JPH06166300A - Liquid pressure transfer printed article and it production - Google Patents

Liquid pressure transfer printed article and it production

Info

Publication number
JPH06166300A
JPH06166300A JP34314792A JP34314792A JPH06166300A JP H06166300 A JPH06166300 A JP H06166300A JP 34314792 A JP34314792 A JP 34314792A JP 34314792 A JP34314792 A JP 34314792A JP H06166300 A JPH06166300 A JP H06166300A
Authority
JP
Japan
Prior art keywords
transfer
water
pattern
ink
printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP34314792A
Other languages
Japanese (ja)
Other versions
JP3249211B2 (en
Inventor
Mitsunori Agui
満範 安喰
Nobuyuki Otaki
信之 大滝
Kiyoshi Watanabe
清 渡辺
Takeshi Niwa
武 丹羽
Toshio Inoue
寿夫 井上
Original Assignee
Kiyuubitsuku:Kk
株式会社キュービック
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kiyuubitsuku:Kk, 株式会社キュービック filed Critical Kiyuubitsuku:Kk
Priority to JP34314792A priority Critical patent/JP3249211B2/en
Publication of JPH06166300A publication Critical patent/JPH06166300A/en
Application granted granted Critical
Publication of JP3249211B2 publication Critical patent/JP3249211B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To improve a feel of a second transfer layer by an execution of coloring through a mutual interference execution of a pearl gloss pigment between a first transfer layer ink or a base color, or by generating a depth feeling and a gloss one. CONSTITUTION:There are included a first transfer layer L1 consisting of a dense concentration color group pattern P1 on a surface of a body 20 to be transferred, and a second transfer layer L2 consisting of a grain pattern P2 on this first transfer layer, and further in this second transfer layer a pearl gloss pigment G is dispersed.

Description

【発明の詳細な説明】Detailed Description of the Invention
【0001】[0001]
【発明の目的】[Object of the Invention]
【産業上の利用分野】本発明は例えばプラスチック素
材、金属素材、セラミックス素材等から成る半製品に特
殊な表面処理を施した液圧転写品に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hydraulic transfer product obtained by subjecting a semi-finished product made of, for example, a plastic material, a metal material, a ceramic material or the like to a special surface treatment.
【0002】[0002]
【発明の背景】曲面に印刷する方法の一つとして、いわ
ゆる液圧転写印刷がある。この印刷方法は、転写パター
ンの印刷された水溶性薄膜に活性剤を塗工して転写パタ
ーンのインクを活性化し、このものを水面に浮かべた状
態で、被転写体を水溶性薄膜に押し付けて、水圧により
転写パターンを被転写体に転写するというものであり、
例えばパターンの転写された部分と転写されずに被転写
体の地色がそのまま出ている部分との色の差や、二色以
上のインクで印刷されたパターンを適用する場合には、
被転写体の地色との重なり合いによってできる色同士の
差によって、種々の模様を描きだすことができるもので
ある。しかし、この手法は種々のパターン模様を描き出
すことができるものの、質感はパターンのインクのもつ
質感を越えることができず、一定の限界がある。
BACKGROUND OF THE INVENTION One of the methods for printing on a curved surface is so-called hydraulic transfer printing. In this printing method, an activator is applied to the water-soluble thin film on which the transfer pattern is printed to activate the ink in the transfer pattern, and while this is floated on the water surface, the transfer target is pressed against the water-soluble thin film. , The transfer pattern is transferred to the transfer target by water pressure,
For example, when applying a color difference between the transferred part of the pattern and the part where the background color of the transfer target is not transferred or is printed, or when applying a pattern printed with two or more colors of ink,
Various patterns can be drawn by the difference between the colors formed by the overlap with the background color of the transferred material. However, although this method can draw various patterns, the texture has a certain limit because it cannot exceed the texture of the ink of the pattern.
【0003】一方今日では自然派指向のブームの中で、
木調の風合いを有する商品の人気が高まっているが、木
材は高価なうえに加工が困難である。そこで液圧転写印
刷で例えば銘木の木目模様を印刷することが試みられて
いるが、木材を加工した製品と比べると、深み感や照り
感の点で見劣りしてしまう。
On the other hand, in today's natural-oriented boom,
Although wood-like products are becoming more popular, wood is expensive and difficult to process. Therefore, it has been attempted to print, for example, a wood grain pattern of a name tree by hydraulic transfer printing, but it is inferior in terms of depth feeling and shiny feeling compared to a product obtained by processing wood.
【0004】[0004]
【開発を試みた技術的事項】本発明はこのような背景に
鑑みなされたものであって、例えば木質等の素材の質感
により近づけることができるような液圧転写印刷方法の
開発を試みたものである。
[Technical Items Attempted to Develop] The present invention has been made in view of such a background, and an attempt has been made to develop a hydraulic transfer printing method that can be made closer to the texture of a material such as wood. Is.
【0005】[0005]
【発明の構成】[Constitution of the invention]
【目的達成の手段】即ち本出願に係る第一の発明たる液
圧転写印刷品は、被転写体の表面に濃色系パターンから
成る第一の転写層を有し、この第一の転写層の上に木目
模様のパターンから成る第二の転写層を有し、且つ第二
の転写層には真珠光沢顔料が分散していることを特徴と
する。
[Means for Achieving the Object] That is, the first aspect of the present invention, which is a hydraulic transfer printed product, has a first transfer layer having a dark color pattern on the surface of a transfer target. It is characterized in that it has a second transfer layer composed of a woodgrain pattern on the top, and that the pearlescent pigment is dispersed in the second transfer layer.
【0006】また本出願に係る第二の発明たる液圧転写
印刷品の印刷方法は、転写パターンをインクで印刷した
水溶性薄膜を、そのインクの活性状態で水面上に浮か
べ、この水溶性薄膜の上から被転写体を押し付けて被転
写体の一部または全部を水面下に没入し、水圧で前記転
写パターンを被転写体に転写するとともに前記水溶性薄
膜を水で除去し、乾燥後トップコートを行なって被転写
体に前記転写パターンを印刷するにあたり、前記イン
ク、このインクの活性剤または前記トップコートの塗料
のいずれか一または二以上に真珠光沢顔料を含むことを
特徴とする。
A second aspect of the present invention, which is a method for printing a hydraulic transfer printed product, is a method for printing a water-soluble thin film on which a transfer pattern is printed with ink, which is floated on the water surface in the active state of the ink. Press the transfer target from above to immerse part or all of the transfer target below the surface of the water, transfer the transfer pattern to the transfer target by hydraulic pressure, remove the water-soluble thin film with water, and dry to top coat When the transfer pattern is printed on the transfer target by performing the above step, any one or more of the ink, the activator of the ink, and the paint of the top coat contains a pearlescent pigment.
【0007】また更に本出願に係る第三の発明たる液圧
転写印刷品の印刷方法は、前記要件に加えて第一の転写
パターンをインクで印刷した水溶性薄膜を、そのインク
の活性状態で水面上に浮かべ、この水溶性薄膜の上から
被転写体を押し付けて被転写体の一部または全部を水面
下に没入し、水圧で前記第一の転写パターンを被転写体
に転写するとともに水溶性薄膜を水で除去後、乾燥して
第一の転写層を形成し、次に第二の転写パターンをイン
クで印刷した水溶性薄膜を、そのインクの活性状態で水
面上に浮かべ、この水溶性薄膜の上から前記第一の転写
層が形成された被転写体を押し付けて被転写体の一部ま
たは全部を水面下に没入し、水圧で前記第二の転写パタ
ーンを前記被転写体の第一の転写層に重ねて転写すると
ともに水溶性薄膜を水で除去後、乾燥して第二の転写層
を形成し、更にトップコートを行なうとともに、前記第
二の転写層の形成過程では、転写パターンのインク、こ
のインクの活性剤またはトップコートの塗料のいずれか
一または二以上に真珠光沢顔料を含むことを特徴とす
る。
Furthermore, in addition to the above-mentioned requirements, the third aspect of the present invention provides a method for printing a hydraulic transfer printing product, wherein a water-soluble thin film obtained by printing the first transfer pattern with an ink is applied to the water surface in the active state of the ink. Float on top, press the transfer target from above this water-soluble thin film to immerse part or all of the transfer target below the water surface, and transfer the first transfer pattern to the transfer target by water pressure and After removing the thin film with water, it is dried to form the first transfer layer, then the water-soluble thin film on which the second transfer pattern is printed with ink is floated on the water surface in the active state of the ink, The transfer target on which the first transfer layer is formed is pressed from above the thin film to immerse part or all of the transfer target below the water surface, and the second transfer pattern is moved to the first transfer target of the transfer target by hydraulic pressure. Water-soluble thin film as well as transfer to one transfer layer After removing with water, it is dried to form a second transfer layer, and further topcoat is performed. In the process of forming the second transfer layer, the transfer pattern ink, the activator of this ink or the topcoat paint is used. Any one or two or more of pearlescent pigments are included.
【0008】また更に本出願に係る第四の発明たる液圧
転写印刷品の印刷方法は、前記要件に加えて前記第二の
転写層の形成過程では、前記第二の転写パターンがイン
クで印刷された水溶性薄膜を、真珠光沢顔料を含む活性
剤で活性化させた状態で水面上に浮かべ、この水溶性薄
膜の上から前記第一の転写層が形成された被転写体を押
し付けて水圧で第二の転写パターンを転写することを特
徴とする。
Furthermore, in addition to the above-mentioned requirements, in the method of printing a hydraulic transfer printed product according to a fourth invention of the present application, the second transfer pattern is printed with ink in the process of forming the second transfer layer. The water-soluble thin film is floated on the water surface in a state where it is activated by an activator containing a pearlescent pigment, and the transferred body on which the first transfer layer is formed is pressed from above the water-soluble thin film by water pressure. It is characterized in that the second transfer pattern is transferred.
【0009】また更に本出願に係る第五の発明たる液圧
転写印刷品の印刷方法は、前記要件に加えて前記第一の
転写パターンのインクは濃色系であることを特徴とす
る。
Further, in addition to the above requirements, the printing method of the hydraulic transfer printing product according to the fifth invention of the present application is characterized in that the ink of the first transfer pattern is a dark color system.
【0010】また更に本出願に係る第六の発明たる液圧
転写印刷品の印刷方法は、前記要件に加えて前記第一の
転写パターンはドット状であることを特徴とする。
Furthermore, in addition to the above-mentioned requirements, the printing method of the hydraulic transfer printed article according to the sixth invention of the present application is characterized in that the first transfer pattern is dot-shaped.
【0011】また更に本出願に係る第七の発明たる液圧
転写印刷品の印刷方法は、前記要件に加えて前記第二の
転写パターンは木目模様であることを特徴とする。
Further, the printing method of the hydraulic transfer printing product according to the seventh invention of the present application is characterized in that, in addition to the above requirements, the second transfer pattern is a wood grain pattern.
【0012】また更に本出願に係る第八の発明たる液圧
転写印刷品の印刷方法は、前記要件に加えて前記第一の
転写層の形成後、クリヤコートを行なうことを特徴とす
る。これら発明により前記目的を達成せんとするもので
ある。
Furthermore, in addition to the above requirements, the printing method of the hydraulic transfer printed article according to the eighth invention of the present application is characterized in that a clear coat is performed after the formation of the first transfer layer. The above objects are achieved by these inventions.
【0013】[0013]
【発明の作用】本発明では液圧転写を行なうにあたり、
転写パターンのインク、このインクの活性剤またはトッ
プコートの塗料のいずれか一または二以上に真珠光沢顔
料を含むから、真珠光沢顔料が素地の色と互いに干渉し
て独特の発色、深み感、照り感を生じる。
In the present invention, when performing hydraulic transfer,
Since the pearlescent pigment is contained in one or more of the ink of the transfer pattern, the activator of this ink, and the paint of the top coat, the pearlescent pigment interferes with the color of the base material to give a unique coloring, depth, and shine. Create a feeling.
【0014】また被転写体に二度の液圧転写を行い、第
二の転写層に真珠光沢顔料が分散しているようにすれ
ば、真珠光沢顔料が第一の転写パターンのインクや素地
の色と互いに干渉して更に独特の発色、深み感、照り感
を生じ、天然素材に近い質感を醸し出すことができる。
Further, if the pearlescent pigment is dispersed in the second transfer layer by performing the hydraulic transfer twice on the transferred material, the pearlescent pigment can be applied to the ink or the base material of the first transfer pattern. By interacting with the colors, a unique color, depth, and shiny feeling can be created, giving a texture close to that of natural materials.
【0015】更に第一の転写パターンのインクが濃色系
であれば、真珠光沢顔料の発色が顕著であり、更にまた
第一の転写パターンをドット状とすれば、ドットの上に
ある真珠光沢顔料とドットの上にない真珠光沢顔料との
発色状態が異なるため、両者の段階的な発色により更に
独特の質感を醸し出すことができる。
Further, if the ink of the first transfer pattern is a dark color system, the pearlescent pigment is remarkably colored, and if the first transfer pattern is dot-shaped, the pearl luster on the dots is increased. Since the pigment and the pearlescent pigment that are not on the dots have different coloring states, it is possible to create a more unique texture by the stepwise coloring of both.
【0016】[0016]
【実施例】以下本発明を図示の実施例に基づいて具体的
に説明する。まず本発明に関連して液圧転写を行なうた
めの液圧転写ライン1について説明する。この液圧転写
ライン1は、図1に示すように液圧転写装置2と、その
側方に連続的に配置される供給コンベア3、連絡コンベ
ア4、排出コンベア5と、連絡コンベア4の上方に設け
られ液圧転写装置2の側方に位置する自動供給装置6及
び自動排出装置7とを具えて成る。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be specifically described below with reference to illustrated embodiments. First, a hydraulic transfer line 1 for performing hydraulic transfer will be described in connection with the present invention. As shown in FIG. 1, the hydraulic transfer line 1 includes a hydraulic transfer device 2, a supply conveyor 3, a connection conveyor 4, a discharge conveyor 5, and a connection conveyor 4 which are continuously arranged on the side thereof. It is provided with an automatic supply device 6 and an automatic discharge device 7 which are provided on the side of the hydraulic transfer device 2.
【0017】液圧転写装置2は、水Wを入れるための転
写槽10と、その上方に位置し被転写体保持装置14を
一定間隔毎に設けた転写コンベア11と、印刷フィルム
供給装置12とを具えて成る。印刷フィルム供給装置1
2は、水溶性薄膜たるパターン印刷フィルムFがロール
状に巻回された原反ロール15と、パターン印刷フィル
ムFに印刷されたインクを活性化するための活性剤Sを
貯留する溶剤タンク16とを具えて成り、原反ロール1
5から繰り出されたパターン印刷フィルムFが、途中溶
剤タンク16内の活性剤Sで活性化されたのち転写槽1
0内へ連続供給されるように、適宜送りローラ17が設
けられる。また自動供給装置6は複数の把持装置18を
具え、この把持装置18により被転写体をチャックし
て、上方から転写槽10内へ供給し、転写完了後、これ
を排出できるようになっている。
The hydraulic transfer device 2 includes a transfer tank 10 for containing water W, a transfer conveyer 11 above which a transfer target holding device 14 is provided at regular intervals, and a print film supply device 12. It consists of. Printing film supply device 1
Reference numeral 2 denotes an original roll 15 in which a pattern printing film F which is a water-soluble thin film is wound in a roll shape, and a solvent tank 16 which stores an activator S for activating the ink printed on the pattern printing film F. It is made up of
The pattern printing film F fed from No. 5 is activated by the activator S in the solvent tank 16 on the way and then transferred to the transfer tank 1.
A feed roller 17 is provided as appropriate so that it can be continuously fed into 0. Further, the automatic supply device 6 is provided with a plurality of gripping devices 18, and the gripping device 18 chucks a transfer target material to supply the transfer target material from above into the transfer tank 10 and to discharge the transfer material after the transfer is completed. .
【0018】このような液圧転写ライン1を用いて液圧
転写印刷を行なうわけであるが、本発明では被転写体に
二度の液圧転写を行なうことを特徴とする。以下自動車
の操作用パネル20を被転写体として、このものに木目
調の模様を液圧転写する工程を説明する。まず印刷フィ
ルム供給装置12から、第一の転写パターンたる黒色の
ドットパターンP1 が印刷された水溶性薄膜たるパター
ン印刷フィルムF1 が、転写槽10内の水面上に供給さ
れる。ここでパターン印刷フィルムF1 は、図2に示す
ようにゼラチン、アルギン酸ナトリウム、ポリビニルア
ルコール等の水溶性フィルムF0 に微細なドットパター
ンP1 を印刷したものである。
Although hydraulic transfer printing is carried out using such a hydraulic transfer line 1, the present invention is characterized in that the hydraulic transfer is performed twice on the transferred material. Hereinafter, the process of hydraulically transferring a woodgrain pattern to an automobile operation panel 20 as a transfer target will be described. First, from the printing film supply device 12, the pattern printing film F 1 which is a water-soluble thin film on which the black dot pattern P 1 which is the first transfer pattern is printed is supplied onto the water surface in the transfer tank 10. Here, the pattern printing film F 1 is obtained by printing a fine dot pattern P 1 on a water-soluble film F 0 such as gelatin, sodium alginate, or polyvinyl alcohol as shown in FIG.
【0019】またパターン印刷フィルムF1 は通常は原
反ロールとして保管する関係上、塗膜は乾燥状態にする
必要があり、そのためパターン印刷フィルムF1 の使用
時には、転写槽10内に供給する前に、図3に示すよう
に溶剤タンク16内の活性剤S1 を作用させて粘着性を
付与させる。尚、パターン印刷フィルムF1 に活性剤を
塗工するタイミングは、パターン印刷フィルムF1 が水
面上に供給された後であっても構わない。また活性剤
は、樹脂分、顔料、溶剤、可塑剤等を配合して成るもの
の他、単純にはシンナー等の溶剤を用いることもでき
る。
Further, since the pattern printing film F 1 is usually stored as an original roll, the coating film needs to be in a dry state. Therefore, when the pattern printing film F 1 is used, it is not supplied into the transfer tank 10. Then, as shown in FIG. 3, the activator S 1 in the solvent tank 16 is made to act to give tackiness. The pattern printing film F 1 may be coated with the activator after the pattern printing film F 1 is supplied onto the water surface. Further, as the activator, a resin such as a resin component, a pigment, a solvent, a plasticizer and the like are mixed, and a solvent such as thinner can be simply used.
【0020】このように活性剤S1 が塗工されたパター
ン印刷フィルムF1 は、水を吸収して軟化膨潤し、四方
に延展する。インクの粘着性と水溶性フィルムの延展度
が適当になった頃、把持装置18に取り付けられた被転
写体たる操作用パネル20を水面上方から水面に接近さ
せ、その後パターン印刷フィルムF1 を押し下げるよう
に水没させる。
The pattern printing film F 1 thus coated with the activator S 1 absorbs water, softens and swells, and spreads in all directions. When the tackiness of the ink and the spreadability of the water-soluble film become appropriate, the operation panel 20 as a transfer target attached to the gripping device 18 is brought close to the water surface from above the water surface, and then the pattern printing film F 1 is pushed down. To submerge.
【0021】これによりパターン印刷フィルムF1 が、
水圧により操作用パネル20の凹凸に沿って密着して被
膜状に覆い、ドットパターンP1 が操作用パネル20に
転写される。このとき水溶性フィルムF0 は一部水Wに
溶解するが、操作用パネル20が転写コンベア11の上
昇部13に到り排出された後、水溶性フィルムF0 の完
全除去のためシャワーリングや水洗浄を行なう。その
後、操作用パネル20は乾燥工程で乾燥されて、操作用
パネル20の表面に第一の転写層L1 が形成される。な
おこの第一の転写層L1 は、後に形成される第二の転写
層L2 の下地となるものであるが、この第一の転写層L
1 にもトップコートと同様なクリヤコートを施すことも
できる。因みに第一の転写層L1 の上にクリヤコートを
した場合には、このクリヤコートが照り感や深み感を増
して高級な質感を生み出すことができる。
As a result, the pattern printing film F 1 is
The dot pattern P 1 is transferred to the operation panel 20 by being closely adhered to the operation panel 20 along the irregularities of the operation panel 20 by water pressure and covering the operation panel 20 with a film. At this time, the water-soluble film F 0 is partially dissolved in the water W, but after the operation panel 20 reaches the rising portion 13 of the transfer conveyor 11 and is discharged, a shower ring or a shower ring is used to completely remove the water-soluble film F 0. Wash with water. After that, the operation panel 20 is dried in the drying step, and the first transfer layer L 1 is formed on the surface of the operation panel 20. The first transfer layer L 1 serves as a base of the second transfer layer L 2 which will be formed later.
1 can also be applied with a clear coat similar to the top coat. By the way, when a clear coat is formed on the first transfer layer L 1 , the clear coat can increase the feeling of shinyness and depth and can produce a high-grade texture.
【0022】次に第二の転写層L2 の形成について説明
する。図4に示すように第二の転写パターンである木目
調パターンP2 をインクで印刷した水溶性薄膜たるパタ
ーン印刷フィルムF2 を用意し、これを一例として金色
を呈する真珠光沢顔料Gを含有した活性剤S2 で活性化
させて水面上に浮かべる。因みにこのように活性剤S2
に真珠光沢顔料Gを含有させることで、真珠光沢顔料G
が第二の転写層L2 に存在するようになり、インクや素
地の色と互いに干渉して独特の発色、深み感、照り感を
生じさせることができる。
Next, the formation of the second transfer layer L 2 will be described. As shown in FIG. 4, a pattern printing film F 2 which is a water-soluble thin film in which a wood-grain pattern P 2 which is a second transfer pattern is printed with ink is prepared, and as an example, it contains a pearlescent pigment G showing a golden color. It is activated with the activator S 2 and floated on the water surface. By the way, the activator S 2
By including the pearlescent pigment G in the
Are present in the second transfer layer L 2 , and can interfere with the colors of the ink and the base material to produce unique color development, depth feeling, and shiny feeling.
【0023】ここで本発明に適用する真珠光沢顔料につ
いて説明する。このものは、光の多重反射により真珠光
沢(perlescence)といわれる優雅な輝きを呈する顔料で
ある。古くから使用されてきた天然真珠光沢顔料は魚の
鱗から採取されるものであるが、天然品は量産がむずか
しく高価であるので多くの合成品が作られている。
Now, the pearlescent pigment applied to the present invention will be described. This is a pigment that has an elegant luster called perlescence due to multiple reflections of light. Although natural pearlescent pigments that have been used for a long time are collected from fish scales, many synthetic products are made because natural products are difficult to mass produce and expensive.
【0024】真珠光沢顔料は透明で屈折率の大きい物質
から成り、粒子は薄片状で、着色した際薄片が層状に配
列することが必要である。薄片の大きさは5〜150μ
mで幅広く、小さいもの(5〜30μm)は絹に似た柔
らかい光沢を呈し、大きいものはキラキラしたメタリッ
ク調の光沢を呈する。
The pearlescent pigment is composed of a transparent substance having a high refractive index, and the particles are flaky, and it is necessary that the flakes are arranged in layers when colored. The size of the flakes is 5-150μ
A wide m and a small one (5 to 30 μm) have a soft luster similar to silk, and a large one has a glittering metallic luster.
【0025】天然真珠光沢顔料はグアニンの微細な結晶
であるが、合成真珠光沢顔料は塩基性炭酸鉛〔PbCO3
Pb(OH)2 〕、ヒ酸水素鉛(PbHAsO4)、酸塩化ビスマス
(BiOCl)などの物質からなるものの他、近年雲母チタン
からなるものが開発され、堅牢性や安全性の点で優れて
いるため広く使用されている。この雲母チタンは、雲母
を辟開面に沿って薄片に剥がし、この薄片に屈折率の大
きい二酸化チタンを被覆することにより得られる。被覆
する二酸化チタンの量は20〜50%で、少ないものは
白色の真珠光沢を呈し、多いものは干渉による虹彩色を
呈する。また薄片の厚さによっても反射光の干渉により
着色した虹彩色ないし干渉色を呈する。このように虹彩
色を呈する真珠光沢顔料が本発明に最も適するものであ
り、このものは下地が濃色であればあるほど発色が強く
なる性質を具える。ここで濃色とは黒色、焦げ茶色、藍
色等の暗色系の色の他、赤色、青色等の色であっても濃
い色であれば含まれる。虹彩色を呈する真珠光沢顔料の
市販品としては、メルク・ジャパン株式会社のIrio
din(登録商標)205 、215 、217 、219 、225 、23
5 やマールコーポレーション株式会社のHi−lite
Goldなどがある。なおこの他の真珠光沢顔料に
は、二酸化チタン層の上に酸化鉄を被覆した着色型もあ
り、これは金色や赤銅色の真珠光沢を呈する。
Natural pearlescent pigments are fine crystals of guanine, while synthetic pearlescent pigments are basic lead carbonate [PbCO 3 ·.
Pb (OH) 2 ], lead hydrogen arsenate (PbHAsO 4 ), bismuth acid chloride (BiOCl) and other substances, as well as titanium mica has been developed in recent years and is superior in terms of robustness and safety. It is widely used because This mica titanium can be obtained by peeling mica into thin pieces along the cleavage plane and coating the thin pieces with titanium dioxide having a high refractive index. The amount of titanium dioxide to be coated is 20 to 50%, a small amount exhibits a white pearl luster, and a large amount exhibits an iris color due to interference. Further, depending on the thickness of the flakes, the iris color or the interference color colored by the interference of the reflected light is exhibited. As described above, the pearlescent pigment exhibiting an iris color is the most suitable for the present invention, and this pigment has a property that the deeper the background color is, the stronger the coloring is. Here, the dark color includes dark colors such as black, dark brown, and indigo, as well as red, blue, and the like, as long as they are dark. Commercially available iris-colored pearlescent pigments include Irio of Merck Japan Co., Ltd.
din (registered trademark) 205, 215, 217, 219, 225, 23
5 and Hi-lite of Marl Corporation
Gold, etc. As another pearlescent pigment, there is also a colored type in which a titanium dioxide layer is coated with iron oxide, which exhibits a golden or bronze pearlescent luster.
【0026】次にパターン印刷フィルムF2 が水面上に
浮かべられた状態で、このパターン印刷フィルムF2
上から上記第一の転写層L1 が形成された操作用パネル
20を押し付けて水面下に没入し、水圧により木目調パ
ターンP2 を黒色のドットパターンP1 の上に重ねて転
写する。その後パターン印刷フィルムF2 を水で除去
し、乾燥後トップコートを行い、更に乾燥して溶剤を蒸
発させた後、必要によりバフ仕上げを行なうことで木目
模様の操作用パネル20が完成する。
Next, in a state in which the pattern printing film F 2 is floated on the water surface, the operation panel 20 having the first transfer layer L 1 formed thereon is pressed from above the pattern printing film F 2 so that it is below the water surface. And the woodgrain pattern P 2 is transferred by being superposed on the black dot pattern P 1 by water pressure. After that, the pattern printing film F 2 is removed with water, and after drying, a top coat is applied, and after drying and evaporation of the solvent, buffing is performed if necessary, whereby the operation panel 20 having a wood pattern is completed.
【0027】因みにこのようにして印刷された操作用パ
ネル20では、図5のように印刷表面の全面に真珠光沢
顔料Gが付着しているが、虹彩色を呈する真珠光沢顔料
は下地が濃色であればあるほど発色が強くなるため、木
目調パターンP2 の印刷されていない部分であって、下
地として真珠光沢顔料Gが最も発色できる黒色のドット
がある部分は、黒色のドットと干渉して深く発色し、独
特の深み感と照り感とを生じる。また木目調パターンP
2 の印刷されていない部分であって黒色のドットがない
部分も、被転写体の素地色が濃色系であれば、真珠光沢
顔料Gが素地色と干渉して、素地色の濃色に応じて黒色
ほどではないが発色し、それなりの深み感と照り感とを
生じる。これにより、真珠光沢顔料Gの下地に応じて段
階的に発色し、深み感と照り感のある銘木の木調に酷似
した質感を生じることができるとともに、第一の転写パ
ターンである黒色ドット部分が、木のふを構成するよう
に見えて木質感が向上する。
Incidentally, in the operation panel 20 printed in this way, the pearlescent pigment G adheres to the entire printing surface as shown in FIG. 5, but the pearlescent pigment exhibiting an iris color has a dark background. If so, the more intense the coloring is, the portion where the woodgrain pattern P 2 is not printed and where there is a black dot where the pearlescent pigment G can be colored most as a background interferes with the black dot. It produces a deep color and a unique feeling of depth and shine. Also, wood grain pattern P
If the base color of the transferred material is dark, the pearlescent pigment G interferes with the base color even if there is no black dot in 2 Correspondingly, the color develops to a lesser degree than black, and a certain depth and shiny feeling are produced. As a result, the pearlescent pigment G develops its color stepwise according to the base, and a texture resembling the wood tone of a name tree with a feeling of depth and a feeling of light can be produced, and the black dot portion that is the first transfer pattern is generated. However, the texture of the wood is improved by appearing to form a tree.
【0028】なお図5では、説明の便宜上、インクとは
別に活性剤S1 、S2 を独立の層として描いているが、
実際にはインクの活性状態では、インクと活性剤とは両
者混合した状態で存在し、また液圧転写完了時点では活
性剤の溶剤は乾燥蒸発してしまい、活性剤の残留成分と
インクあるいは真珠光沢顔料とが混在することになる。
In FIG. 5, the activators S 1 and S 2 are shown as independent layers separately from the ink for convenience of description.
In fact, when the ink is in the active state, both the ink and the active agent exist in a mixed state, and when the hydraulic transfer is completed, the solvent of the active agent evaporates by drying, and the residual components of the active agent and the ink or pearl are It will be mixed with a luster pigment.
【0029】尚、以上の実施例では木質感を出すため、
第一の転写パターンを黒色ドット状とし、第二の転写パ
ターンを木目模様としたが、同じ木質感を出す場合でも
第一の転写パターンをベタ塗り状としたり、他の形態の
転写パターンを適用することもできる。また木質感以外
にも、第一の転写パターンと第二の転写パターンとを適
宜組み合わせることにより、大理石、御影石、オパール
感等の種々の質感を表現することも可能である。
In the above embodiment, in order to give a wood texture,
The first transfer pattern was a black dot shape and the second transfer pattern was a wood grain pattern, but even if the same wood texture is produced, the first transfer pattern can be a solid paint pattern or another form of transfer pattern can be applied. You can also do it. In addition to the wood texture, various textures such as marble, granite, and opal can be expressed by appropriately combining the first transfer pattern and the second transfer pattern.
【0030】また上記実施例では真珠光沢顔料Gを活性
剤S2 に含有させたが、この他、第二の転写パターンを
印刷するためのインクやトップコートの塗料、あるいは
第一の転写層に施すクリヤコートの塗料に真珠光沢顔料
を混入してもよい。この場合には、真珠光沢顔料が混入
される層の下の層が黒色等の暗色系の色であることが、
真珠光沢顔料の上記機能を十分に引き出すために必要で
ある。
Although the pearlescent pigment G is contained in the activator S 2 in the above-mentioned examples, in addition to this, the ink for printing the second transfer pattern, the top coat paint, or the first transfer layer is used. A pearlescent pigment may be mixed in the clear coat paint to be applied. In this case, the layer below the layer in which the pearlescent pigment is mixed has a dark color such as black,
It is necessary to fully bring out the above functions of the pearlescent pigment.
【0031】以上は二度の液圧転写を行なう実施例であ
るが、一度の液圧転写印刷でも本発明が適用できる。即
ち、上記第一の転写層の形成工程と同様にして、インク
で転写パターンの印刷された水溶性薄膜に活性剤を作用
させてインクに粘着性を付与し、この状態で転写槽10
内の水面上に供給する。そして把持装置18に取り付け
られた被転写体を水面上方から水面に接近させ、その後
水溶性薄膜を押し下げるように水没させて、転写パター
ンを被転写体に転写させる。転写後、水溶性薄膜を水で
完全除去し、乾燥工程で乾燥後、トップコートを行な
う。本発明では、このような一度の液圧転写において
も、転写パターンの印刷インク、このインクの活性剤ま
たはトップコートの塗料のいずれか一または二以上に真
珠光沢顔料を含有させておくことができる。
Although the above is an embodiment in which the hydraulic transfer is performed twice, the present invention can be applied to a single hydraulic transfer printing. That is, in the same manner as the step of forming the first transfer layer, the activator acts on the water-soluble thin film on which the transfer pattern is printed by the ink to give tackiness to the ink, and in this state, the transfer tank 10
Supply above the water surface. Then, the transfer target attached to the gripping device 18 is made to approach the water surface from above the water surface, and then the water-soluble thin film is submerged so as to be pushed down to transfer the transfer pattern to the transfer target. After the transfer, the water-soluble thin film is completely removed with water, dried in the drying step, and then top-coated. In the present invention, even in such a single hydraulic transfer, the pearlescent pigment can be contained in one or more of the printing ink of the transfer pattern, the activator of this ink and the top coat paint. .
【0032】このようにすれば印刷表面の全面に真珠光
沢顔料が付着するが、今度は下地の印刷が存在しないた
め、真珠光沢顔料が被転写体の素地の色との関係で発色
するようになる。従って被転写体の素地が例えば種々に
色分けされていれば、色の濃い部分、特に黒色系の部分
では真珠光沢顔料が良く発色し、それ以外の部分ではそ
れ程発色しないというように、部位に応じて発色し、発
色部分ではそれなりの深み感と照り感とを生じるように
なる。
In this way, the pearlescent pigment adheres to the entire surface of the printing surface, but since there is no underlying printing, the pearlescent pigment is colored in relation to the color of the base material of the transferred material. Become. Therefore, if the base material of the transferred material is, for example, variously color-coded, the pearlescent pigment develops well in the dark part, especially in the black part, and not so much in the other parts. The color is developed, and a certain depth and shiny feeling are produced in the color-developed portion.
【0033】[0033]
【発明の効果】本発明では、第一の転写層の上に第二の
転写層を重ねて設け、第二の転写層の転写パターンのイ
ンク、このインクの活性剤またはトップコートの塗料の
いずれか一または二以上には真珠光沢顔料が含まれてい
るから、真珠光沢顔料が第一の転写層のインクや素地の
色と互いに干渉して発色し、また深み感、照り感を生じ
て第二の転写層の転写パターンの質感を向上させること
ができる。
INDUSTRIAL APPLICABILITY In the present invention, the second transfer layer is provided on the first transfer layer in an overlapping manner, and the ink of the transfer pattern of the second transfer layer, the activator of this ink or the top coat paint is used. Since one or more pearlescent pigments are contained in the pearlescent pigment, the pearlescent pigment interferes with the ink of the first transfer layer and the color of the base material to form a color, and the pearlescent pigment gives a feeling of depth and shine. The texture of the transfer pattern of the second transfer layer can be improved.
【0034】また第一の転写パターンを黒色のドットパ
ターンとし、その上に真珠光沢顔料を含む活性剤で活性
化させた木目調パターンを重ねて液圧転写すれば、真珠
光沢顔料の下地に応じて段階的に発色し、深み感と照り
感のある銘木の木調に酷似した質感を生じさせることが
できるとともに、黒色ドット部分が、木のふを構成する
ように見え、木質感を向上させる。
If the first transfer pattern is a black dot pattern and a wood grain pattern activated by an activator containing a pearlescent pigment is superposed thereon and hydraulically transferred, the pearlescent pigment is coated with a base material. The color gradually develops to create a texture that is very similar to the tone of wood with a sense of depth and a feeling of light, and the black dots appear to make up the wood and improve the wood texture. .
【0035】更に液圧転写が一度の場合にも、転写パタ
ーンの印刷インク、このインクの活性剤またはトップコ
ートの塗料のいずれか一または二以上に真珠光沢顔料を
含有させておけば、素地の色との関係で真珠光沢顔料が
発色し、印刷表面の深み感や照り感を得ることができ
る。
Further, even when the hydraulic transfer is performed once, if a pearlescent pigment is contained in one or more of the printing ink for the transfer pattern, the activator of this ink, and the top coat paint, The pearlescent pigment develops a color in relation to the color, and it is possible to obtain a feeling of depth and shine on the printed surface.
【図面の簡単な説明】[Brief description of drawings]
【図1】本発明を実施する液圧転写装置を示す側面図で
ある。
FIG. 1 is a side view showing a hydraulic transfer device embodying the present invention.
【図2】原反ロールから繰り出されるパターン印刷フィ
ルムを示す斜視図である。
FIG. 2 is a perspective view showing a pattern printing film fed from an original roll.
【図3】液圧転写の方法をドットパターン転写工程と木
目調パターン転写工程に分けて示す説明図であって、こ
のうちドットパターン転写工程を示す斜視図である。
FIG. 3 is an explanatory view showing the hydraulic transfer method separately in a dot pattern transfer step and a woodgrain pattern transfer step, and is a perspective view showing the dot pattern transfer step.
【図4】同上木目調パターン転写工程を示す斜視図であ
る。
FIG. 4 is a perspective view showing the same woodgrain pattern transfer process.
【図5】第一の転写層と第二の転写層との形成状態を示
す骨格的断面図である。
FIG. 5 is a skeleton cross-sectional view showing a formation state of a first transfer layer and a second transfer layer.
【図6】自動車の操作用パネルに木目調の模様を液圧転
写した実施例を示す一部拡大斜視図である。
FIG. 6 is a partially enlarged perspective view showing an embodiment in which a woodgrain pattern is hydraulically transferred to an operation panel of an automobile.
【符号の説明】[Explanation of symbols]
1 液圧転写ライン 2 液圧転写装置 3 供給コンベア 4 連絡コンベア 5 排出コンベア 6 自動供給装置 7 自動排出装置 10 転写槽 11 転写コンベア 12 印刷フィルム供給装置 13 上昇部 14 被転写体保持装置 15 原反ロール 16 溶剤タンク 17 送りローラ 18 把持装置 20 操作用パネル F パターン印刷フィルム F0 水溶性フィルム F1 パターン印刷フィルム F2 パターン印刷フィルム G 真珠光沢顔料 L1 第一の転写層 L2 第二の転写層 P1 ドットパターン P2 木目パターン S1 活性剤 S2 活性剤 W 水1 Liquid Transfer Line 2 Liquid Transfer Device 3 Supply Conveyor 4 Communication Conveyor 5 Discharge Conveyor 6 Automatic Supply Device 7 Automatic Discharge Device 10 Transfer Tank 11 Transfer Conveyor 12 Printing Film Supply Device 13 Ascending Part 14 Transferred Object Holding Device 15 Original Fabric Roll 16 Solvent tank 17 Feed roller 18 Gripping device 20 Operation panel F Pattern printing film F 0 Water-soluble film F 1 Pattern printing film F 2 Pattern printing film G Pearlescent pigment L 1 First transfer layer L 2 Second transfer Layer P 1 dot pattern P 2 wood grain pattern S 1 activator S 2 activator W water

Claims (8)

    【特許請求の範囲】[Claims]
  1. 【請求項1】 被転写体の表面に濃色系パターンから成
    る第一の転写層を有し、この第一の転写層の上に木目模
    様のパターンから成る第二の転写層を有し、且つ第二の
    転写層には真珠光沢顔料が分散していることを特徴とす
    る液圧転写印刷品。
    1. A surface of a material to be transferred has a first transfer layer having a dark color pattern, and a second transfer layer having a woodgrain pattern on the first transfer layer, Further, a liquid transfer printing product in which a pearlescent pigment is dispersed in the second transfer layer.
  2. 【請求項2】 転写パターンをインクで印刷した水溶性
    薄膜を、そのインクの活性状態で水面上に浮かべ、この
    水溶性薄膜の上から被転写体を押し付けて被転写体の一
    部または全部を水面下に没入し、水圧で前記転写パター
    ンを被転写体に転写するとともに前記水溶性薄膜を水で
    除去し、乾燥後トップコートを行なって被転写体に前記
    転写パターンを印刷するにあたり、前記インク、このイ
    ンクの活性剤または前記トップコートの塗料のいずれか
    一または二以上に真珠光沢顔料を含むことを特徴とする
    液圧転写印刷品の印刷方法。
    2. A water-soluble thin film on which a transfer pattern is printed is floated on the water surface in an active state of the ink, and the transfer target is pressed against the water-soluble thin film to partially or completely transfer the transfer target. Immersion under the surface of water, transfer the transfer pattern to the transfer target by hydraulic pressure and remove the water-soluble thin film with water, perform a top coat after drying to print the transfer pattern on the transfer target, the ink A method for printing a hydraulic transfer printing product, which comprises a pearlescent pigment in one or more of the activator of the ink and the top coat paint.
  3. 【請求項3】 第一の転写パターンをインクで印刷した
    水溶性薄膜を、そのインクの活性状態で水面上に浮か
    べ、この水溶性薄膜の上から被転写体を押し付けて被転
    写体の一部または全部を水面下に没入し、水圧で前記第
    一の転写パターンを被転写体に転写するとともに水溶性
    薄膜を水で除去後、乾燥して第一の転写層を形成し、次
    に第二の転写パターンをインクで印刷した水溶性薄膜
    を、そのインクの活性状態で水面上に浮かべ、この水溶
    性薄膜の上から前記第一の転写層が形成された被転写体
    を押し付けて被転写体の一部または全部を水面下に没入
    し、水圧で前記第二の転写パターンを前記被転写体の第
    一の転写層に重ねて転写するとともに水溶性薄膜を水で
    除去後、乾燥して第二の転写層を形成し、更にトップコ
    ートを行なうとともに、前記第二の転写層の形成過程で
    は、転写パターンのインク、このインクの活性剤または
    トップコートの塗料のいずれか一または二以上に真珠光
    沢顔料を含むことを特徴とする液圧転写印刷品の印刷方
    法。
    3. A water-soluble thin film on which a first transfer pattern is printed with ink is floated on the water surface in an active state of the ink, and the transfer target is pressed from above the water-soluble thin film to part of the transfer target. Alternatively, the whole is immersed under the surface of the water, the first transfer pattern is transferred to the transfer object by water pressure, the water-soluble thin film is removed with water, and then the film is dried to form the first transfer layer. The water-soluble thin film on which the transfer pattern of (1) is printed is floated on the water surface in the active state of the ink, and the transfer target on which the first transfer layer is formed is pressed from above the water-soluble thin film to transfer the target. Part or all of the above is submerged below the surface of water, and the second transfer pattern is transferred by hydraulic pressure to the first transfer layer of the transfer target while being transferred, and the water-soluble thin film is removed with water and then dried. A second transfer layer is formed and a top coat is applied, In the process of forming the second transfer layer, printing of a hydraulic transfer print product, characterized in that a pearlescent pigment is contained in one or more of an ink of a transfer pattern, an activator of the ink and a top coat paint. Method.
  4. 【請求項4】 前記第二の転写層の形成過程では、前記
    第二の転写パターンがインクで印刷された水溶性薄膜
    を、真珠光沢顔料を含む活性剤で活性化させた状態で水
    面上に浮かべ、この水溶性薄膜の上から前記第一の転写
    層が形成された被転写体を押し付けて水圧で第二の転写
    パターンを転写することを特徴とする請求項3記載の液
    圧転写印刷品の印刷方法。
    4. In the step of forming the second transfer layer, a water-soluble thin film on which the second transfer pattern is printed with ink is activated by an activator containing a pearlescent pigment on the water surface. 4. The hydraulic transfer print product according to claim 3, wherein the second transfer pattern is floated and the second transfer pattern is transferred by hydraulic pressure by pressing the transfer target on which the first transfer layer is formed from above the water-soluble thin film. Printing method.
  5. 【請求項5】 前記第一の転写パターンのインクは濃色
    系であることを特徴とする請求項3または4記載の液圧
    転写印刷品の印刷方法。
    5. The method for printing a hydraulic transfer print product according to claim 3, wherein the ink of the first transfer pattern is a dark color system.
  6. 【請求項6】 前記第一の転写パターンはドット状であ
    ることを特徴とする請求項3、4または5記載の液圧転
    写印刷品の印刷方法。
    6. The method for printing a hydraulic transfer print product according to claim 3, 4 or 5, wherein the first transfer pattern has a dot shape.
  7. 【請求項7】 前記第二の転写パターンは木目模様であ
    ることを特徴とする請求項3、4、5または6記載の液
    圧転写印刷品の印刷方法。
    7. The method for printing a hydraulic transfer print according to claim 3, 4, 5 or 6, wherein the second transfer pattern is a wood grain pattern.
  8. 【請求項8】 前記第一の転写層の形成後、クリヤコー
    トを行なうことを特徴とする請求項3、4、5、6また
    は7記載の液圧転写印刷品の印刷方法。
    8. The method for printing a hydraulic transfer print according to claim 3, 4, 5, 6, or 7, wherein clear coating is performed after the formation of the first transfer layer.
JP34314792A 1992-11-30 1992-11-30 Manufacturing method of hydraulic transfer printing products Expired - Fee Related JP3249211B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34314792A JP3249211B2 (en) 1992-11-30 1992-11-30 Manufacturing method of hydraulic transfer printing products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34314792A JP3249211B2 (en) 1992-11-30 1992-11-30 Manufacturing method of hydraulic transfer printing products

Publications (2)

Publication Number Publication Date
JPH06166300A true JPH06166300A (en) 1994-06-14
JP3249211B2 JP3249211B2 (en) 2002-01-21

Family

ID=18359284

Family Applications (1)

Application Number Title Priority Date Filing Date
JP34314792A Expired - Fee Related JP3249211B2 (en) 1992-11-30 1992-11-30 Manufacturing method of hydraulic transfer printing products

Country Status (1)

Country Link
JP (1) JP3249211B2 (en)

Cited By (12)

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US5916502A (en) * 1994-05-27 1999-06-29 Cubic Co. Ltd. Decorated shaped product having source expression applied thereto, method for manufacturing same and shaped base material therefor
WO2000020128A1 (en) * 1998-10-01 2000-04-13 4Cyte Ltd. Printing method and apparatus
EP0993874A1 (en) * 1998-10-13 2000-04-19 Bush Industries, Inc. Process for transfering a decoration to an object
WO2004108434A1 (en) * 2003-06-02 2004-12-16 Cubic Co., Ltd. Hydraulic transfer method and hydraulic-transferred article
JP2005238674A (en) * 2004-02-26 2005-09-08 Dainippon Printing Co Ltd Hydraulic pressure transfer sheet and method for manufacturing metallic molded article
JP2006224613A (en) * 2005-02-21 2006-08-31 Nishikawa Kasei Co Ltd Decorative body and its manufacturing method
WO2007023577A1 (en) * 2005-08-23 2007-03-01 Taica Corporation Coating agent for hydraulic transfer film, method of hydraulic transfer and hydraulic transfer product
JP2009234187A (en) * 2008-03-28 2009-10-15 Dic Corp Hydraulic transfer film and hydraulically transferred body
KR101023036B1 (en) * 2008-06-24 2011-03-24 주식회사 한국큐빅 Decoration material with alternating hydrographic pattern layer and coating layer and manufacturing method thereof
US8178187B2 (en) 2004-02-18 2012-05-15 Taica Corporation Water pressure transfer article
JP2012200864A (en) * 2011-03-23 2012-10-22 Dic Decor Inc Decoration sheet for water transfer printing, manufacturing method thereof, water transfer printing method using decoration sheet, and product decorated by water transfer printing method
US8850973B2 (en) 2009-04-30 2014-10-07 Taica Corporation Water pressure transfer method, a water pressure transfer article and a coating agent for water pressure transfer film

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Publication number Priority date Publication date Assignee Title
US5925452A (en) * 1994-05-27 1999-07-20 Cubic Co., Ltd. Decorated shaped product having source expression applied thereto, method for manufacturing same and shaped base material therefor
US5916502A (en) * 1994-05-27 1999-06-29 Cubic Co. Ltd. Decorated shaped product having source expression applied thereto, method for manufacturing same and shaped base material therefor
US6103342A (en) * 1994-05-27 2000-08-15 Cubic Co., Ltd. Decorated shaped product having source expression applied thereto, method for manufacturing same and shaped base material therefor
WO2000020128A1 (en) * 1998-10-01 2000-04-13 4Cyte Ltd. Printing method and apparatus
EP0993874A1 (en) * 1998-10-13 2000-04-19 Bush Industries, Inc. Process for transfering a decoration to an object
WO2004108434A1 (en) * 2003-06-02 2004-12-16 Cubic Co., Ltd. Hydraulic transfer method and hydraulic-transferred article
US7951255B2 (en) 2003-06-02 2011-05-31 Taica Corporation Water pressure transfer method and water pressure transfer article
US8178187B2 (en) 2004-02-18 2012-05-15 Taica Corporation Water pressure transfer article
JP2005238674A (en) * 2004-02-26 2005-09-08 Dainippon Printing Co Ltd Hydraulic pressure transfer sheet and method for manufacturing metallic molded article
JP2006224613A (en) * 2005-02-21 2006-08-31 Nishikawa Kasei Co Ltd Decorative body and its manufacturing method
WO2007023577A1 (en) * 2005-08-23 2007-03-01 Taica Corporation Coating agent for hydraulic transfer film, method of hydraulic transfer and hydraulic transfer product
WO2007023525A1 (en) * 2005-08-23 2007-03-01 Taica Corporation Coating agent for hydraulic transfer film, method of hydraulic transfer and hydraulic transfer product
JP2009234187A (en) * 2008-03-28 2009-10-15 Dic Corp Hydraulic transfer film and hydraulically transferred body
KR101023036B1 (en) * 2008-06-24 2011-03-24 주식회사 한국큐빅 Decoration material with alternating hydrographic pattern layer and coating layer and manufacturing method thereof
US8850973B2 (en) 2009-04-30 2014-10-07 Taica Corporation Water pressure transfer method, a water pressure transfer article and a coating agent for water pressure transfer film
JP2012200864A (en) * 2011-03-23 2012-10-22 Dic Decor Inc Decoration sheet for water transfer printing, manufacturing method thereof, water transfer printing method using decoration sheet, and product decorated by water transfer printing method

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