CN107033401A - A kind of military rubber fender of high-performance and preparation method thereof - Google Patents
A kind of military rubber fender of high-performance and preparation method thereof Download PDFInfo
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- CN107033401A CN107033401A CN201710278923.7A CN201710278923A CN107033401A CN 107033401 A CN107033401 A CN 107033401A CN 201710278923 A CN201710278923 A CN 201710278923A CN 107033401 A CN107033401 A CN 107033401A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses military rubber fender of a kind of high-performance and preparation method thereof, include the component of following mass parts：90 parts of standard natural rubber 5#60,10 40 parts of ethylene propylene diene rubber, 35 parts of nano zine oxide, 13 parts of stearic acid, 20 40 parts of white carbon, 10 40 parts of nano-calcium carbonate, 10 30 parts of barium sulfate, 25 parts of PEG4000,0.05 0.5 parts of color masterbatch carbon black, 0.05 0.5 parts of dark green, 10 15 parts of nano titanium oxide, 1.5 2 parts of antioxidant 2246,23 parts of paraffin, accelerator NS（The benzothiazole sulfenamide of the N tert-butyl groups 2）0.8 1.5 parts, Vulcanization accelerator TMTD (tetramethylthiuram disulfide) 0.1 0.5,80 1.2 2.5 parts of insoluble sulfur IS.The features such as military rubber fender of high-performance of the present invention has excellent combination property, mechanical strength height and service life length, colour stable.
Description
Technical field
The present invention relates to the military rubber fender technology field of high-performance, particularly a kind of military rubber fender of high-performance
And preparation method thereof.
Background technology
With the progress of modern ships and shipping technology, rubber fender is on all kinds of harbours using more and more ripe.But army
With harbour as the special facility of a class, there is its particularity in the use of fender.Army uses common black rubber first
Fender just seems improper, it is necessary to using this grey protective coloration of naval, while can also avoid warship color from being contaminated.Next army
Particularity require again fender have than common product have more excellent berthing performance and durability.
The content of the invention
The main purpose of the present invention is the provision of military rubber fender of a kind of high-performance and preparation method thereof, with comprehensive
The features such as closing high excellent performance, mechanical strength and service life length, colour stable
The present invention can be achieved through the following technical solutions：
The invention discloses a kind of military rubber fender of high-performance, include the component of following mass parts：Standard natural rubber 5#
60-90 parts, 10-40 parts of ethylene propylene diene rubber, 3-5 parts of nano zine oxide, 1-3 parts of stearic acid, 20-40 parts of white carbon is received
10-40 parts of calcium carbonate of rice, 10-30 parts of barium sulfate, 2-5 parts of PEG4000,0.05-0.5 parts of color masterbatch carbon black, dark green 0.05-
0.5 part, 10-15 parts of nano titanium oxide, 1.5-2 parts of antioxidant 2246,2-3 parts of paraffin, accelerator NS（The N- tert-butyl groups -2-
Benzothiazole sulfenamide）0.8-1.5 parts, Vulcanization accelerator TMTD (tetramethylthiuram disulfide) 0.1-0.5, insoluble sulfur
1.2-2.5 parts of sulphur IS-80.A kind of preparation method of the military rubber fender of high-performance, comprises the following steps
Dispensing：Dispensing is carried out according to proportioning；
Plasticate：5# standard natural rubbers are plasticated two sections in banbury.Every section is plasticated time 8-10 minute, one section plasticate after stop
Put and carry out two sections again within more than 4 hours and plasticate；Two sections plasticate after park more than 4 hours and kneaded again；
Mixing：In banbury put into two sections plasticate natural rubbers, ethylene propylene diene rubber knead 2-4 minute after, addition nanometer
After zinc oxide, stearic acid, color masterbatch carbon black, dark green, antioxidant 2246, paraffin are kneaded 2-4 minutes, white carbon, nanometer are added
Calcium carbonate, barium sulfate, PEG4000, knead 3-5 minutes back glues, add accelerator NS, promotion after sizing material cooling on a mill
Agent TMTD, insoluble sulfur IS-80, thin logical rear bottom sheet；
Shaping：Elastomeric compound turns refining by mill, after calender slice, cuts, is molded as requested；
Vulcanization：By the mold-locked of forming, enter sulfurizing pot vulcanization；
Deburring：The product vulcanizated is taken out, cooling, deburring.
The military rubber fender of high-performance of the present invention has following beneficial technique effect：
Firstth, excellent combination property, its compound physical performance of the rubber fender product of this formula production fully meets professional standard
It is required that, while the also higher than data of professional standard；
Secondth, mechanical strength is high, and naval's grey rubber fender mechanical property of this formula production meets Industry code requirements, has
High tearing strength and excellent wearability, fatigue performance, greatly improve the service life of fender；
3rd, color fast is approached by adding color masterbatch carbon black and dark green, fender color with warship color, and color fast degree is good
It is good.Avoid the pollution to warship surface color.
Embodiment
In order that those skilled in the art will better understand the technical solution of the present invention, with reference to embodiment and to this
Invention product is described in further detail.
Embodiment 1
The invention discloses a kind of military rubber fender of high-performance, include the component of following mass parts：Standard natural rubber 5# 90
Part, 10 parts of ethylene propylene diene rubber, 5 parts of nano zine oxide, 1.5 parts of stearic acid, 30 parts of white carbon, 15 parts of nano-calcium carbonate, sulphur
Sour 15 parts of barium, 3 parts of PEG4000,0.15 part of color masterbatch carbon black, 0.1 part of dark green, 10 parts of nano titanium oxide, antioxidant 2246
1.5 parts, 1 part of accelerator NS, 0.1 part of Vulcanization accelerator TMTD, 2 parts of insoluble sulfur.
The above-mentioned military rubber fender of high-performance is prepared by following preparation method：
Dispensing：Dispensing is carried out according to proportioning；
Plasticate：5# standard natural rubbers are plasticated two sections in banbury.Every section is plasticated time 8-10 minute, one section plasticate after stop
Put and carry out two sections again within more than 4 hours and plasticate；Two sections plasticate after park more than 4 hours and kneaded again；
Mixing：In banbury put into two sections plasticate natural rubbers, ethylene propylene diene rubber knead 2-4 minute after, addition nanometer
After zinc oxide, stearic acid, color masterbatch carbon black, dark green, antioxidant 2246, paraffin are kneaded 2-4 minutes, white carbon, nanometer are added
Calcium carbonate, barium sulfate, PEG4000, knead 3-5 minutes back glues, add accelerator NS, promotion after sizing material cooling on a mill
Agent TMTD, insoluble sulfur IS-80, thin logical rear bottom sheet；
Shaping：Elastomeric compound turns refining by mill, after calender slice, cuts, is molded as requested；
Vulcanization：By the mold-locked of forming, enter sulfurizing pot vulcanization；
Deburring：The product vulcanizated is taken out, cooling, deburring.
Embodiment 2
The invention discloses a kind of military rubber fender of high-performance, include the component of following mass parts：Standard natural rubber 5# 80
Part, 20 parts of ethylene propylene diene rubber, 5 parts of nano zine oxide, 1.5 parts of stearic acid, 30 parts of white carbon, 10 parts of nano-calcium carbonate, sulfuric acid
15 parts of barium, 3 parts of PEG4000,0.15 part of color masterbatch carbon black, 0.1 part of dark green, 10 parts of nano titanium oxide, antioxidant 2246
1.5 parts, 1 part of accelerator NS, 0.2 part of Vulcanization accelerator TMTD, 1.8 parts of insoluble sulfur IS-80.
The above-mentioned military rubber fender of high-performance is prepared by following preparation method：
Dispensing：Dispensing is carried out according to proportioning；
Plasticate：5# standard natural rubbers are plasticated two sections in banbury.Every section is plasticated time 8-10 minute, one section plasticate after stop
Put and carry out two sections again within more than 4 hours and plasticate；Two sections plasticate after park more than 4 hours and kneaded again；
Mixing：In banbury put into two sections plasticate natural rubbers, ethylene propylene diene rubber knead 2-4 minute after, addition nanometer
After zinc oxide, stearic acid, color masterbatch carbon black, dark green, antioxidant 2246, paraffin are kneaded 2-4 minutes, white carbon, nanometer are added
Calcium carbonate, barium sulfate, PEG4000, knead 3-5 minutes back glues, add accelerator NS, promotion after sizing material cooling on a mill
Agent TMTD, insoluble sulfur IS-80, thin logical rear bottom sheet；
Shaping：Elastomeric compound turns refining by mill, after calender slice, cuts, is molded as requested；
Vulcanization：By the mold-locked of forming, enter sulfurizing pot vulcanization；
Deburring：The product vulcanizated is taken out, cooling, deburring.
Embodiment 3
The invention discloses a kind of military rubber fender of high-performance, include the component of following mass parts：Standard natural rubber 5# 70
Part, 30 parts of ethylene propylene diene rubber, 5 parts of nano zine oxide, 1.5 parts of stearic acid, 30 parts of white carbon, 10 parts of nano-calcium carbonate, sulphur
Sour 15 parts of barium, 3 parts of PEG4000,0.15 part of color masterbatch carbon black, 0.1 part of dark green, 10 parts of nano titanium oxide, antioxidant 2246
1.5 parts, 1 part of accelerator NS, 0.3 part of Vulcanization accelerator TMTD, 1.5 parts of insoluble sulfur.
The above-mentioned military rubber fender of high-performance is prepared by following preparation method：
Dispensing：Dispensing is carried out according to proportioning；
Plasticate：5# standard natural rubbers are plasticated two sections in banbury.Every section is plasticated time 8-10 minute, one section plasticate after stop
Put and carry out two sections again within more than 4 hours and plasticate；Two sections plasticate after park more than 4 hours and kneaded again；
Mixing：In banbury put into two sections plasticate natural rubbers, ethylene propylene diene rubber knead 2-4 minute after, addition nanometer
After zinc oxide, stearic acid, color masterbatch carbon black, dark green, antioxidant 2246, paraffin are kneaded 2-4 minutes, white carbon, nanometer are added
Calcium carbonate, barium sulfate, PEG4000, knead 3-5 minutes back glues, add accelerator NS, promotion after sizing material cooling on a mill
Agent TMTD, insoluble sulfur IS-80, thin logical rear bottom sheet；
Shaping：Elastomeric compound turns refining by mill, after calender slice, cuts, is molded as requested；
Vulcanization：By the mold-locked of forming, enter sulfurizing pot vulcanization；
Deburring：The product vulcanizated is taken out, cooling, deburring.
In order to further assess the performance of products obtained therefrom of the present invention, performance is carried out to the product obtained by embodiment 1-3 respectively
Test, specific test result is as shown in table 1：
The not be the same as Example the performance test results of table 1
The foregoing is only a preferred embodiment of the present invention, not makees any formal limitation to the present invention；All one's own professions
The those of ordinary skill of industry can be shown in by specification and described above and swimmingly implement the present invention；But, it is all that to be familiar with sheet special
Without departing from the scope of the present invention, that is made using disclosed above technology contents is a little by the technical staff of industry
Perhaps the equivalent variations of variation, modification and evolution, are the equivalent embodiment of the present invention；Meanwhile, all substantive skills according to the present invention
Variation, modification and evolution of any equivalent variations that art is made to above example etc., still fall within technical scheme
Protection domain within.
Claims (2)
1. a kind of military rubber fender of high-performance, it is characterised in that include the component of following mass parts：Standard natural rubber 5#
60-90 parts, 10-40 parts of ethylene propylene diene rubber, 3-5 parts of nano zine oxide, 1-3 parts of stearic acid, 20-40 parts of white carbon is received
10-40 parts of calcium carbonate of rice, 10-30 parts of barium sulfate, 2-5 parts of PEG4000,0.05-0.5 parts of color masterbatch carbon black, dark green 0.05-
0.5 part, 10-15 parts of nano titanium oxide, 1.5-2 parts of antioxidant 2246,2-3 parts of paraffin, accelerator NS（The N- tert-butyl groups -2-
Benzothiazole sulfenamide）0.8-1.5 parts, Vulcanization accelerator TMTD (tetramethylthiuram disulfide) 0.1-0.5, insoluble sulfur
1.2-2.5 parts of sulphur IS-80.
2. the preparation method of the military rubber fender of high-performance described in a kind of claim 1, it is characterised in that comprise the following steps：
Dispensing：Dispensing is carried out according to proportioning described in claim 1；
Plasticate：5# standard natural rubbers are plasticated two sections in banbury, every section is plasticated time 8-10 minute, one section plasticate after stop
Put and carry out two sections again within more than 4 hours and plasticate；Two sections plasticate after park more than 4 hours and kneaded again；
Mixing：In banbury put into two sections plasticate natural rubbers, ethylene propylene diene rubber knead 2-4 minute after, addition nanometer
After zinc oxide, stearic acid, color masterbatch carbon black, dark green, antioxidant 2246, paraffin are kneaded 2-4 minutes, white carbon, nanometer are added
Calcium carbonate, barium sulfate, PEG4000, knead 3-5 minutes back glues, add accelerator NS, promotion after sizing material cooling on a mill
Agent TMTD, insoluble sulfur IS-80, thin logical rear bottom sheet；
Shaping：Elastomeric compound turns refining by mill, after calender slice, cuts, is molded as requested；
Vulcanization：By the mold-locked of forming, enter sulfurizing pot vulcanization；
Deburring：The product vulcanizated is taken out, cooling, deburring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710278923.7A CN107033401A (en) | 2017-04-25 | 2017-04-25 | A kind of military rubber fender of high-performance and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710278923.7A CN107033401A (en) | 2017-04-25 | 2017-04-25 | A kind of military rubber fender of high-performance and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107033401A true CN107033401A (en) | 2017-08-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710278923.7A Pending CN107033401A (en) | 2017-04-25 | 2017-04-25 | A kind of military rubber fender of high-performance and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112225954A (en) * | 2020-10-15 | 2021-01-15 | 广东狮特龙实业有限公司 | Anti-aging rubber belt and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0559711A (en) * | 1991-09-02 | 1993-03-09 | Yokohama Rubber Co Ltd:The | Fender |
| JPH07188463A (en) * | 1993-12-27 | 1995-07-25 | Shibata Ind Co Ltd | Rubber composition |
| CN102311564A (en) * | 2010-06-29 | 2012-01-11 | 冯高明 | Rubber for rubber fender |
-
2017
- 2017-04-25 CN CN201710278923.7A patent/CN107033401A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0559711A (en) * | 1991-09-02 | 1993-03-09 | Yokohama Rubber Co Ltd:The | Fender |
| JPH07188463A (en) * | 1993-12-27 | 1995-07-25 | Shibata Ind Co Ltd | Rubber composition |
| CN102311564A (en) * | 2010-06-29 | 2012-01-11 | 冯高明 | Rubber for rubber fender |
Non-Patent Citations (3)
| Title |
|---|
| 李青山: "《着色配色技术手册》", 31 January 2016 * |
| 杨得兵、许辉、刘志芳: "白炭黑活性剂PEG-4000在橡胶配方中的应用", 《首届全国橡胶环保节能补强材料应用技术研讨会论文集》 * |
| 翁国文: "《实用橡胶配方技术》", 31 March 2008 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112225954A (en) * | 2020-10-15 | 2021-01-15 | 广东狮特龙实业有限公司 | Anti-aging rubber belt and preparation method thereof |
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Application publication date: 20170811 |