JPH049734B2 - - Google Patents
Info
- Publication number
- JPH049734B2 JPH049734B2 JP17845384A JP17845384A JPH049734B2 JP H049734 B2 JPH049734 B2 JP H049734B2 JP 17845384 A JP17845384 A JP 17845384A JP 17845384 A JP17845384 A JP 17845384A JP H049734 B2 JPH049734 B2 JP H049734B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- ions
- metal
- formula
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 metal complex ions Chemical class 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- 150000003863 ammonium salts Chemical class 0.000 claims description 12
- 229910021645 metal ion Inorganic materials 0.000 claims description 12
- 239000003960 organic solvent Substances 0.000 claims description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 11
- 229910052731 fluorine Inorganic materials 0.000 claims description 11
- 239000011737 fluorine Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 229910052787 antimony Inorganic materials 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 8
- 229910052733 gallium Inorganic materials 0.000 claims description 8
- 229910052735 hafnium Inorganic materials 0.000 claims description 8
- 229910052741 iridium Inorganic materials 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 229910052718 tin Inorganic materials 0.000 claims description 8
- 229910052732 germanium Inorganic materials 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 125000003158 alcohol group Chemical group 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 4
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 2
- 125000004185 ester group Chemical group 0.000 claims description 2
- 125000000468 ketone group Chemical group 0.000 claims description 2
- 125000003544 oxime group Chemical group 0.000 claims description 2
- 230000001172 regenerating effect Effects 0.000 claims description 2
- 125000000101 thioether group Chemical group 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 229910052745 lead Inorganic materials 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 239000002994 raw material Substances 0.000 description 7
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 6
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 5
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 150000002923 oximes Chemical class 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical group 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- RJYDMIMSSMCNIG-UHFFFAOYSA-N (2-octylphenyl) dihydrogen phosphate Chemical compound CCCCCCCCC1=CC=CC=C1OP(O)(O)=O RJYDMIMSSMCNIG-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910017855 NH 4 F Inorganic materials 0.000 description 1
- 229910018286 SbF 6 Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical class [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17845384A JPS6158814A (ja) | 1984-08-29 | 1984-08-29 | フツ素含有金属アンモニウム塩の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17845384A JPS6158814A (ja) | 1984-08-29 | 1984-08-29 | フツ素含有金属アンモニウム塩の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6158814A JPS6158814A (ja) | 1986-03-26 |
| JPH049734B2 true JPH049734B2 (enrdf_load_stackoverflow) | 1992-02-21 |
Family
ID=16048779
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17845384A Granted JPS6158814A (ja) | 1984-08-29 | 1984-08-29 | フツ素含有金属アンモニウム塩の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6158814A (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5788948A (en) * | 1993-10-22 | 1998-08-04 | The University Of Melbourne | Process for the production of fluorometallate salts useful in the processing of mineral sands and related materials |
-
1984
- 1984-08-29 JP JP17845384A patent/JPS6158814A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6158814A (ja) | 1986-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3211521A (en) | Process for removing iron from acidic aluminum-containing solutions | |
| US4741893A (en) | Process for producing fluorides of metals | |
| MX2012000233A (es) | Procesos para recuperar metales de las soluciones acuosas. | |
| JPH0328376B2 (enrdf_load_stackoverflow) | ||
| JPH10235102A (ja) | 金属元素の溶媒抽出法 | |
| CA1190048A (en) | Selective solvent extraction using organophosphorus and carboxylic acids | |
| US4397682A (en) | Process for preparing metals from their fluorine-containing compounds | |
| CN112662872A (zh) | 一种含草酸溶液的萃取方法 | |
| EP0301783A2 (en) | Method for the recovery of metals from chloride solutions | |
| EP0134643A2 (en) | Preparing metallic zirconium, hafnium or titanium | |
| CA1199501A (en) | Recovery process of uranium | |
| JPH049734B2 (enrdf_load_stackoverflow) | ||
| JPS5812323B2 (ja) | 金属鉄の回収方法 | |
| US3700415A (en) | Vanadium recovery from wet process phosphoric acid using neutral organophosphorus extractants | |
| Stenström et al. | Extraction of cadmium from phosphoric acid solutions with amines Part I. Extractant selection, stripping, scrubbing and effects of other components | |
| AU600541B2 (en) | A process for the production of high quality titanium dioxide by the sulfate method | |
| JPH0148202B2 (enrdf_load_stackoverflow) | ||
| US3243254A (en) | Method for extracting lanthanides and actinides | |
| US3854851A (en) | Method for separating nickel from cobalt in aqueous solution | |
| JPH0225841B2 (enrdf_load_stackoverflow) | ||
| EP0046973B1 (en) | Process for the production of high-purity iron oxide | |
| JP2822183B2 (ja) | 水溶液中の有機リン化合物の回収方法 | |
| JPH0662300B2 (ja) | イットリウムの分離方法 | |
| JPH0234889B2 (ja) | Kinzokufutsukabutsunoseizohoho | |
| Van der Westhuizen et al. | Solvent extraction separation of zirconium (IV) and hafnium (IV) as chloride and fluoride feedstock solutions using amine extractants |