JPH059479A - Method for reforming heavy oil fuel - Google Patents

Method for reforming heavy oil fuel

Info

Publication number
JPH059479A
JPH059479A JP16042491A JP16042491A JPH059479A JP H059479 A JPH059479 A JP H059479A JP 16042491 A JP16042491 A JP 16042491A JP 16042491 A JP16042491 A JP 16042491A JP H059479 A JPH059479 A JP H059479A
Authority
JP
Japan
Prior art keywords
heavy oil
iron
based material
additive
combustion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16042491A
Other languages
Japanese (ja)
Other versions
JP2862406B2 (en
Inventor
Toshimitsu Ichinose
利光 一ノ瀬
Kimiyo Tokuda
君代 徳田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP16042491A priority Critical patent/JP2862406B2/en
Publication of JPH059479A publication Critical patent/JPH059479A/en
Application granted granted Critical
Publication of JP2862406B2 publication Critical patent/JP2862406B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To reform a heavy oil fuel so that it burns at a high combustion efficiency with little smoke dust generation. CONSTITUTION:A heavy oil 11, a powdered additive 42, and an iron-based material 44 are mixed and stirred to cause the iron-based material to wear out, and the remaining coarse particles of the iron-based material are removed from the mixture, thus giving a reformed heavy oil contg. the additive and the finely powdered iron-based material as a catalyst for combustion.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、産業用、事業用の重質
油焚きボイラ等に用いられる重質油燃料の改質方法に関
する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for reforming heavy oil fuel used in heavy oil-fired boilers for industrial and business use.

【0002】[0002]

【従来の技術】ボイラ等における従来の重質油の燃焼シ
ステムでは、重質油の温度を上げ、粘度低下によるバー
ナでの噴霧を良好にする程度の処理しか行なわれていな
かった。図2は、この種の従来の燃焼装置の系統図であ
り、重質油は燃料タンク10からポンプ20で直接ボイ
ラ30へ送られて燃焼されている。
2. Description of the Related Art In a conventional heavy oil combustion system in a boiler or the like, only the treatment for increasing the temperature of the heavy oil and improving the spraying by a burner due to a decrease in viscosity is performed. FIG. 2 is a system diagram of a conventional combustion device of this type, in which heavy oil is directly sent from a fuel tank 10 to a boiler 30 by a pump 20 and burned.

【0003】[0003]

【発明が解決しようとする課題】重質油等の揮発分の少
ない燃料では、かなり良好なバーナでの噴霧状態(平均
噴霧粒径で約百μm 前後)でも完全に燃え切れず、未燃
ばいじんが多く発生する。
[Problems to be Solved by the Invention] With a fuel having a low volatile content such as heavy oil, even if it is sprayed in a fairly good burner (average spray particle size is about 100 μm), it will not burn out completely and will not burn. Often occurs.

【0004】これは、燃料中の残留炭素の燃焼速度が非
常に遅いことに起因しており、このように燃焼速度の遅
い残留炭素の構造は「流れ構造」となっている。同じ残
留炭素でも「モザイク構造」のものは燃焼速度は速く燃
え切り性も優れるが、重質油の残留炭素のほとんどは
「流れ構造」を形成している。
This is because the burning rate of residual carbon in the fuel is very slow, and the structure of residual carbon having such a slow burning rate is a "flow structure". Even with the same residual carbon, those with a “mosaic structure” have a high burning rate and excellent burn-out characteristics, but most of the residual carbon in heavy oil forms a “flow structure”.

【0005】なお、前記の「モザイク構造」とは、残留
炭素が数μm 程度の見掛け粒子の群として存在する状態
をいゝ、また前記の「流れ構造」とは、残留炭素は粒子
群としては存在せず、あたかも流動しているように長く
存在する状態をいう。
The above "mosaic structure" means that residual carbon exists as a group of apparent particles having a size of several μm, and the above "flow structure" means that residual carbon does not form a group of particles. It does not exist, but it exists for a long time as if it were flowing.

【0006】本発明は、従来の重質油の燃焼に当っての
以上の問題点を解決することができる重質油燃料の改質
方法を提供しようとするものである。
The present invention is intended to provide a method for reforming a heavy oil fuel which can solve the above problems in the conventional combustion of heavy oil.

【0007】[0007]

【課題を解決するための手段】本発明の重質油燃料の改
質方法は、重質油に微粉状添加剤と鉄系材料とを添加
し、これを混合、攪拌して鉄系材料を摩耗させると共に
同鉄系材料の微粉末と前記微粉状添加剤を重質油中に混
入させた上、同重質油から鉄系材料の粗粒を分離するよ
うにした。
A method for reforming a heavy oil fuel according to the present invention comprises adding a finely powdered additive and an iron-based material to heavy oil, mixing and stirring the iron-based material. At the same time, the fine powder of the iron-based material and the finely powdered additive were mixed in the heavy oil while being abraded, and the coarse particles of the iron-based material were separated from the heavy oil.

【0008】[0008]

【作用】本発明では、重質油に微粉状添加剤と鉄系材料
を添加したものを混合、攪拌することによって、鉄系材
料の衝突、摩擦によって微粉状添加剤と重質油の混合状
態が均一になる。同時に、鉄系材料の摩耗によって鉄系
材料の微粉末が重質油中に均一に混入する。
In the present invention, the mixed state of the fine powdery additive and the heavy oil is caused by collision and friction of the ironous material by mixing and stirring the heavy oil to which the finely powdered additive and the iron-based material are added. Becomes uniform. At the same time, the fine powder of the iron-based material is uniformly mixed into the heavy oil due to the wear of the iron-based material.

【0009】次いで、この重質油から鉄系材料の粗粒を
分離することによって、微粉状添加剤と鉄系材料の微粉
末が均一に混入した改質された重質油が得られる。
Then, by separating the coarse particles of the iron-based material from the heavy oil, a modified heavy oil in which the fine powdery additive and the fine powder of the iron-based material are uniformly mixed can be obtained.

【0010】この改質された重質油では、均一に混入さ
れた微粉状添加剤が核となって残留炭素の「流れ構造」
が燃焼速度が早い「モザイク構造」となる。また、重質
油に混入された鉄系材料の微粉末は、燃焼場における高
温域で燃焼触媒となり、残留炭素の「モザイク構造」化
を促進すると共に燃焼反応が促進され、未燃ばいじん量
が低減する。従って、この改質された重質油は、効率よ
く未燃ばいじん量が少い状態で燃焼されることゝなる。
In this reformed heavy oil, the finely powdered additive uniformly mixed serves as a core for the "flow structure" of residual carbon.
Has a "mosaic structure" with a fast burning rate. In addition, the fine powder of iron-based material mixed in heavy oil serves as a combustion catalyst in the high temperature region of the combustion field, promotes the formation of residual carbon "mosaic structure", promotes the combustion reaction, and reduces the amount of unburned dust. Reduce. Therefore, the reformed heavy oil is efficiently burned in a state where the amount of unburned dust is small.

【0011】また、重質油中からは鉄系粗粒が除去さ
れ、バーナ等を損傷することがない。なお、本発明で用
いられる前記微粉状添加剤の粒度は、これが核となって
重質油中の残留炭素の状態を「流れ構造」から「モザイ
ク構造」に変える観点から、小さい程よく、0.2mm
以下が望ましい。また、微粉状添加剤は、基本的には直
径ができるだけ小さい粒子であればよいが、燃焼排ガス
の性状に悪影響を与えるものを避ける必要があり、カー
ボンブラック、Ca、鉄(Fe)等の微粉が用いられ
る。
Further, iron-based coarse particles are removed from the heavy oil, and the burner or the like is not damaged. From the viewpoint of changing the state of residual carbon in heavy oil from "flow structure" to "mosaic structure", the finer the particle size of the finely powdered additive used in the present invention, the better. 2 mm
The following is desirable. Further, the fine powder additive basically needs to be particles whose diameter is as small as possible, but it is necessary to avoid those which adversely affect the properties of combustion exhaust gas, and fine powder such as carbon black, Ca, iron (Fe), etc. Is used.

【0012】また、鉄系材料としては、Fe、Fe2
3 、Fe35 等が用いられ、前記の混合、攪拌後に鉄系
材料の粗粒を分離した重質油中に含まれる鉄系材料の微
粉末の粒度を0.2mm以下とすることが望ましい。
Further, as the iron-based material, Fe, Fe 2 O
3, F e3 O 5 or the like is used, mixing of the, the particle size of the fine powder of iron-based material be 0.2mm or less contained in the heavy oil separated coarse iron-based material after stirring desirable.

【0013】[0013]

【実施例】本発明の一実施例を、図1によって説明す
る。燃料タンク10からポンプ20により送られた重質
油11は、ロッドシェル型式等の回転式混合攪拌機40
に供給される。同時に、混合攪拌機40には、微粉状添
加剤42及び鉄くず等の鉄系材料44が供給される。前
記微粉状添加剤42としては、粗度0.2mm以下のカ
ーボンブラック,Ca又はFe等の微粉が用いられ、ま
た鉄系材料44としては、Fe、Fe2 3 、Fe35
等が用いられる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described with reference to FIG. The heavy oil 11 sent from the fuel tank 10 by the pump 20 is a rotary mixing stirrer 40 such as a rod shell type.
Is supplied to. At the same time, the finely powdered additive 42 and the iron-based material 44 such as iron scrap are supplied to the mixing stirrer 40. As the fine powder additive 42, roughness 0.2mm or less of the carbon black, fine powders such as Ca or Fe is used, and as the iron-based material 44, Fe, Fe 2 O 3 , F e3 O 5
Etc. are used.

【0014】この混合攪拌機40では、回転による鉄系
材料同志の衝突、摩擦により鉄系材料の微粉末ができる
とともに、添加剤42と重質油11の均一な混合が行な
われる。
In the mixing stirrer 40, the iron-based materials collide with each other due to the rotation and fine powder of the iron-based material is produced by friction, and the additive 42 and the heavy oil 11 are uniformly mixed.

【0015】混合攪拌機40を出た性状改質後の重質油
41は、粗粒分級器50に導かれ、0.2mm以上の所
定以上の粗粒子の除去が行なわれる。粗粒子51は再び
混合攪拌機40に戻される。粗粒分級器51からの粗粒
子のない改質された重質油52は燃料としてボイラ30
に投入される。
The property-improved heavy oil 41 discharged from the mixing stirrer 40 is introduced into a coarse-grain classifier 50, and coarse particles having a size of 0.2 mm or more are removed. The coarse particles 51 are returned to the mixing stirrer 40 again. The reformed heavy oil 52 without coarse particles from the coarse particle classifier 51 is used as fuel for the boiler 30.
Be thrown into.

【0016】前記の微粉状添加剤42と鉄系材料の微粉
末が混入された改質された重質油52は、微粉状添加剤
42を核として残留炭素が「流れ構造」から「モザイク
構造」の状態となっていて、燃焼速度が早く、かつ、鉄
系材料の微粉末は高温の燃焼物において燃焼触媒とな
り、残留炭素の「モザイク構造」化と重質油の燃焼を促
進する。従って、前記の改質された重質油52は、ボイ
ラ30で効率よく、かつ、未燃ばいじん量が少い状態で
燃焼させることができる。
In the modified heavy oil 52 in which the finely powdered additive 42 and the fine powder of the iron-based material are mixed, the residual carbon is formed from the "flow structure" to the "mosaic structure" with the finely powdered additive 42 as the core. In this state, the combustion speed is fast, and the fine powder of the iron-based material serves as a combustion catalyst in a high-temperature combustion product, and promotes the "mosaic structure" of residual carbon and the combustion of heavy oil. Therefore, the reformed heavy oil 52 can be efficiently burned in the boiler 30 with a small amount of unburned dust.

【0017】更に、改質された重質油52からは鉄系材
料の粗粒が分離されており、粗粒の鉄系材料をボイラ3
0内へ持込まずバーナ等を損傷することのない燃焼が可
能である。
Further, coarse grains of the iron-based material are separated from the reformed heavy oil 52, and the coarse-grained iron-based material is used for the boiler 3.
Combustion is possible without damaging the burner etc. without bringing it into the 0.

【0018】[0018]

【発明の効果】以上説明したように、本発明によれば、
微粉状添加物によって残留炭素が「モザイク構造」とさ
れ、かつ、燃焼触媒となる鉄系材料の微粒子が混入さ
れ、効率よく燃焼できると共に未燃ばいじんの発生の少
い改質された重質油を得ることができる。
As described above, according to the present invention,
Carbon powder is made into a "mosaic structure" by finely powdered additives, and fine particles of iron-based materials that act as combustion catalysts are mixed in to enable efficient combustion and a reformed heavy oil that produces less unburned dust. Can be obtained.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の一実施例の系統図である。FIG. 1 is a system diagram of an embodiment of the present invention.

【図2】従来例の燃焼装置の系統図である。FIG. 2 is a system diagram of a conventional combustion device.

【符号の説明】[Explanation of symbols]

10 燃料タンク 11 重質油 30 ボイラ 40 混合攪拌機 42 微粉状添加剤 44 鉄系材料 50 粗粒分級器 52 改質された重質油 10 Fuel Tank 11 Heavy Oil 30 Boiler 40 Mixing Stirrer 42 Fine Powder Additive 44 Iron-based Material 50 Coarse Grain Classifier 52 Reformed Heavy Oil

Claims (1)

【特許請求の範囲】 【請求項1】 重質油に微粉状添加剤と鉄系材料とを添
加し、これを混合、攪拌して鉄系材料を摩耗させると共
に同鉄系材料の微粉末と前記微粉状添加剤を重質油中に
混入させた上、同重質油から鉄系材料の粗粒を分離する
ことを特徴とする重質油燃料の改質方法。
Claim: What is claimed is: 1. A fine powdery additive and an iron-based material are added to heavy oil, which are mixed and stirred to abrade the iron-based material and fine powder of the iron-based material. A method for reforming a heavy oil fuel, which comprises mixing the finely divided additive into heavy oil and separating coarse particles of an iron-based material from the heavy oil.
JP16042491A 1991-07-01 1991-07-01 Heavy oil fuel reformer Expired - Fee Related JP2862406B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16042491A JP2862406B2 (en) 1991-07-01 1991-07-01 Heavy oil fuel reformer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16042491A JP2862406B2 (en) 1991-07-01 1991-07-01 Heavy oil fuel reformer

Publications (2)

Publication Number Publication Date
JPH059479A true JPH059479A (en) 1993-01-19
JP2862406B2 JP2862406B2 (en) 1999-03-03

Family

ID=15714630

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16042491A Expired - Fee Related JP2862406B2 (en) 1991-07-01 1991-07-01 Heavy oil fuel reformer

Country Status (1)

Country Link
JP (1) JP2862406B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008072619A1 (en) * 2006-12-11 2008-06-19 Opt Creation, Inc. Apparatus and process for production of nanobubble liquid
US8615166B2 (en) 2006-01-26 2013-12-24 Lg Electronics Inc. Steam generator and washing machine therewith

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8615166B2 (en) 2006-01-26 2013-12-24 Lg Electronics Inc. Steam generator and washing machine therewith
WO2008072619A1 (en) * 2006-12-11 2008-06-19 Opt Creation, Inc. Apparatus and process for production of nanobubble liquid
US9416329B2 (en) 2006-12-11 2016-08-16 Opt Creation, Inc. Apparatus and process for production of nanobubble liquid

Also Published As

Publication number Publication date
JP2862406B2 (en) 1999-03-03

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