JPH06500493A - 水素化触媒 - Google Patents
水素化触媒Info
- Publication number
- JPH06500493A JPH06500493A JP3511482A JP51148291A JPH06500493A JP H06500493 A JPH06500493 A JP H06500493A JP 3511482 A JP3511482 A JP 3511482A JP 51148291 A JP51148291 A JP 51148291A JP H06500493 A JPH06500493 A JP H06500493A
- Authority
- JP
- Japan
- Prior art keywords
- group
- nickel
- compound
- oxide
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
Claims (30)
- 1.以下を含む組成物。 a.担体酸化物; b.IVB族ゲル助触媒;および c.VIII族金属からの少くとも一種の成分およびVIB族金属からの少くと も一種の成分を含む水素化成分
- 2.担体酸化物がアルミナである請求項1に記載の組成物。
- 3.IVB族ゲル助触媒が酸化チタンである請求項1に記載の組成物。
- 4.VIII族金属がニッケルおよびコバルトからなる請求項1に記載の組成物 。
- 5.VIB族金属がモリブデンおよびタングステンからなる請求項1に記載の組 成物。
- 6.以下を含む触媒の製造方法。 a.加水分解可能なIVB族化合物を沈殿させてIVB族の水和酸化物ゲルを形 成する; b.IVB族の水和酸化物ゲルを水で洗う;c.IVB族の水和酸化物ゲルに酸 性化合物水溶液と可溶性VIII族金属化合物とを加えスラリーを形成する; d.水和担体酸化物をスラリーと混合し解膠する;e.可溶性VIB族金属化合 物を一部または全部加える;そして f.触媒粒子を形成し、乾燥しそしてか焼する。
- 7.以下を含む請求項1に記載の組成物の製造方法。 a.加水分解可能なチタン化合物を沈殿させて酸化チタン水和物のゲルを形成す る; b.酸化チタン水和物のゲルを水で洗う;c.酸化チタン水和物のゲルに酸性化 合物水溶液と可溶性VIII族金属化合物とを加えスラリーを形成する; d.水和アルミナをスラリーと混合し解膠する;そして e.可溶性VIB族金属化合物を一部または全部加える。
- 8.チタン化合物が四塩化チタン、三塩化チタンまたはその他のハロゲン化チタ ンからなるグループから選ばれる請求項7に記載の方法。
- 9.酸性化合物水溶液が酢酸、硝酸、硫酸、シュウ酸、塩酸およびギ酸からなる グループから選ばれる請求項7に記載の方法。
- 10.VIB族金属化合物がモリブデンを含む請求項7に記載の方法。
- 11.モリブデン化合物がモリブデン酸アンモニウム、酸化モリブデンのアンモ ニウム化合物、酸化モリブデンおよびそれらの過酸化水素溶液からなるグループ から選ばれる請求項10に記載の方法。
- 12.VIII族金属化合物がニッケルを含む請求項7に記載の化合物。
- 13.前記ニッケル化合物が酢酸ニッケル、硝酸ニッケル、硫酸ニッケル、炭酸 ニッケル、酸化ニッケル、水酸;化ニッケル、塩化ニッケルおよびそれらの混合 物からなるグループから選ばれる請求項12に記載の方法。
- 14.請求項6の方法による生成物。
- 15.触媒粒子が、IVB族金属含量が約0.5重量%〜約40重量%、VII I族金属含量が約1重量%〜約15重量%、そしてVIB族金属含量が約5重量 %〜約50重量%であることを更に特徴とする請求項7に記載の方法。
- 16.前記触媒粒子が、チタン含量が約2.5重量%〜約6.5重量%、ニッケ ル含量が約5重量%〜約10重量%、そしてモリブデン含量が約10重量%〜約 20重量%であることを更に特徴とする請求項15に記載の方法。
- 17.窒素化合物を含む供給炭化水素の水素化脱窒方法であって、その方法が水 素化脱窒条件下において水素の存在する反応領域中で前記供給物を以下の記載を 含む方法により調製される触媒と接触させることを含む方法。 a.加水分解可能なIVB族化合物を沈殿させてIVB族の水和酸化物ゲルを形 成する; b.lVB族の水和酸化物ゲルを水で洗う;c.IVB族の水和酸化物ゲルに酸 性化合物水溶液と可溶性VIII族金属化合物とを加えスラリーを形成する; d.水和酸化物担体をスラリーと混合し解膠する;e.可溶性VIB族金属化合 物を一部または全部加えるf.触媒粒子を形成し、乾燥しそしてか焼する;そし て g.低減した窒素レベルをもつ流出物を集める。
- 18.前記酸性化合物水溶液が硝酸、硫酸、ギ酸、酢酸、シュウ酸および塩酸か らなるグループから選ばれる請求項17に記載の方法。
- 19.前記VIII族金属化合物がニッケルを含む請求項17に記載の方法。
- 20.前記VIB族金属化合物がモリブデンを含む請求項17に記載の方法。
- 21.窒素化合物を含む供給炭化水素の水素化脱窒方法であって、その方法が水 素化脱窒条件下において水素の存在する反応領域中で前記供給物を以下の記載を 含む方法により調製される触媒と接触させることを含む方法。 a.加水分解可能なチタン化合物を沈殿させて水和酸化チタンゲルを形成する; b.水和酸化チタンゲルを水で洗い実質的に非チタン化合物を除去する; c.水和酸化チタンゲルに酸性化合物水溶液と可溶性ニッケル化合物を加えスラ リーを形成する;d.水和アルミナをスラリーと混合し解膠する;e.可溶性モ リブデン化合物を加える;f.触媒粒子を成形し、乾燥しそしてか焼する;そし て g.低減した窒素レベルをもつ流出物を集める。
- 22.チタン化合物が四塩化チタンである請求項21に記載の方法。
- 23.前記ニッケル化合物が酢酸ニッケル、硝酸ニッケル、硫酸ニッケル、酸化 ニッケル、塩化ニッケル、炭酸ニッケル、水酸化ニッケルおよびその混合物から なるグループから選ばれる請求項21に記載の方法。
- 24.前記モリブデン化合物がモリブデン酸アンモニウム、酸化モリブデンのア ンモニウム化合物、酸化モリブデンおよひそれらの過酸化水素溶液からなるグル ープから選ばれる請求項21に記載の方法。
- 25.触媒粒子がか焼後、リン含有化合物で含浸される請求項17または21に 記載の方法。
- 26.前記リン含有化合物がリン酸、リン酸アンモニウム、およびホスホモリブ デン酸からなるグループから選ばれる請求項25に記載の方法。
- 27.条件が、温度が約500°F〜850°F(約260℃〜約454℃)の 範囲、全圧が約450〜約35001b/in2G(約32kg/cm2G〜約 246kg/cm2G)の範囲、空間速度が約0.05〜約5.0の範囲、そし て水素分圧が約350〜32001b/in2G(約24.6kg/cm2G〜 約225kg/cm2G)の範囲であることを含む請求項21に記載の方法。
- 28.条件が、温度が約550°F〜約800°F(約288℃〜約427℃) の範囲、全圧が約600〜約280Glb/in2G(約42.2kg/cm2 G〜約197kg/cm2G)の範囲、空間速度が約0.1〜約3.0の範囲、 そして水素分圧が約500〜約25001b/in2G(約35.2kg/cm 2G〜約175.8kg/cm2G)の範囲であることを含む請求項21に記載 の方法。
- 29.供給炭化水素のラムスボトム法残留炭素を更に低減させる請求項17また は21に記載の方法。
- 30.供給炭化水素の硫黄含量を更に低減させる請求項17または21に記載の 方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/543,257 US5089462A (en) | 1990-06-25 | 1990-06-25 | Hydroconversion catalyst and method for making the catalyst |
US543,257 | 1990-06-25 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH06500493A true JPH06500493A (ja) | 1994-01-20 |
JP3246739B2 JP3246739B2 (ja) | 2002-01-15 |
Family
ID=24167238
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51148291A Expired - Fee Related JP3246739B2 (ja) | 1990-06-25 | 1991-06-06 | 水素化触媒 |
Country Status (7)
Country | Link |
---|---|
US (2) | US5089462A (ja) |
EP (1) | EP0536205A4 (ja) |
JP (1) | JP3246739B2 (ja) |
KR (1) | KR930701229A (ja) |
AU (1) | AU8050991A (ja) |
TW (1) | TW283727B (ja) |
WO (1) | WO1992000142A1 (ja) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2942765B1 (ja) * | 1998-06-05 | 1999-08-30 | 株式会社ホンゴウリミテド | 嫌気性微生物を利用する有機性原水処理装置 |
AU2003267854A1 (en) * | 2003-10-10 | 2005-04-27 | Instituto Mexicano Del Petroleo | Catalytic composition for the hydroprocessing of light and intermediate petroleum fractions |
US7416655B2 (en) * | 2003-10-10 | 2008-08-26 | Instituto Mexicano Del Petroleo | Selective adsorbent material and its use |
US20100098602A1 (en) * | 2003-12-19 | 2010-04-22 | Opinder Kishan Bhan | Systems, methods, and catalysts for producing a crude product |
US20050139520A1 (en) * | 2003-12-19 | 2005-06-30 | Bhan Opinder K. | Systems, methods, and catalysts for producing a crude product |
US7745369B2 (en) | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
EP1885822A2 (en) * | 2005-04-11 | 2008-02-13 | Shell Internationale Research Maatschappij B.V. | Systems, methods, and catalysts for producing a crude product |
CA2604015C (en) * | 2005-04-11 | 2014-02-18 | Shell International Research Maatschappij B.V. | Systems, methods, and catalysts for producing a crude product |
MXPA05009283A (es) | 2005-08-31 | 2007-02-27 | Mexicano Inst Petrol | Procedimiento para la preparacion de una composicion catalitica para el hidroprocesamiento de fracciones del petroleo. |
CN101869852B (zh) * | 2009-04-24 | 2014-10-01 | 中国石油化工股份有限公司 | 一种钛改性载体及其制备方法 |
US11084021B2 (en) | 2015-10-27 | 2021-08-10 | W.R. Grace & Co.—Conn | Acid-resistant catalyst supports and catalysts |
CN110773181A (zh) * | 2018-07-31 | 2020-02-11 | 中国石油化工股份有限公司 | 一种加氢活性保护催化剂及其制备与应用 |
CN112973706B (zh) * | 2019-12-15 | 2022-04-22 | 中国科学院大连化学物理研究所 | 一种镍基催化剂及其制备与应用 |
WO2023248198A1 (en) | 2022-06-24 | 2023-12-28 | Chevron U.S.A. Inc. | Renewable solid biomass slurry hydroconversion catalyst, method of making, and slurry hydroconversion process |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3205165A (en) * | 1963-08-23 | 1965-09-07 | Universal Oil Prod Co | Hydrorefining process |
US3401125A (en) * | 1964-05-22 | 1968-09-10 | Chevron Res | Coprecipitation method for making multi-component catalysts |
US3840473A (en) * | 1972-08-09 | 1974-10-08 | Gulf Research Development Co | Hydrodesulfurization catalyst promoted with a group iv-b metal |
US3897365A (en) * | 1973-09-20 | 1975-07-29 | American Cyanamid Co | Hydrotreating catalyst and process therefor |
US4388222A (en) * | 1976-03-29 | 1983-06-14 | Filtrol Corporation | Ni/Co Mo P On titania-alumina hydrodesulfurizing catalyst |
JPS601056B2 (ja) * | 1980-02-19 | 1985-01-11 | 千代田化工建設株式会社 | アスファルテンを含む重質炭化水素油の水素化処理 |
US4465790A (en) * | 1983-03-17 | 1984-08-14 | American Cyanamid Company | Hydrotreating catalyst |
US4490483A (en) * | 1983-05-19 | 1984-12-25 | Gulf Research & Development Company | Process for preparing catalysts |
US4590177A (en) * | 1984-08-10 | 1986-05-20 | Exxon Research And Engineering Co. | Method for preparing dual colloid catalyst compositions |
US4657663A (en) * | 1985-04-24 | 1987-04-14 | Phillips Petroleum Company | Hydrotreating process employing a three-stage catalyst system wherein a titanium compound is employed in the second stage |
US4734186A (en) * | 1986-03-24 | 1988-03-29 | Phillips Petroleum Company | Hydrofining process |
-
1990
- 1990-06-25 US US07/543,257 patent/US5089462A/en not_active Expired - Lifetime
-
1991
- 1991-06-06 EP EP19910911625 patent/EP0536205A4/en not_active Withdrawn
- 1991-06-06 KR KR1019920703368A patent/KR930701229A/ko active IP Right Grant
- 1991-06-06 WO PCT/US1991/003993 patent/WO1992000142A1/en not_active Application Discontinuation
- 1991-06-06 JP JP51148291A patent/JP3246739B2/ja not_active Expired - Fee Related
- 1991-06-06 AU AU80509/91A patent/AU8050991A/en not_active Abandoned
- 1991-10-29 TW TW080108485A patent/TW283727B/zh active
- 1991-11-13 US US07/791,217 patent/US5190641A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5190641A (en) | 1993-03-02 |
TW283727B (ja) | 1996-08-21 |
JP3246739B2 (ja) | 2002-01-15 |
US5089462A (en) | 1992-02-18 |
EP0536205A1 (en) | 1993-04-14 |
AU8050991A (en) | 1992-01-23 |
WO1992000142A1 (en) | 1992-01-09 |
EP0536205A4 (en) | 1993-07-07 |
KR930701229A (ko) | 1993-06-11 |
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