JPH08118106A - Cutting tool coated with hard layer - Google Patents
Cutting tool coated with hard layerInfo
- Publication number
- JPH08118106A JPH08118106A JP28285194A JP28285194A JPH08118106A JP H08118106 A JPH08118106 A JP H08118106A JP 28285194 A JP28285194 A JP 28285194A JP 28285194 A JP28285194 A JP 28285194A JP H08118106 A JPH08118106 A JP H08118106A
- Authority
- JP
- Japan
- Prior art keywords
- hard layer
- coated
- cutting tool
- cutting
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
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- Cutting Tools, Boring Holders, And Turrets (AREA)
- Physical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】この発明は、切削速度が250m
/minを越える高速連続切削に対して優れた切削性能
を示す硬質層被覆切削工具に関するものである。This invention has a cutting speed of 250 m.
The present invention relates to a hard-layer-coated cutting tool that exhibits excellent cutting performance for high-speed continuous cutting exceeding 100 rpm.
【0002】[0002]
【従来の技術】一般に、WCを主成分とするWC基超硬
合金からなる基体(以下、WC基超硬合金基体という)
またはTiCNを主成分とするサーメットからなる基体
(以下、TiCN基サーメット基体という)の表面に、
(Ti0.5 Si0.5 )Cの単一硬質層を被覆してなる硬
質層被覆切削工具は知られている(特開平1−3065
50号公報参照)。2. Description of the Related Art Generally, a substrate made of WC-based cemented carbide containing WC as a main component (hereinafter referred to as WC-based cemented carbide substrate).
Alternatively, on the surface of a base body composed of cermet containing TiCN as a main component (hereinafter referred to as TiCN base cermet base body),
A hard-layer-coated cutting tool formed by coating a single hard layer of (Ti 0.5 Si 0.5 ) C is known (Japanese Patent Laid-Open No. 3065/1991).
No. 50).
【0003】[0003]
【発明が解決しようとする課題】しかし、前記従来の
(Ti0.5 Si0.5 )C硬質層を被覆した硬質層被覆切
削工具は、高速連続切削に用いた場合には耐摩耗性が十
分でなく、したがって、満足のいく使用寿命が得られて
いない。However, the conventional hard layer-coated cutting tool coated with the (Ti 0.5 Si 0.5 ) C hard layer has insufficient wear resistance when used for high-speed continuous cutting. Therefore, a satisfactory service life is not obtained.
【0004】[0004]
【課題を解決するための手段】そこで、本発明者は、上
述のような課題を解決し、高速連続切削に用いた場合に
も一層の長寿命を示す硬質層被覆切削工具を得るべく研
究を行った結果、WC基超硬合金基体またはTiCN基
サーメット基体の表面に、(Ti1-x Six )(C1-y
Ny )z [ただし、0.01≦x≦0.45、0.01≦y≦1.0 、
0.5 ≦z≦1.34]からなる組成のTiとSiの複合炭窒
化物単一硬質層あるいは複合窒化物単一硬質層を被覆し
た硬質層被覆切削工具は、高速連続切削に用いた場合に
従来よりも一層耐摩耗性に優れかつ使用寿命が長くな
る、という知見を得たのである。Therefore, the present inventor has conducted research to solve the above problems and obtain a hard-layer-coated cutting tool that exhibits a longer life even when used for high-speed continuous cutting. As a result, (Ti 1-x Si x ) (C 1-y ) was formed on the surface of the WC-based cemented carbide substrate or the TiCN-based cermet substrate.
N y ) z [where 0.01 ≦ x ≦ 0.45, 0.01 ≦ y ≦ 1.0,
0.5 ≤ z ≤ 1.34] Ti and Si composite carbonitride single hard layer or hard layer coated cutting tool coated with single nitride composite hard layer has been conventionally used in high-speed continuous cutting. It has been found that the wear resistance is even better and the service life is longer.
【0005】この発明は、かかる知見にもとづいて成さ
れたものであって、WC基超硬合金基体またはTiCN
基サーメット基体の表面に、(Ti1-x Six )(C
1-y Ny )z [ただし、0.01≦x≦0.45、0.01≦y≦1.
0 、0.5 ≦z≦1.34]からなる組成のTiとSiの複合
炭窒化物単一硬質層あるいは複合窒化物単一硬質層を被
覆した硬質層被覆切削工具に特徴を有するものである。The present invention has been made on the basis of the above findings, and is based on the WC-based cemented carbide substrate or TiCN.
On the surface of the base cermet substrate, (Ti 1-x Si x ) (C
1-y N y ) z [where 0.01 ≦ x ≦ 0.45, 0.01 ≦ y ≦ 1.
[0, 0.5 ≤ z ≤ 1.34], and is characterized by a hard carbon-nitride single hard layer of Ti and Si or a hard layer-coated cutting tool coated with a single hard nitride composite layer.
【0006】x、yおよびzの値を前記のごとく限定し
たのは、x<0.01、x>0.45であると所望の耐
摩耗性が得られないからであり、y<0.01、y>
1.0であると所望の耐欠損性が得られないからであ
り、さらにz<0.5であると所望の耐摩耗性が得られ
ず、z>1.34であると所望の耐欠損性が低下すると
ともに剥離が起こりやすくなるからである。前記(Ti
1-x Six )(C1-y Ny)z におけるx、y、zの一
層好ましい範囲は、0.01≦x≦0.30、0.3 ≦y≦0.7 、
0.9 ≦z≦1.1 である。したがって、WC基超硬合金基
体またはTiCN基サーメット基体の表面に形成される
一層好ましい単一硬質層は、TiとSiの複合炭窒化物
単一硬質層である。また、この発明の硬質層被覆切削工
具の単一硬質層の膜厚は1〜10μmの範囲内にあるこ
とが好ましい。The values of x, y and z are limited as described above, because desired wear resistance cannot be obtained when x <0.01 and x> 0.45, and y <0. 01, y>
When 1.0, the desired fracture resistance cannot be obtained, and when z <0.5, the desired abrasion resistance cannot be obtained, and when z> 1.34, the desired fracture resistance cannot be obtained. This is because the property is deteriorated and peeling easily occurs. (Ti
1-x Si x) (C 1-y N y) x in z, y, more preferably in the range of z is, 0.01 ≦ x ≦ 0.30,0.3 ≦ y ≦ 0.7,
0.9 ≦ z ≦ 1.1. Therefore, a more preferable single hard layer formed on the surface of a WC-based cemented carbide substrate or a TiCN-based cermet substrate is a Ti / Si composite carbonitride single hard layer. Further, the film thickness of the single hard layer of the hard layer-coated cutting tool of the present invention is preferably in the range of 1 to 10 μm.
【0007】この発明の硬質層被覆切削工具における単
一硬質層を形成するには、アーク放電式イオンプレーテ
ィング法、マグネトロンスパッタリング法などにより成
形することができる。アーク放電式イオンプレーティン
グ法により単一硬質層を形成するには、まず真空装置内
のTiとSiの混合物のターゲット上にアーク放電を発
生させ、TiとSiを蒸発イオン化させる。同時に非金
属ガス(窒素ガスおよび炭化水素ガス)を装置内に導入
し、負の基板電圧をかけた切削工具基板上に(Ti1-x
Six )(C1-y Ny )z [ただし、0.01≦x≦0.45、
0.01≦y≦1.0、0.5 ≦z≦1.34]からなる単一硬質層
を形成する。TiとSiの比率はターゲットのTi/S
i比率を、またメタル/ガス成分の比率はメタル蒸発量
/ガス導入量を調節したり、基板電圧を変化させること
により制御する。In order to form a single hard layer in the hard layer-coated cutting tool of the present invention, it can be formed by an arc discharge type ion plating method, a magnetron sputtering method or the like. In order to form a single hard layer by the arc discharge type ion plating method, first, arc discharge is generated on a target of a mixture of Ti and Si in a vacuum apparatus to vaporize and ionize Ti and Si. At the same time, a non-metal gas (nitrogen gas and hydrocarbon gas) was introduced into the equipment, and (Ti 1-x
Si x ) (C 1-y N y ) z [where 0.01 ≦ x ≦ 0.45,
0.01≤y≤1.0, 0.5≤z≤1.34]. The ratio of Ti and Si is the target Ti / S
The i ratio and the metal / gas component ratio are controlled by adjusting the metal evaporation amount / gas introduction amount or by changing the substrate voltage.
【0008】マグネトロンスパッタリング法により単一
硬質層を形成するには、まず真空装置内のTiとSiの
混合物のターゲットを試料を挾んで対向させる。つぎに
非金属ガス(窒素ガスおよび炭化水素ガス)を装置内に
導入し、対向ターゲット間にグロー放電をさせる。Ti
とSiをスパッタリングイオン化させることにより負の
基板電圧をかけた切削工具基板上に(Ti1-x Six )
(C1-y Ny )z [ただし、0.01≦x≦0.45、0.01≦y
≦1.0 、0.5 ≦z≦1.34]からなる単一硬質層を形成す
る。TiとSiの比率はターゲットのTi/Si比率
を、またメタル/ガス成分の比率はメタル蒸発量/ガス
導入量を調節したり、基板電圧を変化させることにより
制御する。In order to form a single hard layer by the magnetron sputtering method, first, a target of a mixture of Ti and Si in a vacuum apparatus is sandwiched and made to face each other. Next, a non-metal gas (nitrogen gas and hydrocarbon gas) is introduced into the apparatus to cause glow discharge between opposed targets. Ti
On a cutting tool substrate with a negative substrate voltage applied by sputtering and ionizing Si and Si (Ti 1-x Si x )
(C 1-y N y ) z [where 0.01 ≦ x ≦ 0.45, 0.01 ≦ y
≤1.0, 0.5 ≤z≤1.34]. The Ti / Si ratio is controlled by adjusting the Ti / Si ratio of the target, and the metal / gas component ratio is controlled by adjusting the metal evaporation amount / gas introduction amount or by changing the substrate voltage.
【0009】[0009]
【実施例】つぎに、この発明の硬質層被覆切削工具を実
施例に基づいて具体的に説明する。 実施例1 ISO規格P30相当、SNGA120408の形状を
有するWC基WC基超硬合金製チップおよび表1に示さ
れる比率のTiとSiの混合物ターゲットおよびTiタ
ーゲットを用意した。EXAMPLES Next, the hard layer-coated cutting tool of the present invention will be specifically described based on Examples. Example 1 A WC-based WC-based cemented carbide chip having a shape of SNGA120408 equivalent to ISO standard P30, a mixture target of Ti and Si in the ratios shown in Table 1 and a Ti target were prepared.
【0010】このWC基超硬合金製チップを通常のイオ
ンプレーティング装置内の上方に装着し、一方、前記イ
オンプレーティング装置内の下方には、表1に示される
比率のTiとSiの混合物ターゲットを装着し、かかる
状態で前記イオンプレーティング装置内を排気して1×
10-5Torrの真空に保持し、昇温速度:6℃/mi
n.で700℃に昇温させ、つづいて、この温度に保持
しながら、5×10-2TorrのArガス雰囲気に保持
してイオンクリーニングした。This WC-based cemented carbide tip was mounted in the upper part of a normal ion plating apparatus, while in the lower part of the ion plating apparatus, a mixture of Ti and Si in the ratio shown in Table 1 was used. With the target attached, exhaust the inside of the ion plating device in such a state to 1 ×
Maintaining a vacuum of 10 −5 Torr, heating rate: 6 ° C./mi
n. Then, the temperature was raised to 700 ° C., and then, while maintaining this temperature, it was maintained in an Ar gas atmosphere of 5 × 10 −2 Torr for ion cleaning.
【0011】その後、表1に示される比率のTiとSi
の混合物ターゲット上にアーク放電を発生させてTiと
Siを加熱蒸発させイオン化させるとともに、供給口よ
り表1に示される比率の窒素ガスおよびアセチレンガス
を導入し、表1に示される負の基板電圧をかけることに
より、前記WC基超硬合金製チップを基体表面に表2に
示される膜厚を有しさらに表2に示されるx、yおよび
zの値を有する(Ti1-x Six )(C1-y Ny )z 単
一硬質層を被覆した本発明被覆チップ1〜10、比較被
覆チップ1〜7および従来被覆チップ1を作製した。前
記(Ti1-x Six )(C1-y Ny )z 単一硬質層にお
けるx、yおよびzの値はEPMAにて分析して求め
た。Thereafter, the ratios of Ti and Si shown in Table 1 were used.
Arc discharge is generated on the mixture target of No. 1 to heat and vaporize Ti and Si for ionization, and nitrogen gas and acetylene gas in the ratios shown in Table 1 are introduced from the supply port to obtain the negative substrate voltage shown in Table 1. The WC-based cemented carbide chips have the film thicknesses shown in Table 2 and the values of x, y and z shown in Table 2 (Ti 1-x Si x ) The coated chips 1 to 10 of the present invention, the comparative coated chips 1 to 7 and the conventional coated chip 1 coated with a (C 1 -y N y ) z single hard layer were produced. The values of x, y and z in the (Ti 1-x Si x ) (C 1-y N y ) z single hard layer were determined by EPMA analysis.
【0012】これら本発明被覆チップ1〜10、比較被
覆チップ1〜7および従来被覆チップ1を用いて、下記
の条件の連続乾式切削試験を実施した。 連続乾式切削試験条件 被削材:JIS規格SNCM439(ブリネル硬さ:2
50)の丸材、 切削速度:250m/min、 送り:0.3mm/rev.、 切込み:2.0mm、 の条件で連続乾式切削し、切刃の逃げ面の最大摩耗幅が
0.3mmになったところを寿命とし、寿命に至る時間
(分)および摩耗形態を測定し、それらの測定結果を表
2に示した。Using these coated chips 1 to 10 of the present invention, comparative coated chips 1 to 7 and conventional coated chip 1, a continuous dry cutting test was carried out under the following conditions. Continuous dry cutting test conditions Work material: JIS standard SNCM439 (Brinell hardness: 2
50) round material, cutting speed: 250 m / min, feed: 0.3 mm / rev. , Depth of cut: 2.0 mm, continuous dry cutting was performed, and the life when the maximum wear width of the flank of the cutting edge was 0.3 mm was taken as the life, and the time (minute) to reach the life and the wear pattern were measured. The measurement results are shown in Table 2.
【0013】[0013]
【表1】 [Table 1]
【0014】[0014]
【表2】 [Table 2]
【0015】表2に示される結果から、本発明被覆チッ
プ1〜10は比較被覆チップ1〜7および従来被覆チッ
プ1に比べて切削特性が優れていることが分かる。From the results shown in Table 2, it is understood that the coated chips 1 to 10 of the present invention are superior in cutting characteristics to the comparative coated chips 1 to 7 and the conventional coated chip 1.
【0016】実施例2 TiCN−12%WC−8%Co−8%MoC−7%N
i−5%TaCの組成を有し、ISO規格SNGA12
0408の形状を有するTiCN基サーメット製チップ
および表3に示される比率のTiとSiの混合物ターゲ
ットおよびTiターゲットを用意した。Example 2 TiCN-12% WC-8% Co-8% MoC-7% N
i-5% TaC composition, ISO standard SNGA12
A TiCN-based cermet chip having a shape of 0408, a mixture target of Ti and Si in the ratios shown in Table 3 and a Ti target were prepared.
【0017】このTiCN基サーメット製チップ製チッ
プを通常のイオンプレーティング装置内の上方に装着
し、一方、前記イオンプレーティング装置内の下方に
は、表3に示される比率のTiとSiの混合物ターゲッ
トを装着し、かかる状態で前記イオンプレーティング装
置内を排気して1×10-5Torrの真空に保持し、昇
温速度:6℃/min.で700℃に昇温させ、つづい
て、この温度に保持しながら、5×10-2TorrのA
rガス雰囲気に保持してイオンクリーニングした。This TiCN-based cermet chip tip was mounted in the upper part of a normal ion plating apparatus, while in the lower part of the ion plating apparatus, a mixture of Ti and Si in the ratio shown in Table 3 was used. With the target mounted, the inside of the ion plating apparatus was evacuated in such a state to maintain a vacuum of 1 × 10 −5 Torr, and the temperature rising rate was 6 ° C./min. Then, the temperature is raised to 700 ° C., and then while maintaining this temperature, A of 5 × 10 -2 Torr
It was held in an r gas atmosphere for ion cleaning.
【0018】その後、表3に示される比率のTiとSi
の混合物ターゲット上にアーク放電を発生させてTiと
Siを加熱蒸発させイオン化させるとともに、供給口よ
り表3に示される比率の窒素ガスおよびアセチレンガス
を導入し、表3に示される負の基板電圧をかけることに
より、前記TiCN基サーメット製チップを基体表面に
表4に示される膜厚を有しさらに表4に示されるx、y
およびzの値を有する(Ti1-x Six )(C
1-y Ny )z 単一硬質層を被覆した本発明被覆チップ1
1〜20、比較被覆チップ8〜14および従来被覆チッ
プ2を作製した。前記(Ti1-x Six )(C
1-y Ny )z 単一硬質層におけるx、yおよびzの値は
EPMAにて分析して求めた。Then, the ratios of Ti and Si shown in Table 3 were used.
Arc discharge is generated on the mixture target of No. 1 to heat and vaporize Ti and Si for ionization, and nitrogen gas and acetylene gas in the ratios shown in Table 3 are introduced from the supply port to obtain the negative substrate voltage shown in Table 3. The TiCN-based cermet chip has a film thickness shown in Table 4 on the surface of the substrate, and x, y shown in Table 4 are applied.
And (Ti 1-x Si x ) (C
1-y N y ) z A single coated chip 1 of the present invention coated with a single hard layer
1 to 20, comparative coated chips 8 to 14 and conventional coated chip 2 were produced. The above (Ti 1-x Si x ) (C
The values of x, y and z in the 1-y N y ) z single hard layer were obtained by analysis by EPMA.
【0019】これら本発明被覆チップ11〜20、比較
被覆チップ8〜14および従来被覆チップ2を用いて、
下記の条件の連続乾式切削試験を実施した。Using these coated chips 11 to 20 of the present invention, comparative coated chips 8 to 14 and conventional coated chip 2,
A continuous dry cutting test was carried out under the following conditions.
【0020】連続乾式切削試験条件 被削材:JIS規格SNCM439(ブリネル硬さ:2
50)の丸材、 切削速度:300m/min、 送り:0.2mm/rev.、 切込み:2.0mm、 の条件で連続乾式切削し、切刃の逃げ面の最大摩耗幅が
0.3mmになったところを寿命とし、寿命に至る時間
(分)および摩耗形態を測定し、それらの測定結果を表
4に示した。Continuous dry cutting test conditions Work material: JIS standard SNCM439 (Brinell hardness: 2
50) round material, cutting speed: 300 m / min, feed: 0.2 mm / rev. , Depth of cut: 2.0 mm, continuous dry cutting was performed, and the life when the maximum wear width of the flank of the cutting edge was 0.3 mm was taken as the life, and the time (minute) to reach the life and the wear pattern were measured. The measurement results are shown in Table 4.
【0021】[0021]
【表3】 [Table 3]
【0022】[0022]
【表4】 [Table 4]
【0023】表4に示される結果から、本発明被覆チッ
プ11〜20は、比較被覆チップ8〜14および従来被
覆チップ2に比べて切削性能が優れていることが分か
る。From the results shown in Table 4, it can be seen that the coated chips 11 to 20 of the present invention are superior in cutting performance to the comparative coated chips 8 to 14 and the conventional coated chip 2.
【0024】[0024]
【発明の効果】前記実施例1〜2に示される結果から、
この発明の硬質層被覆切削工具は、従来の硬質層被覆切
削工具に比べて一層優れた性能を有し、工業上優れた効
果をもたらすものである。From the results shown in Examples 1 and 2 above,
The hard layer-coated cutting tool of the present invention has more excellent performance than the conventional hard layer-coated cutting tool, and brings an industrially excellent effect.
Claims (2)
Six )(C1-y Ny )z [ただし、0.01≦x≦0.45、
0.01≦y≦1.0 、0.5 ≦z≦1.34]からなる組成のTi
とSiの複合炭窒化物単一硬質層あるいは複合窒化物単
一硬質層を被覆してなることを特徴とする硬質層被覆切
削工具。1. A surface of a WC-based cemented carbide substrate is provided with (Ti 1-x
Si x ) (C 1-y N y ) z [where 0.01 ≦ x ≦ 0.45,
0.01≤y≤1.0, 0.5≤z≤1.34]
A hard-layer-coated cutting tool characterized by coating a composite carbonitride single hard layer or a composite nitride single hard layer of Si and Si.
i1-x Six )(C1-y Ny )z [ただし、0.01≦x≦
0.45、0.01≦y≦1.0 、0.5 ≦z≦1.34]からなる組成
のTiとSiの複合炭窒化物単一硬質層あるいは複合窒
化物単一硬質層を被覆してなることを特徴とする硬質層
被覆切削工具。2. The surface of a TiCN-based cermet substrate is provided with (T
i 1-x Si x ) (C 1-y N y ) z [where 0.01 ≦ x ≦
0.45, 0.01 ≤ y ≤ 1.0, 0.5 ≤ z ≤ 1.34] Ti and Si composite hard carbonitride single hard layer or a hard layer characterized by coating a single composite nitride hard layer Coated cutting tool.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28285194A JP3480086B2 (en) | 1994-10-21 | 1994-10-21 | Hard layer coated cutting tool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP28285194A JP3480086B2 (en) | 1994-10-21 | 1994-10-21 | Hard layer coated cutting tool |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH08118106A true JPH08118106A (en) | 1996-05-14 |
JP3480086B2 JP3480086B2 (en) | 2003-12-15 |
Family
ID=17657898
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP28285194A Expired - Lifetime JP3480086B2 (en) | 1994-10-21 | 1994-10-21 | Hard layer coated cutting tool |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3480086B2 (en) |
Cited By (16)
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US6586122B2 (en) | 2000-07-13 | 2003-07-01 | Hitachi Tool Engineering, Ltd. | Multilayer-coated cutting tool |
US7060345B2 (en) | 2002-07-11 | 2006-06-13 | Sumitomo Electric Industries, Ltd. | Coated tool |
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US7294416B2 (en) * | 2003-03-25 | 2007-11-13 | Kobe Steel, Ltd. | Hard film |
JP2009214196A (en) * | 2008-03-07 | 2009-09-24 | Mitsubishi Materials Corp | Surface-coated cutting tool having hard coating layer exhibiting excellent resistance to defect |
JP2009220239A (en) * | 2008-03-18 | 2009-10-01 | Mitsubishi Materials Corp | Surface coated cutting tool having hard coating layer exerting superior chipping resistance |
JP2009233823A (en) * | 2008-03-28 | 2009-10-15 | Mitsubishi Materials Corp | Surface-coated cutting tool having hard coating layer exhibiting excellent chipping resistance |
US20100135738A1 (en) * | 2007-04-18 | 2010-06-03 | Sandvik Intellectual Property Ab | coated cutting tool and a method of making thereof |
US20110188950A1 (en) * | 2008-04-18 | 2011-08-04 | Sandvik Intellectual Property Ab | Coated cutting tool and a method of making thereof |
US20110311837A1 (en) * | 2009-03-17 | 2011-12-22 | Smc Corporation | Covering member for preventing erosion |
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US8440328B2 (en) | 2011-03-18 | 2013-05-14 | Kennametal Inc. | Coating for improved wear resistance |
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JP2014181388A (en) * | 2013-03-19 | 2014-09-29 | Nippon Coating Center Kk | Metal product |
US20140370309A1 (en) * | 2011-12-05 | 2014-12-18 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E. V. | Hard-material-coated bodies composed of metal, cemented hard material, cermet or ceramic and processes for producing such bodies |
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Cited By (23)
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US6586122B2 (en) | 2000-07-13 | 2003-07-01 | Hitachi Tool Engineering, Ltd. | Multilayer-coated cutting tool |
US7060345B2 (en) | 2002-07-11 | 2006-06-13 | Sumitomo Electric Industries, Ltd. | Coated tool |
US7294416B2 (en) * | 2003-03-25 | 2007-11-13 | Kobe Steel, Ltd. | Hard film |
US7758974B2 (en) | 2003-03-25 | 2010-07-20 | Kobe Steel, Ltd. | Hard film |
JP2006194389A (en) * | 2005-01-14 | 2006-07-27 | Showa Corp | Hydraulic shock absorber for vehicle |
US8206812B2 (en) * | 2006-12-15 | 2012-06-26 | Sandvik Intellectual Property Ab | Coated cutting tool |
US20100135738A1 (en) * | 2007-04-18 | 2010-06-03 | Sandvik Intellectual Property Ab | coated cutting tool and a method of making thereof |
JP2010524701A (en) * | 2007-04-18 | 2010-07-22 | サンドビック インテレクチュアル プロパティー アクティエボラーグ | Coated cutting tool and manufacturing method thereof |
US8247092B2 (en) * | 2007-04-18 | 2012-08-21 | Sandvik Intellectual Property Ab | Coated cutting tool and a method of making thereof |
JP2009214196A (en) * | 2008-03-07 | 2009-09-24 | Mitsubishi Materials Corp | Surface-coated cutting tool having hard coating layer exhibiting excellent resistance to defect |
JP2009220239A (en) * | 2008-03-18 | 2009-10-01 | Mitsubishi Materials Corp | Surface coated cutting tool having hard coating layer exerting superior chipping resistance |
JP2009233823A (en) * | 2008-03-28 | 2009-10-15 | Mitsubishi Materials Corp | Surface-coated cutting tool having hard coating layer exhibiting excellent chipping resistance |
US20110188950A1 (en) * | 2008-04-18 | 2011-08-04 | Sandvik Intellectual Property Ab | Coated cutting tool and a method of making thereof |
US8507110B2 (en) * | 2008-04-18 | 2013-08-13 | Sandvik Intellectual Property Ab | Coated cutting tool and a method of making thereof |
US20110311837A1 (en) * | 2009-03-17 | 2011-12-22 | Smc Corporation | Covering member for preventing erosion |
US8580407B2 (en) * | 2009-03-17 | 2013-11-12 | Smc Corporation | Covering member for preventing erosion |
US8440328B2 (en) | 2011-03-18 | 2013-05-14 | Kennametal Inc. | Coating for improved wear resistance |
US8859114B2 (en) | 2011-03-18 | 2014-10-14 | Kennametal Inc. | Coating for improved wear resistance |
US20140370309A1 (en) * | 2011-12-05 | 2014-12-18 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E. V. | Hard-material-coated bodies composed of metal, cemented hard material, cermet or ceramic and processes for producing such bodies |
US9309593B2 (en) * | 2011-12-05 | 2016-04-12 | Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E. V. | Hard-material-coated bodies composed of metal, cemented hard material, cermet or ceramic and processes for producing such bodies |
US20140037943A1 (en) * | 2012-08-03 | 2014-02-06 | Fih (Hong Kong) Limited | Coated article and method for making same |
JP2014181388A (en) * | 2013-03-19 | 2014-09-29 | Nippon Coating Center Kk | Metal product |
US11440102B2 (en) * | 2015-12-22 | 2022-09-13 | Sandvik Intellectual Property Ab | Coated cutting tool and method |
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