JPH08260385A - Biodegradable paper product and its preparation - Google Patents

Biodegradable paper product and its preparation

Info

Publication number
JPH08260385A
JPH08260385A JP7288826A JP28882695A JPH08260385A JP H08260385 A JPH08260385 A JP H08260385A JP 7288826 A JP7288826 A JP 7288826A JP 28882695 A JP28882695 A JP 28882695A JP H08260385 A JPH08260385 A JP H08260385A
Authority
JP
Japan
Prior art keywords
product
paper
coating
biodegradable
coating solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7288826A
Other languages
Japanese (ja)
Inventor
Sung-Ho Kim
聖浩 金
鳳▲益▼ ▲黄▼
Bong-Ik Hwang
Tae-Sik Kim
台植 金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of JPH08260385A publication Critical patent/JPH08260385A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00Table service
    • A47G19/12Vessels or pots for table use
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/80Paper comprising more than one coating
    • D21H19/84Paper comprising more than one coating on both sides of the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Coating Apparatus (AREA)
  • Paints Or Removers (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Cartons (AREA)
  • Making Paper Articles (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a biodegradable paper product suitable for a disposable paper cup by forming a coating layer comprising an ethylene/vinyl acetate copolymer, an acrylic copolymer and a starch in the inside of the paper product. SOLUTION: An emulsified ethylene/vinyl acetate copolymer is formulated with an emulsified acrylic copolymer and a starch in the ratio of 5.5-6.6:1.7-2.3:0.8-1.3 to prepare a coating solution. One side of a base paper is coated with the coating solution by a coating roller having 100-150 meshes in 10-20 g/m<2> weight, dried at 130-150 deg.C and a coating film is formed to give a first product. Then, if necessary, a letter or a pattern is printed on the first product, a coating film is formed on a thermally bondable region corresponding to one side of a uncoated face of the first product by the similar manner and quenched to 5-7 deg.C to give a secondary product, which is formed into a fixed shape to give a biodegradable paper product.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は生分解性紙製品に係
り、より詳細には生分解性紙容器およびその製造方法に
関する。
TECHNICAL FIELD The present invention relates to a biodegradable paper product, and more particularly to a biodegradable paper container and a method for producing the same.

【0002】[0002]

【従来の技術】近年、急速な経済成長および利便性を重
視する生活パターンにより使い捨て製品の大量消費時代
を迎え、紙カップのような使い捨て紙製品が一日に数百
万個ずつ消費されている。一般家庭や事務室で使われる
このような使い捨て紙製品には、その容器内の内容物に
対する防水性が要求される。このため、防水性とともに
熱接着性および成形性を向上させる方法として、従来は
製品の内外面をポリエチレンで熱押出コーティングする
方法が一般的に使用されてきた。
2. Description of the Related Art In recent years, the era of mass consumption of disposable products has come due to rapid economic growth and lifestyle patterns that place importance on convenience, and millions of disposable paper products such as paper cups are consumed per day. Such disposable paper products used in general households and offices are required to have waterproofness against the contents in the container. Therefore, as a method for improving the heat-adhesiveness and the moldability as well as the waterproof property, conventionally, a method in which the inner and outer surfaces of the product are thermally extrusion-coated with polyethylene has been generally used.

【0003】[0003]

【発明が解決しようとする課題】しかし、一般の防水包
装紙、アイスクリーム、クッキーおよびその他の製菓類
の包装紙、果物箱、紙カップ、サンドイッチ包装紙など
一回だけ使って捨てられる使い捨て包装容器をポリエチ
レンのように数十年が経たなければ分解されない石油化
学製品でコーティングすると、一日に数えられないほど
多量の分解されないごみが放出されることとなり、これ
により深刻な環境汚染の問題が発生された。
However, disposable packaging such as general waterproof packaging, packaging for ice cream, cookies and other confectionary products, fruit boxes, paper cups, sandwich packaging, etc., which can be thrown away only once, is discarded. Coating with petrochemicals, such as polyethylene, that do not decompose after decades, can result in the release of innumerable amounts of undecomposed trash per day, which can cause serious environmental pollution problems. It was

【0004】このような環境問題を解決しようとする努
力の一方法として、捨てられた使い捨て容器を再活用す
るためにポリエチレン層と紙層とに分離する方法が用い
られた。この方法は、回収された製品を粉砕した後、こ
こに多量の産業用水と強酸あるいは強アルカリ性溶剤を
入れてポリエチレン層が解離されるまで混合、攪拌する
方法であるが、かえって多量の産業廃水を発生させる結
果を招いた。さらに、このような再活用方法では、再生
しても経済的な収益性が充足されないのみならず、良質
の再生パルプ製品を得ることもできなかった。
As one of the efforts to solve such environmental problems, a method of separating a discarded disposable container into a polyethylene layer and a paper layer has been used for reuse. This method is a method in which, after crushing the recovered product, a large amount of industrial water and a strong acid or a strong alkaline solvent are added and mixed and stirred until the polyethylene layer is dissociated. Has caused the result to occur. Furthermore, such a recycling method not only does not satisfy the economical profitability by recycling, but also fails to obtain a good quality recycled pulp product.

【0005】本発明の目的は、自然に分解されることに
より環境汚染を防止し得る生分解性紙製品を提供するこ
とにある。本発明の他の目的は、このような生分解性紙
製品の製造方法を提供することにある。
An object of the present invention is to provide a biodegradable paper product which can prevent environmental pollution by being naturally decomposed. Another object of the present invention is to provide a method for producing such a biodegradable paper product.

【0006】[0006]

【課題を解決するための手段】前記の目的を達成するた
めに、本発明においては、乳化エチレンビニルアセテー
ト共重合体、乳化アクリル共重合体および澱粉が 5.5〜
6.6 : 1.7〜 2.3 : 0.8〜1.3 の比率に含まれている生
分解性コーティング層をその内面に有する生分解性紙製
品が提供される。
In order to achieve the above object, in the present invention, an emulsion ethylene vinyl acetate copolymer, an emulsion acrylic copolymer and starch are used in an amount of 5.5 to 5.
There is provided a biodegradable paper product having on its inner surface a biodegradable coating layer contained in a ratio of 6.6: 1.7 to 2.3: 0.8 to 1.3.

【0007】前記紙製品は、使い捨て紙カップであるこ
とが望ましい。前記本発明の他の目的を達成するために
本発明においては、原紙の一側面に、乳化エチレンビニ
ルアセテート共重合体、乳化アクリル共重合体、澱粉お
よび水を 5.5〜 6.6 : 1.7〜 2.3 : 0.8〜1.3 : 1 の比
率に含むコーティング溶液を10〜20g/m2塗布した
後、130〜150℃で乾燥させることにより被膜を形
成して1次製品を製造する第1工程と、前記コーティン
グ溶液を前記1次製品の非コーティング面に10〜20
g/m2塗布して130〜150℃で乾燥した後、5〜7℃
に急冷して2次製品を製造する第2工程と、前記第2工
程で得られた前記2次製品を所望の形状に成形して最終
製品を製造する第3工程と、を含む生分解性紙製品の製
造方法が提供される。
The paper product is preferably a disposable paper cup. In order to achieve the other objects of the present invention, in one aspect of the present invention, one side of the base paper, an emulsion ethylene vinyl acetate copolymer, an emulsion acrylic copolymer, starch and water 5.5 ~ 6.6: 1.7 ~ 2.3: 0.8 The coating solution containing 10 to 20 g / m 2 of the coating solution in a ratio of ˜1.3: 1 is dried at 130 to 150 ° C. to form a film to produce a primary product. 10 to 20 on the non-coated surface of the primary product
After applying g / m 2 and drying at 130-150 ℃, 5-7 ℃
Biodegradability, including a second step of rapidly cooling to a second temperature to manufacture a secondary product, and a third step of molding the secondary product obtained in the second step into a desired shape to manufacture a final product A method of making a paper product is provided.

【0008】必要により、前記第1工程と前記第2工程
との間に印刷工程がさらに含まれることができる。この
際、文字または模様等がグラビア印刷により印刷される
ことが望ましい。前記第1工程および第2工程におい
て、前記コーティング溶液は100〜150メッシュコ
ーティングローラーを用いて塗布されることが望まし
い。
If desired, a printing process may be further included between the first process and the second process. At this time, it is desirable that characters or patterns be printed by gravure printing. In the first and second steps, the coating solution is preferably applied using a 100 to 150 mesh coating roller.

【0009】前記第2工程において、前記コーティング
溶液は前記1次製品の非コーティング面の一側端部に相
当する熱接着領域にのみ塗布してもよい。また、前記原
紙は最終紙製品の用途に応じて決定され、その大きさと
厚さは特に制限されない。
In the second step, the coating solution may be applied only to a heat-bonding region corresponding to one end of the uncoated surface of the primary product. Further, the base paper is determined according to the use of the final paper product, and its size and thickness are not particularly limited.

【0010】[0010]

【発明の実施の形態】以下、添付した図面に基づき本発
明を詳細に説明する。本発明の一実施例による使い捨て
紙カップの製造工程を図1に示す。この使い捨て紙カッ
プは第1〜第7段階を経て製造される。第1段階の紙
は、第2段階においてその表面にコーティング溶液が塗
布された後、乾燥過程を経て第3段階の1次製品とな
る。このコーティング処理により、前記1次製品には毛
細管現象を遮断する被膜が形成される。製品の熱接着面
上にグラビア印刷と呼ばれる過程により文字や模様を印
刷する第4段階の後、容器を成形する際の作業性を向上
させるためにコーティング溶液を再びコーティングして
乾燥させると第5段階の2次製品が得られる。この2次
製品は、第6段階のパンチ工程を経て最後に加工されて
第7段階の最終製品となる。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below with reference to the accompanying drawings. The manufacturing process of a disposable paper cup according to an embodiment of the present invention is shown in FIG. This disposable paper cup is manufactured through steps 1 to 7. After the coating solution is applied to the surface of the first stage paper in the second stage, the first stage paper undergoes a drying process to become a third stage primary product. By this coating treatment, a film for blocking the capillary phenomenon is formed on the primary product. After the fourth step of printing letters and patterns by a process called gravure printing on the heat-bonded surface of the product, the coating solution is re-coated and dried to improve workability when molding the container. A staged secondary product is obtained. This secondary product is finally processed through the punching process of the sixth stage to become the final product of the seventh stage.

【0011】本発明の製造方法による生分解性紙製品の
一例として使い捨て紙カップを製造し、この紙カップに
対する使用上の問題点、再活用性、生分解性および動物
に対する毒性などをテストした。 (実施例1:紙カップの製造)使い捨てカップとして用
いられるに適当な大きさの紙を準備し、この紙の一側面
に乳化エチレンビニルアセテート共重合体60重量%、
乳化アクリル共重合体20重量%、澱粉10重量%およ
び水10重量%を含むコーティング溶液を100〜15
0メッシュコーティングローラーを用いて15g/m2塗布
し、約140℃で乾燥させて被膜を形成した。次いで、
前記被膜の形成されていない側である熱接着面に所望の
文字または模様をグラビア印刷した。その後、前記熱接
着面に前記コーティング溶液を15g/m2塗布して約14
3℃で乾燥させ、5〜7℃に急冷してからパンチ作業を
行って所望の形態のカップを製造した。
Disposable paper cups were manufactured as an example of biodegradable paper products according to the manufacturing method of the present invention, and the problems in use with these paper cups, reusability, biodegradability, and toxicity to animals were tested. (Example 1: Manufacture of paper cup) A paper having a size suitable for use as a disposable cup is prepared, and 60% by weight of an emulsified ethylene vinyl acetate copolymer is provided on one side of the paper.
A coating solution containing 20% by weight of an emulsified acrylic copolymer, 10% by weight of starch and 10% by weight of water was added to 100 to 15
15 g / m 2 was applied using a 0 mesh coating roller and dried at about 140 ° C. to form a film. Then
The desired character or pattern was gravure-printed on the heat-bonded surface, which was the side without the coating. Then, 15 g / m 2 of the coating solution is applied to the heat-bonded surface, and the coating solution is about
It was dried at 3 ° C., quenched at 5 to 7 ° C., and punched to produce a cup having a desired shape.

【0012】(実施例2:テストおよび結果) (1)実施例1により製造された使い捨て紙カップに5
℃の水を200ml程度入れて約18℃で10時間放置し
た。その結果、防水状態は極めて良好であった。 (2)実施例1により製造された使い捨て紙カップ30
gをビーカーに入れて500mlの水を加えて3時間攪拌
した。その結果、ビーカー内の内容物がペースト状とな
った。 (3)実施例1により製造された使い捨てカップに土お
よび植物(豆、葱、西瓜など)の種を入れ、温度20
℃、湿度70〜80%でガラスボックス内の土の中に埋
めた。その結果、10〜13日経過後に黴が広がり始
め、30日経過後にはカップの外へ植物の根が張った。
40〜50日経過後には製品が分解されてカップの形態
が殆どなくなった。 (4)実施例1により製造された使い捨て紙カップに9
0〜95℃の温水を加えて3時間放置した。漏水は全く
起こらなかった。 (5)本発明の紙カップの動物に対する毒性の有無を調
べた。実施例1により製造された紙カップに沸騰水を入
れ、毒性物質があればそれが抽出され得るように10分
間放置して抽出溶液を得た。その後、この抽出溶液を1
0匹の雄と雌の鼠に体重100g当たり 0.5mlの量に経
口投与した。1週間経過後、毒性効果は全く観察されな
かった。
Example 2: Tests and Results (1) 5 in the disposable paper cup produced according to Example 1.
About 200 ml of water at 0 ° C was added and left at about 18 ° C for 10 hours. As a result, the waterproof state was extremely good. (2) Disposable paper cup 30 manufactured according to Example 1
g was put in a beaker, 500 ml of water was added, and the mixture was stirred for 3 hours. As a result, the contents in the beaker became a paste. (3) Put the seeds of soil and plants (beans, green onions, watermelons, etc.) in the disposable cup manufactured according to Example 1, and set the temperature to 20.
It was buried in soil in a glass box at 70 ° C and a humidity of 70-80%. As a result, the mold began to spread after 10 to 13 days had passed, and after 30 days, the roots of the plant had grown outside the cup.
After 40 to 50 days, the product was decomposed and the cup shape was almost lost. (4) 9 in the disposable paper cup manufactured according to Example 1.
Warm water at 0 to 95 ° C was added and the mixture was left for 3 hours. No water leakage occurred. (5) The paper cup of the present invention was examined for toxicity to animals. The paper cup prepared according to Example 1 was charged with boiling water and left for 10 minutes so that any toxic substances could be extracted to obtain an extraction solution. Then add this extraction solution to 1
It was orally administered to 0 male and female rats in an amount of 0.5 ml per 100 g of body weight. No toxic effect was observed after 1 week.

【0013】[0013]

【発明の効果】本発明の紙製品は、従来のポリエチレン
コーティング層の代わりに生分解性コーティング層を有
するため、自然界で生物学的に容易に分解されることが
できる。したがって、使用されてから廃棄された後に表
面のコーティング層と紙とが容易に分解されるので環境
汚染が防止される。
Since the paper product of the present invention has a biodegradable coating layer instead of the conventional polyethylene coating layer, it can be easily biodegraded in nature. Therefore, after being used and then discarded, the surface coating layer and the paper are easily decomposed to prevent environmental pollution.

【0014】このように、本発明の紙製品は従来の使い
捨て紙製品の問題点を解決するのみならず、再生可能で
あり、かつ、回収されなくて再生されずに捨てられると
しても、一定期間経過後には土壌を中性に転換させた
り、植物成長に必要な堆肥となったりするという長所を
有する。さらに、再活用過程でも産業廃水を放出するこ
となく良質の再生用紙が得られる。
As described above, the paper product of the present invention not only solves the problems of the conventional disposable paper products, but is recyclable, and even if it is not collected and discarded without being recycled, it remains for a certain period of time. After passing, it has the advantage of converting soil to neutrality and becoming compost necessary for plant growth. Furthermore, even in the recycling process, good quality recycled paper can be obtained without releasing industrial wastewater.

【0015】以上、本発明による得られる使い捨て紙容
器は、自然で生分解され得るのみならず、コーティング
層とパルプ層が容易に分解されることにより腐らないポ
リエチレンコーティング紙とは異なり環境問題を誘発し
ないという効果がある。
As described above, the disposable paper container obtained according to the present invention not only can be naturally biodegraded, but also induces environmental problems unlike polyethylene-coated paper which does not rot because the coating layer and pulp layer are easily decomposed. The effect is not to.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例による使い捨て紙カップの製
造工程を示す説明図である。
FIG. 1 is an explanatory view showing a manufacturing process of a disposable paper cup according to an embodiment of the present invention.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 B31B 49/00 0332−3E B31B 49/00 K B65D 5/56 B65D 5/56 D C12S 3/08 8931−4B C12S 3/08 // C09D 103/02 PCW C09D 103/02 PCW 131/04 PEY 131/04 PEY 133/00 PFX 133/00 PFX B29K 1:00 29:00 (71)出願人 595156735 金 台植 大韓民国ソウル特別市永登浦区揚坪洞5街 26−8番地 城山ビル407号 (72)発明者 金 聖浩 アメリカ合衆国カリフォルニア州91208 グレンデール ベルドゴロード221番 1717エヌ (72)発明者 ▲黄▼ 鳳▲益▼ 大韓民国京畿道安山市城谷洞671−6番地 始華工業団地5ラ605 (72)発明者 金 台植 大韓民国ソウル特別市永登浦区揚坪洞5街 26−8番地 城山ビル407号─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display location B31B 49/00 0332-3E B31B 49/00 K B65D 5/56 B65D 5/56 D C12S 3/08 8931-4B C12S 3/08 // C09D 103/02 PCW C09D 103/02 PCW 131/04 PEY 131/04 PEY 133/00 PFX 133/00 PFX B29K 1:00 29:00 (71) Applicant 595156735 Gold stand Seosan Building No. 407 (72) Seosan Building No. 407 (72), No. 26-8, Yangpyeong-dong, Yeongdeungpo-gu, Seoul, Republic of Korea Seoul 208 208 Glendale Belldgo Road 221 1717 N (72) Inventor ▲ Yellow ▼ Feng ▲ Profit ▼ 671-6 Seongya-dong, Ansan-si, Gyeonggi-do, South Korea 5 La 605, Sihwa Industrial Park (72) Inventor Kim Tai Plant Yeong, Seoul, Republic of Korea Pudong District Agetsubohora 5 city 26-8 address Shiroyama building 407 No.

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 乳化エチレンビニルアセテート共重合
体、乳化アクリル複合物共重合体および澱粉を 5.5〜
6.6 : 1.7〜 2.3 : 0.8〜1.3 の比率に含む生分解性コ
ーティング層をその内面に有することを特徴とする生分
解性紙製品。
1. An emulsified ethylene vinyl acetate copolymer, an emulsified acrylic composite copolymer and starch are added in an amount of 5.5 to 5.
A biodegradable paper product having a biodegradable coating layer in a ratio of 6.6: 1.7 to 2.3: 0.8 to 1.3 on its inner surface.
【請求項2】 前記紙製品が使い捨て紙カップであるこ
とを特徴とする請求項1記載の生分解性紙製品。
2. The biodegradable paper product of claim 1, wherein the paper product is a disposable paper cup.
【請求項3】 原紙の一側面に、乳化エチレンビニルア
セテート共重合体、乳化アクリル共重合体、澱粉および
水を 5.5〜 6.6 : 1.7〜 2.3 : 0.8〜1.3 :1 の比率に
含むコーティング溶液を10〜20g/m2塗布した後、1
30〜150℃で乾燥させることにより被膜を形成して
1次製品を製造する第1工程と、 前記コーティング溶液を前記1次製品の非コーティング
面に10〜20g/m2塗布して130〜150℃で乾燥し
た後、5〜7℃に急冷して2次製品を製造する第2工程
と、 前記第2工程で得られた前記2次製品を所望の形状に成
形して最終製品を製造する第3工程と、 を含む生分解性紙製品の製造方法。
3. A coating solution containing an emulsified ethylene vinyl acetate copolymer, an emulsified acrylic copolymer, starch and water in a ratio of 5.5 to 6.6: 1.7 to 2.3: 0.8 to 1.3: 1 on one side of the base paper. ~ 20g / m 2 After applying 1
A first step of producing a primary product by forming a coating by drying at 30 to 150 ° C., and a coating solution of 10 to 20 g / m 2 on the non-coated surface of the primary product to 130 to 150. After being dried at 5 ° C., it is rapidly cooled to 5 to 7 ° C. to manufacture a secondary product, and the secondary product obtained in the second process is molded into a desired shape to manufacture a final product. A method for producing a biodegradable paper product, which comprises a third step.
【請求項4】 前記第1工程と第2工程との間に文字ま
たは模様を印刷する工程をさらに含むことを特徴とする
請求項3記載の生分解性紙製品の製造方法。
4. The method for producing a biodegradable paper product according to claim 3, further comprising a step of printing a character or a pattern between the first step and the second step.
【請求項5】 前記第1工程および第2工程において、
前記コーティング溶液は100〜150メッシュコーテ
ィングローラーを用いて塗布されることを特徴とする請
求項3記載の生分解性紙製品の製造方法。
5. In the first step and the second step,
The method of claim 3, wherein the coating solution is applied using a 100-150 mesh coating roller.
【請求項6】 前記第2工程において、前記コーティン
グ溶液は前記1次製品の非コーティング面の一側端部に
相当する熱接着領域にのみ塗布されることを特徴とする
請求項3記載の生分解性紙製品の製造方法。
6. The raw material according to claim 3, wherein in the second step, the coating solution is applied only to a heat-bonding region corresponding to one end of the uncoated surface of the primary product. Manufacturing method of degradable paper products.
JP7288826A 1995-03-13 1995-11-07 Biodegradable paper product and its preparation Pending JPH08260385A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US40285495A 1995-03-13 1995-03-13
US08/402854 1995-03-13

Publications (1)

Publication Number Publication Date
JPH08260385A true JPH08260385A (en) 1996-10-08

Family

ID=23593543

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7288826A Pending JPH08260385A (en) 1995-03-13 1995-11-07 Biodegradable paper product and its preparation

Country Status (2)

Country Link
JP (1) JPH08260385A (en)
DE (1) DE19541681A1 (en)

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