JPH0757852A - Waterproof heating element unit - Google Patents

Waterproof heating element unit

Info

Publication number
JPH0757852A
JPH0757852A JP20603993A JP20603993A JPH0757852A JP H0757852 A JPH0757852 A JP H0757852A JP 20603993 A JP20603993 A JP 20603993A JP 20603993 A JP20603993 A JP 20603993A JP H0757852 A JPH0757852 A JP H0757852A
Authority
JP
Japan
Prior art keywords
adhesive resin
heating element
layer
eva
hot melt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20603993A
Other languages
Japanese (ja)
Inventor
Nobuo Kishi
岸  信夫
Junichi Yoshioka
淳一 吉岡
Akiyoshi Iguchi
昭義 井口
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyo Ink Mfg Co Ltd
Original Assignee
Toyo Ink Mfg Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyo Ink Mfg Co Ltd filed Critical Toyo Ink Mfg Co Ltd
Priority to JP20603993A priority Critical patent/JPH0757852A/en
Publication of JPH0757852A publication Critical patent/JPH0757852A/en
Pending legal-status Critical Current

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  • Resistance Heating (AREA)
  • Manufacturing Of Electrical Connectors (AREA)

Abstract

PURPOSE:To improve waterproofing property by covering a heating element unit with a waterproof insulating material consisting of an outer layer of a specified polyethylene shrink tube and an inner layer of an adhesive resin, and applying an adhesive resin to a lead wire leading hole. CONSTITUTION:This unit has a two-layer structure consisting of an outer layer 3 of a cross-linked polyethylene shrink tube and an inner layer 5 of a thermal shrink tube provided with an adhesive resin. As the adhesive resin of the layer 5, each hot melt composition such as ethylene vinyl acetate copolymer (EVA), ethylene ethyl acrylate copolymer (EEA), and ethylene methyl methacrylate copolymer (EMMA) is given, and the EVA hot melt composition is preferred from the viewpoint of working temperature and water absorptivity. Examples of an adhesive resin 2 to be filled in the leading hole of a wire 1 include hot melt compositions such as EVA, EEA, EMMA. The cover layer 7 of an electric linear heating element is polyethylene, polypropylene, or the like, the added adhesive resin is EVA, EEA, EMMA or the like, and the addition amount is preferably 3-15wt.%. Thus, reliability and waterproofing property are improved.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、融雪,暖房,乾燥装置
等に使用される電気式線状発熱体ユニットに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electric linear heating element unit used for snow melting, heating, drying equipment and the like.

【0002】[0002]

【従来の技術】電気部品等の防水方法としては、 ブチルラバーテープを各防水部に螺旋状に隙間無く巻
き、その上を保護する為に塩化ビニルテープ及び収縮チ
ューブで被覆する方法がある。この方法の欠点として
は、人手に頼る所が多い、機械による効率化がはかりに
くい、複雑な構造特に凹凸が大きい部分の防水が困難で
あり製品の防水性能のばらつきが大きく歩留りが悪い点
が挙げられる。 エポキシ系の接着剤を用いる方法もあるが、2液混合
式が主流である為工程が複雑になる、硬化後に可撓性が
無くなる等の欠点がある。
2. Description of the Related Art As a waterproofing method for electric parts and the like, there is a method in which a butyl rubber tape is spirally wound around each waterproof part without any gaps and covered with vinyl chloride tape and a shrink tube to protect the part. Disadvantages of this method are that it relies heavily on human labor, it is difficult to improve efficiency by machines, it is difficult to waterproof complex structures, especially those with large irregularities, and there are large variations in the waterproof performance of the products, resulting in poor yield. To be There is also a method of using an epoxy adhesive, but there are drawbacks such that the process is complicated because the two-liquid mixing method is the mainstream and the flexibility is lost after curing.

【0003】従来より市販されている防水型絶縁収縮チ
ューブがあるが、端末結線部にリード線の並列結線(2
股引出し)が施される場合、絶縁性能の確保が不十分で
あった。
Although there is a waterproof insulation shrinkable tube commercially available in the past, parallel connection of lead wires (2
When the crotch drawer is applied, the insulation performance was not sufficiently secured.

【0004】[0004]

【発明が解決しようとする課題】本発明者らは、検討の
結果、電気式線状発熱体の結線部の防水被覆を施す場
合、各部品相互の接着の不足,2股引出し部の谷の部分
から水が侵入していることを見出し、本発明に至ったも
ので本発明は、前記の種々の欠点を改良し防水性に優れ
た発熱体ユニットを提供するものである。
DISCLOSURE OF THE INVENTION As a result of investigations, the inventors of the present invention have found that when a waterproof coating is applied to the connection part of an electric linear heating element, insufficient adhesion between parts is caused, and a valley in the two-forked lead-out part occurs. The present invention has been made by discovering that water has invaded from a portion thereof, and the present invention provides a heating element unit which is improved in the above various drawbacks and is excellent in waterproofness.

【0005】[0005]

【課題を解決するための手段】本発明は、熱可塑性樹脂
にカーボンブラックを分散した半導電性組成物の芯層上
に熱可塑性樹脂の被覆層を共押出成形してなる電気式線
状発熱体結線部に外層が架橋ポリエチレン収縮チュー
ブ,内層が接着性樹脂である防水被覆を施し水中絶縁性
2000MΩ以上となる防水型発熱体ユニットである。
ここで用いる外層が架橋ポリエチレン収縮チューブ,内
層が接着性樹脂からなる接着性樹脂内装熱収縮チューブ
は、図1に示す様な2層構造になっており必ずしも内層
と外層が一体でなくてもよく、外層は、電子線により架
橋されたポリエチレン収縮チューブで必要に応じて難燃
性が付与される。
DISCLOSURE OF THE INVENTION The present invention is directed to an electric linear heating method in which a coating layer of a thermoplastic resin is coextruded on a core layer of a semiconductive composition in which carbon black is dispersed in a thermoplastic resin. A waterproof heating element unit having a cross-linked polyethylene shrink tube as an outer layer and a waterproof coating having an adhesive resin as an inner layer on a body connection portion and having a water insulation of 2000 MΩ or more.
The outer layer used here is a cross-linked polyethylene shrink tube, and the inner layer is made of an adhesive resin. The heat-shrinkable tube containing an adhesive resin has a two-layer structure as shown in FIG. 1, and the inner layer and the outer layer do not necessarily have to be integrated. The outer layer is a polyethylene shrink tube cross-linked with an electron beam, and is provided with flame retardancy as needed.

【0006】内層の接着性樹脂としては、エチレン酢酸
ビニル共重合体(EVA),または、エチレンエチルア
クリレート共重合体(EEA),エチレンメチルメタク
リレート共重合体(EMMA),ポリエステル共重合
体,ナイロン共重合体などの各ホットメルト組成のもの
があり、加工温度,吸水率の点でEVAホットメルト組
組成のものが好ましい。本発明で用いる結線部リード
線,例えばビニル電線の2股引き出し口に充填する接着
性樹脂は、EVA,EEA,EMMA,ポリエステル共
重合体、ナイロン共重合体などの各ホットメルト組成の
ものが挙げられ、溶融粘度2000〜15000cps
(180℃)程度のものが好ましい。なお、チューブの
内層である接着性樹脂と2股引き出し口に充填する接着
性樹脂とは同一でも異なっていてもよい。
Examples of the adhesive resin for the inner layer include ethylene vinyl acetate copolymer (EVA), ethylene ethyl acrylate copolymer (EEA), ethylene methyl methacrylate copolymer (EMMA), polyester copolymer and nylon copolymer. There are various hot-melt compositions such as polymers, and EVA hot-melt composition compositions are preferable in terms of processing temperature and water absorption. The adhesive resin used in the present invention for filling the lead wire of the wire connecting portion, for example, a vinyl electric wire, has a hot melt composition such as EVA, EEA, EMMA, a polyester copolymer, and a nylon copolymer. Melt viscosity 2000-15000 cps
It is preferably about (180 ° C.). The adhesive resin that is the inner layer of the tube and the adhesive resin that fills the two-pronged outlet may be the same or different.

【0007】上記の接着性樹脂は、それ自体に接着性を
有しているが、防水性を高める為には、ホットメルト組
成で用いることが好ましい。ホットメルトは、流動性が
高く細部の空隙に充填される。又ホットメルトには粘着
付与剤,その他の添加剤を併用することが出来る。ホッ
トメルトの充填方法としては、ガンによる注入法,金型
使用による圧注入法のいずれでもよい。本発明で、用い
る電気式線状発熱体の被覆層に用いられる熱可塑性樹脂
は、ポリエチレン(PE),ポリプロピレン(PP)な
どが挙げられ、これに添加する接着性樹脂は、EVA,
EEA,EMMA,マレイン酸変性PE及びPP,アオ
イオノマーのうち一種類又は二種類以上のものが併用さ
れる。添加量は、物性低下を考慮して3〜15重量%程
度が好ましい。
Although the above-mentioned adhesive resin has adhesiveness itself, it is preferable to use it in a hot-melt composition in order to enhance waterproofness. The hot melt has a high fluidity and fills the voids of the details. A tackifier and other additives may be used in combination with the hot melt. The hot melt filling method may be either a gun injection method or a pressure injection method using a mold. Examples of the thermoplastic resin used in the coating layer of the electric linear heating element used in the present invention include polyethylene (PE) and polypropylene (PP), and the adhesive resin added to this is EVA,
One or more of EEA, EMMA, maleic acid-modified PE and PP, and aionomer are used in combination. The amount of addition is preferably about 3 to 15% by weight in consideration of deterioration of physical properties.

【0008】本発明の防水型発熱体ユニットの絶縁部な
いし防水部の部分断面図を図1に示す。
FIG. 1 is a partial cross-sectional view of the insulating portion or waterproof portion of the waterproof heating element unit of the present invention.

【0009】[0009]

【実施例】以下、実施例に基づき本発明をさらに詳細に
説明をする。 実施例1 PPにアセチレンブラックを添加してなる半導電性組成
物の芯層及びPEの被覆層を共押出成形した電気式線状
発熱体を得た。この発熱体を2100mmに切断し両端
に2mm径のドリルで穴を開け圧着端子を打ち込み、6
00Vビニル絶縁ビニルシース電線 2本を結線し、電
線の2股引出し口にEVA系ホットメルト(コニシ社製
商品名メルターボール)を充填し、その部分をEVA系
ホットメルト内装型熱収縮チューブ(住友電気工業社製
スミチューブW5C)で被覆し、熱風発生器(シュタイ
ネル社製ホットエアガン)で2分間加熱した後、防水部
を水中に12時間時間以上放置し、電池式絶縁抵抗計
(日置電機社製メガオームハイテスター)で、水中絶縁
抵抗を測定した結果2000MΩ以上の値が得られた。
The present invention will be described in more detail based on the following examples. Example 1 An electric linear heating element was obtained by coextrusion molding a core layer of a semiconductive composition obtained by adding acetylene black to PP and a coating layer of PE. This heating element is cut into 2100 mm, holes are drilled at both ends with a 2 mm diameter drill, and crimp terminals are driven in.
00V vinyl insulated vinyl sheath electric wire is connected, EVA hot melt (product name Melter Ball manufactured by Konishi Co., Ltd.) is filled in the two-forked outlet of the electric wire, and the part is EVA hot melt internal heat shrink tube (Sumitomo Electric Sumitube W5C manufactured by Kogyo Co., Ltd., and heated for 2 minutes by a hot air generator (Hot air gun manufactured by Steinel), and then the waterproof part is left in water for 12 hours or more, and a battery-type insulation resistance meter (Mega Ohm manufactured by Hioki Electric Co., Ltd.) As a result of measuring the underwater insulation resistance with a high tester, a value of 2000 MΩ or more was obtained.

【0010】実施例1 実施例1において、電気式線状発熱体の被覆層としてP
EにEEA12重量%を添加して成形した以外は、実施
例1と同様にして発熱体ユニットを作成し、水中絶縁抵
抗を測定した結果2000MΩ以上の値が得られ、電気
式線状発熱体の被覆層とEVA系ホットメルト内装型熱
収縮チューブとの接着性も良好であった。 比較例1 PPにアセチレンブラックを添加してなる半導電性組成
物の芯層及びPEの被覆層を共押出成形した電気式線状
発熱体を得た。この発熱体を2100mmに切断し両端
に2mm径のドリルで穴を開け圧着端子を打ち込み、6
00Vビニル絶縁ビニルシース電線2本を結線し、発熱
体部及び,圧着端子部,電線部,各部分をブチルゴムを
主成分とした自己融着性絶縁テープ(古河電機工業社製
エフコテープ1号)で螺旋状に巻き、その上からポリエ
チレン基材とブチルゴムを主成分とした粘着層との2層
からなる自己融着性絶縁テープ(古河電機工業社製エフ
コテープ2号)を螺旋状に巻き、さらに保護層として塩
化ビニルテープ又は、電子線により架橋された熱収縮チ
ューブ(住友電気工業社製スミチューブC)で被覆し発
熱体ユニットを作成した後、実施例1と同様にして水中
絶縁抵抗を測定した結果、防水処理箇所100当たり6
か所の絶縁不良(2000MΩ以下)が発生し歩留りが
悪い。
Example 1 In Example 1, P was used as a coating layer for the electric linear heating element.
A heating element unit was prepared in the same manner as in Example 1 except that EEA (12% by weight) was added and molded, and the underwater insulation resistance was measured to obtain a value of 2000 MΩ or more. The adhesiveness between the coating layer and the EVA-based hot melt interior heat shrink tube was also good. Comparative Example 1 An electric linear heating element was obtained by coextrusion molding a core layer of a semiconductive composition obtained by adding acetylene black to PP and a coating layer of PE. This heating element is cut into 2100 mm, holes are drilled at both ends with a 2 mm diameter drill, and crimp terminals are driven in.
Two 00V vinyl-insulated vinyl sheath electric wires are connected, and the heating element, crimp terminal, electric wire, and other parts are spirally wound with a self-bonding insulating tape (Fuco Tape No. 1 manufactured by Furukawa Electric Co., Ltd.) whose main component is butyl rubber. Winding, then spirally wrapping a self-fusing insulating tape (Fuco Tape No. 2 manufactured by Furukawa Electric Co., Ltd.) consisting of two layers of a polyethylene base material and an adhesive layer containing butyl rubber as a main component, and further protecting layer As a result of measuring the underwater insulation resistance in the same manner as in Example 1 after coating a vinyl chloride tape or a heat-shrinkable tube (Sumitube C manufactured by Sumitomo Electric Industries, Ltd.) cross-linked with an electron beam to prepare a heating element unit, 6 per 100 waterproof treatment points
Insulation failure (2000 MΩ or less) occurs at some places, resulting in poor yield.

【0011】比較例1 PPにアセチレンブラックを添加してなる半導電性組成
物の芯層及びPEの被覆層を共押出成形した電気式線状
発熱体を得た。この発熱体を2100mmに切断し両端
に2mm径のドリルで穴を開け圧着端子を打ち込み、6
00Vビニル絶縁ビニルシース電線2本を結線し、その
結線部をEVA系ホットメルト内装型熱収縮チューブ
(住友電気工業社製スミチューブW5C)又は、EVA
内装型熱収縮チューブ(住友電気工業社製スミチューブ
W)のいずれかを用いて被覆し実施例1と同様に加熱し
た後、実施例1と同様にして水中絶縁抵抗を測定した結
果、いずれの場合も2000MΩ以下となり絶縁不良で
あった。
Comparative Example 1 An electric linear heating element was obtained by coextrusion molding a core layer of a semiconductive composition made by adding acetylene black to PP and a coating layer of PE. This heating element is cut into 2100 mm, holes are drilled at both ends with a 2 mm diameter drill, and crimp terminals are driven in.
Two 00V vinyl-insulated vinyl sheath electric wires are connected, and the connection part is an EVA hot-melt interior type heat-shrinkable tube (Sumitube W5C manufactured by Sumitomo Electric Industries, Ltd.) or EVA.
After coating with one of the interior heat-shrinkable tubes (Sumitube W manufactured by Sumitomo Electric Industries, Ltd.) and heating in the same manner as in Example 1, the result of measuring the in-water insulation resistance in the same manner as in Example 1 shows which case. Also was 2000 MΩ or less, and the insulation was poor.

【図面の簡単な説明】[Brief description of drawings]

【図1】は、本発明の一実施態様を示す発熱体ユニット
の結線部及び、防水部の部分断面図を示す。
FIG. 1 is a partial cross-sectional view of a wire connection portion and a waterproof portion of a heating element unit showing an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1:600Vビニル絶縁ビニルシース電線 2:接着性樹脂 3:接着性樹脂内装熱収縮チューブの外層 4:圧着端子 5:接着性樹脂内装熱収縮チューブの内層 6:電気式線状発熱体半導電層 7:電気式線状発熱体被覆層 1: 600V vinyl insulated vinyl sheath electric wire 2: adhesive resin 3: outer layer of heat-shrinkable tube containing adhesive resin 4: crimp terminal 5: inner layer of heat-shrinkable tube containing adhesive resin 6: electrical conductive linear heating element semi-conductive layer 7 : Electric linear heating element coating layer

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 熱可塑性樹脂にカーボンブラックを分散
した半導電性組成物の芯層上に熱可塑性樹脂の被覆層を
共押出成形してなる電気式線状発熱体結線部に外層が架
橋ポリエチレン収縮チューブ、内層が接着性樹脂である
防水絶縁材料による被覆及び結線部のリード線の2股引
出し口に接着性樹脂を施してなることを特徴とする防水
型発熱体ユニット。
1. An electric linear heating element formed by co-extruding a coating layer of a thermoplastic resin on a core layer of a semiconductive composition in which carbon black is dispersed in a thermoplastic resin. A waterproof heating element unit comprising a shrinkable tube, a coating of a waterproof insulating material whose inner layer is an adhesive resin, and an adhesive resin applied to the bifurcated outlets of the lead wires of the connection portion.
【請求項2】 熱可塑性樹脂の被覆層が、極性官能基を
有する接着性樹脂3〜50重量%含有することを特徴と
する請求項1記載の防水型発熱体ユニット。
2. The waterproof heating unit according to claim 1, wherein the coating layer of the thermoplastic resin contains 3 to 50% by weight of the adhesive resin having a polar functional group.
JP20603993A 1993-08-20 1993-08-20 Waterproof heating element unit Pending JPH0757852A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20603993A JPH0757852A (en) 1993-08-20 1993-08-20 Waterproof heating element unit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20603993A JPH0757852A (en) 1993-08-20 1993-08-20 Waterproof heating element unit

Publications (1)

Publication Number Publication Date
JPH0757852A true JPH0757852A (en) 1995-03-03

Family

ID=16516887

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20603993A Pending JPH0757852A (en) 1993-08-20 1993-08-20 Waterproof heating element unit

Country Status (1)

Country Link
JP (1) JPH0757852A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007287647A (en) * 2006-03-22 2007-11-01 Furukawa Electric Co Ltd:The Water cut-off treatment structure of electric core wire and water cut-off method of electric core wire
JP2010205465A (en) * 2009-03-02 2010-09-16 Sparkling Lights Kk Decorative illumination device and method of manufacturing the same
CN110657076A (en) * 2019-09-16 2020-01-07 北京控制工程研究所 Wire switching insulation processing structure for Hall thruster

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007287647A (en) * 2006-03-22 2007-11-01 Furukawa Electric Co Ltd:The Water cut-off treatment structure of electric core wire and water cut-off method of electric core wire
JP2010205465A (en) * 2009-03-02 2010-09-16 Sparkling Lights Kk Decorative illumination device and method of manufacturing the same
CN110657076A (en) * 2019-09-16 2020-01-07 北京控制工程研究所 Wire switching insulation processing structure for Hall thruster

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