JPH05325000A - Sample can label for vending machine - Google Patents

Abstract

PURPOSE:To eliminate the discoloration of the sample can labels even if they are kept in a severe environment for a long period of time. CONSTITUTION:A sample can label 10 is wound round a part or the whole of a dummy container 1 similar to the shape of an actual container of the commodity to be sold. A same or similar pattern as or to the commodity is printed on a base film 2 in the light resistant ink 3. For this ink 3, yellow pigments of the monoazo, condensation azo, benzimidazoron, isoindolinone and surene groups, the red and orange pigments of monoazo, condensation azo, quinacridone, perinone, perylene, and isoindolinone groups, and blue, green and purple pigments of the phthalocyanine, dioxazine, and quinacridone groups, can be used.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sample can label that is wrapped around a sample can of a vending machine.

[0002]

2. Description of the Related Art Conventionally, a sample can of this kind of vending machine is
Labels for sample cans printed on paper or film were attached to real bottles, cans, or other dummy containers. For this sample can label, a normal type process ink, which is the mainstream of printing ink, was used.

[0003]

However, when the vending machine is installed outdoors, the conventional sample can described above is
It is often exposed to direct sunlight for a long period of time, causing a problem that the label for the sample can is discolored.

In the above-mentioned process ink, β-type phthalocyanine blue and carbon black are often used as pigments for indigo and black ink, and they are excellent in various resistances such as light resistance and heat resistance, and have little discoloration. On the other hand, azo pigments such as disazo yellow (AAA) and brilliant carmine 6B used for yellow and crimson have weak resistance, and a marked discoloration is observed when exposed to sunlight and wind and rain.

An object of the present invention is to solve the above-mentioned problems and provide a label for a sample can of a vending machine which does not discolor even when placed in a severe environment for a long time. ..

[0006]

In order to solve the above problems, the sample can label of the vending machine according to the present invention is wrapped around a part or all of a dummy container having a shape similar to the shape of the product to be sold. A label for a sample can of a vending machine is characterized in that the same or similar pattern as that of the product is printed on a base film by using a light resistant ink.

In this case, the light-resistant ink is a yellow pigment such as a monoazo type, a condensed azo type, a benzimidazolone type, an isoindolinone type, a slene type pigment, a monoazo type, a condensed azo type, a quinacridone type, a perinone type, It can be characterized by using red / red / orange pigments such as perylene-based and isoindolinone-based pigments, and blue / green-purple-based pigments such as phthalocyanine-based, dioxazine-based and quinacridone-based pigments.

The light-resistant ink is a titanium oxide-based white inorganic pigment, a carbon black-based black inorganic pigment,
Yellow lead-based, cadmium yellow-based, yellow iron oxide-based, titanium yellow-based and other yellow-based inorganic pigments, red iron oxides such as red iron oxide and cadmium-red-based, ultramarine blue and navy blue-based inorganic pigments, chromium oxide And inorganic green pigments such as cobalt green and the like, purple inorganic pigments such as manganese purple, silver inorganic pigments such as aluminum powder, and gold inorganic pigments such as bronze.

[0009]

Since the sample can label of the present invention is printed on the base film using the light-resistant ink, it does not discolor even when exposed to direct sunlight for a long time.

[0010]

DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the present invention will be described with reference to the drawings. FIG. 1 is a perspective view showing an embodiment of a sample can label of a vending machine according to the present invention, and FIG. 2 is a sectional view showing a part of the sample can label according to the embodiment.

In FIG. 1, a dummy container 1 is a container having a shape similar to that of a product to be sold, and is made of an acrylic resin or the like which can be easily molded. A label 10 for a sample can is wrapped around the dummy container 1. As shown in FIG. 2, this sample can label 10 has characters, patterns, etc. printed on a base film 2 using a milky white polyester film or the like by a light resistant ink 3 described later. Also, the base film 2
An adhesive layer 4 for sticking to the dummy container 1 is formed on the inner end of the.

The sample can label 10 shown in FIG.
Shows an example in which a pattern is printed on the surface of the base film 2 and the ink surface of the light resistant ink 3 is on the outside.
A pattern may be printed on the transparent base film 2 by reverse printing, and the pattern may be wound so that the film surface of the base film 2 is on the outside (ink surface is on the inside). In this case, by kneading an ultraviolet absorber (for example, tinuvin) into the base film 2, the base film 2 itself absorbs the ultraviolet light to reduce the amount of the ultraviolet light reaching the light-resistant ink 3, thereby reducing the light resistance. It is possible to improve. Further, the adhesive layer 4 is not formed only on the end portion as shown in FIG. 2, but is applied on the entire surface, and the ultraviolet absorbing effect of the adhesive layer 4 is also added to further improve the light resistance. It becomes possible.

When the light-resistant ink 3 is yellow, Hansa Yellow G (manufactured by Hoechst), Seika Fast Yellow GH (manufactured by Dainichiseika Kogyo), Hansa Yellow 10G (manufactured by Hoechst), and Rionol Yellow 10G0801 (Toyo). Ink Manufacturing), Hansa Yellow RN (Hoechst), Sun Fast Yellow 65 (Sun Chemical), Hansa Brilliant Yellow 5GX (Hoechst), Shimura Fast Yellow 4191N (Dainippon Ink, hereinafter DIC), Nova Palm Yellow FGL (made by Hoechst),
Shimura Fast Yellow 4186 (manufactured by DIC), Hansa Brilliant Yellow 10GX (manufactured by Hoechst), Lionol Yellow 5G0501 (manufactured by Toyo Ink Manufacturing), Lionol Yellow K-2R (manufactured by Toyo Ink Manufacturing), Shimura Yellow 3056 (manufactured by DIC), etc. Condensed azo pigments such as Chromophthal Yellow 3G (made by Ciba Geigy), Chromophthal Yellow 3GP (made by Ciba Geigy), Chromophthal Yellow 6G (made by Ciba Geigy), Chromophthal Yellow GR (made by Ciba Geigy), Nova Palm Yellow H2G (Hoechst), PV Fast Yellow H2G (Hoechst), Hosta Palm Yellow H4G (Hoechst), Hosta Palm Yellow H
3G (Hoechst), Shimura Fast Yellow 4192
(Made by DIC), Hosta Palm Yellow HLR (made by Hoechst), Hosta Palm Yellow H6G (made by Hoechst), benzimidazolone-based pigment, Irgadine Yellow 2
GLT (Ciba Geigy), Irgadine Yellow 2GL
TN (made by Ciba Geigy), Irgadine Yellow 2 RLT
(Made by Ciba Geigy), Fastgen Super Yellow G
Isoindolinone-based pigments such as RO (manufactured by DIC), Chromophtal yellow A2R (manufactured by Ciba Geigy), Paliogen Yellow L1870 (manufactured by BASF), Paliogen Yellow L1482 (manufactured by BASF), Paliogen Yellow L1520 (manufactured by BASF), Chromo Fine Yellow A
It can be prepared using a slene-based pigment such as F1000 (A) (manufactured by Dainichiseika Kogyo).

In the case of red / red / orange system, Seika Fast Red 4R4016 (manufactured by Dainichiseika Kogyo), Hansa Scarlet RB (manufactured by Hoechst), Lionol Red FB55
00 (manufactured by Toyo Ink Mfg. Co., Ltd.), permanent carmine FB
(Made by Hoechst), Shimura Fast Red 4195 (DI
C), Vulcan Fast Carmine FBB (Hoechst), Nova Palm Carmine HF4C (Hoechst), P
V-Carmine HF4C (Hoechst) and other monoazo series, Chromophthal orange 4R (Ciba Geigy), Chromophthal red GR (Ciba Geigy), Chromophthal red BR (Ciba Geigy), Chromophthal red BRN
(Made by Ciba Geigy), Chromophthal Scarlet RN
(Made by Ciba Geigy), Fastgen Super Red R
Condensed azo such as (made by DIC), Hosta Palm Pink E
(Made by Hoechst), Fastgen Super Magenta R (D
IC), FASTGEN Super Red 2R (DIC
Made), quinacridone series such as Hosta Palm Red EG (made by Hoechst), perinone series such as Hosta Palm Orange GR (made by Hoechst), Lyonogen Orange GR (made by Toyo Ink Manufacturing), Nova Palm Red BL (made by Hoechst),
Paliogen Red B (Hoechst), Paliogen Red L3880HD (BASF), Paliogen Red L3
It can be prepared using a perylene pigment such as 910HD (manufactured by BASF) or an isoindolinone pigment such as Chromophtal Orange 2G (manufactured by Ciba Geigy).

In the case of blue / green / purple colors, Fastgen Blue BB (manufactured by DIC), Heliogen Blue D6840
(Manufactured by BASF), Heliogen Blue D6900 (BAS
F), Hosta Palm Blue A2R (Hoechst), Heliogen Blue D7080 (BASF), Lionol Blue FG7330 (Toyo Ink Mfg. Co.), Fastgen Green S (DIC), Helion Gen Green D8.
730 (manufactured by BASF), Hosta Palm Green 8G (manufactured by Hoechst), Helion Gen Green K9360 (BAS)
F) and other phthalocyanine pigments, Hosta Palm Violet RL (Hoechst), Fastgen Super Violet RN (DIC) and other dioxazine pigments, Hosta Palm Red Violet ER (Hoechst), Shinkasha Red B It can be prepared using a quinacridone-based pigment such as (made by Ciba Geigy).

Further, in the case of an inorganic pigment, it can be prepared using the following. Titanium oxide CR for white type
A pigment such as -58 (manufactured by Ishihara Sangyo) or titanium oxide SR-1 (manufactured by Sakai Chemical Industry) can be used. In the case of black ink, Printex NO. 55 (made by Degussa), M
A pigment such as carbon black based on A-8 carbon (manufactured by Mitsubishi Kasei) can be used. In the case of yellow, chrome yellow YIDG (made by Hoechst), lemon chrome yellow 3
25-7G (manufactured by Dainichiseika Kogyo Co., Ltd.) and the like, cadmium yellow Conc. Deep (Ciba Geigy), Cadmium Yellow Conc. Deep X-2826 (manufactured by Ciba Geigy) and the like, cadmium yellow, iron oxide yellow 1895 (manufactured by BASF), iron oxide yellow such as iron oxide yellow 1897 (manufactured by BASF), Irga color yellow 10401 (manufactured by Ciba Geigy), and luconyl yellow. Pigments such as titanium yellow type such as 1010 (manufactured by BASF) can be used. In the case of red,
Pigments such as iron oxide red 3495 (manufactured by BASF), lacsol red 33-9607 (manufactured by BASF), red iron oxide, cadmium red (manufactured by Ciba Geigy), cadmium red K2900 (manufactured by BASF), and the like can be used. .. In the case of blue, ultramarine blue such as Laxol Blue 62-9607 (manufactured by BASF), Ultramarine Blue 6196 (manufactured by BASF), Miloli Blue (manufactured by DIC), Milori Blue ARX-1750.
Pigments such as navy blue and the like (made by Ciba Geigy) can be used. Chromium oxide green 9 if green
Pigments such as chromium oxide pigments such as 996 (manufactured by BASF) and chromium oxide green 9997 (manufactured by BASF) and cobalt green pigments such as lacsol green 96-1007 (manufactured by BASF) can be used. In the case of a violet type, a manganese violet type pigment such as manganese violet 5395 (manufactured by BASF) or manganese violet 5595 (manufactured by BASF) can be used. In the case of silver,
Euthylen Silver 00-4905 (B
Aluminum powder-based pigments such as ASF) can be used. In case of gold system, Euthylen Gold 0
Bronze-based pigments such as 0-4605 (manufactured by BASF) can be used.

For other intermediate colors, similarly, a pigment having excellent light resistance to each color is used,
Alternatively, the pigments may be mixed and used. Further, in order to improve the light resistance, an ultraviolet absorber is added to 0.1
It is preferable to add ~ 1.0%. This is to absorb the ultraviolet rays that are the cause of deterioration of the pigment and reduce the amount of the ultraviolet rays directly applied to the pigment. On the other hand, in the case of offset ink, yellowing can be prevented by reducing the vegetable oil and alkyd resin in the varnish.

Next, some specific manufacturing examples will be described in more detail. [Production Example 1] Production Example 1 is a yellow ink produced based on the following formulation. Pigment Chromophthal Yellow 3G 20.00wt% Application: Condensed azo yellow pigment (pigment yellow-93) Varnish 73.85wt% Breakdown: Rosin modified phenol 34.00wt% Linseed oil 25.00wt% Petroleum solvent 40.00wt% Gel Agent 1.00 wt% Petroleum solvent 5.00 wt% Dryer 0.15 wt% UV absorber 1.00 wt% Total 100.00 wt% The prepared yellow ink is suitable for 300 hours or more in a light resistance test with a fade meter. there were.

[Comparative Example 1] Comparative Example 1 is a yellow ink prepared based on the following formulation. Pigment Seika First Yellow 2300 20.00 wt% Application: Disazo yellow pigment (pigment yellow-12) Varnish 74.85 wt% Petroleum solvent 5.00 wt% Dryer 0.15 wt% Total 100.00 wt% The yellow ink produced is faded. In the light resistance test with a meter, discoloration was recognized in about 20 hours.

[Production Example 2] Production Example 2 is a brown ink produced based on the following formulation. Pigment Chromophthal Yellow 3G 8.00 wt% Application: Condensed Azo Yellow Pigment (pigment yellow-93) Chromophthal Red GR 12.00 wt% Application: Condensed Azo Red Pigment (pigment red-139) Heliogen Blue D6840 2.00 wt % Application: Phthalocyanine indigo pigment (pigment blue-15) Ink varnish 71.85 wt% Petroleum solvent 5.00 wt% Dryer 0.15 wt% UV absorber 1.00 wt % Total 100.00 wt% The light-resistant brown ink produced is In a light resistance test with a fade meter, it was suitable for 300 hours or more. [Comparative Example 2] Comparative Example 2 is a brown ink produced based on the following formulation. Pigment Seika First Yellow 2300 8.00 wt% Application: Disazo yellow pigment (pigment yellow-12) Shimura Lake Red C 12.00 wt% Application: Azo lake red pigment (pigment red-53: 1) Heliogen Blue D6840 2.00 wt % Application: Phthalocyanine indigo pigment (pigment blue-15) Ink varnish 72.85 wt% Petroleum solvent 5.00 wt% Dryer 0.15 wt% Total 100.00 wt% The brown ink produced was 20 in a light resistance test by a fade meter. Discoloration and fading were observed in about the time.

[0021]

As described above in detail, according to the present invention, even when placed in a severe environment for a long time, discoloration does not occur.

[Brief description of drawings]

FIG. 1 is a perspective view showing an example of a label for a sample can of a vending machine according to the present invention.

FIG. 2 is a cross-sectional view showing a part of a sample can label according to an example.

[Explanation of symbols]

 1 Dummy Container 2 Base Film 3 Light-Resistant Ink 4 Adhesive Layer 10 Label for Sample Can

Claims (3)

[Claims] 1. A label for a sample can of a vending machine, which is wrapped around a part or all of a dummy container having a shape similar to that of a product to be sold, using a light-resistant ink having the same or similar pattern as the product. A label for a sample can of a vending machine, which is printed on a base film. 2. The light-resistant ink is a monoazo type, condensed azo type, benzimidazolone type, isoindolinone type,
Slen-based yellow pigments, monoazo-based, condensed azo-based, quinacridone-based, perinone-based, perylene-based, isoindolinone-based red / red / orange-based pigments, phthalocyanine-based, dioxazine-based, quinacridone-based blue / green A label for a sample can of a vending machine according to claim 1, wherein a purple pigment is used. 3. The light-resistant ink is a titanium oxide-based white inorganic pigment, a carbon black-based black inorganic pigment, a yellow lead-based, cadmium yellow-based, yellow iron oxide-based, titanium yellow-based yellow inorganic pigment, or the like. , Red inorganic pigments such as red iron oxide and cadmium red, blue inorganic pigments such as ultramarine blue and dark blue, green inorganic pigments such as chromium oxide and cobalt green, purple inorganic pigments such as manganese purple, and aluminum The label for a sample can of a vending machine according to claim 1, wherein a powder-type silver-based inorganic pigment and a bronze-type gold-based inorganic pigment are used.