JPH0576602B2 - - Google Patents
Info
- Publication number
- JPH0576602B2 JPH0576602B2 JP59252880A JP25288084A JPH0576602B2 JP H0576602 B2 JPH0576602 B2 JP H0576602B2 JP 59252880 A JP59252880 A JP 59252880A JP 25288084 A JP25288084 A JP 25288084A JP H0576602 B2 JPH0576602 B2 JP H0576602B2
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- polymerization
- refractive index
- container
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000178 monomer Substances 0.000 claims description 64
- 238000006116 polymerization reaction Methods 0.000 claims description 51
- 239000000203 mixture Substances 0.000 claims description 34
- 230000009257 reactivity Effects 0.000 claims description 16
- 230000005540 biological transmission Effects 0.000 claims description 15
- 230000003287 optical effect Effects 0.000 claims description 15
- 229920003002 synthetic resin Polymers 0.000 claims description 15
- 239000000057 synthetic resin Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000009826 distribution Methods 0.000 description 29
- 229920001577 copolymer Polymers 0.000 description 27
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- -1 Vinyl aromatic carboxylates Chemical class 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- 238000012719 thermal polymerization Methods 0.000 description 7
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000013307 optical fiber Substances 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 239000005297 pyrex Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- AUHKVLIZXLBQSR-UHFFFAOYSA-N 1,2-dichloro-3-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC(Cl)=C1Cl AUHKVLIZXLBQSR-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 238000012660 binary copolymerization Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- ZJIHUSWGELHYBJ-UHFFFAOYSA-N ethenyl 2-chlorobenzoate Chemical compound ClC1=CC=CC=C1C(=O)OC=C ZJIHUSWGELHYBJ-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Chemical compound CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229920002100 high-refractive-index polymer Polymers 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- 238000012704 multi-component copolymerization Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Polymerisation Methods In General (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59252880A JPS61130904A (ja) | 1984-11-30 | 1984-11-30 | 合成樹脂光伝送体を製造する方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59252880A JPS61130904A (ja) | 1984-11-30 | 1984-11-30 | 合成樹脂光伝送体を製造する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61130904A JPS61130904A (ja) | 1986-06-18 |
| JPH0576602B2 true JPH0576602B2 (pt) | 1993-10-25 |
Family
ID=17243444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59252880A Granted JPS61130904A (ja) | 1984-11-30 | 1984-11-30 | 合成樹脂光伝送体を製造する方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61130904A (pt) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3010369B2 (ja) * | 1990-08-16 | 2000-02-21 | 康博 小池 | 合成樹脂光伝送体を製造する方法 |
| WO1994029758A1 (fr) * | 1993-06-16 | 1994-12-22 | Sumitomo Electric Industries, Ltd. | Materiau de base pour fibre optique plastique, sa production, et procede et appareil pour sa production |
| WO1995000868A1 (fr) * | 1993-06-18 | 1995-01-05 | Sumitomo Electric Industries, Ltd. | Procede et appareil de production de matiere plastique de base pour fibres optiques |
| JPH11119035A (ja) * | 1997-10-14 | 1999-04-30 | Sumitomo Wiring Syst Ltd | 屈折率分布型プラスチック光ファイバ用プリフォームの製造方法 |
| JP2004240122A (ja) | 2003-02-05 | 2004-08-26 | Fuji Photo Film Co Ltd | プラスチック光ファイバケーブルおよび製造方法 |
| US7590319B2 (en) | 2004-02-06 | 2009-09-15 | Fujifilm Corporation | Preform for plastic optical material, production method thereof, optical coupling method of plastic optical fiber and connector used for optical coupling |
| JP4018071B2 (ja) | 2004-03-30 | 2007-12-05 | 富士フイルム株式会社 | 光ファイバの欠陥検出装置及び方法 |
| JP2005292180A (ja) | 2004-03-31 | 2005-10-20 | Fuji Photo Film Co Ltd | プラスチック光ファイバ及びその製造方法 |
| KR20070054680A (ko) * | 2004-09-22 | 2007-05-29 | 후지필름 가부시키가이샤 | 플라스틱 광섬유 프리폼 및 그 제조 방법 |
| WO2006046749A1 (en) * | 2004-10-28 | 2006-05-04 | Fujifilm Corporation | Plastic optical member and producing method thereof |
| US7701641B2 (en) * | 2006-03-20 | 2010-04-20 | Ophthonix, Inc. | Materials and methods for producing lenses |
-
1984
- 1984-11-30 JP JP59252880A patent/JPS61130904A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61130904A (ja) | 1986-06-18 |
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