JPH0567358B2 - - Google Patents

Info

Publication number
JPH0567358B2
JPH0567358B2 JP13004789A JP13004789A JPH0567358B2 JP H0567358 B2 JPH0567358 B2 JP H0567358B2 JP 13004789 A JP13004789 A JP 13004789A JP 13004789 A JP13004789 A JP 13004789A JP H0567358 B2 JPH0567358 B2 JP H0567358B2
Authority
JP
Japan
Prior art keywords
sludge
methane fermentation
fermentation treatment
trace elements
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP13004789A
Other languages
Japanese (ja)
Other versions
JPH03199A (en
Inventor
Yutaka Yoneyama
Minoru Furuta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ebara Corp
Ebara Research Co Ltd
Original Assignee
Ebara Research Co Ltd
Ebara Infilco Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ebara Research Co Ltd, Ebara Infilco Co Ltd filed Critical Ebara Research Co Ltd
Priority to JP1130047A priority Critical patent/JPH03199A/en
Publication of JPH03199A publication Critical patent/JPH03199A/en
Publication of JPH0567358B2 publication Critical patent/JPH0567358B2/ja
Granted legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Landscapes

  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Treatment Of Sludge (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

〔産業上の利用分野〕 本発明は、食品工業、紙パルプ工業、化学工業
等から排出される有機性廃水のメタン発酵処理に
関するものであり、また有機性汚泥の蒸発乾燥で
生ずる凝縮水のメタン発酵処理に関するものであ
る。 〔従来の技術〕 有機性廃水の処理方法の一つとしてメタン発酵
処理方法があり、この方法はメタン菌を作用させ
て廃水中の有機物質を分解して主としてメタンと
することにより、有機物質の量を減少させて廃水
を浄化するものであるが、メタン菌が増殖してそ
の作用を活発に行わせるには、窒素、燐の他に微
量のFe、Ni、Na、K、Ca、Mg等の無機元素
(これらの元素をこの明細書では「微量元素」と
いう)が必要であると言われている〔エツチ、ヘ
ンツら;固定式膜型反応器における廃水の嫌気性
処理−報文展望;「ウオータ・サイエンス・アン
ド・テクノロジイ」第15巻8/9号、1983年第20
頁(H.Henze et al:Anaerobic treatment of
waste water in fixed film reactors−a
literature review;Water Science and
Technology、Volume 15.Number8/9、1983.
p.20)〕。 食品工業、紙パルプ工業、化学工業等において
排出される有機性廃水の中に、Fe、Ni、Na、
K、Ca、Mg等の無機元素を含まないものがあ
り、このような有機性廃水についてメタン発酵処
理をしようとすると、前記の理由でメタン発酵が
十分に進行せず、処理が行われない。 そこで、このような有機性廃水に微量元素を添
加することが行われ、それは化合物、特に塩の形
で添加されていた。 また、有機性汚泥又は有機性汚泥の脱水ケーキ
などの加熱脱水のさいには、水分が減少した後で
もポンプ操作にかけ得る状態に保たれるように、
前記汚泥などに油を混合して流動しうる混合物と
し、該混合物を加熱して蒸発乾燥する方法が行わ
れているが、その方法における、その蒸発乾燥の
工程で発生する蒸気を凝縮して得た凝縮水も、
Fe、Ni、Na、K、Ca、Mg等の微量元素を含ま
ないため、それをメタン発酵処理をするのには必
要な微量元素の化合物、特に塩を添加することが
必要とされていた。 〔発明が解決しようとする課題〕 上記のように、有機性廃水に微量元素を化合物
の形で添加するためには、有機性廃水に均一に分
散させる必要から、その化合物を溶解して溶液を
調製し、その溶液を貯留し、有機性廃水にその処
理量に比例した量で添加しなければならないか
ら、それに必要な溶解槽、液貯槽、計量装置を設
けなければならなかつた。また、添加するための
微量元素の化合物を購入しなければならず、前記
の附属装置の装置費とともに処理コストを高くす
る要因となつている。 本発明は、前記の微量元素の化合物の添加を特
にしないで有機性廃水等のメタン発酵処理を行う
ことができるメタン発酵処理方法を提供すること
を目的とするものである。 〔課題を解決するための手段〕 本発明は、微量元素を含まない有機性廃水のメ
タン発酵処理方法において、該微量元素を含まな
い有機性廃水に初沈汚泥、活性汚泥、凝沈汚泥、
あるいはこれらの脱水ケーキよりなる微量元素を
含有する汚泥を添加してメタン発酵処理をするこ
とを特徴とするメタン発酵処理方法によつて、上
記の目的を達成した。 また、本発明は、有機性汚泥又は有機性汚泥の
脱水ケーキに油を混合して流動しうる混合物と
し、該混合物を加熱して蒸発乾燥する方法におけ
る、その蒸発乾燥の工程で発生する蒸気を凝縮し
て得た凝縮水に、初沈汚泥、活性汚泥、凝沈汚
泥、あるいはこれらの脱水ケーキよりなる微量元
素を含有する汚泥を添加してメタン発酵処理をす
ることを特徴とするメタン発酵処理方法によつ
て、前記凝縮水の処理について上記の目的を達成
した。 すなわち、本発明は、微量元素の化合物の代わ
りに、このメタン発酵系以外の系からの微量元素
を含有する汚泥を添加するものである。 本発明で処理しようとする有機性廃水は微量元
素を含まないものであり、また処理しようとする
前記凝縮水は、その水質分析結果の一例を示した
第1表に見られるように、アンモニア性窒素を多
量に含むが、燐及び他のメタン発酵処理に必要な
微量元素はほとんど含まれていない。
[Industrial Application Field] The present invention relates to methane fermentation treatment of organic wastewater discharged from the food industry, pulp and paper industry, chemical industry, etc., and also relates to methane fermentation treatment of condensed water produced by evaporation drying of organic sludge. It is related to fermentation processing. [Prior art] One of the methods for treating organic wastewater is the methane fermentation treatment method. This method uses methane bacteria to decompose organic substances in wastewater to mainly produce methane, thereby decomposing organic substances. This method purifies wastewater by reducing the amount of methane, but in order for methane bacteria to proliferate and actively carry out its action, in addition to nitrogen and phosphorus, trace amounts of Fe, Ni, Na, K, Ca, Mg, etc. are required. It is said that inorganic elements (these elements are referred to as "trace elements" in this specification) are necessary [Etsch, Hentz et al.; Anaerobic treatment of wastewater in a fixed membrane reactor - Report Perspective; "Water Science and Technology" Vol. 15, No. 8/9, 1983 No. 20
Page (H. Henze et al: Anaerobic treatment of
waste water in fixed film reactors−a
literature review;Water Science and
Technology, Volume 15. Number 8/9, 1983.
p.20)] Fe, Ni, Na,
Some organic wastewaters do not contain inorganic elements such as K, Ca, and Mg, and when attempting to perform methane fermentation treatment on such organic wastewater, the methane fermentation does not proceed sufficiently for the reasons mentioned above, and the treatment is not carried out. Therefore, it has been practiced to add trace elements to such organic wastewaters, which have been added in the form of compounds, especially salts. In addition, when heating and dewatering organic sludge or a dehydrated cake of organic sludge, it is necessary to keep it in a state where it can be pumped even after the water content has decreased.
A method has been used in which oil is mixed with the sludge to form a fluid mixture, and the mixture is heated and evaporated to dryness. The condensed water also
Since it does not contain trace elements such as Fe, Ni, Na, K, Ca, Mg, etc., it has been necessary to add necessary trace element compounds, especially salt, to perform methane fermentation treatment. [Problems to be Solved by the Invention] As mentioned above, in order to add trace elements in the form of compounds to organic wastewater, it is necessary to uniformly disperse them in the organic wastewater, so the compound must be dissolved to form a solution. Since the solution must be prepared, stored, and added to organic wastewater in an amount proportional to the amount to be treated, it was necessary to provide the necessary dissolution tank, liquid storage tank, and metering device. Furthermore, it is necessary to purchase a trace element compound for addition, which is a factor that increases the processing cost as well as the equipment cost of the above-mentioned auxiliary equipment. An object of the present invention is to provide a methane fermentation treatment method that can perform methane fermentation treatment on organic wastewater, etc., without the addition of any of the above-mentioned trace element compounds. [Means for Solving the Problems] The present invention provides a methane fermentation treatment method for organic wastewater that does not contain trace elements, in which the organic wastewater that does not contain trace elements is treated with primary sludge, activated sludge, coagulated sludge,
Alternatively, the above object was achieved by a methane fermentation treatment method characterized in that sludge containing trace elements made of these dehydrated cakes is added for methane fermentation treatment. The present invention also provides a method for mixing oil with organic sludge or a dehydrated cake of organic sludge to form a fluid mixture, and heating the mixture to evaporate and dry the mixture, in which steam generated in the evaporative drying step is removed. A methane fermentation process characterized by adding sludge containing trace elements such as initial settling sludge, activated sludge, flocculated sludge, or a dehydrated cake of these to the condensed water obtained by condensation to perform methane fermentation treatment. The method achieved the above objectives for the treatment of the condensate. That is, in the present invention, instead of trace element compounds, sludge containing trace elements from a system other than the methane fermentation system is added. The organic wastewater to be treated in the present invention does not contain trace elements, and the condensed water to be treated is ammoniacal, as shown in Table 1 showing an example of the water quality analysis results. Although it contains large amounts of nitrogen, it contains little phosphorus and other trace elements necessary for methane fermentation processing.

【表】 本発明において、これらの有機性廃水などへの
添加に用いる汚泥としては、下水の初沈汚泥、活
性汚泥法における活性汚泥(余剰汚泥)、凝沈汚
泥(「凝集沈殿汚泥」をいう)が挙げられ、これ
らは脱水されて脱水ケーキとなつたものでもよ
い。第2表に都市下水を対象とした活性汚泥処理
における余剰汚泥の金属含有率の一例を示す。
[Table] In the present invention, the sludge used for addition to organic wastewater, etc. includes initial settling sludge of sewage, activated sludge (excess sludge) in the activated sludge method, and coagulated sludge (referring to "coagulated and settled sludge"). ), and these may be dehydrated to form a dehydrated cake. Table 2 shows an example of the metal content of surplus sludge in activated sludge treatment for urban sewage.

〔作用〕[Effect]

微量元素を含有しない有機性廃水及び前記凝縮
水は、メタン発酵処理をしたさいメタン発酵に必
要な微量元素を含有しないために、その発酵処理
が十分に進行しないが、それらに前記した汚泥を
添加すると、この汚泥中に含有される金属元素に
よつて添加された有機性廃水等は微量元素を含有
するものとなり、またメタン発酵の栄養素となる
有機物が混入しているので促進され、メタン発酵
処理を十分に行うことができる。 〔実施例〕 以下、実施例によつて本発明を具体的に示す。
ただし、本発明はこれらの実施例に限定されるも
のではない。 実施例 1 有機性廃水として食品工場の生産工程から排出
される凝縮水を取り上げ、これについてメタン発
酵処理をした実験例を示す。 メタン発酵処理方法としてはUASB法を用い
た。UASB法(Upflow Amaerobic Sludge
Blanket Processの略;上向流嫌気性汚泥床法)
は、メタン発酵微生物群によつて構成された粒状
化凝集体(グラニユール)からなる汚泥のブラン
ケツト型メタン発酵槽を用いるものであつて、高
密度の微生物ペレツトの存在下で処理するため
に、従来のメタン発酵処理法に比べて高負荷処理
が可能な方法である。 第1図はその実験装置を示す。実容積2の
UASB槽7にグラニユール汚泥8を入れ、これ
を恒温槽9内に置き、35℃±2℃で温度制御を行
つた。 第3表に処理すべき凝縮水の水質を示す。前記
凝縮水に含まれる有機物の主体は、酢酸、プロピ
オン酸、エタノール等である。
When organic wastewater and the condensed water that do not contain trace elements are subjected to methane fermentation treatment, the fermentation treatment does not proceed sufficiently because they do not contain the trace elements necessary for methane fermentation, but the above-mentioned sludge is added to them. Then, the organic wastewater added by the metal elements contained in this sludge contains trace elements, and is also mixed with organic matter that serves as nutrients for methane fermentation, which accelerates the methane fermentation process. can be carried out satisfactorily. [Example] Hereinafter, the present invention will be specifically illustrated by examples.
However, the present invention is not limited to these examples. Example 1 An experimental example will be shown in which condensed water discharged from the production process of a food factory as organic wastewater was taken up and subjected to methane fermentation treatment. The UASB method was used as the methane fermentation treatment method. UASB method (Upflow Amaerobic Sludge
Abbreviation for Blanket Process; upflow anaerobic sludge bed method)
This method uses a blanket-type methane fermentation tank for sludge consisting of granulated aggregates (granules) composed of methane-fermenting microorganisms. This method allows for higher load processing compared to the methane fermentation processing method. Figure 1 shows the experimental setup. Actual volume 2
Granule sludge 8 was placed in a UASB tank 7, placed in a constant temperature bath 9, and the temperature was controlled at 35°C±2°C. Table 3 shows the quality of condensed water to be treated. The organic substances contained in the condensed water are mainly acetic acid, propionic acid, ethanol, etc.

【表】 前記凝縮水1を原水貯槽4に入れ、それにリン
酸2をBCD:P≒100:1になるように添加し、
さらに汚泥3を添加した。添加する汚泥は、A系
列(活性汚泥の余剰汚泥)、B系列(初沈汚泥)、
C系列(凝沈汚泥)の3種類を用い、それぞれに
ついて実験を行つた。なお、汚泥の添加率は第4
表に示す。 原水貯槽4から汚泥が添加された前記凝縮水5
を原水ポンプ6より吸引し、UASB槽7の底部
に送り、グラニユール汚泥8の存在下でメタン発
酵処理を行う。処理が終つた水はUASB槽7の
上部から処理水11として取り出す。処理にさい
して発生した、主としてメタンからなるガス12
はUASB槽7の上部に設けたガス室10に貯め
られ、該室からガスメーター13を経て取り出さ
れる。 比較のため、汚泥を添加せず、無機薬品を添加
してメタン発酵処理を行つた。これをD系列とす
る。 これらの実験による実験結果を次の第4表に示
す。
[Table] Put the condensed water 1 into the raw water storage tank 4, add phosphoric acid 2 to it so that BCD:P≒100:1,
Furthermore, sludge 3 was added. The sludge to be added is A series (excess sludge of activated sludge), B series (primary settling sludge),
Experiments were conducted using three types of C series (settled sludge). In addition, the addition rate of sludge is the fourth
Shown in the table. The condensed water 5 to which sludge has been added from the raw water storage tank 4
is sucked by the raw water pump 6, sent to the bottom of the UASB tank 7, and subjected to methane fermentation treatment in the presence of the granule sludge 8. The treated water is taken out from the upper part of the UASB tank 7 as treated water 11. Gas mainly composed of methane generated during processing 12
is stored in a gas chamber 10 provided at the top of the UASB tank 7, and taken out from the chamber via a gas meter 13. For comparison, methane fermentation treatment was performed without adding sludge, but with the addition of inorganic chemicals. This is called the D series. The experimental results from these experiments are shown in Table 4 below.

【表】 〓
[Table] 〓

Claims (1)

【特許請求の範囲】 1 微量元素を含まない有機性廃水のメタン発酵
処理方法において、該微量元素を含まない有機性
廃水に初沈汚泥、活性汚泥、凝沈汚泥、あるいは
これらの脱水ケーキよりなる微量元素を含有する
汚泥を添加してメタン発酵処理をすることを特徴
とするメタン発酵処理方法。 2 有機性汚泥又は有機性汚泥の脱水ケーキに油
を混合して流動しうる混合物とし、該混合物を加
熱して蒸発乾燥する方法における、その蒸発乾燥
の工程で発生する蒸気を凝縮して得た凝縮水に、
初沈汚泥、活性汚泥、凝沈汚泥、あるいはこれら
の脱水ケーキよりなる微量元素を含有する汚泥を
添加してメタン発酵処理をすることを特徴とする
メタン発酵処理方法。
[Claims] 1. A method for methane fermentation treatment of organic wastewater that does not contain trace elements, wherein the organic wastewater that does not contain trace elements is made of primary sludge, activated sludge, flocculated sludge, or a dehydrated cake thereof. A methane fermentation treatment method characterized by performing methane fermentation treatment by adding sludge containing trace elements. 2 A method in which oil is mixed with organic sludge or a dehydrated cake of organic sludge to form a fluid mixture, and the mixture is heated and evaporated to dryness, obtained by condensing the vapor generated in the evaporation drying process. In the condensed water,
A methane fermentation treatment method comprising adding sludge containing trace elements such as initial settling sludge, activated sludge, flocculated sludge, or a dehydrated cake of these to perform methane fermentation treatment.
JP1130047A 1989-05-25 1989-05-25 Methane fermentation treatment Granted JPH03199A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1130047A JPH03199A (en) 1989-05-25 1989-05-25 Methane fermentation treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1130047A JPH03199A (en) 1989-05-25 1989-05-25 Methane fermentation treatment

Publications (2)

Publication Number Publication Date
JPH03199A JPH03199A (en) 1991-01-07
JPH0567358B2 true JPH0567358B2 (en) 1993-09-24

Family

ID=15024801

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1130047A Granted JPH03199A (en) 1989-05-25 1989-05-25 Methane fermentation treatment

Country Status (1)

Country Link
JP (1) JPH03199A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0274137B1 (en) * 1987-01-07 1993-07-21 Yamaha Corporation Tone signal generation device having a tone sampling function
US6855254B1 (en) * 2003-12-19 2005-02-15 Shalom Recycling Inc. Magerle metal waste recovery process
SE529177E (en) 2005-12-01 2012-12-21 Tekniska Verken Linkoeping Ab Use of an additive for digestion of organic matter

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57136995A (en) * 1981-02-19 1982-08-24 Kurita Water Ind Ltd Treatment of waste water
JPS5845796A (en) * 1981-09-16 1983-03-17 Nishihara Environ Sanit Res Corp Anaerobic digestion of highly-concentrated organic waste water
JPS59392A (en) * 1982-06-25 1984-01-05 Ebara Infilco Co Ltd Treatment of organic waste liquor
JPS59395A (en) * 1982-06-24 1984-01-05 Ebara Infilco Co Ltd Treatment of organic waste liquor containing ammonia nitrogen
JPS605293A (en) * 1983-06-24 1985-01-11 Nippon Kokan Kk <Nkk> Two-phase anaerobic digestion treatment of organic waste liquid
JPS63252958A (en) * 1987-04-10 1988-10-20 Nippon Telegr & Teleph Corp <Ntt> Production of ceramics

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57136995A (en) * 1981-02-19 1982-08-24 Kurita Water Ind Ltd Treatment of waste water
JPS5845796A (en) * 1981-09-16 1983-03-17 Nishihara Environ Sanit Res Corp Anaerobic digestion of highly-concentrated organic waste water
JPS59395A (en) * 1982-06-24 1984-01-05 Ebara Infilco Co Ltd Treatment of organic waste liquor containing ammonia nitrogen
JPS59392A (en) * 1982-06-25 1984-01-05 Ebara Infilco Co Ltd Treatment of organic waste liquor
JPS605293A (en) * 1983-06-24 1985-01-11 Nippon Kokan Kk <Nkk> Two-phase anaerobic digestion treatment of organic waste liquid
JPS63252958A (en) * 1987-04-10 1988-10-20 Nippon Telegr & Teleph Corp <Ntt> Production of ceramics

Also Published As

Publication number Publication date
JPH03199A (en) 1991-01-07

Similar Documents

Publication Publication Date Title
US4666605A (en) Methane fermentation process for treating evaporator condensate from pulp making system
US20020030012A1 (en) Comprehensive waste treatment system and related methods for animal feeding operations to effectively recover waste solids for beneficial re-use and for treatment of wastewater for nutrient removal and recycle, re-use or discharge
JP4512823B2 (en) Organic waste treatment method and treatment system
CN102976543A (en) Garbage leachate disposal method and system
CN203173935U (en) Rubbish leach liquor processing system
JPH0567358B2 (en)
CN202449962U (en) System for treating high-salinity wastewater from chemical industry
JPH0114836B2 (en)
JPH0135720B2 (en)
JPH09290249A (en) Treatment of organic waste liquid
JP3797114B2 (en) How to remove nitrogen or phosphorus in wastewater
JPH0114832B2 (en)
JPH0114833B2 (en)
JP2002079298A (en) Method and apparatus for methane fermentation treatment of organic waste
JPS6366593B2 (en)
RU2767075C1 (en) Method of recycling liquid fraction of livestock effluents
JPS5919598A (en) Treatment of organic liquid waste
JPH0135719B2 (en)
JPH0114835B2 (en)
JPS63175700A (en) Treatment of sludge
JPS63214389A (en) Treatment of organic sewage
JPH0114839B2 (en)
JP2003039100A (en) Solid-liquid separation method for solid-liquid mixture and apparatus therefor
JPS5898198A (en) Treatment of sewage sludge
JP2000153296A (en) Sewage treating method and device therefor

Legal Events

Date Code Title Description
LAPS Cancellation because of no payment of annual fees