JPH05506873A - cleansing products - Google Patents

Abstract

(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

[Detailed description of the invention] Products made by Rinjin Technical field FIELD OF THE INVENTION The present invention relates to cleansing products. In particular, the invention relates to skin and/or are suitable for cleaning hair and can be used, for example, in make-up removal cleansers and detergents. May be used in the form of facial cleansers, foam baths, shower products, shampoos, etc. Regarding foam-produced personal cleansing products Ru. The cleansing product is also suitable for other applications requiring stable foam generation .

In addition, according to Invention 1, the product contains functional ingredients such as antibacterial agents and exhibits improved efficacy. Regarding cleansing products.

Background technique Foaming cosmetic compositions have cleansing power, foaming properties and the mucous membranes of the skin, hair and eyes. A number of criteria must be met, including mildness/low irritation.

The skin is covered with keratin and collagen fibrous proteins that form the structural skeleton. Consists of several layers of cells that cover and protect. The outermost of these layers, called the stratum corneum, is It is well known to consist of 250 protein bundles surrounded by a thick layer of 80 be. Anionic surfactants penetrate the stratum corneum membrane and delipidate (i.e., delipidate from the stratum corneum). (removal of lipids) may disrupt integrity. skin surface topography - This destruction results in a rough feel and eventually causes the surfactant to interact with the keratin. May cause irritation when used.

The ideal cosmetic cleanser gently cleanses the skin or hair without degreasing and and/or does not dry out the skin and leave the skin taut after frequent use. Little or no stimulation should be given. most liquid and solid foaming soaps fail in this regard.

These synthetic surfactants are known to be mild. However, the skin The main deficiency of most mild synthetic surfactant systems when formulated for cleansing. Highest bar standard (coconut soap rich and superfatted bar) Poor foam performance compared to On the other hand, known highly foaming anionic surfactants and foam Combination with build-up enhancers can produce acceptable lather volume and quality. death Unfortunately, however, the best foaming anionic surfactants are actually Poor skin mildness. Surfactants among the mildest, e.g. , Sodium lauryl glyceryl ether sulfonate (AGS) has limited foam. It is. These two facts allow surfactant selection, lather and skin feel benefits to be obtained. make the prescription process a delicate balancing act.

The rather stringent requirements of cosmetic cleansers limit the choice of surfactants and the final formulation. represents some degree of compromise.

Mildness is often obtained at the expense of effectiveness or ranges, or foaming. may be sacrificed for either mildness, product stability, or both. be.

Thus, it is possible to produce foam that is abundant, stable, and of high quality. It is an effective skin and hair cleanser and is effective for skin, hair and eyes. There is a need for cleansing products that are very mild to the mucous membranes of the skin.

Aqueous skin cleansing compositions are treated with so-called "non-pressurized" aerated compositions. ) for use in foaming detergent products as disclosed in U.S. Pat. No. 3,962,150. It is shown.

However, it has excellent mildness, product stability and a full range of use and temperature conditions. Provides excellent foam stability and creaminess with ease of use properties across the range There is a need for a foaming cleaning product that would. It also has improved antibacterial performance. There is a need for personal cleansing products that will provide.

Demonstration of invention The gist of the invention is a method suitable for personal cleansing of skin or hair and - Cap remover and facial cleansers, foam bath and shower products, It is a foaming cleansing product that can be used as a shampoo. The product is reservoir, dispensing head, liquid/air mixing device and Preferably a compressible non-aerosol dispersion with a homogenizer and a check valve device. Consisting of pencers.

In one aspect of the invention, the reservoir includes: (a) Formula I (wherein R1 is C7-C22 alkyl or alkenyl, R is hydrogen or C'H2Z tomorrow, each 2 independently C02M or CH2C02M, M is H1 alkali metal, alkaline earth metal, ammonium or alkanol ammonium) and/or an imidazolinium derivative of the formula (wherein R%R and Z are defined above) according to righteousness) 0.1 to about 16% by weight of an amphoteric surfactant selected from ammonium derivatives of ; (b) Formula ■ RNH(CH2). Co2M II ] Aminoalkanoate, formula ■ Iminodialkanoates of RN[(CH2)IIC02M]2m and the like (where n and m are numbers from 1 to 4, and R1 and M are independently the mixture of ( , selected from the groups specified in a)) about 0.1 to about 16% by weight of a second amphoteric surfactant selected from; (c) an aqueous cleansing agent optionally containing up to about 10% anionic surfactant; Compositions (cleansing compositions having a total surfactant concentration of 0.2% to about 20% by weight) And the total concentration of the first amphoteric surfactant and the second amphoteric surfactant is the total surfactant concentration. (accounting for at least 20% by weight).

All concentrations and ratios herein refer to the weight of the cleansing composition, unless otherwise specified. It is based on quantity.

BEST MODE FOR CARRYING OUT THE INVENTION The present invention combines excellent mildness, stability, cleansing ability and germicidal performance. Foaming cream with excellent foaming properties (creaminess, richness, stability) related to packaging products. In one aspect of the invention, the cleansing product is , so-called "squeeze former" vessels - dispensing hesods and liquid/air mixing devices. Features of an amphoteric surfactant packaged in a compressible dispenser with a cleansing composition in the form of an aqueous liquid containing a mixture of The cleansing composition can be easily dispensed in the form of an aqueous foam by squeezing).

Essential and optional features of products of aspects of the invention are described below.

A preferred cleansing composition for use herein is a mixture of 2N amphoteric surfactants. wherein the first amphoteric surfactant is of formula I (wherein R1 is C7-C22 alkyl or alkenyl, R is hydrogen or CH2Z tomorrow, each Z independently C02M or CHCo2M, where M is H1 alkali metal, alkaline earth metal, ammonium or alkanol ammonium) and/or an imidazolinium surfactant of the formula ■ (wherein R1R2 and Z is as defined above) and the second amphoteric surfactant has the formula ■ RNH(CH2)nCo2M I1 Aminoalkanoate of formula m Iminodialkanoate of RN((CH2), Co2M)2 II1 and its (wherein n and m are numbers from 1 to 4, and R1 and M are independently (selected from the group)

Cleansing compositions for use herein include other, preferably mild, cleansing compositions. Surfactant components may also be included, particularly anionic surfactants. However, the first The total concentration of monoampholytic surfactant and second amphoteric surfactant is less than the total surfactant concentration. The composition is at least about 20% by weight, preferably at least about 50% by weight. , which is desirable from the point of view of achieving optimal foaming properties. preferred In the composition, the mixture of the first amphoteric surfactant and the second amphoteric surfactant is At least about 60% by weight of total surfactants, more preferably at least about 75% by weight %.

Suitable amphoteric surfactants of type No.-1 are commercially available under the trade name Miranol. It is understood that it is a complex mixture of species. CTFA cosmetics The Ingredient Dictionary, 3rd edition shows acyclic structures. Traditionally, milanols have been described as having the general formula I. In fact, the cyclic Complex mixtures of species and acyclic species are likely to exist, and one definition of both is complete. give here for.

Examples of suitable amphoteric surfactants for use as the primary amphoteric surfactant include R is 08H17 (especially isocabryl), CH and C1IH23 alkyl I and/or compounds of formula (■). R1 is CHZ, COM, R2 is E A certain compound; 19ゝゝ　2 and R is CH, Z is COM, and R2 is Particularly preferred are compounds that are CH2CO2M.

A number of commercially available amphoteric surfactants of this type have been produced and have anionic surfactants. agents, especially sulfated C-C18 alcohols, C8-C18 ethoxylated alcohols or is sold in the form of a complex with 08-C18 acylglyceride types. will be understood. Therefore, in one aspect of the invention, the composition , the first amphoteric surfactant and the anionic surfactant in an equivalence ratio of about 1=1 to give approximate electroneutrality. Contains premixes or complexes with on-surfactants.

Examples of amphoteric surfactants suitable for use as the second amphoteric surfactant include salts , especially triethanolammonium salt and N-lauryl-β-aminopropylene Salts of acid and N-lauryl-imino-dipropionic acid are mentioned.

The cleansing composition preferably comprises a first amphoteric surfactant and a second amphoteric surfactant. and about 0.5 to about 10% by weight, more preferably about 0.5 to about 4% by weight, respectively. do.

The weight ratio of first amphoteric surfactant:second amphoteric surfactant is preferably about 10:1 or less. from about 1=10, more preferably from about 5=1 to about 1:5, especially from about 3=1 to about 1= It is 3.

The composition of the present invention may contain surfactants other than the amphoteric surfactants, or or can be supplemented by them. However, the total amount of surfactant in the composition generally from about 0.2 to about 20% by weight, preferably from about 1 to about 16%, more preferably from about 1 to about 16% by weight. or preferably within the range of about 1 to about 8% by weight, especially about 2 to about 6% by weight. So They provide excellent foam stability and creaminess even in small amounts of cleansing surfactants. It is a feature of the product of the present invention that it can impart moisturizing properties.

Preferred optional surfactants in the composition are anionic surfactants. this is , preferably about 0.1 to 10% by weight, more preferably about 0.5 to 5% by weight, especially is present in an amount of about 1 to about 3% by weight. The above alkyl sulfates, ethoxylated Other than alkyl sulfates and acylglyceride sulfates, Preferred anionic surfactants are fatty acid condensates of amino acids or mixtures of such condensates. in a highly preferred embodiment In this case, the fatty acid condensate is (i) C=C preferably added with CLO-018 fatty acid 812゜ condensate with water-splitting protein, (11) C-C preferably derived from CLO-C18 fatty acid 822ゝ fatty acid sarcosinate, and (111) Mixtures thereof selected from.

Other suitable mild synthetic detergent surfactants for use in cleansing compositions include , methyl acyl taurate; fatty acyl glycinate; N-acyl glutamate ; Alkyl glucosides; Alkyl glycerides and ethoxylated glycerides: Lewisethionate; Alkyl sulfosuccinate; α-sulfonated fatty acid; salts and/or esters thereof; alkyl phosphate esters: ethoxylation Alkyl phosphate ester; alkyl ether sulfate; glucose ester and alkylation, e.g. methyl glucose ester: alkyl ether sal Mixture of phate and alkylamine oxide dibetaine cosultaine: and Mixtures thereof may be mentioned. Alkyl ethers with up to 12 ethoxy groups Rusulfates, especially ammonium lauryl ether sulfate and lauryl ether Surfactants include sodium sulfate. Alkyl of these surfactants and/or the acyl chain length is C-C, preferably C1o-018.

Suitable mild synthetic detergent surfactants of these types include 08-C18 mono Alkyl phosphates (preferably at least partially in the form of polyalkanols), e.g. For example, N, N, N', N'-tetraethanol-(ethylenediamine) Quadrol salt; N-(C8-C fatty acyl) glutamate; Synthesis of C-Cis fatty acylglycinates and/or their additional anions Mixtures with detergent surfactants and/or mixtures thereof may be mentioned.

The compositions of the present invention preferably contain about 0.01% to about 5%, preferably about 0.04% % to about 2%, especially about 0.05% to about 1%. High molecular Thickeners increase the creaminess and quality of the foam without negatively affecting the product dispensing properties. is found to be worthwhile.

Generally, useful polymers will increase the viscosity of the corresponding composition without the polymer to 70"F (2 at least about 1 cps, preferably about 2 to about IQ cps, and more Preferably, it is soluble or dispersible in water by an amount that will raise about 2 to about 5 cps. Should. Suitable polymers are high molecular weight materials (e.g. The measured weight average molecular weight is generally from about 2,000 to about 3,000,000, preferably preferably about 5,000 to about 1,000,000, more preferably about 7,000 to about 1 ．． 000,000). Polymers obviously manipulated by increasing the viscosity of the composition Therefore, the polymer preferably contains 1% of the polymer in 70°C (21,2°C) water. Thickening capacity such that the dispersion exceeds about 1 centipoise, preferably about 2 centipoise have power.

Useful polymers include cationic, nonionic, and amphoteric polymers useful in the cosmetic field. It is an anionic and anionic polymer. Hair or skin conditioning in the cosmetics field Cationic and nonionic polymers used as blocking agents are preferred.

Typical types of polymeric hair or skin conditioning agents include cationic and and nonionic polysaccharides; cations derived from acrylic acid and/or methacrylic acid cationic and nonionic homopolymers and copolymers; cationic and nonionic cellulose Resin; Cationic copolymer of dimethyldiallylammonium chloride and acrylic acid ;Cationic homopolymer of dimethyldiallylammonium chloride;Cationic polyal Kylenimine and ethoxypolyalkyleneimine; quaternized silicone; and mixtures thereof.

By way of example, preferred cationic polymeric conditioning agents for use herein In addition to the above cationic groups, hydroxypropyl substituents (d, s, 0. Product name: Jaguar C-14-S (containing 8-1.1) RTM), Shagua C-17 (RTM), Shagua C-16 (RTM) Hydroxypropyltrimethylammonium guar gum (d, s.

0.11-0.22), and the product name Uca re) Polymer JR, quaternized cellulose commercially available from Celquat -Suether is mentioned. Other suitable cationic polymers are available under the trade name Merckor. Dimethyldiallyl ammonium chloride commercially available from Merquat 100. Autopolymer, dimethyl acetic acid, commercially available under the trade names Mercquart 550 and Mercquot 5. Copolymer of minoethyl methacrylate and acrylamide, dimethyl chloride Copolymer of ammonium and acrylamide, trade name: Gafq quaternized vinyl pyrrolidone acrylate of amino alcohol commercially available or methacrylate copolymers, and polyalkyleneimines, e.g. tyrenimine and ethoxylated polyethyleneimine.

Other polymers suitable for use herein include hydroxyethylcellulose [ For example, Natrosol 250 MXR, Natrosol (250HHR); xanthan rubber [e.g. Keltrol T); Polymer of sugar or oligosaccharide and compatible synthetic monomer; Quaternized polycarbohydrate Xylate; polyethylene glycol mono- and di-esters/ethers (e.g. For example, polyethylene glycol [20-500] distearate) .

Cleansing compositions may include hair or skin moisturizers. Can be included. A preferred amount of moisturizer is from about 3 to about 40% by weight. good In preferred embodiments, the moisturizer is non-occlusive and 1. Water-soluble liquid polyol; 2. Essential amino acid compounds naturally occurring and found in the stratum corneum of the skin; and 3. Water-soluble non-polyol non-occlusion substances and mixtures thereof selected from.

Some examples of more preferred non-occlusion moisturizers are glycerin, polyethylene Polymer glycol, propylene glycol, sorbitol, methylglucose Ethylene glycol ether and propylene glycol ether of methylglucose polyethylene (e.g. methylglucan-20), lanolin alcohol Propylene glycol ether of glycol ether and lanolin alcohol [For example, Solulan-75), sodium pyrrolidone carboxylate lactic acid, urea, L-proline, guanidine, pyrrolidone and mixtures thereof. It is a compound. Of the above, glycerin is highly preferred.

Examples of other water-soluble non-occlusive moisturizers include adipic acid, lactic acid, oleic acid, Water of inic acid, stearic acid, isostearic acid, myristic acid or linoleic acid Soluble hexadecyl ester, myristyl ester, isodecyl ester or Sopropyl esters and many of their corresponding alcohol esters (isopropyl esters) Sodium tearoyl-2-lactate, sodium caprylic lactate), hydrolyzed protein collagen and other collagen-inducing proteins, aloe vera gel and acetamide An example is MEA.

Another valuable feature of the present invention is that the cream contains functional ingredients such as antibacterial and fungicidal agents. The efficacy of the cleansing composition is enhanced by the aerated foaming cleansing bath of the cleansing composition. This is an amazing finding that it can be substantially fixed by adding it to the pack. especially in water in the cleansing composition in the form of a substantially insoluble but preferably isotropic micellar solution. Solubilizing functional ingredients provide superior surface deposition and adhesion properties and improved efficacy It was found that Therefore, according to the near aspect of the present invention, Personal Cleansing Composition Packaged in a Foamer Container [Composition is a surfactant (synthetic surfactant, soap or mixture thereof) about 0.5% to 16 %, and preferably water-insoluble functional compounds such as antimicrobial agents from about 0.01 to about 5% by weight. %, preferably from about 0.1 to about 4% by weight] is provided. -tribromosalicylanilide, 4,4'-dichloro-3-(trifluoromethyl ) Carbanilide, 3,4.4'-trichlorocarbanilide, phenoxyetha Nol, phenokidibrobanol, chlorhexidine salt, hexaamidine salt, 2 ',4,4'-Trichloro-2-hydroxy-diphenyl ether [triclosa (Trichlosan), 2, 2’-methylenebis(4-k) lolo-6-bromophenol), salicylic acid, parachloromethaxylenol, 1 -hydroxy-4-methyl-6-(2,4,4-)limethylbentyl)-2-( IH)-pyridone salt [octopirox] and its Examples include mixtures of these. In the case of water-insoluble antimicrobial agents, solubilizing agents (e.g. Pyrene glycol) is also preferably added in an amount of about 0.1 to about 5% by weight.

A number of additional optional substances can be added to the cleansing composition. Such substances proteins and polypeptides and their derivatives; chemical preservatives, such as Germall 115, hydroxybenzoin Methyl, ethyl, propyl and butyl esters of acids , EDTA, Euxyl (RTM) K 400, Pronopo (2-bromo-2-nitropropane-1,3-diol); other moisturizing agents , for example, hyalonic acid, chitin, and starch-grafted sodium polyacrylates. For example, Celanese Spar Absorber from Boatsmith, Virginia, USA. No. 4,076,663 and available from Kent Materials, Inc. Sanwet (RTM) IM-1000, IM-150 as described 0 and IM-2500; hexylene glycol, propylene glycol, etc. Solvent; Low temperature phase modifier such as ammonium ion source (e.g. NH4C1); Coloring Agents include fragrances, fragrance solubilizers, and the like. Normal non-ionic emollients are , up to about 10% as additional skin conditioning agents, preferably from about 1% to about It can be added in an amount of 6%. Such substances include, for example, mineral oil, fatty sorbitan Stell (U.S. Pat. No. 3,988,255 to Seiden, issued October 26, 1976) (see specification), lanolin and lanolin derivatives, isopropyl myristate, etc. and triglycerides such as coconut oil. Water also contains this composition. It is present in an amount of about 60 to about 99% by weight, preferably at least about 75%.

The pI3 of the composition is preferably about 4 to about 9, more preferably about 4.5 to about 8.5. and the pH is controlled using, for example, a citrate buffer system.

The cleansing composition of the present invention includes a reservoir, a dispensing head, and a liquid/air mixing device. and a so-called “squeegee” preferably equipped with a homogenizer and a check valve device. Packaged in a compressible, non-aerosol dispenser in the form of a Zformer.

The squeeze former package is as illustrated by the disclosures in the following patents: Well known: U.S. Pat. No. 3,709,437 (Wright, January 1973) Published on the 9th); U.S. Patent No. 3,937,364 (Wright, issued February 10, 1976) : U.S. Patent No. 4,022,351 (Wright, issued May 10, 1977) : U.S. Pat. No. 4,147.306 (Bennett, issued April 3, 1979) ; U.S. Patent No. 4,184,615 (Wright, issued January 22, 1980) ; U.S. Pat. No. 4,598.862 (Rice, issued July 8, 1986); U.S. Pat. No. 4,615,467 (Grogan et al., Jan. 7, 1986) Issued on: and Buddhist Patent No. 2,604,622 (Berlhalst, 1988.4) (Announced on August 8th).

The package does not use propellants and is therefore safe for consumers and the environment. Ru. The cleansing composition can be placed in a container reservoir (e.g. plastic squeeze (You can also take the shape of a bottle). By manually squeezing the container reservoir, the composition is forced through a liquid/air mixing device where the composition is mixed with air and then and preferably homogenization to make the foam more homogeneous and control the consistency of the foam. Pass through the device. The foam is then distributed evenly through the dispensing head of the dispenser. Discharge as a non-pressurized aeration pond.

The minimum force to actuate the squeeze former is about 1 psig, preferably From about 2 psig to about 15 psig. Minimum force is applied to the chamber in the dispenser. It is proportional to the size of the flannel, the viscosity of the composition, etc.

Generally, the density of the foam is about 0.002 to about 0.25 g/cc, preferably about 0.0 It should be between 1 and about 0.07 g/cc. Foam density is inversely proportional to foam creaminess. , therefore lower foam densities are preferred.

The invention is illustrated by the following non-limiting examples.

In the examples, all concentrations are based on 100% active bone, and abbreviations are as follows: have

Amphoteric surfactant A Modified Milanol MSA-R, CHR is H, Z is C02N Formulas 1 and 9 19ゝ 2 that are a /or ■ Amphoteric surfactants (ampholyte surfactants are sodium lauryl sulfate, etc.) (added as molar complex).

Amphoteric surfactant B modified Milanol 2MCA-R is CH, R is CHCo, Na, Z is CO2N a and 1.1232 22 Certain amphoteric surfactants of formula 1 and/or (added as an equimolar complex with thorium).

Amphoteric surfactant CN-sodium lauryl-β-aminopropionate.

Amphoteric surfactant DN-sodium lauryl-β-iminodipropionate.

Polymer 1 Hydroxyethyl cellulose (HEC) rubber [Natrozol 250H R] Molecular weight approximately 1.000,000° Polymer 2 Quaternized cellulose ether (Polymer JR400).

Anionic surfactant 1 Coco hydrolyzed animal protein potassium.

Anionic surfactant 2 Palm kernel oil fatty acid sarcosinate.

Preservative Elaxil 400° Dispenser: Kunstraf Spermatician dispenser consisting of: Ease Former 121, 150m1 round HDPE/LDPE bin.

2. Standard bootstrap, off-on distribution・Sodo 3, “White” e) J mixing chamber.

4. Drying tube with a diameter of 2.00+*m and a length of 11.5 m.

Amphoteric surfactant A --1,1-2,8 Amphoteric surfactant B 2.8 0.9 -- 0.5 -Ampholytic surfactant C--L, L-- Amphoteric surfactant D 2.8 1 - 0.4 2.8 Anionic surfactant 1 - 2.7 − − − Anionic surfactant 2-1 −− Polymer 1 0.12 - 0.1 0.26 - Polymer 2 - - - 0. 3 Glycerol 5-5″5 Hexylene glycol 0.6 0.2 0.4 Q, 1 0.8 EDTA O , 1G, 1 0.1 G, 1 0.1 Preservative 0.2 0.2 0.2 0.2 0.2 water remaining (assume 100) Squeeze foamer products are prepared by conventional liquid mixing/filling methods. Example 1 -V viscosity of the cleansing composition (Brookfield LVTSUL adapter) , 70 teeth, 60 rpm, spindle speed correction) is within the range of 1 to 10 cps. (The 60 rpm correction factor is (spindle reading - 0, 4)Xo, 1).

The product has improved foaming properties along with excellent cleansing properties and mildness. (creaminess, richness, stability).

Amphoteric surfactant A--1,1 Ampholytic surfactant B O,60,8- Amphoteric surfactant C--1,1 Amphoteric surfactant D 1.7 15 - Anionic surfactant 1-2- Anionic surfactant 2 - l - Polymer 1 0.1 - 0.1 Glycerol 1285 Ammonium chloride 1. Q 1.0 1.0 Hexylene glycol 0. BO ,20,4 propylene glycol 3. Q 4.0 2.5 EDTA O, 10 ,10゜l Triclosan 0.3 0.4 0.2 Water balance (assumed to be 100) Squeeze foamer products are prepared by conventional liquid mixing/filling methods. Example■ ~ ■ Viscosity of cleansing composition (Brookfield LVT, UL adapter) , 70 lower, 60 r p m s spindle speed correction) ranges from 1 to 10 cps. (60 rpm correction factor is (spindle reading - 0, 4) Xo, 1) .

The product is improved along with excellent cleansing properties, antibacterial performance and mildness. It exhibits good foaming properties (creaminess, richness, stability).

Summary book Compressible non-aerosol with reservoir, dispensing head and liquid/air mixing device A foaming cleansing product consisting of a bubble dispenser with a reservoir ( a) 0.1-16% of imidazolinium or ammonium amphoteric surfactant, ( b) Aminoalkanoate or iminodialkanoate amphoteric surfactant 0.1 ~16%; (C) optionally up to 10% anionic surfactant; and (d) water The cleansing composition contains a total surfactant concentration. from 0.2% to 20% by weight, at least 20% of which is a mixture of (a) and (b). A foaming cleansing product characterized by being made of a compound. The composition is excellent Improved foam stability and creaminess along with gelling performance and mildness have It is suitable for makeup cleansers and facial cleansers, foams and shampoos. Suitable for use as hair products, shampoos, etc.

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Claims (1)

[Claims] 1. Compressible non-evacuation device with reservoir, dispensing head and liquid/air mixing device A foaming cleansing product consisting of an azole dispenser and a reservoir. (a) Formula I ▲There are mathematical formulas, chemical formulas, tables, etc.▼I (wherein R1 is C7-C22 alkyl or alkenyl, R2 is hydrogen or is CH2Z, and each Z is independently CO2M or CH2CO2M, where M is H, alkali metal, alkaline earth metal, ammonium or alkanol ammonium) and/or an imidazolinium derivative of formula IV ▲Contains mathematical formulas, chemical formulas, tables, etc.▼IV (where R1, R2 and Z are defined above) ) from about 0.1 to about 16% by weight of a first amphoteric surfactant selected from ammonium derivatives of ; (b) Formula II R1NH(CH2)nCO2M II Aminoalkanoate of formula III R1N[(CH2)mCO2M]2　III iminodialkanoate and its mixtures thereof (wherein n and m are numbers from 1 to 4, and R1 and M are independently selected from the groups specified in (a)) about 0.1 to about 16% by weight of a second amphoteric surfactant selected from; (c) optionally up to about 10% anionic surfactant; and (d) Water and the cleansing composition contains all surfactants. a first amphoteric surfactant and a second amphoteric surfactant; characterized in that the combined concentration with the surfactant accounts for at least 20% by weight of the total surfactant concentration. Foaming cleansing product. 2. A mixture of a first amphoteric surfactant and a second amphoteric surfactant accounts for a small amount of total surfactant. at least 50% by weight, preferably at least about 60% by weight, more preferably less 2. The cleansing product of claim 1, comprising at least about 75% by weight. 3. The total surfactant concentration is preferably from about 1% to about 16% by weight of the cleansing composition. is from about 1 to about 8% by weight, more preferably from about 2 to about 6% by weight. The cleansing product described in 2. 4. from about 0.5 to about 10%, preferably from about 0.5 to about 4% by weight of the cleansing composition % of each of a first amphoteric surfactant and a second amphoteric surfactant. The cleansing product according to any one of item 3. 5. The weight ratio of first amphoteric surfactant to second amphoteric surfactant is from about 10:1 to about 1:10, preferably about 5:1 to about 1:5, more preferably about 3:1 to about 1 The cleansing product according to any one of claims 1 to 4, wherein: :3. 6. from about 0.1 to about 10%, preferably from about 0.5 to about 5% by weight of the cleansing composition additionally comprises % by weight, more preferably from about 1 to about 3% by weight of an anionic surfactant. , a cleansing product according to any one of claims 1 to 5. 7. A premix of a first amphoteric surfactant and an anionic surfactant in an equivalent ratio of about 1:1. 7. A cleansing product according to claim 6, comprising a cleansing product. 8. Anionic surfactants can break down protein, protein or amino acid fats. The cleansing agent according to claim 6, which is an acid condensate or a mixture of the fatty acid condensates. product. 9. The fatty acid condensate is (i) C8-C12, preferably C10-C18 fatty acid and hydrolyzed protein; condensate of, (ii) Fatty acids derived from C8-C22, preferably C10-C18 fatty acids cosinate, and (iii) mixtures thereof; 9. A cleansing product according to claim 8, selected from: 10. The cleansing composition has a viscosity (Brookfield LVT, UL adapter) -, 70°F, 30-60 rpm, speed correction) 50 cps or less, preferably 20 The cleansing agent according to any one of claims 1 to 9, having a cps or less. product. 11. The cleansing composition has a viscosity of about 2 to about 15, preferably about 2 to about 12, and so on. 11. The cleansing product of claim 10, preferably having from about 4 to about 12 cps. Goods. 12. 0.01 to 5% by weight of the cleansing composition, preferably about 0.04 to about 2% % by weight, more preferably from 0.05 to 1% by weight of a polymeric thickener. The cleansing product according to any one of item 11. 13. The aqueous cleansing composition contains about 3% to hair or skin moisturizer. A cleansing product according to any one of claims 1 to 12, comprising about 40%. . 14. The moisturizer is non-occlusive and 1. Water-soluble liquid polyol; 2. essential amino acid compounds found naturally in the stratum corneum of the skin; and 3. Water-soluble non-polyol non-occluded substances and mixtures thereof 14. A cleansing product according to claim 13, selected from: 15. If your moisturizer contains glycerin, polyethylene glycol, or propylene polyethylene glycol ether of glycol, sorbitol, and methylglucose propylene glycol ether of ester and methylglucose, lanolin alcohol polyethylene glycol ether of alcohol and propylene of lanolin alcohol Glycol ether, sodium pyrrolidone carboxylate, lactic acid, L-proline and 15. A cleansing product according to claim 14, selected from: and mixtures thereof. 16. The cleanser according to claim 15, wherein the moisturizer is glycerin. products. 17. The polymer is a polymeric hair or skin conditioning agent, which is preferred. Preferably cationic and nonionic polysaccharides; acrylic acid and/or methacrylic acid Cationic and nonionic homopolymers and copolymers derived from acids; and non-ionic cellulose resin; dimethyl diallylammonium chloride and acrylic acid. Cationic copolymer of dimethyl diallylammonium chloride; cationic homopolymer of dimethyldiallylammonium chloride ; Cationic polyalkyleneimine and ethoxypolyalkyleneimine; Quaternary 13. The cleaner according to claim 12, selected from silicone oxides, and mixtures thereof. ging products. 18. Adding about 0.01 to about 5%, preferably about 0.1 to about 4% by weight of an antimicrobial agent 18. A cleansing product according to any one of claims 1 to 17, comprising: 19. The antibacterial agent is 3,4-di- and 3,4',5-tribromosalicylaniline. 4,4'-dichloro-3-(trifluoromethyl)carbanilide, 3,4, 4'-trichlorocarbanilide, phenoxyethanol, phenoxypropanol chlorhexidine salt, pexamidine salt, 2',4,4'-trichloro-2 -Hydroxy-diphenyl ether (triclosan), 2,2'-methylenebis (4-chloro-6-bromophenol), salicylic acid, rosechloromethaxyleno 1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl) Selected from -2-(1H)-pyridone salt (octopirox) and mixtures thereof. 19. The cleansing product of claim 18, wherein the cleansing product is