JPH0770145A - 固体有機アルミノキシ組成物の製造方法 - Google Patents

固体有機アルミノキシ組成物の製造方法

Info

Publication number
JPH0770145A
JPH0770145A JP6125473A JP12547394A JPH0770145A JP H0770145 A JPH0770145 A JP H0770145A JP 6125473 A JP6125473 A JP 6125473A JP 12547394 A JP12547394 A JP 12547394A JP H0770145 A JPH0770145 A JP H0770145A
Authority
JP
Japan
Prior art keywords
solid
aluminoxane
solution
catalyst system
borane compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6125473A
Other languages
English (en)
Japanese (ja)
Inventor
Rolf L Geerts
エル.ギアーツ ロルフ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of JPH0770145A publication Critical patent/JPH0770145A/ja
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/603Component covered by group C08F4/60 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06Aluminium compounds
    • C07F5/061Aluminium compounds with C-aluminium linkage
    • C07F5/066Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602Component covered by group C08F4/60 with an organo-aluminium compound
    • C08F4/6028Component covered by group C08F4/60 with an organo-aluminium compound with an alumoxane, i.e. a compound containing an -Al-O-Al-group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
JP6125473A 1993-06-22 1994-06-07 固体有機アルミノキシ組成物の製造方法 Pending JPH0770145A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US080899 1993-06-22
US08/080,899 US5354721A (en) 1993-06-22 1993-06-22 Organo-aluminoxy product and use

Publications (1)

Publication Number Publication Date
JPH0770145A true JPH0770145A (ja) 1995-03-14

Family

ID=22160353

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6125473A Pending JPH0770145A (ja) 1993-06-22 1994-06-07 固体有機アルミノキシ組成物の製造方法

Country Status (8)

Country Link
US (2) US5354721A (en:Method)
EP (1) EP0630900A1 (en:Method)
JP (1) JPH0770145A (en:Method)
KR (1) KR950000712A (en:Method)
BR (1) BR9402351A (en:Method)
CA (1) CA2119952A1 (en:Method)
FI (1) FI942993L (en:Method)
NO (1) NO942369L (en:Method)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019533750A (ja) * 2016-11-07 2019-11-21 エスシージー ケミカルズ カンパニー,リミテッド 重合ポリエチレンワックスの調製のための方法

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5411925A (en) * 1993-02-12 1995-05-02 Phillips Petroleum Company Organo-aluminoxy product and use
DE4203753A1 (de) * 1992-02-10 1993-08-12 Basf Ag Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5449650A (en) * 1992-12-08 1995-09-12 Mitsubishi Petrochemical Company Limited Catalyst components for polymerization of olefins and use thereof
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use
US5436212A (en) * 1994-04-15 1995-07-25 Phillips Petroleum Company Organoaluminoxy product, preparation, and use
US5496781A (en) * 1994-05-16 1996-03-05 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use
US5622906A (en) * 1994-09-16 1997-04-22 Phillips Petroleum Company Compositions useful for olefin polymerization and processes therefor and therewith
EP0728773B1 (en) * 1995-02-21 1998-11-04 Mitsubishi Chemical Corporation Catalysts for olefin polymerization and a process for preparing olefin polymers therewith
BR9604776A (pt) * 1995-03-10 1998-06-23 Dow Chemical Co Componente de catalisador sustentado catalisador sustentado processo para preparar um componente de catalisador sustentado e um catalisador sustentado aduto de um composto organometálico processo de polimerizaçao por adiç o composto complexo e método para preparar um composto complexo
US5700748A (en) * 1995-09-29 1997-12-23 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers comprising a bridging allyl-cyclodienyl ligand on a metal atom
US5777143A (en) * 1995-12-22 1998-07-07 Akzo Nobel Nv Hydrocarbon soluble alkylaluminoxane compositions formed by use of non-hydrolytic means
US5767034A (en) * 1996-05-31 1998-06-16 Intevep, S.A. Olefin polymerization catalyst with additive comprising aluminum-silicon composition, calixarene derivatives or cyclodextrin derivatives
SG84505A1 (en) * 1996-06-12 2001-11-20 Phillips Petroleum Co Process for producing an organo-aluminoxane composition for olefin polymerization
KR20000070004A (ko) 1997-01-08 2000-11-25 마이클 비. 키한 탄화수소 수지 제조용 촉매로서의 금속 산화물 고체 산
DE19709866A1 (de) * 1997-03-11 1998-09-17 Basf Ag Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen
EP1995258B1 (en) 1998-05-18 2013-08-21 Chevron Phillips Chemical Company Lp Catalyst composition for polymerizing monomers
US6812182B2 (en) * 1998-10-23 2004-11-02 Albemarle Corporation Compositions formed from hydroxyaluminoxane and their use as catalyst components
US6465385B1 (en) 1999-02-12 2002-10-15 Sunoco, Inc. (R&M) Zwitterionic polymerization catalyst
CN1217733C (zh) 1999-12-16 2005-09-07 菲利浦石油公司 有机金属化合物催化剂
AU2003302033A1 (en) 2002-10-15 2004-06-15 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7541402B2 (en) * 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7897539B2 (en) * 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US8058200B2 (en) * 2007-05-17 2011-11-15 Chevron Phillips Chemical Company, L.P. Catalysts for olefin polymerization
ES2687676T3 (es) 2011-03-08 2018-10-26 Dow Global Technologies Llc Proceso para reciclar disolvente usado en una reacción de polimerización basada en etileno
US8440772B2 (en) 2011-04-28 2013-05-14 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8487053B2 (en) 2011-11-30 2013-07-16 Chevron Phillips Chemical Company Lp Methods for removing polymer skins from reactor walls
US8501882B2 (en) 2011-12-19 2013-08-06 Chevron Phillips Chemical Company Lp Use of hydrogen and an organozinc compound for polymerization and polymer property control
US8703883B2 (en) 2012-02-20 2014-04-22 Chevron Phillips Chemical Company Lp Systems and methods for real-time catalyst particle size control in a polymerization reactor
US10273315B2 (en) 2012-06-20 2019-04-30 Chevron Phillips Chemical Company Lp Methods for terminating olefin polymerizations
US8916494B2 (en) 2012-08-27 2014-12-23 Chevron Phillips Chemical Company Lp Vapor phase preparation of fluorided solid oxides
US8940842B2 (en) 2012-09-24 2015-01-27 Chevron Phillips Chemical Company Lp Methods for controlling dual catalyst olefin polymerizations
KR101746744B1 (ko) 2013-02-08 2017-06-13 미쓰이 가가쿠 가부시키가이샤 고체상 폴리알루미녹세인 조성물, 올레핀 중합용 촉매, 올레핀 중합체의 제조 방법, 및 고체상 폴리알루미녹세인 조성물의 제조 방법
WO2016183008A1 (en) 2015-05-11 2016-11-17 W.R. Grace & Co.-Conn. Process to produce modified clay, modified clay produced and use thereof
JP6963350B2 (ja) 2015-05-11 2021-11-05 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 改質粘土を生成するプロセス、担持メタロセン重合触媒、生成された触媒及びその使用
US9708426B2 (en) 2015-06-01 2017-07-18 Chevron Phillips Chemical Company Lp Liquid-solid sampling system for a loop slurry reactor
US10005861B2 (en) 2016-06-09 2018-06-26 Chevron Phillips Chemical Company Lp Methods for increasing polymer production rates with halogenated hydrocarbon compounds
US10774161B2 (en) 2019-01-31 2020-09-15 Chevron Phillips Chemical Company Lp Systems and methods for polyethylene recovery with low volatile content
US11339229B2 (en) 2020-01-27 2022-05-24 Formosa Plastics Corporation, U.S.A. Process for preparing catalysts and catalyst compositions
JP7578702B2 (ja) 2020-01-27 2024-11-06 フォルモサ プラスティクス コーポレイション, ユーエスエー 触媒および触媒組成物の調製プロセス
US12077616B2 (en) 2021-12-15 2024-09-03 Chevron Phillips Chemical Company Lp Production of polyethylene and ethylene oligomers from ethanol and the use of biomass and waste streams as feedstocks to produce the ethanol
US11845814B2 (en) 2022-02-01 2023-12-19 Chevron Phillips Chemical Company Lp Ethylene polymerization processes and reactor systems for the production of multimodal polymers using combinations of a loop reactor and a fluidized bed reactor
US12466900B2 (en) 2022-04-19 2025-11-11 Chevron Phillips Chemical Company Lp Loop slurry periodogram control to prevent reactor fouling and reactor shutdowns
WO2023239560A1 (en) 2022-06-09 2023-12-14 Formosa Plastics Corporaton, U.S.A. Clay composite support-activators and catalyst compositions
WO2025042807A1 (en) 2023-08-22 2025-02-27 Chevron Phillips Chemical Company Lp Integrated processes utilizing water electrolysis and oxidative dehydrogenation of ethane

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4496699A (en) * 1981-03-13 1985-01-29 National Distillers And Chemical Corporation Process for polymerizing high melt index olefins and polymerization catalysts used therefore
US4952714A (en) * 1988-06-22 1990-08-28 Exxon Chemical Patents Inc. Non-aqueous process for the preparation of alumoxanes
CA1327366C (en) * 1988-06-22 1994-03-01 Howard Curtis Welborn, Jr. Non-aqueous process for the preparation of alumoxanes
US5091352A (en) * 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
DE4203753A1 (de) * 1992-02-10 1993-08-12 Basf Ag Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5354721A (en) * 1993-06-22 1994-10-11 Phillips Petroleum Company Organo-aluminoxy product and use

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019533750A (ja) * 2016-11-07 2019-11-21 エスシージー ケミカルズ カンパニー,リミテッド 重合ポリエチレンワックスの調製のための方法

Also Published As

Publication number Publication date
US5480848A (en) 1996-01-02
FI942993A7 (fi) 1994-12-23
EP0630900A1 (en) 1994-12-28
US5354721A (en) 1994-10-11
FI942993A0 (fi) 1994-06-21
NO942369D0 (en:Method) 1994-06-21
BR9402351A (pt) 1995-01-17
CA2119952A1 (en) 1994-12-23
KR950000712A (ko) 1995-01-03
NO942369L (no) 1994-12-23
FI942993L (fi) 1994-12-23

Similar Documents

Publication Publication Date Title
JPH0770145A (ja) 固体有機アルミノキシ組成物の製造方法
KR100309224B1 (ko) 중합촉매에유용한고형유기-알루미녹시생성물제조방법
JP2816469B2 (ja) 気相重合用メタロセン−アルモキサン担持触媒の製造方法
KR0137960B1 (ko) 가스상 중합에 의한 폴리에틸렌 왁스의 제조방법
US5414180A (en) Organo-aluminoxy product and use
AU625601B2 (en) A supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
JP2740921B2 (ja) トリエチルアルミニウムを用いる活性メタロセン―アルモキサン担持触媒の製法
JP3093795B2 (ja) 1−オレフィンの(共)重合用の担持触媒
US5416179A (en) Catalyst compositions and olefin polymerization
CA2113601A1 (en) Catalyst compositions and process for preparing polyolefins
JPH03502207A (ja) オレフィンの重合用担持バナジウム触媒及びその製造及び使用方法
EP0618931B1 (en) A modified monocyclopentadienyl transition metal/alumoxane catalyst system for polymerization of olefins
US5670589A (en) Organoaluminoxy product, catalyst systems, preparation, and use
KR20000076121A (ko) 알크-1-엔 중합용 지지된 촉매 시스템
WO1999020660A1 (en) Polymerization catalyst systems, their preparation and use
CA2423246A1 (en) Supported catalyst systems
EP0812860B1 (en) Processes to produce organo-aluminoxane compositions
CA2219816C (en) Azaborolinyl metal complexes as olefin polymerization catalysts