CN108359511A - A kind of military solid alcohol fuel of environment-friendly type - Google Patents

A kind of military solid alcohol fuel of environment-friendly type Download PDF

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Publication number
CN108359511A
CN108359511A CN201810147041.1A CN201810147041A CN108359511A CN 108359511 A CN108359511 A CN 108359511A CN 201810147041 A CN201810147041 A CN 201810147041A CN 108359511 A CN108359511 A CN 108359511A
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China
Prior art keywords
parts
environment
friendly type
fuel
military
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810147041.1A
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Chinese (zh)
Inventor
张成如
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Beijing Oumeizhong Science and Technology Research Institute
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Beijing Oumeizhong Science and Technology Research Institute
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Priority to CN201810147041.1A priority Critical patent/CN108359511A/en
Publication of CN108359511A publication Critical patent/CN108359511A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L7/00Fuels produced by solidifying fluid fuels
    • C10L7/02Fuels produced by solidifying fluid fuels liquid fuels
    • C10L7/04Fuels produced by solidifying fluid fuels liquid fuels alcohol
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

The invention discloses a kind of military solid alcohol fuels of environment-friendly type, belong to clean energy technology field, including gelling agent, stabilizer, main fuel and antismoke agent and water, it is characterized in that, the gelling agent and antismoke agent are all stearic acid and/or nitrocellulose, and the stabilizer and the ethanol solution mixed liquor that combustion adjuvant is all methanol and purity is 98%, further include combustion adjuvant paraffin, 18% sodium hydrate aqueous solution body, water are distilled water;Also contain polyacrylic acid Chitosan Ester, by mixing, stirring, heats, is cooled into the pure fuel of solid.The present invention has the beneficial effect that:The product of the present invention is easily lighted, combustion heat value is high, without black smoke, free from extraneous odour, and residue is few after burning, under conditions of vacuum anoxic, flameholding can be still kept, flame is vigorous, has good combustibility, and syneresis, period of storage be not long when storing, suitable for being used as military fuel.

Description

A kind of military solid alcohol fuel of environment-friendly type
Technical field
The invention discloses a kind of military solid alcohol fuels of environment-friendly type, belong to clean energy technology field.
Background technology
Solid fuel can be carried around as one kind, safe ready, economical and practical heat source have been widely used for it is military and It is civilian, still, since common solid fuel is also easy to produce in burning to human body and the harmful oxynitrides of environment, and it is not easy Fully burning, will produce a large amount of black smokes, and pollution heating apparatus is made troubles to reuse.
Existing solid alcohol fuel is easy for that local gelling phenomenon occurs, is difficult to realize industrialized in preparation process Continuous production;And exist it is heated easily melt, energy and calorific value are low, and when burning is easily wandering, and residue is more after burning, and hardness is inadequate, And it cannot preserve for a long time, the requirement of quartermaster equipment exhibition area cannot be met.
Invention content
For the problems of the prior art, the present invention provides a kind of stability height, calorific value is big and the ring of storage time length The military solid alcohol fuel of guarantor's type, to substitute the military solid fuel of tradition, the present invention program is as follows.
A kind of military solid alcohol fuel of environment-friendly type, including gelling agent, stabilizer, main fuel and antismoke agent and water, wherein institute It is stearic acid and/or nitrocellulose, the stabilizer and combustion adjuvant is all methanol and purity is to state gelling agent and antismoke agent all 98% ethanol solution mixed liquor further includes combustion adjuvant paraffin, and 18% sodium hydrate aqueous solution body, water is distilled water;Also contain poly- Acrylic acid Chitosan Ester.
Preferably, the above-mentioned military solid alcohol fuel of a kind of environment-friendly type, by weight, including 8-15 parts of stearic acid, methanol 20-30 parts of ethanol solution mixed liquor for being 98% with purity, 5-10 parts of paraffin, 18% 3-6 parts of sodium hydrate aqueous solution body, distilled water 8-12 parts, 2-5 parts of nitrocellulose, 2-5 parts of polyacrylic acid Chitosan Ester by mixing, stirring, heats, is cooled into solid Pure fuel.
Preferably, the above-mentioned military solid alcohol fuel of a kind of environment-friendly type, by weight, including 8-15 parts of stearic acid, methanol 20-30 parts of ethanol solution mixed liquor for being 98% with purity, 5-10 parts of paraffin, 18% 3-6 parts of sodium hydrate aqueous solution body, distilled water 8-12 parts, 2-5 parts of polyacrylic acid Chitosan Ester by mixing, stirring, heats, is cooled into the pure fuel of solid.
Preferably, the above-mentioned military solid alcohol fuel of a kind of environment-friendly type, by weight, including 11 parts of stearic acid, methanol and 25 parts of the ethanol solution mixed liquor that purity is 98%, 8 parts of paraffin, 18% 5 parts of sodium hydrate aqueous solution body, 10 parts of distilled water, nitrification 4 parts of cellulose, 3 parts of polyacrylic acid Chitosan Ester by mixing, stirring, heat, are cooled into the pure fuel of solid.
Preferably, above-mentioned heating temperature is 70 DEG C, and by practice, the solid alcohol fuel that the present invention obtains at this temperature is imitated Fruit is best.
Preferably, the ethanol solution mixed liquor proportioning that above-mentioned methanol and purity are 98% is 2:3, by many experiments and Performance test, the ratio are bringd into play most useful for by the performance of methanol and ethyl alcohol, the fuel value highest of obtained product.
Preferably, the invention also includes corrosion inhibitor, the corrosion inhibitor is 1-2 parts of citric acids, prevents solid alcohol Fuel corrodes when in use, extends solid alcohol fuel service life.
Preferably, the invention also includes 1-2 parts of combustion adjuvant methyl cyclopentadiene trihydroxy manganese, be conducive to further increase combustion Burning value.
Preferably, it the invention also includes 1-2 parts of eliminating smell agent camphor, prevents solid alcohol fuel from having peculiar smell, influences user, profit In militarily using, the interference of taste is prevented.
Above-mentioned polyacrylic acid Chitosan Ester is conducive to fully combine the propellant composition of the present invention, convenient follow-up use.
The preparation method is that:All operationss carry out at 70 DEG C, by raw material by mixing, stirring, heating, cooling Solid alcohol fuel is made in process.
Present invention advantageous effect compared with prior art:With easily light, combustion heat value is high, without black smoke, free from extraneous odour, combustion Residue is few after burning, the features such as not softening separation, especially under conditions of vacuum anoxic, can still keep flameholding, flame It is vigorous, there is good combustibility, still can burn in the plateau of more than 6300 meters of height above sea level or mountain environment, be other What similar product cannot achieve, do not melt when scorching soldier's field exercise and plateau mountain operations burn, does not scatter, be no different Taste, flame stabilization is in light blue, to stove without any corrosivity, without ashes, no blacking pan bottom after burning, and when storing not from Slurry, period of storage are long.
Specific implementation mode
The invention will now be further described with reference to specific embodiments, the advantages and features of the present invention will be with description and It is apparent.
Embodiment 1
Every part of the present embodiment is 1kg.
A kind of military solid alcohol fuel of environment-friendly type of the present embodiment, including gelling agent, stabilizer, main fuel and antismoke agent and Water, wherein by weight, including following components, 8 parts of stearic acid, methanol and purity are 98% ethanol solution mixed liquor 20 Part, 10 parts of paraffin, 18% 3 parts of sodium hydrate aqueous solution body, 12 parts of distilled water, 2 parts of nitrocellulose, polyacrylic acid Chitosan Ester 5 Part, 1 part of citric acid;2 parts of methyl cyclopentadiene trihydroxy manganese;1 part of camphor by mixing, stirring, heats, is cooled into solid Pure fuel;Heating temperature is 70 DEG C;The ethanol solution mixed liquor proportioning that methanol and purity are 98% is 2:3.
Embodiment 2
Every part of the present embodiment is 2kg.
A kind of military solid alcohol fuel of environment-friendly type of the present embodiment, including gelling agent, stabilizer, main fuel and antismoke agent and Water, wherein by weight, including following components, 15 parts of stearic acid, methanol and purity are 98% ethanol solution mixed liquor 30 Part, 5 parts of paraffin, 18% 6 parts of sodium hydrate aqueous solution body, 8 parts of distilled water, 5 parts of nitrocellulose, polyacrylic acid Chitosan Ester 2 Part, 2 parts of citric acid;1 part of methyl cyclopentadiene trihydroxy manganese;2 parts of camphor by mixing, stirring, heats, is cooled into solid Pure fuel;Heating temperature is 70 DEG C;The ethanol solution mixed liquor proportioning that methanol and purity are 98% is 2:3.
Embodiment 3
Every part of the present embodiment is 5kg.
A kind of military solid alcohol fuel of environment-friendly type of the present embodiment, including gelling agent, stabilizer, main fuel and antismoke agent and Water, wherein by weight, including following components, 11 parts of stearic acid, methanol and purity are 98% ethanol solution mixed liquor 25 Part, 8 parts of paraffin, 18% 5 parts of sodium hydrate aqueous solution body, 10 parts of distilled water, 4 parts of nitrocellulose, polyacrylic acid Chitosan Ester 3 Part, 1 part of citric acid;2 parts of methyl cyclopentadiene trihydroxy manganese;1 part of camphor by mixing, stirring, heats, is cooled into solid Pure fuel;Heating temperature is 70 DEG C;The ethanol solution mixed liquor proportioning that methanol and purity are 98% is 2:3.
Embodiment 4
Every part of the present embodiment is 10kg.
A kind of military solid alcohol fuel of environment-friendly type of the present embodiment, including gelling agent, stabilizer, main fuel and antismoke agent and Water, wherein by weight, including following components, 11 parts of stearic acid, methanol and purity are 98% ethanol solution mixed liquor 25 Part, 8 parts of paraffin, 18% 5 parts of sodium hydrate aqueous solution body, 10 parts of distilled water, 4 parts of nitrocellulose, polyacrylic acid Chitosan Ester 3 Part, by mixing, stirring, heats, is cooled into the pure fuel of solid;Heating temperature is 70 DEG C;The ethyl alcohol that methanol and purity are 98% Solution mixed liquor proportioning is 2:3.
Embodiment 5
Every part of the present embodiment is 15kg.
A kind of military solid alcohol fuel of environment-friendly type of the present embodiment, including gelling agent, stabilizer, main fuel and antismoke agent and Water, wherein by weight, including following components, 8 parts of stearic acid, methanol and purity are 98% ethanol solution mixed liquor 30 Part, 5 parts of paraffin, 18% 3 parts of sodium hydrate aqueous solution body, 2 parts of distilled water, 5 parts of polyacrylic acid Chitosan Ester, 1 part of citric acid;First 1 part of butylcyclopentadiene trihydroxy manganese;2 parts of camphor by mixing, stirring, heats, is cooled into the pure fuel of solid;Heating temperature It is 70 DEG C;The ethanol solution mixed liquor proportioning that methanol and purity are 98% is 2:3.
Embodiment 6
Every part of the present embodiment is 20kg.
A kind of military solid alcohol fuel of environment-friendly type of the present embodiment, including gelling agent, stabilizer, main fuel and antismoke agent and Water, wherein by weight, including following components, 8 parts of stearic acid, methanol and purity are 98% ethanol solution mixed liquor 30 Part, 5 parts of paraffin, 18% 3 parts of sodium hydrate aqueous solution body, 2 parts of distilled water, 5 parts of polyacrylic acid Chitosan Ester, by mixing, stirring It mixes, heat, being cooled into the pure fuel of solid;Heating temperature is 70 DEG C;The ethanol solution mixed liquor that methanol and purity are 98% matches It is 2:3.
Embodiment 7
Every part of the present embodiment is 1kg.
A kind of military solid alcohol fuel of environment-friendly type of the present embodiment, including gelling agent, stabilizer, main fuel and antismoke agent and Water, wherein by weight, including following components, 8 parts of stearic acid, 30 parts of methanol, 2 parts of distilled water are cooled down by being mixed At solid alcohol fuel.
The solid alcohol fuel obtained with 7 commonsense method of embodiment by the solid alcohol fuel obtained to embodiment 1-6 carries out Comparison knows that the product of the present invention is easily lighted, combustion heat value is high, without black smoke, free from extraneous odour, and residue is few after burning, in vacuum anoxic Under conditions of, flameholding can be still kept, flame is vigorous, not syneresis, storage when having good combustibility, and storing It is long to deposit the time, suitable for being used as military fuel.
But examples are merely exemplary, and it is not intended to limit the scope of the present invention in any way;Those skilled in the art answer It should be appreciated that can be repaiied without departing from the spirit and scope of the invention to the details and form of technical solution of the present invention Change or replace, but these modifications and replacement are each fallen in protection scope of the present invention.

Claims (9)

1. a kind of military solid alcohol fuel of environment-friendly type, including gelling agent, stabilizer, main fuel and antismoke agent and water, feature exist All it is stearic acid and/or nitrocellulose in, the gelling agent and antismoke agent, the stabilizer and combustion adjuvant are all methanol and pure Degree is 98% ethanol solution mixed liquor, further includes combustion adjuvant paraffin, 18% sodium hydrate aqueous solution body, water is distilled water;Also contain There is polyacrylic acid Chitosan Ester.
2. the military solid alcohol fuel of a kind of environment-friendly type according to claim 1, which is characterized in that by weight, including 20-30 parts of the ethanol solution mixed liquor that 8-15 parts of stearic acid, methanol and purity are 98%, 5-10 parts of paraffin, 18% sodium hydroxide water 3-6 parts of solution body, 8-12 parts of distilled water, 2-5 parts of nitrocellulose, 2-5 parts of polyacrylic acid Chitosan Ester, by mixing, stirring, It heats, be cooled into the pure fuel of solid.
3. the military solid alcohol fuel of a kind of environment-friendly type according to claim 1, which is characterized in that by weight, including 20-30 parts of the ethanol solution mixed liquor that 8-15 parts of stearic acid, methanol and purity are 98%, 5-10 parts of paraffin, 18% sodium hydroxide water 3-6 parts of solution body, 8-12 parts of distilled water, 2-5 parts of polyacrylic acid Chitosan Ester, by mixing, stirring, heat, be cooled into it is solid The pure fuel of body.
4. the military solid alcohol fuel of a kind of environment-friendly type according to claim 2, which is characterized in that by weight, including 25 parts of the ethanol solution mixed liquor that 11 parts of stearic acid, methanol and purity are 98%, 8 parts of paraffin, 18% sodium hydrate aqueous solution body 5 Part, 10 parts of distilled water, 4 parts of nitrocellulose, 3 parts of polyacrylic acid Chitosan Ester, by mixing, stirring, heat, be cooled into it is solid The pure fuel of body.
5. the military solid alcohol fuel of a kind of environment-friendly type according to Claims 2 or 3 or 4, which is characterized in that the heating temperature Degree is 70 DEG C.
6. the military solid alcohol fuel of a kind of environment-friendly type according to Claims 1-4, which is characterized in that the methanol and The ethanol solution mixed liquor proportioning that purity is 98% is 2:3.
7. the military solid alcohol fuel of a kind of environment-friendly type according to any one of claims 1 to 4, which is characterized in that further include Corrosion inhibitor, the corrosion inhibitor are 1-2 parts of citric acids.
8. the military solid alcohol fuel of a kind of environment-friendly type according to any one of claims 1 to 4, which is characterized in that further include 1-2 parts of combustion adjuvant methyl cyclopentadiene trihydroxy manganese.
9. the military solid alcohol fuel of a kind of environment-friendly type according to any one of claims 1 to 4, which is characterized in that further include 1-2 parts of eliminating smell agent camphor.
CN201810147041.1A 2018-02-12 2018-02-12 A kind of military solid alcohol fuel of environment-friendly type Pending CN108359511A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109536236A (en) * 2018-11-30 2019-03-29 乐山师范学院 Application, solid alcohol and preparation method of the biodiesel in solid alcohol preparation
CN113637512A (en) * 2021-08-25 2021-11-12 张国 Alcohol-based solid fuel and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944603A (en) * 2006-11-02 2007-04-11 中国人民解放军总后勤部军需装备研究所 Solid alcohol fuel and its preparing method
CN1966630A (en) * 2006-11-27 2007-05-23 华南理工大学 Solid methanol fuel and preparation method thereof
CN101418244A (en) * 2008-11-24 2009-04-29 山西东方深蓝醇醚燃料科技有限公司 Alcohol-base liquid fuel
CN103710055A (en) * 2013-11-27 2014-04-09 湖北力瑞新能源科技有限公司 Alcohol-based liquid fuel and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944603A (en) * 2006-11-02 2007-04-11 中国人民解放军总后勤部军需装备研究所 Solid alcohol fuel and its preparing method
CN1966630A (en) * 2006-11-27 2007-05-23 华南理工大学 Solid methanol fuel and preparation method thereof
CN101418244A (en) * 2008-11-24 2009-04-29 山西东方深蓝醇醚燃料科技有限公司 Alcohol-base liquid fuel
CN103710055A (en) * 2013-11-27 2014-04-09 湖北力瑞新能源科技有限公司 Alcohol-based liquid fuel and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109536236A (en) * 2018-11-30 2019-03-29 乐山师范学院 Application, solid alcohol and preparation method of the biodiesel in solid alcohol preparation
CN113637512A (en) * 2021-08-25 2021-11-12 张国 Alcohol-based solid fuel and preparation method thereof

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Application publication date: 20180803

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