JPH0570678B2 - - Google Patents

Info

Publication number
JPH0570678B2
JPH0570678B2 JP60127303A JP12730385A JPH0570678B2 JP H0570678 B2 JPH0570678 B2 JP H0570678B2 JP 60127303 A JP60127303 A JP 60127303A JP 12730385 A JP12730385 A JP 12730385A JP H0570678 B2 JPH0570678 B2 JP H0570678B2
Authority
JP
Japan
Prior art keywords
zsm
catalyst
zeolite
cracking
zeolites
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP60127303A
Other languages
English (en)
Japanese (ja)
Other versions
JPS6112788A (ja
Inventor
Maikeru Pasukaru Geirii
Chuu Hoochen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24485330&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=JPH0570678(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of JPS6112788A publication Critical patent/JPS6112788A/ja
Publication of JPH0570678B2 publication Critical patent/JPH0570678B2/ja
Granted legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44Noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/26After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/36Steaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
JP60127303A 1984-06-13 1985-06-13 接触クラツキング方法 Granted JPS6112788A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US620283 1984-06-13
US06/620,283 US4522705A (en) 1984-06-13 1984-06-13 Octane enhancement and total liquid product yield improvements in catalytic cracking using in-situ crystallized ZSM-5 clay aggregates

Publications (2)

Publication Number Publication Date
JPS6112788A JPS6112788A (ja) 1986-01-21
JPH0570678B2 true JPH0570678B2 (en, 2012) 1993-10-05

Family

ID=24485330

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60127303A Granted JPS6112788A (ja) 1984-06-13 1985-06-13 接触クラツキング方法

Country Status (10)

Country Link
US (1) US4522705A (en, 2012)
EP (1) EP0165011B1 (en, 2012)
JP (1) JPS6112788A (en, 2012)
AU (1) AU567815B2 (en, 2012)
BR (1) BR8502801A (en, 2012)
CA (1) CA1248482A (en, 2012)
DE (1) DE3585850D1 (en, 2012)
ES (1) ES8605566A1 (en, 2012)
IN (1) IN165192B (en, 2012)
ZA (1) ZA854097B (en, 2012)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4828679A (en) * 1984-03-12 1989-05-09 Mobil Oil Corporation Octane improvement with large size ZSM-5 catalytic cracking
DE3687592T2 (de) * 1985-05-14 1993-05-19 Mobil Oil Corp Verfahren zur synthese von zeolithen.
US5063038A (en) * 1985-10-21 1991-11-05 Mobil Oil Corp. Zeolite synthesis using an alcohol or like molecule
AU605503B2 (en) * 1986-09-03 1991-01-17 Mobil Oil Corporation FCC naphtha in a single riser fluid catalytic cracking operation employing a catalyst mixture.
US5051164A (en) * 1987-09-04 1991-09-24 Mobil Oil Corporation Crystalline porous silicate composite and its use in catalytic cracking
GB8820358D0 (en) * 1988-08-26 1988-09-28 Shell Int Research Process for catalytic cracking of hydrocarbon feedstock
US4962074A (en) * 1989-06-02 1990-10-09 Mobil Oil Corporation Catalytic cracking of hydrocarbons with oxygen promoted alkali metal zeolite cracking catalyst
GB9101456D0 (en) * 1991-01-23 1991-03-06 Exxon Chemical Patents Inc Process for producing substantially binder-free zeolite
FR2673123B1 (fr) * 1991-02-21 1993-05-14 Inst Francais Du Petrole Catalyseur de craquage de charges hydrocarbones comprenant une zeolithe mtw, une zeolithe et une matrice.
US5302567A (en) * 1991-11-04 1994-04-12 W. R. Grace & Co.-Conn. Zeolite octane additive
US5254322A (en) * 1992-08-10 1993-10-19 Mobil Oil Corporation Method for reducing automotive NOx emissions in lean burn internal combustion engine exhaust using a transition metal-containing zeolite catalyst which is in-situ crystallized
US5308475A (en) * 1992-11-23 1994-05-03 Mobil Oil Corporation Use of ZSM-12 in catalytic cracking for gasoline octane improvement and co-production of light olefins
EP0674600B1 (en) * 1992-12-16 2001-10-17 Chevron U.S.A. Inc. Preparation of aluminosilicate zeolites
US5552129A (en) * 1994-07-07 1996-09-03 Mobil Oil Corporation Catalytic system for the reduction of nitrogen oxides
ES2137566T3 (es) * 1994-11-23 1999-12-16 Exxon Chemical Patents Inc Procedimiento de conversion de hidrocarburos que emplea un catalizador de zeolita unido a zeolita.
BR9709398A (pt) 1996-05-29 1999-08-10 Exxon Chemical Patents Inc Catalisador zeólito e seu uso em conversão de hidrocarboneto
JP2000044969A (ja) * 1998-07-27 2000-02-15 Tonen Corp 無鉛高オクタン価ガソリン組成物
US6261534B1 (en) 1999-11-24 2001-07-17 Chevron U.S.A. Inc. Method for making ZSM-5 zeolites
US6632415B2 (en) 2001-04-09 2003-10-14 Chevron U.S.A. Inc. Methods for making molecular sieves
US6908603B2 (en) * 2003-06-02 2005-06-21 Engelhard Corporation In-situ ZSM-5 synthesis
US20050063901A1 (en) * 2003-09-24 2005-03-24 Miller Stephen J. Preparation of molecular sieves involving spray drying
CN100450617C (zh) * 2005-10-18 2009-01-14 中国石油天然气股份有限公司 一种高岭土基复合分子筛及其制备方法
CN101797515B (zh) * 2009-02-06 2011-12-07 中国石油天然气股份有限公司 一种zsm-5沸石/粘土复合催化材料的无胺制备方法
CN102989500B (zh) * 2011-09-14 2015-01-21 中国石油天然气股份有限公司 一种催化裂化助催化剂的制备方法
WO2013123297A2 (en) 2012-02-17 2013-08-22 Kior, Inc. Catalyst composition with increased bulk active site accessibility for the catalytic thermoconversion of biomass to liquid fuels and chemicals and for upgrading bio-oils
EP3135373A1 (en) 2015-08-24 2017-03-01 INDIAN OIL CORPORATION Ltd. Preparation and composition of a fluid catalytic cracking catalyst additive with lower phosphate content for enhanced lpg yield
US10413889B2 (en) 2015-11-24 2019-09-17 Indian Oil Corporation Limited Composition and process for preparation of cracking catalyst suitable for enhancing yields of light olefins
US20240299916A1 (en) * 2023-03-10 2024-09-12 Saudi Arabian Oil Company Processes and bimetallic cracking additives for steam enhanced catalytic cracking of crude oil to produce light olefins and aromatics

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7018223A (en, 2012) * 1969-12-18 1971-06-22
US3758402A (en) * 1970-10-06 1973-09-11 Mobil Oil Corp Catalytic hydrocracking of hydrocarbons
US3758403A (en) * 1970-10-06 1973-09-11 Mobil Oil Olites catalytic cracking of hydrocarbons with mixture of zsm-5 and other ze
US4091007A (en) * 1972-12-01 1978-05-23 Mobil Oil Corporation Preparation of zeolites
US3894934A (en) * 1972-12-19 1975-07-15 Mobil Oil Corp Conversion of hydrocarbons with mixture of small and large pore crystalline zeolite catalyst compositions to accomplish cracking cyclization, and alkylation reactions
JPS5437162A (en) * 1977-08-30 1979-03-19 Mitsubishi Chem Ind Ltd Production of uniform slurry of mineral fibers
US4235753A (en) * 1979-03-16 1980-11-25 Engelhard Minerals & Chemicals Corporation Zeolitized composite bodies and manufacture thereof
US4289606A (en) * 1979-05-31 1981-09-15 Exxon Research & Engineering Co. Hydrocarbon cracking with mixture of zeolites Y and ZSM-5
US4242237A (en) * 1979-05-31 1980-12-30 Exxon Research & Engineering Co. Hydrocarbon cracking catalyst and process utilizing the same
ZA803517B (en) * 1979-06-21 1981-06-24 Mobil Oil Corp Octane improvement in catalytic cracking
US4309279A (en) * 1979-06-21 1982-01-05 Mobil Oil Corporation Octane and total yield improvement in catalytic cracking

Also Published As

Publication number Publication date
BR8502801A (pt) 1986-02-18
ES544087A0 (es) 1986-03-16
DE3585850D1 (de) 1992-05-21
EP0165011B1 (en) 1992-04-15
US4522705A (en) 1985-06-11
EP0165011A2 (en) 1985-12-18
AU4314985A (en) 1985-12-19
AU567815B2 (en) 1987-12-03
EP0165011A3 (en) 1987-12-23
ES8605566A1 (es) 1986-03-16
IN165192B (en, 2012) 1989-08-26
JPS6112788A (ja) 1986-01-21
ZA854097B (en) 1987-01-28
CA1248482A (en) 1989-01-10

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