JPH05142560A - Anisotropic conductive film - Google Patents

Anisotropic conductive film

Info

Publication number
JPH05142560A
JPH05142560A JP30323091A JP30323091A JPH05142560A JP H05142560 A JPH05142560 A JP H05142560A JP 30323091 A JP30323091 A JP 30323091A JP 30323091 A JP30323091 A JP 30323091A JP H05142560 A JPH05142560 A JP H05142560A
Authority
JP
Japan
Prior art keywords
adhesive
particles
conductive film
anisotropic conductive
conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP30323091A
Other languages
Japanese (ja)
Other versions
JP3100436B2 (en
Inventor
Yuichi Ota
祐一 太田
Masakuni Itagaki
雅訓 板垣
Takumi Suzuki
巧 鈴木
Yuji Narumi
雄二 鳴海
Hisao Takahashi
久雄 高橋
Hiroshi Fujimura
浩 藤村
Hiroyuki Sakayori
寛幸 坂寄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ricoh Co Ltd
Original Assignee
Ricoh Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ricoh Co Ltd filed Critical Ricoh Co Ltd
Priority to JP03303230A priority Critical patent/JP3100436B2/en
Publication of JPH05142560A publication Critical patent/JPH05142560A/en
Application granted granted Critical
Publication of JP3100436B2 publication Critical patent/JP3100436B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/30Assembling printed circuits with electric components, e.g. with resistor
    • H05K3/32Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
    • H05K3/321Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by conductive adhesives
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/36Assembling printed circuits with other printed circuits
    • H05K3/361Assembling flexible printed circuits with other printed circuits

Landscapes

  • Liquid Crystal (AREA)

Abstract

PURPOSE:To prevent the generation of microcracks in a wiring pattern or to suppress the propagation of microcracks by dispersing the grains of a conductive adhesive in an insulating adhesive resin sheet. CONSTITUTION:A thermosetting epoxy-resin adhesive is used for an insulating adhesive sheet 11, and the conductive grains 12 are dispersed in the sheet 11 to obtain an anisotropic conductive film A1. The grain 12 is obtained by mixing a conductive material 12b consisting of fine carbon particles into the grain of an epoxy-resin adhesive 12a. The conductive film A1 is arranged between the transparent electrodes 14 on the two base films 13 consisting of a flexible resin. The base films 13 are pressed from both sides and heated, hence the conductive grain 12 is softened and deformed between the electrodes 14, and the base films 13 are bound together by the cured sheet 11.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、液晶表示素子の基板に
形成した透明電極端子と外部回路の電極端子等の接続に
使用される異方性導電膜の改良に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to improvement of an anisotropic conductive film used for connecting a transparent electrode terminal formed on a substrate of a liquid crystal display element and an electrode terminal of an external circuit.

【0002】[0002]

【従来の技術】従来、液晶表示素子における透明電極を
外部回路の配線パターンと接続するに際して異方性導電
膜が使用されている。その異方性導電膜の構造として、
絶縁性接着シートの中に金属粒子もしくは樹脂粒子表面
をAuメッキしたものを所定の濃度で分散された構成3
が用いられている。前記金属粒子としては、半田,Ni
等が使用されている。
2. Description of the Related Art Conventionally, an anisotropic conductive film has been used to connect a transparent electrode in a liquid crystal display element to a wiring pattern of an external circuit. As the structure of the anisotropic conductive film,
Structure 3 in which metal particles or resin particles whose surfaces are plated with Au in an insulating adhesive sheet are dispersed at a predetermined concentration.
Is used. The metal particles include solder and Ni
Etc. are used.

【0003】また、異方性導電膜の他の構造として、図
4に示すように、液晶表示素子のベースフイルム1上の
導電性インクで印刷された配線パターン2と外部回路の
配線パターンとを接続するため、前記ベースフイルム1
上に、前記金属粒子3を絶縁性接着剤4に混ぜた材料5
を印刷するタイプのものがある。いずれの異方性導電膜
も、二つの配線パターンの間に配置され、配線パターン
を支持したベースフイルム及び外部回路基板を加熱、加
圧することにより、金属粒子3が二つの配線パターン間
の導通をとり、絶縁性接着シート1又は絶縁性接着剤4
が溶けて二つの配線パターン間の接合を行っている。
As another structure of the anisotropic conductive film, as shown in FIG. 4, a wiring pattern 2 printed with conductive ink on a base film 1 of a liquid crystal display element and a wiring pattern of an external circuit are provided. The base film 1 for connecting
On top of this, a material 5 in which the metal particles 3 are mixed with an insulating adhesive 4
There is a type of printing. Any of the anisotropic conductive films is disposed between the two wiring patterns, and the base film supporting the wiring pattern and the external circuit board are heated and pressed to allow the metal particles 3 to conduct electricity between the two wiring patterns. Insulating adhesive sheet 1 or insulating adhesive 4
Melts and joins the two wiring patterns.

【0004】二つの配線パターンを接合した異方性導電
膜は、その後、金属粒子3の回りに位置する絶縁性接着
シート又は絶縁性接着剤4が硬化することによって、金
属粒子3の移動を阻止しているものの、温度の変化によ
って基板であるベースフイルム1が伸縮を生じ、この伸
縮により金属粒子3が配線パターン2の表面から浮き上
がり、このため、二つの配線パターンの導通を不安定な
ものとしている。
The anisotropic conductive film in which the two wiring patterns are joined together is prevented from moving by the hardening of the insulating adhesive sheet or insulating adhesive 4 located around the metal particles 3. However, the base film 1, which is the substrate, expands and contracts due to a change in temperature, and the expansion and contraction causes the metal particles 3 to float up from the surface of the wiring pattern 2, thus making the conduction of the two wiring patterns unstable. There is.

【0005】また、可撓性樹脂材料からなるベースフイ
ルム1上に形成されたITO等の配線パターン2と金属
粒子3とが接触導通する際、ITO等の配線パターン2
はベースフイルムに対する接着強度が弱いため、金属粒
子3が加熱加圧により配線パターン2に圧接させられる
ときに、配線パターン2に微小クラックが発生する可能
性がある。この微小クラックはその後の進行によって、
配線パターンの断線の一原因となることが判明してい
る。現在、このような微小クラックの進行を抑える適当
な手段は見当たらない。
When the wiring pattern 2 made of ITO or the like formed on the base film 1 made of a flexible resin material and the metal particles 3 come into contact with each other, the wiring pattern 2 made of ITO or the like is formed.
Since the adhesive strength to the base film is weak, minute cracks may occur in the wiring pattern 2 when the metal particles 3 are pressed against the wiring pattern 2 by heating and pressing. This minute crack,
It has been found to be a cause of disconnection of the wiring pattern. At present, no suitable means for suppressing the progress of such minute cracks is found.

【0006】[0006]

【発明が解決しようとする課題】本発明は、従来技術に
おける問題に鑑み、二つの配線パターンを異方性導電膜
により接合するに際して、配線パターンに微小クラック
が発生することがなく、そして、仮に発生したとして
も、その微小クラックの進行を抑えることができる、接
続の信頼性の高い異方性導電膜を提供することを目的と
するものである。
SUMMARY OF THE INVENTION In view of the problems in the prior art, the present invention is such that when two wiring patterns are joined by an anisotropic conductive film, fine cracks do not occur in the wiring patterns, and It is an object of the present invention to provide an anisotropic conductive film having a highly reliable connection that can suppress the progress of the minute cracks even if they occur.

【0007】[0007]

【課題を解決するための手段】本発明は、前記目的を達
成するために、異方性導電膜が、絶縁性接着樹脂シート
の中に、導電性接着剤の粒子を分散させたことを特徴と
し、前記導電性接着剤の粒子は、絶縁性接着剤に導電物
質の粉末を混入したこと、又は絶縁性接着剤の粒子の表
面を金属皮膜で覆ったことを特徴とするものである。
In order to achieve the above object, the present invention is characterized in that an anisotropic conductive film has particles of a conductive adhesive dispersed in an insulating adhesive resin sheet. The particles of the conductive adhesive are characterized in that powder of a conductive substance is mixed in the insulating adhesive, or the surface of the particles of the insulating adhesive is covered with a metal film.

【0008】[0008]

【作用】本発明の構成により、絶縁性接着剤シートの中
に分散した導電性粒子自体が接着剤として作用し、且つ
加圧加熱により変形するため、可撓性樹脂からなるベー
スフイルムの上の透明電極を傷付けることなく導通さ
せ、微小クラックが発生しても、前記導電性粒子が溶け
て前記微小クラック間に入り込んで硬化するため、クラ
ックの進行を阻止する作用を有する。
According to the constitution of the present invention, the conductive particles themselves dispersed in the insulating adhesive sheet act as an adhesive and are deformed by heating under pressure, so that the conductive film on the base film made of a flexible resin is formed. Even if the transparent electrode is brought into conduction without being damaged and a minute crack is generated, the conductive particles are melted and enter between the minute cracks to be hardened, so that it has an action of preventing the progress of the crack.

【0009】[0009]

【実施例】以下、本発明の実施例を図面に基づいて説明
する。図1には、本発明の異方性導電膜についての第1
実施例を示し、図1(a)は圧着前の異方性導電膜その
ものの断面形状であり、図1(b)は、その異方性導電
膜が透明電極を形成した二つのベースフイルム間に圧着
された状態を示している。
Embodiments of the present invention will be described below with reference to the drawings. FIG. 1 shows a first example of the anisotropic conductive film of the present invention.
FIG. 1A shows a cross-sectional shape of the anisotropic conductive film itself before pressure bonding, and FIG. 1B shows a space between two base films in which the anisotropic conductive film forms a transparent electrode. It has been crimped to.

【0010】本発明の異方性導電膜A1 は、熱硬化型の
エポキシ樹脂系の接着剤を絶縁性接着剤シート11と
し、この絶縁性接着剤シート11の中に、導電性粒子1
2が分散される構成からなり、その導電性粒子12は、
エポキシ樹脂系の接着剤12aにカーボンの微粉末から
なる導電物質12bを混入して粒子化したものである。
In the anisotropic conductive film A 1 of the present invention, a thermosetting epoxy resin adhesive is used as an insulating adhesive sheet 11, and the conductive particles 1 are contained in the insulating adhesive sheet 11.
2 is dispersed, and the conductive particles 12 are
The conductive material 12b made of fine carbon powder is mixed into the epoxy resin adhesive 12a to form particles.

【0011】導電性粒子12の粒子径は、この実施例の
場合、ベースフイルムであるPET基板13上の透明電
極14のパターン幅及び高さが125μm,0.2μm
であるため、約20μmとした。よって、透明電極14
のパターン幅及び高さに応じて、その粒子径は5〜50
μmに適宜変更される。
In the present embodiment, the particle size of the conductive particles 12 is 125 μm and 0.2 μm, respectively, when the pattern width and height of the transparent electrode 14 on the PET substrate 13 which is the base film.
Therefore, it was set to about 20 μm. Therefore, the transparent electrode 14
Depending on the pattern width and height of the
It is appropriately changed to μm.

【0012】導電性粒子12として接着剤12aには、
60〜80℃のガラス転移点を有する熱硬化型の性質か
らなるエポキシ樹脂系接着剤が使用された。このような
接着剤は、ベースフイルムであるPET基板同士の接
続、又はPET基板とTABとの接続の際、接着剤のガ
ラス転移点がPET基板のガラス転移点よりも低いこと
から、PET基板に導電性粒子12の痕跡を付けること
がなく接着させることができる。PET基板のガラス転
移点を越えても、導電性粒子が軟化しないと、接着の際
の加圧により、導電性粒子によりPET基板が歪み、透
明電極(ITO)にダメージを与えることになる。導電
性粒子中の接着剤としては、エポキシ樹脂系接着剤の
他、フェノール樹脂系接着剤等を使用することができ
る。
As the conductive particles 12, the adhesive 12a includes
An epoxy resin adhesive having a thermosetting property having a glass transition point of 60 to 80 ° C. was used. Such an adhesive has a glass transition point lower than that of the PET substrate when the PET substrates, which are base films, are connected to each other or the PET substrate and the TAB are connected to each other. The conductive particles 12 can be adhered without leaving a trace. If the conductive particles do not soften even if the glass transition point of the PET substrate is exceeded, the PET particles will be distorted by the conductive particles due to the pressure applied during adhesion, and the transparent electrode (ITO) will be damaged. As the adhesive in the conductive particles, a phenol resin adhesive or the like can be used in addition to the epoxy resin adhesive.

【0013】導電性粒子12を分散させる絶縁性接着剤
シート11としては、熱硬化型のエポキシ樹脂系接着剤
が使用された。絶縁性接着剤シート11中に分散される
導電性粒子12の分散濃度は、透明電極14のパターン
幅及び高さに応じて変更され、絶縁性接着剤シート11
の厚みは、導電性粒子12の粒子径と一致する厚みとし
てシート状に形成される。
As the insulating adhesive sheet 11 in which the conductive particles 12 are dispersed, a thermosetting epoxy resin adhesive is used. The dispersion concentration of the conductive particles 12 dispersed in the insulating adhesive sheet 11 is changed according to the pattern width and height of the transparent electrode 14, and the insulating adhesive sheet 11
Is formed in a sheet shape so as to have a thickness corresponding to the particle diameter of the conductive particles 12.

【0014】このようにして構成された本発明の異方性
導電膜A1 は、可撓性樹脂からなる二つのベースフイル
ム13の上の透明電極14間に配置され、二つのベース
フイルム13の両側から加圧、加熱すると、図1(b)
に示されるように、エポキシ樹脂系の接着剤の粒子12
aと導電物質12bとからなる導電性粒子12は、透明
電極14との間で軟化変形すると共に、絶縁性接着剤シ
ート11は二つのベースフイルム13の間を結合して硬
化する。
The anisotropic conductive film A 1 of the present invention thus constructed is disposed between the transparent electrodes 14 on the two base films 13 made of a flexible resin, and the two base films 13 are formed. When pressurized and heated from both sides, Fig. 1 (b)
As shown in FIG.
The conductive particles 12 including a and the conductive material 12b are softened and deformed with the transparent electrode 14, and the insulating adhesive sheet 11 bonds between the two base films 13 and hardens.

【0015】よって、導電性粒子12は自己保持され、
絶縁性接着剤シート11の硬化により、導電性粒子12
の移動を防ぎ、ベースフイルムは結合する。そして、透
明電極に微小クラックが発生している場合において、本
発明の異方性導電膜A1 の導電性粒子12は前記クラッ
クの間に充填され、クラックの進行を抑え、断線を防止
する作用をもたらす。
Therefore, the conductive particles 12 are self-supported,
By curing the insulating adhesive sheet 11, the conductive particles 12
To prevent the movement of the base film. When the transparent electrode has micro cracks, the conductive particles 12 of the anisotropic conductive film A 1 of the present invention are filled between the cracks to suppress the progress of cracks and prevent disconnection. Bring

【0016】前記実施例において、異方性導電膜は、導
電性粒子12を絶縁性接着剤シート11に分散している
が、その絶縁性接着剤シートの代わりに、ゴム系接着剤
11Aを使用することができる。この実施例では、ゴム
系接着剤11Aの中に導電性粒子12を分散攪拌した
後、透明電極14を形成した可撓性樹脂からなるベース
フイルム13上に、図2に示すように、一定の厚みで印
刷し、しかる後、他方の透明電極14を形成したベース
フイルム13と重ね合わせ、加熱加圧して両ベースフイ
ルムを接合する。この場合においても、この接合時に、
透明電極表面に微小クラックが発生しても、導電性粒子
がクラック間に充填され、クラックの進行を抑え、断線
を防止する作用をもたらす。
In the above-mentioned embodiment, the anisotropic conductive film has the conductive particles 12 dispersed in the insulating adhesive sheet 11, but the rubber adhesive 11A is used in place of the insulating adhesive sheet. can do. In this embodiment, after the conductive particles 12 are dispersed and stirred in the rubber-based adhesive 11A, a fixed film is formed on the base film 13 made of a flexible resin on which the transparent electrode 14 is formed, as shown in FIG. After printing with a thickness, the base film 13 on which the other transparent electrode 14 is formed is superposed, and heated and pressed to bond both base films. Even in this case, at the time of this joining,
Even if a minute crack is generated on the surface of the transparent electrode, the conductive particles are filled in between the cracks, which suppresses the progress of the crack and prevents disconnection.

【0017】図3は本発明の他の異方性導電膜の実施例
を示す。図3(a)は圧着前の本発明の異方性導電膜そ
のものの断面形状を示し、その異方性導電膜が、夫々透
明電極(ITO)を形成した二つのベースフイルムの間
に圧着された後の状態の断面を図3(b)で示してい
る。
FIG. 3 shows another embodiment of the anisotropic conductive film of the present invention. FIG. 3A shows a cross-sectional shape of the anisotropic conductive film of the present invention itself before pressure bonding, and the anisotropic conductive film is pressure bonded between two base films each having a transparent electrode (ITO) formed thereon. FIG. 3B shows a cross section of the state after the heating.

【0018】本発明の異方性導電膜A2 は、熱硬化型の
エポキシ樹脂系の接着剤を絶縁性接着剤シート11と
し、この絶縁性接着剤シート11の中に、導電性粒子1
5が分散される構成からなり、その導電性粒子15は、
エポキシ樹脂系の粉末接着剤(例えば、東レ(株)製の
商品名「トレパールEP−AD)の粒子15aと、この
接着剤粒子12a表面に金属メッキ処理を施し、メッキ
皮膜15bとを設けたものである。前記メッキ皮膜15
bにより、導電性を有するものである。この場合、粉末
接着剤の粒子15aの平均粒子径が10μmであり、メ
ッキ皮膜15bの厚みは0.2μmとした。なお、メッ
キ皮膜15bの厚みは、他の条件に応じて0.1〜10
μm程度とすることができる。メッキ皮膜15bは、蒸
着手段により形成することも可能である。本発明の前記
異方性導電膜A2 において、絶縁性接着剤シート11の
中の導電性粒子15すなわちエポキシ樹脂系の粉末接着
剤の粒子15aは60〜80℃程度でガラス転移点に達
し、その後、硬化に到るものを使用される。
In the anisotropic conductive film A 2 of the present invention, a thermosetting epoxy resin adhesive is used as the insulating adhesive sheet 11, and the conductive particles 1 are contained in the insulating adhesive sheet 11.
5 is dispersed, and the conductive particles 15 are
Epoxy resin-based powder adhesive (for example, Toray Co., Ltd. trade name “Trepearl EP-AD”) particles 15a, and adhesive particles 12a whose surface is subjected to metal plating treatment and plated coating 15b is provided. The plating film 15
By b, it has conductivity. In this case, the particles 15a of the powder adhesive had an average particle diameter of 10 μm, and the plating film 15b had a thickness of 0.2 μm. The thickness of the plating film 15b is 0.1-10 depending on other conditions.
It can be about μm. The plating film 15b can also be formed by vapor deposition means. In the anisotropic conductive film A 2 of the present invention, the conductive particles 15 in the insulating adhesive sheet 11, that is, the particles 15a of the epoxy resin-based powder adhesive reach the glass transition point at about 60 to 80 ° C., After that, the one that reaches the curing is used.

【0019】このような異方性導電膜A2 を、可撓性樹
脂からなる二つのベースフイルムの上の透明電極13,
14間に設け、二つのベースフイルムの両側から加圧、
加熱すると、図3(b)に示されるように、エポキシ樹
脂系の粉末接着剤の粒子15aは変形し、その外側に位
置するメッキ皮膜15bは破れ、破れたメッキ皮膜15
bからエポキシ樹脂系の粉末状接着剤粒子15aが溶け
て出して硬化する。したがって、本発明の導電性粒子1
2のエポキシ樹脂系の粉末接着剤の粒子15aは柔らか
く変形しながら、破れたメッキ皮膜15bを剥離飛散す
ることなく、同時に変形するため、透明電極14の表面
を傷付けることがなく、ベースフイルム13間を接続す
ることができる。
Such an anisotropic conductive film A 2 is formed on the transparent electrodes 13 on two base films made of a flexible resin.
It is installed between 14 and pressure is applied from both sides of the two base films.
When heated, as shown in FIG. 3B, the particles 15a of the epoxy resin-based powder adhesive are deformed, the plating film 15b located outside thereof is broken, and the broken plating film 15 is broken.
The epoxy resin-based powdery adhesive particles 15a are melted and ejected from b to cure. Therefore, the conductive particles 1 of the present invention
The particles 15a of the epoxy resin-based powder adhesive of No. 2 are deformed softly, and at the same time, they are deformed without peeling and scattering the torn plating film 15b. Therefore, the surface of the transparent electrode 14 is not damaged and the base film 13 is not damaged. Can be connected.

【0020】そして、前記粉末状接着剤粒子12aはベ
ースフイルム13上の透明電極(ITO)14に固着す
ることにより、仮に、透明電極に微細なクラックが発生
した場合においても、粉末状接着剤粒子12aの接着機
能により、粉末状接着剤粒子12aはクラックの間に充
填され、クラックの進行を抑えることができる。そし
て、従来の金属粒子と比べて、本発明の導電性粒子12
は柔らかく、したがって、基板上の透明電極に対して変
形等の影響を与えることが少ない。
By adhering the powdery adhesive particles 12a to the transparent electrode (ITO) 14 on the base film 13, even if fine cracks are generated in the transparent electrode, the powdery adhesive particles 12a are formed. Due to the adhesive function of 12a, the powdery adhesive particles 12a are filled between the cracks, and the progress of the cracks can be suppressed. And compared with the conventional metal particles, the conductive particles 12 of the present invention
Is soft, and therefore, the transparent electrode on the substrate is rarely affected by deformation or the like.

【0021】本発明の異方性導電膜においては、絶縁性
接着剤シート11と、該絶縁性接着剤シート11の中に
分散して設けられた粉末状接着剤粒子12a,15aを
有する導電性粒子12,15とからなり、接着剤粒子1
2a,15aと絶縁性接着剤シート11の樹脂の性質と
して、熱可塑性又は熱硬化性のいずれを選んでもかまわ
ない。
In the anisotropic conductive film of the present invention, a conductive material having an insulating adhesive sheet 11 and powdery adhesive particles 12a and 15a dispersed in the insulating adhesive sheet 11 is provided. Adhesive particle 1 consisting of particles 12 and 15
As the properties of the resin of 2a, 15a and the insulating adhesive sheet 11, either thermoplasticity or thermosetting may be selected.

【0022】また、前記絶縁性接着樹脂シートを熱可塑
性接着剤とし、導電性接着剤の粒子を熱硬化性接着剤と
することにより、絶縁性接着樹脂シートの加熱温度を低
く設定することができ、樹脂材料からなるベースフイル
ムに与える温度の影響を小さくすることができ、更に、
リペアを行う場合、接着されたベースフイルムを剥離さ
せ易い。更に、前記絶縁性接着樹脂シートを熱硬化性接
着剤とし、導電性接着剤の粒子を熱可塑性接着剤とする
ことにより、絶縁性接着樹脂シートは耐熱温度をあげる
ことができ、信頼性が向上する。
By using the insulating adhesive resin sheet as a thermoplastic adhesive and the particles of the conductive adhesive as a thermosetting adhesive, the heating temperature of the insulating adhesive resin sheet can be set low. It is possible to reduce the effect of temperature on the base film made of resin material.
When repairing, the adhered base film is easily peeled off. Furthermore, by using the insulating adhesive resin sheet as a thermosetting adhesive and using the particles of the conductive adhesive as a thermoplastic adhesive, the insulating adhesive resin sheet can have a higher heat resistant temperature and improved reliability. To do.

【0023】[0023]

【発明の効果】本発明の構成により、絶縁性接着剤シー
トの中に分散した導電性粒子自体が接着剤として作用
し、且つ加圧加熱により変形するため、可撓性樹脂から
なるベースフイルムの上の透明電極を傷付けることなく
導通させ、微小クラックが発生しても、前記導電性粒子
が溶けて前記微小クラック間に入り込んで硬化するた
め、クラックの進行を阻止する効果を有する。
According to the constitution of the present invention, since the conductive particles themselves dispersed in the insulating adhesive sheet act as an adhesive and are deformed by pressure and heating, a base film made of a flexible resin is used. Even if the upper transparent electrode is brought into conduction without being damaged, and even if a minute crack is generated, the conductive particles are melted and enter between the minute cracks to be hardened, which has an effect of preventing the progress of the crack.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の異方性導電膜に関する第1の実施例で
あり、(a)は使用前の異方性導電膜の概略断面図、
(b)はベースフイルムの上の透明電極間において、加
圧加熱された状態を示す異方性導電膜の概略断面図であ
る。
FIG. 1 is a first embodiment of the anisotropic conductive film of the present invention, (a) is a schematic cross-sectional view of the anisotropic conductive film before use,
(B) is a schematic cross-sectional view of the anisotropic conductive film showing a state of being pressurized and heated between the transparent electrodes on the base film.

【図2】本発明の異方性導電膜の変形例をベースフイル
ムの上の透明電極端子に適用した概略断面図である。
FIG. 2 is a schematic cross-sectional view in which a modified example of the anisotropic conductive film of the present invention is applied to a transparent electrode terminal on a base film.

【図3】本発明の異方性導電膜に関する第2の実施例で
あり、(a)は使用前の異方性導電膜の概略断面図、
(b)はベースフイルムの上の透明電極間において、加
圧加熱された状態を示す異方性導電膜の概略断面図であ
る。
FIG. 3 is a second embodiment relating to the anisotropic conductive film of the present invention, (a) is a schematic sectional view of the anisotropic conductive film before use,
(B) is a schematic cross-sectional view of the anisotropic conductive film showing a state of being pressurized and heated between the transparent electrodes on the base film.

【図4】従来の印刷される形式の異方性導電膜を示す概
略断面図である。
FIG. 4 is a schematic sectional view showing an anisotropic conductive film of a conventional printed type.

【符号の説明】[Explanation of symbols]

1 ,A2 異方性導電膜 11 絶縁性接着剤シート 11A ゴム系接着剤 12 導電性粒子 12a 粉末状接着剤粒子 12b 混入された導電物質 13 ベースフイルム 14 透明電極 15 導電性粒子 15a 絶縁性粉末状接着剤粒子 15b メッキ皮膜A 1 , A 2 anisotropic conductive film 11 insulating adhesive sheet 11A rubber adhesive 12 conductive particles 12a powdered adhesive particles 12b mixed conductive material 13 base film 14 transparent electrode 15 conductive particles 15a insulating Powder adhesive particles 15b Plating film

フロントページの続き (72)発明者 鳴海 雄二 東京都大田区中馬込1丁目3番6号 株式 会社リコー内 (72)発明者 高橋 久雄 東京都大田区中馬込1丁目3番6号 株式 会社リコー内 (72)発明者 藤村 浩 東京都大田区中馬込1丁目3番6号 株式 会社リコー内 (72)発明者 坂寄 寛幸 東京都大田区中馬込1丁目3番6号 株式 会社リコー内Front Page Continuation (72) Inventor Yuji Narumi 1-3-6 Nakamagome, Ota-ku, Tokyo Within Ricoh Company (72) Inventor Hisao Takahashi 1-3-6 Nakamagome, Ota-ku, Tokyo Within Ricoh Company (72) Inventor Hiroshi Fujimura 1-3-6 Nakamagome, Ota-ku, Tokyo In Ricoh Co., Ltd. (72) Inventor Hiroyuki Sakayo 1-3-6 Nakamagome, Ota-ku, Tokyo In Ricoh Co., Ltd.

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 絶縁性接着樹脂シートの中に、導電性接
着剤の粒子を分散させたことを特徴とする異方性導電
膜。
1. An anisotropic conductive film in which particles of a conductive adhesive are dispersed in an insulating adhesive resin sheet.
【請求項2】 前記導電性接着剤の粒子として、絶縁性
接着剤に導電物質の粉末を混入したことを特徴とする請
求項1記載の異方性導電膜。
2. The anisotropic conductive film according to claim 1, wherein as the particles of the conductive adhesive, a powder of a conductive substance is mixed in an insulating adhesive.
【請求項3】 前記導電性接着剤の粒子として、絶縁性
接着剤の粒子の表面を金属皮膜で覆ったことを特徴とす
る請求項1記載の異方性導電膜。
3. The anisotropic conductive film according to claim 1, wherein, as the particles of the conductive adhesive, the surfaces of the particles of the insulating adhesive are covered with a metal film.
【請求項4】 前記絶縁性接着樹脂シートをゴム系接着
剤により構成したことを特徴とする請求項1記載の異方
性導電膜。
4. The anisotropic conductive film according to claim 1, wherein the insulating adhesive resin sheet is made of a rubber adhesive.
JP03303230A 1991-11-19 1991-11-19 Anisotropic conductive film Expired - Fee Related JP3100436B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP03303230A JP3100436B2 (en) 1991-11-19 1991-11-19 Anisotropic conductive film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP03303230A JP3100436B2 (en) 1991-11-19 1991-11-19 Anisotropic conductive film

Publications (2)

Publication Number Publication Date
JPH05142560A true JPH05142560A (en) 1993-06-11
JP3100436B2 JP3100436B2 (en) 2000-10-16

Family

ID=17918448

Family Applications (1)

Application Number Title Priority Date Filing Date
JP03303230A Expired - Fee Related JP3100436B2 (en) 1991-11-19 1991-11-19 Anisotropic conductive film

Country Status (1)

Country Link
JP (1) JP3100436B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012064559A (en) * 2010-08-16 2012-03-29 Nippon Shokubai Co Ltd Conductive fine particulate and anisotropic conductive material

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5143329B2 (en) * 2002-02-28 2013-02-13 日立化成工業株式会社 Manufacturing method of circuit connection body

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012064559A (en) * 2010-08-16 2012-03-29 Nippon Shokubai Co Ltd Conductive fine particulate and anisotropic conductive material

Also Published As

Publication number Publication date
JP3100436B2 (en) 2000-10-16

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