CN102626375A - Cleaning composition containing amino acid type surfactants - Google Patents

Cleaning composition containing amino acid type surfactants Download PDF

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Publication number
CN102626375A
CN102626375A CN2012101025859A CN201210102585A CN102626375A CN 102626375 A CN102626375 A CN 102626375A CN 2012101025859 A CN2012101025859 A CN 2012101025859A CN 201210102585 A CN201210102585 A CN 201210102585A CN 102626375 A CN102626375 A CN 102626375A
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China
Prior art keywords
amino acid
surfactant
cleasing compositions
acid type
contains amino
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CN2012101025859A
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Chinese (zh)
Inventor
罗发松
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FUJIAN MENGJIAOLAN DAILY CHEMICALS Co Ltd
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FUJIAN MENGJIAOLAN DAILY CHEMICALS Co Ltd
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Priority to CN2012101025859A priority Critical patent/CN102626375A/en
Publication of CN102626375A publication Critical patent/CN102626375A/en
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Abstract

The invention provides a cleaning composition containing amino acid type surfactants, which comprises at least one amino acid type surfactant, at least non-ionic surfactant, at least one betaine surfactant, and at least one cation regulating polymer. The cleaning composition has the advantages of mild action to hair and skin, little irritation, low toxicity, good foaming and emulsifying property, strong dirt-removing power and good biological degradation property, can be better in compatibility with other surfactants, and has better mold resistance and sterilization property.

Description

A kind of Cleasing compositions that contains amino acid type surfactant
Technical field
The present invention relates to a kind of Cleasing compositions, relate in particular to a kind of Cleasing compositions that contains amino acid type surfactant.
Background technology
As everyone knows, employed many surfactants have stimulation to eyes and skin in cleaning combination, and especially the injury to infant is bigger.Therefore, exploitation is not also grown the inevitable choice that perfect eyes and lachrymal gland and the nontoxic non-stimulated product of skin have just become articles for children manufacturers to the child.
Summary of the invention
The object of the present invention is to provide a kind of to hair and skin action temperature with, zest is little, low toxicity, bubble and emulsifiability good, dirt-removing power is strong, the cleaning combination that contains amino acid type surfactant that biodegradability is good.
For realizing above-mentioned purpose, technical scheme of the present invention is:
A kind of Cleasing compositions that contains amino acid type surfactant, it comprises
The surfactant of at least a amino acid pattern;
At least a non-ionic surfactant;
The surfactant of at least a betanin;
At least a cation telomerized polymer.
The amount of surfactant of said amino acid pattern is come in the gross weight of Cleasing compositions, and its amount ranges is 1%~10%.
Said non-ionic amount of surfactant is come in the gross weight of Cleasing compositions, and its amount ranges is 1%~10%.
The amount of surfactant of said betanin is come in the gross weight of Cleasing compositions, and its amount ranges is 1%~20%.
The amount of surfactant summation of said non-ionic surfactant and betanin and the amount of surfactant ratio of said amino acid pattern are between 3: 1 to 4: 1.
The surfactant of described amino acid pattern is the lauric acid sodium glutamate.
The surfactant of described nonionic is a PEG-80 anhydrous sorbitol laurate.
The surfactant of described betanin is a cocamido propyl betaine.
The consumption of said cation telomerized polymer comes in the gross weight of Cleasing compositions, and its amount ranges is 0.01%~1%, and said cation telomerized polymer is an Oleum Ricini amido propyl trimethyl ammonium chloride.
It can also comprise thickening agent, chelating agen, additive, antiseptic and deionized water; Said thickening agent is the PEG-150 distearate; Said chelating agen is a disodiumedetate, and said additive is a hyaluronate sodium, and said antiseptic is a Methylisothiazolinone.
Compared with prior art, the present invention has following beneficial effect:
1. the surfactant of the amino acid pattern that cleaning combination of the present invention adopts to hair and skin action temperature and; Zest is little, low toxicity, and foaming and emulsifiability are good; Dirt-removing power is strong; Biodegradability is good, and good with the compatibility of other various surfactants, has good antibacterial performance and bactericidal property.
2. the surfactant of the amino acid pattern that cleaning combination of the present invention adopts has also satisfied the requirement of people to Product Safety and mildness because the good surface property that it had makes it not only satisfy environment amenable requirement.
The specific embodiment
Below in conjunction with specific embodiment the present invention is done further detailed explanation.
A kind of Cleasing compositions that contains amino acid type surfactant, it comprises the surfactant of at least a amino acid pattern; At least a non-ionic surfactant; The surfactant of at least a betanin.
First kind of composition of Cleasing compositions of the present invention is for contain a kind of surfactant of amino acid pattern at least.The surfactant of amino acid pattern is the surface-active one type of material that has that is reacted and generated by aminoacid and hydrophobic substance, and the surfactant of representational amino acid pattern is the N-acyl amino hydrochlorate that is generated with fatty acid generation condensation reaction by amino.The N-acylamino acid has physiologically active, and for example the N-acyl sarcosinates has antibiosis active to lactobacillus, and N-acyl group valine has antibiosis active to rice blast pathogen; N-acyl glutamic acid salt pair phage has antibiosis; It is the surfactant of amino acid pattern that present embodiment is selected sodium lauroyl glutamate for use, and sodium lauroyl glutamate comes in the gross weight of Cleasing compositions; Its amount ranges is 1%~10%, and present embodiment selects 5% for use.
Second kind of composition of Cleasing compositions of the present invention is at least a non-ionic surfactant.The one type of polyoxyethylene deriv that non-ionic surfactant is a multi-hydroxy ester that is used for the present invention, the polyoxyethylene deriv of the multi-hydroxy ester here (1) contains from about 8 to about 22 carbon atoms, preferably from about 10 fatty acids to about 14 carbon atoms derived from (a); And (b) polyol is selected from sorbitol, sorbitan, glucose; The Alpha-Methyl glucosides; The polyglucose that contains average 1 to 3 glucose residue in each molecule, glycerin, tetramethylolmethane and their mixture; (2) contain on average from about 10 to about 120, preferably from about 20 to about 80 oxyethylene group groups; And on average contain about 1 to 3 fatty acid residue in the molecule of the polyoxyethylene deriv of (3) each multi-hydroxy ester; It is non-ionic surfactant that present embodiment is selected PEG-80 anhydrous sorbitol laurate for use; PEG-80 anhydrous sorbitol laurate; Gross weight in Cleasing compositions is come, and its amount ranges is 1%~10%, and present embodiment selects 2% for use.
The third composition is the surfactant of at least a betanin in the Cleasing compositions of the present invention.Betanin as used herein is at low pH value, and promptly 4 or more hour, be cation, at medium pH value, for example approximately pH value=7 o'clock is isoelectric.The surfactant of suitable betanin comprises, but is not limited in alkyl betaine; Decyl betaine for example; Such as the alkyl sulfobetaines of dodecyl hydroxyl sulfo betaine, such as the amido alkyl betanin of Folium Cocoe amido propyl betaine, such as the amido alkyl sulfobetaines of oleoyl amido propyl hydroxy sulfobetaines; And their mixture, the alkyl here contains about 8 to about 22 carbon atoms.It is the surfactant of betanin that present embodiment is selected cocamido propyl betaine for use, and cocamido propyl betaine comes in the gross weight of Cleasing compositions, and its amount ranges is 1%~20%, and present embodiment selects 14% for use.
In addition, Cleasing compositions of the present invention also comprises at least a cation telomerized polymer, and in the gross weight of Cleasing compositions, its amount ranges is 0.01%~1.0%.Also comprise among the present invention making its thickening agent that obtains proper viscosity, can protect the suitable chelating agen of material of Cleasing compositions of the present invention, the present invention can also optionally comprise antiseptic and suitable auxiliary agent etc.
In the present embodiment, the preferred cation telomerized polymer is an Oleum Ricini amido propyl trimethyl ammonium chloride.
In the present embodiment, preferred thickening is the PEG-150 distearate.
In the present embodiment, preferred chelating agen is a disodiumedetate.
In the present embodiment, preferred antiseptic is a Methylisothiazolinone.
A kind of Cleasing compositions that contains amino acid type surfactant, raw material is pressed following proportional arrangement:
Figure BSA00000699133700041
Use following method of testing in the above embodiments:
Human eye's stimulation test: this be double blinding, at random, Unit two research, test material is used once.Specimen is diluted into 10% solution, and it is maintained 37-38 ℃, this test material is added drop-wise to gradually in tester's the eye, then that sterile pure water is added drop-wise in tester's the another eye gradually.This research needs 10 testers.
Inferior ordered pair tester according at random tests, and the material of specifying which kind of material that which eye is dripped and drips also is to carry out with mode at random.A suitable test fluid is added drop-wise to first eye of tester at leisure, then sterile water is added drop-wise to second eye at leisure.All use new sterile disposable eyedropper for each test material, and promptly dispose later at eyes that are used for the tester.All work that slowly drips material is accomplished by investigator or well-trained technician.All use independent napkin with exhaustion effusive tear from eyes separately for every eye.
In 30 seconds, or as soon as possible after dripping test material, the inquiry tester, utilize standards to they the eyes irriate feel carry out classification: 0=is within normal limit; The 1=gentleness, very slight stimulation; The medium stimulation of 2=; Seriously stimulate with 3=.Dripping test material after 1/4 hour and 1 hour, inquire the tester again, stimulating eyes is carried out classification.
Carry out the eye irritation test of human body with the Cleasing compositions that contains amino acid type surfactant that makes.The result of research is as shown in table 1.
Table 1
Sample Grade to eye irritation
The pure water of sterilizing 0
The Cleasing compositions that contains amino acid type surfactant 0
This example shows that compositions of the present invention is more serious to stimulating eyes unlike sterile pure water.

Claims (10)

1. Cleasing compositions that contains amino acid type surfactant, it is characterized in that: it comprises
The surfactant of at least a amino acid pattern;
At least a non-ionic surfactant;
The surfactant of at least a betanin;
At least a cation telomerized polymer.
2. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1 is characterized in that: the amount of surfactant of said amino acid pattern, to come in the gross weight of Cleasing compositions, and its amount ranges is 1%~10%.
3. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1 is characterized in that: said non-ionic amount of surfactant, to come in the gross weight of Cleasing compositions, and its amount ranges is 1%~10%.
4. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1 is characterized in that: the amount of surfactant of said betanin, to come in the gross weight of Cleasing compositions, and its amount ranges is 1%~20%.
5. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1 is characterized in that: the amount of surfactant summation of said non-ionic surfactant and betanin and the amount of surfactant ratio of said amino acid pattern are between 3: 1 to 4: 1.
6. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1 is characterized in that: the surfactant of described amino acid pattern is the lauric acid sodium glutamate.
7. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1 is characterized in that: the surfactant of described nonionic is a PEG-80 anhydrous sorbitol laurate.
8. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1 is characterized in that: the surfactant of described betanin is a cocamido propyl betaine.
9. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 1; It is characterized in that: the consumption of said cation telomerized polymer; Gross weight in Cleasing compositions is come; Its amount ranges is 0.01%~1%, and said cation telomerized polymer is an Oleum Ricini amido propyl trimethyl ammonium chloride.
10. a kind of Cleasing compositions that contains amino acid type surfactant according to claim 9; It is characterized in that: it can also comprise thickening agent, chelating agen, additive, antiseptic and deionized water; Said thickening agent is the PEG-150 distearate; Said chelating agen is a disodiumedetate, and said additive is a hyaluronate sodium, and said antiseptic is a Methylisothiazolinone.
CN2012101025859A 2012-03-28 2012-03-28 Cleaning composition containing amino acid type surfactants Pending CN102626375A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103251522A (en) * 2013-04-28 2013-08-21 福建省梦娇兰日用化学品有限公司 Relaxing shower gel
CN106309234A (en) * 2016-09-22 2017-01-11 佛山慧创正元新材料科技有限公司 Weak-acid bath wash for baby
CN115975620A (en) * 2023-02-03 2023-04-18 西安石油大学 Gas well foam scrubbing agent and preparation method and application thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991017237A1 (en) * 1990-04-27 1991-11-14 The Procter & Gamble Company Cleansing products
WO1992005234A1 (en) * 1990-09-21 1992-04-02 The Procter & Gamble Company Cleansing compositions
WO1992018100A1 (en) * 1991-04-15 1992-10-29 The Procter & Gamble Company Antibacterial mild liquid skin cleanser
US6734155B1 (en) * 1997-07-09 2004-05-11 The Procter & Gamble Company Cleaning compositions comprising an oxidoreductase
CN101313881A (en) * 2007-05-29 2008-12-03 李燕强 Shampoo composition redounding to hair generation

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991017237A1 (en) * 1990-04-27 1991-11-14 The Procter & Gamble Company Cleansing products
WO1992005234A1 (en) * 1990-09-21 1992-04-02 The Procter & Gamble Company Cleansing compositions
WO1992018100A1 (en) * 1991-04-15 1992-10-29 The Procter & Gamble Company Antibacterial mild liquid skin cleanser
US6734155B1 (en) * 1997-07-09 2004-05-11 The Procter & Gamble Company Cleaning compositions comprising an oxidoreductase
CN101313881A (en) * 2007-05-29 2008-12-03 李燕强 Shampoo composition redounding to hair generation

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103251522A (en) * 2013-04-28 2013-08-21 福建省梦娇兰日用化学品有限公司 Relaxing shower gel
CN103251522B (en) * 2013-04-28 2015-06-17 福建省梦娇兰日用化学品有限公司 Relaxing shower gel
CN106309234A (en) * 2016-09-22 2017-01-11 佛山慧创正元新材料科技有限公司 Weak-acid bath wash for baby
CN115975620A (en) * 2023-02-03 2023-04-18 西安石油大学 Gas well foam scrubbing agent and preparation method and application thereof
CN115975620B (en) * 2023-02-03 2024-05-14 西安石油大学 Gas well foam discharging agent and preparation method and application thereof

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Application publication date: 20120808