JPH07247489A - Cold calendering lubricant - Google Patents

Abstract

PURPOSE:To obtain the subject lubricant causing no scorching even under calendering in high speed at high pressure, good in surface gloss, excellent in productivity, thus suitable for calendering lubrication of e.g. stainless steel, containing, as the base oil, a specified amount of a specific mixed synthetic ester. CONSTITUTION:This cold calendering lubricant contains, as the base oil, 50-90wt.% of a mixed synthetic ester having a viscosity at 40 deg.C of 8.5-20mPa.S, which is the mixture of (A) dimer acid isobutyl glycol diester and/or dimer acid butyl glycol diester of formula I (D is a dimer acid residue of formula II; C4H9 denotes isobutyl or n-butyl) and (B) butoxyethyl and/or isobutoxyethyl stearate palminate of formula III (R is stearic acid residue; R' is palmitic acid residue). Other ingredient(s) for this lubricant is pref. at least one kind selected from higher alcohols, surfactants, high-pressure additives, rustproofing agents, antioxidants and organic amines.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a cold rolling lubricant used for rolling lubrication of ordinary steel, stainless steel, titanium, aluminum, copper and other metal sheets.

[0002]

2. Description of the Related Art In cold rolling, a lubricant is supplied to the surfaces of a plate and a work roll in order to reduce the rolling load and prevent surface defects of the plate. As a lubricant supply method, an emulsion supply method is widely used in terms of workability, concentration control, effect and the like. In the emulsion supply system, a lubricant is mixed with water, and the emulsified lubricant is sprayed on the surfaces of the plate and the roll by a nozzle. As the lubricant, mineral oil, animal or vegetable oil, or synthetic ester is used.

Particularly, a material having a large deformation resistance, for example, a stainless steel plate is rolled by a multi-stage cluster mill such as 12 or 20 steps. In this case, mineral oil type as a lubricant or 100% neat oil based on synthetic ester as a base oil,
A mineral oil emulsion type rolling oil is used. (Kajima et al .: 38th Plastic Karen Lecture, (1987), 11
7. reference)

[0004]

When rolling at high speed,
Large friction heat is generated between the work roll and the rolled material. When frictional heat is accumulated in the work rolls and the roll surface becomes high in temperature, seizure easily occurs between the work rolls and the rolled material. In particular, when a rolled material having a large deformation resistance is subjected to high speed rolling using a conventional lubricant, seizure occurs and rolling is difficult. For example, rolling speed is 500 ~ 1200 m / min
When cold rolling a stainless steel sheet at a high speed, the rolling oil of neat oil had a small roll cooling ability, so that seizure occurred and stable rolling was difficult. Further, with a mineral oil-based emulsion type rolling oil, although the roll cooling ability is large, seizure resistance is poor, so that it was difficult to carry out cold rolling at such a high speed as described above.

The present invention is intended to provide a cold rolling lubricant capable of rolling under high speed and high pressure even if the material has a high deformation resistance.

[0006]

The cold rolling lubricant of the present invention comprises isobutyl glycol diester dimer and / or butyl glycol dimer diester, butoxyethyl barmitate stearate and / or isobutoxyethyl barmitate stearate. 50% or more of a mixed synthetic ester having a viscosity of 8.5 mPa · s or more and 20 mPa · s or less at 40 ° C. as a base oil,
Contains 90% or less.

The chemical structural formulas of dimer acid isobutyl glycol diester and / or dimer acid butyl glycol diester (hereinafter referred to as A ester) are as follows.

[0008]

[Chemical 3]

Further, the chemical structural formulas of butoxyethyl barmitate stearate and / or isobutoxyethyl barmitate stearate (hereinafter referred to as B ester) are as follows.

[0010]

[Chemical 4]

A suitable mixing ratio of the A ester to the B ester is 50 to 1%. Generally, this mixing ratio is determined from the viscosity of the rolling lubricating oil prepared by mixing the synthetic synthetic ester with other additives. If the viscosity of the mixed synthetic ester at 40 ° C. is less than 8.5 mPa · s, sufficient seizure resistance cannot be secured. Further, if the viscosity at 40 ° C. exceeds 20 mPa · s, sufficient gloss cannot be secured. However, the unit viscosity at 40 ° C is
Mineral oil is 5.2 mPa · s, A ester is 65.0 mPa · s
, B ester is 8.3 mPa · s.

Further, the viscosity at 40 ° C. is 8.5 mPa · s or more,
If the concentration of the mixed synthetic ester of 20 mPa · s or less is less than 50%, sufficient seizure resistance cannot be secured. When it exceeds 90%, when a higher alcohol, a surfactant, and other additives are added, the addition amount is insufficient, it becomes difficult to secure the emulsion particle size, and a clean lubricant cannot be obtained.

In the above cold rolling lubricant, mineral oil, animal and vegetable oil, other synthetic esters, additives and the like are appropriately used as components other than the mixed synthetic ester. As an additive
Higher alcohols (eg lauryl alcohol), surfactants (eg fatty acid amine soaps), extreme pressure additives (eg alkyl phosphates), rust inhibitors (eg fatty acid amines), antioxidants (eg ditertiary butyl). At least one of para-cresol) and an organic amine (for example, naphthylamine) may be contained. In this case, the viscosity at 40 ° C is 8.5 mPa
s or more and 20 mPa · s or less. Higher alcohols and organic amines prevent stains on the rolled plate. Extreme pressure additives improve seizure resistance. The rust preventive prevents rust on the rolling plate and the piping of the lubricant system. Further, the antioxidant prevents oxidation of the lubricant, and the surfactant controls the emulsified state of the lubricant.

The cold rolling lubricant is used as an emulsion having a concentration of 1 to 30%. It is desirable that the average value of the emulsion particle size distribution be 3 μm or more and 15 μm or less. If the average particle size of the emulsion is less than 3 μm, it becomes difficult to produce it as a lubricant, and if the average particle size exceeds 15 μm, sufficient gloss cannot be secured.

[0015]

EXAMPLE An example of cold rolling a stainless steel sheet will be described. The rolling and lubricating conditions are as follows.

4Hi rolling mill Backup roll: 4
00φ × 100mm Work roll: 70φ × 100mm Rolling material SUS430, Plate thickness × Plate width 1.0mm ^t
× 50 mm ^w Rolling rate 20% Rolling speed 0 to 1200 m / min Tension Tension on the inlet side: 10 kgf / mm ² , Tension on the outlet side:
15 kgf / mm ² Lubricant Ingredients Table 1 However, mixed synthetic ester: isobutyl glycol diester dimer (15%) + butoxyethyl barmitate stearate (85%) Concentration 10% Emulsion Temperature 50 ° C

[Table 1]

As a result of rolling under the above conditions, seizure occurred at a rolling speed of 600 m / min in the conventional mineral oil type lubricant. In contrast, the A / B mixed synthetic ester lubricant according to the present invention did not cause seizure even at a rolling speed of 1200 m / min, and the rolled sheet showed good gloss.

FIG. 1 shows an example of the results obtained by measuring the seizure resistance of mineral oil, A ester, and B ester alone by the slip cold rolling test method.

FIG. 2 shows the results of the seizure resistance of the lubricants shown in Table 1 measured by the above experimental method. From this figure,
It can be seen that the seizure resistance of the lubricant of the present invention is remarkably higher than that of the conventional one.

FIG. 3 shows an example of the measurement results of the glossiness of rolled stainless steel. The glossiness of the lubricant of the present invention is slightly inferior to that of the conventional one, but the difference between the two cannot be visually recognized.

Incidentally, a mixed synthetic ester of dimer acid isobutyl glycol diester and stearic acid isobutoxyethyl stearate, a mixed synthetic ester of dimer acid butyl glycol diester and stearic butoxyethyl barmitate ester, and a dimer acid butyl glycol diester and stearin. When the mixed synthetic ester with isobutoxyethyl barmitate was used, the effects were exactly the same as those described above.

[0022]

The cold rolling lubricant according to the present invention does not cause seizure even when a material having high deformation resistance is rolled at high speed and high pressure. For example, when SUS430 stainless steel is rolled at a reduction rate of 20%, the maximum rolling speed of the conventional lubricant that was 500 m / min can be increased to 1200 m / min. Therefore, the productivity of cold rolling can be improved. Further, even when rolled at high speed and high pressure, the surface luster of the rolled plate is good, so that a high quality product can be provided.

[Brief description of drawings]

FIG. 1 is a bar graph showing the results of a seizure resistance test for mineral oil, A ester, and B ester alone.

FIG. 2 is a bar graph showing the results of the seizure resistance test method performed on the lubricants shown in Table 1.

FIG. 3 is a bar graph showing the measurement results of glossiness of stainless steel rolled using the lubricant shown in Table 1.

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[Procedure amendment]

[Submission date] April 21, 1994

[Procedure Amendment 1]

[Document name to be amended] Statement

[Name of item to be corrected] Claim 1

[Correction method] Change

[Correction content]

[Chemical 1]

[Chemical 2]

[Procedure Amendment 2]

[Document name to be amended] Statement

[Correction target item name] 0006

[Correction method] Change

[Correction content]

[0006]

The cold rolling lubricant of the present invention comprises isobutyl glycol diester dimer and / or butyl glycol dimer dimer and butoxyethyl palmitate stearate and / or isobutoxyethyl palmitate stearate. 50% or more of a mixed synthetic ester having a viscosity of 8.5 mPa · s or more and 20 mPa · s or less at 40 ° C. as a base oil,
Contains 90% or less.

[Procedure 3]

[Document name to be amended] Statement

[Correction target item name] 0009

[Correction method] Change

[Correction content]

Further, butoxyethyl palmitic stearic acid and / or palmitic acid iso butoxy ethyl stearate (hereinafter, B referred ester) chemical structural formula of is as follows.

[Procedure amendment 4]

[Document name to be amended] Statement

[Correction target item name] 0016

[Correction method] Change

[Correction content]

4Hi rolling mill Backup roll: 4
00φ × 100mm Work roll: 70φ × 100mm Rolling material SUS430, Plate thickness × Plate width 1.0mm ^t
× 50 mm ^w Rolling rate 20% Rolling speed 0 to 1200 m / min Tension Tension on the inlet side: 10 kgf / mm ² , Tension on the outlet side:
15 kgf / mm ² lubricant component Table 1 except mixing synthetic esters: dimer acid isobutyl glycol diester (15%) + Palmitic Stearic acid
Acid butoxyethyl (85%) 10% concentration emulsion temperature 50 ° C.

[Table 1]

[Procedure Amendment 5]

[Document name to be amended] Statement

[Correction target item name] 0021

[Correction method] Change

[Correction content]

It should be noted that a mixed synthetic ester of dimer acid isobutyl glycol diester and stearic acid isobutoxyethyl palmitate , a mixed synthetic ester of dimer acid butyl glycol diester and stearic acid palmitate palmitate , and a dimer acid butyl glycol diester and stearin. In the case of using the mixed synthetic ester with acid isobutoxyethyl palmitate, the effects were exactly the same as those described above.

─────────────────────────────────────────────────── ─── Continuation of the front page (51) Int.Cl. ⁶ Identification number Office reference number FI technical display location C10N 20:06 Z 30:06 30:20 40:24 (72) Inventor Toru Kajima Chiyoda-ku, Tokyo 2-6-3 Otemachi Nippon Steel Co., Ltd. (72) Inventor Yuzo Higaki 1-3 Chiba-cho, Kanagawa-ku, Yokohama, Kanagawa Nissei Fine Chemical Co., Ltd. (72) Yoshiaki Iwamoto, Yokohama-shi, Kanagawa 1-3 Chiwaka-cho, Kanagawa-ku Nissei Fine Chemical Co., Ltd.

Claims (3)

[Claims] 1. A dimer acid isobutyl glycol diester represented by the formula (1) and / or a dimer acid butyl glycol diester represented by the formula (2) and a butoxyethyl stearate valmitate and / or an isobaric acid stearate isoform represented by the formula (2). Mix with butoxyethyl,
A mixed synthetic ester whose viscosity at 40 ° C is 8.5 mPa · s or more and 20 mPa · s or less is 50% or more as a base oil, and 90
% Cold-rolling lubricant. [Chemical 1] [Chemical 2] 2. A component other than the mixed synthetic ester, which contains at least one of a higher alcohol, a surfactant, an extreme pressure additive, a rust inhibitor, an antioxidant, and an organic amine, and has a viscosity of 40 ° C. The cold rolling lubricant according to claim 1, which has a viscosity of 8.5 mPa · s or more and 20 mPa · s or less. 3. The average value of the emulsion particle size distribution is 3 μm.
The cold rolling lubricant according to claim 1 or 2, which has a diameter of 15 μm or less.