JPH0613536B2 - 降下した氷点を有するチタニウムエステル組成物とその製法 - Google Patents
降下した氷点を有するチタニウムエステル組成物とその製法Info
- Publication number
- JPH0613536B2 JPH0613536B2 JP58206102A JP20610283A JPH0613536B2 JP H0613536 B2 JPH0613536 B2 JP H0613536B2 JP 58206102 A JP58206102 A JP 58206102A JP 20610283 A JP20610283 A JP 20610283A JP H0613536 B2 JPH0613536 B2 JP H0613536B2
- Authority
- JP
- Japan
- Prior art keywords
- titanate
- pentanedione
- empirical formula
- composition
- iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 Titanium ester Chemical class 0.000 title claims abstract description 29
- 238000007710 freezing Methods 0.000 title claims abstract description 10
- 230000008014 freezing Effects 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 title claims description 75
- 239000010936 titanium Substances 0.000 title claims description 38
- 229910052719 titanium Inorganic materials 0.000 title claims description 19
- 238000004519 manufacturing process Methods 0.000 title claims 3
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims abstract description 96
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 17
- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 claims abstract description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 5
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims abstract description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 5
- 239000002667 nucleating agent Substances 0.000 claims abstract description 5
- 125000004200 2-methoxyethyl group Chemical group [H]C([H])([H])OC([H])([H])C([H])([H])* 0.000 claims abstract description 4
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract 3
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract 3
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
- 125000003545 alkoxy group Chemical group 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 8
- TZMFJUDUGYTVRY-UHFFFAOYSA-N pentane-2,3-dione Chemical compound CCC(=O)C(C)=O TZMFJUDUGYTVRY-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004781 supercooling Methods 0.000 claims 3
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 239000004971 Cross linker Substances 0.000 claims 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 1
- GYUPBLLGIHQRGT-UHFFFAOYSA-N pentane-2,4-dione;titanium Chemical compound [Ti].CC(=O)CC(C)=O GYUPBLLGIHQRGT-UHFFFAOYSA-N 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract description 2
- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 description 24
- VXUYXOFXAQZZMF-UHFFFAOYSA-N tetraisopropyl titanate Substances CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 24
- 239000013078 crystal Substances 0.000 description 21
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 239000000047 product Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 7
- 238000004821 distillation Methods 0.000 description 7
- ITNVWQNWHXEMNS-UHFFFAOYSA-N methanolate;titanium(4+) Chemical compound [Ti+4].[O-]C.[O-]C.[O-]C.[O-]C ITNVWQNWHXEMNS-UHFFFAOYSA-N 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 125000006606 n-butoxy group Chemical group 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 150000003608 titanium Chemical class 0.000 description 2
- 244000007835 Cyamopsis tetragonoloba Species 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- ZEIWWVGGEOHESL-UHFFFAOYSA-N methanol;titanium Chemical compound [Ti].OC.OC.OC.OC ZEIWWVGGEOHESL-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Liquid Crystal Substances (AREA)
- Materials For Medical Uses (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43956782A | 1982-11-05 | 1982-11-05 | |
| US439567 | 1982-11-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59176297A JPS59176297A (ja) | 1984-10-05 |
| JPH0613536B2 true JPH0613536B2 (ja) | 1994-02-23 |
Family
ID=23745224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58206102A Expired - Lifetime JPH0613536B2 (ja) | 1982-11-05 | 1983-11-04 | 降下した氷点を有するチタニウムエステル組成物とその製法 |
Country Status (8)
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3337100C2 (de) * | 1983-10-12 | 1986-01-09 | Dynamit Nobel Ag, 5210 Troisdorf | Wasserlösliche Titan(IV)-bis-acetylacetonate |
| DE4023851A1 (de) * | 1990-07-27 | 1992-01-30 | Huels Chemische Werke Ag | Neue kaeltestabile titanchelate |
| US8044001B2 (en) | 2007-11-20 | 2011-10-25 | Dorf Ketal Speciality Catalysts, Llc | Solid zirconium-based cross-linking agent and use in oil field applications |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE577999A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1958-04-25 | |||
| US3682688A (en) * | 1970-06-17 | 1972-08-08 | Du Pont | Method of fixing a chelated organic titanate vehicle to a substrate |
| DE3008193C2 (de) * | 1980-03-04 | 1982-07-08 | Dynamit Nobel Ag, 5210 Troisdorf | Kältestabile, Katalytisch wirksame Lösung von Diisopropoxy-bis(2,4-pentandionato)-titan(IV) |
-
1983
- 1983-10-24 DK DK487783A patent/DK487783A/da not_active Application Discontinuation
- 1983-11-03 CA CA000440404A patent/CA1218667A/en not_active Expired
- 1983-11-04 DE DE8383111027T patent/DE3372616D1/de not_active Expired
- 1983-11-04 GR GR72875A patent/GR78748B/el unknown
- 1983-11-04 IE IE2579/83A patent/IE56207B1/en not_active IP Right Cessation
- 1983-11-04 EP EP83111027A patent/EP0109014B1/en not_active Expired
- 1983-11-04 JP JP58206102A patent/JPH0613536B2/ja not_active Expired - Lifetime
- 1983-11-04 AT AT83111027T patent/ATE28463T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0109014B1 (en) | 1987-07-22 |
| IE832579L (en) | 1984-05-05 |
| DE3372616D1 (en) | 1987-08-27 |
| GR78748B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1984-10-02 |
| JPS59176297A (ja) | 1984-10-05 |
| DK487783A (da) | 1984-05-06 |
| EP0109014A1 (en) | 1984-05-23 |
| ATE28463T1 (de) | 1987-08-15 |
| IE56207B1 (en) | 1991-05-22 |
| DK487783D0 (da) | 1983-10-24 |
| CA1218667A (en) | 1987-03-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH05255350A (ja) | シクロアルコキシシラン | |
| CA1278578C (en) | Organic solvent soluble polyvalent metal alkoxy alkoxides | |
| JPH07182939A (ja) | 透明導電膜形成用組成物及び透明導電膜形成方法 | |
| KR840003038A (ko) | 로듐촉매의 제조방법과 그들의 이용 | |
| JPS5923318B2 (ja) | アルコキシ−ビス（トリアルコキシシロキシ）−シラン化合物 | |
| US3948803A (en) | Catalyst | |
| US5021596A (en) | Zirconium chelates, their preparation, and their use in printing inks | |
| US4551544A (en) | Titanium ester compositions having depressed freezing points | |
| JPH0613536B2 (ja) | 降下した氷点を有するチタニウムエステル組成物とその製法 | |
| JP2004507554A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JPH0228598B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| US4478755A (en) | Titanate compositions having depressed freezing points | |
| JP2676918B2 (ja) | 塗布液用組成物 | |
| JPH04270292A (ja) | 可溶性の重金属アミノアルコキシド | |
| JPS62263138A (ja) | 有機溶剤可溶性亜鉛アルコキシアルコキシドおよびその製造方法 | |
| JP2612996B2 (ja) | 有機けい素基含有イソシアヌレートの製造方法 | |
| JPS60136573A (ja) | １，２，４−トリアゾロン誘導体の製造方法 | |
| KR100521062B1 (ko) | (3-알콕시페닐)마그네슘클로라이드의제조방법및당해클로라이드를사용한알콜제조방법 | |
| US5677543A (en) | Dissolved methyllithium-containing composition for use in synthesis reactions | |
| CA1319935C (en) | Condensed acetoacetic-acid-ester titanium-chelates and process for the production thereof | |
| JPH0434529B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| US5349073A (en) | Low-temperature-stable titanium chelates and method for their preparation | |
| JPS5828844B2 (ja) | カ−バメ−トの安定化方法 | |
| JP3840810B2 (ja) | β−ケトアルデヒアルカリ塩の製造方法 | |
| JPS5885874A (ja) | イソシアヌル酸エステルの製造方法 |