JPH07188463A - Rubber composition - Google Patents
Rubber compositionInfo
- Publication number
- JPH07188463A JPH07188463A JP5346908A JP34690893A JPH07188463A JP H07188463 A JPH07188463 A JP H07188463A JP 5346908 A JP5346908 A JP 5346908A JP 34690893 A JP34690893 A JP 34690893A JP H07188463 A JPH07188463 A JP H07188463A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- rubber composition
- ethylene
- fender
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は防舷材用のゴム組成物に
関する。TECHNICAL FIELD The present invention relates to a rubber composition for a fender.
【0002】[0002]
【従来の技術】従来、防舷材として、天然ゴムの優れた
ゴム弾性を利用して、カ−ボンブラック補強系のもの
(いわゆる黒物)が広く使用されているが、近年、黒物
だけでなく、カラフルな色物のニ−ズが増している。し
かしながら、非カ−ボンブラック補強系のもの(いわゆ
る色物)は、耐候性などが悪く、いまだ実用されるには
いたっていない。すなわち、天然ゴムとスチレン−ブタ
ヂエンゴム系によるものは、耐候性が劣り、塗装をおこ
なうと、衝突時に塗膜が剥離し易い。クロロプレンゴム
系のもは、コスト上問題があり、耐摩耗性が劣る。ポリ
オレフィン系樹脂のものは、耐衝撃性と復元性のバラン
スをとるのが困難である。2. Description of the Related Art Conventionally, carbon black reinforced materials (so-called black products) have been widely used as fenders by utilizing the excellent rubber elasticity of natural rubber, but in recent years, only black products have been used. Not only that, but the needs of colorful objects are increasing. However, the non-carbon black reinforced type (so-called color type) has poor weather resistance and has not yet been put to practical use. That is, those made of natural rubber and styrene-butadiene rubber have poor weather resistance, and the coating film is likely to be peeled off at the time of collision when coating is performed. The chloroprene rubber type has a problem in cost and is inferior in abrasion resistance. It is difficult to balance impact resistance and resilience with a polyolefin resin.
【0003】[0003]
【発明が解決しようとする課題】本発明は、耐候性やゴ
ム弾性、耐衝撃性に優れた色物防舷材用のゴム組成物を
提供せんとするものである。SUMMARY OF THE INVENTION The present invention is to provide a rubber composition for a color fender that is excellent in weather resistance, rubber elasticity and impact resistance.
【0004】[0004]
【課題を解決するための手段】すなわち、本発明は色物
防舷材用のゴム組成物として、エチレン−プロピレン系
弾性共重合体および天然ゴム成分を含有するものを見出
すにいたった。 そして、両者の好ましい配合比は、エ
チレン−プロピレン系弾性共重合体が20〜40重量
%、天然ゴムが60〜80重量%である。エチレン−プ
ロピレン系弾性共重合体は、20重量%以下で耐候性が
悪化し、40重量%以上で引張強度や引張伸びが低下し
て好ましくない。エチレンン−プロピレン系弾性共重合
体は、エチレン含有量が50〜85重量%の範囲のもの
が好ましく、たとえばEPDM(エチレン−プロピレン
−ジエンメチレンゴム)を選択使用することができる。
なお、天然ゴムはそのまま使用することができる。That is, the present invention has led to finding a rubber composition for a color fender that contains an ethylene-propylene elastic copolymer and a natural rubber component. The preferable compounding ratio of both is 20 to 40% by weight of the ethylene-propylene elastic copolymer and 60 to 80% by weight of the natural rubber. When the ethylene-propylene elastic copolymer is 20% by weight or less, the weather resistance is deteriorated, and when it is 40% by weight or more, the tensile strength and the tensile elongation are decreased, which is not preferable. The ethylene-propylene-based elastic copolymer preferably has an ethylene content of 50 to 85% by weight, and for example, EPDM (ethylene-propylene-diene methylene rubber) can be selectively used.
Natural rubber can be used as it is.
【0005】本発明のゴム組成物を用いて防舷材製品を
得るまでの工程を述べれば、原料の天然ゴムと、たとえ
ばEPDMに、配合材として、補強材、パラフィンオイ
ル、助剤(加硫剤、着色剤など)を加え、これらを密閉
式混練機に入れ、混練してコンパウンドを作成する。つ
ぎに、これをロ−ルなどに通して、所定の厚さのシ−ト
に成形する。得られたシ−トを金型などを用いて、所定
の温度、時間で加硫をおこない、所定形状の防舷材に成
形して製品を得る。The steps for obtaining a fender product using the rubber composition of the present invention are as follows: raw material natural rubber and, for example, EPDM, as a compounding material, a reinforcing material, paraffin oil, an auxiliary agent (vulcanization Agents, colorants, etc.), and put them in a closed kneader to knead them to form a compound. Next, this is passed through a roll or the like to form a sheet having a predetermined thickness. The sheet thus obtained is vulcanized at a predetermined temperature and time using a mold or the like, and molded into a fender having a predetermined shape to obtain a product.
【0006】[0006]
【実施例】以下、実施例および比較例により本発明をさ
らに具体的に説明する。第1表−1(実施例1〜4)、
第1表−2(比較例1、2)ならびに第2表−2(比較
例3〜5)に示す組成からなる各種材料について、各種
物性を測定した結果を第2表−1(実施例1〜4)およ
び第2表−2(比較例1〜5)に示す。なお、防舷材と
して要求される物性値は、一般に引張強度が180以
上、引張伸びが400以上、引裂強度が50以上、硬さ
が72以下、耐摩耗性が0.2以下、永久伸びが15以
下が望ましく、耐候性はここにおける試験でクラック発
生をしないもの(○印)である。クラックが発生したも
のは×印としてある。以上の結果から明らかなように、
実施例のものは、防舷材として必要な物性をすべて具備
するが、比較例のものは、いずれかを欠く。EXAMPLES The present invention will be described in more detail with reference to Examples and Comparative Examples. Table 1-1 (Examples 1 to 4),
The results of measuring various physical properties of various materials having the compositions shown in Table 1-2 (Comparative Examples 1 and 2) and Table 2-2 (Comparative Examples 3 to 5) are shown in Table 2-1 (Example 1). ~ 4) and Table 2-2 (Comparative Examples 1 to 5). The physical properties required as a fender are generally tensile strength of 180 or more, tensile elongation of 400 or more, tear strength of 50 or more, hardness of 72 or less, wear resistance of 0.2 or less, and permanent elongation of It is preferably 15 or less, and the weather resistance is such that cracks do not occur in the test here (circle mark). Those with cracks are marked with x. As is clear from the above results,
The example has all the physical properties necessary for the fender, but the comparative example lacks any of them.
【0007】[0007]
【表1】 [Table 1]
【0008】[0008]
【表2】 [Table 2]
【0009】[0009]
【表3】 [Table 3]
【0010】[0010]
【表4】 [Table 4]
【0011】[0011]
【発明の効果】本発明のゴム組成物は、耐候性やゴム弾
性、耐衝撃性に優れ、各種色彩を施すことができるの
で、防舷材として需要者の要望に応え得るものである。The rubber composition of the present invention is excellent in weather resistance, rubber elasticity, and impact resistance, and can be applied with various colors, so that it can meet the demand of consumers as a fender.
Claims (3)
天然ゴム成分を含有する防舷材用ゴム組成物。1. A rubber composition for a fender, comprising an ethylene-propylene elastic copolymer and a natural rubber component.
20〜40重量%で、天然ゴムが60〜80重量%であ
る請求項1記載のゴム組成物。2. The rubber composition according to claim 1, wherein the elastic copolymer of ethylene-propylene is 20 to 40% by weight and the natural rubber is 60 to 80% by weight.
EPDMである請求項1または請求項2記載のゴム組成
物。3. The rubber composition according to claim 1, wherein the ethylene-propylene elastic copolymer is EPDM.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5346908A JPH07188463A (en) | 1993-12-27 | 1993-12-27 | Rubber composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5346908A JPH07188463A (en) | 1993-12-27 | 1993-12-27 | Rubber composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH07188463A true JPH07188463A (en) | 1995-07-25 |
Family
ID=18386631
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5346908A Pending JPH07188463A (en) | 1993-12-27 | 1993-12-27 | Rubber composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH07188463A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008179656A (en) * | 2007-01-23 | 2008-08-07 | Yokohama Rubber Co Ltd:The | Rubber composition for fender and fender |
JP2012211277A (en) * | 2011-03-31 | 2012-11-01 | Yokohama Rubber Co Ltd:The | Rubber composition for rubber bearing wall, and rubber bearing |
CN107033401A (en) * | 2017-04-25 | 2017-08-11 | 广州海宁橡胶有限公司 | A kind of military rubber fender of high-performance and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01135850A (en) * | 1987-11-20 | 1989-05-29 | Bridgestone Corp | Rubber composition and production thereof |
JPH0559711A (en) * | 1991-09-02 | 1993-03-09 | Yokohama Rubber Co Ltd:The | Fender |
-
1993
- 1993-12-27 JP JP5346908A patent/JPH07188463A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01135850A (en) * | 1987-11-20 | 1989-05-29 | Bridgestone Corp | Rubber composition and production thereof |
JPH0559711A (en) * | 1991-09-02 | 1993-03-09 | Yokohama Rubber Co Ltd:The | Fender |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008179656A (en) * | 2007-01-23 | 2008-08-07 | Yokohama Rubber Co Ltd:The | Rubber composition for fender and fender |
JP2012211277A (en) * | 2011-03-31 | 2012-11-01 | Yokohama Rubber Co Ltd:The | Rubber composition for rubber bearing wall, and rubber bearing |
CN107033401A (en) * | 2017-04-25 | 2017-08-11 | 广州海宁橡胶有限公司 | A kind of military rubber fender of high-performance and preparation method thereof |
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