JPH0579378B2 - - Google Patents

Info

Publication number

JPH0579378B2

JPH0579378B2 JP1205669A JP20566989A JPH0579378B2 JP H0579378 B2 JPH0579378 B2 JP H0579378B2 JP 1205669 A JP1205669 A JP 1205669A JP 20566989 A JP20566989 A JP 20566989A JP H0579378 B2 JPH0579378 B2 JP H0579378B2

Authority

JP

Japan

Prior art keywords

catalyst

alumina

silver

palladium

slurry

Prior art date

1989-08-10

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

Links

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• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 46
• 239000003054 catalyst Substances 0.000 claims description 38
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 27
• 229910052709 silver Inorganic materials 0.000 claims description 19
• 229910052763 palladium Inorganic materials 0.000 claims description 18
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
• 239000004332 silver Substances 0.000 claims description 11
• 239000000446 fuel Substances 0.000 claims description 8
• 238000002485 combustion reaction Methods 0.000 claims description 7
• 239000000203 mixture Substances 0.000 claims description 5
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
• 229910052710 silicon Inorganic materials 0.000 claims 1
• 239000010703 silicon Substances 0.000 claims 1
• 229910052719 titanium Inorganic materials 0.000 claims 1
• 239000010936 titanium Substances 0.000 claims 1
• 229910052726 zirconium Inorganic materials 0.000 claims 1
• 239000002002 slurry Substances 0.000 description 16
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
• 239000007864 aqueous solution Substances 0.000 description 11
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 9
• 239000007789 gas Substances 0.000 description 9
• 239000000843 powder Substances 0.000 description 8
• 150000003839 salts Chemical class 0.000 description 8
• 230000000052 comparative effect Effects 0.000 description 7
• 238000000746 purification Methods 0.000 description 7
• 239000011248 coating agent Substances 0.000 description 5
• 238000000576 coating method Methods 0.000 description 5
• 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 5
• UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
• MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
• 229910002091 carbon monoxide Inorganic materials 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
• 238000001035 drying Methods 0.000 description 3
• 238000010304 firing Methods 0.000 description 3
• 238000000034 method Methods 0.000 description 3
• 229940100890 silver compound Drugs 0.000 description 3
• 150000003379 silver compounds Chemical class 0.000 description 3
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• 150000001298 alcohols Chemical class 0.000 description 2
• 238000006243 chemical reaction Methods 0.000 description 2
• 229930195733 hydrocarbon Natural products 0.000 description 2
• 150000002430 hydrocarbons Chemical class 0.000 description 2
• 239000007788 liquid Substances 0.000 description 2
• 229910052751 metal Inorganic materials 0.000 description 2
• 239000002184 metal Substances 0.000 description 2
• 238000002156 mixing Methods 0.000 description 2
• 150000002940 palladium Chemical class 0.000 description 2
• RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
• SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
• 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
• 229910002796 Si–Al Inorganic materials 0.000 description 1
• 239000013543 active substance Substances 0.000 description 1
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
• 238000007664 blowing Methods 0.000 description 1
• 229910001593 boehmite Inorganic materials 0.000 description 1
• 239000000919 ceramic Substances 0.000 description 1
• HLVXFWDLRHCZEI-UHFFFAOYSA-N chromotropic acid Chemical compound OS(=O)(=O)C1=CC(O)=C2C(O)=CC(S(O)(=O)=O)=CC2=C1 HLVXFWDLRHCZEI-UHFFFAOYSA-N 0.000 description 1
• 239000003245 coal Substances 0.000 description 1
• 239000011247 coating layer Substances 0.000 description 1
• 239000006255 coating slurry Substances 0.000 description 1
• 238000004737 colorimetric analysis Methods 0.000 description 1
• 230000008602 contraction Effects 0.000 description 1
• 229910052878 cordierite Inorganic materials 0.000 description 1
• 239000013078 crystal Substances 0.000 description 1
• 230000006866 deterioration Effects 0.000 description 1
• JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
• 238000005516 engineering process Methods 0.000 description 1
• 238000011049 filling Methods 0.000 description 1
• 238000004817 gas chromatography Methods 0.000 description 1
• FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
• 239000012212 insulator Substances 0.000 description 1
• 230000007774 longterm Effects 0.000 description 1
• 238000004519 manufacturing process Methods 0.000 description 1
• 229910052757 nitrogen Inorganic materials 0.000 description 1
• TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
• 239000001301 oxygen Substances 0.000 description 1
• 229910052760 oxygen Inorganic materials 0.000 description 1
• GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
• 238000011056 performance test Methods 0.000 description 1
• 230000002035 prolonged effect Effects 0.000 description 1
• 238000010298 pulverizing process Methods 0.000 description 1
• 239000012495 reaction gas Substances 0.000 description 1
• 239000000377 silicon dioxide Substances 0.000 description 1
• 229910001961 silver nitrate Inorganic materials 0.000 description 1
• 229910001220 stainless steel Inorganic materials 0.000 description 1
• 239000010935 stainless steel Substances 0.000 description 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1