JP2001187867A - Coating composition - Google Patents

Coating composition

Info

Publication number
JP2001187867A
JP2001187867A JP32312599A JP32312599A JP2001187867A JP 2001187867 A JP2001187867 A JP 2001187867A JP 32312599 A JP32312599 A JP 32312599A JP 32312599 A JP32312599 A JP 32312599A JP 2001187867 A JP2001187867 A JP 2001187867A
Authority
JP
Japan
Prior art keywords
coating
coating composition
weight
slaked lime
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP32312599A
Other languages
Japanese (ja)
Other versions
JP3083519B1 (en
Inventor
Rikuo Himeno
陸男 姫野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP11323125A priority Critical patent/JP3083519B1/en
Application granted granted Critical
Publication of JP3083519B1 publication Critical patent/JP3083519B1/en
Publication of JP2001187867A publication Critical patent/JP2001187867A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Panels For Use In Building Construction (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Paints Or Removers (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a coating material having slaked lime as the major component which excels in opacifying power with a small coating amount, and a coated product having been coated with the same. SOLUTION: The coating composition comprises slaked lime, a polymer component, and water with (1) the state in a container, (2) the coating workability, (3) the low temperature stability, (4) the external appearance of a coated film, (5) the alkali resistance, (6) the washing resistance, and (8) the contrast ratio of the coating fluid or the dried coated film which meat at least second grade coating properties regulated by JIS K 5663-1995. The coated product is obtained by applying the coating composition on a material.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、各種建築物の壁や
天井などの内装若しくは外装の化粧塗装に適した水性塗
料に関する。より詳細には、本発明は、水性塗料として
要求される各種の塗料性能並びに塗膜物性を充足すると
ともに、漆喰特有の落ち着いた艶消しの質感を有し且つ
調湿機能のある塗膜を形成する塗料に関する。さらに本
発明は該塗料組成物を塗布してなる塗装物に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water-based paint suitable for decorative coating of interior or exterior such as walls and ceilings of various buildings. More specifically, the present invention forms a coating film having a calm matte texture peculiar to plaster and a humidity control function, while satisfying various coating properties and coating film properties required as an aqueous coating material. To paint. Further, the present invention relates to a coated article obtained by applying the coating composition.

【0002】[0002]

【従来の技術】漆喰は、落ち着きのある重厚な仕上がり
感に加えて、調湿性(吸湿性及び放湿性)、結露防止性
及び防カビ性といった機能に優れているため、日本建築
の屋内外の塗り壁材として古くから使用されている建築
材料である。
2. Description of the Related Art In addition to the calm and profound finish, plaster has excellent functions such as humidity control (moisture absorption and moisture release), anti-condensation and anti-mold properties. It is a building material that has long been used as a painted wall material.

【0003】しかし、漆喰の施工には熟練を要する左官
作業が必要であり、作業者の技術によって仕上がりにバ
ラツキが生じ易く、また複数回の繰り返し施工(塗りと
コテこすり)の必要性から施工能率が悪く、施工期間が
長くかかったり施工コストも高くつくという欠点があ
る。
However, plastering requires plastering work that requires skill, and the finish is likely to vary due to the skill of the worker. In addition, the necessity of multiple repetitions (painting and rubbing) makes the construction efficient. However, there is a disadvantage that the construction period is long and the construction cost is high.

【0004】このため、近年の住宅建築における室内壁
面の仕上げには、塩ビクロス貼りや合成樹脂エマルジョ
ン塗装などの仕上げ方法が多く採用されているが、最近
になって化学物質過敏症やシックハウス症候群などとい
った化学物質の悪害が問題視されるようになり、漆喰な
どの天然素材が再び見直されてきている。
For this reason, in order to finish the interior wall of a recent residential building, many finishing methods such as PVC cloth application and synthetic resin emulsion painting have been adopted, but recently, chemical sensitivity, sick house syndrome, etc. The harm of such chemical substances has become a problem, and natural materials such as plaster have been reviewed again.

【0005】[0005]

【発明が解決しようとする課題】本発明は、漆喰壁材の
成分である消石灰を主成分とする水性塗料を提供するこ
とを目的とする。より具体的には、本発明は水性塗料と
しての性能を有するとともに、形成される塗膜が漆喰壁
特有の質感を有し且つ耐アルカリ性や耐洗浄性を始めと
する塗膜物性並びに調湿性、防カビ性及び耐火性等とい
った塗膜機能に優れた塗料組成物を提供することを目的
とするものである。
SUMMARY OF THE INVENTION An object of the present invention is to provide a water-based paint mainly composed of slaked lime which is a component of a plaster wall material. More specifically, the present invention has the performance as a water-based paint, the coating film formed has a texture unique to the stucco wall and coating film properties including alkali resistance and washing resistance, as well as humidity control properties, It is an object of the present invention to provide a coating composition having excellent coating functions such as mold resistance and fire resistance.

【0006】さらに本発明は、上記水性塗料から形成さ
れる塗膜を有する塗装物、具体的には上記塗膜機能に基
づいて調湿や結露防止等の有用な機能を有する塗布物を
提供することを目的とするものである。
Further, the present invention provides a coated product having a coating film formed from the above-mentioned water-based coating material, and more specifically, a coated product having useful functions such as humidity control and dew condensation prevention based on the coating film function. The purpose is to do so.

【0007】[0007]

【課題を解決するための手段】本発明者は、漆喰の優れ
た美粧性及び機能に着目し、JIS K 5663に規定の合成樹
脂エマルションペイントの品質を有すると共に漆喰特有
の質感及び機能を備えた水性塗料を開発することを目的
として、鋭意検討を重ねたところ、漆喰の主成分である
消石灰にポリマー成分及び水を配合し水性塗料の調製方
法に従って調製した本発明の水性組成物が、貯蔵安定性
及び塗装作業性に優れており上記目的にかなうものであ
ることを見出した。また、かかる塗料組成物から形成さ
れる塗膜は、従来漆喰壁材に必須であったすさ等の繊維
素材を含有していなくても十分な靱性を発揮し成膜性に
優れること、また逆に繊維素材を含まないことによっ
て、より少ない塗布量で薄塗膜化が可能となり、刷毛、
ローラー、スプレー等によって塗膜を簡単にかつ美しく
仕上げることができることを見出した。
Means for Solving the Problems The present inventor has paid attention to the excellent aesthetics and functions of stucco, and has the quality of synthetic resin emulsion paint specified in JIS K 5663 and the texture and function peculiar to stucco. After intensive studies with the aim of developing a water-based paint, the aqueous composition of the present invention prepared according to the method of preparing a water-based paint by blending a polymer component and water with slaked lime, which is a main component of the plaster, has a storage stability. It has been found that it has excellent properties and coating workability and meets the above-mentioned object. Further, a coating film formed from such a coating composition exhibits sufficient toughness even if it does not contain a fiber material such as susa, which has been essential for a plaster wall material in the past. By eliminating the use of fiber material, it is possible to make a thin coating with a smaller coating amount,
It has been found that a coating film can be easily and beautifully finished by a roller, a spray or the like.

【0008】さらに本発明者は、かかる知見に基づいて
更なる検討を進めたところ、上記塗料組成物に更に顔料
として酸化チタンを特定量配合することにより、調湿性
などの機能を有しながら極めて少量の塗布量で施工面を
隠蔽でき、かつ成膜性に優れることを見出し、以上のこ
とから、本発明の塗料組成物によれば、低コストでかつ
少ない労力で、落ち着きのある漆喰特有の質感を有する
とともに調湿性や結露防止性等の機能を発揮する塗膜が
形成できることを確認した。
Further, the present inventor has further studied based on this finding. As a result of adding a specific amount of titanium oxide as a pigment to the above-mentioned coating composition, the present coating composition has extremely good functions such as humidity control. It is possible to conceal the construction surface with a small amount of application, and found that it is excellent in film formability, and from the above, according to the coating composition of the present invention, at low cost and with a small amount of labor, peculiar to calm plaster. It was confirmed that a coating film having a texture and exhibiting functions such as humidity control properties and dew condensation prevention properties could be formed.

【0009】本発明は、かかる知見に基づいて開発され
たものである。
The present invention has been developed based on such knowledge.

【0010】すなわち本発明は、下記1.〜9.に掲げ
る塗料組成物である: 1.消石灰、ポリマー成分及び水を含有する塗料組成物
であって、塗液またはその乾燥塗膜の (1)容器の中での
状態、(2)塗装作業性、(3)低温安定性、(4)塗膜の外
観、(5)耐アルカリ性、(6)耐洗浄性、(7)隠蔽率が、JIS
K 5663-1995に規定される少なくとも2種ペイントの性
質を満たすものである塗料組成物。 2.乾燥塗膜の隠蔽力が500μ以下である1に記載の
塗料組成物。 3.繊維素材を含まないことを特徴とする1または2に
記載の塗料組成物。 4.消石灰を固形換算で30〜80重量%の割合で含有
する1乃至3のいずれかに記載の塗料組成物。 5.消石灰100重量部に対してポリマー成分を10〜
70重量部(固形換算)の割合で含むものである1乃至
4のいずれかに記載の塗料組成物。 6.ポリマー成分がアクリル系樹脂である1乃至5のい
ずれかに記載の塗料組成物。 7.消石灰100重量部に対して酸化チタンを2〜30
重量部(固形換算)の割合で含む1乃至6のいずれかに
記載の塗料組成物。 8.固形分含有率が50〜70重量%であることを特徴
とする1乃至7のいずれかに記載の塗料組成物。 9.粘度が常温で300〜3000センチポイズである
1乃至8のいずれかに記載の塗料組成物。
That is, the present invention provides the following 1. ~ 9. The coating compositions are as follows: A paint composition containing slaked lime, a polymer component and water, wherein the coating liquid or its dried coating film is (1) a state in a container, (2) workability of coating, (3) low-temperature stability, (4 ) Coating appearance, (5) Alkali resistance, (6) Washing resistance, (7) Concealment ratio is JIS
A coating composition which satisfies the properties of at least two paints specified in K 5663-1995. 2. 2. The coating composition according to 1, wherein the hiding power of the dried coating film is 500 μ or less. 3. 3. The coating composition according to 1 or 2, wherein the coating composition does not contain a fiber material. 4. 4. The coating composition according to any one of 1 to 3, which contains slaked lime in a ratio of 30 to 80% by weight in terms of solids. 5. 10 parts by weight of polymer component per 100 parts by weight of slaked lime
5. The coating composition according to any one of 1 to 4, which is contained in a proportion of 70 parts by weight (solid basis). 6. 6. The coating composition according to any one of 1 to 5, wherein the polymer component is an acrylic resin. 7. 2-30 titanium oxides per 100 parts by weight of slaked lime
7. The coating composition according to any one of 1 to 6, which is contained in parts by weight (solid basis). 8. 8. The coating composition according to any one of 1 to 7, wherein the solid content is 50 to 70% by weight. 9. 9. The coating composition according to any one of 1 to 8, which has a viscosity of 300 to 3000 centipoise at room temperature.

【0011】また、本発明は上記に掲げる塗料組成物か
ら形成される塗膜を有する、例えば化粧材や建材等の塗
装物に関する。
[0011] The present invention also relates to a coated material such as a decorative material or a building material having a coating film formed from the above-mentioned coating composition.

【0012】[0012]

【発明の実施の形態】(1)塗料組成物 本発明の塗料組成物は、消石灰、ポリマー成分及び水を
含有する塗料組成物であって、塗液の性状並びにその乾
燥塗膜の外観及び物性が日本工業規格 JIS K 5663-1995
に規定の少なくとも2種ペイントに関する(1) 容器の中
での状態、(2)塗装作業性、(3) 低温安定性、(4) 塗膜
の外観、(5) 耐アルカリ性、(6) 耐洗浄性及び(7) 隠蔽
率の要件を満たすものである。
BEST MODE FOR CARRYING OUT THE INVENTION (1) Coating composition The coating composition of the present invention is a coating composition containing slaked lime, a polymer component and water. The properties of the coating solution and the appearance and physical properties of the dried coating film Is the Japanese Industrial Standard JIS K 5663-1995
(1) State in a container, (2) Painting workability, (3) Low temperature stability, (4) Appearance of coating film, (5) Alkali resistance, (6) Resistance It meets the requirements of cleanability and (7) concealment rate.

【0013】具体的には、本発明の塗料組成物は、JIS
K 5663-1995の規定に従ってJIS K 5400の方法に準じて
測定した場合に少なくとも下記の品質(JIS K 5663-199
5)を有する塗料組成物である: (1) 容器の中での状態:かき混ぜた場合に塊がなく中身
全体が一様になる: (2) 塗装作業性:2回塗りで塗装作業に支障がない: (3) 低温安定性:−5℃に冷やしたとき変質しない: (4) 塗膜の外観:塗膜の外観が正常である: (5) 耐アルカリ性:水酸化カルシウム飽和溶液(20±1
℃)に18時間浸したときに異常がない: (6) 耐洗浄性:100回の洗浄に耐える: (7) 隠蔽率:0.95以上 さらに本発明の塗料組成物は、耐水性(JIS K 5400の8.
19)に関して、脱イオン水に96時間浸しても異常がな
く(JIS K 5663-1995の5.9)、促進耐候性(JIS K 5400
の9.8.1)に関して、白亜化度が8点以上で、膨れ・は
がれ・割れがなく、色の変化の程度が見本品に比べて大
きくない(JIS K 5663-1995の5.12)ことが好ましく、
また隠蔽率が0.93以上(JIS K 5663-1995の5.8)をみた
し、さらに耐候性(JIS K 5400の9.9)に関して、12ヶ
月の試験期間後に膨れ・はがれ・割れがなく色の変化の
程度と白亜化度が見本品に比べて大きくない(JIS K 56
63-1995の5.13)という要件を満たしていることが好ま
しい。
Specifically, the coating composition of the present invention
When measured according to the method of JIS K 5400 according to the provisions of K 5663-1995, at least the following quality (JIS K 5663-199
It is a coating composition having 5): (1) State in a container: When stirred, there is no lump and the entire contents become uniform: (2) Painting workability: Coating work is difficult with two coats No: (3) Low temperature stability: No deterioration when cooled to -5 ° C: (4) Appearance of coating: Appearance of coating is normal: (5) Alkali resistance: Saturated calcium hydroxide solution (20 ± 1
(6) Washing resistance: withstands 100 washes: (7) Hiding ratio: 0.95 or more Furthermore, the coating composition of the present invention has a water resistance (JIS K 5400). 8.
Regarding item 19), there is no abnormality when immersed in deionized water for 96 hours (5.9 of JIS K 5663-1995), and accelerated weather resistance (JIS K 5400
Regarding 9.8.1), it is preferable that the degree of chalk is 8 or more, there is no blistering, peeling or cracking, and the degree of color change is not greater than that of the sample (5.12 of JIS K 5663-1995). ,
In addition, the concealment ratio was 0.93 or more (5.8 in JIS K 5663-1995), and the weather resistance (9.9 in JIS K 5400) showed no change in color without swelling, peeling, or cracking after a 12-month test period. The degree of chalk is not large compared to the sample (JIS K 56
It is preferable to meet the requirement of 5.13) of 63-1995.

【0014】本発明の塗料組成物は、その乾燥時間によ
って特に限定されるものではないが、JIS K 5663-1995
の5.6に従って、JIS K 5400の6.5の試験方法に準じて実
施した場合に20℃で2時間以内に半硬化状態になるよ
うに、また5℃で4時間以内に半硬化状態になるように
調製されることが好ましい。これは塗料組成物に配合す
る固形含量や水分含量並びに粘度を適宜調製することに
よって行うことができる。
[0014] The coating composition of the present invention is not particularly limited by its drying time, but is JIS K 5663-1995.
In accordance with 5.6 of JIS K 5400, when prepared according to the test method of 6.5, prepare a semi-cured state at 20 ° C within 2 hours and a semi-cured state at 5 ° C within 4 hours. Is preferably performed. This can be performed by appropriately adjusting the solid content, the water content, and the viscosity to be added to the coating composition.

【0015】本発明で用いられる消石灰としては、通常
漆喰壁材の成分として用いられるものであればよく特に
制限されない。例えば、工業用消石灰をはじめ、水硬性
及び気硬性の別なく各種の水酸化カルシウムを用いるこ
とができる。また着色等の処理を施した消石灰を使用す
ることもできる。
The slaked lime used in the present invention is not particularly limited as long as it is usually used as a component of a plaster wall material. For example, various types of calcium hydroxide can be used regardless of hydraulic or air-hardness, including industrial slaked lime. Slaked lime that has been subjected to a treatment such as coloring can also be used.

【0016】塗料組成物中の消石灰の配合割合は、貯蔵
安定性や塗装作業性並びに成膜性等といった水性塗料と
して要求される性能、具体的には前述するJIS K 5663-1
995に規定の少なくとも2種ペイントの性質を充足する
範囲であれば特に制限されず、塗料組成物の固形分10
0重量%あたりの配合割合が30〜80重量%となるよ
うな範囲から適宜選択することができる。好ましくは4
0〜70重量%、より好ましくは50〜70重量%であ
る。
The mixing ratio of slaked lime in the coating composition depends on the performance required as an aqueous coating such as storage stability, coating workability and film formability, specifically JIS K5663-1.
There is no particular limitation as long as it satisfies the properties of at least two kinds of paint specified in 995, and the solid content of the paint composition is 10%.
It can be appropriately selected from a range in which the mixing ratio per 0% by weight is 30 to 80% by weight. Preferably 4
It is 0 to 70% by weight, more preferably 50 to 70% by weight.

【0017】また本発明で用いられるポリマー成分は、
消石灰と混和性があるものであればよく、酢酸ビニル
系、ポリアクリル酸エステル系、アクリル−スチレン共
重合体系、エチレン−酢酸ビニル共重合体系、酢酸ビニ
ル−アクリル共重合体系、エチレン−塩化ビニル共重合
体系、酢酸ビニル−ベオバ共重合体系、スチレン/ブタ
ジエン系、エポキシ系及びウレタン系等のポリマーが含
まれる。当該ポリマー成分は塗料組成物中の消石灰同士
の接着強度、消石灰と後述する添加剤との接着強度、並
びに塗料組成物と被塗布物との接着強度を高め、その結
果として、被塗物表面に積層された塗膜層(被覆層)の
ひび割れを防止し、建材の靱性を向上させる働きを有し
ている。
The polymer component used in the present invention comprises:
Any material that is miscible with slaked lime may be used, such as vinyl acetate, polyacrylate, acrylic-styrene copolymer, ethylene-vinyl acetate copolymer, vinyl acetate-acryl copolymer, and ethylene-vinyl chloride copolymer. Polymers, vinyl acetate-veova copolymers, styrene / butadiene-based, epoxy-based and urethane-based polymers are included. The polymer component enhances the adhesive strength between slaked limes in the coating composition, the adhesive strength between slaked lime and additives described below, and the adhesive strength between the coating composition and the object to be coated, and as a result, on the surface of the object to be coated. It has the function of preventing cracks in the laminated coating layer (coating layer) and improving the toughness of building materials.

【0018】好ましいポリマー成分としては、アクリル
樹脂系(ポリアクリル酸エステル系、アクリル−スチレ
ン共重合体系等)、酢酸ビニル系、スチレン/ブタジエ
ンゴム系等の合成ポリマーを挙げることができる。これ
らのポリマー成分は上記性質を有するものであれば、そ
の分子量、重合度、粘度等を特に制限するものではな
い。またこれらは1種単独で、または2種以上を任意に
組み合わせて用いることができる。また消石灰に配合さ
れるポリマー成分の形態は特に制限されず、エマルジョ
ン形態及び粉末形態等のいずれの態様であってもよい。
エマルジョンとして配合する場合、エマルジョンは重合
性不飽和二重結合を有するモノマーをエマルジョン重合
して得られるもの、または、予め合成した樹脂を水系分
散媒に分散剤を使用して分散したものの何れでもよく、
さらに粉末型のポリマーを水等に分散して調製したもの
を挙げることができる。
Preferred polymer components include synthetic polymers such as acrylic resin (polyacrylate, acryl-styrene copolymer), vinyl acetate, and styrene / butadiene rubber. As long as these polymer components have the above properties, their molecular weight, degree of polymerization, viscosity and the like are not particularly limited. These may be used alone or in any combination of two or more. The form of the polymer component to be added to slaked lime is not particularly limited, and may be any of an emulsion form, a powder form, and the like.
When blended as an emulsion, the emulsion may be obtained by emulsion polymerization of a monomer having a polymerizable unsaturated double bond, or may be obtained by dispersing a previously synthesized resin in an aqueous dispersion medium using a dispersant. ,
Further, there may be mentioned those prepared by dispersing a powder type polymer in water or the like.

【0019】ポリマー成分の配合割合は、貯蔵安定性や
塗装作業性並びに成膜性等といった水性塗料として要求
される性能、具体的には前述するJIS K 5663-1995に規
定の少なくとも2種ペイントの性質を充足する範囲であ
れば特に制限されず、使用するポリマー成分の種類に応
じて適宜定めることができる。具体的には、消石灰10
0重量部に対するポリマー成分の配合割合として、通常
10〜70重量部(固形換算)の範囲から選択調整する
ことができる。好ましくは10〜50重量部、より好ま
しくは20〜40重量部、更に好ましくは25〜35重
量部である。
The mixing ratio of the polymer component is determined by the performance required for an aqueous paint such as storage stability, coating workability and film formability, and more specifically, at least two paints specified in JIS K 5663-1995 described above. There is no particular limitation as long as the range satisfies the properties, and it can be appropriately determined according to the type of the polymer component used. Specifically, slaked lime 10
The mixing ratio of the polymer component to 0 part by weight can be usually selected and adjusted from a range of 10 to 70 parts by weight (solid basis). It is preferably 10 to 50 parts by weight, more preferably 20 to 40 parts by weight, and still more preferably 25 to 35 parts by weight.

【0020】本発明においては、上記消石灰及びポリマ
ー成分に加えて、更に顔料並びに各種の添加剤を配合す
ることができる。かかる添加剤としては、例えば無機材
料、無機細骨材、消泡剤、増粘剤、レオロジー調整剤、
分散剤、界面活性剤、湿潤剤、可塑剤、防腐剤などを例
示することができる。
In the present invention, in addition to the slaked lime and the polymer component, a pigment and various additives can be further blended. Such additives include, for example, inorganic materials, inorganic fine aggregates, defoamers, thickeners, rheology modifiers,
Dispersants, surfactants, wetting agents, plasticizers, preservatives and the like can be exemplified.

【0021】顔料としては、水性塗料に用いられるもの
であれば特に制限されず、いずれの顔料をも採用するこ
ともできるが、好ましくは無機顔料を挙げることができ
る。かかる無機顔料としては、酸化チタン,亜鉛華,リ
トポン,アンチモン白等の白色顔料:カーボンブラック
や酸化鉄等の黒色顔料:カドミウムレッド,べんがら,
モリブデンレッド等の赤色顔料:黄鉛,チタンイエロ
ー,カドミウムイエロー,酸化鉄等の黄色顔料:酸化ク
ロムやチタンコバルトグリーン等の緑色顔料:群青など
の青色顔料:タルク,カオリンクレー,水酸化アルミニ
ウム,炭酸カルシウム,ベントナイトなどの体質顔料を
例示することができる。本発明の塗料組成物中に配合す
る顔料の割合は特に制限されず、所望の色彩(明度、色
度、彩度)に応じて適宜選択調整することができる。
The pigment is not particularly limited as long as it is used for an aqueous paint, and any pigment can be employed, but an inorganic pigment is preferred. Examples of such inorganic pigments include white pigments such as titanium oxide, zinc white, lithopone, and antimony white: black pigments such as carbon black and iron oxide: cadmium red, red iron oxide,
Red pigments such as molybdenum red: yellow pigments such as graphite, titanium yellow, cadmium yellow, and iron oxide: green pigments such as chromium oxide and titanium cobalt green: blue pigments such as ultramarine blue: talc, kaolin clay, aluminum hydroxide, and carbonic acid An extender such as calcium and bentonite can be exemplified. The proportion of the pigment to be blended in the coating composition of the present invention is not particularly limited, and can be appropriately selected and adjusted according to a desired color (lightness, chromaticity, saturation).

【0022】顔料として好ましくは酸化チタンを挙げる
ことができる。酸化チタンはルチル形及びアナターゼ形
の別を特に問わないが、一般にルチル形のほうがアナタ
ーゼ形よりも耐光性や隠蔽力が優れている。また粒径及
び形状も特に制限されず、市販品の中から目的に応じて
適宜選択することができるが、一般に酸化チタンとし
て、粒径0.2〜0.5μmの略球状形のものや0.0
1〜0.05μmの超微粒子のもの、並びに紫外線吸収
用板状酸化チタン等が知られている。
The pigment is preferably titanium oxide. There is no particular limitation on the type of titanium oxide, rutile type and anatase type. In general, the rutile type has better light resistance and hiding power than the anatase type. The particle size and shape are not particularly limited, and can be appropriately selected from commercially available products according to the purpose. Generally, titanium oxide having a substantially spherical shape having a particle size of 0.2 to 0.5 μm or 0 is used. .0
Ultrafine particles having a particle size of 1 to 0.05 μm, plate-like titanium oxide for absorbing ultraviolet light, and the like are known.

【0023】酸化チタンを配合する場合、その配合割合
は、消石灰100重量部に対する割合として2〜30重
量部、好ましくは4〜20重量部、より好ましくは8〜
15重量部の範囲を挙げることができる。
When titanium oxide is compounded, the compounding ratio is 2 to 30 parts by weight, preferably 4 to 20 parts by weight, more preferably 8 to 10 parts by weight based on 100 parts by weight of slaked lime.
A range of 15 parts by weight can be mentioned.

【0024】酸化チタンをかかる割合で塗料組成物に配
合することにより、本発明の塗料組成物はより少ない塗
布量で被塗面を隠蔽することができ、しかもかかる少量
の塗料で形成された塗膜は、薄塗膜ながら所望の外観や
物性を有しており、調湿性やそれに伴う結露防止性等の
機能を発揮させることも可能である。
By blending titanium oxide in the coating composition in such a ratio, the coating composition of the present invention can cover the surface to be coated with a smaller amount of coating, and can form a coating formed with such a small amount of coating. The film has a desired appearance and physical properties even though it is a thin coating film, and can exhibit functions such as humidity control and accompanying dew condensation prevention.

【0025】このような塗膜は、本発明の塗料組成物を
1m2あたり固形重量換算で少なくとも100g使用す
ることによって達成することができる。調湿性等の塗膜
機能は塗料組成物の塗布量を増すに従って向上するた
め、かかる機能に鑑みれば、本発明は塗料組成物の塗布
量の上限を制限するものではない。しかしながら、塗料
の成膜性、コスト並びに塗装作業性等を考慮すれば、本
発明の塗料組成物は1m 2あたり固形重量換算で100
g〜1000g、好ましくは100〜500g、より好
ましくは200〜300gの塗布量を用いることが望ま
しい。
Such a coating film is formed by coating the coating composition of the present invention.
1mTwoUse at least 100 g per solid weight
Can be achieved by Coating film such as humidity control
Performance improves with increasing coating composition application rate.
In view of such a function, the present invention relates to the application of a coating composition.
It does not limit the upper limit. However, paint
Considering the film forming property, cost and coating workability of
The coating composition of the invention is 1 m Two100 per solid weight conversion
g to 1000 g, preferably 100 to 500 g, more preferably
Preferably, a coating amount of 200 to 300 g is used.
New

【0026】本発明の塗料組成物は、形成される塗膜の
隠蔽力が500μ以下、好ましくは300μ以下、より
好ましくは200μ以下、更に好ましくは100μ以下
となるように調整することができる。なお、本発明にお
いて隠蔽力とは、その素地に色を認識し得なくなる最小
膜厚さのことであり、具体的には黒白板上に塗装した塗
膜を通して肉眼で観察した場合に下地の黒白の判別が不
可能となる最小膜厚を意味する。
The coating composition of the present invention can be adjusted so that the hiding power of the formed coating film is 500 μm or less, preferably 300 μm or less, more preferably 200 μm or less, and further preferably 100 μm or less. In the present invention, the hiding power refers to a minimum film thickness at which a color cannot be recognized on the base material. Specifically, when observed with the naked eye through a coating film coated on a black-and-white plate, the black-and-white background Is the minimum film thickness at which it is impossible to determine

【0027】無機材料としては、例えば炭酸カルシウ
ム、炭酸バリウム及び水酸化バリウムなどを挙げること
ができる。無機材料を配合する場合、その配合割合は適
宜設定することができるが、消石灰100重量部に対し
て5〜100重量部の範囲を例示することができる。
Examples of the inorganic material include calcium carbonate, barium carbonate and barium hydroxide. When the inorganic material is blended, the blending ratio can be set as appropriate, and a range of 5 to 100 parts by weight with respect to 100 parts by weight of slaked lime can be exemplified.

【0028】無機細骨材としては、例えば珪砂、寒水
砂、マイカ、セラミックサンド、ガラスビーズ、パーラ
イト、バーミキュライトなどを挙げることができる。こ
れらの粒度は特に制限されないが、60〜130メッシ
ュ、または80〜100メッシュの範囲を例示すること
ができる。無機細骨材を配合する場合、その配合割合は
適宜設定することができるが、消石灰100重量部に対
して5〜100重量部、好ましくは10〜50重量部、
より好ましくは20〜30重量部の範囲を例示すること
ができる。
Examples of the inorganic fine aggregate include silica sand, cold water sand, mica, ceramic sand, glass beads, perlite, vermiculite and the like. Although the particle size is not particularly limited, a range of 60 to 130 mesh or 80 to 100 mesh can be exemplified. When blending the inorganic fine aggregate, the blending ratio can be set as appropriate, 5 to 100 parts by weight, preferably 10 to 50 parts by weight with respect to 100 parts by weight of slaked lime,
More preferably, a range of 20 to 30 parts by weight can be exemplified.

【0029】消泡剤としては、通常塗料や建築用吹き付
け材に配合して用いられるものであれば特に制限され
ず、いずれをも採用することもできる。例えば、オクチ
ルアルコール、グリコール誘導体、シクロヘキサン、シ
リコン、プルロニック系界面活性剤、ポリオキシエチレ
ンアルキルフェニルエーテル等の各種の抑泡剤及び破泡
剤を挙げることができる。これらの配合割合も、適宜選
択でき制限はされないが、通常消石灰100重量部に対
して0.01〜5重量部を範囲、特に0.1〜2重量部
の範囲を例示することができる。
The defoaming agent is not particularly limited as long as it is usually used by being blended into a paint or a building spray material, and any of them can be employed. For example, various foam inhibitors and foam breakers such as octyl alcohol, glycol derivatives, cyclohexane, silicon, pluronic surfactants, and polyoxyethylene alkyl phenyl ether can be mentioned. The mixing ratio of these components can also be appropriately selected and is not limited, but is usually in the range of 0.01 to 5 parts by weight, particularly 0.1 to 2 parts by weight, per 100 parts by weight of slaked lime.

【0030】増粘剤としてはメチルセルロース、ヒドロ
キシエチルセルロース、ヒドロキシプロピルメチルセル
ロース等のセルロース系;サッカロース、グルコースな
どの多糖類;アクリル系;その他、アルミニウムステア
レート、ジンクステアレート、有機ベントナイト、シリ
カゲル、ポリビニルアルコール、アルギン酸ソーダ、ケ
イ酸系、ベントナイト、カゼイン酸ソーダ等を例示する
ことができる。
Examples of the thickener include cellulosics such as methylcellulose, hydroxyethylcellulose and hydroxypropylmethylcellulose; polysaccharides such as saccharose and glucose; acrylics; and others, aluminum stearate, zinc stearate, organic bentonite, silica gel, polyvinyl alcohol, Examples thereof include sodium alginate, silicic acid, bentonite, and sodium caseinate.

【0031】また本発明の塗料組成物には更に珪藻土ま
たはゼオライト(合成ゼオライトを含む)を配合するこ
ともできる。珪藻土は漆喰と同様に有害物質を含まない
自然素材として注目されている素材であり、珪藻土やゼ
オライトを配合することによって塗膜の調湿性や結露防
止性を向上改善したり、断熱性や脱臭効果等の諸機能性
を付与することができる。
The coating composition of the present invention may further contain diatomaceous earth or zeolite (including synthetic zeolite). Diatomaceous earth is attracting attention as a natural material that does not contain harmful substances like stucco.By mixing diatomaceous earth and zeolite, it improves and improves the humidity control and dew condensation prevention of the coating film, and also has heat insulation and deodorizing effects And other functionalities can be provided.

【0032】本発明の塗料組成物は、固形分あたり、そ
れぞれ固形重量換算で、消石灰を30〜80重量%、好
ましくは40〜70重量%、より好ましくは50〜70
重量%;ポリマー成分を3〜55重量%、好ましくは4
〜50重量%、より好ましくは10〜30重量%の割合
で含むことが好ましく、さらに必要に応じて顔料を1〜
15重量%、好ましくは2〜10重量%、より好ましく
は3〜8重量%の割合で含むことが好ましい。これらの
成分は、本発明の塗料組成物の固形分含有量が塗料組成
物100重量%あたり40〜80重量%、好ましくは5
0〜70重量%となるように配合調整される。
The coating composition of the present invention contains slaked lime in an amount of 30 to 80% by weight, preferably 40 to 70% by weight, more preferably 50 to 70% by weight, in terms of solid weight, per solid content.
3% to 55% by weight, preferably 4% by weight;
Preferably, the pigment is contained in a proportion of from 50 to 50% by weight, more preferably from 10 to 30% by weight.
It is preferably contained in a proportion of 15% by weight, preferably 2 to 10% by weight, more preferably 3 to 8% by weight. These components have a solid content of 40 to 80% by weight, preferably 5 to 100% by weight of the coating composition of the present invention.
The composition is adjusted so as to be 0 to 70% by weight.

【0033】本発明の塗料組成物は、従来漆喰壁材にひ
び割れ防止を目的に配合されていた、麻、和紙、しゅ
ろ、木材パルプ、合成繊維及びガラス繊維といった各種
の繊維素材を配合しなくても、ひび割れすることなく靱
性及び成膜性に優れた塗膜が形成できることを1つの特
徴とするものである。
The coating composition of the present invention can be prepared by blending various fiber materials such as hemp, Japanese paper, palm, wood pulp, synthetic fiber and glass fiber, which have been conventionally blended into stucco wall material for the purpose of preventing cracking. However, one of the features is that a coating film excellent in toughness and film forming property can be formed without cracking.

【0034】一般に塗料中の繊維素材の存在は、塗装に
際してスプレーやガンの吐出口が閉塞するという問題や
塗着工程後にコテ押さえを必要とするといった施工性
(塗装作業性)の悪さ、塗装後に塗膜表面が毛羽立った
り塗布面が不均一となる外観上並びに成膜性の問題、及
び塗膜が可燃性(易燃性)となるといった機能の低下を
伴う傾向があり望ましくない。よって、低塗布量で美観
並びに成膜性に優れた薄塗膜を形成するためには、繊維
素材を含まない塗料組成物であることが好ましい。しか
しながら、塗装作業性、成膜性並びに塗膜の外観等に影
響を与えない範囲であれば、本発明はその塗料組成物中
に繊維素材を含むことをなんら制限するものではない。
In general, the presence of the fiber material in the paint is caused by the problem that the discharge port of the spray or the gun is blocked at the time of painting, poor workability (painting workability) such as necessity of ironing down after the painting process, and This is undesirable because the coating film surface tends to be fuzzy or the coating surface becomes non-uniform, and there is a problem with the film forming property, and the coating film tends to be flammable (flammable) with a reduced function. Therefore, in order to form a thin coating film having excellent appearance and film-forming properties with a low coating amount, a coating composition containing no fiber material is preferable. However, the present invention does not restrict inclusion of a fiber material in the coating composition as long as it does not affect the coating workability, the film forming property, the appearance of the coating film, and the like.

【0035】本発明の塗料組成物は、上記各成分と水を
混合して塗料の常套方法、例えば塗料調合用機器(ミキ
サー、シェーカー、ミル、ニーダーなど)を用いて混合
することにより、消石灰、ポリマー成分及び顔料等を水
中に安定に分散させて、スプレー液、スラリー、または
パテ等の各種形態の塗料として調製することができる。
混合は通常20〜95℃で行うことができる。
The coating composition of the present invention is prepared by mixing the above components with water and mixing with a conventional method of coating, for example, using a coating preparation equipment (mixer, shaker, mill, kneader, etc.) to obtain slaked lime, A polymer component, a pigment, and the like can be stably dispersed in water to prepare a paint in various forms such as a spray liquid, a slurry, and a putty.
Mixing can be usually performed at 20 to 95 ° C.

【0036】この際、塗料組成物は、例えばスプレー塗
り(エアスプレー、エアレススプレーなど)、刷毛塗
り、ローラー塗り、パテ塗り、コート塗りなどの各種塗
装方法に応じて所望の粘度を有するように調製すること
が好ましく、塗装作業性、レベリング、塗膜外観等を考
慮して好ましい粘度範囲を適宜選択調製することができ
る。通常、常温で100〜60000センチポイズの範
囲となるように調製される。例えば、液状の塗料組成物
の粘度としては、刷毛塗り、ローラー塗りまたはスプレ
ー塗りに適するように常温で300〜3000センチポ
イス、好ましくは500〜2000センチポイズ、より
好ましくは700〜1300センチポイズ、さらに好ま
しくは800〜1000センチポイズの範囲を挙げるこ
とができる。またパテ状の塗料組成物の粘度としては、
制限されないが、常温で20000〜60000センチ
ポイズ、好ましくは30000〜50000センチポイ
ズ、より好ましくは40000〜50000センチポイ
ズの範囲を挙げることができる。
At this time, the coating composition is prepared so as to have a desired viscosity according to various coating methods such as spray coating (air spray, airless spray, etc.), brush coating, roller coating, putty coating and coat coating. Preferably, the viscosity range can be appropriately selected and adjusted in consideration of coating workability, leveling, coating film appearance, and the like. Usually, it is prepared to be in the range of 100 to 60,000 centipoise at room temperature. For example, the viscosity of the liquid coating composition is 300 to 3000 centipoise at room temperature, preferably 500 to 2000 centipoise, more preferably 700 to 1300 centipoise, and still more preferably 800 at room temperature so as to be suitable for brush coating, roller coating or spray coating. A range of 10001000 centipoise can be mentioned. Also, as the viscosity of the putty-like coating composition,
Although not limited, a range of 20,000 to 60,000 centipoise at room temperature, preferably 30,000 to 50,000 centipoise, more preferably 40,000 to 50,000 centipoise can be mentioned.

【0037】本発明の塗料組成物は、各種建築物の天井
や壁(内・外壁)等の下地や基材の塗装、並びに無機基
材や有機基材からなる建材等の各種基材の塗装に使用す
ることができる。また、本発明の塗料組成物は常法に従
って塗装した後に、凹凸模様付けローラーで模様付けを
行ったり、塗膜表面を処理することによってさらに意匠
仕上げを施すこともできる。 (2)塗装物 また、本発明は上記塗料組成物を塗布してなる塗装物を
提供する。
The coating composition of the present invention can be used for coating base materials and base materials such as ceilings and walls (inner and outer walls) of various buildings, and for coating various base materials such as building materials composed of inorganic and organic base materials. Can be used for Further, after the coating composition of the present invention is applied according to a conventional method, it is possible to further apply a design finish by performing patterning with an uneven patterning roller or treating the coating film surface. (2) Painted article The present invention also provides a coated article obtained by applying the above coating composition.

【0038】本発明の塗料組成物を塗布する基材(被塗
物)としては、特に制限されることなく、紙、各種繊維
からなる不織布または織布(繊維質シート)、及び各種
のボード等を挙げることができる。なお、かかる基材は
表面がシーラー処理等の各種処理がなされていてもよ
い。
The substrate (substrate) to which the coating composition of the present invention is applied is not particularly limited, and paper, nonwoven fabric or woven fabric (fibrous sheet) composed of various fibers, various boards, etc. Can be mentioned. In addition, the surface of such a base material may be subjected to various treatments such as a sealer treatment.

【0039】紙としては、和紙、洋紙(上質紙、中質
紙)、クラフト紙、薄葉紙、裏打紙、樹脂含浸紙等、ボ
ール紙、厚紙等のいずれであってもよく、例えば難燃処
理を施した紙であって壁紙の施工に適したもの、例えば
難燃性裏打紙や不燃紙等も包含される。繊維質シートと
しては、例えば天然繊維;ガラス繊維;またはポリプロ
ピレン、アクリル、ナイロン、ポリエステル、ポリアミ
ド、ビニロン等の合成繊維などを構成素材として得られ
る多孔性の織布や不織布、編み物等を挙げることができ
る。なお、上記素材は、1種単独で用いられても、また
2種以上を任意で組み合わせて用いることもできる。ボ
ードとしては、例えば建築用の内装(室内の壁や天井
等)や外装に用いられるボードを広く挙げることができ
る。具体的には、木質板、合板、中密度繊維板、プラス
チック板、セメントモルタル、コンクリート板、PCパ
ネル、ALCパネル、石綿スレート、石膏ボード、パー
ティクルボード、発泡セメントボード、木片セメント
板、ケイ酸カルシウムボードなどを例示することができ
る。好ましくは、石膏ボード、石膏パーティクルボー
ド、木質板、中密度繊維板、プラスチック板等である。
The paper may be any of Japanese paper, Western paper (high quality paper, medium quality paper), kraft paper, tissue paper, backing paper, resin impregnated paper, cardboard, cardboard, etc. Paper that has been applied and is suitable for application of wallpaper, such as flame-retardant backing paper and non-combustible paper, is also included. Examples of the fibrous sheet include a porous woven fabric, a nonwoven fabric, and a knitted fabric obtained by using natural fibers; glass fibers; or synthetic fibers such as polypropylene, acrylic, nylon, polyester, polyamide, and vinylon as constituent materials. it can. The above materials may be used alone or in any combination of two or more. As the board, for example, a board used for an interior (a wall or a ceiling in a room) or an exterior of a building can be widely used. Concretely, wood board, plywood, medium density fiber board, plastic board, cement mortar, concrete board, PC panel, ALC panel, asbestos slate, gypsum board, particle board, foam cement board, wood chip cement board, calcium silicate A board etc. can be illustrated. Preferred are gypsum board, gypsum particle board, wood board, medium density fiber board, plastic board and the like.

【0040】基材への塗料組成物の塗布方法は、特に制
限されず、ロールコーターやフローコーター、ハケやロ
ール等を用いる塗付け方法及びスプレーや各種ガンを用
いた吹きつけ方法を挙げることができる。一例として圧
縮空気を用いたスプレー塗装によれば、例えば、まず適
量の水で適当な粘度に調製した塗料組成物のスプレー液
若しくはスラリーを基材の一面に吹き付ける。この吹き
付けによって、塗料組成物は基材の表面に塗膜を形成し
基材と一体化する。この際、塗料組成物に含まれるポリ
マー成分が消石灰などの成分を強固に結合させるととも
に、塗料組成物を基材表面に抱合させて、塗膜層と基材
を一体化する。これにより層間剥離が防止できる。次い
で、基材に塗布された塗料組成物を乾燥、硬化させる。
かかる方法は、基材に塗料組成物を塗布後、自然乾燥ま
たは通風乾燥に供することにより簡便に行うことができ
る。なお、本発明の塗装物は必要に応じてさらに形成さ
れた塗膜層の表面を凹凸模様付きローラー等で意匠を施
したりヤスリや各種研磨機で研磨ずりして仕上げること
もできる。
The method of applying the coating composition to the substrate is not particularly limited, and examples thereof include a coating method using a roll coater, a flow coater, a brush or a roll, and a spraying method using a spray or various guns. it can. According to spray coating using compressed air as an example, for example, first, a spray liquid or slurry of a coating composition adjusted to an appropriate viscosity with an appropriate amount of water is sprayed on one surface of a substrate. By this spraying, the coating composition forms a coating film on the surface of the substrate and is integrated with the substrate. At this time, the polymer component contained in the coating composition firmly binds components such as slaked lime, and conjugates the coating composition to the surface of the base material to integrate the coating layer with the base material. Thereby, delamination can be prevented. Next, the coating composition applied to the substrate is dried and cured.
Such a method can be easily carried out by applying the coating composition to the substrate and then subjecting it to natural drying or ventilation drying. The coated product of the present invention can be finished by applying a design to the surface of the further formed coating layer with a roller having a concavo-convex pattern or polishing and polishing with a file or various types of polishing machines, if necessary.

【0041】本発明の塗料組成物から形成される塗膜の
厚さは、基材の塗布面が十分に隠蔽被覆される厚さであ
れば特に制限されない。本発明の塗料組成物は、形成さ
れる塗膜の隠蔽力が前述するように500μ以下となる
ように調整することができるものである。よって、膜厚
として500μ以上の厚さ、好ましくは300μ以上、
より好ましくは200μ以上、更に好ましくは100μ
以上の厚さを挙げることができるが、コスト、塗装作業
性及び成膜性、並びに調湿性等といった塗膜の物性や機
能等に鑑みれば、通常0.1〜3mm、好ましくは0.
2〜2mm、より好ましくは0.3〜1.5mm、さら
に好ましくは0.5〜1mmの範囲を例示することがで
きる。
The thickness of the coating film formed from the coating composition of the present invention is not particularly limited as long as the coating surface of the substrate is sufficiently covered and covered. The coating composition of the present invention can be adjusted so that the hiding power of the formed coating film is 500 μ or less as described above. Therefore, as a film thickness of 500μ or more, preferably 300μ or more,
More preferably 200μ or more, further preferably 100μ
Although the above thicknesses can be mentioned, in view of the physical properties and functions of the coating film such as cost, coating workability and film forming property, and humidity control property, it is usually 0.1 to 3 mm, preferably 0.1 to 3 mm.
A range of 2 to 2 mm, more preferably 0.3 to 1.5 mm, and still more preferably 0.5 to 1 mm can be exemplified.

【0042】本発明の塗料組成物から形成される塗膜を
有する塗装物は、調湿性(吸湿性及び放湿性)に優れ、
高い結露防止効果を発揮するとともに、漆喰特有の質感
(色、つや、きめ細かさ等の外観やテクスチャー)を呈
する。またかくして製造される塗装物は、直射日光、斜
光、照明、陰影等の建材が配置される場所の種々の光に
対しても吹きむら、色むら及び艶むら等の不都合を生じ
ず、常に一定の色、艶及びきめを有した外観を呈してい
る。塗装物のかかる性質は、壁材、天井材等の各種建材
に有用である。
A coated article having a coating film formed from the coating composition of the present invention has excellent humidity control properties (moisture absorption and moisture release properties),
While exhibiting a high dew condensation preventing effect, it exhibits a plaster-specific texture (appearance and texture such as color, gloss, and fineness). In addition, the painted product thus produced does not cause inconvenience such as unevenness in color, unevenness in gloss and unevenness in blown light, unevenness in color, and unevenness in various places where building materials are arranged, such as direct sunlight, oblique light, lighting, and shading. With a color, luster and texture. Such properties of painted objects are useful for various building materials such as wall materials and ceiling materials.

【0043】一般にボードやクロスなどの建材の場合、
施工後の建材間の継目や接合部の処理が問題となりやす
い。繊維素材を含まない本発明の塗料組成物を塗布して
調製された塗装物(建材)によれば、壁などに施工後、
建材の継目や接合部の塗膜表面を研磨ずりすることによ
り周囲の塗膜層と殆ど区別できないほどに連続的かつ均
一に仕上げることができる。また繊維素材を含まない本
発明の塗料組成物を塗布して調製された塗装物(建材)
によれば、壁などに施工された後の修繕が簡便にできる
という利点もある。すなわち、施工後に建材に傷や汚れ
が生じた場合、繊維素材を含まない本発明の塗料組成物
を使用してその損傷部だけを部分的に修繕することが可
能である。かかる修繕は、具体的にはまず損傷部を削
り、該部分に周辺塗膜層と同じ組成であって含水率を低
減して粘度を高くした本発明の塗料組成物を充填し、養
生硬化後、必要に応じて表面を研磨ずりすることによっ
て行うことができる。研磨ずりすることによって損傷部
が他周辺領域と区別できないほどに修復修繕することが
可能となる。
In general, for building materials such as boards and cloths,
Treatment of joints and joints between building materials after construction tends to be a problem. According to the coating material (building material) prepared by applying the coating composition of the present invention containing no fiber material, after being applied to a wall or the like,
By polishing and polishing the surface of the coating film at the joints and joints of the building material, it is possible to achieve a continuous and uniform finish almost indistinguishable from the surrounding coating film layer. A painted product (building material) prepared by applying the coating composition of the present invention containing no fiber material
According to this, there is also an advantage that repair after the work is performed on a wall or the like can be easily performed. That is, when the building material is damaged or stained after the construction, it is possible to partially repair only the damaged portion by using the coating composition of the present invention containing no fiber material. Specifically, such repair is performed by first shaving the damaged portion, filling the portion with the coating composition of the present invention having the same composition as the peripheral coating layer but having a reduced water content and increased viscosity, and after curing and curing. The polishing can be performed by polishing the surface as required. By polishing, it becomes possible to repair and repair the damaged portion so that the damaged portion cannot be distinguished from other peripheral regions.

【0044】また、これは建材の施工(内外装の施工)
においても有用である。すなわち、本発明の塗装物(建
材)とくに内外装パネルを壁下地材に釘やビス打ち施工
する場合、釘(ビス)打ちによって形成された建材表面
の釘頭凹部に、上記のように比較的粘度の高い塗料組成
物(パテ)を充填し、また必要であればその上からさら
に塗料組成物(スプレー液、スラリー)を塗布して、養
生硬化し、更に必要に応じて該塗膜表面を研磨ずりする
ことによって、釘打ち部がほとんどわからぬように施工
することが可能となる(図1参照)。これによって、接
着剤による建材の貼着が回避できる。 (3)建築内外装の施工方法 更に本発明は、上記塗料組成物または塗装物(建材)を
用いた建築物内装・外装の施工方法に関する。本発明の
施工方法としては、下記の実施態様を挙げることができ
る。 A.建築下地材の表面に、上記本発明の塗料組成物を塗
布し、乾燥後、必要に応じて塗膜面を研磨ずりすること
を特徴とする塗装方法。 B. (i)建築下地材に本発明の建材を複数連設する工
程、(ii)各建材の接合部に、本発明の塗料組成物を充填
若しくは塗布して乾燥する工程、及び(iv)必要に応じ
て、塗膜面を研磨ずりする工程を含む、建築物内外装の
施工方法。 C.(i)建築下地材に本発明の建材を複数連設する工
程、(ii)必要に応じて、各建材の接合部に本発明の塗料
組成物を充填若しくは塗布する工程、(iii)該接合部を
補強部材で覆う工程、(iv)該補強部材上に本発明の塗料
組成物を塗布して乾燥する工程、及び(v)必要に応じ
て、塗膜面を研磨ずりする工程を含む、建築物内外装の
施工方法。
In addition, this is construction material construction (interior / exterior construction)
It is also useful in That is, when the painted object (building material) of the present invention, in particular, the interior and exterior panels are nailed or screwed on the wall base material, the nail head recesses on the surface of the building material formed by nailing (screw) as described above are relatively small. A high-viscosity coating composition (putty) is filled, and if necessary, a coating composition (spray liquid, slurry) is further applied thereon to cure and cure. By grinding and polishing, the nailing portion can be constructed so that the nailing portion is hardly recognized (see FIG. 1). Thereby, the sticking of the building material with the adhesive can be avoided. (3) Construction method of interior and exterior of building Further, the present invention relates to a construction method of interior and exterior of a building using the coating composition or the painted product (building material). Examples of the construction method of the present invention include the following embodiments. A. A coating method, which comprises applying the coating composition of the present invention to the surface of a building base material, drying the coating composition, and optionally polishing the coating film surface, if necessary. B. (i) a step of connecting a plurality of the building materials of the present invention to the building base material, (ii) a step of filling or applying the coating composition of the present invention to the joint of each building material and drying, and (iv) A method for constructing interior and exterior of buildings, including a step of polishing and polishing the coating film surface as necessary. C. (i) a step of arranging a plurality of building materials of the present invention in a building base material, (ii) a step of filling or applying the coating composition of the present invention to a joint of each building material, if necessary, (iii) the joining. Covering the part with a reinforcing member, (iv) a step of applying the coating composition of the present invention on the reinforcing member and drying, and (v) if necessary, a step of polishing and polishing the coating film surface, Construction method of building interior and exterior.

【0045】本発明の建築内外装の施工方法には、建
築物の内外壁や天井の下地材(内外壁下地材)に直接、上
記本発明の塗料組成物を塗布積層する方法、並びに内
外壁下地材に本発明の建材(クロス、パネル、ボード)
を貼着または配設する方法が含まれる。
The construction method of the interior and exterior of a building according to the present invention includes a method of applying and laminating the above-mentioned coating composition of the present invention directly on a base material (a base material for an inner and outer wall) of an inner and outer wall and a ceiling of a building; Base material of the present invention (cloth, panel, board)
And a method of attaching or arranging them.

【0046】の施工方法は、具体的には、建築物の内
外壁下地材の表面に、直接前記本発明の塗料組成物、好
適には常温での粘度が300〜3000センチポイズ、
好ましくは500〜2000センチポイズ、より好まし
くは700〜1300センチポイズの塗料組成物を塗布
して、固化するまで乾燥し、次いで必要に応じて内外壁
下地材上に積層された塗膜層の表面を研磨ずりすること
によって、行うことができる。
Specifically, the coating method of the present invention is to apply the coating composition of the present invention directly to the surface of the base material for the inner and outer walls of a building, preferably having a viscosity of 300 to 3000 centipoise at room temperature.
A coating composition of preferably 500 to 2000 centipoise, more preferably 700 to 1300 centipoise is applied, dried until solidified, and then, if necessary, the surface of the coating layer laminated on the inner and outer wall base material is polished. It can be done by shearing.

【0047】また、の施工方法は、建築物の内外壁下
地材もしくは下地材に設けられた内外壁枠や下桟等に前
記本発明の塗装物(クロス、パネル、ボードなどの建
材)を、各側端面同士を当接して配置する工程、各建材
の接合部の表面領域に本発明の塗料組成物、好適には常
温での粘度が300〜3000センチポイズ、好ましく
は500〜2000センチポイズ、より好ましくは70
0〜1300センチポイズの塗料組成物を塗布して固化
するまで乾燥し、次いで必要に応じて当該塗膜層領域の
表面を研磨ずりすることによって行うことができる。
Further, the construction method of the present invention is characterized in that the coating material of the present invention (building material such as cloth, panel, board, etc.) is applied to the inner and outer wall base material of the building or the inner and outer wall frames and lower crossbars provided on the base material. A step of abutting and arranging each side end face, a coating composition of the present invention in a surface region of a joint portion of each building material, suitably having a viscosity at room temperature of 300 to 3000 centipoise, preferably 500 to 2000 centipoise, more preferably Is 70
The coating can be carried out by applying a coating composition of 0 to 1300 centipoise, drying until solidified, and then, if necessary, polishing the surface of the coating layer region.

【0048】建材として内外装パネルを用いる場合、各
パネルの連設態様は特に制限されないが、一例として図
2に示す連設方法を挙げることができる。具体的には、
垂直な側面を有するパネルの該側面同士を当接して連設
することにより平坦なパネル面を形成する突付け張り法
(図2(a))、少なくとも表面側に面取り斜面を有す
る内外装パネルを各々その側面同士を当接して連設し
て、該連設部においてV字状の溝を有するパネル面を形
成する突付けV形みぞ張り法(図2(b))、辺部がお
互いに相じゃくり、又は相じゃくりざね又は本ざね等の
仕口を形成してなる内外装パネルを各々その側面同士を
当接して連設して、該連設部において角溝を有するパネ
ル面を形成する突付け張りもしくは目透かし張り法(図
2(c))を例示できる。
When the interior and exterior panels are used as a building material, there is no particular limitation on the manner in which the panels are connected, but an example is the connection method shown in FIG. In particular,
A bumping method (FIG. 2 (a)) for forming a flat panel surface by abutting the side surfaces of a panel having vertical side surfaces to form a continuous panel surface (FIG. 2 (a)). A butt V-groove method (FIG. 2B) in which the side surfaces are abutted and connected to form a panel surface having a V-shaped groove in the connected portion (FIG. 2B), The interior and exterior panels each forming a connection such as phase-locking or phase-locking or main-linking are connected to each other with their side surfaces in contact with each other, and a panel surface having a square groove in the connecting portion is formed. An example of a butt or eye-opening method (FIG. 2 (c)) is shown.

【0049】図2(b)及び(c)のようにパネルの接
合部分に溝が形成される場合は、上記塗料組成物の塗布
に先立って接合部の該溝部に塗布した塗料組成物と同じ
組成の粘度の高い(低含水率)塗料組成物、好適には常
温で20000〜60000センチポイズ、好ましくは
30000〜50000センチポイズ、より好ましくは
40000〜50000センチポイズの粘度を有する塗
料組成物をシール材として充填することが好ましい。ま
た、塗料組成物の塗布に先立って、パネル間の接合部を
補強部材で被覆することもできる(図3、図4)。
When a groove is formed at the joint portion of the panel as shown in FIGS. 2B and 2C, the same as the coating composition applied to the groove portion of the joint before the application of the coating composition. Filling as a sealing material a coating composition having a high viscosity (low water content), preferably having a viscosity of 20,000 to 60,000 centipoise at room temperature, preferably 30,000 to 50,000 centipoise, more preferably 40,000 to 50,000 centipoise. Is preferred. Prior to the application of the coating composition, the joint between the panels can be covered with a reinforcing member (FIGS. 3 and 4).

【0050】補強部材としては、織布、不織布、セラミ
ックペーパー、合成紙、メッシュ、寒冷紗などのテープ
状部材を例示することができ、これらはそのまま、ある
いはこれに目止め塗料、樹脂などを塗布して、あるいは
フィルムをラミネートして使用することができる(図
3)。また、補強部材として、断面略T字型若しくは略
エ字型のプラスチック製もしくは金属製のジョイナーを
用いることもできる(図4)。
Examples of the reinforcing member include woven fabric, non-woven fabric, ceramic paper, synthetic paper, mesh, and tape-shaped members such as cold gauze. These can be used as they are or by applying a filling paint, resin, or the like to them. Or laminated film (FIG. 3). Further, a plastic or metal joiner having a substantially T-shaped or substantially E-shaped cross section can be used as the reinforcing member (FIG. 4).

【0051】本発明の施工方法によれば、特に仕上げ工
程における塗装または研磨ずりによって、クロスやパネ
ル等の建材の接合部において、その継目が目立つことな
く、建材表面を実質上均一乃至連続した綺麗な状態にす
ることができ、美観の良好な内外装を施すことが可能と
なる。 (4)建築内外装の修復方法 また本発明は、上記建材または塗料組成物を用いた建築
物内装・外装の施工面の修復方法に関する。かかる修復
・修繕方法の実施態様としては下記のものを挙げること
ができる。
According to the construction method of the present invention, especially at the joint of building materials such as cloths and panels, the joints are not conspicuous and the surface of the building materials is substantially uniform or continuous by the coating or polishing shearing in the finishing step. It is possible to provide interior and exterior with good appearance. (4) Method of Restoring Building Interior / Exterior The present invention also relates to a method of restoring a construction surface of a building interior / exterior using the above-mentioned building material or coating composition. Embodiments of such a repair / repair method include the following.

【0052】消石灰、ポリマー成分及び水を含有し繊維
素材を含まない本発明の塗料組成物を塗布して形成され
る塗膜層を表面に有する壁面の損傷部を修復する方法で
あって、(i) 必要であれば該損傷部の塗膜層を削りとる
工程、(ii) 壁面損傷部に本発明の塗料組成物を充填若
しくは塗布して乾燥する工程、及び(iii)必要に応じ
て、当該塗膜面を研磨ずりする工程を含む、建築物内外
装壁面の修復方法。
A method for repairing a damaged part of a wall surface having a coating layer formed by applying a coating composition of the present invention containing slaked lime, a polymer component and water and not containing a fibrous material, comprising: i) the step of shaving off the coating layer of the damaged part if necessary, (ii) the step of filling or applying the coating composition of the present invention to the damaged wall part and drying, and (iii) if necessary, A method for repairing a building interior / exterior wall surface, including a step of polishing and polishing the coating film surface.

【0053】[0053]

【発明の効果】本発明の塗料組成物は、JIS 5663-1995
に規定される合成樹脂エマルションペイントの少なくと
も2種(屋内用ペイント)の品質を備える、消石灰を主
成分とする一液型塗料である。従って、事前に工場など
で1液に調合したものを容器に充填して提供できるた
め、現場での調合の手間を省くことができ、また塗装後
残ったものは再び容器に戻して貯蔵できる利点を有する
ものである。また本発明の塗料組成物は、主に消石灰と
いう自然素材から調製されるものであるため、「化学物
質過敏症」や「シックハウス症候群」等が問題となって
いる今日において人に優しい屋内塗料として有用であ
る。
According to the present invention, the coating composition of the present invention is JIS 5663-1995
Is a one-pack type paint having slaked lime as a main component and having at least two types of synthetic resin emulsion paints (indoor paints) specified in (1). Therefore, since it is possible to fill a container with a mixture prepared in one liquid at a factory or the like in advance, it is possible to save the trouble of preparation at the site and to save the remaining material after coating in the container again. It has. In addition, since the coating composition of the present invention is prepared mainly from a natural material called slaked lime, it is used as a human-friendly indoor coating today in which `` chemical sensitivity '' or `` sick house syndrome '' has become a problem. Useful.

【0054】また本発明の塗料組成物は、水性塗料であ
りながら、消石灰を含有することによって、調湿性及び
結露防止性といった機能を発揮する。このため、マンシ
ョン等のセメント張り内壁や高湿度となる押入の塗料若
しくは建材用塗料として極めて有用である。また、特に
酸化チタンを顔料として含む本発明の塗料組成物は、調
湿性を損なうことなく、低塗布量で500μ以下、より
好ましくは200μ以下といった優れた隠蔽力を有し、
しかも成膜性(歩留まり、耐ひび割れ性、可撓性、外観
性)に優れているため、低コストで調湿性等の有用な機
能を有する薄塗膜を形成することができる。また、本発
明の塗料組成物は、従来消石灰を主成分とする漆喰には
必須であったスサなどの繊維素材を配合しなくても、成
膜性(歩留まり、耐ひび割れ性、可撓性、靱性)に優れ
ており、これによってさらに塗装作業の簡便化を図るこ
とができるものである。
The coating composition of the present invention, even though it is an aqueous coating, exhibits functions such as humidity control and dew condensation prevention by containing slaked lime. For this reason, it is extremely useful as a cement-coated inner wall of an apartment or the like, or as a paint for push-in or a paint for a building material which becomes high in humidity. In addition, the coating composition of the present invention particularly containing titanium oxide as a pigment has excellent hiding power of 500 μm or less, more preferably 200 μm or less at a low coating amount without impairing humidity control properties,
Moreover, since it has excellent film-forming properties (yield, crack resistance, flexibility, and appearance), a thin coating film having useful functions such as humidity control can be formed at low cost. In addition, the coating composition of the present invention can be used for film formation (yield, crack resistance, flexibility, Toughness), which can further simplify the painting operation.

【0055】従って、本発明の塗料組成物は、低コスト
性、施工の簡便性、美観性、機能性等の点からきわめて
商品価値の高い塗料組成物である。また本発明の塗料組
成物は、クロス間またはパネル間の継目の隠蔽処理にも
好適に使用でき、また薄塗膜化が可能であることから内
外装壁面の修復・修繕にも有用であり、この点からも新
規施工並びにリフォーム施工にも幅広く使用できる商品
価値の高い塗料組成物である。
Therefore, the coating composition of the present invention is a coating composition having a very high commercial value from the viewpoints of low cost, easiness of construction, aesthetics, and functionality. In addition, the coating composition of the present invention can be suitably used for concealing a seam between cloths or between panels, and is also useful for repairing and repairing interior and exterior wall surfaces since a thin film can be formed. From this point as well, it is a paint composition with high commercial value that can be widely used for new construction and renovation construction.

【0056】[0056]

【実施例】以下、本発明の内容を以下の実施例を用いて
具体的に説明する。ただし、これらの実施例は本発明の
一態様にすぎず、本発明はこれらの例に何ら限定される
ものではない。実施例1 消石灰 40 (100 %) アクリル樹脂エマルジョン 32 ( 40 %) (ポリトロンA-1450、旭化成) 酸化チタン(EP-498、大日精化) 5 (12.5%) 増粘剤(SP-600、ダイセル化学) 0.3 消泡剤(KM-70、新越化学) 0.3 防腐剤(PL-600、東京ファインケミカル・大和化学) 0.9 水 残 部 全 量 100.0重量部 上記成分を塗料調合用ミキサーに入れて撹拌することに
より固形分及び樹脂成分を水に安定に分散させて、本発
明の一液型水性塗料組成物(粘度800cps(25℃)B型粘
度計;固形分含有率62.5%)を調製した。尚、上記アク
リル樹脂エマルジョン(アクリル−スチレン系)は固形
分を50重量%の割合で含むものを使用した。上記処方
において、かっこ内の数値は消石灰を100重量%とし
た場合のアクリル樹脂エマルジョン(固形分)及び酸化
チタンの配合割合を示すものである。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be specifically described below with reference to the following embodiments. However, these examples are only one embodiment of the present invention, and the present invention is not limited to these examples. Example 1 Slaked lime 40 (100%) Acrylic resin emulsion 32 (40%) (Polytron A-1450, Asahi Kasei) Titanium oxide (EP-498, Dainichi Seika) 5 (12.5%) Thickener (SP-600, Daicel) Chemical) 0.3 Antifoaming agent (KM-70, Shin-Etsu Chemical) 0.3 Preservative (PL-600, Tokyo Fine Chemicals / Yamato Chemical) 0.9 Water Residual total amount 100.0 parts by weight Paint the above components The solid content and the resin component are stably dispersed in water by stirring in a mixing mixer, and the one-component aqueous coating composition of the present invention (viscosity 800 cps (25 ° C.) B-type viscometer; solid content content 62.5%). The acrylic resin emulsion (acrylic-styrene type) used had a solid content of 50% by weight. In the above formula, the values in parentheses indicate the mixing ratio of the acrylic resin emulsion (solid content) and titanium oxide when slaked lime is 100% by weight.

【0057】 実施例2 消石灰 40 (100 %) アクリル樹脂エマルジョン 16 ( 20 %) (ポリトロンA-1450、旭化成) 酸化チタン(EP-498、大日精化) 5 (12.5%) 増粘剤(SP-600、ダイセル化学) 0.3 消泡剤(KM-70、新越化学) 0.3 防腐剤(PL-600、東京ファインケミカル・大和化学) 0.9 水 残 部 全 量 100.0重量部 上記成分を塗料用ミキサーに入れて撹拌することにより
固形分及び樹脂成分を水に安定に分散させて、本発明の
一液型塗料組成物(粘度800cps(25℃)B型粘度計;固
形分含有率54.5%)を調製した。尚、上記アクリル樹脂
エマルジョンは固形分を50重量%の割合で含むものを
使用した。
Example 2 Slaked lime 40 (100%) Acrylic resin emulsion 16 (20%) (Polytron A-1450, Asahi Kasei) Titanium oxide (EP-498, Dainichi Seika) 5 (12.5%) Thickener (SP- 600, Daicel Chemical) 0.3 Antifoaming agent (KM-70, Shin-Etsu Chemical) 0.3 Preservative (PL-600, Tokyo Fine Chemicals / Daiwa Chemical) 0.9 Water Residual Total 100.0 parts by weight The solid component and the resin component are stably dispersed in water by stirring the components in a paint mixer, and the one-component coating composition of the present invention (viscosity 800 cps (25 ° C.) B-type viscometer; 54.5%). The acrylic resin emulsion used contained a solid content of 50% by weight.

【0058】実施例3 消石灰100重量部に対して、アクリルエマルジョン系
樹脂(ポリトロンA−1450、旭化成社製)を40重
量部(固形換算)の割合で含む組成物に水を入れて混練
りして、塗料組成物(粘度800cps(25℃)B型粘度計)
を調製した。
Example 3 Water was added to a composition containing 40 parts by weight (solid basis) of an acrylic emulsion resin (Polytron A-1450, manufactured by Asahi Kasei Corporation) with respect to 100 parts by weight of slaked lime and kneaded. And paint composition (viscosity 800cps (25 ℃) B-type viscometer)
Was prepared.

【0059】実施例4 消石灰100重量部に対して、アクリルエマルジョン系
樹脂(ポリトロンA−1450、旭化成社製)を40重
量部(固形換算)及び酸化チタンを12重量部の割合で
含む組成物に水を入れて混練りして、塗料組成物(粘度
800cps(25℃)B型粘度計)を調製した。
Example 4 A composition containing 40 parts by weight of acrylic emulsion resin (Polytron A-1450, manufactured by Asahi Kasei Corporation) and 12 parts by weight of titanium oxide was added to 100 parts by weight of slaked lime. Add water, knead, paint composition (viscosity
800 cps (25 ° C.) type B viscometer).

【0060】実施例5 消石灰100重量部に対して、アクリル樹脂エマルジョ
ン(ポリトロンA−1450、旭化成製)33重量部
(固形換算)からなる組成物に水を入れて塗料用ミキサ
ーで固形分が安定に分散するように撹拌して、本発明の
塗料組成物(粘度800センチポイズ、25℃)を調製
した。これをエアレススプレー用ガンに入れて、難燃性
裏打紙(坪量40g/m2)の一面に満遍なく吹き付
け、自然乾燥によって塗膜を形成した。固化後、紙やす
りで紙表面に形成された塗膜層の表面を研磨紙ずりし
て、厚さ1mm程度の塗膜層を有する建築用内装材(ク
ロス)を調製した。
Example 5 Water was added to a composition composed of 33 parts by weight (in terms of solids) of an acrylic resin emulsion (Polytron A-1450, manufactured by Asahi Kasei) with respect to 100 parts by weight of slaked lime, and the solid content was stabilized with a paint mixer. To prepare a coating composition of the present invention (viscosity: 800 centipoise, 25 ° C.). This was put into an airless spray gun, sprayed evenly on one side of a flame-retardant backing paper (basis weight 40 g / m 2 ), and a coating film was formed by natural drying. After solidification, the surface of the coating layer formed on the paper surface was sanded with sandpaper to prepare a building interior material (cloth) having a coating layer having a thickness of about 1 mm.

【0061】得られた内装クロスは、直射日光、斜光、
照明及び陰影など、内装材が施工される可能性ある様々
の光に対して、いずれも吹きムラ、色ムラ及び艶ムラが
見られず、均一な外観を有していた。該内装シートに形
成された塗膜は隠蔽力、成膜性、可撓性並びに靱性に優
れており、シートを折り曲げてもひび割れを生じなかっ
た。さらに、室内の壁に施工後も、ひび割れすることな
く十分な耐久性を備えていた。また、該内装シートは、
吸湿性及び放湿性に優れており湿度80%の環境下にお
いても結露の発生を有意に防止することができた。さら
に、該シートの塗膜層の表面に直火を近づけても発火せ
ず、また煙も発生せず、耐燃性に優れていることが確認
された。
The obtained interior cloth was obtained by direct sunlight, oblique light,
With respect to various lights, such as lighting and shading, on which the interior material may be applied, none of the blowing unevenness, the color unevenness, and the gloss unevenness were observed, and all had a uniform appearance. The coating film formed on the interior sheet was excellent in hiding power, film formability, flexibility and toughness, and did not crack even when the sheet was folded. Furthermore, even after being installed on the indoor wall, it had sufficient durability without cracking. In addition, the interior sheet,
It was excellent in hygroscopicity and dehumidifying properties, and was able to significantly prevent the occurrence of dew condensation even in an environment with a humidity of 80%. Further, it was confirmed that even when an open flame was brought close to the surface of the coating layer of the sheet, it did not ignite, did not generate smoke, and had excellent flame resistance.

【0062】実施例6 消石灰100重量部に対して、アクリル樹脂エマルジョ
ン(ポリトロンA−1450、旭化成製)30重量部
(固形換算)、及び増粘材からなる組成物に水を入れて
塗料用ミキサーで固形分が安定に分散するように撹拌し
て、本発明の塗料組成物(粘度700センチポイズ、2
5℃)を調製した。これをエアレススプレーに入れて、
石膏ボード(タテ20cm×ヨコ20cm×厚さ1c
m、吉野石膏製)の一面に満遍なく吹き付け、通風乾燥
によって塗膜を形成した。固化後、紙鑢で紙表面に形成
された塗膜層の表面を研磨紙ずりして、厚さ2.5mm
の塗膜層を有する建築用内装材(パネル)を調製した。
得られた内装シートは、直射日光、斜光、照明及び陰影
など、内装材が施工される可能性ある様々の光に対し
て、いずれも吹きムラ、色ムラ及び艶ムラが見られず、
均一な外観を有していた。該内装パネルは、吸湿性及び
放湿性に優れており湿度80%の環境下においても結露
の発生を有意に防止することができた。さらに、該ボー
ドの塗膜層の表面に直火を近づけても発火せず、また煙
も発生せず、耐燃性に優れていることが確認された。
Example 6 A paint mixer was prepared by adding 30 parts by weight (in terms of solids) of an acrylic resin emulsion (Polytron A-1450, manufactured by Asahi Kasei Corporation) to 100 parts by weight of slaked lime, and adding water to a composition comprising a thickener. And stir so that the solid content is stably dispersed.
5 ° C.). Put this in an airless spray,
Gypsum board (vertical 20cm x horizontal 20cm x thickness 1c
m, manufactured by Yoshino Gypsum Co., Ltd.) and spray dried evenly to form a coating film. After solidification, the surface of the coating layer formed on the paper surface was polished with a paper file to a thickness of 2.5 mm.
Architectural interior materials (panels) having a coating layer of
The resulting interior sheet, for direct light, oblique light, lighting and shading, etc., for various lights where the interior material may be installed, none of the blowing unevenness, color unevenness and gloss unevenness are seen,
It had a uniform appearance. The interior panel was excellent in hygroscopicity and hygroscopicity, and was able to significantly prevent the occurrence of dew condensation even in an environment with a humidity of 80%. Furthermore, even if a direct flame was brought close to the surface of the coating layer of the board, it did not ignite or generate smoke, and it was confirmed that the board had excellent flame resistance.

【0063】次いで得られた内装パネルを、室内の内装
壁材として、壁下地材に塗膜層を表にして釘で打付施工
した。釘頭が被覆層の内部に陥没するまで打ち付け、そ
れによって形成された釘頭凹部に、消石灰100重量部
に対して、アクリルエマルジョン系樹脂(ポリトロンA
−1450、旭化成製)30重量部(固形換算)、及び
増粘材からなる塗料組成物に水を入れてやや固めに混練
りしたパテ状塗料(粘度40000センチポイズ)を挿
入・充填し、固化後、釘打ち部及びその周辺部を紙鑢で
研磨して仕上げた。壁材として施工された内装材は、釘
打部(補修部)表面が紙やすりによる研磨ずりによって
毛羽立つこともなく、周辺部と区別できないほど一体化
してきれいに仕上がった。また、該内装パネルに塗布形
成された塗膜は、室内の壁に施工後も、ひび割れするこ
となく十分な靱性並びに可撓性を備えていた。
Next, the obtained interior panel was nailed with a coating layer on a wall base material with a nail as an interior wall material in the room. The nail head is nailed until it sinks into the inside of the coating layer. The nail head recess formed thereby is coated with 100 parts by weight of slaked lime and an acrylic emulsion resin (Polytron A).
-1450, manufactured by Asahi Kasei) 30 parts by weight (in terms of solids), and a putty-like paint (viscosity of 40,000 centipoise), which is slightly kneaded with water in a paint composition comprising a thickener, is inserted and filled, and then solidified. The nailed part and its surroundings were polished and finished with a paper file. The interior material constructed as a wall material did not become fluffy due to the sanding of the nailing part (repair part) due to sanding by sandpaper, and was unified so as to be indistinguishable from the peripheral part and was finished neatly. Moreover, the coating film formed on the interior panel had sufficient toughness and flexibility without cracking even after being applied to the indoor wall.

【0064】実験例1 実施例1で調製した塗料組成物をエアレススプレーに入
れて、石膏ボード(タテ40cm×ヨコ25cm×厚さ
5mm)の一面に満遍なく吹き付け、通風乾燥によって
固化させて、塗膜厚0.6mmのパネルを作成した。
EXPERIMENTAL EXAMPLE 1 The coating composition prepared in Example 1 was put into an airless spray, sprayed evenly on one side of a gypsum board (length 40 cm × width 25 cm × thickness 5 mm) and solidified by ventilation drying to form a coating film. A panel having a thickness of 0.6 mm was prepared.

【0065】かかるパネルを6検体用いて調湿試験を行
った。なお、塗膜層の調湿性を正当に評価するためにパ
ネルの側面及び裏面(塗料非塗布面)には防湿性シール
を施して水蒸気が透過しないようにした。具体的には、
本発明の建材パネルを相対湿度65%温度20℃の環境
下に放置して、水分吸収量がほぼ平衡に達する48時間
後に秤量し、次いで被検体を相対湿度98%温度20℃
の環境下に移して、再び水分吸収率がほぼ平衡に達する
48時間後に秤量して単位表面積(1m2)あたりのパ
ネルの水分吸収量を求めた。次に吸湿試験後の検体を同
様に相対湿度65%温度20℃の環境下に移して、24
時間放置した後に秤量して単位表面積(1m2)あたり
のパネルの水分吸収量を求めた。そして、これらの実験
における水分吸収量の差をそれぞれ吸湿量及び放湿量と
して評価した。
A humidity control test was performed using six samples of such panels. In order to properly evaluate the humidity control of the coating film layer, a moisture-proof seal was applied to the side and back surfaces of the panel (the surface on which no paint was applied) to prevent the passage of water vapor. In particular,
The building material panel of the present invention was left in an environment at a relative humidity of 65% and a temperature of 20 ° C., weighed 48 hours after the amount of water absorbed almost reached equilibrium, and then the subject was weighed at a relative humidity of 98% and a temperature of 20 ° C.
Was weighed 48 hours after the water absorption rate reached substantially equilibrium again, to determine the water absorption of the panel per unit surface area (1 m 2 ). Next, the sample after the moisture absorption test was similarly transferred to an environment of a relative humidity of 65% and a temperature of 20 ° C.
After standing for a period of time, the weight was measured to determine the amount of water absorbed by the panel per unit surface area (1 m 2 ). Then, the difference between the water absorption amounts in these experiments was evaluated as the moisture absorption amount and the moisture release amount, respectively.

【0066】結果を比較品として用いた塩化ビニル製の
壁紙(タテ40cm×ヨコ25cm)の調湿効果と併せ
て、表1に示す。
The results are shown in Table 1 together with the humidity control effect of a vinyl chloride wallpaper (length 40 cm × width 25 cm) used as a comparative product.

【0067】[0067]

【表1】 [Table 1]

【0068】なお、表中の表示は下記のことを意味す
る。 20℃65%重量(g/m2)*1:20℃65%RH 48時間放置後の1m2
あたりの重量 20℃65%重量(g/m2)*2:20℃65%RH 24時間放置後の1m2
あたりの重量 20℃98%重量(g/m2) :20℃98%RH 48時間放置後の1m2
たりの重量 吸湿性 (g/m2) :20℃98%重量 − 20℃65%重量*1 放湿性 (g/m2) :20℃98%重量 − 20℃65%重量*2 このことから、本発明の塗料組成物を塗布して形成され
る塗膜には優れた調湿機能(吸湿性、放出性)があるこ
とが確認された。
The indications in the table mean the following. 20 ° C 65% weight (g / m 2 ) * 1 : 1m 2 after standing at 20 ° C 65% RH for 48 hours
Weight per unit 20 ° C 65% weight (g / m 2 ) * 2 : 1m 2 after standing at 20 ° C 65% RH for 24 hours
Weight 20 ° C. 98% by weight per (g / m 2): 20 ℃ 98% RH 48 hours 1 m 2 per weight hygroscopic after standing (g / m 2): 20 ℃ 98% by weight - 20 ° C. 65% by weight * 1 Moisture release (g / m 2 ): 98% by weight at 20 ° C-65% by weight at 20 ° C * 2 This indicates that the coating formed by applying the coating composition of the present invention has an excellent humidity control function. (Hygroscopicity and release) were confirmed.

【0069】実験例2 実施例1及び2で調製した塗料組成物(塗料1及び2)
について、日本工業規格JIS K 5400に規定されている方
法に基づいて、(1)容器の中での状態(JIS K 5400の4.1
(2))、(2)塗装作業性(JIS K 5400の6.1)、(3)低温安
定性(JIS K 5400の5.1)について調べ、さらに形成さ
れた塗膜について、(4)乾燥時間(JIS K5400の6.5)、
(5)塗膜の外観(JIS K 5400の7.1)、(6)隠蔽率(JIS K
5400の7.2)、(7)耐アルカリ性(JIS K 5400の8.2
1)、(8)耐洗浄性(JIS K 5400の8.11)、(9)耐水性(J
IS K 5400の8.19)及び(10)促進耐候性(JIS K 5400の
9.8.1)の各項目について調べた。なお各項目の試験方
法並びに評価は、全てJIS K5663-1995に規定されている
方法に準拠した。
Experimental Example 2 The coating compositions prepared in Examples 1 and 2 (Coatings 1 and 2)
Based on the method specified in Japanese Industrial Standards JIS K 5400, (1) state in the container (JIS K 5400 4.1
(2)), (2) Paint workability (6.1 of JIS K 5400), (3) Low temperature stability (5.1 of JIS K 5400), and check the formed coating film for (4) Drying time (JIS 6.5 of K5400),
(5) Appearance of coating film (JIS K 5400 7.1), (6) Hiding ratio (JIS K 5400
7.2 of 5400), (7) Alkali resistance (8.2 of JIS K 5400
1), (8) Washing resistance (8.11 of JIS K 5400), (9) Water resistance (J
8.19 of IS K 5400) and (10) Accelerated weather resistance (JIS K 5400
9.8.1). The test method and evaluation of each item were all based on the method specified in JIS K5663-1995.

【0070】(1) 容器の中での状態(JIS K5663-1995の
5.3) 塗料を容器(金属製内面コート缶)に充填し、室温で2
4時間以上静置した後、容器の蓋を開け棒で中身をかき
混ぜて塗料の状態を調べた。かき混ぜたときに、堅い塊
がなくて中身全体が一様になる場合を「良好」、塊はな
いが一様になりにくい場合を「普通」、塊を認める場合
を「不良」とした。
(1) State in a container (JIS K5663-1995)
5.3) Fill the container (metal inner coated can) with paint,
After leaving still for 4 hours or more, the lid of the container was opened and the contents were stirred with a stick to check the state of the paint. When the mixture was stirred, there was no hard lump and the whole contents were uniform. "Good", when there was no lump but it was difficult to make it uniform, "normal", and when the lump was recognized was "poor".

【0071】(2) 塗装作業性(JIS K5663-1995の5.4) 試験板(フレキシブル板、500×200×3mm)の平滑な面
に塗料をそれぞれ刷毛で一様に塗り(1回目、塗布量:1
0〜13mml/1枚)、6時間おいてから2回目の刷毛塗り
(塗布量:9〜11mml/1枚)を行い、2回目を塗る際の
刷毛運びの困難性の有無から塗装作業性を評価した。2
回目を塗る際の刷毛運びが困難でない場合を「2回塗り
で塗装作業に支障がない」として評価を「良好」とし、
刷毛運びの困難性に応じて順次「普通」、「不良」とし
た。
(2) Coating workability (JIS K5663-1995, 5.4) Paint was uniformly applied to the smooth surface of a test plate (flexible plate, 500 × 200 × 3 mm) with a brush (first time, amount of application: 1
0 to 13 mml / sheet), and after 6 hours, a second brush coating (coating amount: 9 to 11 mml / sheet) is performed, and the coating workability is determined based on the difficulty of carrying the brush when applying the second time. evaluated. 2
When it is not difficult to carry the brush when applying the second time, the evaluation is "good" as "two coats do not hinder the painting work",
“Normal” and “Poor” were sequentially determined according to the difficulty of brush transfer.

【0072】(3) 低温安定性(JIS K5663-1995の5.5) 塗料を容器(金属製内面コート缶)にほぼ一杯に満たし
て密閉し、温度−5±2℃の低温恒温器中に18時間収
納した後、取り出して室温下に6時間放置する操作を3
回繰り返した。次いで、容器の蓋を開けて中の塗料を棒
でかき混ぜて一様になるかどうかを調べた。また、前述
する(2)の方法に準じて塗装作業性を調べた。具体的
には、低温恒温器に入れる前の塗料で1回塗りし、低温
安定性を調べた処理塗料を用いて2回塗りを行い、2回
目の刷毛運びの困難性を評価した。さらに、上記塗装作
業性試験の終わった試験板を24時間乾燥して、形成され
た塗膜の外観を評価した。塗料が容易に一様となり、塗
装作業性と塗膜の外観に異常がないとき「−5℃に冷や
したときに変質しない」として評価を「良好」とし、順
次不良の程度に応じて「普通」及び「不良」とした。
(3) Low-temperature stability (5.5 of JIS K5663-1995) A container (metal inner coated can) is filled almost completely with paint and sealed, and kept in a low-temperature incubator at a temperature of -5 ± 2 ° C. for 18 hours. After storing, remove and leave at room temperature for 6 hours.
Repeated times. Next, the lid of the container was opened, and the paint in the container was stirred with a stick to check whether the paint became uniform. Further, the coating workability was examined according to the method (2) described above. Specifically, it was applied once with a paint before being put into a low-temperature constant temperature oven, applied twice using a treated paint whose low-temperature stability was checked, and evaluated for difficulty in carrying a second brush. Furthermore, the test plate after the above-mentioned coating workability test was dried for 24 hours, and the appearance of the formed coating film was evaluated. When the paint was easily uniform and there was no abnormality in the coating workability and appearance of the coating film, the evaluation was "good" as "no deterioration when cooled to -5 ° C". And "Poor".

【0073】(4) 乾燥時間(JIS K5663-1995の5.6) 塗料をガラス板(200×100×2mm)の片面に隙間100μ
mのB形フィルムアプリケータを用いて塗布し、これを
20±1℃、湿度65±5%の恒温恒湿室に入れて、塗
膜が半硬化状態(塗面の中央を指先で静かに軽くこすっ
て塗面に擦り傷がつかない状態)まで乾燥する時間を測
定した。
(4) Drying time (5.6 of JIS K5663-1995) Paint was applied to one side of a glass plate (200 × 100 × 2 mm) with a clearance of 100 μm.
m using a B-type film applicator, put it in a thermo-hygrostat at 20 ± 1 ° C, 65 ± 5% humidity, and the coating film is in a semi-cured state. The drying time was measured until the coated surface was rubbed gently so as not to scratch the coated surface.

【0074】(5) 塗膜の外観(JIS K5663-1995の5.7) 上記(2)塗装作業性の試験で塗料を塗布した試験板を24
時間乾燥させて、拡散昼光の下で塗面を肉眼でみて、刷
毛目の程度の大きさ、穴や弛みの有無、塗膜表面の一様
性(むらなし)を評価した。刷毛目の程度が大きくな
く、穴や弛みがなく、塗膜表面が一様(むらなし)であ
るとき、「塗膜の外観が正常である」として評価を「良
好」とし、順次不良の程度に応じて「普通」及び「不
良」とした。
(5) Appearance of the coating film (5.7 of JIS K5663-1995)
After drying for an hour, the coated surface was visually observed under diffused daylight to evaluate the size of the brush, the presence or absence of holes and slackness, and the uniformity of the coating surface (unevenness). When the degree of brush eyes is not large, there are no holes or slacks, and the coating film surface is uniform (no unevenness), the evaluation is evaluated as "good" as "the appearance of the coating film is normal", and the degree of failure is sequentially "Normal" and "Poor" according to

【0075】(6) 隠蔽率(JIS K5663-1995の5.8) 隠蔽率試験紙をガラス板の上に固定し、その上に塗料を
隙間150μmのB形フィルムアプリケーターを用いて塗
り、24時間放置して乾燥させた。試験紙の白地と黒地の
上に形成された塗膜の視感反射率を反射率測定装置を用
いて、試験片の3カ所について測定した。得られた視感
反射率から下記の式から隠蔽率を求めた。
(6) Hiding Ratio (5.8 of JIS K5663-1995) A hiding ratio test paper was fixed on a glass plate, and a paint was applied thereon using a B-type film applicator having a gap of 150 μm, and allowed to stand for 24 hours. And dried. The luminous reflectance of the coating film formed on the white background and the black background of the test paper was measured at three places of the test piece using a reflectance measuring device. From the obtained luminous reflectance, the hiding ratio was determined from the following equation.

【0076】[0076]

【数1】 (Equation 1)

【0077】(7) 耐アルカリ性(JIS K5663-1995の5.1
0) 試験片:予め周辺及び裏面を同種の塗料で2〜3回
塗り包んでおいたフレキシブル板(150×70×3mm)の表
面に塗料を刷毛で1±0.1ml/100cm2 の割合で一様に
塗り、6時間後、同様に更に1回塗って5日間乾燥し、
次いで試験板の周辺及び裏面をパラフィンで被覆して、
試験片とした(3枚準備、うち1枚は原状試験片)。 上記試験片を水酸化カルシウム飽和溶液(20±1
℃)中に18〜48時間浸漬し、2枚の試験片について
溶液から取り出した直後と2時間後の観察で、塗膜の状
態を原状試験片との比較で評価した(膨れ、割れ、剥が
れ、穴、軟化、色、艶)。 評価:48時間または18時間の浸漬処理で、試験片2
枚の塗膜に膨れ、割れ、剥がれ、穴、軟化を認めず、更
に浸漬溶液の着色や濁りがなく、原状試験片と比べて艶
の変化や変色の程度が大きくない時を、それぞれ「48時
間浸したとき異常がない」として評価を「良好」、また
は「18時間浸したとき異常がない」として評価を「良」
とした。
(7) Alkali resistance (5.1 of JIS K5663-1995)
0) Test piece: A paint was applied to the surface of a flexible plate (150 × 70 × 3 mm) whose peripheral and back surfaces were previously coated with the same type of paint two or three times with a brush at a rate of 1 ± 0.1 ml / 100 cm 2. After 6 hours, apply once more in the same manner and dry for 5 days.
Next, the periphery and back surface of the test plate were covered with paraffin,
Test pieces were prepared (three pieces were prepared, one of which was an original test piece). The test piece was placed in a calcium hydroxide saturated solution (20 ± 1).
C.) for 18 to 48 hours, and the state of the coating film was evaluated by comparing it with the original test piece immediately after taking out the two test pieces from the solution and two hours later (swelling, cracking, and peeling). , Holes, softening, color, luster). Evaluation: Test piece 2 after immersion treatment for 48 hours or 18 hours
When no swelling, cracking, peeling, pitting, or softening was observed on the coating films, there was no coloring or turbidity of the immersion solution, and the degree of gloss change or discoloration was not greater than that of the original test specimen, `` 48 Evaluation is "good" as "No abnormality when soaked for 18 hours", or "Good" as "No abnormality when soaked for 18 hours"
And

【0078】(8) 耐洗浄性(JIS K5663-1995の5.11) 試験片:フレキシブル板(430×170×5mm)の中央部
の長辺の長さ約400mmに隙間150μmのB形フィルムアプ
リケーターで塗料を塗り、塗面を上向きにして7日間乾
燥したものを試験片とした(2枚準備)。 ウォッシャビリティーマシンを用いて、0.5%の石鹸
水で濡らした試験片(2枚)の塗膜面をブラシで往復
(100回〜500回)して擦り、その後試験片を試験機から
外して水で洗い、ブラシで擦った跡の中央にあたる長さ
100mmの部分の塗膜を拡散昼光の下で、塗膜の破れや摩
滅の有無を目視で調べた。 評価:500回以上のブラシ往復で、試験片2枚とも中
央部分の塗膜が破れまたは摩滅によって試験片の素地の
露出が認められない場合を「500回の洗浄に耐える」と
して評価を「良好」とし、また100回以上の往復で試験
片の素地の露出が認められない場合を「100回の洗浄に
耐える」として評価を「良」とした。
(8) Washing resistance (5.11 of JIS K5663-1995) Specimen: Painted with a B-type film applicator with a gap of 150 μm on the long side of about 400 mm at the center of a flexible plate (430 × 170 × 5 mm) And dried for 7 days with the coated surface facing upward as test pieces (two pieces prepared). Using a washer machine, rub the coating surface of the test piece (2 pieces) wetted with 0.5% soap water by reciprocating (100 to 500 times) with a brush, and then remove the test piece from the testing machine. Wash with water and brush the length of the center of the mark
The coating film of the 100 mm portion was visually inspected under diffused daylight for the presence or absence of breakage or wear of the coating film. Evaluation: When 500 or more brush reciprocations, the coating film in the center part of both test pieces was not broken or worn and no exposure of the base material of the test piece was recognized, and the evaluation was "good" as "withstanding 500 washes". In addition, when no exposure of the substrate of the test specimen was observed after 100 or more reciprocations, the evaluation was "good" as "withstanding 100 washes".

【0079】(9) 耐水性(JIS K5663-1995の5.9) 上記(7)耐アルカリ性試験で使用した試験片と同じもの
を使用して(2枚)、これを脱イオン水(20±1℃)に
96時間浸漬して、試験片2枚について溶液から取り出
した直後と2時間後の観察で、塗面の状態を評価した
(シワ、膨れ、割れ、剥がれ、色、艶)。
(9) Water resistance (5.9 of JIS K5663-1995) Using the same test pieces (2 sheets) used in the above (7) Alkali resistance test, deionized water (20 ± 1 ° C.) ) For 96 hours, and the state of the coated surface was evaluated (wrinkles, blisters, cracks, peeling, color, gloss) immediately after the two test pieces were taken out of the solution and two hours later.

【0080】(10) 促進耐候性(JIS K5663-1995の5.1
2)(サンシャインカーボンアーク灯式:JIS K 5400 9.
8.1) 試験片:予めJPIA-23の合成樹脂エマルジョンシーラ
ーで処理したフレキシブル板(150×70×3mm)に塗料
を2回一様に刷毛塗りし(一回につき塗布量:1.0±0.1
ml/cm2)、5日間乾燥して試験片とした(2枚、うち
1枚原状試験片)。尚、1回塗りと2回塗りとの間が6
時間とした。 サンシャインカーボンアーク灯式耐光性試験器(ブ
ラックパネル温度:63℃、降雨サイクル:120分間隔で
18分間)を用いて200時間照射して、原状試験片と
耐候試験片の塗膜を肉眼観察して、色むらと色つやの変
化の程度、白亜化・か膨れ・剥がれ・割れの有無を調べ
た。 白亜化度が8点以上で、膨れ、はがれ、割れがな
く、色の変化の程度が原状試験片に比べて大きくないと
きは、評価を「良好」とし、順次不良の程度に応じて
「普通」及び「不良」とした。
(10) Accelerated weathering resistance (JIS K5663-1995, 5.1
2) (Sunshine carbon arc lamp type: JIS K 5400 9.)
8.1) Specimen: A flexible plate (150 x 70 x 3 mm) previously treated with a synthetic resin emulsion sealer of JPIA-23 was evenly brushed twice with paint (amount applied per time: 1.0 ± 0.1).
ml / cm 2 ) and dried for 5 days to obtain test pieces (two pieces, one of which was an original test piece). In addition, the interval between the first coating and the second coating is 6
Time. Irradiation was performed for 200 hours using a sunshine carbon arc lamp type light resistance tester (black panel temperature: 63 ° C, rain cycle: 120 minutes, 18 minutes), and the coating films of the original test piece and the weather resistance test piece were visually observed. Then, the degree of color unevenness and color gloss change, and the presence or absence of chalking, blistering, peeling, and cracking were examined. If the degree of chalk is 8 or more, no swelling, peeling or cracking, and the degree of color change is not greater than that of the original test specimen, the evaluation is evaluated as “good”, and the evaluation is evaluated as “normal” in accordance with the degree of failure. And "Poor".

【0081】結果を表2に示す。Table 2 shows the results.

【0082】[0082]

【表2】 [Table 2]

【0083】これらの結果から、本発明の塗料組成物
は、合成樹脂エマルジョンペイントの少なくとも2種、
特に1種の規格(JIS K5663-1995)を満たす塗料である
ことが確認された。
From these results, it was found that the coating composition of the present invention contains at least two kinds of synthetic resin emulsion paints,
In particular, it was confirmed that the paint satisfied one type of standard (JIS K5663-1995).

【0084】なお、実施例1において、消石灰100重
量部に対する顔料(酸化チタン)の割合を、6重量部、
8重量部、10重量部及び14重量部とした塗料組成物
をそれぞれ調製し、かかる塗料組成物の隠蔽率をJIS K5
400の7.2に従って同様にして調べた。その結果、いずれ
の塗料組成物も隠蔽率0.93以上を満たしていた。
In Example 1, the ratio of the pigment (titanium oxide) to 100 parts by weight of slaked lime was 6 parts by weight,
8 parts by weight, 10 parts by weight and 14 parts by weight of each of the coating compositions were prepared, and the hiding ratio of such coating compositions was measured according to JIS K5.
In the same way, it was examined according to 7.2 of 400. As a result, all the coating compositions satisfied the hiding ratio of 0.93 or more.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の建材の下地材へ配設方法を示す断面図
である。
FIG. 1 is a cross-sectional view showing a method for arranging a building material on a base material according to the present invention.

【図2】本発明のパネルの連設態様を示す断面図であ
る。(a)は突付け張り、(b)は突付けV形みぞ張
り、及び(c)相じゃくりの仕口による目透かし張りを
それぞれ示す。
FIG. 2 is a cross-sectional view showing a continuous arrangement of panels according to the present invention. (A) shows an abutment, (b) shows an abutment V-shaped groove, and (c) shows an eye-opening by a phased joint.

【図3】パネルの施工方法によって処理された(補強部
材として寒冷紗等のテープ材を使用)、パネル接合部を
示す断面図である。
FIG. 3 is a cross-sectional view showing a panel joint, which has been processed by a panel construction method (using a tape material such as cold gauze as a reinforcing member).

【図4】パネルの施工方法によって処理された(補強部
材として略T字形ジョイナーを使用)、パネル接合部を
示す断面図である。
FIG. 4 is a cross-sectional view showing a panel joint processed by a panel construction method (using a substantially T-shaped joiner as a reinforcing member).

【符号の説明】[Explanation of symbols]

1.パネル基材 2.塗膜層 3.釘 4.塗料組成物(パテ)充填部 5.壁下地材 6.接合部 7.テープ材(補強部材) 8.ジョイナー(補強部材) 1. Panel substrate 2. Coating layer 3. Nail 4. 4. Paint composition (putty) filling section Wall base material 6. Joint 7. 7. Tape material (reinforcing member) Joiner (reinforcing member)

─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成12年4月21日(2000.4.2
1)
[Submission date] April 21, 2000 (200.4.2
1)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】特許請求の範囲[Correction target item name] Claims

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【特許請求の範囲】[Claims]

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0010[Correction target item name] 0010

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0010】すなわち本発明は、下記1.〜8.に掲げ
る塗料組成物である: 1.消石灰、ポリマー成分、酸化チタン及び水を含有す
る塗料組成物であって、(a)消石灰の配合割合が30
〜80重量%(固形換算)、(b)ポリマー成分がアク
リル−スチレン共重合体,酢酸ビニルポリマー及びスチ
レン/ブタジエンゴムに属する群から選択される少なく
とも1種の合成ポリマーであって、消石灰100重量部
に対する配合割合が10〜70重量部(固形換算)、並
びに (c)酸化チタンの消石灰100重量部に対する配
合割合が2〜30重量部(固形換算)であり、しかも
(d)塗液またはその乾燥塗膜の (1)容器の中での状
態、(2)塗装作業性、(3)低温安定性、(4)塗膜の外観、
(5)耐アルカリ性、(6)耐洗浄性、(7)隠蔽率が、JISK 56
63-1995に規定される少なくとも2種ペイントの性質を
満たすものである、建築物の天井,内壁,外壁または建
材用の塗料組成物。2.繊維素材を含まないことを特徴とする1記載の塗料
組成物。 3.顔料を固形分あたり2〜10重量%(固形重量換
算)の割合で含有する1または2記載の塗料組成物。 4.酸化チタンの消石灰100重量部に対する配合割合
が8〜15重量部(固形換算)である1乃至3のいずれ
かに記載の塗料組成物。 5.ポリマー成分の消石灰100重量部に対する配合割
合が25〜35重量部(固形換算)である、1乃至4の
いずれかに記載の塗料組成物。 6.乾燥塗膜の隠蔽力が500μ以下である1乃至5の
いずれかに記載の塗料組成物。 7.粘度が常温で300〜3000センチポイズである
1乃至6のいずれかに記載の塗料組成物。 8.建材がクロス、ボードまたはパネルである1乃至7
のいずれかに記載の塗料組成物。
That is, the present invention provides the following 1. ~8.Raised in
The coating composition is: Slaked lime, polymer component, Titanium oxideAnd water
Paint composition,(A) The proportion of slaked lime is 30
-80% by weight (solid basis), the polymer component (b)
Ryl-styrene copolymer, vinyl acetate polymer and styrene
At least one selected from the group consisting of ren / butadiene rubber
Both are one kind of synthetic polymer, 100 parts by weight of slaked lime
10 to 70 parts by weight (solid basis)
Bini (C) Distribution of titanium oxide to 100 parts by weight of slaked lime
The mixing ratio is 2 to 30 parts by weight (solid basis), and
(D) The state of the coating liquid or its dried coating in (1) container
Condition, (2) painting workability, (3) low temperature stability, (4) appearance of coating film,
(5) Alkali resistance, (6) Wash resistance, (7) Concealment ratio is JISK 56
At least two paints specified in 63-1995
To satisfy,The ceiling, inner wall, outer wall or building of the building
For timberPaint composition.2. The paint according to 1, wherein the paint does not contain a fiber material.
Composition. 3. 2 to 10% by weight of pigment per solid (solid weight conversion)
3. The coating composition according to 1 or 2, which is contained in the ratio of 4. Mixing ratio of titanium oxide to 100 parts by weight of slaked lime
Is 1 to 3 which is 8 to 15 parts by weight (solid basis)
A coating composition according to any one of the above. 5. Composition ratio of polymer component to 100 parts by weight of slaked lime
1 to 4 in which the combination is 25 to 35 parts by weight (solid basis).
The coating composition according to any one of the above. 6. 1 to 5 wherein the hiding power of the dried coating film is 500 μ or less.
The coating composition according to any one of the above. 7. Viscosity is 300-3000 centipoise at room temperature
7. The coating composition according to any one of 1 to 6. 8. 1 to 7 where the building material is cloth, board or panel
The coating composition according to any one of the above.

【手続補正3】[Procedure amendment 3]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0011[Correction target item name] 0011

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0011】また、本発明は上記に掲げる塗料組成物か
ら形成される塗膜を有する塗装物、具体的には例えば壁
材及び天井材などの建材に関する。さらに、本発明は上
記塗料組成物の塗装方法及び上記建材を用いた建築物内
外装の施工方法に関する。また本発明は上記塗料組成物
を用いた建築物内外装壁面の修復方法に関する。
The present invention also relates to a coated article having a coating film formed from the above-mentioned coating composition , specifically, for example, a wall.
Related to building materials such as materials and ceiling materials. Furthermore, the present invention
Method for applying the coating composition and inside a building using the above building material
The present invention relates to an exterior construction method. The present invention also relates to the above coating composition.
The present invention relates to a method for repairing a building interior / exterior wall surface using a method.

【手続補正4】[Procedure amendment 4]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0056[Correction target item name] 0056

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0056】[0056]

【実施例】以下、本発明の内容を以下の実施例を用いて
具体的に説明する。ただし、これらの実施例は本発明の
一態様にすぎず、本発明はこれらの例に何ら限定される
ものではない。実施例1 消石灰 40 (100 %) アクリル樹脂エマルジョン 32 ( 40 %) (ポリトロンA-1450、旭化成) 酸化チタン(EP-498、大日精化) 5 (12.5%) 増粘剤(SP-600、ダイセル化学) 0.3 消泡剤(KM-70、信越化学) 0.3 防腐剤(PL-600、東京ファインケミカル・大和化学) 0.9 水 残 部 全 量 100.0重量部 上記成分を塗料調合用ミキサーに入れて撹拌することに
より固形分及び樹脂成分を水に安定に分散させて、本発
明の一液型水性塗料組成物(粘度800cps(25℃)B型粘
度計;固形分含有率62.5%)を調製した。尚、上記アク
リル樹脂エマルジョン(アクリル−スチレン系)は固形
分を50重量%の割合で含むものを使用した。上記処方
において、かっこ内の数値は消石灰を100重量%とし
た場合のアクリル樹脂エマルジョン(固形分)及び酸化
チタンの配合割合を示すものである。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be specifically described below with reference to the following embodiments. However, these examples are only one embodiment of the present invention, and the present invention is not limited to these examples. Example 1 Slaked lime 40 (100%) Acrylic resin emulsion 32 (40%) (Polytron A-1450, Asahi Kasei) Titanium oxide (EP-498, Dainichi Seika) 5 (12.5%) Thickener (SP-600, Daicel) Chemical) 0.3 Defoamer (KM-70, Shin - Etsu Chemical) 0.3 Preservative (PL-600, Tokyo Fine Chemicals / Daiwa Chemical) 0.9 Water Residual amount 100.0 parts by weight Compounding the above components The solid content and the resin component are stably dispersed in water by stirring in a mixer for water, and the one-component aqueous coating composition of the present invention (viscosity 800 cps (25 ° C.) B-type viscometer; solid content 62.5 %) Was prepared. The acrylic resin emulsion (acrylic-styrene type) used had a solid content of 50% by weight. In the above formula, the values in parentheses indicate the mixing ratio of the acrylic resin emulsion (solid content) and titanium oxide when slaked lime is 100% by weight.

【手続補正5】[Procedure amendment 5]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0057[Correction target item name] 0057

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0057】 実施例2 消石灰 40 (100 %) アクリル樹脂エマルジョン 16 ( 20 %) (ポリトロンA-1450、旭化成) 酸化チタン(EP-498、大日精化) 5 (12.5%) 増粘剤(SP-600、ダイセル化学) 0.3 消泡剤(KM-70、信越化学) 0.3 防腐剤(PL-600、東京ファインケミカル・大和化学) 0.9 水 残 部 全 量 100.0重量部 上記成分を塗料用ミキサーに入れて撹拌することにより
固形分及び樹脂成分を水に安定に分散させて、本発明の
一液型塗料組成物(粘度800cps(25℃)B型粘度計;固
形分含有率54.5%)を調製した。尚、上記アクリル樹脂
エマルジョンは固形分を50重量%の割合で含むものを
使用した。
Example 2 Slaked lime 40 (100%) Acrylic resin emulsion 16 (20%) (Polytron A-1450, Asahi Kasei) Titanium oxide (EP-498, Dainichi Seika) 5 (12.5%) Thickener (SP- 600, Daicel Chemical) 0.3 Antifoaming agent (KM-70, Shin - Etsu Chemical) 0.3 Preservative (PL-600, Tokyo Fine Chemicals / Daiwa Chemical) 0.9 Total water 100.0 parts by weight The solid component and the resin component are stably dispersed in water by stirring the mixture in a paint mixer, and the one-component paint composition of the present invention (viscosity 800 cps (25 ° C.) B-type viscometer; solid content) 54.5%). The acrylic resin emulsion used contained a solid content of 50% by weight.

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】消石灰、ポリマー成分及び水を含有する塗
料組成物であって、塗液またはその乾燥塗膜の (1)容器
の中での状態、(2)塗装作業性、(3)低温安定性、(4)塗
膜の外観、(5)耐アルカリ性、(6)耐洗浄性、(7)隠蔽率
が、JIS K 5663-1995に規定される少なくとも2種ペイ
ントの性質を満たすものである塗料組成物。
1. A coating composition containing slaked lime, a polymer component and water, wherein a coating liquid or a dried coating film thereof is (1) in a container, (2) workability of coating, and (3) low temperature. Stability, (4) Appearance of coating film, (5) Alkali resistance, (6) Washing resistance, (7) Concealment ratio satisfies the properties of at least two types of paint specified in JIS K 5663-1995. Certain coating compositions.
【請求項2】乾燥塗膜の隠蔽力が500μ以下である請
求項1に記載の塗料組成物。
2. The coating composition according to claim 1, wherein the hiding power of the dried coating film is 500 μm or less.
【請求項3】繊維素材を含まないことを特徴とする請求
項1または2に記載の塗料組成物。
3. The coating composition according to claim 1, wherein the coating composition does not contain a fiber material.
【請求項4】消石灰を固形換算で30〜80重量%の割
合で含有する請求項1乃至3のいずれかに記載の塗料組
成物。
4. The coating composition according to claim 1, wherein slaked lime is contained at a ratio of 30 to 80% by weight in terms of solids.
【請求項5】消石灰100重量部に対してポリマー成分
を10〜70重量部(固形換算)の割合で含むものであ
る請求項1乃至4のいずれかに記載の塗料組成物。
5. The coating composition according to claim 1, comprising a polymer component in an amount of 10 to 70 parts by weight (as solid) based on 100 parts by weight of slaked lime.
【請求項6】ポリマー成分がアクリル系樹脂である請求
項1乃至5のいずれかに記載の塗料組成物。
6. The coating composition according to claim 1, wherein the polymer component is an acrylic resin.
【請求項7】消石灰100重量部に対して酸化チタンを
2〜30重量部(固形換算)の割合で含む請求項1乃至
6のいずれかに記載の塗料組成物。
7. The coating composition according to claim 1, comprising 2 to 30 parts by weight (solid basis) of titanium oxide based on 100 parts by weight of slaked lime.
【請求項8】固形分含有率が50〜70重量%であるこ
とを特徴とする請求項1乃至7のいずれかに記載の塗料
組成物。
8. The coating composition according to claim 1, wherein the solid content is 50 to 70% by weight.
【請求項9】粘度が常温で300〜3000センチポイ
ズである請求項1乃至8のいずれかに記載の塗料組成
物。
9. The coating composition according to claim 1, which has a viscosity of 300 to 3000 centipoise at room temperature.
【請求項10】請求項1乃至9のいずれかに記載の塗料
組成物から形成される塗膜を有することを特徴とする塗
装物。
10. A coated article having a coating film formed from the coating composition according to claim 1.
JP11323125A 1999-05-21 1999-11-12 Paint composition Expired - Lifetime JP3083519B1 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003073998A (en) * 2001-08-31 2003-03-12 Nakamura Seishishiyo:Kk Peelable backing paper
JP2005105010A (en) * 2003-09-26 2005-04-21 Yamaguchi Prefecture Inorganic coating material and voc-adsorbing functional material using the same
KR100803170B1 (en) 2006-08-09 2008-02-14 광진산업(주) Friendly-environment Well-being lime paint
JP2011152102A (en) * 2010-01-28 2011-08-11 Sunrise Sangyo Co Ltd Lasting alkaline stable coating film and epidemic prevention method for animal-breeding building by using lasting alkaline stable coating film
JP2019055487A (en) * 2017-09-19 2019-04-11 東京カラーグラビヤ工業株式会社 Plaster sheet

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2001269489A1 (en) * 2000-07-10 2002-01-21 Mutsuo Himeno Coating composition
JP5393942B2 (en) * 2005-04-08 2014-01-22 アイカ工業株式会社 Water-based paint composition and wall surface
JP6195401B1 (en) * 2017-01-27 2017-09-13 家庭化学工業株式会社 Stucco paint composition

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003073998A (en) * 2001-08-31 2003-03-12 Nakamura Seishishiyo:Kk Peelable backing paper
JP2005105010A (en) * 2003-09-26 2005-04-21 Yamaguchi Prefecture Inorganic coating material and voc-adsorbing functional material using the same
KR100803170B1 (en) 2006-08-09 2008-02-14 광진산업(주) Friendly-environment Well-being lime paint
JP2011152102A (en) * 2010-01-28 2011-08-11 Sunrise Sangyo Co Ltd Lasting alkaline stable coating film and epidemic prevention method for animal-breeding building by using lasting alkaline stable coating film
JP2019055487A (en) * 2017-09-19 2019-04-11 東京カラーグラビヤ工業株式会社 Plaster sheet

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