JPH052371B2 - - Google Patents
Info
- Publication number
- JPH052371B2 JPH052371B2 JP60041188A JP4118885A JPH052371B2 JP H052371 B2 JPH052371 B2 JP H052371B2 JP 60041188 A JP60041188 A JP 60041188A JP 4118885 A JP4118885 A JP 4118885A JP H052371 B2 JPH052371 B2 JP H052371B2
- Authority
- JP
- Japan
- Prior art keywords
- supported
- solid acid
- catalyst
- acid
- preparing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 claims description 59
- 238000000034 method Methods 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000011973 solid acid Substances 0.000 claims description 22
- 239000007789 gas Substances 0.000 claims description 15
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 229910052796 boron Inorganic materials 0.000 claims description 11
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- -1 boron alkoxide Chemical class 0.000 claims description 10
- 229910052810 boron oxide Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical group COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 claims 1
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 description 17
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000005470 impregnation Methods 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 238000006237 Beckmann rearrangement reaction Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- AJSTXXYNEIHPMD-UHFFFAOYSA-N triethyl borate Chemical compound CCOB(OCC)OCC AJSTXXYNEIHPMD-UHFFFAOYSA-N 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000006462 rearrangement reaction Methods 0.000 description 2
- 238000007086 side reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- NHDIQVFFNDKAQU-UHFFFAOYSA-N tripropan-2-yl borate Chemical compound CC(C)OB(OC(C)C)OC(C)C NHDIQVFFNDKAQU-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60041188A JPS61200855A (ja) | 1985-03-04 | 1985-03-04 | 固体酸触媒の調製法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60041188A JPS61200855A (ja) | 1985-03-04 | 1985-03-04 | 固体酸触媒の調製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61200855A JPS61200855A (ja) | 1986-09-05 |
| JPH052371B2 true JPH052371B2 (enExample) | 1993-01-12 |
Family
ID=12601437
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60041188A Granted JPS61200855A (ja) | 1985-03-04 | 1985-03-04 | 固体酸触媒の調製法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61200855A (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6412045U (enExample) * | 1987-07-11 | 1989-01-23 | ||
| JP4681705B2 (ja) * | 2000-01-28 | 2011-05-11 | 住友化学株式会社 | ε−カプロラクタムの製造方法およびこれに使用する触媒 |
| WO2007083736A1 (ja) * | 2006-01-20 | 2007-07-26 | National University Corporation Chiba University | 不飽和アルコール製造用触媒およびそれを用いた不飽和アルコール製造法 |
-
1985
- 1985-03-04 JP JP60041188A patent/JPS61200855A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61200855A (ja) | 1986-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Sato et al. | Vapor-phase Beckmann rearrangement over silica-supported boria catalyst prepared by vapor decomposition method | |
| IT9022477A1 (it) | Gel cataliticamente attivo e procedimento per la sua preparazione | |
| US4324694A (en) | Supported catalysts containing vanadium pentoxide, titanium dioxide, phosphorus, rubidium and/or cesium, with or without zirconium dioxide | |
| SU571184A3 (ru) | Способ получени бензола и его низкомолекул рных гомологов | |
| US6908878B2 (en) | Catalyst compound for the metathesis of olefins | |
| US3931348A (en) | Process for preparing dimethyl naphthalene | |
| Kob et al. | Catalysis of the formation of-caprolactam from cyclohexanone oxime by tungsten oxide solid acids | |
| CN113877560A (zh) | 一种丙烯酸甲酯的合成方法及其固体碱催化剂 | |
| JPS6150638A (ja) | チタニアで担持されたニオビア及びまたはタンタラからなる触媒 | |
| Pinglian et al. | Aromatization of methane over different Mo-supported catalysts in the absence of oxygen | |
| CN110801828A (zh) | 一种乙烷化学链氧化脱氢制烯烃催化剂及其在乙烷氧化脱氢反应中的应用 | |
| US2379372A (en) | Splitting-off of hydrogen halide from halogenated hydrocarbons | |
| JPS61200855A (ja) | 固体酸触媒の調製法 | |
| Ushikubo et al. | Preparation, characterization, and catalytic activities of silica-supported tantalum oxide for the vapor phase decomposition of methyl tert-butyl ether | |
| Katada et al. | Vapor-phase Beckmann rearrangement over silica monolayers prepared by chemical vapor deposition | |
| CN114713266B (zh) | 丙烷氧化脱氢用铵改性氧化硅负载氧化硼及其制备方法 | |
| US5095166A (en) | Process for cracking paraffins to olefins | |
| EP0748305A1 (en) | Catalyst and process for alkylation of aromatics | |
| CN100531908C (zh) | 用于环己酮肟制己内酰胺催化剂的制备方法 | |
| Kozhevnikov et al. | Transalkylation of phenols over heteropoly acids | |
| US3437709A (en) | Disproportionation of alkyl aromatics with a crystalline aluminosilicate and oxygen | |
| US4305879A (en) | Process for producing a 2-tertiary-alkyl substituted anthraquinones | |
| CN107497479B (zh) | 一种堇青石为载体合成β分子筛制备甲氧基乙酸甲酯方法 | |
| US3230270A (en) | Alkylation of aromatics and catalyst therefor | |
| JPS59107921A (ja) | ｐ―キシレンの製造方法 |