JP2862406B2 - Heavy oil fuel reformer - Google Patents

Heavy oil fuel reformer

Info

Publication number
JP2862406B2
JP2862406B2 JP16042491A JP16042491A JP2862406B2 JP 2862406 B2 JP2862406 B2 JP 2862406B2 JP 16042491 A JP16042491 A JP 16042491A JP 16042491 A JP16042491 A JP 16042491A JP 2862406 B2 JP2862406 B2 JP 2862406B2
Authority
JP
Japan
Prior art keywords
heavy oil
iron
based material
fine powder
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP16042491A
Other languages
Japanese (ja)
Other versions
JPH059479A (en
Inventor
利光 一ノ瀬
君代 徳田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP16042491A priority Critical patent/JP2862406B2/en
Publication of JPH059479A publication Critical patent/JPH059479A/en
Application granted granted Critical
Publication of JP2862406B2 publication Critical patent/JP2862406B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、産業用、事業用の重質
油焚きボイラ等に用いられる重質油燃料の改質装置に関
する。
The present invention relates to industrial, related to <br/> the reformer of heavy oil fuels used in heavy oil-fired boiler or the like for business.

【0002】[0002]

【従来の技術】ボイラ等における従来の重質油の燃焼シ
ステムでは、重質油の温度を上げ、粘度低下によるバー
ナでの噴霧を良好にする程度の処理しか行なわれていな
かった。図2は、この種の従来の燃焼装置の系統図であ
り、重質油は燃料タンク10からポンプ20で直接ボイ
ラ30へ送られて燃焼されている。
2. Description of the Related Art In a conventional heavy oil combustion system in a boiler or the like, only a process of raising the temperature of the heavy oil and improving spraying by a burner due to a decrease in viscosity has been performed. FIG. 2 is a system diagram of a conventional combustion apparatus of this type, in which heavy oil is directly sent from a fuel tank 10 to a boiler 30 by a pump 20 for combustion.

【0003】[0003]

【発明が解決しようとする課題】重質油等の揮発分の少
ない燃料では、かなり良好なバーナでの噴霧状態(平均
噴霧粒径で約百μm 前後)でも完全に燃え切れず、未燃
ばいじんが多く発生する。
A fuel with a low volatility, such as heavy oil, cannot completely burn even in a spray state with a fairly good burner (approximately 100 μm in average spray particle size), and does not burn unburned dust. Often occur.

【0004】これは、燃料中の残留炭素の燃焼速度が非
常に遅いことに起因しており、このように燃焼速度の遅
い残留炭素の構造は「流れ構造」となっている。同じ残
留炭素でも「モザイク構造」のものは燃焼速度は速く燃
え切り性も優れるが、重質油の残留炭素のほとんどは
「流れ構造」を形成している。
[0004] This is because the burning rate of residual carbon in the fuel is very slow, and the structure of residual carbon having such a slow burning rate is a "flow structure". Even with the same residual carbon, those with a “mosaic structure” have a high burning rate and excellent burn-out properties, but most of the residual carbon in heavy oil forms a “flow structure”.

【0005】なお、前記の「モザイク構造」とは、残留
炭素が数μm 程度の見掛け粒子の群として存在する状態
をいゝ、また前記の「流れ構造」とは、残留炭素は粒子
群としては存在せず、あたかも流動しているように長く
存在する状態をいう。
[0005] The "mosaic structure" refers to a state in which residual carbon exists as a group of apparent particles having a size of about several µm. The "flow structure" refers to a state in which residual carbon is a particle group. It is a state that does not exist and exists for a long time as if it were flowing.

【0006】本発明は、従来の重質油の燃焼に当っての
以上の問題点を解決することができる重質油燃料の改質
を行うものであって、従来の燃焼系統に組み込め、重質
油燃料の改質のための添加物を効率よく効果的に混入し
調整することができ、バーナーでの燃焼において障害を
生じない重質油燃料の改質装置を提供することを課題
するものである。
[0006] The present invention is directed to reforming heavy oil fuel which can solve the above-mentioned problems associated with conventional heavy oil combustion.
That can be incorporated into conventional combustion systems,
Add additives for reforming oil fuel efficiently and effectively
Can be adjusted to prevent obstruction in combustion in the burner
It is an object of the present invention to provide a heavy oil fuel reforming apparatus that does not generate .

【0007】[0007]

【課題を解決するための手段】本発明の重質油燃料の改
装置は、重質油に微粉状添加剤と鉄系材料とを添加
し、これを混合、攪拌して鉄系材料を摩耗させると共に
同鉄系材料の微粉末と前記微粉状添加剤を重質油中に混
入させる混合攪拌機と、同混合攪拌機から取り出された
混合物から粗粒を分離する粗粒分級機とを有し、同粗粒
分級機で分離された粗粒を前記混合攪拌機に戻すように
構成されてなることを特徴とするものである
The heavy oil fuel reforming apparatus of the present invention comprises adding a fine powdered additive and an iron-based material to heavy oil, mixing and stirring the same, and converting the iron-based material. a fine powder and mixing agitator Ru is mixed the fine powder additive to the heavy oil of the same iron-based material causes wear, it has been removed from the mixing stirrer
A coarse particle classifier for separating coarse particles from the mixture;
The coarse particles separated by the classifier are returned to the mixing stirrer.
It is characterized by being constituted .

【0008】[0008]

【作用】本発明装置によれば、重質油に改質のための添
加物として微粉状添加剤と鉄系材料を添加したものを
合攪拌機内で混合、攪拌することによって、鉄系材料の
衝突、摩擦によって微粉状添加剤と重質油の混合状態が
均一になる。同時に、鉄系材料の摩耗によって鉄系材料
の微粉末が重質油中に均一に混入する。
According to the device of the present invention, heavy oil is added for reforming.
Mixing the material obtained by adding fine powder additive and ferrous material as Addendum
By mixing and stirring in the mixing stirrer, the mixing state of the fine powder additive and the heavy oil becomes uniform due to the collision and friction of the iron-based material. At the same time, the fine powder of the iron-based material is uniformly mixed in the heavy oil due to the wear of the iron-based material.

【0009】次いで、この混合物から粗粒子は粗粒分級
器により分離されて混合攪拌機に戻され再度混合、攪拌
されるので、重質油から鉄系材料の粗粒を分離すること
ができ混入される鉄系材料の粒度が調整され、微粉状添
加剤と鉄系材料の微粉末が均一に混入した改質された重
質油が得られるものである
Next, coarse particles are separated from this mixture by coarse classification.
Separated by a mixer and returned to the mixing stirrer to mix and stir again
Since it is, separating the coarse iron-based material from heavy oil
It is adjusted grain size of the ferrous material to be mixed can, in which heavy oil that has been modified fine powder was homogeneously mixed pulverulent additive and ferrous material is obtained.

【0010】この改質された重質油では、均一に混入さ
れた微粉状添加剤が核となって残留炭素の「流れ構造」
が燃焼速度が早い「モザイク構造」となる。また、重質
油に混入された鉄系材料の微粉末は、燃焼場における高
温域で燃焼触媒となり、残留炭素の「モザイク構造」化
を促進すると共に燃焼反応が促進され、未燃ばいじん量
が低減する。従って、この改質された重質油は、効率よ
く未燃ばいじん量が少い状態で燃焼されることゝなる。
[0010] In this modified heavy oil, the finely powdered additive uniformly mixed serves as a nucleus to form a "flow structure" of residual carbon.
Has a “mosaic structure” with a fast burning rate. In addition, the fine powder of the iron-based material mixed into the heavy oil serves as a combustion catalyst in a high temperature region in the combustion field, and promotes a “mosaic structure” of the residual carbon, promotes a combustion reaction, and reduces the amount of unburned soot and dust. Reduce. Therefore, the reformed heavy oil is efficiently burned in a state where the amount of unburned dust is small.

【0011】また、重質油中からは鉄系粗粒が除去さ
れ、バーナ等を損傷することがない。なお、本発明で用
いられる前記微粉状添加剤の粒度は、これが核となって
重質油中の残留炭素の状態を「流れ構造」から「モザイ
ク構造」に変える観点から、小さい程よく、0.2mm
以下が望ましい。また、微粉状添加剤は、基本的には直
径ができるだけ小さい粒子であればよいが、燃焼排ガス
の性状に悪影響を与えるものを避ける必要があり、カー
ボンブラック、Ca、鉄(Fe)等の微粉が用いられ
る。
Further, iron-based coarse particles are removed from the heavy oil, so that the burner and the like are not damaged. The particle size of the fine powder additive used in the present invention is preferably as small as possible from the viewpoint of changing the state of the residual carbon in the heavy oil from the “flow structure” to the “mosaic structure” as a core. 2mm
The following is desirable. In addition, the finely powdered additive may basically be particles having a diameter as small as possible, but it is necessary to avoid those that adversely affect the properties of the combustion exhaust gas, and fine powders such as carbon black, Ca, iron (Fe), etc. Is used.

【0012】また、鉄系材料としては、Fe、Fe2
3 、Fe35 等が用いられ、前記の混合、攪拌後に鉄系
材料の粗粒を分離した重質油中に含まれる鉄系材料の微
粉末の粒度を0.2mm以下とすることが望ましい。
Further, as the iron-based material, Fe, Fe 2 O
3, F e3 O 5 or the like is used, mixing of the, the particle size of the fine powder of iron-based material be 0.2mm or less contained in the heavy oil separated coarse iron-based material after stirring desirable.

【0013】[0013]

【実施例】本発明の一実施例を、図1によって説明す
る。燃料タンク10はポンプ20を介してロッドシェル
型式等の回転式の混合攪拌機40に接続しており、同混
合攪拌機40には重質油燃料改質のための添加物として
微粉状添加剤42及び鉄くず等の鉄系材料44が供給さ
れる。混合攪拌機40には下流側に粗粒分級器50が接
続しており、混合攪拌機40でできた混合物中の粗粒が
分離される。同粗粒は粗粒分級器50から混合攪拌機4
0への適宜の送給手段により混合攪拌機40へ戻され、
再度混合攪拌される。上記の本実施例においては、供給
燃料タンク10からポンプ20により送られた重質油1
1は、混合攪拌機40に供給され同時に、混合攪拌機
40には、微粉状添加剤42及び鉄くず等の鉄系材料4
4が供給される。前記微粉状添加剤42としては、粗度
0.2mm以下のカーボンブラック,Ca又はFe等の
微粉が用いられ、また鉄系材料44としては、Fe、F
2 3 、Fe35 等が用いられる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS One embodiment of the present invention will be described with reference to FIG. The fuel tank 10 is connected to a rod shell via a pump 20.
It is connected to a rotary mixing stirrer 40 such as
As an additive for heavy oil fuel reforming,
The powdery additive 42 and the iron-based material 44 such as iron scrap are supplied.
It is. A coarse particle classifier 50 is connected to the mixing stirrer 40 on the downstream side.
The coarse particles in the mixture formed by the mixing stirrer 40
Separated. The coarse particles are fed from a coarse classifier 50 to a mixing stirrer 4.
0 to the mixing stirrer 40 by appropriate feeding means,
It is mixed and stirred again. In the above embodiment, the heavy oil 1 sent from the supply fuel tank 10 by the pump 20 is used.
1 is supplied to a mixing stirrer 40, and at the same time, a fine powdery additive 42 and an iron-based material 4
4 are supplied. Fine powder such as carbon black, Ca or Fe having a roughness of 0.2 mm or less is used as the fine powder additive 42, and Fe, F
e 2 O 3, F e3 O 5 or the like is used.

【0014】この混合攪拌機40では、回転による鉄系
材料同志の衝突、摩擦により鉄系材料の微粉末ができる
とともに、添加剤42と重質油11の均一な混合が行な
われる。
In the mixing stirrer 40, fine powder of the iron-based material is produced by the collision and friction between the iron-based materials due to rotation, and the additive 42 and the heavy oil 11 are uniformly mixed.

【0015】混合攪拌機40を出た混合物、すなわち
状改質後の重質油41は、粗粒分級器50に導かれ、
0.2mm以上の所定以上の粗粒51の除去が行なわれ
る。粗粒51は適宜の送給手段によって再び混合攪拌機
40に戻される。粗粒分級器5からの粗粒51のない
添加物の粒度の調整された改質された重質油52は燃料
としてボイラ30に投入される。
The mixture leaving the mixing stirrer 40 , that is, the heavy oil 41 after the property modification , is led to a coarse particle classifier 50,
Removal of coarse particles 51 of a predetermined size of 0.2 mm or more is performed. The coarse particles 51 are returned to the mixing stirrer 40 again by an appropriate feeding means . No coarse 51 from coarse classifier 5 0
The reformed heavy oil 52 whose additive particle size has been adjusted is fed into the boiler 30 as fuel.

【0016】前記の微粉状添加剤42と鉄系材料の微粉
末が混入された改質された重質油52は、微粉状添加剤
42を核として残留炭素が「流れ構造」から「モザイク
構造」の状態となっていて、燃焼速度が早く、かつ、鉄
系材料の微粉末は高温の燃焼物において燃焼触媒とな
り、残留炭素の「モザイク構造」化と重質油の燃焼を促
進する。従って、前記の改質された重質油52は、ボイ
ラ30で効率よく、かつ、未燃ばいじん量が少い状態で
燃焼させることができる。
In the modified heavy oil 52 into which the fine powder additive 42 and the fine powder of the iron-based material are mixed, the residual carbon is changed from the “flow structure” to the “mosaic structure” with the fine powder additive 42 as a core. , The combustion speed is high, and the fine powder of the iron-based material becomes a combustion catalyst in a high-temperature combustion product, and promotes the "mosaic structure" of residual carbon and the combustion of heavy oil. Therefore, the reformed heavy oil 52 can be efficiently burned in the boiler 30 with a small amount of unburned dust.

【0017】更に、改質された重質油52からは鉄系材
料の粗粒51が分離されており、粗粒の鉄系材料をボイ
ラ30内へ持込まずバーナ等を損傷することのない燃焼
が可能である。
Further, coarse particles 51 of an iron-based material are separated from the reformed heavy oil 52, so that the coarse-grained iron-based material is not brought into the boiler 30 and combustion without damaging a burner or the like. Is possible.

【0018】[0018]

【発明の効果】以上説明したように、本発明によれば
重質油中に微粉状添加物と鉄系材料と を加え混合攪拌
し、混合物中の粗粒は粗粒分級器により分離されて戻さ
れ再度混合攪拌するので、鉄系材料の衝突、摩擦によっ
て微粉状添加剤と重質油の混合状態を均一にでき、同時
に、鉄系材料の摩耗によって生ずる鉄系材料の微粉末を
粒度を調整して重質油中に均一に混入させることができ
るものであり、以上本発明装置により改質された重質油
燃料は、微粉状添加物によって残留炭素が「モザイク構
造」とされ、かつ、燃焼触媒となる鉄系材料の微粉末
混入され、効率よく燃焼できると共に未燃ばいじんの発
生の少いものとなる
As described above, according to the present invention ,
Add fine powdered additives and iron-based materials to heavy oil and mix and stir
The coarse particles in the mixture are separated and returned by a coarse classifier.
Mixed and stirred again, causing collisions and friction of ferrous materials.
The mixing state of the fine powdered additive and heavy oil can be
In addition, fine powder of iron-based material generated by wear of iron-based material
The particle size can be adjusted to mix evenly into heavy oil
Heavy oil modified by the apparatus of the present invention
Fuel, residual carbon by pulverulent additive is a "mosaic structure", and is mixed fine powder of iron-based material as a combustion catalyst becomes less occurrence of unburned soot with can be efficiently burned .

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施例の系統図である。FIG. 1 is a system diagram of one embodiment of the present invention.

【図2】従来例の燃焼装置の系統図である。FIG. 2 is a system diagram of a conventional combustion device.

【符号の説明】[Explanation of symbols]

10 燃料タンク 11 重質油20 ポンプ 30 ボイラ 40 混合攪拌機 42 微粉状添加剤 44 鉄系材料 50 粗粒分級器51 粗粒 52 改質された重質油DESCRIPTION OF SYMBOLS 10 Fuel tank 11 Heavy oil 20 Pump 30 Boiler 40 Mixing stirrer 42 Fine powder additive 44 Iron-based material 50 Coarse classifier 51 Coarse particle 52 Modified heavy oil

───────────────────────────────────────────────────── フロントページの続き (58)調査した分野(Int.Cl.6,DB名) C10L 1/12 C10L 10/06──────────────────────────────────────────────────続 き Continued on the front page (58) Field surveyed (Int.Cl. 6 , DB name) C10L 1/12 C10L 10/06

Claims (1)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】 重質油に微粉状添加剤と鉄系材料とを添
加し、これを混合、攪拌して鉄系材料を摩耗させると共
に同鉄系材料の微粉末と前記微粉状添加剤を重質油中に
混入させる混合攪拌機と、同混合攪拌機から取り出され
た混合物から粗粒を分離する粗粒分級機とを有し、同粗
粒分級機で分離された粗粒を前記混合攪拌機に戻すよう
に構成されてなることを特徴とする重質油燃料の改質
1. A fine powder additive and an iron-based material are added to heavy oil, mixed and stirred to wear the iron-based material, and a fine powder of the same iron-based material and the fine powdered additive are added. a mixing agitator Ru is mixed into the heavy oil is withdrawn from the mixing stirrer
A coarse particle classifier for separating coarse particles from the mixed mixture.
The coarse particles separated by the particle classifier are returned to the mixing stirrer.
Modifying instrumentation of heavy oil fuel, characterized by comprising configured
Place .
JP16042491A 1991-07-01 1991-07-01 Heavy oil fuel reformer Expired - Fee Related JP2862406B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16042491A JP2862406B2 (en) 1991-07-01 1991-07-01 Heavy oil fuel reformer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16042491A JP2862406B2 (en) 1991-07-01 1991-07-01 Heavy oil fuel reformer

Publications (2)

Publication Number Publication Date
JPH059479A JPH059479A (en) 1993-01-19
JP2862406B2 true JP2862406B2 (en) 1999-03-03

Family

ID=15714630

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16042491A Expired - Fee Related JP2862406B2 (en) 1991-07-01 1991-07-01 Heavy oil fuel reformer

Country Status (1)

Country Link
JP (1) JP2862406B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101233164B1 (en) 2006-01-26 2013-02-15 엘지전자 주식회사 Steam generator and washing machine using the same
EP2116589A4 (en) 2006-12-11 2013-12-11 Opt Creation Inc Apparatus and process for production of nanobubble liquid

Also Published As

Publication number Publication date
JPH059479A (en) 1993-01-19

Similar Documents

Publication Publication Date Title
US4752302A (en) Method and composition for improving flame combustion of liquid carbonaceous fuels
AU2005201468B2 (en) Additive-induced control of NOx emissions in a coal burning utility furnace
EP2129750B1 (en) Method of supplying iron to the particulate trap of a diesel engine exhaust
CN101126037A (en) Nanoalloy fuel additives
JP2862406B2 (en) Heavy oil fuel reformer
WO2009090760A1 (en) Fuel additives
JP2005520927A (en) Catalytic metal additive concentrates and methods for making and using the same
CN101134347A (en) Production technology of unburned aluminum carbon sliding brick containing nanometer aluminum oxide
US4722740A (en) Dispersions of coal in water useful as a fuel
EP1111027B1 (en) Water-in-oil type emulsion fuel oil
JP2007015884A (en) Method and apparatus for manufacturing spherical fine inorganic powder
US4080177A (en) Colloidal magnesium suspension in critical low concentration in jet fuel
US3019145A (en) High energy hydrocarbon fuel containing magnesium alloys
JP2625240B2 (en) Coal / water slurry production method
JP3045395B2 (en) Method for producing silicon carbide-containing aluminum alloy
US4530701A (en) Process of manufacturing a co-fuel additive with combustion-modifying effects
WO2005017076A1 (en) Metal oxide-containing dispersion and method of preparing the same
JP2787692B2 (en) How to burn solid fuel
JP3670023B2 (en) Method for producing toner for developing electrostatic image
JPS644560B2 (en)
KR100227965B1 (en) Comburent composition for reforming heavy fuel oil
JPH0633373B2 (en) Iron oxide for fuel additive and method of using the same
Clayfield et al. COLLOIL manufacture and application
JPS5921374B2 (en) NOx suppression sintering operation method
Singh et al. A Review on Methods Available for Doping of High Energy Boron Particles Into Liquid Fuels

Legal Events

Date Code Title Description
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 19981110

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20071211

Year of fee payment: 9

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20081211

Year of fee payment: 10

LAPS Cancellation because of no payment of annual fees