JPH0764687B2 - Insecticidal composition - Google Patents
Insecticidal compositionInfo
- Publication number
- JPH0764687B2 JPH0764687B2 JP2109840A JP10984090A JPH0764687B2 JP H0764687 B2 JPH0764687 B2 JP H0764687B2 JP 2109840 A JP2109840 A JP 2109840A JP 10984090 A JP10984090 A JP 10984090A JP H0764687 B2 JPH0764687 B2 JP H0764687B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- compound
- acid ester
- musca domestica
- cis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【発明の詳細な説明】 ＜産業上の利用分野＞ 本発明は殺虫組成物に関する。DETAILED DESCRIPTION OF THE INVENTION <Field of Industrial Application> The present invention relates to an insecticidal composition.
＜従来の技術および解決すべき課題＞ で示される2,4−ジオキソ−１−（２−プロピニル）イ
ミダゾリジン−３−イルメチル クリサンテマート（以
下、化合物Ａと記す。）は特公昭60−9715号公報に記載
の化合物であり、殺虫剤の有効成分として使用できるこ
とは知られているが、殺虫効力において必ずしも充分で
あるとは言えない。<Conventional technology and problems to be solved> 2,4-dioxo-1- (2-propynyl) imidazolidin-3-ylmethyl chrysanthemate (hereinafter referred to as compound A) is a compound described in JP-B-60-9715, It is known that it can be used as an active ingredient of an agent, but it is not always sufficient in insecticidal efficacy.
＜課題を解決するための手段＞ 本発明者らは、化合物Ａの殺虫力増強について鋭意検討
した結果、（ａ）化合物Ａに、（ｂ）１種以上の、炭素
数16〜19個のモノカルボン酸エステルまたは／および炭
素数16〜19個のジカルボン酸エステルを（ａ）と（ｂ）
の重量比が3:1〜1:100になるように加えた時に、化合物
Ａの殺虫力が著しく増強されることを見い出し、本発明
に至った。すなわち、本発明は、 （ａ） 2,4−ジオキソ−１−（２−プロピニル）イミ
ダゾリジン−３−イルメチル クリサンテマート（化合
物Ａ） と （ｂ） １種以上の、炭素数16〜19個のモノカルボン酸
エステルまたは／および炭素数16〜19個のジカルボン酸
エステル を含み、（ａ）と（ｂ）の重量比が3:1〜1:100であるこ
とを特徴とする殺虫組成物を提供するものである。<Means for Solving the Problems> As a result of intensive studies on the enhancement of the insecticidal activity of the compound A, the present inventors have found that (a) the compound A, (b) one or more mono C16-19 mono compounds. Carboxylic acid ester and / or dicarboxylic acid ester having 16 to 19 carbon atoms (a) and (b)
It was found that the insecticidal activity of Compound A is remarkably enhanced when added in a weight ratio of 3: 1 to 1: 100 to achieve the present invention. That is, the present invention provides (a) 2,4-dioxo-1- (2-propynyl) imidazolidin-3-ylmethyl chrysanthemate (Compound A) and (b) one or more kinds having 16 to 19 carbon atoms. An insecticidal composition comprising a monocarboxylic acid ester of (1) or / and a dicarboxylic acid ester having 16 to 19 carbon atoms in a weight ratio of (a) and (b) of 3: 1 to 1: 100. It is provided.
化合物Ａには各種の光学異性体や幾何異性体が存在する
が、本発明ではそれらのうち殺虫活性を有する任意の異
性体およびその混合物が使用できる。化合物Ａの本発明
組成物中の含量は、通常重量比で0.001％〜75％であ
る。Compound A has various optical isomers and geometrical isomers, but in the present invention, any isomer having insecticidal activity and a mixture thereof can be used. The content of the compound A in the composition of the present invention is usually 0.001% to 75% by weight.
本発明の組成物において、用いられる炭素数16〜19個の
モノカルボン酸エステルまたは炭素数16〜19個のジカル
ボン酸エステルとしては、たとえば、フタル酸ジブチ
ル，パルミチン酸イソプロピル，ミリスチン酸イソプロ
ピル，ラウリン酸ヘキシル等が挙げられる。これらは２
種以上混合して用いることもでき、本発明の組成物中
に、通常重量比で0.0003％〜75％配合して用いられる。Examples of the monocarboxylic acid ester having 16 to 19 carbon atoms or the dicarboxylic acid ester having 16 to 19 carbon atoms used in the composition of the present invention include dibutyl phthalate, isopropyl palmitate, isopropyl myristate, and lauric acid. Hexyl and the like can be mentioned. These are 2
It is also possible to mix and use one or more kinds, and it is usually used by blending 0.0003 to 75% by weight in the composition of the present invention.
本発明の組成物にはさらに他の殺虫剤、共力剤、香料、
殺菌剤、溶剤、噴射剤、固体担体等を１種以上配合する
こともできる。The composition of the present invention further comprises other insecticides, synergists, fragrances,
One or more kinds of germicides, solvents, propellants, solid carriers and the like may be blended.
他の殺虫剤としては、例えば、 （RS）−３−アリル−２−メチル−４−オキソシクロペ
ント−２−エニル（IRS）−シス，トランス−クリサン
テメート〔アレスリン〕 3,4,5,6−テトラヒドロフタルイミドメチル（1RS）−シ
ス，トランス−クリサンテメート〔テトラメスリン〕 （Ｓ）−２−メチル−４−オキソ−３−（２−プロピニ
ル）シクロペント−２−エニル（1R）−シス，トランス
−クリサンテメート〔プラレスリン〕 ３−フェノキシベンジル（1RS）−シス，トランス−ク
リサンテメート〔フェノスリン〕 ５−ベンジル−３−フリルメチル（1RS）−シス，トラ
ンス−クリサンテメート〔レスメスリン〕 （RS）−α−シアノ−３−フェノキシベンジル（1R）−
シス，トランス−クリサンテメート〔サイフェノスリ
ン〕 ３−フェノキシベンジル（1RS）−シス，トランス−３
−（2,2−ジクロロビニル）−2,2−ジメチルシクロプロ
パンカルボキシレート〔パーメスリン〕 （RS）−α−シアノ−３−フェノキシベンジル（1RS）
−シス，トランス−３−（2,2−ジクロロビニル）−2,2
−ジメチルシクロプロパンカルボキシレート〔サイパー
メスリン〕 （Ｓ）−α−シアノ−３−フェノキシベンジル（1R）−
シス−３−（2,2,−ジブロモビニル）−2,2−ジメチル
シクロプロパンカルボキシレート〔デルタメスリン〕 （RS）−α−シアノ−４−フルオロ−３−フェノキシベ
ンジル（1RS）−シス，トランス−３−（2,2−ジクロロ
ビニル）−2,2−ジメチルシクロプロパンカルボキシレ
ート〔サイフルスリン〕 ５−（２−プロピニル）フルフリル（1RS）−シス，ト
ランス−クリサンテメート〔フラメスリン〕 ２−（４−エトキシフェニル）−２−メチルプロピル３
−フェノキシベンジル エーテル〔エトフェンプロク
ス〕 2,2−ジクロロビニル ジメチル フォスフォート〔ジ
クロロボス〕 O,O−ジメチルＯ−（３−メチル−４−ニトロフェニ
ル）フォスフォロチオエート〔フェニトロチオン〕 ２−（１−メチルエトキシ）フェノール メチルカーバ
メート〔プロポキサー〕 ４−フェノキシフェニル（RS）−２−（２−ピリジルオ
キシ）プロピルエーテル〔ピリプロキシフェン〕 イソプロピル（2E,4E）−11−メトキシ−3,7,11−トリ
メチル−2,4−ドデカジエノエート〔メトプレン〕 エチル（2E,4E）−3,7,11−トリメチルドデカ−2,4−ジ
エノエート〔ハイドロプレン〕 １−（４−クロロフェニル）−３−（2,6−ジフルオロ
ベンゾイル）ウレア〔ジフルベンズロン〕 Ｎ−シクロプロピル−1,3,5−トリアジン−2,4,6−トリ
アミン〔シロマジン〕 等が挙げられる。Other insecticides include, for example, (RS) -3-allyl-2-methyl-4-oxocyclopent-2-enyl (IRS) -cis, trans-chrysanthemate [allethrin] 3,4,5, 6-Tetrahydrophthalimidomethyl (1RS) -cis, trans-chrysanthemate [tetramethrin] (S) -2-methyl-4-oxo-3- (2-propynyl) cyclopent-2-enyl (1R) -cis, trans -Chrysanthemate [praresulin] 3-phenoxybenzyl (1RS) -cis, trans-chrysanthemate [phenothrin] 5-benzyl-3-furylmethyl (1RS) -cis, trans-chrysanthemate [resmethrin] (RS) -Α-Cyano-3-phenoxybenzyl (1R)-
Cis, trans-chrysanthemate [cyphenothrin] 3-phenoxybenzyl (1RS) -cis, trans-3
-(2,2-Dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate [permethrin] (RS) -α-cyano-3-phenoxybenzyl (1RS)
-Cis, trans-3- (2,2-dichlorovinyl) -2,2
-Dimethylcyclopropanecarboxylate [cypermethrin] (S) -α-cyano-3-phenoxybenzyl (1R)-
Cis-3- (2,2, -dibromovinyl) -2,2-dimethylcyclopropanecarboxylate [deltamethrin] (RS) -α-cyano-4-fluoro-3-phenoxybenzyl (1RS) -cis, trans- 3- (2,2-Dichlorovinyl) -2,2-dimethylcyclopropanecarboxylate [cyfluthrin] 5- (2-propynyl) furfuryl (1RS) -cis, trans-chrysanthemate [flamesulin] 2- (4- Ethoxyphenyl) -2-methylpropyl 3
-Phenoxybenzyl ether [ethofenprox] 2,2-dichlorovinyl dimethyl phosphor [dichloroboss] O, O-dimethyl O- (3-methyl-4-nitrophenyl) phosphorothioate [fenitrothion] 2- (1 -Methylethoxy) phenol methylcarbamate [propoxer] 4-phenoxyphenyl (RS) -2- (2-pyridyloxy) propyl ether [pyriproxyfen] isopropyl (2E, 4E) -11-methoxy-3,7,11- Trimethyl-2,4-dodecadienoate [methoprene] ethyl (2E, 4E) -3,7,11-trimethyldodeca-2,4-dienoate [hydroprene] 1- (4-chlorophenyl) -3- (2 , 6-Difluorobenzoyl) urea [diflubenzuron] N-cyclopropyl-1,3,5-triazine-2,4,6-tria Emissions [cyromazine], and the like.
共力剤としては、例えば、 α−〔２−（２−ブトキシエトキシ）エトキシ〕−4,5
−メチレンジオキシ−２−プロピルトルエン〔ピペロニ
ルブトキサイド〕、Ｎ−（２−エチルヘキシル）−ビシ
クロ〔2,2,1〕ヘプタ−５−エン−2,3−ジカルボキシイ
ミド〔MGK−264〕、オクタクロロジプロピルエーテル
〔Ｓ−421〕等が挙げられる。Examples of the synergist include α- [2- (2-butoxyethoxy) ethoxy] -4,5
-Methylenedioxy-2-propyltoluene [piperonyl butoxide], N- (2-ethylhexyl) -bicyclo [2,2,1] hept-5-ene-2,3-dicarboximide [MGK-264 ], Octachlorodipropyl ether [S-421] and the like.
溶剤としては、例えば、イソプロピルアルコール、ケロ
シン、ドデシルベンゼン等が挙げられる。Examples of the solvent include isopropyl alcohol, kerosene, dodecylbenzene and the like.
噴射剤としては、例えば、プロパン／ブタン、ジメチル
エーテル、フロンガス等が挙げられる。Examples of the propellant include propane / butane, dimethyl ether, CFC gas and the like.
本発明組成物は、例えば所定量の化合物Ａ、前記のカル
ボン酸エステル、さらに必要により他の殺虫剤、共力
剤、香料、殺菌剤、溶剤、噴射剤、固体担体等を室温下
または加温下に混合、溶解させることにより調製され
る。The composition of the present invention contains, for example, a predetermined amount of compound A, the above-mentioned carboxylic acid ester, and optionally other insecticide, synergist, perfume, bactericide, solvent, propellant, solid carrier, etc. at room temperature or under heating. It is prepared by mixing and dissolving below.
このようにして調製された、本発明組成物が有効な害虫
類としては、たとえば次のものが挙げられる。Examples of the pests for which the composition of the present invention is effective, prepared in this manner, include the following.
鱗翅目害虫、 イガ、コイガ等 双翅目害虫、 アカイエカ、コガタアカイエカ等のイエカ類、ネッタイ
シマカ、ヒトスジシマカ等のヤブカ類、シナハマダラカ
等のハマダラカ類、ユスリカ類、イエバエ、オオイエバ
エ等のイエバエ類、クロバエ類、ニクバエ類、ヒメイエ
バエ、タネバエ、タマネギバエ等のハナバエ類、ミバエ
類、ショウジョウバエ類、チョウバエ類、アブ類、ブユ
類、サシバエ類等 網翅目害虫、 チャバネゴキブリ、クロゴキブリ、ワモンゴキブリ、ト
ビイロゴキブリ、コバネゴキブリ等 膜翅目害虫、 アリ類、スズメバチ類、アリガタバチ類、カブラハバチ
類のハバチ類等 等翅目害虫、 ヤマトシロアリ、イエシロアリ等 マダニ類、 オウシマダニ等 室内塵性ダニ類、 コナダニ類、チリダニ類、ツメダニ類、イエダニ類等 本発明の組成物を殺虫目的に使用する際、そのまま用い
ることもできるが、通常はエアゾールや油剤等に製剤し
て使用する。その際、エアゾールや油剤における化合物
Ａの配合量は重量比で0.001〜５％が好ましい。Lepidopteran pests, squid, carp, etc. Diptera pests, Culex pipiens, Culex pipiens, Culex mosquitoes, Aedes aegypti, Aedes albopictus, Anopheles mosquitoes such as Aedes albopictus, Chironomid mosquitoes, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica, Musca domestica , Drosophila melanogaster, fly, fly, onion fly, etc., fruit fly, fruit fly, butterfly fly, flies, gnats, flies, sand flies, etc. Pests of the eyes, ants, wasps, wasps, wasps, wasps, etc., etc., etc., pests, etc., pests of the order, Yamato termites, house termites, etc. Etc. When using Ming composition insecticidally purposes, it can be used as they are usually used formulated into an aerosol or oil, or the like. At that time, the compounding amount of the compound A in the aerosol or the oil agent is preferably 0.001 to 5% by weight.
＜実施例＞ 以下、本発明を実施例および比較例にてさらに詳しく説
明するが、本発明はこれらの例のみに限定されるもので
はない。<Examples> Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited to these examples.
尚、以下の例において部は重量部を表わす。In the following examples, parts represent parts by weight.
実施例１ 化合物Ａ（酸側がｄ−トランス体）50.0部、ミリスチン
酸イソプロピル50.0部を加温下に混合溶解して殺虫組成
物を得た。Example 1 50.0 parts of compound A (d-trans form on the acid side) and 50.0 parts of isopropyl myristate were mixed and dissolved under heating to obtain an insecticidal composition.
上記と同様にして得られた殺虫組成物を第１表に示す。The insecticidal composition obtained in the same manner as above is shown in Table 1.
実施例１〜７および比較例１〜６の各殺虫組成物につい
て、化合物Ａまたはフェノスリンがが10mg/m2になるよ
う、アセトン希釈液0.3mlを直径8.5cmのガラスシャーレ
に塗布し、アセトン風乾後チャバネゴキブリ10頭を放虫
し、ノックダウン効力KT50（50％ノックダウンするのに
要する時間）を調べた結果を第２表に示す。 For each of the insecticidal compositions of Examples 1 to 7 and Comparative Examples 1 to 6, 0.3 ml of the acetone diluted solution was applied to a glass petri dish having a diameter of 8.5 cm so that the compound A or phenothrin was 10 mg / m 2, and the mixture was air-dried with acetone. Table 2 shows the results of examining the knockdown efficacy KT50 (the time required for 50% knockdown) of 10 adult German cockroaches.
実施例８ 0.1部の化合物Ａ、0.1部のミリスチン酸イソプロピルお
よび0.3部のサイフェノスリンを、ドデシルベンゼン20.
0部およびケロシン39.5部に溶解し、全混合物を缶に入
れ、プロパンおよびブタンとからなる噴射剤混合物40.0
部を装入してエアゾールを得た。 Example 8 0.1 part of compound A, 0.1 part of isopropyl myristate and 0.3 part of cyphenothrin, 20 parts of dodecylbenzene.
A propellant mixture consisting of propane and butane, dissolved in 0 parts and 39.5 parts of kerosene, the whole mixture was placed in a can 40.0.
Parts were charged to obtain an aerosol.
実施例９ 1.0部の化合物Ａおよび1.0部のミリスチン酸イソプロピ
ルをイソプロピルアルコール20.0部およびケロシン28.0
部に溶解し、全混合物を缶に入れ、プロパン、ブタンお
よびジメチルエーテルからなる噴射剤混合物50.0部を装
入してエアゾールを得た。Example 9 1.0 part of compound A and 1.0 part of isopropyl myristate were mixed with 20.0 parts of isopropyl alcohol and 28.0 parts of kerosene.
The mixture was dissolved in 1 part, and the whole mixture was put into a can and charged with 50.0 parts of a propellant mixture consisting of propane, butane and dimethyl ether to obtain an aerosol.
実施例10 1.0部の化合物Ａおよび31.0部のミリスチン酸イソプロ
ピルをケロシン18.0部に溶解し、全混合物を缶に入れ、
プロパン、ブタンおよびジメチルエーテルからなる噴射
剤混合物50.0部を装入してエアゾールを得た。Example 10 1.0 part of compound A and 31.0 parts of isopropyl myristate were dissolved in 18.0 parts of kerosene and the whole mixture was placed in a can.
An aerosol was obtained by charging 50.0 parts of a propellant mixture consisting of propane, butane and dimethyl ether.
実施例11 1.0部の化合物Ａおよび1.0部のフタル酸ジブチルを、イ
ソプロピルアルコール2.5部およびドデシルベンゼン45.
5部に溶解し、全混合物を缶に入れ、プロパン、ブタン
およびジメチルエーテルからなる噴射剤混合物50.0部を
装入してエアゾールを得た。Example 11 1.0 part of compound A and 1.0 part of dibutyl phthalate, 2.5 parts of isopropyl alcohol and 45 parts of dodecylbenzene.
The mixture was dissolved in 5 parts, and the whole mixture was put into a can and charged with 50.0 parts of a propellant mixture consisting of propane, butane and dimethyl ether to obtain an aerosol.
＜発明の効果＞ 本発明の殺虫組成物は網翅目害虫、双翅目害虫等に優れ
た殺虫効力を有する。<Effects of the Invention> The insecticidal composition of the present invention has an excellent insecticidal effect against insect pests of the order Diptera, insect pests of the order Diptera and the like.
Claims (2)
ピニル）イミダゾリジン−３−イルメチル クリサンテ
マート と （ｂ） １種以上の、炭素数16〜19個のモノカルボン酸
エステルまたは／および炭素数16〜19個のジカルボン酸
エステル を含み、（ａ）と（ｂ）の重量比が3:1〜1:100であるこ
とを特徴とする殺虫組成物。1. (a) 2,4-Dioxo-1- (2-propynyl) imidazolidin-3-ylmethyl chrysanthemate and (b) one or more monocarboxylic acid ester having 16 to 19 carbon atoms. Or / and a dicarboxylic acid ester having 16 to 19 carbon atoms, wherein the weight ratio of (a) to (b) is 3: 1 to 1: 100.
がフタル酸ジブチル，パルミチン酸イソプロピル，ミリ
スチン酸イソプロピルまたはラウリン酸ヘキシルである
請求項１記載の殺虫組成物。2. The insecticidal composition according to claim 1, wherein at least one of the carboxylic acid esters is dibutyl phthalate, isopropyl palmitate, isopropyl myristate or hexyl laurate.
Priority Applications (25)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2109840A JPH0764687B2 (en) | 1990-04-24 | 1990-04-24 | Insecticidal composition |
| AU74201/91A AU636471B2 (en) | 1990-04-24 | 1991-04-09 | Insecticidal compositions |
| FR9104478A FR2661070B1 (en) | 1990-04-24 | 1991-04-12 | INSECTICIDE COMPOSITIONS BASED ON 2,4-DIOXO-1- (2-PROPYNYL) IMIDAZOLIDINE-3-YLMETHYL CHRYSANTHEMATE. |
| CA002040370A CA2040370C (en) | 1990-04-24 | 1991-04-12 | Insecticidal compositions |
| GB9107920A GB2243297B (en) | 1990-04-24 | 1991-04-15 | Insecticidal compositions |
| CH1136/91A CH682706A5 (en) | 1990-04-24 | 1991-04-16 | Insecticidal compositions based chrysanthemate 2,4-dioxo-1- (2-propynyl) imidazolidin-3-ylmethyl. |
| BE9100352A BE1004726A3 (en) | 1990-04-24 | 1991-04-17 | INSECTICIDE COMPOSITIONS BASED ON 2,4-DIOXO-1- (2-PROPYNYL) IMIDAZOLIDINE-3-YLMETHYL CHRYSANTHEMATE. |
| NL9100673A NL9100673A (en) | 1990-04-24 | 1991-04-18 | INSECTICIDE COMPOSITIONS. |
| ZA912907A ZA912907B (en) | 1990-04-24 | 1991-04-18 | Insecticidal compositions |
| ITRM910273A IT1244979B (en) | 1990-04-24 | 1991-04-22 | INSECTICIDE COMPOSITION |
| BR919101639A BR9101639A (en) | 1990-04-24 | 1991-04-23 | INSECTICIDE COMPOSITION, PROCESS TO CONTROL INSECTS, TO PREPARE INSECTICIDE COMPOSITION AND TO PREPARE AN INSECTICIDE AEROSOL |
| MX025480A MX172672B (en) | 1990-04-24 | 1991-04-23 | INSECTICIDE COMPOSITION AND METHOD FOR REPRESSING INSECTS |
| HU911351A HU209631B (en) | 1990-04-24 | 1991-04-23 | Insecticides with improved activity |
| YU73691A YU47780B (en) | 1990-04-24 | 1991-04-23 | INSECTICIDE MIXTURE AND PROCEDURE FOR THE PRODUCTION OF INSECTICIDE AEROSOL |
| PT97450A PT97450B (en) | 1990-04-24 | 1991-04-23 | PROCESS FOR THE PREPARATION OF INSECTICIDAL COMPOSITIONS CONTAINING 2,4-DIOXO-1- (2-PROPYINYL) IMIDAZOLIDIN-3-ILYMETHYL CRISANTEMATE |
| ES9101021A ES2035768B1 (en) | 1990-04-24 | 1991-04-23 | INSECTICIDE COMPOSITIONS CONTAINING A CHRYSANTHEMATE. |
| SI9110736A SI9110736A (en) | 1990-04-24 | 1991-04-23 | Insecticidal compositions |
| SU914895311A RU2035142C1 (en) | 1990-04-24 | 1991-04-23 | Insecticidal composition |
| KR1019910006610A KR0161534B1 (en) | 1990-04-24 | 1991-04-24 | Insecticidal compositions |
| DE4113383A DE4113383C2 (en) | 1990-04-24 | 1991-04-24 | Insecticidal agents |
| US07/856,557 US5190745A (en) | 1990-04-24 | 1992-03-24 | Insecticidal compositions |
| HR920865A HRP920865A2 (en) | 1990-04-24 | 1992-10-02 | Insecticidal compositions |
| LVP-92-387A LV10158B (en) | 1990-04-24 | 1992-12-22 | Insecticides (composition of insecticides) |
| LTIP1063A LT3606B (en) | 1990-04-24 | 1993-09-21 | Insecticidal composition |
| SG156894A SG156894G (en) | 1990-04-24 | 1994-10-24 | Insecticidal compositions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2109840A JPH0764687B2 (en) | 1990-04-24 | 1990-04-24 | Insecticidal composition |
| SG156894A SG156894G (en) | 1990-04-24 | 1994-10-24 | Insecticidal compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH049306A JPH049306A (en) | 1992-01-14 |
| JPH0764687B2 true JPH0764687B2 (en) | 1995-07-12 |
Family
ID=26449553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2109840A Expired - Lifetime JPH0764687B2 (en) | 1990-04-24 | 1990-04-24 | Insecticidal composition |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPH0764687B2 (en) |
| AU (1) | AU636471B2 (en) |
| BE (1) | BE1004726A3 (en) |
| CH (1) | CH682706A5 (en) |
| DE (1) | DE4113383C2 (en) |
| FR (1) | FR2661070B1 (en) |
| GB (1) | GB2243297B (en) |
| HU (1) | HU209631B (en) |
| IT (1) | IT1244979B (en) |
| NL (1) | NL9100673A (en) |
| SG (1) | SG156894G (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4445546A1 (en) * | 1994-12-20 | 1996-06-27 | Bayer Ag | Use of lauric acid esters as substances that increase activity |
| JP3855311B2 (en) * | 1996-08-07 | 2006-12-06 | 住友化学株式会社 | Aerosol composition |
| KR100471016B1 (en) * | 1996-08-07 | 2005-07-12 | 스미또모 가가꾸 가부시키가이샤 | Insecticidal aerosol compositions and pesticidal compositions for preparing them |
| US7030156B2 (en) | 2001-03-05 | 2006-04-18 | University Of Florida Research Foundation, Inc | Devices and methods for eliminating termite colonies |
| US6716421B2 (en) | 2001-03-05 | 2004-04-06 | University Of Florida Research Foundation, Inc. | Devices and methods for eliminating termite colonies |
| US6969512B2 (en) | 2001-03-05 | 2005-11-29 | The University Of Florida Research Foundation, Inc. | Devices and methods for eliminating termite colonies |
| JP5326320B2 (en) * | 2007-03-30 | 2013-10-30 | 住友化学株式会社 | Pest control composition and pest control method |
| AR082963A1 (en) * | 2010-09-17 | 2013-01-23 | Sumitomo Chemical Co | COMPOSITION FOR PEST CONTROL AEROSOL |
| JP6132703B2 (en) * | 2012-08-28 | 2017-05-24 | 大日本除蟲菊株式会社 | Aerosol for bee nesting control and method for controlling bee nesting using the same |
| JP6754197B2 (en) * | 2015-12-28 | 2020-09-09 | 大日本除蟲菊株式会社 | Pest control aerosol |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4899337A (en) * | 1972-04-05 | 1973-12-15 | ||
| JPS609715A (en) * | 1983-06-25 | 1985-01-18 | ワイエムオ−エス・アクチエンゲゼルシヤフト・インドウストリ−プロドウクテ | Method and device for manufacturing synthetic resin thin wall body |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5372821A (en) * | 1976-12-09 | 1978-06-28 | Sumitomo Chem Co Ltd | Aerosol insecticides |
| IT1114770B (en) * | 1977-03-23 | 1986-01-27 | Bernabe Giuseppina | Long-acting pyrethroid insecticide compositions - contg. a vaporisation-modifying agent e.g. butyl stearate |
| JPS609715B2 (en) * | 1977-06-20 | 1985-03-12 | 住友化学工業株式会社 | Carboxylic acid esters, their production methods, and insecticides and acaricides containing them as active ingredients |
| JPS5428818A (en) * | 1977-08-05 | 1979-03-03 | Fumakilla Ltd | Method of enhancing effect of pesticide smoked in short time |
| DE3029426A1 (en) * | 1980-08-02 | 1982-03-11 | Bayer Ag, 5090 Leverkusen | AGAINST EFFECTIVE POUR-ON FORMULATIONS |
| DE3317823A1 (en) * | 1983-05-17 | 1984-11-22 | Bayer Ag, 5090 Leverkusen | PEST CONTROL |
| JPS60139605A (en) * | 1983-12-27 | 1985-07-24 | Sumitomo Chem Co Ltd | Fumigation composition |
| NZ230699A (en) * | 1988-11-11 | 1991-02-26 | Sumitomo Chemical Co | Insecticidal composition comprising 2,4-dioxo-1-(2-propynyl)imidazolidin-3-ylmethyl chrysanthemate and an aromatic hydrocarbon/kerosene solvent |
-
1990
- 1990-04-24 JP JP2109840A patent/JPH0764687B2/en not_active Expired - Lifetime
-
1991
- 1991-04-09 AU AU74201/91A patent/AU636471B2/en not_active Expired
- 1991-04-12 FR FR9104478A patent/FR2661070B1/en not_active Expired - Lifetime
- 1991-04-15 GB GB9107920A patent/GB2243297B/en not_active Expired - Lifetime
- 1991-04-16 CH CH1136/91A patent/CH682706A5/en not_active IP Right Cessation
- 1991-04-17 BE BE9100352A patent/BE1004726A3/en not_active Expired - Fee Related
- 1991-04-18 NL NL9100673A patent/NL9100673A/en not_active Application Discontinuation
- 1991-04-22 IT ITRM910273A patent/IT1244979B/en active IP Right Grant
- 1991-04-23 HU HU911351A patent/HU209631B/en not_active IP Right Cessation
- 1991-04-24 DE DE4113383A patent/DE4113383C2/en not_active Expired - Lifetime
-
1994
- 1994-10-24 SG SG156894A patent/SG156894G/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4899337A (en) * | 1972-04-05 | 1973-12-15 | ||
| JPS609715A (en) * | 1983-06-25 | 1985-01-18 | ワイエムオ−エス・アクチエンゲゼルシヤフト・インドウストリ−プロドウクテ | Method and device for manufacturing synthetic resin thin wall body |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4113383C2 (en) | 2000-02-24 |
| FR2661070B1 (en) | 1998-11-20 |
| CH682706A5 (en) | 1993-11-15 |
| SG156894G (en) | 1995-03-17 |
| IT1244979B (en) | 1994-09-13 |
| JPH049306A (en) | 1992-01-14 |
| ITRM910273A0 (en) | 1991-04-22 |
| ITRM910273A1 (en) | 1992-10-22 |
| AU636471B2 (en) | 1993-04-29 |
| BE1004726A3 (en) | 1993-01-19 |
| HU209631B (en) | 1994-09-28 |
| DE4113383A1 (en) | 1991-10-31 |
| AU7420191A (en) | 1991-11-07 |
| GB2243297A (en) | 1991-10-30 |
| GB2243297B (en) | 1993-09-08 |
| NL9100673A (en) | 1991-11-18 |
| FR2661070A1 (en) | 1991-10-25 |
| GB9107920D0 (en) | 1991-05-29 |
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