JPH0454613B2 - - Google Patents
Info
- Publication number
- JPH0454613B2 JPH0454613B2 JP59259867A JP25986784A JPH0454613B2 JP H0454613 B2 JPH0454613 B2 JP H0454613B2 JP 59259867 A JP59259867 A JP 59259867A JP 25986784 A JP25986784 A JP 25986784A JP H0454613 B2 JPH0454613 B2 JP H0454613B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- slurry
- red phosphorus
- titanium
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 96
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 72
- 229920005989 resin Polymers 0.000 claims description 68
- 239000011347 resin Substances 0.000 claims description 68
- 239000002245 particle Substances 0.000 claims description 44
- 239000002002 slurry Substances 0.000 claims description 44
- 239000004408 titanium dioxide Substances 0.000 claims description 33
- 239000003822 epoxy resin Substances 0.000 claims description 30
- 229920000647 polyepoxide Polymers 0.000 claims description 30
- 229920000877 Melamine resin Polymers 0.000 claims description 21
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- 239000010936 titanium Substances 0.000 claims description 10
- 150000003609 titanium compounds Chemical class 0.000 claims description 10
- 235000011007 phosphoric acid Nutrition 0.000 claims description 8
- 238000000151 deposition Methods 0.000 claims description 7
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 claims description 6
- 229910000348 titanium sulfate Inorganic materials 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 229910052719 titanium Inorganic materials 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 230000008021 deposition Effects 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 6
- 238000001035 drying Methods 0.000 claims 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 44
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 230000003647 oxidation Effects 0.000 description 14
- 238000007254 oxidation reaction Methods 0.000 description 14
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 229910010413 TiO 2 Inorganic materials 0.000 description 12
- 230000001590 oxidative effect Effects 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 8
- 238000001723 curing Methods 0.000 description 8
- 239000004640 Melamine resin Substances 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 6
- 230000006641 stabilisation Effects 0.000 description 6
- 238000011105 stabilization Methods 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 5
- 239000004593 Epoxy Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 229910018626 Al(OH) Inorganic materials 0.000 description 3
- -1 aliphatic polyols Chemical class 0.000 description 3
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 3
- 150000003016 phosphoric acids Chemical class 0.000 description 3
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229920003180 amino resin Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- VGGLHLAESQEWCR-UHFFFAOYSA-N N-(hydroxymethyl)urea Chemical compound NC(=O)NCO VGGLHLAESQEWCR-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 229920003265 Resimene® Polymers 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001688 coating polymer Polymers 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/003—Phosphorus
- C01B25/006—Stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA442810 | 1983-12-08 | ||
| CA000442810A CA1214314A (en) | 1983-12-08 | 1983-12-08 | Stabilization of red phosphorus |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60141609A JPS60141609A (ja) | 1985-07-26 |
| JPH0454613B2 true JPH0454613B2 (es) | 1992-08-31 |
Family
ID=4126693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59259867A Granted JPS60141609A (ja) | 1983-12-08 | 1984-12-08 | 赤リン含有組成物及びその製法 |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS60141609A (es) |
| CA (1) | CA1214314A (es) |
| DE (1) | DE3444539C2 (es) |
| GB (1) | GB2150925B (es) |
| IT (1) | IT1179852B (es) |
| SE (1) | SE461332B (es) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52125489A (en) * | 1976-04-08 | 1977-10-21 | Phosphorus Chem Ind | Method of reforming red phosphorus |
| JPS52131695A (en) * | 1976-04-27 | 1977-11-04 | Nippon Chemical Ind | Flame resisting thermosetting resin composition |
| JPS5420225A (en) * | 1977-07-15 | 1979-02-15 | Nissan Motor Co Ltd | Sucked air amount compensating device |
| JPS5439200A (en) * | 1977-09-02 | 1979-03-26 | Hitachi Ltd | Automatic vender |
| JPS5510462A (en) * | 1978-07-11 | 1980-01-24 | Nippon Chem Ind Co Ltd:The | Modified red phosphorus and production thereof |
| JPS5673606A (en) * | 1979-11-08 | 1981-06-18 | Hoechst Ag | Stabilized powdery red phosphorus and its manufacture |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1880538A (en) * | 1931-02-27 | 1932-10-04 | Coronet Phosphate Company | Protection of phosphorus |
| DE2249638B2 (de) * | 1972-10-11 | 1981-01-15 | Hoechst Ag, 6000 Frankfurt | Phlegmatisierter roter Phosphor |
| JPS51105996A (en) * | 1975-03-14 | 1976-09-20 | Phosphorus Chem Ind | Sekirinno kaishitsuhoho |
| US4208317A (en) * | 1975-06-10 | 1980-06-17 | Rhone-Poulenc Industries | Flameproofed plastic compositions |
| FR2314219A1 (fr) * | 1975-06-10 | 1977-01-07 | Rhone Poulenc Ind | Compositions destinees a l'ignifugation de matieres plastiques |
| FR2314221A1 (fr) * | 1975-06-10 | 1977-01-07 | Rhone Poulenc Ind | Compositions destinees a l'ignifugation de matieres plastiques |
| FR2344615A1 (fr) * | 1976-03-19 | 1977-10-14 | Rhone Poulenc Ind | Compositions destinees a l'ignifugation de matieres plastiques |
| DE2631532C2 (de) * | 1976-07-14 | 1984-09-13 | Hoechst Ag, 6230 Frankfurt | Stabilisierter pulverförmiger roter Phosphor sowie Verfahren zu seiner Herstellung |
| GB1526367A (en) * | 1976-10-12 | 1978-09-27 | Ici Ltd | Polypeptide |
| DE2647093C2 (de) * | 1976-10-19 | 1984-12-06 | Hoechst Ag, 6230 Frankfurt | Stabilisierter pulverförmiger roter Phosphor sowie Verfahren zu seiner Herstellung |
| DE2813151A1 (de) * | 1978-03-25 | 1979-09-27 | Hoechst Ag | Stabilisierter roter phosphor |
| CA1178788A (en) * | 1982-06-29 | 1984-12-04 | Erco Industries Limited | Stabilization of red phosphorus |
-
1983
- 1983-12-08 CA CA000442810A patent/CA1214314A/en not_active Expired
-
1984
- 1984-11-21 GB GB08429424A patent/GB2150925B/en not_active Expired
- 1984-12-06 DE DE3444539A patent/DE3444539C2/de not_active Expired
- 1984-12-07 IT IT68221/84A patent/IT1179852B/it active
- 1984-12-07 SE SE8406231A patent/SE461332B/sv not_active IP Right Cessation
- 1984-12-08 JP JP59259867A patent/JPS60141609A/ja active Granted
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52125489A (en) * | 1976-04-08 | 1977-10-21 | Phosphorus Chem Ind | Method of reforming red phosphorus |
| JPS52131695A (en) * | 1976-04-27 | 1977-11-04 | Nippon Chemical Ind | Flame resisting thermosetting resin composition |
| JPS5420225A (en) * | 1977-07-15 | 1979-02-15 | Nissan Motor Co Ltd | Sucked air amount compensating device |
| JPS5439200A (en) * | 1977-09-02 | 1979-03-26 | Hitachi Ltd | Automatic vender |
| JPS5510462A (en) * | 1978-07-11 | 1980-01-24 | Nippon Chem Ind Co Ltd:The | Modified red phosphorus and production thereof |
| JPS5673606A (en) * | 1979-11-08 | 1981-06-18 | Hoechst Ag | Stabilized powdery red phosphorus and its manufacture |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2150925B (en) | 1987-09-30 |
| DE3444539C2 (de) | 1987-04-02 |
| SE461332B (sv) | 1990-02-05 |
| DE3444539A1 (de) | 1985-06-13 |
| JPS60141609A (ja) | 1985-07-26 |
| CA1214314A (en) | 1986-11-25 |
| SE8406231L (sv) | 1985-06-09 |
| IT1179852B (it) | 1987-09-16 |
| IT8468221A1 (it) | 1986-06-07 |
| IT8468221A0 (it) | 1984-12-07 |
| SE8406231D0 (sv) | 1984-12-07 |
| GB2150925A (en) | 1985-07-10 |
| GB8429424D0 (en) | 1985-01-03 |
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