JPH05159244A - Magneto-resistance effect head - Google Patents

Abstract

PURPOSE:To provide the magneto-resistance effect head which obviates deterioration in magnetic characteristics even after a heating stage and has excellent linear responsiveness and high reproduction efficiency. CONSTITUTION:The magneto-resistance effect head has the structure laminated with the ferromagnetic magneto-resistance effect element 1 and an amorphous soft magnetic material later 5 via a nonmagnetic conductor layer and is formed with the nonmagnetic conductor layer consisting of a TiW layer 7. The deterioration in the characteristics of the MR element or the amorphous soft magnetic material layer in a heating stage during the production process of the MR head is averted by forming the TiW film having low diffusivity as the nonmagnetic conductor layer.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a magnetoresistive device having a ferromagnetic magnetoresistive effect element (hereinafter abbreviated as MR element) for reading out magnetic information written in a magnetic storage medium by utilizing a magnetoresistive effect. The present invention relates to an effect head (hereinafter abbreviated as MR head).

[0002]

As is well known, when an MR element is used as a highly efficient read-only magnetic head which exhibits a linear response to magnetic information written in a magnetic storage medium,
Bias means for setting an angle θ (hereinafter referred to as a bias angle) formed by the sense current I flowing through the MR element and the magnetization M of the MR element to a predetermined value (preferably 45 degrees) must be provided.

Various methods have been disclosed as the above-mentioned biasing means.
In the MR head disclosed in Japanese Patent Laid-Open No. 8 or Japanese Patent Laid-Open No. 63-237204, a structure in which a nonmagnetic conductor layer and an amorphous soft magnetic material layer (for example, CoZrMo film) are sequentially laminated on the MR element is preferable. It has been shown that a wide bias angle θ can be obtained and an MR head excellent in linear response can be realized. That is, as shown in FIG. 4, an MR element 1 (for example, a film) made of a ferromagnetic thin film is formed on an insulating substrate (not shown) having a smooth surface made of glass, ferrite or the like by a sputtering method or an evaporation method. NiFe alloy with a thickness of 20 to 50 nm) is formed, and Ti, Mo,
An MR head having a structure in which a non-magnetic conductor layer 2 such as Cr is formed by the same method and an amorphous soft magnetic layer 5 is formed on the non-magnetic conductor layer 2 by the same method is disclosed. Here, 6 is a terminal for energizing the laminated body of the MR element 1, the non-magnetic conductor layer 2 and the amorphous soft magnetic material layer 5.

In such an MR head, the sense current I supplied from the terminal 6 is shunted not only to the MR head 1 but also to the non-magnetic conductor layer 2 and the amorphous soft magnetic layer 5.
Therefore, in such a structure, the sense current I shunted to the MR element 1 and the non-magnetic conductor layer 2 causes a magnetic field passing through the plane of the amorphous soft magnetic material layer 5 and perpendicular to the direction of the sense current I. Is generated, and this magnetic field causes the amorphous soft magnetic layer 5 to
The magnetization direction of rotates. Therefore, the magnetization in the amorphous soft magnetic layer 5 generates a magnetic field in the direction opposite to the direction of the magnetization around the amorphous soft magnetic layer 5, and a part of the magnetic field is applied to the MR element 1. . On the other hand, the sense current I shunted to the amorphous soft magnetic material layer 5 and the non-magnetic conductor layer 2 causes a magnetic field that passes through the plane of the MR element 1 and is perpendicular to the sense current I, and the direction of this magnetic field is as described above. It coincides with the direction of the magnetic field generated by the magnetization of the amorphous soft magnetic layer 5. That is, the magnetic field generated by the magnetization of the amorphous soft magnetic layer 5 and the magnetic field generated by the sense current I are applied to the MR element 1 as a bias magnetic field. This bias magnetic field rotates the magnetization of the MR element 1 with respect to the sense current I, and sets the bias angle θ of the MR element to a predetermined value (ideally 45 degrees) to realize an MR head with excellent linear response. To do.

[0005]

By the way, the above-mentioned M
In the MR head having a structure in which the R element 1, the non-magnetic conductor layer 2 and the amorphous soft magnetic layer 5 are laminated, when the non-magnetic conductor layer 2 is a Ti film, a Mo film, or a Cr film, it is manufactured. Heating step during the process (300-350 ° C)
Therefore, there is a problem that the magnetic characteristics of the amorphous soft magnetic material layer 5 or the MR element 1 are deteriorated and the reproducing efficiency of the MR head is lowered. The heating step in the manufacturing process improves the magnetic properties of the amorphous soft magnetic layer 5, and the easy axis of magnetization of the amorphous soft magnetic layer 5 and the easy axis of the MR element 1 are in the same direction. In order to realize a good bias level, it is an essential step in the manufacturing process of the MR head according to the present invention.

According to the study by the present inventor, the cause of the deterioration of the characteristics in the heating process is the interface between the non-magnetic conductor layer 2 and the MR element 1 or the non-magnetic conductor layer in the heating process of the MR head manufacturing process. It has been clarified that this is because diffusion occurs at the interface between 2 and the amorphous soft magnetic layer 5. Less than,
Reference will be made in detail in this regard.

FIG. 3 shows a NiFe film of about 50 nm on a Si substrate.
An example of the analysis result in the depth direction by the Auger analyzer before and after the heat treatment of the sample in which the film (corresponding to the MR element 1) and the Ti film of about 30 nm (corresponding to the non-magnetic conductor layer 2) are laminated in this order. Is. Here, the heat treatment condition is 30
It is 0 ° C. for 1 hour, and the heat treatment is performed in vacuum (vacuum degree: 2 ×
10 ⁻⁶ Torr). FIG. 3A shows the Auger analysis result before the heat treatment, but the distribution of each element is about 3 depth.
It is clear at the boundary of 0 nm, and it can be said that the NiFe film and the Ti film are hardly diffused. On the other hand, FIG. 3B shows the analysis result after the heat treatment, but the distribution of each element is broader in the depth direction compared to FIG. 3A, and particularly Ti has a depth of about 60 nm. It is spreading.

Further, a sample in which a CoZrMo film with a film thickness of about 50 nm is laminated on a Ti film with a film thickness of about 30 nm is similarly prepared with 30
In vacuum at 0 ° C for 1 hour (vacuum degree: 2 × 10 ^-6 Torr)
Similar diffusion of Ti was observed even after the heat treatment in (1).

As described above, according to the Auger analysis result,
Due to the heating step in the manufacturing process of the MR head, diffusion occurs between the non-magnetic conductor layer 2 and the MR element 1 or between the non-magnetic conductor layer 2 and the amorphous soft magnetic material layer 5, whereby the MR element 1 or It is considered that the magnetic characteristics of the crystalline soft magnetic material layer 5, for example, the saturation magnetization, the anisotropic magnetic field, the resistance change rate, and the like are deteriorated.

Approximately similar analysis results were obtained for samples using a Mo film or a Cr film instead of the Ti film.
The deterioration of the characteristics when these materials are used as the non-magnetic conductor layer 2 is also considered to be caused by diffusion.

Therefore, in order to solve the deterioration of the magnetic characteristics of the MR element 1 or the amorphous soft magnetic material layer 5 due to the diffusion in the heating step as described above, diffusion occurs even after the heating step of the manufacturing process. It is important to use a material that cannot be obtained as the non-magnetic conductor layer 2 in order to solve the problem.

It is an object of the present invention to provide a magnetoresistive head having excellent linear response and high reproduction efficiency without deterioration of magnetic characteristics even after a heating process.

[0013]

The present invention provides a magnetoresistive effect head having a structure in which a ferromagnetic magnetoresistive effect element and an amorphous soft magnetic material layer are laminated with a nonmagnetic conductor layer interposed therebetween. The magnetic conductor layer is made of a TiW film.

[0014]

FIG. 2 shows the heat treatment of a sample obtained by laminating a NiFe film (corresponding to the MR element 1) of about 50 nm and a TiW film (corresponding to the nonmagnetic conductor layer 2) of about 30 nm on a Si substrate in this order. It is an example of the analysis result of the depth direction by the Auger analyzer later. Here, the heat treatment condition is 350
℃, 2 hours, heat treatment in vacuum (vacuum degree: 2 × 1
0 ⁻⁶ Torr). As is clear from FIG. 2, even after the heat treatment, the distribution of each element is clear at a depth of about 30 nm, and the NiFe film and the TiW film are hardly diffused.

Thus, by using the TiW film as the non-magnetic conductor layer, diffusion between the non-magnetic conductor layer and the MR element or between the non-magnetic conductor layer and the amorphous soft magnetic layer can be prevented, and the MR head can be prevented. It is possible to avoid deterioration of the characteristics of the MR element or the amorphous soft magnetic material layer in the heating step during the manufacturing process.

[0016]

FIG. 1 is a diagram showing an embodiment of the present invention.

In FIG. 1, M is formed on a non-magnetic substrate (not shown) such as glass by a sputtering method in an Ar gas atmosphere.
40-nm-thick permalloy (Ni 82%)
-Fe 18%, weight%) film was formed. During deposition, a magnetic field of 100 Oe was applied by a permanent magnet to give uniaxial anisotropy to the permalloy film.

Next, in a mixed atmosphere of Ar gas and nitrogen gas (flow rate conversion: Ar: 100 sccm, N ₂ : 10 s).
The TiW film 7 having a film thickness of 30 nm to be a non-magnetic conductor layer was formed on the permalloy film by a sputtering method at a ccm). During film formation, a bias voltage of -50 V is applied to the substrate side to remove impurities in the TiW film, particularly oxygen, to remove Ti.
The specific resistance of the W film was reduced. The specific resistance of the formed TiW film was about 120 μΩcm. Further, the composition of the TiW film was Ti: 20 and W: 80 in weight%.

Further, the amorphous soft magnetic layer 5 has a film thickness of 30.
nm, an anisotropic magnetic field Hk5Oe of CoZrMo film (film composition: Co82% -Zr6% -Mo12%, atomic%) was formed on the above-mentioned TiW film 7 by a sputtering method in an Ar gas atmosphere. ..

Thereafter, the amorphous soft magnetic layer 5 (CoZrM
In order to impart uniaxial anisotropy to the (o film), the above-mentioned laminated body of the permalloy film, the TiW film, and the CoZrMo film has a thickness of 3
Heat treatment was performed in vacuum while applying a magnetic field of 480 Oe at 50 ° C. for 2 hours in the same direction as the easy axis of magnetization of the permalloy film.

Next, a photoresist pattern having a predetermined shape was formed on this laminate, and ion etching was performed in an Ar gas atmosphere to form a rectangular pattern having a length of 50 μm and a width of 5 μm. Here, the etching conditions are an acceleration voltage of 500 V and an Ar gas pressure of 0.1 mtorr.

Next, an MR head was manufactured by forming a terminal 6 for supplying a sense current I to the above-mentioned laminated body by using an integrated thin film technique. The terminal 6 is a laminated vapor deposition film of Ti and Au. The film thicknesses are 5 nm and 0.5 μm, respectively.

The M according to this embodiment having the above-mentioned configuration
In the R head, the sense current I is 5 to 15 mA and M
It was confirmed that the bias angle θ of the R element 1 could be set to about 45 degrees, and an MR head having good linear response and high reproduction efficiency was realized.

(Comparative Example) An MR head was manufactured in exactly the same manner as in Example except that the TiW film in Example was replaced with a Ti film. In this MR head, the MR process is performed at 350 ° C. for 2 hours for imparting uniaxial anisotropy to the amorphous soft magnetic layer.
Permalloy film or amorphous soft magnetic layer 2 to be the element 1
Since the magnetic characteristics of the CoZrMo film, which has the following characteristics, are deteriorated, a sufficient bias is not applied to the MR element even when a sense current of about 35 to 40 mA is applied, and the reproducing efficiency is about 30 to 50% as compared with the MR head according to the present invention. It was revealed that it was small and not suitable for practical use. An MR head using a Cr film and a Mo film as a non-magnetic conductor layer was also manufactured, but a sufficient bias level could not be obtained like the MR head described in this comparative example, and the MR head was also described in the embodiment of the present invention. The reproduction efficiency was lower than that of the MR head.

In the above description, only the example in which the MR element (permalloy film), the TiW film layer, and the amorphous soft magnetic material layer are laminated in this order has been mentioned, but the amorphous soft magnetic material layer, An excellent linear response and high reproducing efficiency were obtained also in the MR head in which the TiW film layer and the MR element were laminated in this order. The material forming the amorphous soft magnetic layer is CoZrMo.
The film is not limited to a film, and for example, a CoTaMo film,
A CoZrTa film or the like may be used. Furthermore, the method and conditions for forming the TiW film in the examples are merely examples, and other methods and conditions may be used. Of course, in this case, TiW
If the resistivity of the film is extremely large, the conductivity is impaired and the problem of heat generation due to Joule heat occurs, so attention should be paid to the value of the resistivity of the film formed. The specific resistance value of the TiW film depends on the design and specifications of the MR head to which the present invention is applied and the state of the sheet sink, and therefore cannot be generally stated, but it is desirable that the specific resistance value is 200 μΩcm or less.

[0026]

As described above, according to the present invention, the TiW film having a low diffusivity is used as the non-magnetic conductor layer, so that the MR in the heating step in the MR head manufacturing process is improved.
It is possible to avoid deterioration of the characteristics of the element or the amorphous soft magnetic layer,
An MR head having excellent linear response and high reproduction efficiency is realized.

[Brief description of drawings]

FIG. 1 is a diagram showing an embodiment of the present invention.

FIG. 2 is a diagram for explaining the operation of the present invention.

FIG. 3 is a diagram for explaining a problem of the conventional technique.

FIG. 4 is a schematic view of a conventional MR head.

[Explanation of symbols]

 1 MR element 2 Non-magnetic conductor layer 5 Amorphous soft magnetic layer 6 Terminal 7 TiW film

Claims (1)

[Claims] 1. A magnetoresistive effect head having a structure in which a ferromagnetic magnetoresistive effect element and an amorphous soft magnetic material layer are laminated via a nonmagnetic conductor layer, wherein the nonmagnetic conductor layer is TiW.
A magnetoresistive head comprising a film.