JPH07310249A - Conjugated yarn for elastic polyester fabric and production of elastic polyester fabric using the same - Google Patents
Conjugated yarn for elastic polyester fabric and production of elastic polyester fabric using the sameInfo
- Publication number
- JPH07310249A JPH07310249A JP6099981A JP9998194A JPH07310249A JP H07310249 A JPH07310249 A JP H07310249A JP 6099981 A JP6099981 A JP 6099981A JP 9998194 A JP9998194 A JP 9998194A JP H07310249 A JPH07310249 A JP H07310249A
- Authority
- JP
- Japan
- Prior art keywords
- yarn
- polyester
- woven
- knitted fabric
- multifilament
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明はポリエステル捲縮糸使い
のポリエステル織編物の伸縮性の付与に係わり、詳しく
は織編物の強い拘束下でも良好な伸縮性を織編物に付与
する事のできる複合糸及び伸縮性ポリエステル織編物の
製造方法に関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to imparting stretchability to a polyester woven or knitted fabric using a polyester crimped yarn, and more specifically to a composite capable of imparting good stretchability to a woven or knitted fabric even under strong restraint of the woven or knitted fabric. The present invention relates to a method for producing a yarn and a stretchable polyester woven / knitted fabric.
【0002】[0002]
【従来の技術】従来からポリエステルマルチフィラメン
ト糸を用いた織編物に伸縮性を付与するには該マルチフ
ィラメントを仮撚加工等の捲縮糸にしてから織編する方
法がとられている。この方法によれば織編物の密度が低
い場合は確かに良好な伸縮性が得られるが、織編物の密
度が高い場合や糸に撚りを付与した場合などは良好な伸
縮性を得る事が難しい。この対策として弾性糸を芯糸に
ポリエステルマルチフィラメント糸を鞘糸にしたカバリ
ング糸を用いる方法もあるが取扱い性が難しい事や価格
が高くなる事から多くは用いられていない。2. Description of the Related Art Conventionally, in order to impart elasticity to a woven or knitted product using a polyester multifilament yarn, a method has been adopted in which the multifilament is formed into crimped yarn such as false twisting and then woven and knitted. According to this method, good stretchability is certainly obtained when the density of the woven or knitted material is low, but it is difficult to obtain good stretchability when the density of the woven or knitted material is high or when the yarn is twisted. . As a countermeasure against this, there is a method of using a covering yarn in which an elastic yarn is used as a core yarn and a polyester multifilament yarn is used as a sheath yarn, but it is not often used because it is difficult to handle and the cost becomes high.
【0003】[0003]
【発明が解決しようとする課題】安価で取扱い性も良い
仮撚加工等の捲縮糸を用いて、織編物の密度が高くても
又糸に撚りが入っていても良好な伸縮性のある織編物を
提供する事が本発明の課題である。[Problems to be Solved by the Invention] By using crimped yarn such as false twisting which is inexpensive and easy to handle, good stretchability can be obtained even if the density of the woven or knitted fabric is high or the yarn is twisted. It is an object of the present invention to provide a woven / knitted fabric.
【0004】[0004]
【課題を解決するための手段】即ち、本発明は、伸縮性
織編物製造に好適な複合糸及びこれを用いた伸縮性織編
物の製造法に関し、ポリエステル系マルチフィラメント
捲縮糸Aと該Aより糸長差が0%から15%短く、かつ
加水分解速度が10倍以上速い易溶解性ポリエステル系
マルチフィラメント糸Bとから成り、撚り係数が40〜
220で、かつ下記式(1)を満足する伸縮性ポリエス
テル織編物用複合糸。 撚り数(回/メートル)=100K/√D …………(1) (Dは複合糸のデニール数)であり、さらにThat is, the present invention relates to a composite yarn suitable for producing a stretchable woven or knitted fabric and a method for producing a stretchable woven or knitted fabric using the same. The yarn length difference is 0% to 15% shorter, and the hydrolysis rate is 10 times or more faster. The easily soluble polyester multifilament yarn B has a twist coefficient of 40 to
A composite yarn for stretchable polyester woven or knitted fabric, which is 220 and satisfies the following formula (1). Number of twists (times / meter) = 100K / √D (1) (D is the denier of the composite yarn)
【0005】本発明の製造方法は、ポリエステル系マル
チフィラメント捲縮糸Aと該Aより糸長差が0%から1
5%短く、かつ加水分解速度が10倍以上速い易溶解性
ポリエステル系マルチフィラメント糸Bとから成る複合
糸条を少なくとも一部に用いた織編物を、易溶解性ポリ
エステル系マルチフィラメント糸Bを加水分解除去した
後、リラックス染色仕上げ加工する事を特徴とする伸縮
性ポリエステル織編物の製造方法である。In the production method of the present invention, the polyester multifilament crimped yarn A and the yarn length difference from the A are 0% to 1
A woven or knitted fabric containing at least a part of a composite yarn composed of a 5% shorter and more easily 10 times faster hydrolyzable polyester-based multifilament yarn B was added to the easily soluble polyester-based multifilament yarn B. A method for producing a stretchable polyester woven or knitted fabric, characterized in that after relaxing and removing, it is subjected to a relaxing dyeing finishing process.
【0006】本発明の複合糸における易溶解性ポリエス
テル系マルチフィラメント糸Bの占める割合が40重量
%以下5重量%以上である事が好ましい。The proportion of the easily soluble polyester multifilament yarn B in the composite yarn of the present invention is preferably 40% by weight or less and 5% by weight or more.
【0007】さらに、本発明において、ポリエステル系
マルチフィラメント捲縮糸Aの捲縮堅牢度率(CD)が
12%以上あることが好ましく、また、易溶解性ポリエ
ステル系マルチフィラメント糸Bの70℃の加水分解速
度がポリエステル系マルチフィラメント捲縮糸Aより1
0倍以上速く、かつ織編物の易溶解性ポリエステル系マ
ルチフィラメント糸Bを加水分解除去する温度が70℃
以下である事が好ましい。さらにまた、ウォータージェ
ット織機を用いて織物を製造した後、染色仕上げ加工等
によるリラックス処理にて易溶解性ポリエステル系マル
チフィラメント糸Bを加水分解除去する事が望ましい。Further, in the present invention, the crimp fastness ratio (CD) of the polyester multifilament crimped yarn A is preferably 12% or more, and the easily soluble polyester multifilament crimped yarn B has a crimp fastness ratio (CD) of 70 ° C. Hydrolysis rate of polyester multifilament crimped yarn A is 1
0 times faster or more, and the temperature at which the easily soluble polyester multifilament yarn B of the woven or knit is hydrolyzed and removed is 70 ° C.
The following is preferable. Furthermore, it is desirable that after the woven fabric is produced using a water jet loom, the easily soluble polyester multifilament yarn B is hydrolyzed and removed by a relaxation treatment such as dyeing finishing.
【0008】以下本発明について更に詳しく述べる。本
発明で示すところのポリエステル系マルチフィラメント
捲縮糸Aはポリエチレンテレフタレート又はポリエチレ
ンテレフタレートを主成分とし、それに第3成分として
イソフタール酸、5−ナトリウムスルホン酸金属塩等を
重合させたポリマーを紡糸し高配向未延伸糸とした後、
延伸仮撚加工し得る方法が一般的であるが特にこれに限
定する物ではない。The present invention will be described in more detail below. The polyester multifilament crimped yarn A shown in the present invention has polyethylene terephthalate or polyethylene terephthalate as a main component, and a polymer obtained by polymerizing isophthalic acid, 5-sodium sulfonic acid metal salt or the like as a third component is spun into After the oriented undrawn yarn,
A method capable of performing draw false twisting is generally used, but the method is not particularly limited to this.
【0009】易溶解性ポリエステル系マルチフィラメン
ト糸Bは、例えばポリエチレングリコール混合ポリエチ
レンテレフタレート繊維の様な容易にアルカリで加水分
解する繊維であって、ポリエステル系マルチフィラメン
ト捲縮糸Aより加水分解速度が10倍以上速い事が必要
である。加水分解速度が10倍未満であると、製織編後
の易溶解性ポリエステル系マルチフィラメント糸Bを溶
解除去する過程でポリエステル系マルチフィラメント捲
縮糸Aも加水分解が進み伸縮性能を低下させる事になり
好ましくない。The easily soluble polyester multifilament yarn B is a fiber which is easily hydrolyzed by an alkali such as polyethylene glycol mixed polyethylene terephthalate fiber, and has a hydrolysis rate of 10 than that of the polyester multifilament crimped yarn A. It is necessary to be twice as fast. When the hydrolysis rate is less than 10 times, the polyester multifilament crimped yarn A is also hydrolyzed in the process of dissolving and removing the easily soluble polyester multifilament yarn B after weaving and knitting, and the stretchability is deteriorated. It is not preferable.
【0010】易溶解性ポリエステル系マルチフィラメン
ト糸Bの糸長差はポリエステル系マルチフィラメント捲
縮糸Aより0%から15%短い事が必要である。こうす
る事によってポリエステル系マルチフィラメント捲縮糸
Aが製織編時に伸ばされる事を防ぎ、易溶解性ポリエス
テル系マルチフィラメント糸Bを溶解除去した後の織編
物で伸縮性を発揮する事が出来る。この糸長差は易溶解
性ポリエステル系マルチフィラメント糸Bと、それより
0%から15%過供給させたポリエステル系マルチフィ
ラメント捲縮糸Aを空気交絡処理等を施して複合糸とし
て得る事が出来る。0%より糸長差が少ないと良好な伸
縮性は得られず、15%より糸長差が大きいと複合糸に
ループやネップの欠点が出て品位が悪くなり好ましくな
い。It is necessary that the yarn length difference of the easily soluble polyester multifilament yarn B is 0% to 15% shorter than that of the polyester multifilament crimped yarn A. By doing so, the polyester-based multifilament crimped yarn A can be prevented from being stretched during weaving and knitting, and the stretchability can be exhibited in the woven or knitted product after the easily soluble polyester-based multifilament yarn B is dissolved and removed. This yarn length difference can be obtained as a composite yarn by subjecting the easily soluble polyester-based multifilament yarn B and the polyester-based multifilament crimped yarn A, which is over-fed by 0% to 15%, to the air entanglement treatment or the like. . If the difference in yarn length is less than 0%, good stretchability cannot be obtained, and if the difference in yarn length is greater than 15%, the composite yarn has defects such as loops and neps, which is not preferable.
【0011】前記複合糸を少なくとも一部に用いた織編
物はリラックス、染色仕上げ加工に先駆けてカセイソー
ダ等で易容易性ポリエステル系マルチフィラメント糸B
を加水分解除去される。こうする事によって織編物中で
弛緩した状態のポリエステル系マルチフィラメント捲縮
糸Aが従来の方法では見られなかった大きなリラックス
収縮を発現する事が出来る。ポリエステル繊維の捲縮は
通常80℃前後から発現するので、リラックス工程で捲
縮が発現する前に易溶解性ポリエステル系マルチフィラ
メント糸Bを加水分解しておくことが好ましく、そのた
めには易溶解性ポリエステル系マルチフィラメント糸B
の加水分解速度が70℃以下の低温でポリエステル系マ
ルチフィラメント捲縮糸Aより10倍以上速い事がより
好ましい条件になる。A woven or knitted fabric using at least a part of the composite yarn can be easily made with caustic soda or the like prior to relaxing and dyeing and finishing. Polyester multifilament yarn B
Is removed by hydrolysis. By doing so, the polyester-based multifilament crimped yarn A in a relaxed state in the woven or knitted fabric can exhibit a large relaxed shrinkage which has not been found by the conventional method. Since crimps of polyester fibers usually appear around 80 ° C., it is preferable to hydrolyze the easily-dissolvable polyester-based multifilament yarn B before the crimps develop in the relaxation step. Polyester multifilament yarn B
It is a more preferable condition that the hydrolysis rate of the product is 10 times or more faster than that of the polyester-based multifilament crimped yarn A at a low temperature of 70 ° C. or less.
【0012】複合糸における易溶解性ポリエステル系マ
ルチフィラメント糸Bの占める割合は40重量%から5
重量%の範囲が好ましい。40重量%を越えると生地の
価格が高く成りすぎるのと織編物中に大きすぎる空隙が
でき、生地がしっかりしたものでなくなってしまい好ま
しくなく、5重量%以下であるとポリエステル系マルチ
フィラメント捲縮糸Aがリラックス時に自由に伸縮発現
できる空隙が少なすぎる事及び織編物を製造時に糸切れ
等が発生し好ましくない。The ratio of the easily soluble polyester multifilament yarn B in the composite yarn is 40% by weight to 5%.
A weight% range is preferred. If it exceeds 40% by weight, the price of the fabric becomes too high, and too large voids are formed in the woven or knitted fabric, so that the fabric is not solid, which is not preferable, and if it is 5% by weight or less, the polyester multifilament crimp There are too few voids in which the yarn A can freely expand and contract when relaxing, and yarn breakage or the like occurs during the production of the woven or knitted fabric, which is not preferable.
【0013】複合糸の下記式で示される撚り係数K40
から220の範囲にあるとき本発明はより大きな効果を
発揮できる。 撚り数(回/メートル)=100K/√D ただしDは複合糸のデニール数 通常の仮撚加工糸等の捲縮糸は撚りを施すに従って伸縮
性は低下する事が知られているが、本発明の複合糸を用
いた伸縮性ポリエステル織編物の製造方法においてはそ
の度合いは著しく改善される。撚り係数Kが40未満で
あると撚りの効果は少なく220以上であると伸縮性は
発現しない。The twist coefficient K40 of the composite yarn represented by the following formula
The present invention can exert a greater effect when it is in the range of 220 to 220. Number of twists (turns / meter) = 100K / √D where D is the number of denier of the composite yarn It is known that the crimped yarn such as the usual false twisted yarn has a reduced elasticity as it is twisted. In the method for producing a stretchable polyester woven / knitted fabric using the composite yarn of the invention, the degree is remarkably improved. When the twist coefficient K is less than 40, the twisting effect is small, and when it is 220 or more, the elasticity does not appear.
【0014】以上述べたように、本発明によれば従来に
はない伸縮性に優れたポリエステル織編物を製造する事
が出来る。更に本発明の易溶解性ポリエステル系マルチ
フィラメント糸Bはウォータージェット織機で製織する
ことができ高い生産性も本発明の特徴である。As described above, according to the present invention, it is possible to produce a polyester woven or knitted fabric having excellent elasticity, which has not been obtained in the past. Further, the easily-dissolvable polyester-based multifilament yarn B of the present invention can be woven by a water jet loom and is also a feature of the present invention.
【0015】以下、本発明を実施例により説明するが、
本発明は何らこれに限定されるものではない。The present invention will be described below with reference to examples.
The present invention is not limited to this.
【実施例】ポリエチレンテレフタレートを速度3200
m/分で紡糸した後、延伸仮撚を施して125デニール
24フィラメントの仮撚加工糸(ポリエステル系マルチ
フィラメント捲縮糸A)を得た。この糸の捲縮堅牢度
(CD)は16%であった。 捲縮堅牢度(CD)の測定方法:1周の長さが1mのラ
ップリールを用いて8回巻きのカセを作り、糸のデニー
ル×(5/1000)×8×2gの荷重を掛けた状態で
ラピゾール液を2g/1り濃度に溶解した98℃の熱水
中に5分間浸漬する。次に試料を取り出し湿潤状態のま
ま、糸のデニール×0.2×8×2gの荷重を掛け1分
後の長さaを測定する。その後60℃で30分間熱風乾
燥した後、1時間以上放置し、糸のデニール×(2/1
000)×8×2gの荷重を掛け、1分後の長さbを測
定する。こうして得られたa、bのデータを下記式に代
入して捲縮堅牢度(CD)を求める。 捲縮堅牢度=100(a−b)/aExample: Polyethylene terephthalate was fed at a speed of 3200.
After spinning at m / min, false false twist was applied to obtain a false twist textured yarn of 125 denier 24 filaments (polyester multifilament crimped yarn A). The crimp fastness (CD) of this yarn was 16%. Method of measuring crimp fastness (CD): A wrap reel having a length of 1 m per lap was used to make a cassette with 8 windings, and a load of denier of yarn × (5/1000) × 8 × 2 g was applied. In this state, the rapizole solution is immersed for 5 minutes in hot water at 98 ° C. in which the concentration is 2 g / 1. Then, the sample is taken out and a load of denier of the yarn × 0.2 × 8 × 2 g is applied in the wet state to measure the length a after 1 minute. After that, it was dried with hot air at 60 ° C. for 30 minutes and then left for 1 hour or more, and the denier of the yarn × (2/1
000) × 8 × 2 g is applied and the length b after 1 minute is measured. The crimp fastness (CD) is obtained by substituting the data of a and b thus obtained in the following formula. Crimping fastness = 100 (ab) / a
【0016】イソフタール酸10モル%共重合ポリエチ
レンテレフタレートと分子量20000のポリエチレン
グリコールを混合したポリマーを速度3200m/分で
紡糸した後、延伸を施して10デニール6フィラメント
の易溶解性ポリエステル系マルチフィラメント糸Bを得
た。該糸の70℃の加水分解速度は前記ポリエステル系
マルチフィラメント捲縮糸Aの32倍であった。加水分
解速度はカセイソーダ50g/1の溶液中で繊維が半分
の重量に成るまでの時間逆数で示したものである。A polymer prepared by mixing 10 mol% of isophthalic acid copolymerized polyethylene terephthalate and polyethylene glycol having a molecular weight of 20,000 was spun at a speed of 3200 m / min, and then stretched to give 10 denier 6 filaments, a highly soluble polyester multifilament yarn B. Got The hydrolysis rate of the yarn at 70 ° C. was 32 times that of the polyester multifilament crimped yarn A. The hydrolysis rate is expressed as the reciprocal of the time until the weight of the fiber becomes half in the solution of caustic soda 50 g / 1.
【0017】易溶解性ポリエステル系マルチフィラメン
ト糸Bとポリエステル系マルチフィラメント捲縮糸Aを
1ないし複数本組み合わせて、送り量を任意に採れる空
気交絡加工機を用いていくつかの水準の複合糸を作っ
た。該複合糸を経糸が50デニール36フィラメントの
ポリエステルマルチフィラメント、密度が45本/セン
チの織物の緯糸に打ち込んで後、加水分解処理、リラッ
クス処理、染色仕上げ加工を順次実施し、試料の伸縮性
について評価を行った。その結果を表1に示す。By combining one or a plurality of easily soluble polyester multifilament yarns B and polyester multifilament crimped yarns A, an air entanglement machine capable of arbitrarily adjusting the feed amount is used to produce several levels of composite yarns. Had made. Stretchability of the sample was obtained by driving the composite yarn into a polyester multifilament having a warp yarn of 36 filaments and a weft yarn of a fabric having a density of 45 filaments / cm, and then sequentially performing hydrolysis treatment, relaxation treatment, and dyeing finishing treatment. An evaluation was made. The results are shown in Table 1.
【0018】[0018]
【表1】 [Table 1]
【0019】[0019]
【発明の効果】以上のように本発明によれば、従来のポ
リエステルマルチフィラメント捲縮糸では十分に得る事
のできなかった織編物の伸縮性が大幅に改善できる。特
に捲縮糸を撚糸して用いる場合、その効果は特に大き
い。INDUSTRIAL APPLICABILITY As described above, according to the present invention, the stretchability of a woven or knitted material, which cannot be sufficiently obtained by the conventional polyester multifilament crimped yarn, can be greatly improved. In particular, when the crimped yarn is twisted and used, the effect is particularly large.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 D06C 19/00 D06M 11/38 // D01F 6/62 303 K 6/84 305 C D06M 101:32 ─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. 6 Identification code Internal reference number FI Technical display location D06C 19/00 D06M 11/38 // D01F 6/62 303 K 6/84 305 C D06M 101: 32
Claims (2)
糸Aと該Aより糸長差が0%から15%短く、かつ加水
分解速度が10倍以上速い易溶解性ポリエステル系マル
チフィラメント糸Bとから成り、撚り係数が40〜22
0で、かつ下記式(1)を満足する伸縮性ポリエステル
織編物用複合糸。 撚り数(回/メートル)=100K/√D …………(1) (Dは複合糸のデニール数)1. A twist comprising a polyester-based multifilament crimped yarn A and a readily soluble polyester-based multifilament yarn B having a yarn length difference of 0% to 15% shorter than that of A and a hydrolysis rate 10 times or more faster. Coefficient is 40-22
A composite yarn for stretchable polyester woven or knitted fabric, which is 0 and satisfies the following formula (1). Number of twists (times / meter) = 100K / √D (1) (D is the number of denier of the composite yarn)
糸Aと該Aより糸長差が0%から15%短く、かつ加水
分解速度が10倍以上速い易溶解性ポリエステル系マル
チフィラメント糸Bとから成る複合糸を少なくとも一部
に用いた織編物を、易溶解性ポリエステル系マルチフィ
ラメント糸Bを加水分解除去した後、リラックス処理す
る事を特徴とする伸縮性ポリエステル織編物の製造方
法。2. A composite yarn comprising a polyester-based multifilament crimped yarn A and a readily soluble polyester-based multifilament yarn B having a yarn length difference of 0% to 15% shorter than the A and having a hydrolysis rate 10 times or more faster. A method for producing a stretchable polyester woven / knitted fabric, which comprises subjecting a woven / knitted fabric containing at least part of the above to a relaxing treatment after hydrolyzing and removing the easily soluble polyester multifilament yarn B.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6099981A JPH07310249A (en) | 1994-05-13 | 1994-05-13 | Conjugated yarn for elastic polyester fabric and production of elastic polyester fabric using the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6099981A JPH07310249A (en) | 1994-05-13 | 1994-05-13 | Conjugated yarn for elastic polyester fabric and production of elastic polyester fabric using the same |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH07310249A true JPH07310249A (en) | 1995-11-28 |
Family
ID=14261849
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6099981A Pending JPH07310249A (en) | 1994-05-13 | 1994-05-13 | Conjugated yarn for elastic polyester fabric and production of elastic polyester fabric using the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH07310249A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998005271A3 (en) * | 1996-08-02 | 1998-02-12 | Sulzer Vascutek Ltd | Expansible woven fabric |
-
1994
- 1994-05-13 JP JP6099981A patent/JPH07310249A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998005271A3 (en) * | 1996-08-02 | 1998-02-12 | Sulzer Vascutek Ltd | Expansible woven fabric |
WO1998005271A2 (en) * | 1996-08-02 | 1998-02-12 | Sulzer Vascutek Ltd. | Expansible woven fabric |
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