JPH0633385B2 - Gelled fuel composition - Google Patents
Gelled fuel compositionInfo
- Publication number
- JPH0633385B2 JPH0633385B2 JP62065541A JP6554187A JPH0633385B2 JP H0633385 B2 JPH0633385 B2 JP H0633385B2 JP 62065541 A JP62065541 A JP 62065541A JP 6554187 A JP6554187 A JP 6554187A JP H0633385 B2 JPH0633385 B2 JP H0633385B2
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- Prior art keywords
- fuel composition
- water
- weight
- alcohol
- gelled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Description
【発明の詳細な説明】 （産業上の利用分野） 本発明はハイキング、登山等で炊事、暖房用、卓上コン
ロなどの燃料として用いるゲル状燃料組成物に関する。
さらに詳細にはエチレングリコールと炭素数１〜３の一
価アルコールと水および少量の水溶性ポリマーからなる
ゲル状燃料組成物に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a gel fuel composition used as a fuel for cooking, heating, table-top stove, etc. during hiking, mountain climbing and the like.
More specifically, it relates to a gel fuel composition comprising ethylene glycol, a monohydric alcohol having 1 to 3 carbon atoms, water and a small amount of a water-soluble polymer.
（従来技術と問題点） 野外での炊事、暖房が簡単にできたり、室内での卓上コ
ンロにも使用できる持ち運びの便利な燃焼器の利用が、
最近増加してきているが、かかる燃焼器に用いる燃料は
従来からガソリン、灯油などの石油系炭化水素の液状物
が使用されている。これらの燃料は、小型のプラスチッ
ク製燃料タンク等に入れて持ち運びをするのが一般であ
り、水筒の水と間違えて飲んだという事故例もあるほ
か、タンクが万一破損した場合には液状物が漏洩し、衣
類その他持ちものを汚すばかりでなく、特にテント内等
の狭隘な場所および電車内等の混雑した場所での漏洩は
非常に危険を伴なう恐れがあるという問題があった。(Conventional technology and problems) The convenient use of a combustor that can be easily used for outdoor cooking and heating, and can also be used as a tabletop stove indoors,
Although it has been increasing in recent years, liquid fuels of petroleum hydrocarbons such as gasoline and kerosene have been used as fuels for such combustors. Generally, these fuels are carried in small plastic fuel tanks, etc., and there are cases of accidents where they accidentally drank it as water in a water bottle. However, there is a problem in that not only the clothes are leaked and the clothes and other belongings are polluted, but also leakage in a narrow place such as a tent and a crowded place such as a train may be extremely dangerous.
また、メチルアルコールを主成分とする固形あるいはゼ
リー状の燃料も市販されているが、真夏の炎天下では、
蒸気圧が高くなり、例えば８５℃では蒸気圧が２．１kg
／cm2（絶対圧力）に上昇し、燃料容器を破損する危険
性のほか、単位容量当りの発熱量が小さいという欠点を
有していた。In addition, solid or jelly-like fuel containing methyl alcohol as the main component is also commercially available, but under hot summer in the midsummer,
The vapor pressure becomes high, for example, at 85 ℃, the vapor pressure becomes 2.1 kg.
In addition to the risk of damaging the fuel container by increasing the pressure to / cm 2 (absolute pressure), it has the drawback that the calorific value per unit volume is small.
（問題点を解決するための手段） 本発明者らは上記の問題に対処するため、種々検討した
結果、 (イ) ５０重量％以上のエチレングリコール (ロ) １０〜４０重量％の炭素数１〜３の一価アルコー
ル (ハ) ３〜１５重量％の水 (ニ) ０．２〜１重量％の水溶性ポリマー を少なくとも含有することを特徴とするゲル状燃料組成
物を発明するに至った。ここに水溶性ポリマーについて
は、ポリアクリル酸と塩基との塩および／または分子量
が５０万〜１０００万のポリエチレングリコールが特に
適していることは、実施例の通りである。(Means for Solving Problems) As a result of various investigations by the present inventors in order to address the above problems, (a) 50% by weight or more of ethylene glycol (b) 10 to 40% by weight of carbon number 1 To 3 monohydric alcohol (c) at least 3 to 15% by weight of water (d) 0.2 to 1% by weight of a water-soluble polymer, a gel fuel composition has been invented. . As for the water-soluble polymer, the salt of polyacrylic acid and a base and / or polyethylene glycol having a molecular weight of 500,000 to 10,000,000 are particularly suitable as described in the examples.
（作用） 本発明の特徴とするところは、沸点１９８℃のエチレン
グリコールを主成分としているため蒸気圧が低く押える
ことができ、真夏の高温下でも燃料容器を損傷する心配
がなく、さらに炭素数１〜３の一価アルコールが適量混
合されているため、着火性ならびに燃焼性がすぐれてお
り、またこれらの組成の選択により燃料時にすすの発生
がなく、鍋の底部をよごす心配がない等にある。また、
エチレングリコールの比重がメタノールのそれに比較し
て１．３倍であるため、単位体積当りの発熱量がメタノ
ールの１．２倍と、高い点にも特徴がある。従って同一
のものを加熱するのにエチレングリコールを主成分とす
る本発明の燃料組成物は、容量に換算すると少量の消費
量で良いことが判かる。(Function) The feature of the present invention is that the main component is ethylene glycol having a boiling point of 198 ° C., so that the vapor pressure can be suppressed to be low, there is no fear of damaging the fuel container even at a high temperature in midsummer, and the carbon number is further reduced. Since an appropriate amount of 1 to 3 monohydric alcohols are mixed, it has excellent ignitability and combustibility. Also, by selecting these compositions, soot is not generated during fuel, and there is no need to worry about cleaning the bottom of the pot. is there. Also,
Since the specific gravity of ethylene glycol is 1.3 times that of methanol, the calorific value per unit volume is 1.2 times that of methanol, which is also characteristic. Therefore, it can be understood that the fuel composition of the present invention containing ethylene glycol as a main component for heating the same one can consume a small amount in terms of volume.
さらに詳細には、エチレングリコールを主成分とし、こ
れにメチルアルコール、ノルマルプロピルアルコール、
水および水溶性ポリマーにより均一なゲル状となってい
る。More specifically, ethylene glycol as a main component, methyl alcohol, normal propyl alcohol,
A uniform gel is formed by water and water-soluble polymer.
この燃料に着火させると、先ず沸点の低いメチルアルコ
ールおよびノルマルプロピルアルコールが勢いよく燃焼
して鍋の中の水を沸騰させた後、ゲル状となっているエ
チレングリコールが適度に蒸発速度が抑制されつつ、長
時間燃焼して、野外での簡単な炊事、暖房、および、室
内での卓上コンロでの簡単な炊事などの目的を果たすこ
とができる。When this fuel is ignited, first, methyl alcohol and normal propyl alcohol, which have low boiling points, are vigorously burned to boil the water in the pot, and then the evaporation rate of the gelled ethylene glycol is moderately suppressed. While burning for a long time, it can serve the purpose of simple cooking outdoors, heating, and simple cooking on a tabletop stove indoors.
本発明による燃料組成物はゲル状、すなわち半固体状の
ため容器が転倒しても、広範囲に広がることもなく、非
常に安心して使用できる点も特徴としてあげられる。Since the fuel composition according to the present invention is in a gel form, that is, a semi-solid form, even if the container falls, it does not spread over a wide range and can be used with a great sense of security.
よって、本発明による燃料組成物は特に携帯燃料として
適している他、卓上コンロなどの軽便な用途にも使用で
きる。Therefore, the fuel composition according to the present invention is particularly suitable as a portable fuel, and can also be used for convenient applications such as a tabletop stove.
（実施例） つぎに、本発明を実施例により具体的に示すが、その要
旨を越えない限り、この実施例により制限を受けるもの
ではない。(Examples) Next, the present invention will be specifically described with reference to Examples, but the present invention is not limited to these Examples unless the gist thereof is exceeded.
実施例−１ ６０ｇの水に水溶性ポリマーである５ｇのポリアクリル
酸および１ｇの分子量７００万のポリエチレングリコー
ルを溶解させた後、１７０ｇのメチルアルコールおよび
１００ｇのノルマルプロピルアルコールを混合し、均一
になった混合物に６６３．４ｇのエチレングリコールを
加え、さらに０．６ｇのトリエチルアミンを加え、攪拌
を続けると、ちよう度（ＪＩＳ Ｋ−2560の測定法によ
る）が３６０のゲル状の燃料組成物1000ｇを得た。Example 1 After dissolving 5 g of polyacrylic acid, which is a water-soluble polymer, and 1 g of polyethylene glycol having a molecular weight of 7 million in 60 g of water, 170 g of methyl alcohol and 100 g of normal propyl alcohol were mixed to homogenize the mixture. 663.4 g of ethylene glycol was added to the mixture, 0.6 g of triethylamine was further added, and stirring was continued to obtain 1000 g of a gel-like fuel composition having a degree of rotation (according to JIS K-2560) of 360. Obtained.
該ゲル状燃料組成物のうち５５mlを、上部の水平断面が
直径８cmの円形で、下部の断面が同じく直径６cmの円形
で４cmの深さのステンレス製の燃料容器に、充填し、架
台を置き、マッチで容易に点火した後、アルミ製の鍋に
米２合と水をいれて架台の上にのせて、野外にて炊飯し
た。55 ml of the gelled fuel composition was filled in a stainless steel fuel container having a horizontal cross section of 8 cm in diameter at the upper part and a circular cross section of 6 cm in diameter at the lower part and having a depth of 4 cm, and placed a pedestal. After igniting easily with a match, I put 2 go of rice and water in an aluminum pot, put it on a stand, and cooked it outdoors.
２２分後、米は炊き上った。この間何ら燃焼音を発生す
ることなく、かつ臭気もなく快調に燃焼が進行した。After 22 minutes, the rice was cooked. During this period, the combustion proceeded smoothly without producing any burning noise and without odor.
また、得られた本実施例によるゲル状の燃料組成物の８
５℃での蒸気圧を測定したところ、０．８kg／cm2（絶
対圧力）となり、市販されているメチルアルコールを主
成分とする固形あるいは、ゼリー状の燃料の蒸気圧の半
分以下となった。従って、１．０kg／cm2（絶対圧力）
以下のため、沸とう現象は起らない。In addition, 8 of the obtained gel-like fuel composition according to the present example
When the vapor pressure at 5 ° C was measured, it was 0.8 kg / cm 2 (absolute pressure), which was less than half the vapor pressure of commercially available methyl alcohol-based solid or jelly-like fuel. . Therefore, 1.0 kg / cm 2 (absolute pressure)
The boiling phenomenon does not occur because of the following.
実施例−２ ６０ｇの水に水溶性ポリマーである５ｇのポリアクリル
酸を溶解させた後、１７０ｇのメチルアルコールおよび
１００ｇのノルマルプロピルアルコールを混合し、均一
になった混合物に６６４．４ｇのエチレングリコールを
加え、さらに０．６ｇのトリエチルアミンを加え、攪拌
を続けると、ちよう度（ＪＩＳ Ｋ−2560の測定法によ
る）が３９０のゲル状の燃料組成物1000ｇを得た。Example-2 After dissolving 5 g of polyacrylic acid, which is a water-soluble polymer, in 60 g of water, 170 g of methyl alcohol and 100 g of normal propyl alcohol were mixed, and 664.4 g of ethylene glycol was added to the homogenized mixture. Then, 0.6 g of triethylamine was added, and stirring was continued to obtain 1000 g of a gelled fuel composition having a strength (according to the measurement method of JIS K-2560) of 390.
該ゲル状燃料組成物のうち５５mlを、上部の水平断面が
直径８cmの円形で、下部の断面が同じく直径６cmの円形
で４cmの深さのステンレス製の燃焼容器に、充填し、架
台を置き、マッチで容易に点火した後、アルミ製の鍋に
米２合と水をいれて架台の上にのせて、野外にて炊飯し
た。55 ml of the gelled fuel composition was filled into a stainless steel combustion container having a circular cross section with a diameter of 8 cm at the top and a circular cross section with a diameter of 6 cm at the bottom and a depth of 4 cm, and placed a pedestal. After igniting easily with a match, I put 2 go of rice and water in an aluminum pot, put it on a stand, and cooked it outdoors.
２２分後、米は炊き上った。この間何ら燃焼音を発生す
ることなく、かつ、臭気もなく快調に燃焼が進行した。After 22 minutes, the rice was cooked. During this period, the combustion proceeded smoothly without generating any combustion noise and without odor.
実施例−３ ６０ｇの水に５ｇの分子量７００万のポリエチレングリ
コールを溶解させた後、１７０ｇのメチルアルコールお
よび１００ｇのノルマルプロピルアルコールを混合し、
均一になった混合物に６６５．０ｇのエチレングリコー
ルを加え、攪拌を続けると、ちよう度（ＪＩＳ Ｋ−25
60の測定法による）が４０５のゲル状の燃料組成物1000
ｇを得た。Example 3 After dissolving 5 g of polyethylene glycol having a molecular weight of 7 million in 60 g of water, 170 g of methyl alcohol and 100 g of normal propyl alcohol were mixed,
665.0 g of ethylene glycol was added to the homogenized mixture, and stirring was continued.
Gel fuel composition 1000 of 405)
g was obtained.
該ゲル状燃料組成物のうち５５mlを、上部の水平断面が
直径８cmの円形で、下部の断面が同じく直径６cmの円形
で４cmの深さのステンレス製の燃焼容器に、充填し、架
台を置き、マッチで容易に点火した後、アルミ製の鍋に
米２合と水をいれて架台の上にのせて、野外にて炊飯し
た。55 ml of the gelled fuel composition was filled into a stainless steel combustion container having a circular cross section with a diameter of 8 cm at the top and a circular cross section with a diameter of 6 cm at the bottom and a depth of 4 cm, and placed a pedestal. After igniting easily with a match, I put 2 go of rice and water in an aluminum pot, put it on a stand, and cooked it outdoors.
２４分後、米は炊き上った。この間何ら燃焼音を発生す
ることなく、かつ、臭気もなく快調に燃焼が進行した。After 24 minutes, the rice was cooked. During this period, the combustion proceeded smoothly without generating any combustion noise and without odor.
実施例−４ ６０ｇの水に水溶性ポリマーである５ｇのポリアクリル
酸および１ｇの分子量７００万のポリエチレングリコー
ルを溶解させた後、２４０ｇのメチルアルコールおよび
１００ｇのノルマルプロピルアルコールを混合し、均一
になった混合物に５９３．４ｇのエチレングリコールを
加え、さらに０．６ｇのトリエチルアミンを加え、攪拌
を続けるとゲル状の燃料組成物1000ｇを得た。Example 4 After dissolving 5 g of polyacrylic acid, which is a water-soluble polymer, and 1 g of polyethylene glycol having a molecular weight of 7 million in 60 g of water, 240 g of methyl alcohol and 100 g of normal propyl alcohol were mixed to homogenize the mixture. 593.4 g of ethylene glycol was added to the above mixture, 0.6 g of triethylamine was further added, and stirring was continued to obtain 1000 g of a gelled fuel composition.
つぎに、上部の水平断面が直径８cmの円形で、下部の断
面が同じく直径６cmの円形で４cmの深さのステンレス製
の燃焼容器に、該ゲル状燃料組成物のうち５５mlを充填
し、家庭の食卓の中央に置き、湯豆腐の材料５人分を入
れたアルミ製鍋を架台にのせ、マッチにて該燃料に点火
した。Next, 55 ml of the gelled fuel composition was filled into a stainless steel combustion container having a horizontal cross section of 8 cm in diameter at the upper part and a circular cross section of 6 cm in diameter at the lower part and having a depth of 4 cm. Was placed in the center of the table, and an aluminum pan containing 5 ingredients of yudofu was placed on a stand and the fuel was lit at a match.
約１７分後、適温の湯豆腐となり、この間何ら燃焼音を
発生することなく、かつ、臭気もなく快調に燃焼が進行
した。After about 17 minutes, the tofu was heated to an appropriate temperature, and during this period, no burning noise was generated, and the combustion proceeded smoothly without odor.
また、得られた本実施例によるゲル状の燃料組成物の８
５℃での蒸気圧を測定したところ、０．９kg／cm2（絶
対圧力）となり、市販されているメチルアルコールを主
成分とする固形あるいは、ゼリー状の燃料の蒸気圧の半
分以下となった。従って１．０kg／cm2（絶対圧力）以
下のため、沸とう現象は起らない。In addition, 8 of the obtained gel-like fuel composition according to the present example
When the vapor pressure at 5 ° C was measured, it was 0.9 kg / cm 2 (absolute pressure), which was less than half of the vapor pressure of commercially available solid or jelly fuel containing methyl alcohol as the main component. . Therefore, since it is 1.0 kg / cm 2 (absolute pressure) or less, the boiling phenomenon does not occur.
比較例−１ １２０ｇの水に８６０ｇのメチルアルコールを混合し、
さらに２０ｇの分子量３００万のポリエチレングリコー
ルを徐々に溶解させることによりゲル状の燃料組成物10
00ｇを得た。Comparative Example-1 120 g of water was mixed with 860 g of methyl alcohol,
Further, by gradually dissolving 20 g of polyethylene glycol having a molecular weight of 3,000,000, the gelled fuel composition 10
I got 00g.
該ゲル状燃料組成物のうち５５mlを、上部の水平断面が
直径８cmの円形で、下部の断面が同じく直径６cmの円形
で４cmの深さのステンレス製の燃焼容器に、充填し、架
台を置き、マッチで容易に点火した後、アルミ製の鍋に
米２合と水をいれて架台の上にのせ、放置した。55 ml of the gelled fuel composition was filled into a stainless steel combustion container having a circular cross section with a diameter of 8 cm at the top and a circular cross section with a diameter of 6 cm at the bottom and a depth of 4 cm, and placed a pedestal. After igniting easily with a match, put 2 go of rice and water in an aluminum pot, put it on a stand, and let it stand.
１５分後、燃料が無くなり火炎が消失した。なお、米は
炊き上っていなかった。After 15 minutes, the fuel ran out and the flame disappeared. The rice was not cooked.
また、得られた、本比較例によるゲル状の燃料組成物の
８５℃での蒸気圧を測定したところ、２．３kg／cm
2（絶対圧力）となり、ポリエチレン製の容器が破損
し、ゲル状の燃料組成物が飛散した。The vapor pressure of the obtained gel fuel composition according to this comparative example at 85 ° C. was measured to be 2.3 kg / cm 2.
At 2 (absolute pressure), the polyethylene container was damaged and the gelled fuel composition was scattered.
（発明の効果） 本発明による実施例−１乃至実施例−４および比較例−
１から明らかなように、本発明によるエチレングリコー
ルを主成分とするゲル状燃料組成物は、従来のメタノー
ルを主成分とするものと異なり、炊事等の燃焼に際して
は適格に利用することができる。(Effects of the Invention) Examples 1 to 4 and Comparative Example according to the present invention
As is clear from 1, the gelled fuel composition containing ethylene glycol as a main component according to the present invention can be properly used in combustion such as cooking, unlike the conventional one containing methanol as a main component.
また、貯蔵についても、８５℃といった高温下でも圧力
の増加が小さく安定に貯蔵することができる。Also, as for storage, the increase in pressure is small even under a high temperature of 85 ° C., and stable storage is possible.
よって、携帯燃料として優れている他、卓上コンロ用燃
料等としても優れた効果が期待できる。Therefore, in addition to being excellent as a portable fuel, an excellent effect can be expected as a fuel for a tabletop stove and the like.
Claims (5)
ル (ハ) ３〜１５重量％の水 (ニ) ０．２〜１重量％の水溶性ポリマー を少なくとも含有することを特徴とするゲル状燃料組成
物。1. The following components (a) 50% by weight or more of ethylene glycol (b) 10 to 40% by weight of monohydric alcohol having 1 to 3 carbon atoms (c) 3 to 15% by weight of water (d) 0 A gelled fuel composition comprising at least 2 to 1% by weight of a water-soluble polymer.
３の一価アルコールが、メチルアルコール、エチルアル
コール、イソプロピルアルコール、ノルマルプロピルア
ルコールのうち単体もしくはこれらの２つ以上の混合物
であるゲル状燃料組成物。2. A carbon number 1 to 1 according to claim 1.
The gel fuel composition in which the monohydric alcohol 3 is a single substance of methyl alcohol, ethyl alcohol, isopropyl alcohol, and normal propyl alcohol, or a mixture of two or more thereof.
マーがポリアクリル酸と塩基との塩および／または分子
量が５０万〜1000万のポリエチレングリコールであるゲ
ル状燃料組成物。3. A gelled fuel composition, wherein the water-soluble polymer according to claim 1 is a salt of polyacrylic acid and a base and / or polyethylene glycol having a molecular weight of 500,000 to 10,000,000.
組成物からなる携帯燃料組成物。4. A portable fuel composition comprising the gelled fuel composition according to claim 1.
組成物からなる卓上コンロ用燃料組成物。5. A fuel composition for a tabletop stove, comprising the gel fuel composition according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62065541A JPH0633385B2 (en) | 1986-12-16 | 1987-03-23 | Gelled fuel composition |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29758186 | 1986-12-16 | ||
| JP61-297581 | 1986-12-16 | ||
| JP62065541A JPH0633385B2 (en) | 1986-12-16 | 1987-03-23 | Gelled fuel composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63270797A JPS63270797A (en) | 1988-11-08 |
| JPH0633385B2 true JPH0633385B2 (en) | 1994-05-02 |
Family
ID=26406688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62065541A Expired - Fee Related JPH0633385B2 (en) | 1986-12-16 | 1987-03-23 | Gelled fuel composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0633385B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007516305A (en) * | 2003-06-25 | 2007-06-21 | ザ ルブリゾル コーポレイション | Fuel gel additive that reduces soot and / or emissions from the engine |
| KR101480556B1 (en) * | 2008-04-18 | 2015-01-09 | 마사히로 고조네 | Process of fossil oil mixed water fuel additive and process of water fossil oil fuel |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4686052B2 (en) * | 2001-05-11 | 2011-05-18 | 株式会社カネコ | Candle burning liquid |
| KR100738811B1 (en) | 2006-02-16 | 2007-07-12 | 고재훈 | Fuel gel composition and method of manufacture |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4935401A (en) * | 1972-08-08 | 1974-04-02 | ||
| JPS50138001A (en) * | 1974-04-22 | 1975-11-04 |
-
1987
- 1987-03-23 JP JP62065541A patent/JPH0633385B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007516305A (en) * | 2003-06-25 | 2007-06-21 | ザ ルブリゾル コーポレイション | Fuel gel additive that reduces soot and / or emissions from the engine |
| KR101480556B1 (en) * | 2008-04-18 | 2015-01-09 | 마사히로 고조네 | Process of fossil oil mixed water fuel additive and process of water fossil oil fuel |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63270797A (en) | 1988-11-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |