JPH0587110B2 - - Google Patents
Info
- Publication number
- JPH0587110B2 JPH0587110B2 JP63125423A JP12542388A JPH0587110B2 JP H0587110 B2 JPH0587110 B2 JP H0587110B2 JP 63125423 A JP63125423 A JP 63125423A JP 12542388 A JP12542388 A JP 12542388A JP H0587110 B2 JPH0587110 B2 JP H0587110B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- oil
- catalysts
- reaction
- heavy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 claims description 55
- 239000003921 oil Substances 0.000 claims description 28
- 238000005984 hydrogenation reaction Methods 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000002803 fossil fuel Substances 0.000 claims description 6
- 238000004821 distillation Methods 0.000 claims description 5
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 4
- 239000003502 gasoline Substances 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 description 13
- 238000000354 decomposition reaction Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 7
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 238000005504 petroleum refining Methods 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 4
- 229910000423 chromium oxide Inorganic materials 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- ADCBRSDRBJKLFK-UHFFFAOYSA-N zinc chromium(3+) oxygen(2-) Chemical compound [O-2].[Cr+3].[O-2].[Zn+2] ADCBRSDRBJKLFK-UHFFFAOYSA-N 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- -1 nickel-zinc oxide-chromium oxide Chemical compound 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 238000000944 Soxhlet extraction Methods 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- MSCWBQOVPYHYMA-UHFFFAOYSA-N [O-2].[Cr+3].[Zn+2].[O-2].[Fe+2] Chemical compound [O-2].[Cr+3].[Zn+2].[O-2].[Fe+2] MSCWBQOVPYHYMA-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63125423A JPH01294796A (ja) | 1988-05-23 | 1988-05-23 | 化石燃料油の多段式水素化分解方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63125423A JPH01294796A (ja) | 1988-05-23 | 1988-05-23 | 化石燃料油の多段式水素化分解方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01294796A JPH01294796A (ja) | 1989-11-28 |
| JPH0587110B2 true JPH0587110B2 (es) | 1993-12-15 |
Family
ID=14909734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63125423A Granted JPH01294796A (ja) | 1988-05-23 | 1988-05-23 | 化石燃料油の多段式水素化分解方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01294796A (es) |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS48102804A (es) * | 1972-03-13 | 1973-12-24 | ||
| JPS4933902A (es) * | 1972-07-28 | 1974-03-28 | ||
| JPS4961204A (es) * | 1972-05-12 | 1974-06-13 | ||
| JPS5263203A (en) * | 1975-11-17 | 1977-05-25 | Gulf Research Development Co | Maltiistage hydrogenation desulfurization method of residual oil |
| JPS5285109A (en) * | 1976-01-05 | 1977-07-15 | Inst Francais Du Petrole | Method of hydrogenation of unstable fraction of hydrocarbon |
| JPS5527399A (en) * | 1978-08-11 | 1980-02-27 | Uop Inc | Production of hydrocarbon distillate |
| JPS57177349A (en) * | 1981-04-08 | 1982-11-01 | British Petroleum Co | Catalyst for hydrogenation |
| JPS57190080A (en) * | 1981-05-16 | 1982-11-22 | Chiyoda Chem Eng & Constr Co Ltd | Hydrogenation of hydrocarbon in presence of fine particle |
| JPS6023482A (ja) * | 1983-02-10 | 1985-02-06 | カナダ国 | ドライブレンドした添加剤の存在下における重質油の水素添加分解方法 |
| JPS60195191A (ja) * | 1984-02-16 | 1985-10-03 | エイチアールアイ・インコーポレーテツド | 重質炭化水素液体供給原料の高転化用多段階接触方法 |
-
1988
- 1988-05-23 JP JP63125423A patent/JPH01294796A/ja active Granted
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS48102804A (es) * | 1972-03-13 | 1973-12-24 | ||
| JPS4961204A (es) * | 1972-05-12 | 1974-06-13 | ||
| JPS4933902A (es) * | 1972-07-28 | 1974-03-28 | ||
| JPS5263203A (en) * | 1975-11-17 | 1977-05-25 | Gulf Research Development Co | Maltiistage hydrogenation desulfurization method of residual oil |
| JPS5285109A (en) * | 1976-01-05 | 1977-07-15 | Inst Francais Du Petrole | Method of hydrogenation of unstable fraction of hydrocarbon |
| JPS5527399A (en) * | 1978-08-11 | 1980-02-27 | Uop Inc | Production of hydrocarbon distillate |
| JPS57177349A (en) * | 1981-04-08 | 1982-11-01 | British Petroleum Co | Catalyst for hydrogenation |
| JPS57190080A (en) * | 1981-05-16 | 1982-11-22 | Chiyoda Chem Eng & Constr Co Ltd | Hydrogenation of hydrocarbon in presence of fine particle |
| JPS6023482A (ja) * | 1983-02-10 | 1985-02-06 | カナダ国 | ドライブレンドした添加剤の存在下における重質油の水素添加分解方法 |
| JPS60195191A (ja) * | 1984-02-16 | 1985-10-03 | エイチアールアイ・インコーポレーテツド | 重質炭化水素液体供給原料の高転化用多段階接触方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01294796A (ja) | 1989-11-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |