JPH0571606B2 - - Google Patents
Info
- Publication number
- JPH0571606B2 JPH0571606B2 JP63085538A JP8553888A JPH0571606B2 JP H0571606 B2 JPH0571606 B2 JP H0571606B2 JP 63085538 A JP63085538 A JP 63085538A JP 8553888 A JP8553888 A JP 8553888A JP H0571606 B2 JPH0571606 B2 JP H0571606B2
- Authority
- JP
- Japan
- Prior art keywords
- maleic anhydride
- vinyl ether
- methyl vinyl
- polymerization
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 36
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229920001577 copolymer Polymers 0.000 claims abstract description 24
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 12
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000003505 polymerization initiator Substances 0.000 claims description 8
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000007870 radical polymerization initiator Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 6
- 239000003999 initiator Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000000843 powder Substances 0.000 description 9
- -1 alkyl vinyl ethers Chemical class 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000003006 anti-agglomeration agent Substances 0.000 description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229920006222 acrylic ester polymer Polymers 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/04—Anhydrides, e.g. cyclic anhydrides
- C08F222/06—Maleic anhydride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polyethers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873712265 DE3712265A1 (de) | 1987-04-10 | 1987-04-10 | Verfahren zur herstellung von copolymerisaten mit hohem polymerisationsgrad |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6414222A JPS6414222A (en) | 1989-01-18 |
| JPH0571606B2 true JPH0571606B2 (US06534493-20030318-C00166.png) | 1993-10-07 |
Family
ID=6325383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63085538A Granted JPS6414222A (en) | 1987-04-10 | 1988-04-08 | Production of powdery copolymer of maleic anhydride and methyl vinyl ether |
Country Status (6)
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2692202B2 (ja) * | 1988-11-29 | 1997-12-17 | 日本油脂株式会社 | 無機粉末の油中分散安定剤 |
| DE3922170A1 (de) * | 1989-07-06 | 1991-01-10 | Giulini Chemie | Neue salze von poly(alkylvinylether-maleinsaeureanhydrid) und damit hergestellte zahnprothesehaftmittel |
| DE3937982A1 (de) * | 1989-11-15 | 1991-05-16 | Giulini Chemie | Verfahren zur herstellung von copolymerisaten aus maleinsaeuremonoalkylestern und vinylalkylethern |
| US5013806A (en) * | 1990-03-23 | 1991-05-07 | Eastman Kodak Company | Butadiene monoepoxide/maleic anhydride copolymers |
| US5064897A (en) * | 1990-08-30 | 1991-11-12 | Isp Investments Inc. | Process for making ethanol solutions of alkyl half-esters of copolymers of maleic anhydride and a C1 -C4 alkyl vinyl ether |
| JPH059235A (ja) | 1991-07-04 | 1993-01-19 | Daicel Chem Ind Ltd | 無水マレイン酸−アルキルビニルエ−テル共重合体の製造方法 |
| US5385995A (en) * | 1992-07-01 | 1995-01-31 | Daicel Chemical Industries, Ltd. | Process for the preparation of an alkyl vinyl ether/maleic anhydride copolymer |
| US5696181A (en) * | 1995-09-22 | 1997-12-09 | The Block Drug Company, Inc. | Denture fixative |
| US6214956B1 (en) * | 1997-10-02 | 2001-04-10 | Isp Investments Inc. | Solvent-free copolymers of maleic anhydride and alkyl vinyl ethers having a specific viscosity of 0.5 to 5 and method of making |
| US6184325B1 (en) * | 1999-03-16 | 2001-02-06 | Isp Investments Inc. | Solvent-free, fine white powders of high molecular weight copolymers of maleic anhydride and a C1-C4 alky vinyl ether without odor or taste |
| AU2001257480A1 (en) * | 2000-06-15 | 2001-12-24 | Isp Investments Inc. | Continuous, solvent-free process for making copolymers of maleic anhydride and c1-4 alkyl vinyl ether |
| DE10163449A1 (de) | 2000-07-28 | 2002-07-11 | Daicel Chem | Verfahren zur Herstellung von Copolymer aus Alkylvinylether und Maleinsäureanhydrid und Copolymer aus Alkylvinylether und Maleinsäureanhydrid |
| JP4009700B2 (ja) * | 2003-10-20 | 2007-11-21 | 株式会社テクノネットワーク四国 | ラジカル重合体の製造方法 |
| EP3137040B1 (en) | 2014-04-30 | 2022-08-24 | Colgate-Palmolive Company | Oral care composition containing silica and zinc citrate |
| MX359754B (es) | 2014-06-20 | 2018-10-01 | Colgate Palmolive Co | Composiciones orales que contienen fuentes de ion de zinc, estaño y fluoruro. |
| MX2018005912A (es) | 2015-11-13 | 2019-04-04 | Procter & Gamble | Composiciones dentifricas con beneficios antisarro y antibacterianos. |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57158214A (en) * | 1981-03-04 | 1982-09-30 | Basf Ag | Manufacture of copolymer of maleic acid anhydride |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2782182A (en) * | 1951-10-30 | 1957-02-19 | Gen Aniline & Film Corp | Process for interpolymerization of maleic anhydride with vinyl alkyl ethers |
| GB906230A (en) * | 1960-03-14 | 1962-09-19 | Gen Aniline & Film Corp | Stabilized vinyl alkyl ether-maleic anhydride interpolymer composition |
| BE634099A (US06534493-20030318-C00166.png) * | 1962-06-25 | |||
| DE1299119B (de) * | 1963-07-03 | 1969-07-10 | Basf Ag | Verfahren zur Herstellung von feinteiligen Maleinsaeureanhydridmischpolymerisaten |
| GB1117515A (en) * | 1966-07-08 | 1968-06-19 | Ici Ltd | Maleic anhydride/alkyl vinyl ether copolymer |
| US3532771A (en) * | 1967-03-08 | 1970-10-06 | Gaf Corp | Process of preparing powdery copolymers of vinyl ethers and maleic anhydride using polymeric anti-clumping additives derived from vinyl alkoxyalkyl ethers |
| US3530102A (en) * | 1968-05-16 | 1970-09-22 | Union Carbide Corp | Terpolymers of maleic anhydride,vinyl alkyl ether and divinylbenzene and process for production thereof |
| US3553183A (en) * | 1969-03-27 | 1971-01-05 | Gaf Corp | Interpolymeric anti-clumping additives |
| DE3042471A1 (de) * | 1980-11-11 | 1982-06-16 | Bayer Ag, 5090 Leverkusen | Maleinsaeureanhydridcopolymerisate und ihre herstellung |
| CA1183994A (en) * | 1981-06-29 | 1985-03-12 | Earl P. Williams | Water swellable polymers |
-
1987
- 1987-04-10 DE DE19873712265 patent/DE3712265A1/de active Granted
-
1988
- 1988-02-13 EP EP88102141A patent/EP0289713B1/de not_active Expired - Lifetime
- 1988-02-13 ES ES198888102141T patent/ES2041709T3/es not_active Expired - Lifetime
- 1988-02-13 AT AT88102141T patent/ATE89294T1/de active
- 1988-02-13 DE DE8888102141T patent/DE3880883D1/de not_active Expired - Fee Related
- 1988-04-08 JP JP63085538A patent/JPS6414222A/ja active Granted
-
1989
- 1989-07-14 US US07/382,064 patent/US5047490A/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57158214A (en) * | 1981-03-04 | 1982-09-30 | Basf Ag | Manufacture of copolymer of maleic acid anhydride |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0289713B1 (de) | 1993-05-12 |
| EP0289713A3 (en) | 1990-03-21 |
| ES2041709T3 (es) | 1993-12-01 |
| DE3880883D1 (de) | 1993-06-17 |
| EP0289713A2 (de) | 1988-11-09 |
| DE3712265A1 (de) | 1988-10-20 |
| DE3712265C2 (US06534493-20030318-C00166.png) | 1989-02-16 |
| ATE89294T1 (de) | 1993-05-15 |
| US5047490A (en) | 1991-09-10 |
| JPS6414222A (en) | 1989-01-18 |
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