafter, when you do not enter the detection signal B and the detection signal C, the amount of silver remaining in the negative film 1 [cm ^2] per 10
It is estimated to be higher than [μg].

As described above, since the processing liquid state is determined by determining whether or not infrared rays having different radiation amounts have passed through the negative film N, the amount of silver remaining on the negative film can be determined with a simple structure. Detection can be performed.

At step 270, the estimated residual silver amount is stored. Here, in the above processing, the peak portion of the spectral distribution of the energy emitted from the radiating diode is set to 0.95 [μm], but the present invention is not limited to this, and is approximately 0.75 [μm]. Approximately 2.5 [μ
m]. That is, the peak part of infrared rays is usually 0.75 [μm] to 25 [μm], but approximately 0.75 [μm] to approximately excluding the portion where the infrared absorption rate of the film base resin of the negative film N is high. 2.5 [μ
m].

Further, in the above-mentioned embodiment, the sensor 124
A is composed of a radiating diode and a photodiode, but the present invention is not limited to this, and is a film detection sensor that does not use infrared rays (a structure in which the negative film N is detected by contact with the negative film N, etc.). It may be.

Further, in the above-mentioned embodiment, the radiation amounts of the radiation diodes 12A, 12B and 12C are different from each other like the radiation amounts W1, W2 and W3, but the present invention is not limited to this. Alternatively, for example, infrared rays may be emitted from each of the radiation diodes 12A, 12B, and 12C having substantially the same radiation amount (for example, the radiation amount W1) and different spectral distributions of energy emitted.

That is, for example, as shown in FIG. 37, the peak portion of the spectral distribution of the radiated energy is 0.80 [μm], 0.95 [μm], 1.00.
It can be [μm]. In this case, the spectral sensitivity characteristics of the photodiodes are substantially the same (for example, 0.
85 [μm]). This allows the sensor to have high sensitivity, medium sensitivity, and low sensitivity due to the combination of the radiation diode and the photodiode. Therefore, the treatment liquid state can be determined in three stages.

Further, in the above-mentioned embodiment, the processing liquid state is judged in three stages, but the present invention is not limited to this, and it may be judged in a plurality of other stages.

In the above-mentioned embodiment, the amount of silver remaining in the negative film N is determined from the amount of infrared rays transmitted through the negative film N, but the present invention is not limited to this. The amount of silver remaining on the negative film N may be determined from the amount of reflected infrared rays.
Further, in the above, the amount of residual silver was detected in the light-exposed portion at the tip of the negative film, but for a film that does not have a light-exposed portion, it is sufficient to pre-expose it to form a portion similar to the light-exposed portion. The amount of residual silver may be detected.

As described above, in the present embodiment, like the first embodiment, when the processing performance of the processing liquid is abnormal, the cause can be specified, and based on the specified cause. As a measure is taken to ensure that the density of the exposed part of the container is within the allowable range, the density of the exposed part of the container may be set to a value within the allowable range if this measure is taken. Therefore, the processing performance of the processing liquid can be set within an allowable range.

Also, the D _min part, LD part and H of the const
When the density of at least one of the D parts is abnormal, the physical quantity is determined in a predetermined order according to the mode,
Since the cause of the abnormal concentration of at least one of the D _min part, the LD part and the HD part of the const is specified,
The cause can be identified quickly and efficiently, and the density of at least one of the unexposed part, the LD part, and the HD part of the captured context is set to a value within the allowable range based on the identified cause. By implementing the measures described in (1), even if the density of the negative film becomes abnormal, the value can be promptly set within the allowable range.

The inventors of the present invention used the film processor FP360B (trade name) for a small developing laboratory (minilab) manufactured by Fuji Photo Film Co., Ltd. as the film processor described above, and used CN-16L manufactured by the same as the processing liquid. (Product name) was used. In addition, this film processor FP3
The processing steps of 60B are development, bleaching, fixing 1, fixing 2, rinsing, stable 1, stable 2, and drying in this order.

Also, this film processor FP360
When B was used, a Fuji Photo Film Co., Ltd. composition was treated in the above treatment step. The composition was exposed in advance to a standard density and a high density higher than the standard density under predetermined standard exposure conditions. As a result, the unexposed part (D _min ) not exposed and the standard density part (L
D part) and a high density part (HD part) were formed.

Furthermore, this film processor FP36
In 0B, D of processed control strips processed through the above-mentioned processing steps so that this embodiment can be applied.
_A densitometer was installed at the outlet of the drying unit so that the concentrations of the _min portion, LD portion and HD portion could be measured. The film processor FP360B is provided with the following various functions so that this embodiment can be applied. That is, the processing amount of the negative film N in the past one week and the past one month is recorded, the function of comparing the recorded treatment amount in the past one week and the past month and the allowable range, and the temperature of each treatment liquid are recorded. A function of comparing the recorded temperature of each processing solution with an allowable range and a function of recording the replenishment accuracy of each processing solution were provided.
As the replenishment accuracy, the replenishment accuracy based on the throughput in the past week is recorded. Also, the function of measuring the electric conductivity of the final washing water in the stabilizing tank and comparing the measured electric conductivity with the allowable range, the pH of the developing solution, the bleaching solution and the fixing solution.
And a function of measuring the specific gravity and comparing the measured pH and specific gravity with each allowable range, a function of recording the amount of water added to each treatment liquid and comparing the recorded amount of water with the allowable range, and infrared rays after drying. A device was provided for measuring the amount of silver remaining in the negative film N from the detected amount by detecting the amount of infrared light that was transmitted through the LD part of the control strips or was reflected from this LD part while irradiating.

As a result, as shown in FIG. 38, the yellow density (result of sampling) of the HD portion of the const is calculated from the high density value HD from the sampling value SP ₇₂ of the yellow density of the HD portion of the const 2 days before. _It started to exceed _y10, and the sampling value SP ₇₀ this time exceeded the upper limit value HD _y11 (+0.08) of the allowable range. In addition, H of the const
The magenta and cyan densities (results of sampling) in the D portion were values near the high density center values HD _m10 and HD _c10 , respectively, as shown in FIGS. 39 and 40.

As described above, since the yellow density of the HD portion of the const exceeds the upper limit of the allowable range, the H of the const
In the order of increasing relevance to the cause that the density of yellow in Part D exceeds the upper limit of the allowable range, in the same order as above, replenishment accuracy of the bleaching tank, residual silver amount, pH of each processing solution, and final stability Check whether each physical quantity is abnormal in the order of electric conductivity of tank, temperature and specific gravity of each processing solution, amount of water added to each processing solution, processing amount of negative film N, and replenishment accuracy of tanks other than bleaching tank. did.

As a result, as shown in FIG. 41, the replenishment accuracy based on the treatment amount of the bleaching treatment solution for one week was calculated from the sampling value SP ₈₂ based on the treatment amount for one week from three weeks before, to _{obtain the} ideal replenishment accuracy h ₂₀ . Starts falling below this time's sampling value SP
The lower limit of the ₈₀ allowable range h ₂₂ (-10%) thou. At this stage, the cause could not be identified.

As shown in FIG. 42, the sampled value SP ₉₃ of the amount of silver remaining in the processed negative film N 3 days before SP ₉₃
Started to increase, and the sampling value SP ₉₀ this time exceeded the upper limit value X ₂₁ (10 [μg / cm ² ]) of the allowable range. Furthermore, as shown in FIG.
The ideal pH started to be exceeded from the sampling value SP _{103 of the} day before, and the sampling value SP _{100 of} this time exceeded the upper limit value P ₂₁ (+0.30) of the allowable range.

After checking up to this point, it was estimated that the replenishment accuracy to the bleaching solution was deteriorated as the cause of the poor desilvering performance, so the later scheduled check of physical quantities was omitted. At the end of this treatment, when other physical quantities planned later were checked, the electrical conductivity of the stable treatment liquid, the temperature of each treatment liquid, the specific gravity of each treatment liquid, and the addition to each treatment liquid were checked. The water amount, the treatment amount of the negative film N, and the replenishment accuracy of the treatment liquids other than the bleaching treatment liquid were all within the allowable range.

As described above, the replenishment accuracy of the bleaching solution becomes the lower limit value of the allowable range, the pH of the bleaching solution exceeds the upper limit value of the allowable range, and the processed negative film N is processed.
Since the amount of silver halide remaining in the solution exceeded the permissible range, it was indicated as "lower limit of replenishment accuracy of bleaching solution", "upper limit of pH of bleaching solution" and "defective desilvering".

Further, the replenishment amount of the bleaching tank 10B was increased by a predetermined amount. Then, one week later, the result of measuring the concentration of the const was found to be within the acceptable range.

Further, although the film processor or the printer processor has been described as an example in the above-mentioned embodiment, the present invention is not limited to this, and the film processor and the printer processor are integrated as shown in FIG.
It is applicable to the photographic processing device shown in FIG. That is, in this photographic processing apparatus 10L, the negative film 12L is pulled out from the cartridge 14K and processed for development, and the color paper 20L rolled up and accommodated in the magazine 18L is pulled out and processed. An image exposure unit 22L that exposes according to the image recorded on the negative film 12L, and a paper processing unit 24L that develops the color paper 20L that has finished image exposure are integrally housed in a casing (not shown).

The film processing section 16L includes a developing tank 26L for storing a developing solution, a bleaching tank 28L for storing a bleaching solution, a first fixing tank 30L, a second fixing tank 32L for storing a fixing solution in each of them, and washing water. Washing tank 34L for storing, first stabilizing bath 36L for storing stabilizing liquid in each, and second stabilizing bath 3
8L are continuously arranged, and a drying chamber 42L and a reservoir section 44L are provided on the downstream side of the second stabilizing bath 38L.

The negative film 12L pulled out from the cartridge 14L is transferred to the developing tank 2 by a conveying means (not shown).
6L, bleaching tank 28L, first fixing tank 30L, second fixing tank 3
2L, a washing tank 34L, a first stabilizing bath 36L, and a second stabilizing bath 38L are sequentially conveyed, and a developing solution, a bleaching solution, a fixing solution,
The treatment liquid is treated with washing water and a stabilizing liquid. The negative film 12L for which the treatment liquid treatment has been completed is dried by blowing dry air generated by a heater and a drying fan (not shown) in the drying chamber 42L, and the reservoir portion 44L.
It is sent to L.

On the other hand, in the image exposure section 22L, the negative film 12L which has been developed is drawn from the reservoir section 44L and the color paper 20 is fed from the magazine 18L.
L to pull out the negative film 12 on the color paper 20L.
The images recorded in L are sequentially exposed. The image exposure unit 22L may be configured as slit exposure for exposing the image recorded on the negative film 12L onto the color paper 20L while conveying the negative film 12L and the color paper 20L at a predetermined speed, or the negative film 12L.
It is possible to use various exposure methods such as reading the image recorded on the image recording means by the image reading means, and then scanning and exposing the read image to the color paper 20L with laser light or the like. The color paper 20L imagewise exposed in this way is provided with an image exposure unit 22L and a paper processing unit 24.
It is sent out to the reservoir portion 46L provided between L.

The color paper 2 is stored in the paper processing unit 24L.
A developing tank 48L for storing 0 L of the developing solution, a bleach-fixing tank 50L for storing the bleach-fixing solution, a first rinse tank 52L and a second rinsing tank 54L for respectively storing a rinse solution,
A third rinse tank 56L is provided, and a drying chamber 58L is provided downstream of the third rinse tank 56L in the color paper transport direction. The color paper 20L sent to the reservoir portion 46L and subjected to the manual image exposure is drawn into the paper processing portion 24L by a conveying means (not shown), and then the developing tank 48.
L, the bleach-fixing tank 50L, the first rinsing tank 52L, the second rinsing tank 56L, and the third rinsing tank 56L are sequentially transported and processed by the developing solution, the bleach-fixing solution, and the rinsing solution. The processed color paper 20L is conveyed in the drying chamber 58L and is dried by being blown with the drying air generated by a heater, a drying fan and the like (not shown).

Color paper 20L that has been dried
Is cut, for example, for each image frame and discharged as a photographic print.

Then, for the film processing section 16L and the paper processing section 24L, the above-mentioned first embodiment,
It suffices to perform the same processing as in the second embodiment.

As described above, in the photographic processing apparatus equipped with the film processing section 16L and the paper processing section 24L, more information can be obtained and the cause of the abnormality can be estimated accurately.

[0254]

As described above, according to the present invention, when the specific concentration measured by the concentration measuring means is out of the predetermined range including the predetermined concentration, the physical quantity is judged in a predetermined order. Since the cause of the abnormality in which the specific concentration measured by the concentration measuring means is out of the predetermined range is estimated, it is possible to efficiently estimate the cause of the abnormality without judging all physical quantities. Have.

[Brief description of drawings]

FIG. 1 is a schematic diagram showing a printer processor according to a first embodiment of the present invention.

FIG. 2 is a schematic view of a photo sensor.

FIG. 3 is a sectional view showing the structure of a color developing tank.

FIG. 4 is a cross-sectional view showing a configuration of a rinse tank.

FIG. 5 is a cross-sectional view showing a configuration of a final rinse tank.

FIG. 6 is a cross-sectional view of a hydrometer and a diagram showing an electric circuit.

FIG. 7 is a block diagram of a control system of this embodiment.

FIG. 8 is a flowchart showing a processing performance management routine.

9 is a flow chart showing details of a density loading routine of step 102 of FIG.

10 is a flowchart showing details of a physical quantity determination routine in step 106 of FIG.

FIG. 11 is a flowchart showing a processing amount detection processing routine.

FIG. 12 is a flowchart showing a processing liquid temperature detection processing routine.

FIG. 13 is a flowchart showing a replenishment accuracy calculation routine.

FIG. 14 is a flowchart showing a specific gravity detection processing routine.

FIG. 15 is a diagram showing the relationship between the output value proportional to the propagation velocity in the bleaching solution of a plurality of processing machines and the specific gravity of the processing solution.

16 is a diagram similar to FIG. 15 showing the relationship between the output value proportional to the propagation velocity in the fixing liquid of a plurality of processing machines and the density of the processing liquid.

FIG. 17 is a diagram showing a map for calculating specific gravity from detected propagation velocity.

FIG. 18 is a flowchart showing a water addition amount detection processing routine.

FIG. 19 is a diagram showing density data.

FIG. 20 is a diagram showing processing amount data.

FIG. 21 is a diagram showing replenishment accuracy data.

FIG. 22 is a diagram showing electric conductivity data.

FIG. 23 is a diagram showing density data.

FIG. 24 is a diagram showing density data.

FIG. 25 is a diagram showing processing amount data for each past week.

FIG. 26 is a diagram showing processing amount data for each past month.

FIG. 27 is a schematic view of a film processor according to a second embodiment of the present invention.

FIG. 28 is a schematic view of an infrared sensor unit.

FIG. 29 is a block diagram of a control unit according to the second embodiment.

FIG. 30 is a diagram showing a spectral distribution of a radiating diode.

FIG. 31 is a diagram showing a spectral sensitivity characteristic of a photodiode.

FIG. 32 is a diagram showing a radiation amount of each radiation diode.

FIG. 33 is a flowchart showing a density acquisition processing routine in the second embodiment.

FIG. 34 is a flowchart showing a routine for obtaining the amount of residual silver.

FIG. 35 is a plan view showing a front end portion of a film.

FIG. 36 is a diagram showing a map of residual silver amount.

FIG. 37 is a diagram showing another example of the peak portion of the spectral distribution of radiated energy.

FIG. 38 is a diagram showing density data.

FIG. 39 is a diagram showing density data.

FIG. 40 is a diagram showing density data.

FIG. 41 is a diagram showing replenishment accuracy data.

FIG. 42 is a diagram showing daily residual silver content data.

FIG. 43 is a diagram showing daily pH data.

FIG. 44 is a schematic view of a photographic processing device in which a film processor and a printer processor are integrated.

[Explanation of symbols]

22 densitometer 32N infrared radiation portion 34N detector 36N _1, 36N ₂ hydrometer 38N _1, 38N ₂ pH sensor 40N ₁ ~40N ₆ Temperature sensor 44N ₁ ~44N ₆ replenishing pump 46N ₁ ~46N ₆ ultrasonic level meter 48N ₁ ~ 48N ₆ Replenishment flow meter 50 Conductivity meter 54 Environmental temperature sensor 56 Environmental humidity sensor 60 Controller

Claims (6)

[Claims] 1. A density measuring means for measuring a specific density of a processed photographic light-sensitive material which has been processed by passing through a processing liquid, and different physical quantities which affect the photographic characteristics of the processed photographic light-sensitive material. A plurality of physical quantity detecting means, a determining means for determining whether or not the specific concentration measured by the concentration measuring means is a value outside a predetermined range including a predetermined concentration, and the measured specific When the concentration of is outside the predetermined range, the cause is estimated by estimating the physical quantity in a predetermined order and estimating the reason why the measured specific concentration is outside the predetermined range. And a photographic light-sensitive material processing apparatus including: 2. The physical quantity detection means is one of the physical quantities.
The photographic light-sensitive material processing apparatus according to claim 1, wherein the state of the processing solution is detected as one. 3. The photographic light-sensitive material processing apparatus according to claim 1, wherein the physical quantity detection means detects at least the processing quantity of the photographic light-sensitive material per unit time as the physical quantity and the replenishment accuracy of a replenisher for replenishing the processing solution. . 4. The predetermined order is different depending on whether the measured specific concentration is larger than an upper limit value of the predetermined range or smaller than a lower limit value of the predetermined range. Item 5. The photographic light-sensitive material processing apparatus according to any one of Items 3. 5. A maintaining unit that maintains the processing liquid in an appropriate state based on a control condition that is determined according to the physical quantity and that maintains the processing liquid in an appropriate state, and a cause estimated by the cause estimating unit. The photograph according to any one of claims 1 to 4, further comprising: changing means for changing the control condition so that the measured specific concentration becomes a value within the predetermined range based on Photosensitive material processing device. 6. The density measuring means measures at least the density of an unexposed portion of the processed photographic light-sensitive material.
6. The photographic light-sensitive material processing apparatus according to claim 5.