JPH07196355A - Inorganic finishing material composition and method for construction using the same - Google Patents

Inorganic finishing material composition and method for construction using the same

Info

Publication number
JPH07196355A
JPH07196355A JP34898593A JP34898593A JPH07196355A JP H07196355 A JPH07196355 A JP H07196355A JP 34898593 A JP34898593 A JP 34898593A JP 34898593 A JP34898593 A JP 34898593A JP H07196355 A JPH07196355 A JP H07196355A
Authority
JP
Japan
Prior art keywords
material composition
water
composition
undercoat
topcoat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP34898593A
Other languages
Japanese (ja)
Other versions
JP3569306B2 (en
Inventor
Susumu Harada
原田  進
Takashi Tsuneyama
隆 常山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujikawa Kenzai Kogyo Ltd
Original Assignee
Fujikawa Kenzai Kogyo Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujikawa Kenzai Kogyo Ltd filed Critical Fujikawa Kenzai Kogyo Ltd
Priority to JP34898593A priority Critical patent/JP3569306B2/en
Publication of JPH07196355A publication Critical patent/JPH07196355A/en
Application granted granted Critical
Publication of JP3569306B2 publication Critical patent/JP3569306B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PURPOSE:To propose a composition, usable for interior and exterior finishings, rich in durability, fire protecting and respiratory properties and excellent in executability and a method for construction by which various textures can be formed. CONSTITUTION:This undercoating material composition contains silica fume, an alcohol, ethylene glycol, a water-soluble viscosity increasing agent, bentonite, etc., in slaked lime and is prepared by kneading the components with water by using a dispersing agent such as a polycarboxylic acid-based or a naphthalenesulfonic acid-based dispersing agent. A topcoating material composition contains the silica fume, ethylene glycol, water-soluble viscosity increasing agent, calcium carbonate, etc., in the slaked lime and is obtained by kneading the components with water by using a dispersing agent such as the polycarboxylic acid-based or the naphthalenesulfonic acid-based dispersing agent.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、内外装仕上げに用いる
ことができ、耐久性、防火性、呼吸性に富み、且つ施工
性に優れた無機質仕上げ材組成物及びそれを用いた工法
に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an inorganic finishing material composition which can be used for interior and exterior finishing, is excellent in durability, fire resistance, breathability, and is excellent in workability, and a method of using the same.

【0002】[0002]

【従来の技術】従来より無機質素材は、その素材の持っ
ている素朴さ、重厚感、高い耐久性から、古き時代から
広く用いられている。このような無機質素材の一つに
「漆喰」があるが、漆喰は主として消石灰、フノリ、角
又、スサ等を原料として、現場で調合して、大変な労力
をかけて水で練って使用されるものであり、寺院、仏閣
等の日本建築物の外装、内装材として使用されている。
2. Description of the Related Art Conventionally, inorganic materials have been widely used since ancient times because of their simpleness, solid feeling and high durability. There is "plaster" as one of such inorganic materials, but plaster is mainly used as a raw material of slaked lime, funori, kakumata, bamboo grass, etc., and is mixed with water with great effort to use. It is used as the exterior and interior materials of Japanese buildings such as temples and temples.

【0003】上記漆喰の組成物は、下塗り材として、消
石灰に、スサ、増粘剤、水等を混合し、さらに砂を混合
して砂漆喰とされ、下地作り、下地調整に使用されてい
た。また、上塗り材として、消石灰に、スサ、増粘剤、
水等を混合し、必要に応じて顔料等の着色剤を混合して
使用されていた。そして、最近では消石灰に増粘剤等を
加え、粉体のみを調合した混合物も販売されているので
はあるが、上記混合物に、建築現場で水を加えて作業し
易い状態まで練り上げるには大変な労力を要するもので
あった。即ち、粉塵が発生したり、粘度が高いためママ
コができ易いという問題があった。そこで、水を加えて
混練りした組成物がポリ袋等に入れられて販売されるよ
うにもなった。さらに、漆喰の耐水性、防水性、耐久性
を向上することを目的として、或いは仕上げ外観の向上
を目的として、以下に示すような種々の検討も行われて
きた。
The above-mentioned plaster composition was used as an undercoat material by mixing slaked lime with susa, a thickener, water and the like, and further mixing sand to form a sand plaster, which was used for preparing a groundwork and preparing a groundwork. . In addition, as a top coat material, slaked lime, Susa, thickener,
It has been used by mixing water or the like and, if necessary, a colorant such as a pigment. Recently, a mixture of slaked lime with a thickener added and only a powder is sold, but it is difficult to add water to the above mixture at the construction site to knead it into a workable state. It took a lot of effort. That is, there is a problem that dust is generated and the mother's daughter is easily formed because of high viscosity. Therefore, a composition obtained by adding water and kneading is put in a plastic bag or the like for sale. Furthermore, various studies as described below have been conducted for the purpose of improving the water resistance, waterproofness, and durability of plaster, or for the purpose of improving the finish appearance.

【0004】特開昭54−13537号公報には、漆
喰の主原料中に穀の粉末を混入し、耐水性、防水性、固
着性、固形性、強靭堅牢性、耐腐食性、耐熱性を向上さ
せた漆喰組成物が記載されている。 特開昭54−43930号公報には、植物油を漆喰中
に混入することにより、耐水性、防水性、耐腐食性を付
与した漆喰組成物が記載されている。 特開昭54−105132号公報にはアルコールを漆
喰原料中に混入せしめることにより、耐腐食性を向上さ
せた漆喰組成物が記載されている。 特開昭54−85226号公報には消石灰、漂白木材
パルプ解砕物、水溶性セルロース誘導体を主成分とする
漆喰組成物を吹付け塗布し、組成物が流動性を保ってい
る間に空気を吹付けて表面模様を形成させる塗装法が記
載されている。 特開昭55−90451号公報には消石灰、繊維状添
加材、及び水溶性増粘剤としてのセルロース誘導体を主
成分としてなり、パターン溝を有する仕上げローラ等を
用いて表面模様を形成される塗装法が記載されている。 特開昭60−16855号公報には消石灰、骨材、無
機質繊維、合成糊剤、水からなる混練り物に、合成ゴム
エマルジョンを含有させ、クラックの発生を防止するよ
うにした漆喰組成物が記載されている。 特開昭61−195171号公報には荒壁土、中塗り
土等の特定原料群から選択して調合した下塗り用泥、中
塗り用泥または漆喰塗り材に水を加え、捏練りしたもの
を密閉容器に封入して、こまい壁塗り用等の品質の一定
な塗材を得る製造方法が記載されている。
In Japanese Patent Laid-Open No. 54-13537, grain powder is mixed in the main raw material of plaster to improve water resistance, waterproofness, stickiness, solidity, toughness, corrosion resistance and heat resistance. An improved stucco composition is described. JP-A-54-43930 describes a plaster composition in which vegetable oil is mixed into plaster to impart water resistance, waterproofness, and corrosion resistance. JP-A-54-105132 describes a plaster composition having improved corrosion resistance by mixing alcohol into a plaster raw material. In JP-A-54-85226, slaked lime, bleached wood pulp crushed product, and a plaster composition containing a water-soluble cellulose derivative as a main component are spray-coated, and air is blown while the composition maintains fluidity. A coating method for applying a surface pattern is described. Japanese Patent Application Laid-Open No. 55-90451 discloses a coating which contains slaked lime, a fibrous additive, and a cellulose derivative as a water-soluble thickener as main components, and a surface pattern is formed by using a finishing roller having a pattern groove. The law is described. JP-A-60-16855 describes a plaster composition in which a synthetic rubber emulsion is contained in a kneaded product composed of slaked lime, aggregate, inorganic fiber, synthetic sizing agent, and water to prevent the occurrence of cracks. Has been done. Japanese Patent Laid-Open No. 61-195171 discloses an undercoat mud prepared by selecting from a specific raw material group such as rough wall soil and intermediate coating soil, an intermediate coating mud or a plaster coating material, kneaded and kneaded. It describes a manufacturing method in which a coating material having a constant quality, such as for coating a fine wall, is obtained by enclosing it in a container.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、前記何
れの組成物もこて塗りにより塗工されるのであるが、こ
の仕上げ塗りには左官の熟練した技術が要求されるもの
であった。即ち、白壁をムラなく均一な壁面にすること
は難しく、さらに着色した色漆喰をムラなく仕上げるこ
とはそれ以上難しいものであった。しかも、左官技能者
の老齢化や若年技能者の減少が深刻な問題となっている
今日、“漆喰仕上げ”は減少の一途をたどっていた。
However, although any of the above compositions is applied by trowel coating, this finishing coating requires the skill of a plasterer. That is, it was difficult to make the white wall even and uniform, and it was even more difficult to finish the colored plaster evenly. Moreover, with the aging of plasterers and the decline of young technicians becoming a serious problem, "stucco finishing" was steadily decreasing.

【0006】また、漆喰は施工後長時間かけて、空気中
の炭酸ガスを吸収して硬化し、耐久性が向上するもので
あるが、その過程でクラックが発生し易いため、施工後
も壁面として美観を保ち、耐久性の高い仕上げ材が要求
されていた。
[0006] In addition, plaster absorbs carbon dioxide in the air and hardens over a long period of time after construction to improve durability, but cracks easily occur in the process, so that wall surface remains even after construction. As a result, there was a demand for a finishing material that is aesthetically pleasing and highly durable.

【0007】さらに、建築様式の変化でテクスチャーが
平滑面だけでは顧客の要求に対応できないため、施工し
易いことは勿論、様々なテクスチャーに対応できる仕上
げ材が要求されていた。また、素朴さ、味のある壁面が
要求され、併せて呼吸機能、透湿機能、耐久性等も要求
され、新しい仕上げ材が望まれてきた。尚、塗料等の有
機質素材をベースにした仕上げ材は既に開発され、施工
し易いことから広く用いられてきたが、無機質素材が有
する重厚感、高級感、耐久性を発現できるものではなか
った。したがって、有機質素材の施工性の良さ、仕上げ
の均一さを備え、様々なテクスチャーが表現でき、しか
も無機質素材の持つ、高級感、重厚感、耐久性を併せ持
ち、多彩仕上げが可能となるような無機質仕上げ材組成
物及び工法が希求されていた。
[0007] Furthermore, since the texture cannot meet the customer's request only with a smooth surface due to a change in the architectural style, there is a demand for a finishing material which is not only easy to construct, but also compatible with various textures. Further, a simple and tasteful wall surface is required, and a breathing function, a moisture permeability function, durability, etc. are also required, and a new finishing material has been desired. Incidentally, finishing materials based on organic materials such as paints have already been developed and have been widely used because they are easy to apply, but they have not been able to express the solid feeling, high-class feeling and durability of inorganic materials. Therefore, the workability of the organic material is good, the finish is uniform, and various textures can be expressed. In addition, the inorganic material has the high-class feeling, the solid feeling, and the durability, and the inorganic material enables a variety of finishes. A finishing material composition and a construction method have been desired.

【0008】[0008]

【課題を解決するための手段】本発明は、上記に鑑み提
案されたもので、上塗り材組成物と下塗り材組成物とか
らなって、下塗り材組成物は、消石灰に、シリカヒュー
ム、アルコール、エチレングリコール、水溶性増粘剤、
ベントナイト等を含有し、必要に応じてパルプ質、アク
リル、ポリエステル、ビニロン繊維等の化学繊維、或い
は麻等の天然繊維を含有し、ポリカルボン酸系、ナフタ
リンスルホン酸系等の分散剤を用いて水と混練したもの
であることを特徴とする無機質仕上げ材組成物に関する
ものである。
The present invention has been proposed in view of the above, and comprises an overcoat material composition and an undercoat material composition, wherein the undercoat material composition is slaked lime, silica fume, alcohol, Ethylene glycol, water-soluble thickener,
Contains bentonite, etc., if necessary, pulp fiber, acrylic, polyester, chemical fiber such as vinylon fiber, or natural fiber such as hemp, and uses a dispersant such as polycarboxylic acid type or naphthalene sulfonic acid type. The present invention relates to an inorganic finishing material composition characterized by being kneaded with water.

【0009】上記下塗り材組成物中の消石灰は、重油
焼、塩焼どちらも使用できるが、塩焼の方が作業性が良
好である。
The slaked lime in the above-mentioned undercoat material composition may be either heavy oil-fired or salt-baked, but salt-baked has better workability.

【0010】また、シリカヒューム、アルコール、エチ
レングリコールは、ムラ乾きをできるだけなくし、仕上
げ後の色調を均一にするためのものである。即ち、上記
成分を含まない従来の漆喰組成物は、粘度が高く、保水
性が高いために乾燥が非常に遅く、色ムラが発生し易
く、強度の発現も遅かった。上記シリカヒュームは、下
塗り材組成物中に溶解しているCaイオンと反応して下
塗り材組成物の仕上げ表面に遊離析出するのを防止する
ので、色ムラを防止することができる。また、混練り物
に流動性の向上を付与し、作業性を向上させる。また、
一般に揮発性が高いアルコールは、下塗り材組成物中に
存在する水を抱き込んで蒸発するので樹脂系仕上げ材と
同様な乾燥性を示し、強度の発現を速める。さらに、一
般に揮発性が低いエチレングリコールは、下塗り材組成
物の表面のみの乾燥を防止し、組成物の内部を含めた全
体から均等に乾燥させるようにするものであり、凸部の
形成(造形)、こて押さえなどを容易にする。
Silica fume, alcohol, and ethylene glycol are for eliminating uneven drying as much as possible and making the color tone after finishing uniform. That is, the conventional stucco composition not containing the above-mentioned components had a high viscosity and a high water retention property, so that the drying was very slow, color unevenness was likely to occur, and the strength was also delayed. The silica fume prevents the Ca ions dissolved in the undercoating material composition from being liberated and deposited on the finished surface of the undercoating material composition, and thus can prevent color unevenness. Further, it improves the fluidity of the kneaded product and improves the workability. Also,
Generally, a highly volatile alcohol evaporates by embracing water present in the undercoat material composition, and thus exhibits the same drying property as that of the resin-based finishing material and accelerates the development of strength. In addition, ethylene glycol, which is generally low in volatility, prevents drying of only the surface of the undercoating material composition and makes it possible to uniformly dry the entire surface including the inside of the composition. ), Make it easier to press the iron.

【0011】さらに、ベントナイトは、こて塗りの際の
こて伸び、こて切れを向上させ、凸部を形成(造形)し
た後のたれを防止する。特に、白色として仕上げるため
には白色度80%以上のものを用いることが好ましい。
Further, bentonite improves trowel elongation and trowel breakage during trowel application, and prevents sagging after forming (modeling) convex portions. In particular, it is preferable to use one having a whiteness of 80% or more in order to finish it as white.

【0012】必要に応じて添加するパルプ質、アクリ
ル、ポリエステル、ビニロン繊維等の化学繊維、或いは
麻等の天然繊維は、クラックの発生を防止し、こて塗り
の際のこて伸びを向上させる。上記パルプ質としてはパ
ルププロック、或いは古紙の粉砕品を用いることができ
る。
Chemical fibers such as pulp, acrylic, polyester and vinylon fibers, or natural fibers such as hemp, which are added as necessary, prevent the occurrence of cracks and improve the trowel elongation during trowel application. . As the pulp quality, pulp block or crushed waste paper can be used.

【0013】水溶性増粘剤は、前記ベントナイトと同様
に凸部を形成(造形)した後のたれを防止する。また、
粘性挙動、増粘効果、混練り時の混和性、粘度の安定
性、保水性を付与する。上記水溶性増粘剤としてはメチ
ルセルロース、ヒドロキシプロピルメチルセルロース等
通常用いられているものの中から適宜に選定して用いる
ことができ、添加量は保水性、作業性を考慮して決めれ
ば良い。
The water-soluble thickener prevents dripping after forming (modeling) a convex portion as in the case of the bentonite. Also,
It imparts viscous behavior, thickening effect, miscibility during kneading, stability of viscosity, and water retention. The water-soluble thickener can be appropriately selected and used from commonly used ones such as methylcellulose and hydroxypropylmethylcellulose, and the addition amount may be determined in consideration of water retention and workability.

【0014】ポリカルボン酸系、ナフタリンスルホン酸
系等の分散剤は、できるだけ少ない水で下塗り材組成物
を分散混合することにより、乾燥性を向上させ、さらに
水に溶解するCaイオンの量を低減し、色ムラを防止す
る。また、着色剤を添加する場合には、着色剤を安定に
分散させ、色別れや色ムラを防止する。さらに、下塗り
材組成物の混練り物を適宜な包装材に充填する場合に
は、混練り物の粘性が変化して組成物がしまり、流動性
がなくなることを防止し、包装材から出したそのままの
状態での使用を可能にする。この分散剤は、用いた着色
剤の色別れや混練り物の粘性の変化のないものを予め試
験して適宜に選択すれば良い。
Dispersants such as polycarboxylic acid type and naphthalene sulfonic acid type dispersants improve the drying property by dispersing and mixing the undercoating material composition with as little water as possible, and further reduce the amount of Ca ions dissolved in water. To prevent color unevenness. When a colorant is added, the colorant is stably dispersed to prevent color separation and color unevenness. Further, when the kneaded product of the undercoat material composition is filled in an appropriate packaging material, the viscosity of the kneaded material is changed to prevent the composition from becoming clogged and the fluidity is prevented from being lost. Allows use in the state. This dispersant may be appropriately selected by testing in advance a colorant that does not cause color separation or change in viscosity of the kneaded product.

【0015】尚、上記各成分の作用を阻害しない限り付
加させる目的に応じてどのような成分を添加しても良
い。例えばアクリル系、酢酸ビニル系等の合成樹脂エマ
ルジョンを混入することにより、初期の乾燥を速め、初
期強度、接着性、耐水性等を向上させることができる。
It should be noted that any component may be added depending on the purpose of addition as long as the action of each component is not impaired. For example, by mixing a synthetic resin emulsion such as an acrylic type or vinyl acetate type, the initial drying can be accelerated, and the initial strength, adhesiveness, water resistance, etc. can be improved.

【0016】また、本発明は、上塗り材組成物と下塗り
材組成物とからなって、上塗り材組成物は、消石灰に、
シリカヒューム、エチレングリコール、水溶性増粘剤、
炭酸カルシウム等を含有し、必要に応じてパルプ質、ア
クリル、ポリエステル、ビニロン繊維等の化学繊維、或
いは麻等の天然繊維を含有し、ポリカルボン酸系、ナフ
タリンスルホン酸系等の分散剤を用いて水と混練したも
のであることを特徴とする無機質仕上げ材組成物をも提
案するものである。
The present invention also comprises a topcoat material composition and an undercoat material composition, wherein the topcoat material composition is slaked lime.
Silica fume, ethylene glycol, water-soluble thickener,
Contains calcium carbonate, etc., and if necessary, chemical fibers such as pulp, acrylic, polyester, vinylon fibers, etc., or natural fibers such as hemp, etc., and uses a dispersant such as polycarboxylic acid type or naphthalene sulfonic acid type. The present invention also proposes an inorganic finishing material composition characterized by being kneaded with water.

【0017】前記下塗り材組成物を塗工し、乾燥後その
表面に塗工する上塗り材組成物として有機質樹脂系組成
物を用いると、前記下塗り材組成物が炭酸ガスを吸収す
ることができずに硬化が不十分となって十分な物性を得
ることができない。また、施工後の乾燥が速いため、例
えば凸部を形成させた下塗り材組成物の表面全面に上塗
り材組成物を塗布して凸部に付着した上塗り材組成物を
拭き取ろうとしても乾燥して拭き取ることができない。
したがって、通気性、呼吸性、適当な乾燥性を有する必
要があり、前記下塗り材組成物と同様の組成を有するも
のでなければならない。また、デザイン上濃色も要求さ
れるため、白化による色ムラにならないような組成物が
必要である。
When an organic resin-based composition is used as the overcoating material composition which is applied to the surface of the undercoating material composition after being dried, the undercoating material composition cannot absorb carbon dioxide gas. In addition, curing is insufficient and sufficient physical properties cannot be obtained. Further, since the drying after the construction is fast, for example, the topcoat material composition applied to the entire surface of the undercoat material composition having the convex portions formed thereon is dried even if it is attempted to wipe off the topcoat material composition adhered to the convex portions. Cannot be wiped off.
Therefore, it must have breathability, breathability, and appropriate drying properties, and must have a composition similar to that of the undercoat material composition. Further, a dark color is also required for the design, and therefore a composition that does not cause color unevenness due to whitening is required.

【0018】上塗り材組成物中のシリカヒュームは、前
述同様組成物中のCaイオンと反応し、色ムラの防止に
なる。また、エチレングリコールは、下塗り材凸部に付
着した上塗り材を拭き取るまで乾燥しないよう添加され
るものであり、好ましくは1〜10%の範囲で添加す
る。さらに、炭酸カルシウムは、白色顔料の作用と漆喰
の強度調整、こて塗りの際のこてのすべりを向上させ
る。また、本発明の上塗り材組成物にも、接着性の向
上、耐水性の向上のため、拭き取り作業を阻害しない範
囲内でアクリル系、酢酸ビニル系等の合成樹脂エマルジ
ョンを混入しても良い。
Silica fume in the overcoat material composition reacts with Ca ions in the composition as described above to prevent color unevenness. Further, ethylene glycol is added so as not to dry until the upper coating material adhering to the convex portions of the lower coating material is wiped off, and is preferably added in the range of 1 to 10%. Furthermore, calcium carbonate improves the action of the white pigment, the strength adjustment of plaster, and the trowel slip during trowel application. Further, to the top coat material composition of the present invention, in order to improve the adhesiveness and the water resistance, a synthetic resin emulsion such as an acrylic type or vinyl acetate type may be mixed within a range that does not hinder the wiping operation.

【0019】尚、下塗り材組成物、上塗り材組成物はそ
れぞれ単体で仕上げに使用することも可能であり、極め
て施工性が良好である。しかし、単色仕上げとなるた
め、特に平滑面に仕上げる場合には視覚的に面白みがあ
るものではない。そこで、本発明は、前記構成の下塗り
材組成物及び上塗り材組成物を用いて、様々なテクスチ
ャーを表現でき、しかも各組成物の色彩により多彩な仕
上げを可能とした工法をも提案する。即ち、本発明は、
前記構成の下塗り材組成物をこて或いは治具、ローラー
等を用いて凸部が形成(造形)されるように塗工し、乾
燥した後、上記下塗り材組成物と同色または異色の前記
構成の上塗り材組成物を上記凸部を除く部分に塗工する
工法を提案するものである。
The undercoating material composition and the topcoating material composition can be used individually for finishing, and they have very good workability. However, since it is a single color finish, it is not visually interesting especially when finishing a smooth surface. Therefore, the present invention also proposes a construction method in which various textures can be expressed by using the undercoating material composition and the overcoating material composition having the above-mentioned constitutions, and moreover, various finishes can be achieved by the color of each composition. That is, the present invention is
The undercoating material composition having the above-mentioned constitution is applied using a trowel or a jig, a roller or the like so that a convex portion is formed (modeled), and after drying, the above-mentioned undercoating material composition having the same color or different color The present invention proposes a method of coating the above-mentioned topcoat material composition on the portion excluding the above-mentioned convex portions.

【0020】上記凸部は、前記下塗り材組成物を塗工し
て流動性を有しているうちに適宜方法で所望の表面模様
(凸部)を形成し、見掛け上水浮き等がなくなって生乾
きの状態で凸部表面処理をすれば良く、特にその方法を
限定するものではないが、例えば以下の方法がある。下
塗り材組成物をこてで壁面に塗り付けた後、木製治具を
壁面に直角に押し当てて引き上げ、水引き後に上下にこ
てを動かして押さえると、あやめ状の模様が形成され
る。また、木製治具を壁面に直角に押し当てて廻しなが
ら引き上げ、水引き後にこてを廻しながら押さえると、
ばら状の模様が形成される。さらに、マスチックローラ
ーでパターン出しを行い、水引後、こてで押えるとくち
なし状の模様が形成され、金ごての尻を用いてランダム
にパターン出しを行うとあじさい状の模様が形成され
る。
The above-mentioned convex portions form a desired surface pattern (convex portion) by an appropriate method while being coated with the undercoat material composition and have fluidity, and apparently water floating and the like disappear. The surface treatment of the convex portion may be performed in a dry state, and the method is not particularly limited, but the following methods are available, for example. After the undercoat material composition is applied to the wall surface with a trowel, a wooden jig is pressed against the wall surface at a right angle to pull it up, and after the water is drawn, the trowel is moved up and down and pressed to form an iris-shaped pattern. Also, press the wooden jig at a right angle against the wall and pull it up while turning it, and after drawing water, press the iron while turning it,
A rose pattern is formed. Furthermore, patterning is performed with a mastic roller, and after water drawing, it is pressed with a trowel to form a gussetless pattern, and when patterning is randomly performed using the butt of a metal iron, a hydrangea pattern is formed.

【0021】凸部を形成(造形)させた後には、合成樹
脂エマルジョン又は合成樹脂溶液を凸部に塗布しても良
い。上記合成樹脂エマルジョン又は合成樹脂溶液は、凸
部の艶出し効果を有するが、下塗り材組成物が炭酸ガス
を吸収することができるような通気性を有していること
が必要である。上記合成樹脂溶液としては、例えばイソ
シアネート基10〜0.5重量%及び加水分解性シラン
基(珪素原子を基準として)7.5〜0.4重量%を含
有して平均分子量が50000〜3000であるポリマ
ーを主成分とする一液硬化型樹脂組成物またはフッ素系
エマルジョン樹脂等の透湿性能の高い樹脂を用いること
ができる。
After forming (molding) the convex portion, a synthetic resin emulsion or a synthetic resin solution may be applied to the convex portion. The above-mentioned synthetic resin emulsion or synthetic resin solution has a glossy effect on the convex portion, but it is necessary that the undercoating material composition has air permeability so that carbon dioxide gas can be absorbed. The synthetic resin solution contains, for example, 10 to 0.5% by weight of an isocyanate group and 7.5 to 0.4% by weight of a hydrolyzable silane group (based on silicon atom) and has an average molecular weight of 50,000 to 3,000. A resin having a high moisture permeability such as a one-pack curable resin composition containing a certain polymer as a main component or a fluorine-based emulsion resin can be used.

【0022】その後、前記上塗り材組成物を、上記凸部
を除く部分(凹部)に塗工するのであるが、凹部のみに
塗り付けるようにしても良いし、或いは全面に塗り付け
て凸部に付着した上塗り材組成物を拭き取るようにして
も良い。上記上塗り材組成物は、下塗り材組成物と同色
のものを用いても良いが、下塗り材組成物と異色のもの
を用いて多彩仕上げとする方が視覚的興趣に富むものと
なる。
After that, the above-mentioned overcoat material composition is applied to the portions (recesses) excluding the above-mentioned convex portions, but it may be applied only to the concave portions, or it may be applied to the entire surface and attached to the convex portions. You may make it wipe off the said topcoat material composition. The above-mentioned topcoat material composition may have the same color as that of the undercoat material composition, but it is more visually appealing to use various finishes by using those having different colors from those of the undercoat material composition.

【0023】このような工法により施工された漆喰壁
は、極めて視覚的興趣に富んだものとすることができ、
しかも無機質素材が有する高級感、重厚感、耐久性を併
せ持ち、呼吸性、通気性、素朴さ等をも有するものとな
る。
The plastered wall constructed by such a construction method can be made very visually appealing.
In addition, the inorganic material has a high-class feeling, a solid feeling, and durability, and also has breathability, breathability, and rusticness.

【0024】[0024]

【実施例】以下に、本発明の実施例を示す。EXAMPLES Examples of the present invention will be shown below.

【0025】[配合例1〜8]下記表1に示す配合組成
により下塗り材組成物を調合し、以下に示す性能評価試
験を行った。
[Formulation Examples 1 to 8] Undercoat material compositions were prepared according to the composition shown in Table 1 below, and the following performance evaluation tests were conducted.

【0026】[0026]

【表1】 [Table 1]

【0027】[配合例9〜16]下記表2に示す配合組
成により上塗り材組成物を調合し、以下に示す性能評価
試験を行った。
[Formulation Examples 9 to 16] Topcoat material compositions were prepared according to the composition shown in Table 2 below, and the following performance evaluation tests were conducted.

【0028】[0028]

【表2】 [Table 2]

【0029】[比較例1〜4]下記表3に示す配合組成
の組成物を調合し、以下に示す性能評価試験を行った。
[Comparative Examples 1 to 4] Compositions having the composition shown in Table 3 below were prepared, and the following performance evaluation tests were conducted.

【0030】[0030]

【表3】 [Table 3]

【0031】[下塗り材組成物の作業性、ダレの有無、
乾燥状態、色ムラの確認]温度20℃、湿度65%のシ
ュミレーション環境試験室に石膏ボード厚9mm(18
20×910)を2枚貼り、SSプラスター(富士川建
材工業株式会社製)を約3mm厚に施工し、1週間乾燥
養生後試験用下地とした。配合例1〜8の下塗り材組成
物を3.3m2 分施工し、10×5cm角程度の押さえ
面を有する木製治具を直角に押し当てて(押さえ面を塗
布面と平行にして垂直方向から押さえる)引き上げ、水
引後に上下にこてを動かしてこて押さえを行い、あやめ
状の凸部を形成した。そして、作業性、パターン出し後
のダレの有無を確認し、施工後の乾燥状態、色ムラの状
態を目視により観察し、評価した。
[Workability of the undercoat material composition, presence of sagging,
Confirmation of dry state and color unevenness] Gypsum board thickness 9 mm (18 mm) in a simulation environment test room at a temperature of 20 ° C and a humidity of 65%
20 × 910) was pasted on the sheet, SS plaster (manufactured by Fujikawa Kenzai Kogyo Co., Ltd.) was applied to a thickness of about 3 mm, and it was used as a test base after 1 week of dry curing. The undercoat material compositions of formulation examples 1 to 8 were applied for 3.3 m 2 minutes, and a wooden jig having a pressing surface of about 10 × 5 cm square was pressed at a right angle (the pressing surface was made parallel to the application surface in the vertical direction). After pulling up and drawing water, the trowel was moved by moving the trowel up and down to form a iris-shaped convex portion. Then, the workability and the presence or absence of sagging after patterning were confirmed, and the dry state and uneven color state after the construction were visually observed and evaluated.

【0032】[保存安定性の確認]配合例1〜8の下塗
り材組成物及び配合例9〜16の上塗り材組成物を50
0ccのポリビンに入れ、50℃の恒温水槽に7日間放
置し、下塗り材組成物の粘度の変化(しまり具合)を確
認した。
[Confirmation of Storage Stability] 50 of the undercoat material compositions of Formulation Examples 1 to 8 and the topcoat material compositions of Formulation Examples 9 to 16 were used.
It was placed in a 0 cc polybin and allowed to stand in a constant temperature water bath at 50 ° C. for 7 days, and the change in the viscosity (tightness) of the undercoat material composition was confirmed.

【0033】[拭き取り易さの確認]下塗り材組成物の
作業性を評価した試験面に、短毛ローラーを用いて合成
樹脂エマルジョン(東洋インキ株式会社製)を凸部に塗
布し、乾燥後、配合例9〜16の上塗り材組成物をゴム
こてを用いて塗り付け、凸部にできる限り残らないよう
に伸ばし、凹部が水引後、硬めのスポンジを用いて凸部
に付着している上塗り材組成物を拭き取り評価した。
[Confirmation of Ease of Wiping] A test surface on which the workability of the undercoat material composition was evaluated was coated with a synthetic resin emulsion (manufactured by Toyo Ink Co., Ltd.) on the convex portion using a short-hair roller, and after drying, Formulation Examples 9 to 16 are coated with a topcoat material composition using a rubber trowel, the protrusions are stretched so as not to remain as much as possible, and after the recesses are drained, a hard sponge is used to adhere to the protrusions. The material composition was wiped and evaluated.

【0034】[上塗り材組成物の作業性、乾燥状態、色
ムラ、アクの確認]拭き取り易さを評価した際の作業
性、壁面の乾燥状態、色ムラ、アクの発生状態を目視に
より評価した。
[Confirmation of workability, dry state, color unevenness and scratches of topcoat material composition] Workability upon evaluation of easiness of wiping, dry state of wall surface, color unevenness, and occurrence of scratches were visually evaluated. .

【0035】尚、上記各試験項目の評価基準は以下の通
りである。 作業性は、こての伸び・こてぎれ等の良いものを ◎、 こての伸び・こてぎれ等の普通のものを ○、 こての伸び・こてぎれ等の悪いものを ×、 と評価し、表4〜6に示した。 パターン出具合は、パターンの出具合が良く、ダレの無いものを ◎、 パターンの出具合が良いが、ダレの有るものを○、 パターンの出具合が悪く、ダレの有るものを ×、 と評価し、表4,6に示した。 乾燥状態は、乾燥時間が適当であるもの ○、 乾燥時間が早過ぎるか遅過ぎるもの ×、 と評価し、表4〜6に示した。 色ムラは、色ムラの発生が無いものを ◎、 色ムラの発生が少ないものと ○、 色ムラの発生が多いものを ×、 と評価し、表4〜6に示した。 保存安定性は、50℃の温水に7日間浸し、凝固しないものを ○、 50℃の温水に7日間浸し、凝固するものを ×、 と評価し、表4〜6に示した。 拭き取り易さは、スポンジ等で拭き取り易いものを ○、 スポンジ等で拭き取り難いものを ×、 と評価し、表5,6に示した。 アクは、アクの発生が無いものを ◎、 アクの発生が少ないものと ○、 アクの発生が多いものを ×、 と評価し、表5,6に示した。
The evaluation criteria for the above test items are as follows. As for workability, good things such as trowel growth and sewage are marked with ◎, normal trowel growth and lugs are marked with ○, and trowel growth and trowels are not marked with ×. Was evaluated and shown in Tables 4 to 6. Regarding the pattern appearance, the pattern appearance is good and there is no sag. ◎, the pattern appearance is good, but the sagging is ○, the pattern appearance is bad and the sagging is x. The results are shown in Tables 4 and 6. The dry state was evaluated as ○ when the drying time was appropriate, and when the drying time was too early or too late, and shown in Tables 4 to 6. The color unevenness was evaluated as ⊚ when no color unevenness was generated, as ◯ when there was little color unevenness, and as x when there was many color unevenness, and is shown in Tables 4 to 6. The storage stability was evaluated as ◯ when the sample was immersed in warm water of 50 ° C. for 7 days and did not coagulate, and as × when immersed in warm water of 50 ° C. for 7 days and shown in Tables 4 to 6. The easiness of wiping off was evaluated as ◯ when it was easy to wipe off with a sponge or the like, and as x when it was difficult to wipe off with a sponge or the like. As for the acres, those with no accretion were evaluated as ⊚, those with little accretion were evaluated as ○, and those with a large amount of accretion were evaluated as ×, and the results are shown in Tables 5 and 6.

【0036】[0036]

【表4】 [Table 4]

【0037】[0037]

【表5】 [Table 5]

【0038】[0038]

【表6】 [Table 6]

【0039】[透湿度試験]外径110mm,高さ68
mmのスチロール容器にろ紙で蓋をし、配合例7の下塗
り材組成物及び配合例15の上塗り材組成物を表7の塗
布量にて塗布し、標準状態(20℃,65%RH)で7
日間養生した。次に、容器に100gの水を入れ、パラ
フィンで密閉した。さらに、容器全体の重量を測定し、
40℃の乾燥器で24時間,48時間,72時間後の重
量を測定し、48時間から72時間迄の重量変化を透湿
量として表8に示した。尚、比較のために比較例1の組
成物を表7の塗布量にて塗布したもの、クロスを被覆さ
せたもの、樹脂系仕上げ材を表7の塗布量にて塗布した
ものを同様に試験し、その結果を表8に併せて示した。
[Water vapor permeability test] Outer diameter 110 mm, height 68
A styrene container of mm is covered with a filter paper, and the undercoat material composition of formulation example 7 and the topcoat material composition of formulation example 15 are applied in the coating amounts shown in Table 7, and in a standard state (20 ° C., 65% RH). 7
I was cured for a day. Next, 100 g of water was put into the container and the container was sealed with paraffin. Furthermore, weigh the entire container,
The weight after 24 hours, 48 hours and 72 hours was measured with a drier at 40 ° C., and the change in weight from 48 hours to 72 hours is shown in Table 8 as the amount of moisture permeation. For comparison, the composition of Comparative Example 1 was applied at the coating amount shown in Table 7, the cloth was coated, and the resin-based finishing material was coated at the coating amount shown in Table 7 in the same manner. The results are also shown in Table 8.

【0040】[0040]

【表7】 [Table 7]

【0041】[0041]

【表8】 [Table 8]

【0042】[吸放湿性試験]吸放湿の状態は図1に示
す通りである。試験方法は、石膏ボードに配合例7の下
塗り材組成物及び配合例15の上塗り材組成物を用いて
表7の塗布量にて塗布し、養生終了後、側面及び裏面を
パラフィンでシールし、シュミレーション環境試験室を
温度20℃一定とし、湿度は図2に示すサイクルに設定
して4サイクル繰り返し、24時間経過毎に重量を測定
し、吸放湿量を求めた。吸湿量は図3に、放湿量は図4
に示した。比較のために比較例1の組成物を塗布したも
の、クロスを被覆させたもの、樹脂系仕上げ材を塗布し
たものを同様に試験し、その結果を図1,3,4に併せ
て示した。本発明の配合例より形成された漆喰構造は、
一般的なクロスや樹脂系仕上げ材、並びに既調合漆喰で
ある比較例1よりも優れた吸放湿性を有することが確認
された。
[Moisture Absorption / Desorption Test] The moisture absorption / desorption state is as shown in FIG. The test method was to apply the undercoat material composition of formulation example 7 and the topcoat material composition of formulation example 15 to the gypsum board at the coating amounts shown in Table 7, and after curing, seal the side and back surfaces with paraffin. The temperature in the simulation environment test chamber was kept constant at 20 ° C., the humidity was set to the cycle shown in FIG. 2, and four cycles were repeated, and the weight was measured every 24 hours to determine the moisture absorption / release amount. Fig. 3 shows the amount of moisture absorption and Fig. 4 shows the amount of moisture released.
It was shown to. For comparison, one coated with the composition of Comparative Example 1, one coated with cloth, and one coated with a resinous finishing material were similarly tested, and the results are also shown in FIGS. . The stucco structure formed from the formulation example of the present invention,
It was confirmed that it has a better moisture absorption and desorption property than that of Comparative Example 1 which is a general cloth, resin-based finishing material, and already-prepared plaster.

【0043】[接着強度]石膏ボードに、薄塗り石膏プ
ラスターを3mm塗り、1週間恒温室で養生したものを
下地板とした。この下地板に配合例7の下塗り材組成物
及び配合例15の上塗り材組成物を用いて表7の塗布量
にて塗布し、恒温室で7日間養生した。その後、JIS
A 6909に規定する付着試験方法に準じて測定を
行い、その結果を表9に示した。比較のために比較例
1,2の組成物を塗布したものを同様に試験し、その結
果を表9に併せて示した。
[Adhesive Strength] A gypsum board was coated with a thin-coated gypsum plaster to a thickness of 3 mm and aged for 1 week in a constant temperature room to obtain a base plate. The undercoat material composition of formulation example 7 and the topcoat material composition of formulation example 15 were applied to the base plate at the coating amounts shown in Table 7, and cured in a temperature-controlled room for 7 days. Then JIS
The measurement was performed according to the adhesion test method specified in A 6909, and the results are shown in Table 9. For comparison, those coated with the compositions of Comparative Examples 1 and 2 were similarly tested, and the results are also shown in Table 9.

【0044】[0044]

【表9】 [Table 9]

【0045】以上本発明を実施例に基づいて説明した
が、本発明は前記した実施例に限定されるものではな
く、特許請求の範囲に記載した構成を変更しない限りど
のようにでも実施することができる。
Although the present invention has been described based on the embodiments, the present invention is not limited to the above-mentioned embodiments, and may be carried out in any manner as long as the configuration described in the claims is not changed. You can

【0046】[0046]

【発明の効果】以上説明したように本発明の無機質仕上
げ材組成物は、左官の熟練した技術を必要としなくても
容易に白壁をムラなく均一な壁面にすることができ、さ
らに着色した色漆喰をムラなく仕上げることと共に様々
なテクスチャーと多彩仕上げが容易にできるものであ
る。
Industrial Applicability As described above, the inorganic finishing material composition of the present invention can easily form a white wall evenly and uniformly without requiring the skill of a plasterer. It is possible to finish plaster evenly and to easily create various textures and various finishes.

【0047】また、本発明により形成される漆喰構造
は、施工後もクラックを発生させることが無く、壁面と
して美観を保ち、耐久性の高い仕上げ材となる。
The stucco structure formed according to the present invention does not generate cracks even after construction, maintains a beautiful appearance as a wall surface, and is a highly durable finish material.

【0048】さらに、本発明の無機質仕上げ材組成物
は、様々なテクスチャーに対応できるものであって、有
機質素材の施工性の良さ、仕上げの均一さを備え、しか
も無機質素材の持つ、高級感、重厚感、耐久性を併せ持
ち、多彩仕上げが可能となるものである。
Further, the inorganic finishing material composition of the present invention can be applied to various textures, has good workability of organic material and uniform finish, and has a high-class feeling of inorganic material. It has a solid feeling and durability, and allows for a variety of finishes.

【0049】したがって、本発明の工法は、従来にない
優れた外観を呈する壁面構造を形成することができるも
のである。
Therefore, the method of the present invention is capable of forming a wall surface structure having an unprecedented excellent appearance.

【図面の簡単な説明】[Brief description of drawings]

【図1】実施例の評価試験における吸放湿の状態を示す
グラフである。
FIG. 1 is a graph showing a state of moisture absorption and desorption in an evaluation test of Examples.

【図2】実施例の吸放湿試験における湿度設定条件を示
すグラフである。
FIG. 2 is a graph showing humidity setting conditions in a moisture absorption / desorption test of an example.

【図3】実施例の吸放湿試験における吸湿量結果を示す
グラフである。
FIG. 3 is a graph showing a moisture absorption amount result in a moisture absorption / desorption test of an example.

【図4】実施例の吸放湿試験における放湿量結果を示す
グラフである。
FIG. 4 is a graph showing a moisture release amount result in a moisture absorption / release test of an example.

フロントページの続き (51)Int.Cl.6 識別記号 庁内整理番号 FI 技術表示箇所 C04B 22:10 24:04 14:10 Z 18:14 Z 14:28 16:02 Z 24:38 D 16:00) 103:30 103:40 103:44 103:60 Continuation of front page (51) Int.Cl. 6 Identification code Office reference number FI Technical display area C04B 22:10 24:04 14:10 Z 18:14 Z 14:28 16:02 Z 24:38 D 16: 00) 103: 30 103: 40 103: 44 103: 60

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 上塗り材組成物と下塗り材組成物とから
なって、下塗り材組成物は、消石灰に、シリカヒュー
ム、アルコール、エチレングリコール、水溶性増粘剤、
ベントナイト等を含有し、必要に応じてパルプ質、アク
リル、ポリエステル、ビニロン繊維等の化学繊維、或い
は麻等の天然繊維を含有し、ポリカルボン酸系、ナフタ
リンスルホン酸系等の分散剤を用いて水と混練したもの
であることを特徴とする無機質仕上げ材組成物。
1. An undercoat material composition comprising an overcoat material composition and an undercoat material composition, wherein the undercoat material composition contains slaked lime, silica fume, alcohol, ethylene glycol, a water-soluble thickener,
Contains bentonite, etc., if necessary, pulp fiber, acrylic, polyester, chemical fiber such as vinylon fiber, or natural fiber such as hemp, and uses a dispersant such as polycarboxylic acid type or naphthalene sulfonic acid type. An inorganic finishing material composition characterized by being kneaded with water.
【請求項2】 上塗り材組成物と下塗り材組成物とから
なって、上塗り材組成物は、消石灰に、シリカヒュー
ム、エチレングリコール、水溶性増粘剤、炭酸カルシウ
ム等を含有し、必要に応じてパルプ質、アクリル、ポリ
エステル、ビニロン繊維等の化学繊維、或いは麻等の天
然繊維を含有し、ポリカルボン酸系、ナフタリンスルホ
ン酸系等の分散剤を用いて水と混練したものであること
を特徴とする無機質仕上げ材組成物。
2. A topcoat material composition comprising a topcoat material composition and a basecoat material composition, wherein the topcoat material composition contains silica fume, ethylene glycol, a water-soluble thickener, calcium carbonate and the like in slaked lime, if necessary. It contains chemical fibers such as pulp, acrylic, polyester and vinylon fibers, or natural fibers such as hemp and is kneaded with water using a dispersant such as polycarboxylic acid type or naphthalene sulfonic acid type. A characteristic inorganic finishing material composition.
【請求項3】 請求項1記載の下塗り材組成物をこて或
いは治具、ローラー等を用いて凸部が形成されるように
塗工し、乾燥した後、上記下塗り材組成物と同色または
異色の請求項2記載の上塗り材組成物を上記凸部を除く
部分に塗工する工法。
3. The undercoating material composition according to claim 1 is coated with a trowel, a jig, a roller or the like so that a convex portion is formed, and after drying, the same color as that of the undercoating material composition or A method for applying the differently colored topcoat material composition according to claim 2 to the portion excluding the convex portions.
JP34898593A 1993-12-28 1993-12-28 Inorganic finishing material composition and method using the same Expired - Fee Related JP3569306B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34898593A JP3569306B2 (en) 1993-12-28 1993-12-28 Inorganic finishing material composition and method using the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34898593A JP3569306B2 (en) 1993-12-28 1993-12-28 Inorganic finishing material composition and method using the same

Publications (2)

Publication Number Publication Date
JPH07196355A true JPH07196355A (en) 1995-08-01
JP3569306B2 JP3569306B2 (en) 2004-09-22

Family

ID=18400716

Family Applications (1)

Application Number Title Priority Date Filing Date
JP34898593A Expired - Fee Related JP3569306B2 (en) 1993-12-28 1993-12-28 Inorganic finishing material composition and method using the same

Country Status (1)

Country Link
JP (1) JP3569306B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0874698A1 (en) * 1996-01-04 1998-11-04 Chemical Lime Company Method of preventing corrosion in concrete pipe
JP2005002787A (en) 2002-02-15 2005-01-06 Rikuo Himeno Method for inhibiting color difference of colored plaster coating resulting from re-coating
US7201798B2 (en) * 2005-05-05 2007-04-10 Halliburton Energy Services, Inc. Set-delayed cement compositions comprising hydrated lime and silica and methods of cementing in subterranean formations
JP2008169062A (en) * 2007-01-10 2008-07-24 Dic Corp Urethane cement-based composition, coated floor material, and construction method thereof
JP2012131882A (en) * 2010-12-21 2012-07-12 Denki Kagaku Kogyo Kk Inorganic paint composition
JP2013519616A (en) * 2010-02-10 2013-05-30 リメコ リミテッド Hydraulic lime composition

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0874698A1 (en) * 1996-01-04 1998-11-04 Chemical Lime Company Method of preventing corrosion in concrete pipe
EP0874698A4 (en) * 1996-01-04 2000-01-19 Chemical Lime Ltd Method of preventing corrosion in concrete pipe
JP2005002787A (en) 2002-02-15 2005-01-06 Rikuo Himeno Method for inhibiting color difference of colored plaster coating resulting from re-coating
US7201798B2 (en) * 2005-05-05 2007-04-10 Halliburton Energy Services, Inc. Set-delayed cement compositions comprising hydrated lime and silica and methods of cementing in subterranean formations
JP2008169062A (en) * 2007-01-10 2008-07-24 Dic Corp Urethane cement-based composition, coated floor material, and construction method thereof
JP2013519616A (en) * 2010-02-10 2013-05-30 リメコ リミテッド Hydraulic lime composition
US9067830B2 (en) 2010-02-10 2015-06-30 Limeco Limited Hydraulic lime composition
JP2012131882A (en) * 2010-12-21 2012-07-12 Denki Kagaku Kogyo Kk Inorganic paint composition

Also Published As

Publication number Publication date
JP3569306B2 (en) 2004-09-22

Similar Documents

Publication Publication Date Title
EP0044690B1 (en) Anti-graffiti facing of walls or similar surfaces
JPH07196355A (en) Inorganic finishing material composition and method for construction using the same
US20130209686A1 (en) Coating or cladding and method of preparing same
JP7438804B2 (en) Face material
JP2013240749A (en) Surface finishing method
JP5512945B2 (en) Non-combustible water-based coating composition, finish coating material and construction method thereof
JP6273564B2 (en) Wall coating material using shells
US7396567B2 (en) Weathered stone and the manufacturing method thereof
CN112680035B (en) Artistic paint and preparation method thereof
JP5173494B2 (en) Surface finishing method
JP5580509B2 (en) Water-based coating material composition, construction method thereof, and wall structure thereby
JPH041353A (en) Wall-surface finishing material displaying hexagonal pattern and execution method thereof
JP2001187867A (en) Coating composition
JP6341636B2 (en) Laminate
CN100376638C (en) Decorative coating material and construction material
JP5354932B2 (en) Surface finishing method
JP7438803B2 (en) Face material
JP4877719B2 (en) Pattern formation method
CN100425657C (en) Decorative coating material and construction material
JP4484569B2 (en) Decorative coating laminate
JP2005296785A (en) Decorated coating film superposed body
GB2376229A (en) Plaster composition containing a colourant
JP2004251109A (en) Wet painting material used for makeup method of construction of wall surface and this in building
DE102022003270A1 (en) Plaster wall coating mixture
JP5393942B2 (en) Water-based paint composition and wall surface

Legal Events

Date Code Title Description
A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20040120

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20040311

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20040405

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20040525

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20040618

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080625

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20080625

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090625

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20090625

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100625

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100625

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110625

Year of fee payment: 7

LAPS Cancellation because of no payment of annual fees