JPH041739B2 - - Google Patents
Info
- Publication number
- JPH041739B2 JPH041739B2 JP18009283A JP18009283A JPH041739B2 JP H041739 B2 JPH041739 B2 JP H041739B2 JP 18009283 A JP18009283 A JP 18009283A JP 18009283 A JP18009283 A JP 18009283A JP H041739 B2 JPH041739 B2 JP H041739B2
- Authority
- JP
- Japan
- Prior art keywords
- sulfonate
- carboxylic acid
- reaction
- acid
- acyloxybenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 claims description 64
- 238000006243 chemical reaction Methods 0.000 claims description 60
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 37
- 239000002253 acid Substances 0.000 claims description 31
- 239000003054 catalyst Substances 0.000 claims description 30
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 24
- 230000008569 process Effects 0.000 claims description 24
- 239000011541 reaction mixture Substances 0.000 claims description 23
- -1 alkali metal salt Chemical class 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 18
- 239000007787 solid Substances 0.000 claims description 16
- 238000005809 transesterification reaction Methods 0.000 claims description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 150000001735 carboxylic acids Chemical class 0.000 claims description 11
- 229940044652 phenolsulfonate Drugs 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000006227 byproduct Substances 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 9
- 150000008064 anhydrides Chemical class 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 238000010992 reflux Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- VILAVOFMIJHSJA-UHFFFAOYSA-N dicarbon monoxide Chemical compound [C]=C=O VILAVOFMIJHSJA-UHFFFAOYSA-N 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000011065 in-situ storage Methods 0.000 claims description 5
- 159000000000 sodium salts Chemical class 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000006228 supernatant Substances 0.000 claims description 4
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 239000012298 atmosphere Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 150000008065 acid anhydrides Chemical class 0.000 claims 1
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 27
- 239000000047 product Substances 0.000 description 21
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 239000007795 chemical reaction product Substances 0.000 description 13
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 239000001632 sodium acetate Substances 0.000 description 12
- 235000017281 sodium acetate Nutrition 0.000 description 12
- 150000007513 acids Chemical class 0.000 description 11
- 229940087596 sodium phenolsulfonate Drugs 0.000 description 11
- 238000004821 distillation Methods 0.000 description 10
- BLXAGSNYHSQSRC-UHFFFAOYSA-M sodium;2-hydroxybenzenesulfonate Chemical compound [Na+].OC1=CC=CC=C1S([O-])(=O)=O BLXAGSNYHSQSRC-UHFFFAOYSA-M 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 239000012429 reaction media Substances 0.000 description 9
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000000376 reactant Substances 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- 239000003599 detergent Substances 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 239000012530 fluid Substances 0.000 description 6
- XMIIGOLPHOKFCH-UHFFFAOYSA-N 3-phenylpropionic acid Chemical group OC(=O)CCC1=CC=CC=C1 XMIIGOLPHOKFCH-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 125000002252 acyl group Chemical group 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 235000019645 odor Nutrition 0.000 description 5
- 150000004967 organic peroxy acids Chemical class 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 238000006136 alcoholysis reaction Methods 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 150000004965 peroxy acids Chemical class 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- RPQSWSMNPBZEHT-UHFFFAOYSA-M sodium;2-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=CC=C1S([O-])(=O)=O RPQSWSMNPBZEHT-UHFFFAOYSA-M 0.000 description 4
- OILUAKBAMVLXGF-UHFFFAOYSA-N 3,5,5-trimethyl-hexanoic acid Chemical compound OC(=O)CC(C)CC(C)(C)C OILUAKBAMVLXGF-UHFFFAOYSA-N 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000001266 acyl halides Chemical class 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 150000003871 sulfonates Chemical class 0.000 description 3
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 2
- LZBBEECOKDJNLB-UHFFFAOYSA-N 3-phenylpropanoic acid Chemical group OC(=O)CCC1=CC=CC=C1.OC(=O)CCC1=CC=CC=C1 LZBBEECOKDJNLB-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 239000012433 hydrogen halide Substances 0.000 description 2
- 229910000039 hydrogen halide Inorganic materials 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000005580 one pot reaction Methods 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical class [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- VBDFPNJHQVMOPA-UHFFFAOYSA-N 2-acetyloxybenzenesulfonic acid Chemical compound CC(=O)OC1=CC=CC=C1S(O)(=O)=O VBDFPNJHQVMOPA-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 208000034809 Product contamination Diseases 0.000 description 1
- 238000006853 Ziegler synthesis reaction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 125000004423 acyloxy group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 150000002531 isophthalic acids Chemical class 0.000 description 1
- ZUBZATZOEPUUQF-UHFFFAOYSA-N isopropylhexane Natural products CCCCCCC(C)C ZUBZATZOEPUUQF-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- JFOJYGMDZRCSPA-UHFFFAOYSA-J octadecanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JFOJYGMDZRCSPA-UHFFFAOYSA-J 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000013587 production medium Substances 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- YDLQSTFHBCVEJV-UHFFFAOYSA-M sodium;2-(3,5,5-trimethylhexanoyloxy)benzenesulfonate Chemical compound [Na+].CC(C)(C)CC(C)CC(=O)OC1=CC=CC=C1S([O-])(=O)=O YDLQSTFHBCVEJV-UHFFFAOYSA-M 0.000 description 1
- PHIMXFJEDZOCMI-UHFFFAOYSA-M sodium;2-hexanoyloxy-3,4,5-trimethylbenzenesulfonate Chemical compound [Na+].CCCCCC(=O)OC1=C(C)C(C)=C(C)C=C1S([O-])(=O)=O PHIMXFJEDZOCMI-UHFFFAOYSA-M 0.000 description 1
- ZHVCSGCGBCHVLW-UHFFFAOYSA-M sodium;3,5,5-trimethylhexanoate Chemical compound [Na+].[O-]C(=O)CC(C)CC(C)(C)C ZHVCSGCGBCHVLW-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- LTOCMXUTASYUOC-UHFFFAOYSA-M sodium;nonanoate Chemical compound [Na+].CCCCCCCCC([O-])=O LTOCMXUTASYUOC-UHFFFAOYSA-M 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003504 terephthalic acids Chemical class 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
çºæã®åé
æ¬çºæã¯ãããšããŒã«ãšã¹ãã«ã®ãšã¹ãã«äº€æ
ã«é¢ããæŽã«è©³çŽ°ã«ã¯ã¹ã«ãã³åããšããŒã«ãšã¹
ãã«ã®ãšã¹ãã«äº€ææ³ã«é¢ãããã¹ã«ãã³åããš
ããŒã«ãšã¹ãã«ã¯ãæè¬æŒçœå€æŽ»æ§å€ãšããŠãæŽ
ã«æ£ç¢ºã«ã¯ææ©ãã«ãªãã·é žåé§ç©è³ªãšããŠç¹åŸŽ
ã¥ãããããæŽå€çµæç©ã«äœ¿çšããã®ã«å¥œé©ãªçš®
é¡ã®ç©è³ªãããªãããããã®åé§ç©è³ªã¯ã氎溶液
äžã§ãæŽå€çµæç©ã«éåžžé åãããç¡æ©éé žçŽ æŒ
çœå€ãäŸãã°éããŠé žå¡©ãŸãã¯éçé žå¡©ãšåå¿ã
ãŠãäœæž©ïŒïŒ70âïŒã§ç¡æ©ãã«ãªãã·å¡©ãããã
ãªãæå¹ãªæŒçœå€ã§ããææ©ãã«ãªãã·é žãçæ
ããã
ã«é¢ããæŽã«è©³çŽ°ã«ã¯ã¹ã«ãã³åããšããŒã«ãšã¹
ãã«ã®ãšã¹ãã«äº€ææ³ã«é¢ãããã¹ã«ãã³åããš
ããŒã«ãšã¹ãã«ã¯ãæè¬æŒçœå€æŽ»æ§å€ãšããŠãæŽ
ã«æ£ç¢ºã«ã¯ææ©ãã«ãªãã·é žåé§ç©è³ªãšããŠç¹åŸŽ
ã¥ãããããæŽå€çµæç©ã«äœ¿çšããã®ã«å¥œé©ãªçš®
é¡ã®ç©è³ªãããªãããããã®åé§ç©è³ªã¯ã氎溶液
äžã§ãæŽå€çµæç©ã«éåžžé åãããç¡æ©éé žçŽ æŒ
çœå€ãäŸãã°éããŠé žå¡©ãŸãã¯éçé žå¡©ãšåå¿ã
ãŠãäœæž©ïŒïŒ70âïŒã§ç¡æ©ãã«ãªãã·å¡©ãããã
ãªãæå¹ãªæŒçœå€ã§ããææ©ãã«ãªãã·é žãçæ
ããã
çºæã®èæ¯
ã¹ã«ãã³åããšããŒã«ãšã¹ãã«ã®éåžžã®åææ³
ã¯ã溶åªãäŸãã°ãžãªããµã³ãŸãã¯ãžã¯ãã«ãšã¿
ã³äžã§ããšããŒã«ã¹ã«ãã³é žå¡©ãããã²ã³åã¢ã·
ã«ïŒéåžžãå¡©åç©ïŒã§ã¢ã·ã«åããããã²ã³åæ°Ž
çŽ ãæé€ããããšãå å«ããããããããã®æ¹æ³
ã¯ãæ°çš®ã®äžå©ããããããåºçºããã²ã³åã¢ã·
ã«ã¯ãããèªäœå€éã«åãæ±ãã®ãå°é£ã§äžå¿«ãª
ç©è³ªã§ããããããŠåå¿ã®å¯çç©ããã²ã³åæ°ŽçŽ
ã«ããè é£æ»æã«èããã®ã«å¿ èŠãªè£ 眮ã¯ãé«äŸ¡
ã§ãããæŽã«å¥ã®åé¡ã¯ãåå¿ç³»ããã®ããã²ã³
åæ°ŽçŽ ã®æé€ã«ãããŠçãããããã¯ãéåžžãäž
掻æ§ã¬ã¹ã¹ããŒãžã³ã°ç³»ã«ãã€ãŠå®æœããããã
æžæ¿åºäœåå¿çæç©ãåå¿æ··åç©ã®çºæ³¡ãçãã
ããåŸåããã³æº¶åªããã³ïŒãŸãã¯ïŒããã²ã³å
ã¢ã·ã«ã®é€å»ãåé¿ããå¿ èŠæ§ã¯ãã¬ã¹æµéãå¶
éããããæ é€å»ã®å®å šããå¶éãããHClãå
åã«é€å»ãããªãå Žåã«ã¯ããããªãŠã ã€ãªã³ã«
察ããŠã¹ã«ãããŒãåºãšã®ç«¶äºããããå¡©åãã
ãªãŠã ããã³çæç©ã®äœãå®å®ã§ã¯ãªãã¹ã«ãã³
é žåœ¢æ ã®äž¡æ¹ãçæããããæåŸã«ã倧ã¹ã±ãŒã«
ã§ã®åå¿ã®å®æœã¯åå¿ã®å®å šãã«æªåœ±é¿ãæãã
ãããããããŠ70ïŒ ãè¶ ãã転åçã¯åŸãã®ãå°
é£ã§ããã
ã¯ã溶åªãäŸãã°ãžãªããµã³ãŸãã¯ãžã¯ãã«ãšã¿
ã³äžã§ããšããŒã«ã¹ã«ãã³é žå¡©ãããã²ã³åã¢ã·
ã«ïŒéåžžãå¡©åç©ïŒã§ã¢ã·ã«åããããã²ã³åæ°Ž
çŽ ãæé€ããããšãå å«ããããããããã®æ¹æ³
ã¯ãæ°çš®ã®äžå©ããããããåºçºããã²ã³åã¢ã·
ã«ã¯ãããèªäœå€éã«åãæ±ãã®ãå°é£ã§äžå¿«ãª
ç©è³ªã§ããããããŠåå¿ã®å¯çç©ããã²ã³åæ°ŽçŽ
ã«ããè é£æ»æã«èããã®ã«å¿ èŠãªè£ 眮ã¯ãé«äŸ¡
ã§ãããæŽã«å¥ã®åé¡ã¯ãåå¿ç³»ããã®ããã²ã³
åæ°ŽçŽ ã®æé€ã«ãããŠçãããããã¯ãéåžžãäž
掻æ§ã¬ã¹ã¹ããŒãžã³ã°ç³»ã«ãã€ãŠå®æœããããã
æžæ¿åºäœåå¿çæç©ãåå¿æ··åç©ã®çºæ³¡ãçãã
ããåŸåããã³æº¶åªããã³ïŒãŸãã¯ïŒããã²ã³å
ã¢ã·ã«ã®é€å»ãåé¿ããå¿ èŠæ§ã¯ãã¬ã¹æµéãå¶
éããããæ é€å»ã®å®å šããå¶éãããHClãå
åã«é€å»ãããªãå Žåã«ã¯ããããªãŠã ã€ãªã³ã«
察ããŠã¹ã«ãããŒãåºãšã®ç«¶äºããããå¡©åãã
ãªãŠã ããã³çæç©ã®äœãå®å®ã§ã¯ãªãã¹ã«ãã³
é žåœ¢æ ã®äž¡æ¹ãçæããããæåŸã«ã倧ã¹ã±ãŒã«
ã§ã®åå¿ã®å®æœã¯åå¿ã®å®å šãã«æªåœ±é¿ãæãã
ãããããããŠ70ïŒ ãè¶ ãã転åçã¯åŸãã®ãå°
é£ã§ããã
ã¹ã«ãã³åããšããŒã«ãšã¹ãã«ãç¹ã«é·éã¢ã·
ã«åºãæãããã®ã®åæã®å¥ã®ã«ãŒãã¯ããšã¹ã
ã«äº€æã§ãããããã¯ãææ©ååç©éã®ãšã¹ãã«
åºã亀æããè¯ã確ç«ãããæ¹æ³ã§ããããããŠ
ã¢ã«ã³ãŒãªã·ã¹ãã¢ã·ããªã·ã¹ãŸãã¯ãšã¹ãã«â
ãšã¹ãã«çžäºäº€æã«ãã€ãŠéæããåŸããâOH
åºå«æååç©ãææã®ã¢ã·ã«åºãæããäœçŽã¢ã«
ãã«ãšã¹ãã«ãšåå¿ãããã¢ã«ã³ãŒãªã·ã¹ã¯ãæ
ããã°ãã°äœ¿çšãããæè¡ã§ãããã¢ã·ããªã·ã¹
ã¯ãéåžžäœã䜿çšãããããããŠäœçŽã¢ã«ãã«ãš
ã¹ãã«åºãæããååç©ãšé©åœãªã«ã«ãã³é žãšã®
éã®åå¿ãå å«ããããšã¹ãã«äº€æã¯ããã®çšèª
ã瀺åããããã«ãåã«ååç©éã®ãšã¹ãã«åºã®
亀æã§ããã
ã«åºãæãããã®ã®åæã®å¥ã®ã«ãŒãã¯ããšã¹ã
ã«äº€æã§ãããããã¯ãææ©ååç©éã®ãšã¹ãã«
åºã亀æããè¯ã確ç«ãããæ¹æ³ã§ããããããŠ
ã¢ã«ã³ãŒãªã·ã¹ãã¢ã·ããªã·ã¹ãŸãã¯ãšã¹ãã«â
ãšã¹ãã«çžäºäº€æã«ãã€ãŠéæããåŸããâOH
åºå«æååç©ãææã®ã¢ã·ã«åºãæããäœçŽã¢ã«
ãã«ãšã¹ãã«ãšåå¿ãããã¢ã«ã³ãŒãªã·ã¹ã¯ãæ
ããã°ãã°äœ¿çšãããæè¡ã§ãããã¢ã·ããªã·ã¹
ã¯ãéåžžäœã䜿çšãããããããŠäœçŽã¢ã«ãã«ãš
ã¹ãã«åºãæããååç©ãšé©åœãªã«ã«ãã³é žãšã®
éã®åå¿ãå å«ããããšã¹ãã«äº€æã¯ããã®çšèª
ã瀺åããããã«ãåã«ååç©éã®ãšã¹ãã«åºã®
亀æã§ããã
ãããã®ãã¹ãŠã®åå¿ã¯éåžžæ¥è§Šäœçšãåãã
ãããŠåäžåããã³äžåäžåã®äž¡æ¹ã®åºç¯å²ã®é ž
觊åªããã³å¡©åºè§Šåªã¯ãåŸæ¥æè¡ã«ãã€ãŠäžè¬ç
å¿çšæ§ãæãããšé瀺ãããŠããããå€æ°ã®åå¿
ç³»ã¯ã觊åªç¹ç°æ§ã§ããããšãèŠãåºãããŠã
ãã
ãããŠåäžåããã³äžåäžåã®äž¡æ¹ã®åºç¯å²ã®é ž
觊åªããã³å¡©åºè§Šåªã¯ãåŸæ¥æè¡ã«ãã€ãŠäžè¬ç
å¿çšæ§ãæãããšé瀺ãããŠããããå€æ°ã®åå¿
ç³»ã¯ã觊åªç¹ç°æ§ã§ããããšãèŠãåºãããŠã
ãã
ããšããŒã«ãšã¹ãã«ã®ãšã¹ãã«äº€æã¯ãéåžžã¢
ã«ã³ãŒãªã·ã¹ã«ãã€ãŠå®æœãããããã¹ã«ãã³å
ããšããŒã«ãšã¹ãã«ã®å Žåã«ãã®æ¹æ³ã䜿çšãã
ãšå°é£ãããããã第äžã«ãã¹ã«ãã³åèªå°äœ
ã¯ã芪氎æ§ã§ãããããæ ãã®çš®ã®ãšã¹ãã«äº€æ
åå¿ã«äœ¿çšãããæ¯èŒçé極æ§ã®åå¿åªäœãäŸã
ã°ã¢ã«ã³ãŒã«ããã³çåæ°ŽçŽ ã«äžæº¶æ§ã§ããã
ã«ã³ãŒãªã·ã¹ã«ãã€ãŠå®æœãããããã¹ã«ãã³å
ããšããŒã«ãšã¹ãã«ã®å Žåã«ãã®æ¹æ³ã䜿çšãã
ãšå°é£ãããããã第äžã«ãã¹ã«ãã³åèªå°äœ
ã¯ã芪氎æ§ã§ãããããæ ãã®çš®ã®ãšã¹ãã«äº€æ
åå¿ã«äœ¿çšãããæ¯èŒçé極æ§ã®åå¿åªäœãäŸã
ã°ã¢ã«ã³ãŒã«ããã³çåæ°ŽçŽ ã«äžæº¶æ§ã§ããã
第äºã«ãã¹ã«ãããŒãåºã®ååšã¯ãããšããŒã«
ã®âOHåºã倱掻ããåŸåããããå¯åå¿ããã³
çæç©å£åã®å±éºã®å¢å€§ã®ããåå¿é床è«ã«æªåœ±
é¿ãåãŒãããããŠé«ãåå¿å®å šããéæããã®
ãå°é£ã«ããããåå¿é床ãå¢å€§ãããããã®é«
æž©ã®äœ¿çšã¯ãåã«ãããã®åé¡ãæªåãããåå¿
æ··åç©ã®é床ã®çåãããããã
ã®âOHåºã倱掻ããåŸåããããå¯åå¿ããã³
çæç©å£åã®å±éºã®å¢å€§ã®ããåå¿é床è«ã«æªåœ±
é¿ãåãŒãããããŠé«ãåå¿å®å šããéæããã®
ãå°é£ã«ããããåå¿é床ãå¢å€§ãããããã®é«
æž©ã®äœ¿çšã¯ãåã«ãããã®åé¡ãæªåãããåå¿
æ··åç©ã®é床ã®çåãããããã
ä»æ¹ã®ãšã¹ãã«äžã®äœçŽã¢ã«ãã«åºãåå¿æã«
åå¿æ¡ä»¶äžã§å®¹æã«ã¯çœ®æãããªãã®ã§ããšã¹ã
ã«äº€ææ³ãã¹ã«ãã³åããšããŒã«ãšã¹ãã«ã®å Žå
ã«ã¯äžæåã§ããã
åå¿æ¡ä»¶äžã§å®¹æã«ã¯çœ®æãããªãã®ã§ããšã¹ã
ã«äº€ææ³ãã¹ã«ãã³åããšããŒã«ãšã¹ãã«ã®å Žå
ã«ã¯äžæåã§ããã
ã¢ã·ããªã·ã¹ã¯ãè³éŠæé
žã®ã¢ãªãŒã«ãšã¹ãã«
ã®çæã«ãããŠæå¹ãªãšã¹ãã«äº€ææè¡ã§ãããš
ææ¡ãããŠããããããŠè³éŠæãžã«ã«ãã³é žãç¹
ã«ã€ãœãã¿ã«é žããã³ãã¬ãã¿ã«é žã®ããšãã«ãš
ã¹ãã«ããã³ã¯ã¬ã·ã«ãšã¹ãã«ã®çæã«ãããã¢
ã·ããªã·ã¹äœ¿çšã®é瀺ã¯ãè±åœç¹èš±ç¬¬1009484å·
æ现æžã«äžããããŠããããã®ç¹èš±ã¯ããšã¹ãã«
亀æåå¿çšã®åºçºææãšããŠã®äœçŽã¢ã·ã«è³éŠæ
ãšã¹ãã«ã®ãã®å Žçæãæ瀺ããŠããã
ã®çæã«ãããŠæå¹ãªãšã¹ãã«äº€ææè¡ã§ãããš
ææ¡ãããŠããããããŠè³éŠæãžã«ã«ãã³é žãç¹
ã«ã€ãœãã¿ã«é žããã³ãã¬ãã¿ã«é žã®ããšãã«ãš
ã¹ãã«ããã³ã¯ã¬ã·ã«ãšã¹ãã«ã®çæã«ãããã¢
ã·ããªã·ã¹äœ¿çšã®é瀺ã¯ãè±åœç¹èš±ç¬¬1009484å·
æ现æžã«äžããããŠããããã®ç¹èš±ã¯ããšã¹ãã«
亀æåå¿çšã®åºçºææãšããŠã®äœçŽã¢ã·ã«è³éŠæ
ãšã¹ãã«ã®ãã®å Žçæãæ瀺ããŠããã
ããã«ãæãããè±åœç¹èš±ç¬¬1009484å·æ现æž
ã«é瀺ã®æ¹æ³ã¯ããèªäœå¥œé©ã§ãããšäžè¬ã«æ瀺
ãããŠãã觊åªãæ¯èŒçç¹ç°æ§ã§ããïŒæãå Žå
ã«ã¯æå¹ã§ãããä»ã®å Žåã«ã¯æå¹ã§ã¯ãªããšèš
èŒãããŠããïŒç¹ã«ãããŠå°é£ãçãããæŽã«å¥
ã®äžå©ã¯ãè±åœç¹èš±ç¬¬1009484å·æ现æžã«èšèŒã®
奜é©ãªéå±å«æ觊åªãäŸãã°ããã«ãã¿ããŒãã
ãã³ã¹ãã¢ãªã³é žã¹ãºã®äœ¿çšããçãããå³ã¡ã
åèšè§Šåªã¯åå¿çæç©å ã«ä¿æãããåŸåãã
ããå®å šãªé€å»ãéæããããã«æŽã«å¥ã®ä»äžæ®µ
éãå¿ èŠãšãããæ¬çºæã®æ¹æ³ã®åå¿çæç©ã®äž»
èŠå¿çšã¯ãææ©ãã«ãªãã·é žåé§åç©è³ªãå³ã¡é
é žåæ°ŽçŽ ã®ã¢ã«ã«ãªäŸçµŠæºãšã®åå¿æã«ææ©ãã«
ãªãã·é žã«è»¢åãããç©è³ªãšããŠã§ããããã®çš®
ã®åé§ç©è³ªäžã®éå±ã€ãªã³ã®ååšã¯ãçæããã
ãã«ãªãã·é žã®å®å®æ§ã«æªåœ±é¿ãåãŒãããããŠ
åé§ç©è³ªâéé žåæ°ŽçŽ åå¿ããã®ãã«ãªãã·é žã®
åçãäœäžãããããšãããã
ã«é瀺ã®æ¹æ³ã¯ããèªäœå¥œé©ã§ãããšäžè¬ã«æ瀺
ãããŠãã觊åªãæ¯èŒçç¹ç°æ§ã§ããïŒæãå Žå
ã«ã¯æå¹ã§ãããä»ã®å Žåã«ã¯æå¹ã§ã¯ãªããšèš
èŒãããŠããïŒç¹ã«ãããŠå°é£ãçãããæŽã«å¥
ã®äžå©ã¯ãè±åœç¹èš±ç¬¬1009484å·æ现æžã«èšèŒã®
奜é©ãªéå±å«æ觊åªãäŸãã°ããã«ãã¿ããŒãã
ãã³ã¹ãã¢ãªã³é žã¹ãºã®äœ¿çšããçãããå³ã¡ã
åèšè§Šåªã¯åå¿çæç©å ã«ä¿æãããåŸåãã
ããå®å šãªé€å»ãéæããããã«æŽã«å¥ã®ä»äžæ®µ
éãå¿ èŠãšãããæ¬çºæã®æ¹æ³ã®åå¿çæç©ã®äž»
èŠå¿çšã¯ãææ©ãã«ãªãã·é žåé§åç©è³ªãå³ã¡é
é žåæ°ŽçŽ ã®ã¢ã«ã«ãªäŸçµŠæºãšã®åå¿æã«ææ©ãã«
ãªãã·é žã«è»¢åãããç©è³ªãšããŠã§ããããã®çš®
ã®åé§ç©è³ªäžã®éå±ã€ãªã³ã®ååšã¯ãçæããã
ãã«ãªãã·é žã®å®å®æ§ã«æªåœ±é¿ãåãŒãããããŠ
åé§ç©è³ªâéé žåæ°ŽçŽ åå¿ããã®ãã«ãªãã·é žã®
åçãäœäžãããããšãããã
ããããåºé¡äººã¯ãé©ç°çãªããšã«ãC2ãC3
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã®ãšã¹ãã«äº€
æã觊åªãå¿ èŠãšããã«é«åºŠã®å®å šãã«å®æœãã
åŸãããšãä»ãèŠãåºããã觊åªã®ååšã¯ãæ¬æ³
ã®é床è«ãæ¹åããããåå¿ãéå§ããããã«ã¯
å¿ é ã§ã¯ãªãã
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã®ãšã¹ãã«äº€
æã觊åªãå¿ èŠãšããã«é«åºŠã®å®å šãã«å®æœãã
åŸãããšãä»ãèŠãåºããã觊åªã®ååšã¯ãæ¬æ³
ã®é床è«ãæ¹åããããåå¿ãéå§ããããã«ã¯
å¿ é ã§ã¯ãªãã
ãã®çºèŠã«å¿çããåå¿æ©æ§ã«é¢ããŠã¯åŠäœãª
ãçè«ã«ãã€ãŠãéå®ãããããšãæãŸãªããã
ã¹ã«ãããŒãåºã®é»åæ±åŒæ§ã¯ãšã¹ãã«ã®ã¢ã·ã«
åºãè³éŠææ žããéè£ããåŸåãå¢å€§ãããã®
ã§ããããã®ããšããŒã«ãšã¹ãã«ã®ãšã¹ãã«äº€æ
çšã«ã¢ã·ããªã·ã¹æè¡ã䜿çšããããšã¯ã芪ããš
ããŒã«ã®ã¢ã«ã³ãŒãªã·ã¹ã§éå¶ãã倱掻åé¡ãå
æãããšèãããããåºé¡äººã¯ããšã¹ãã«äº€æå
å¿ãåå¿åªäœãäžãã以å€ã®ç®çã§ã¯åœ¹ç«ããªã
溶åªã䜿çšããªããšãå®æœããåŸãããšãèŠãåº
ãããã«ã«ãã³é žåå¿äœããšã¹ãã«ã®ãããªä»ã®
溶åªç©è³ªããã極æ§ã§ããéãã«ãããŠãåå¿åª
äœãšããŠã®ã«ã«ãã³é žåå¿äœã®äœ¿çšã¯ãåºçºã¹ã«
ãã³åãšã¹ãã«ç©è³ªããã³çæç©ã¹ã«ãã³åãšã¹
ãã«ç©è³ªã®äž¡æ¹ã®æº¶è§£åºŠãåäžããããšèããã
ããããã«ãæããã溶åªãšããŠã®ã«ã«ãã³é žå
å¿äœã®äœ¿çšã®äºæž¬ãããäžå©ã¯ãã¢ã·ã«ãªãã·ã¹
ã«ãããŒãçæç©ãšåå¿ããŠã¢ã«ã«ã³é žç¡æ°Žç©ã
çæããããã«ãã€ãŠçæç©ã®åçããã³çŽåºŠã
äœäžãããå¯èœæ§ããããããããé©ç°çãªããš
ã«ãã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãçæç©
ã¯ãæ¬æ³çšã«æºè¶³ã§ãããšèŠãåºãããæ¡ä»¶äžã§
ã¯ã«ã«ãã³é žæº¶åªãšã¯åå¿ããªãããšãèŠãåºã
ããŠããããã®çç±ã¯ååã«ã¯ç解ããããŠããª
ããæŽã«ãæãçš®ã®å¥œãŸããå ·äœäŸã«ãããŠã¯ã
C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©äžŠã³
ã«ã«ã«ãã³é žãããªãåå¿æ··åç©ã¯ãã¢ã·ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãã³é žå¡©èªäœãåé¢ããäžé溶åª
æœåºå·¥çšãªãã«ãæŽå€è£œåã§äœ¿çšããã®ã«å¥œé©ãª
圢æ ã«çŽæ¥å å·¥ããåŸãããšãèŠãåºãããŠã
ãã
ãçè«ã«ãã€ãŠãéå®ãããããšãæãŸãªããã
ã¹ã«ãããŒãåºã®é»åæ±åŒæ§ã¯ãšã¹ãã«ã®ã¢ã·ã«
åºãè³éŠææ žããéè£ããåŸåãå¢å€§ãããã®
ã§ããããã®ããšããŒã«ãšã¹ãã«ã®ãšã¹ãã«äº€æ
çšã«ã¢ã·ããªã·ã¹æè¡ã䜿çšããããšã¯ã芪ããš
ããŒã«ã®ã¢ã«ã³ãŒãªã·ã¹ã§éå¶ãã倱掻åé¡ãå
æãããšèãããããåºé¡äººã¯ããšã¹ãã«äº€æå
å¿ãåå¿åªäœãäžãã以å€ã®ç®çã§ã¯åœ¹ç«ããªã
溶åªã䜿çšããªããšãå®æœããåŸãããšãèŠãåº
ãããã«ã«ãã³é žåå¿äœããšã¹ãã«ã®ãããªä»ã®
溶åªç©è³ªããã極æ§ã§ããéãã«ãããŠãåå¿åª
äœãšããŠã®ã«ã«ãã³é žåå¿äœã®äœ¿çšã¯ãåºçºã¹ã«
ãã³åãšã¹ãã«ç©è³ªããã³çæç©ã¹ã«ãã³åãšã¹
ãã«ç©è³ªã®äž¡æ¹ã®æº¶è§£åºŠãåäžããããšèããã
ããããã«ãæããã溶åªãšããŠã®ã«ã«ãã³é žå
å¿äœã®äœ¿çšã®äºæž¬ãããäžå©ã¯ãã¢ã·ã«ãªãã·ã¹
ã«ãããŒãçæç©ãšåå¿ããŠã¢ã«ã«ã³é žç¡æ°Žç©ã
çæããããã«ãã€ãŠçæç©ã®åçããã³çŽåºŠã
äœäžãããå¯èœæ§ããããããããé©ç°çãªããš
ã«ãã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãçæç©
ã¯ãæ¬æ³çšã«æºè¶³ã§ãããšèŠãåºãããæ¡ä»¶äžã§
ã¯ã«ã«ãã³é žæº¶åªãšã¯åå¿ããªãããšãèŠãåºã
ããŠããããã®çç±ã¯ååã«ã¯ç解ããããŠããª
ããæŽã«ãæãçš®ã®å¥œãŸããå ·äœäŸã«ãããŠã¯ã
C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©äžŠã³
ã«ã«ã«ãã³é žãããªãåå¿æ··åç©ã¯ãã¢ã·ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãã³é žå¡©èªäœãåé¢ããäžé溶åª
æœåºå·¥çšãªãã«ãæŽå€è£œåã§äœ¿çšããã®ã«å¥œé©ãª
圢æ ã«çŽæ¥å å·¥ããåŸãããšãèŠãåºãããŠã
ãã
çºæã®æŠèŠ
åŸã€ãŠãæ¬çºæã¯ã
(a) 液ç¶C6ãC18眮æãŸãã¯é眮æèèªæã«ã«ã
ã³é žåªäœäžã®C2ãC3ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹
ã«ãã³é žå¡©ã®åäžåæ£æ··åç©ã調補ããã€ç¶æ
ãïŒã«ã«ãã³é žå¯Ÿã¹ã«ãã³é žå¡©ã®ã¢ã«æ¯ã¯ïŒïŒ
ïŒãè¶ ãããããŠã¹ã«ãã³é žå¡©ã¯ç²ç¶åœ¢æ ã§ã
ãïŒã (b) æ··åç©ã®æž©åºŠããã¢ã·ããªã·ã¹åå¿ãçãã
ããã€å¯çç©C2ãC3ã¢ã«ã«ã³é žã®æ®çºããã³
é€å»ãå¯èœãšãããã®ã«ååãªå€ã«ææž©ããã
ã㊠(c) C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©
ãååãã ããšãããªãC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«
ãã³é žã®è£œæ³ãæäŸããã
ã³é žåªäœäžã®C2ãC3ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹
ã«ãã³é žå¡©ã®åäžåæ£æ··åç©ã調補ããã€ç¶æ
ãïŒã«ã«ãã³é žå¯Ÿã¹ã«ãã³é žå¡©ã®ã¢ã«æ¯ã¯ïŒïŒ
ïŒãè¶ ãããããŠã¹ã«ãã³é žå¡©ã¯ç²ç¶åœ¢æ ã§ã
ãïŒã (b) æ··åç©ã®æž©åºŠããã¢ã·ããªã·ã¹åå¿ãçãã
ããã€å¯çç©C2ãC3ã¢ã«ã«ã³é žã®æ®çºããã³
é€å»ãå¯èœãšãããã®ã«ååãªå€ã«ææž©ããã
ã㊠(c) C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©
ãååãã ããšãããªãC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«
ãã³é žã®è£œæ³ãæäŸããã
æ¬çºæã®å¥œãŸããå
·äœäŸã«ãããŠã¯ãC2ãC3
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã¯ãC2ãC3
ã¢ã·ã«ç¡æ°Žç©ããã³ã¢ã«ã«ãªéå±ããšããŒã«ã¹ã«
ãã³é žå¡©ãããã®å Žã§çæãããïŒç¡æ°Žç©ã¯è¥å¹²
éå°ã«äœ¿çšããããããŠæ«æ¶è²»ç¡æ°Žç©ã¯C2ãC3
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã®çæå®äºåŸ
ã«èžçã«ãã€ãŠé€å»ãããïŒã
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã¯ãC2ãC3
ã¢ã·ã«ç¡æ°Žç©ããã³ã¢ã«ã«ãªéå±ããšããŒã«ã¹ã«
ãã³é žå¡©ãããã®å Žã§çæãããïŒç¡æ°Žç©ã¯è¥å¹²
éå°ã«äœ¿çšããããããŠæ«æ¶è²»ç¡æ°Žç©ã¯C2ãC3
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã®çæå®äºåŸ
ã«èžçã«ãã€ãŠé€å»ãããïŒã
æ¬çºæã®æ¹æ³ã®éåžžã«å¥œãŸããå
·äœäŸã«ãããŠ
ã¯ãå¡©åºæ§è§Šåªã奜ãŸããã¯é ¢é žãããªãŠã ãã
åå¿æ··åç©ã«æ·»å ãããã
ã¯ãå¡©åºæ§è§Šåªã奜ãŸããã¯é ¢é žãããªãŠã ãã
åå¿æ··åç©ã«æ·»å ãããã
çºæã®å
·äœç説æ
æ¬çºæã¯ãå±éºã§è
é£æ§ã®ããã²ã³ååºçºææ
ã䜿çšããã«C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«
ãã³é žå¡©ãçæããæ¹æ³ãããªãããããŠæ¬æ³ã«
ãããŠã¯é«è»¢åçãéæããããã«é«ãåå¿æž©åºŠ
ã¯äžèŠã§ãããæŽã«å¥ã®å©ç¹ã¯ã觊åªéå±ã«ãã
æçµçæç©ã®æ±æããã³åå¿å·¥çšã«ããã溶åªã®
䜿çšãåé¿ãããããšã§ãããæ¬çºæã®å¥œãŸãã
å®æœæ³ã«ãããŠã¯ããã¯ã³ãããïŒoneâpotïŒã
æ³ã䜿çšãããããã«ãã€ãŠæ¬æ³ã®æŽãªãåçŽå
ãäžããã
ã䜿çšããã«C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«
ãã³é žå¡©ãçæããæ¹æ³ãããªãããããŠæ¬æ³ã«
ãããŠã¯é«è»¢åçãéæããããã«é«ãåå¿æž©åºŠ
ã¯äžèŠã§ãããæŽã«å¥ã®å©ç¹ã¯ã觊åªéå±ã«ãã
æçµçæç©ã®æ±æããã³åå¿å·¥çšã«ããã溶åªã®
䜿çšãåé¿ãããããšã§ãããæ¬çºæã®å¥œãŸãã
å®æœæ³ã«ãããŠã¯ããã¯ã³ãããïŒoneâpotïŒã
æ³ã䜿çšãããããã«ãã€ãŠæ¬æ³ã®æŽãªãåçŽå
ãäžããã
æ¬çºæã¯ãã¢ã·ã«åºã®ãããã«ã«ãã«éšåãé
ç°åŒç·ç¶ãŸãã¯åæéšåã§ããããèèªæãŸãã¯
è³éŠæã§ããããšã®ã§ããç°çœ®æåºãå«æããè
èªæéšåã§ããC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹
ã«ãããŒãã®çæã«å¿çšã§ãããã«ã«ãã³é žåœ¢æ
ã®åŸè ã®äŸã¯ãïŒâããšãã«ããããªã³é žïŒãã
ãã±ã€ç®é žïŒã§ããã
ç°åŒç·ç¶ãŸãã¯åæéšåã§ããããèèªæãŸãã¯
è³éŠæã§ããããšã®ã§ããç°çœ®æåºãå«æããè
èªæéšåã§ããC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹
ã«ãããŒãã®çæã«å¿çšã§ãããã«ã«ãã³é žåœ¢æ
ã®åŸè ã®äŸã¯ãïŒâããšãã«ããããªã³é žïŒãã
ãã±ã€ç®é žïŒã§ããã
æ¬çºæã®äžå
·äœäŸã¯ãç·ç¶ãŸãã¯å®è³ªäžç·ç¶ã®
C6ãC12ã¢ã·ã«ãªãã·ã¹ã«ãããŒããç¹ã«ç·ç¶ãŸ
ãã¯å®è³ªäžç·ç¶ã®C8ãC10ã¢ã·ã«ãªãã·ãã³ãŒã³
ã¹ã«ãããŒãã®çæã«ã€ããŠã§ãããæ¬æ现æžã«
ãããŠãå®è³ªäžç·ç¶ãã¯çŽ25ïŒ ä»¥äžã®ã¡ãã«åæ
ãæãããããã«ã«ãã«éšåãæå³ãããšè§£éã
ããã®ã§ããããç·ç¶C8ãC10ã¢ã·ã«åºã®å¥œãŸã
ãäŸçµŠæºã¯ãäž»ãšããŠC8èèªé žãšC10èèªé žãšã®
æ··åç©ãããªãã³ã³ãããèèªé žã®ã©ã€ã
ïŒlightïŒãã©ã¯ã·ãšã³ã§ããã
C6ãC12ã¢ã·ã«ãªãã·ã¹ã«ãããŒããç¹ã«ç·ç¶ãŸ
ãã¯å®è³ªäžç·ç¶ã®C8ãC10ã¢ã·ã«ãªãã·ãã³ãŒã³
ã¹ã«ãããŒãã®çæã«ã€ããŠã§ãããæ¬æ现æžã«
ãããŠãå®è³ªäžç·ç¶ãã¯çŽ25ïŒ ä»¥äžã®ã¡ãã«åæ
ãæãããããã«ã«ãã«éšåãæå³ãããšè§£éã
ããã®ã§ããããç·ç¶C8ãC10ã¢ã·ã«åºã®å¥œãŸã
ãäŸçµŠæºã¯ãäž»ãšããŠC8èèªé žãšC10èèªé žãšã®
æ··åç©ãããªãã³ã³ãããèèªé žã®ã©ã€ã
ïŒlightïŒãã©ã¯ã·ãšã³ã§ããã
ããããæ¬çºæã®å¥œãŸããå
·äœäŸã«ãããŠã¯ã
ã«ã«ãã³é žã®C6ãC18èèªæåºã¯ãã«ã«ããã«ç
çŽ ããã®ã³ãã€ã«ã«ããã«ççŽ ãå å«ããççŽ æ°
ïŒä»¥äžã®ç·ç¶ã¢ã«ãã«éãæããéç·ç¶éšåã§ã
ãããã®çš®ã®éç·ç¶C6ãC18èèªæã«ã«ãã³é žã®
æŽã«å¥œãŸããå ·äœäŸã¯ãã«ã«ããã«ççŽ ååã«é¢
ããŠå°ãªããšãïŒäœããã³ïŒãŸãã¯ïŒïŒäœã«åæ
ãæãããããŠéåžžã«å¥œãŸããå ·äœäŸã«ãããŠã¯
ã«ã«ãã³é žã¯ççŽ æ°çŽïŒãçŽ10ãæãããæ¬çºæ
ã®æ¹æ³ã®ãã®å ·äœäŸã¯ã1983幎ïŒæ23æ¥åºé¡ã®è±
åœç¹èš±ç¬¬8304990å·æ现æžã«é瀺ãããã€è«æ±ã
ããååç©ã補é ããã®ã«ç¹ã«å¥œé©ã§ããã
ã«ã«ãã³é žã®C6ãC18èèªæåºã¯ãã«ã«ããã«ç
çŽ ããã®ã³ãã€ã«ã«ããã«ççŽ ãå å«ããççŽ æ°
ïŒä»¥äžã®ç·ç¶ã¢ã«ãã«éãæããéç·ç¶éšåã§ã
ãããã®çš®ã®éç·ç¶C6ãC18èèªæã«ã«ãã³é žã®
æŽã«å¥œãŸããå ·äœäŸã¯ãã«ã«ããã«ççŽ ååã«é¢
ããŠå°ãªããšãïŒäœããã³ïŒãŸãã¯ïŒïŒäœã«åæ
ãæãããããŠéåžžã«å¥œãŸããå ·äœäŸã«ãããŠã¯
ã«ã«ãã³é žã¯ççŽ æ°çŽïŒãçŽ10ãæãããæ¬çºæ
ã®æ¹æ³ã®ãã®å ·äœäŸã¯ã1983幎ïŒæ23æ¥åºé¡ã®è±
åœç¹èš±ç¬¬8304990å·æ现æžã«é瀺ãããã€è«æ±ã
ããååç©ã補é ããã®ã«ç¹ã«å¥œé©ã§ããã
æ¬çºæã®æ¹æ³ã¯ããã®æãåºã圢æ
ã«ãããŠ
ã¯ãã¢ã»ãã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žã®ãããª
ãŠã å¡©ãC9èèªæã«ã«ãã³é žãšåå¿ãããŠC9ã¢
ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ãçæ
ããäŸã«ãã€ãŠäŸç€ºããåŸãã
ã¯ãã¢ã»ãã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žã®ãããª
ãŠã å¡©ãC9èèªæã«ã«ãã³é žãšåå¿ãããŠC9ã¢
ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ãçæ
ããäŸã«ãã€ãŠäŸç€ºããåŸãã
ã¢ã»ããã·ãã³ãŒã³ã¹ã«ãã³é
žãããªãŠã ã¯ã
åœè©²æè¡åéã§æ¢ç¥ã®æ¹æ³ã«ãããäŸãã°è±åœç¹
蚱第864798å·æ现æžã®äŸïŒã«é瀺ã®æè¡ã«ããå¥
ã«çæããåŸããæãã¯ããããŠå¥œãŸããã¯ãã¢
ã»ããã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã¯ãåŸè¿°
ã®æ¹æ³ã«ããããã®å Žã§çæãããã
åœè©²æè¡åéã§æ¢ç¥ã®æ¹æ³ã«ãããäŸãã°è±åœç¹
蚱第864798å·æ现æžã®äŸïŒã«é瀺ã®æè¡ã«ããå¥
ã«çæããåŸããæãã¯ããããŠå¥œãŸããã¯ãã¢
ã»ããã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã¯ãåŸè¿°
ã®æ¹æ³ã«ããããã®å Žã§çæãããã
éœã€ãªã³ã¯å¥œãŸããã¯ãããªãŠã ã§ããããä»
ã®ã¢ã«ã«ãªéå±ãäŸãã°ã«ãªãŠã ããã³ãªããŠ
ã ãããã³ã¢ã«ã«ãªåé¡éå±ãäŸãã°ãã°ãã·ãŠ
ã ã䜿çšããåŸããäœçŽã¢ã·ã«ãªãã·ãã³ãŒã³ã¹
ã«ãã³é žå¡©ãçæããéã«ãç¡æ°Žããããªã³é žã
ç¡æ°Žé ¢é žã®ä»£ããã«äœ¿çšããåŸãããåŸè ãå ¥æ
æ§ãã³ã¹ããåå¿æ§ããã³åŠçã®å®¹æãã®çç±ã§
奜ãŸããã
ã®ã¢ã«ã«ãªéå±ãäŸãã°ã«ãªãŠã ããã³ãªããŠ
ã ãããã³ã¢ã«ã«ãªåé¡éå±ãäŸãã°ãã°ãã·ãŠ
ã ã䜿çšããåŸããäœçŽã¢ã·ã«ãªãã·ãã³ãŒã³ã¹
ã«ãã³é žå¡©ãçæããéã«ãç¡æ°Žããããªã³é žã
ç¡æ°Žé ¢é žã®ä»£ããã«äœ¿çšããåŸãããåŸè ãå ¥æ
æ§ãã³ã¹ããåå¿æ§ããã³åŠçã®å®¹æãã®çç±ã§
奜ãŸããã
æ¬çºæã®æãåºãæ¹æ³ã«ãããŠã¯ã埮ç²ç ç²ç¶
圢æ ã®ã¢ã«ã«ãªãŸãã¯ã¢ã«ã«ãªåé¡éå±C2ãC3
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ã¯ã液ç¶C6
ãC18èèªæã«ã«ãã³é žã«åæ£ããããé žå¯Ÿå¡©ã®
ã¢ã«æ¯ã¯ïŒïŒïŒãè¶ ãããã«ã«ãã³é žæž©åºŠã¯çŽ
190ãçŽ240âã®ç¯å²å ã®å€ã«ææž©ããããããŠæ··
åç©ã¯å¥œãŸããã¯äžæŽ»æ§ã¬ã¹ã¹ããŒãžã³ã°ãšäžç·
ã«æ¹æãããŠåå¿ã容æã«ããããã€C2ãC3ã¢
ã«ã«ã³é žå¯çç©äžŠã³ã«C6ãC18èèªæã«ã«ãã³é ž
ã®å°ãªããšãäžéšåãèžçã«ãã€ãŠæ®çºãããã€
é€å»ãããããšãå¯èœã«ãããããã®æ®µéã«ãã
ãC6ãC18èèªæã«ã«ãã³é žã®é€å»çšåºŠã¯ãé žã®
éé·ã«éåžžã«äŸåãããçŽC12ãããé·ãççŽ é
é·ã®é žã®å Žåã«ã¯ãæ®çºãæžå§äžã§å®æœãããªã
ãã°ãã»ãšãã©é€å»ã¯çããªããããããæŽå€æ©
èœãæããåå¿æ··åç©ã®æåãèžçæ¡ä»¶äžã§çºæ³¡
ããåŸåã¯ãç空ã®äœ¿çšã«ãã€ãŠæªåããããã
æ ããã¯å¥œãŸããæè¡ã§ã¯ãªããéç·ç¶é žã®äžè¬
ã«äœãèžçºæž©åºŠã¯åäžççŽ æ°ã®ç·ç¶é žã«æ¯èŒããŠ
æå®ã®åå¿æ··åç©æž©åºŠã«ãããŠåè ã®å€§ããé€å»
ãçããã®ã§ãé žåªäœé€å»ãé žã®æ§é ã«ãã€ãŠåœ±
é¿ãããã
圢æ ã®ã¢ã«ã«ãªãŸãã¯ã¢ã«ã«ãªåé¡éå±C2ãC3
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ã¯ã液ç¶C6
ãC18èèªæã«ã«ãã³é žã«åæ£ããããé žå¯Ÿå¡©ã®
ã¢ã«æ¯ã¯ïŒïŒïŒãè¶ ãããã«ã«ãã³é žæž©åºŠã¯çŽ
190ãçŽ240âã®ç¯å²å ã®å€ã«ææž©ããããããŠæ··
åç©ã¯å¥œãŸããã¯äžæŽ»æ§ã¬ã¹ã¹ããŒãžã³ã°ãšäžç·
ã«æ¹æãããŠåå¿ã容æã«ããããã€C2ãC3ã¢
ã«ã«ã³é žå¯çç©äžŠã³ã«C6ãC18èèªæã«ã«ãã³é ž
ã®å°ãªããšãäžéšåãèžçã«ãã€ãŠæ®çºãããã€
é€å»ãããããšãå¯èœã«ãããããã®æ®µéã«ãã
ãC6ãC18èèªæã«ã«ãã³é žã®é€å»çšåºŠã¯ãé žã®
éé·ã«éåžžã«äŸåãããçŽC12ãããé·ãççŽ é
é·ã®é žã®å Žåã«ã¯ãæ®çºãæžå§äžã§å®æœãããªã
ãã°ãã»ãšãã©é€å»ã¯çããªããããããæŽå€æ©
èœãæããåå¿æ··åç©ã®æåãèžçæ¡ä»¶äžã§çºæ³¡
ããåŸåã¯ãç空ã®äœ¿çšã«ãã€ãŠæªåããããã
æ ããã¯å¥œãŸããæè¡ã§ã¯ãªããéç·ç¶é žã®äžè¬
ã«äœãèžçºæž©åºŠã¯åäžççŽ æ°ã®ç·ç¶é žã«æ¯èŒããŠ
æå®ã®åå¿æ··åç©æž©åºŠã«ãããŠåè ã®å€§ããé€å»
ãçããã®ã§ãé žåªäœé€å»ãé žã®æ§é ã«ãã€ãŠåœ±
é¿ãããã
åå¿ãçåºç©æµã®åæ¢ã«ãã€ãŠç€ºãããããã«
å®äºããããæ··åç©ã¯ãçŽ100â以äžã®æž©åºŠã«å·
åŽããã次ãã§æŽã«å¥ã®åŠçã«ä»ãããŠæŽå€è£œå
ã«é åããã®ã«å¥œé©ãªC6ãC18ã¢ã·ã«ãªãã·ãã³
ãŒã³ã¹ã«ãã³é žå¡©ãçæããã
å®äºããããæ··åç©ã¯ãçŽ100â以äžã®æž©åºŠã«å·
åŽããã次ãã§æŽã«å¥ã®åŠçã«ä»ãããŠæŽå€è£œå
ã«é åããã®ã«å¥œé©ãªC6ãC18ã¢ã·ã«ãªãã·ãã³
ãŒã³ã¹ã«ãã³é žå¡©ãçæããã
æ¬çºæã®äžé¢ã«ãããŠã¯ãåå¿çæç©ã¯ãåå¿
容åšããé€å»ããããããŠçæ°Žæ§æº¶åªã«åæ£ãã
ãŠC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ã
æ²æ®¿ãããã次ãã§ãããã¯C6ãC18èèªæã«ã«
ãã³é žå«æäžæŸã¿æ¶²ããéããããããŠä¹Ÿç¥ã
ãããæ¬çºæã®ãã®é¢ã«ãããŠã¯ã次ãã§äžæŸã¿
液ããèªäœãå ç±ãããŠçæ°Žæ§æº¶åªãæ®çºããã
ã€éå°ã®C6ãC18èèªæã«ã«ãã³é žããåé¢ããã
次ãã§ã溶åªããã³ã«ã«ãã³é žã®äž¡æ¹ã¯ãæ¬æ³ã«
ããããããã®ããããã®äœ¿çšç¹ã«å埪ç°ããåŸ
ãã
容åšããé€å»ããããããŠçæ°Žæ§æº¶åªã«åæ£ãã
ãŠC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ã
æ²æ®¿ãããã次ãã§ãããã¯C6ãC18èèªæã«ã«
ãã³é žå«æäžæŸã¿æ¶²ããéããããããŠä¹Ÿç¥ã
ãããæ¬çºæã®ãã®é¢ã«ãããŠã¯ã次ãã§äžæŸã¿
液ããèªäœãå ç±ãããŠçæ°Žæ§æº¶åªãæ®çºããã
ã€éå°ã®C6ãC18èèªæã«ã«ãã³é žããåé¢ããã
次ãã§ã溶åªããã³ã«ã«ãã³é žã®äž¡æ¹ã¯ãæ¬æ³ã«
ããããããã®ããããã®äœ¿çšç¹ã«å埪ç°ããåŸ
ãã
èèªæã«ã«ãã³é
žãéç·ç¶C6ãC12ç©è³ªã§ãã
ãã€æªåå¿é žã®ããªãã®å²åãæ®çºã«ãã€ãŠé€å»
ãããæ¬çºæã®å¥ã®å¥œãŸããé¢ã«ãããŠã¯ã溶è
æ§ææ©ãã€ãªã€ãŒç©è³ªããå·åŽãããŠãããäŸç¶
ãšããŠæµåæ§ã§ããåå¿çæç©ã«æ·»å ããããæ·»
å ã¯ãäžæŽ»æ§ã¬ã¹ãäŸãã°çªçŽ ã®é°å²æ°äžã§çã
ãŠçæç©å£åãåé¿ãããã次ãã§ããã®æ··åç©
ã®æž©åºŠã¯ãåžžæž©ã«å·åŽããåã«èª¿æŽãããŠæ··åç©
ãç²ç¶ç©ãäŸãã°ãã¬ãŒã¯ãé¡ç²ãããŒãã«ãŸã
ã¯ããªã«ã«æ©æ¢°çã«å å·¥ãããã
ãã€æªåå¿é žã®ããªãã®å²åãæ®çºã«ãã€ãŠé€å»
ãããæ¬çºæã®å¥ã®å¥œãŸããé¢ã«ãããŠã¯ã溶è
æ§ææ©ãã€ãªã€ãŒç©è³ªããå·åŽãããŠãããäŸç¶
ãšããŠæµåæ§ã§ããåå¿çæç©ã«æ·»å ããããæ·»
å ã¯ãäžæŽ»æ§ã¬ã¹ãäŸãã°çªçŽ ã®é°å²æ°äžã§çã
ãŠçæç©å£åãåé¿ãããã次ãã§ããã®æ··åç©
ã®æž©åºŠã¯ãåžžæž©ã«å·åŽããåã«èª¿æŽãããŠæ··åç©
ãç²ç¶ç©ãäŸãã°ãã¬ãŒã¯ãé¡ç²ãããŒãã«ãŸã
ã¯ããªã«ã«æ©æ¢°çã«å å·¥ãããã
ç·ç¶èèªæC6ãC12ã«ã«ãã³é
žãåå¿åªäœãšã
ãŠäœ¿çšãããŠããåå¿æ··åç©ã¯ãåèšã®ããã«çŽ
æ¥å©çšãããŠç²ç¶ç©ã圢æããããšãã§ãããã
ããããã®æ¹åŒã§ã®ãã®çš®ã®æ··åç©ã®äœ¿çšã¯ãé
åç©ã®èæ°ãç²ç¶åœ¢æ ã®åå¿çæç©ã®éèŠãªèŠä»¶
ã§ããå Žåã«ã¯äœãæå©ã§ã¯ãªãããã®çç±ã¯ã
å°éã®ç·ç¶ã«ã«ãã³é žããïŒäŸãã°ãã¢ã·ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãã³é žå¡©åºæºã§ïŒïŒ ïŒçæç©ãæŽ
å€çµæç©ã«é åãããå Žåã«ãã¹ã¯ããããšãå°
é£ã§ããéãèæ°ãåå¿çæç©ã«äžãããèæ°
ã¯ãååéã®å¥œé©ãªå¡©åºïŒäŸãã°ãçé žãããªãŠ
ã ïŒãæ·»å ããŠæ®çç·ç¶ã«ã«ãã³é žãã±ã³åãã
ããšã«ãã€ãŠé²æ¢ããåŸããé ¢é žãããªãŠã ãã¢
ã·ããªã·ã¹åå¿ã«ãããŠè§ŠåªãšããŠäœ¿çšãããæ¬
çºæã®éåžžã«å¥œãŸããå ·äœäŸã«ãããŠã¯ãæ®çã«
ã«ãã³é žã¯è§Šåªããã®ãããªãŠã ã€ãªã³ãšäŒåã
ããã§ããããé žãã±ã³åãèæ°ãé€ãããã«å¡©
åºãæ·»å ããããšã¯ãäžèŠã§ããããšããããã
ã®èæ°åé¡ã¯ãåŸè¿°ã®å¥œãŸããæ§é ãæããéç·
ç¶èèªæã«ã«ãã³é žã䜿çšããå Žåã«ã¯çããª
ãã
ãŠäœ¿çšãããŠããåå¿æ··åç©ã¯ãåèšã®ããã«çŽ
æ¥å©çšãããŠç²ç¶ç©ã圢æããããšãã§ãããã
ããããã®æ¹åŒã§ã®ãã®çš®ã®æ··åç©ã®äœ¿çšã¯ãé
åç©ã®èæ°ãç²ç¶åœ¢æ ã®åå¿çæç©ã®éèŠãªèŠä»¶
ã§ããå Žåã«ã¯äœãæå©ã§ã¯ãªãããã®çç±ã¯ã
å°éã®ç·ç¶ã«ã«ãã³é žããïŒäŸãã°ãã¢ã·ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãã³é žå¡©åºæºã§ïŒïŒ ïŒçæç©ãæŽ
å€çµæç©ã«é åãããå Žåã«ãã¹ã¯ããããšãå°
é£ã§ããéãèæ°ãåå¿çæç©ã«äžãããèæ°
ã¯ãååéã®å¥œé©ãªå¡©åºïŒäŸãã°ãçé žãããªãŠ
ã ïŒãæ·»å ããŠæ®çç·ç¶ã«ã«ãã³é žãã±ã³åãã
ããšã«ãã€ãŠé²æ¢ããåŸããé ¢é žãããªãŠã ãã¢
ã·ããªã·ã¹åå¿ã«ãããŠè§ŠåªãšããŠäœ¿çšãããæ¬
çºæã®éåžžã«å¥œãŸããå ·äœäŸã«ãããŠã¯ãæ®çã«
ã«ãã³é žã¯è§Šåªããã®ãããªãŠã ã€ãªã³ãšäŒåã
ããã§ããããé žãã±ã³åãèæ°ãé€ãããã«å¡©
åºãæ·»å ããããšã¯ãäžèŠã§ããããšããããã
ã®èæ°åé¡ã¯ãåŸè¿°ã®å¥œãŸããæ§é ãæããéç·
ç¶èèªæã«ã«ãã³é žã䜿çšããå Žåã«ã¯çããª
ãã
æ¬çºæã®æ¹æ³ã®ïŒã€ã®å©ç¹ã¯ãåå¿æ··åç©ãã
åå¿äœçšã®éåžžã®åªäœãæé€ã§ããããšã§ããã
ãã®ä»£ããåå¿äœã®äžæ¹ãå³ã¡C6ãC18èèªæã«
ã«ãã³é žã¯ãããèªäœåå¿åªäœãšããŠäœ¿çšããã
ãããã®ããšã¯ã«ã«ãã³é žã液çžã«ããããšãå¿
èŠãšãã奜ãŸããã¯äœç²åºŠãæãããççŽ æ°12以
äžãæããèèªæã«ã«ãã³é žã¯ãåžžæž©ã§åºäœã§ã
ããããæ å ç±ãããŠãC2ãC3ã¢ã·ã«ãªãã·ã
ã³ãŒã³ã¹ã«ãããŒããåæ£ããåŸã液äœåªäœãäž
ããããšãå¿ èŠã§ããããC6ãC10èèªæã«ã«ã
ã³é žã¯ãåžžæž©ã§æ¶²äœã§ãããããæ åºäœããšããŒ
ã«ã¹ã«ãããŒãã®åæ£ã容æã«ãããã
åå¿äœçšã®éåžžã®åªäœãæé€ã§ããããšã§ããã
ãã®ä»£ããåå¿äœã®äžæ¹ãå³ã¡C6ãC18èèªæã«
ã«ãã³é žã¯ãããèªäœåå¿åªäœãšããŠäœ¿çšããã
ãããã®ããšã¯ã«ã«ãã³é žã液çžã«ããããšãå¿
èŠãšãã奜ãŸããã¯äœç²åºŠãæãããççŽ æ°12以
äžãæããèèªæã«ã«ãã³é žã¯ãåžžæž©ã§åºäœã§ã
ããããæ å ç±ãããŠãC2ãC3ã¢ã·ã«ãªãã·ã
ã³ãŒã³ã¹ã«ãããŒããåæ£ããåŸã液äœåªäœãäž
ããããšãå¿ èŠã§ããããC6ãC10èèªæã«ã«ã
ã³é žã¯ãåžžæž©ã§æ¶²äœã§ãããããæ åºäœããšããŒ
ã«ã¹ã«ãããŒãã®åæ£ã容æã«ãããã
æ¬çºæã®æ¹æ³ã§äœ¿çšããã®ã«å¥œé©ãªèèªæã«ã«
ãã³é žã¯ãç·ç¶ãŸãã¯äž»ãšããŠç·ç¶ïŒåŸè¿°ïŒã§ã
ãããšãã§ããããã®çš®ã®é žã¯ã倩ç¶æ²¹èããèª
å°ããããŸãã¯å®è³ªäžç·ç¶ã®ç©è³ªã®å Žåã«ã¯ãªã
ãœãŸãã¯ããŒã°ã©ãŒåææè¡ã䜿çšããŠç³æ²¹çå
æ°ŽçŽ åæããèªå°ãããã
ãã³é žã¯ãç·ç¶ãŸãã¯äž»ãšããŠç·ç¶ïŒåŸè¿°ïŒã§ã
ãããšãã§ããããã®çš®ã®é žã¯ã倩ç¶æ²¹èããèª
å°ããããŸãã¯å®è³ªäžç·ç¶ã®ç©è³ªã®å Žåã«ã¯ãªã
ãœãŸãã¯ããŒã°ã©ãŒåææè¡ã䜿çšããŠç³æ²¹çå
æ°ŽçŽ åæããèªå°ãããã
ãããã奜ãŸããèèªæã«ã«ãã³é
žã¯æ§é ãé
ç·ç¶ã§ãããã«ã«ããã«ççŽ ããã®ã³ãã€ã«ã«ã
ãã«ççŽ ãå å«ããç·ç¶éå ã«ççŽ æ°å°ãªããšã
ïŒãæããããªã¯ã¿ããŒã«ãšæ°Žãšã®éã®åé ä¿æ°
ã«ãã€ãŠè¡šããããææ©ååç©ã®çæ°Žæ§ã«å¯ŸããŠ
ã®æ§é ã®å¹æã¯ããšã€ã»ã¬ãªçã«ããã±ãã«ã«ã»
ã¬ããŠãŒãºïŒChemical ReviewsïŒã71ã第525é
ã第616é ïŒ1971幎ïŒã«èšèŒãããŠããããã®æ
ç®ã¯ãåºç¯å²ã®æ§é ãžã®åçš®ã®çœ®æåºã®å°å ¥ã«é¢
é£ããLog POCTïŒåŒäžãPOCTã¯ãªã¯ã¿ããŒã«ãšæ°Ž
ãšã®éã®åé ä¿æ°ã§ããïŒã®å€åã®å€æ°ã®å€ãäž
ãããããã¯Log POCTã®å€ãåŠäœãªãæ§é ã«å¯Ÿ
ããŠãäºæž¬ãããããšãå¯èœãšãããããŠãã®åº
æºã§å¥œãŸããéç·ç¶ã«ã«ãã³é žã¯ãçŽ1.9ãçŽ4.1
ã®ç¯å²å ã®log POCTãæãããã®ã§ããã
ç·ç¶ã§ãããã«ã«ããã«ççŽ ããã®ã³ãã€ã«ã«ã
ãã«ççŽ ãå å«ããç·ç¶éå ã«ççŽ æ°å°ãªããšã
ïŒãæããããªã¯ã¿ããŒã«ãšæ°Žãšã®éã®åé ä¿æ°
ã«ãã€ãŠè¡šããããææ©ååç©ã®çæ°Žæ§ã«å¯ŸããŠ
ã®æ§é ã®å¹æã¯ããšã€ã»ã¬ãªçã«ããã±ãã«ã«ã»
ã¬ããŠãŒãºïŒChemical ReviewsïŒã71ã第525é
ã第616é ïŒ1971幎ïŒã«èšèŒãããŠããããã®æ
ç®ã¯ãåºç¯å²ã®æ§é ãžã®åçš®ã®çœ®æåºã®å°å ¥ã«é¢
é£ããLog POCTïŒåŒäžãPOCTã¯ãªã¯ã¿ããŒã«ãšæ°Ž
ãšã®éã®åé ä¿æ°ã§ããïŒã®å€åã®å€æ°ã®å€ãäž
ãããããã¯Log POCTã®å€ãåŠäœãªãæ§é ã«å¯Ÿ
ããŠãäºæž¬ãããããšãå¯èœãšãããããŠãã®åº
æºã§å¥œãŸããéç·ç¶ã«ã«ãã³é žã¯ãçŽ1.9ãçŽ4.1
ã®ç¯å²å ã®log POCTãæãããã®ã§ããã
éç·ç¶æ§ã¯ãèèªæåæãŸãã¯è³éŠæãŸãã¯ã·
ã¯ãèèªææ§é ã®åœ¢æ ããšãããšãã§ãããåæ
ã¯ãã«ã«ããã«ççŽ ã«é¢ããŠïŒããã³ïŒãŸãã¯ïŒ
ïŒççŽ ååäžã«å°ãªããšãããããšã奜ãŸãã
ããïŒïŒïŒâåæã¯ãããããçæãããã¢ã·ã«
ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ã®éå æ°Žå解æ§èœã«
察ããŠã®é 眮ã®æªåœ±é¿ã®ãã奜ãŸãããªãã
ã¯ãèèªææ§é ã®åœ¢æ ããšãããšãã§ãããåæ
ã¯ãã«ã«ããã«ççŽ ã«é¢ããŠïŒããã³ïŒãŸãã¯ïŒ
ïŒççŽ ååäžã«å°ãªããšãããããšã奜ãŸãã
ããïŒïŒïŒâåæã¯ãããããçæãããã¢ã·ã«
ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ã®éå æ°Žå解æ§èœã«
察ããŠã®é 眮ã®æªåœ±é¿ã®ãã奜ãŸãããªãã
éåžžã«å¥œãŸããèèªæã«ã«ãã³é
žã¯ãççŽ æ°çŽ
ïŒãçŽïŒãæãããããŠãã®çš®ã®éç·ç¶é žã®äŸ
ã¯ãïŒâãšãã«ãããµã³é žãïŒïŒïŒïŒïŒâããªã¡
ãã«ãããµã³é žããã³ïŒâããšãã«ããããªã³é ž
ã§ããã
ïŒãçŽïŒãæãããããŠãã®çš®ã®éç·ç¶é žã®äŸ
ã¯ãïŒâãšãã«ãããµã³é žãïŒïŒïŒïŒïŒâããªã¡
ãã«ãããµã³é žããã³ïŒâããšãã«ããããªã³é ž
ã§ããã
åå¿æ··åç©ãæ¹æå¯èœãªæµäœãšããŠç¶æããã®
ã«å¿ èŠãªC6ãC18ã«ã«ãã³é žã®éã¯ãç³»ã®ç©çç
ç¹æ§ãäŸãã°é žã®ç²åºŠã®æž©åºŠäŸåæ§ããã³ããšã
ãŒã«ã¹ã«ãããŒãåºçºææããã³çæç©ã®çµæ¶åœ¢
æ ã®é¢æ°ã§ãããããããåå¿å šäœã«ããã€ãŠã®
é©åœãªæµåæ§ãç¶æããããã«C6ãC18ã«ã«ãã³
é žå¯ŸããšããŒã«ã¹ã«ãããŒãã®åºçºã¢ã«æ¯å°ãªã
ãšãçŽïŒïŒïŒãæããããšãéåžžã«æãŸããããš
ãèŠãåºãããŠããããããŠã¢ã«æ¯å°ãªããšã
ïŒïŒïŒã奜ãŸãããæã奜ãŸããã¢ã«æ¯ã¯çŽïŒïŒ
ïŒããçŽïŒïŒïŒã§ãããçŽïŒïŒïŒãè¶ ããã¢ã«æ¯
ã®äœ¿çšã¯ãæŽã«æµåæ§ã®åå¿æ··åç©ãäžãããã
C6ãC18ã«ã«ãã³é žãšC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒ
ã³ã¹ã«ãããŒãçæç©ãšã®éåå¿ãC6ãC18ã¢ã«
ã«ã³é žç¡æ°Žç©ãçæããå±éºãå¢å€§ãããã®ã§ã
æå©ã§ãããšã¯èããããªããæŽã«ãããå€ãå
å¿å®¹éãåãæ±ãããªããã°ãªããããããŠãã
å€ãã«ã«ãã³é žãååãããã€åå¿ã«å埪ç°ãã
ãªããã°ãªããªãã
ã«å¿ èŠãªC6ãC18ã«ã«ãã³é žã®éã¯ãç³»ã®ç©çç
ç¹æ§ãäŸãã°é žã®ç²åºŠã®æž©åºŠäŸåæ§ããã³ããšã
ãŒã«ã¹ã«ãããŒãåºçºææããã³çæç©ã®çµæ¶åœ¢
æ ã®é¢æ°ã§ãããããããåå¿å šäœã«ããã€ãŠã®
é©åœãªæµåæ§ãç¶æããããã«C6ãC18ã«ã«ãã³
é žå¯ŸããšããŒã«ã¹ã«ãããŒãã®åºçºã¢ã«æ¯å°ãªã
ãšãçŽïŒïŒïŒãæããããšãéåžžã«æãŸããããš
ãèŠãåºãããŠããããããŠã¢ã«æ¯å°ãªããšã
ïŒïŒïŒã奜ãŸãããæã奜ãŸããã¢ã«æ¯ã¯çŽïŒïŒ
ïŒããçŽïŒïŒïŒã§ãããçŽïŒïŒïŒãè¶ ããã¢ã«æ¯
ã®äœ¿çšã¯ãæŽã«æµåæ§ã®åå¿æ··åç©ãäžãããã
C6ãC18ã«ã«ãã³é žãšC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒ
ã³ã¹ã«ãããŒãçæç©ãšã®éåå¿ãC6ãC18ã¢ã«
ã«ã³é žç¡æ°Žç©ãçæããå±éºãå¢å€§ãããã®ã§ã
æå©ã§ãããšã¯èããããªããæŽã«ãããå€ãå
å¿å®¹éãåãæ±ãããªããã°ãªããããããŠãã
å€ãã«ã«ãã³é žãååãããã€åå¿ã«å埪ç°ãã
ãªããã°ãªããªãã
ããšããŒã«ã¹ã«ãã³é
žå¡©ã¯ãã¢ã«ã«ã³é
žã«é£æº¶
æ§ã§ããããããŠåŸ®ç²ç ãããŠåå¿çšã«å©çšã§ã
ãè¡šé¢ç©ãæ倧éã«ããªããã°ãªããªãã奜ãŸã
ãã¯ãåèšç©è³ªã®ç²åŸã¯ãçŽ100ãã¯ãã³æªæºã§
ããã¹ãã§ãããçæ³çã«ã¯ã§ããã ã埮现ã§ã
ãã¹ãã§ããããããã®åºæºã¯ãC2ãC3ã¢ã·ã«
ãªãã·ãã³ãŒã³ã¹ã«ãããŒãããã®å Žã§çæãã
ãã€çŽ50ãã¯ãã³æªæºã®ç²åŸã®éåžžã«åŸ®ç²ç ã®åº
äœãšããŠååšãã奜ãŸããæ¹æ³ã«ãããŠã¯ãæºã
ããããããããC2ãC3ã¢ã·ã«ãªãã·ãã³ãŒã³
ã¹ã«ãããŒããå¥ã®äœçœ®ã§çæãããå Žåã«ã¯ã
éåžžã®ç²ç æè¡ãäŸãã°åºäœã®æžæ¿æ¶²ã®ã³ãã€ã
æ©ç ã䜿çšãããŠææã®ç²åŸãéæããããšãã§
ããã
æ§ã§ããããããŠåŸ®ç²ç ãããŠåå¿çšã«å©çšã§ã
ãè¡šé¢ç©ãæ倧éã«ããªããã°ãªããªãã奜ãŸã
ãã¯ãåèšç©è³ªã®ç²åŸã¯ãçŽ100ãã¯ãã³æªæºã§
ããã¹ãã§ãããçæ³çã«ã¯ã§ããã ã埮现ã§ã
ãã¹ãã§ããããããã®åºæºã¯ãC2ãC3ã¢ã·ã«
ãªãã·ãã³ãŒã³ã¹ã«ãããŒãããã®å Žã§çæãã
ãã€çŽ50ãã¯ãã³æªæºã®ç²åŸã®éåžžã«åŸ®ç²ç ã®åº
äœãšããŠååšãã奜ãŸããæ¹æ³ã«ãããŠã¯ãæºã
ããããããããC2ãC3ã¢ã·ã«ãªãã·ãã³ãŒã³
ã¹ã«ãããŒããå¥ã®äœçœ®ã§çæãããå Žåã«ã¯ã
éåžžã®ç²ç æè¡ãäŸãã°åºäœã®æžæ¿æ¶²ã®ã³ãã€ã
æ©ç ã䜿çšãããŠææã®ç²åŸãéæããããšãã§
ããã
åæ£æ¶²ã®æž©åºŠã¯ã80ã100âã«ææž©ãããŠåå¿
ãéå§ãããããŠåå¿åšã«ã¯æå¹ãªæ¹æã·ã¹ãã
ãåãä»ããããŠåå¿æéå šäœã«ããã€ãŠåæ£æ¶²
ã®åäžæ§ãç¶æããªããã°ãªããªããããããå
å¿ãé²è¡ãããšãåå¿æ··åç©ã®ç²åºŠã¯ã挞é²çã«
åºäœå¯Ÿæ¶²äœã®æ¯çã®å¢å€§ã«ã€ããŠå¢å€§ãããããŠ
ãã®ç²åºŠãäžããããã«åå¿æ··åç©ã®æž©åºŠãææž©
ããããšã¯å±éšéç±ãããããããã®çµæè²å£å
ãããããã®ã§ãå¯çç©C2ãC3ã¢ã«ã«ã³é žã®é€
å»ã¯æŽã«å°é£ã«ãªããããæ ãæ¹æã·ã¹ãã ã®èš
èšã¯ãæ®çºå¯çç©é žã®é¢è±ãä¿èšŒããã®ã«å¹çè¯
ãæ··åã®ç¶æãšåæã«åå¿å šäœã«ããã€ãŠã®åºäœ
å«éã®æŒžé²çå¢å€§ã«é å¿ããªããã°ãªããªãã
ãéå§ãããããŠåå¿åšã«ã¯æå¹ãªæ¹æã·ã¹ãã
ãåãä»ããããŠåå¿æéå šäœã«ããã€ãŠåæ£æ¶²
ã®åäžæ§ãç¶æããªããã°ãªããªããããããå
å¿ãé²è¡ãããšãåå¿æ··åç©ã®ç²åºŠã¯ã挞é²çã«
åºäœå¯Ÿæ¶²äœã®æ¯çã®å¢å€§ã«ã€ããŠå¢å€§ãããããŠ
ãã®ç²åºŠãäžããããã«åå¿æ··åç©ã®æž©åºŠãææž©
ããããšã¯å±éšéç±ãããããããã®çµæè²å£å
ãããããã®ã§ãå¯çç©C2ãC3ã¢ã«ã«ã³é žã®é€
å»ã¯æŽã«å°é£ã«ãªããããæ ãæ¹æã·ã¹ãã ã®èš
èšã¯ãæ®çºå¯çç©é žã®é¢è±ãä¿èšŒããã®ã«å¹çè¯
ãæ··åã®ç¶æãšåæã«åå¿å šäœã«ããã€ãŠã®åºäœ
å«éã®æŒžé²çå¢å€§ã«é å¿ããªããã°ãªããªãã
å¯çç©C2ãC3ã¢ã«ã«ã³é
žã®é€å»ã¯ãåå¿æ··å
ç©ã®é žåå£åãé²æ¢ããã®ã«ã圹ç«ã€äžæŽ»æ§ã¬ã¹
ã¹ããŒãžã³ã°ã«ãã€ãŠä¿é²ããããã¬ã¹ã¯ããã®
ç®çã«é垞䜿çšãããåŠäœãªããã®ã§ããããšã
ã§ããçªçŽ ãæã奜ãŸãããåå¿æž©åºŠã¯ãçŽ190
âãçŽ240âã®ç¯å²å ã®å€ã«å¢å€§ããããããã
ãŠåå¿ã®é²è¡ã¯ãå¯çç©ã¢ã«ã«ã³é žäžŠã³ã«éå°ã®
æªåå¿C6ãC18ã«ã«ãã³é žã®å°ãªããšãäžéšåã®
é€å»é床ã«ãã€ãŠç£èŠãããã
ç©ã®é žåå£åãé²æ¢ããã®ã«ã圹ç«ã€äžæŽ»æ§ã¬ã¹
ã¹ããŒãžã³ã°ã«ãã€ãŠä¿é²ããããã¬ã¹ã¯ããã®
ç®çã«é垞䜿çšãããåŠäœãªããã®ã§ããããšã
ã§ããçªçŽ ãæã奜ãŸãããåå¿æž©åºŠã¯ãçŽ190
âãçŽ240âã®ç¯å²å ã®å€ã«å¢å€§ããããããã
ãŠåå¿ã®é²è¡ã¯ãå¯çç©ã¢ã«ã«ã³é žäžŠã³ã«éå°ã®
æªåå¿C6ãC18ã«ã«ãã³é žã®å°ãªããšãäžéšåã®
é€å»é床ã«ãã€ãŠç£èŠãããã
èèªæã«ã«ãã³é
žåå¿åªäœãççŽ æ°çŽ12以äžã
æããæ¬æ³ã«ãããŠã¯ãæªåå¿é žã®çŽ90ïŒ ã¯ãå
å¿æéã«ãããŠæ®çºãããã€é€å»ããåŸãã倧éš
åã®é žã®é€å»ã¯ãåå¿ãå®è³ªäžå®äºããå Žåã«å
å¿æéã®çµãã§çãããããŠåå¿æ··åç©ã®æž©åºŠ
ã¯ãå¯çç©C2ãC3ã¢ã«ã«ã³é žã®é€å»åŸã«ææž©ã
ãã
æããæ¬æ³ã«ãããŠã¯ãæªåå¿é žã®çŽ90ïŒ ã¯ãå
å¿æéã«ãããŠæ®çºãããã€é€å»ããåŸãã倧éš
åã®é žã®é€å»ã¯ãåå¿ãå®è³ªäžå®äºããå Žåã«å
å¿æéã®çµãã§çãããããŠåå¿æ··åç©ã®æž©åºŠ
ã¯ãå¯çç©C2ãC3ã¢ã«ã«ã³é žã®é€å»åŸã«ææž©ã
ãã
ãããçµã€ãããåå¿çæç©ã¯ãæŽã«åŠçãã
åã«çŽ100â以äžã®æž©åºŠã«å·åŽãããã
åã«çŽ100â以äžã®æž©åºŠã«å·åŽãããã
ç·ç¶ã«ã«ãã³é
žãå©çšããåå¿ã®å Žåã«ã¯ãå
å¿çæç©ã¯ãèèªé žåå¿åªäœãå¯æº¶æ§ã§ãããã€
C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ãäž
溶æ§ã§ãã溶åªã«å¥œãŸããã¯ååæ£ããããåå¿
æ··åç©ãå·åŽããã枩床ããã³æº¶åªã¯ãåå¿æ··å
ç©ãåãæ±ãã«ååãªçšæµåæ§ã§ãããã€æº¶åªã
ãã®æ²žç¹ä»¥äžã§ããããã«ãéžæãããã奜é©ãª
溶åªã¯ããããµã³ããžãšãã«ãšãŒãã«ããžã¯ãã«
ãšã¿ã³ãããã³è³éŠæç©è³ªãäŸãã°ãã«ãšã³ãŸã
ã¯ãã·ã¬ã³ã§ããã
å¿çæç©ã¯ãèèªé žåå¿åªäœãå¯æº¶æ§ã§ãããã€
C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ãäž
溶æ§ã§ãã溶åªã«å¥œãŸããã¯ååæ£ããããåå¿
æ··åç©ãå·åŽããã枩床ããã³æº¶åªã¯ãåå¿æ··å
ç©ãåãæ±ãã«ååãªçšæµåæ§ã§ãããã€æº¶åªã
ãã®æ²žç¹ä»¥äžã§ããããã«ãéžæãããã奜é©ãª
溶åªã¯ããããµã³ããžãšãã«ãšãŒãã«ããžã¯ãã«
ãšã¿ã³ãããã³è³éŠæç©è³ªãäŸãã°ãã«ãšã³ãŸã
ã¯ãã·ã¬ã³ã§ããã
次ãã§ãC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ã
ããŒãåºäœã¯ãéã«ãã€ãŠé€å»ãããäžæ¹æ¶²
ã¯ãããèªäœäŸãã°æŽ»æ§çã§åŠçãããŠçè²äœã
é€å»ãããæåŸã«ãçæ°Žæ§æº¶åªã¯ãèžçºã«ãã€ãŠ
èèªé žããåé¢ããããããŠæº¶åªããã³èèªé žã®
äž¡æ¹ã¯ãæ¬æ³ã«ããããããã®ããããã®äœ¿çšç¹
ã«å埪ç°ãããã
ããŒãåºäœã¯ãéã«ãã€ãŠé€å»ãããäžæ¹æ¶²
ã¯ãããèªäœäŸãã°æŽ»æ§çã§åŠçãããŠçè²äœã
é€å»ãããæåŸã«ãçæ°Žæ§æº¶åªã¯ãèžçºã«ãã€ãŠ
èèªé žããåé¢ããããããŠæº¶åªããã³èèªé žã®
äž¡æ¹ã¯ãæ¬æ³ã«ããããããã®ããããã®äœ¿çšç¹
ã«å埪ç°ãããã
倧éšåã®æªåå¿èèªæã«ã«ãã³é
žåå¿åªäœãæ®
çºãããæ¬çºæã®æ¹æ³ã®å ·äœäŸã«ãããŠã¯ïŒå³
ã¡ãççŽ æ°ïŒã12ãæããèèªæã«ã«ãã³é žãæŽ
ã«å¥œãŸããã¯ççŽ æ°çŽïŒãçŽïŒãæãããã®ãå©
çšããå ·äœäŸãç¹ã«C7ãC9éç·ç¶èèªæã«ã«ã
ã³é žã䜿çšããå ·äœäŸã«ãããŠïŒãå·åŽãããå
å¿æ··åç©ã¯ãææ©çµåå€ç©è³ªãšæ··åããããããŠ
æŽã«ã¯ç²Ÿè£œããã«ç²ç¶ç©ã«æ圢ããåŸããçµå
å€ãäŸãã°éåžžåºäœã®éã€ãªã³çé¢æŽ»æ§å€ãããª
ãšãã¬ã³ã°ãªã³ãŒã«ãèèªé žãæãçš®ã®é°ã€ãªã³
çé¢æŽ»æ§å€ããã€ã«ã 圢ææ§éåäœãŸãã¯ããã
ã®æ··åç©ãã䜿çšããåŸããå°ãªããšã40âã®çµ
åå€èç¹ãã貯èµå®å®æ§ãç²ç¶ç©ã«äžããããã«
å¿ èŠã§ããããçµåå€ã®èç¹ã¯80âæªæºã§ããã¹
ãã§ããã奜ãŸããã¯50ã70âã®ç¯å²å ã§ããã¹
ãã§ããã
çºãããæ¬çºæã®æ¹æ³ã®å ·äœäŸã«ãããŠã¯ïŒå³
ã¡ãççŽ æ°ïŒã12ãæããèèªæã«ã«ãã³é žãæŽ
ã«å¥œãŸããã¯ççŽ æ°çŽïŒãçŽïŒãæãããã®ãå©
çšããå ·äœäŸãç¹ã«C7ãC9éç·ç¶èèªæã«ã«ã
ã³é žã䜿çšããå ·äœäŸã«ãããŠïŒãå·åŽãããå
å¿æ··åç©ã¯ãææ©çµåå€ç©è³ªãšæ··åããããããŠ
æŽã«ã¯ç²Ÿè£œããã«ç²ç¶ç©ã«æ圢ããåŸããçµå
å€ãäŸãã°éåžžåºäœã®éã€ãªã³çé¢æŽ»æ§å€ãããª
ãšãã¬ã³ã°ãªã³ãŒã«ãèèªé žãæãçš®ã®é°ã€ãªã³
çé¢æŽ»æ§å€ããã€ã«ã 圢ææ§éåäœãŸãã¯ããã
ã®æ··åç©ãã䜿çšããåŸããå°ãªããšã40âã®çµ
åå€èç¹ãã貯èµå®å®æ§ãç²ç¶ç©ã«äžããããã«
å¿ èŠã§ããããçµåå€ã®èç¹ã¯80âæªæºã§ããã¹
ãã§ããã奜ãŸããã¯50ã70âã®ç¯å²å ã§ããã¹
ãã§ããã
çµåå€ç©è³ªãšããŠå¥œé©ãªäžçŸ€ã®éã€ãªã³çé¢æŽ»
æ§å€ã¯ãã¢ã«ã³ãŒã«ïŒã¢ã«åœããçŽ20ãçŽ100ã¢
ã«ã®ãšãã¬ã³ãªãã·ããå«æããã第äžçŽãŸãã¯
第äºçŽC8ãC18ã¢ã«ã³ãŒã«ãšããã·ã¬ãŒãã«ãã€
ãŠæ§æããããç¹å®ã®äŸã¯ãã¢ã«ã³ãŒã«ïŒã¢ã«åœ
ããå¹³å22ã80ã¢ã«ã®ãšãã¬ã³ãªãã·ããšçž®åã
ããã¿ããŒã¢ã«ã³ãŒã«ãšããã·ã¬ãŒãã§ãããç¹
ã«å¥œãŸããçµåå€ã§ããéãšããã·åéã€ãªã³ç
é¢æŽ»æ§å€ã¯ã1983幎ïŒæ27æ¥åºé¡ã®è±åœç¹èš±åºé¡
第8323127å·æ现æžã«é瀺ã®ã°ãªã»ãªã«ã¢ãC10ã
C14èèªé žãšã¹ãã«ã§ããã奜é©ãªããªãšãã¬ã³
ã°ãªã³ãŒã«ã¯ãååéçŽ2000ãçŽ15000ãæŽã«å¥œ
ãŸããã¯çŽ4000ãçŽ8000ã®ãã®ã§ããã奜é©ãªè
èªé žã¯ã奜ãŸããã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ãŸã
ã¯éã€ãªã³çé¢æŽ»æ§å€ãšã®æ··åç©ã§äœ¿çšããã
C12ãC18èèªé žã§ãããé°ã€ãªã³çé¢æŽ»æ§å€ã¯ã
äŸãã°ç³ãããαâã¹ã«ãã³åèèªé žå¡©ãã¢ã«ã
ã«ã°ãªã»ãªã«ãšãŒãã«ã¹ã«ãããŒããã¢ã«ã³ãŒã«
ïŒã¢ã«åœããçŽ10ã¢ã«ãŸã§ã®ãšãã¬ã³ãªãã·ãã
å«æããã¢ã«ãã«ãšããã·ãµã«ããšãŒãããã³ã¢
ã«ãã«ãã³ãŒã³ã§ããã
æ§å€ã¯ãã¢ã«ã³ãŒã«ïŒã¢ã«åœããçŽ20ãçŽ100ã¢
ã«ã®ãšãã¬ã³ãªãã·ããå«æããã第äžçŽãŸãã¯
第äºçŽC8ãC18ã¢ã«ã³ãŒã«ãšããã·ã¬ãŒãã«ãã€
ãŠæ§æããããç¹å®ã®äŸã¯ãã¢ã«ã³ãŒã«ïŒã¢ã«åœ
ããå¹³å22ã80ã¢ã«ã®ãšãã¬ã³ãªãã·ããšçž®åã
ããã¿ããŒã¢ã«ã³ãŒã«ãšããã·ã¬ãŒãã§ãããç¹
ã«å¥œãŸããçµåå€ã§ããéãšããã·åéã€ãªã³ç
é¢æŽ»æ§å€ã¯ã1983幎ïŒæ27æ¥åºé¡ã®è±åœç¹èš±åºé¡
第8323127å·æ现æžã«é瀺ã®ã°ãªã»ãªã«ã¢ãC10ã
C14èèªé žãšã¹ãã«ã§ããã奜é©ãªããªãšãã¬ã³
ã°ãªã³ãŒã«ã¯ãååéçŽ2000ãçŽ15000ãæŽã«å¥œ
ãŸããã¯çŽ4000ãçŽ8000ã®ãã®ã§ããã奜é©ãªè
èªé žã¯ã奜ãŸããã¯ããªãšãã¬ã³ã°ãªã³ãŒã«ãŸã
ã¯éã€ãªã³çé¢æŽ»æ§å€ãšã®æ··åç©ã§äœ¿çšããã
C12ãC18èèªé žã§ãããé°ã€ãªã³çé¢æŽ»æ§å€ã¯ã
äŸãã°ç³ãããαâã¹ã«ãã³åèèªé žå¡©ãã¢ã«ã
ã«ã°ãªã»ãªã«ãšãŒãã«ã¹ã«ãããŒããã¢ã«ã³ãŒã«
ïŒã¢ã«åœããçŽ10ã¢ã«ãŸã§ã®ãšãã¬ã³ãªãã·ãã
å«æããã¢ã«ãã«ãšããã·ãµã«ããšãŒãããã³ã¢
ã«ãã«ãã³ãŒã³ã§ããã
çµåå€ã¯ãåå¿çæç©ãåå¿å®¹åšããé€å»ãã
ãåŸåå¿çæç©ã«æ·»å ãããããåå¿å®¹åšèªäœã«
çŽæ¥æ·»å ããåŸããåŸè ã®å¥œãŸããæè¡ã«ãããŠ
ã¯ãåå¿çæç©ã¯ã液äœãšããŠç¶æããããããŠ
çµåå€ãäžæŽ»æ§ã¬ã¹é°å²æ°äžã§æ¶²äœåœ¢æ ã§æ·»å ã
ããããããããã¹ãŠã®å Žåã«ãããŠãç²ç¶ç©åœ¢
æåã«çµåå€ãšåå¿çæç©ãšã®ç·å¯æ··åç©ã調補
ããããšããå¿ é ã§ããããã®çš®ã®ç²ç¶ç©ã®å¥œãŸ
ãã調補æ³ã¯ã1982幎11æ15æ¥åºé¡ã®ç±³åœç¹èš±ç¬¬
441978å·æ现æžã«é瀺ãããã€è«æ±ãããŠããã
ãåŸåå¿çæç©ã«æ·»å ãããããåå¿å®¹åšèªäœã«
çŽæ¥æ·»å ããåŸããåŸè ã®å¥œãŸããæè¡ã«ãããŠ
ã¯ãåå¿çæç©ã¯ã液äœãšããŠç¶æããããããŠ
çµåå€ãäžæŽ»æ§ã¬ã¹é°å²æ°äžã§æ¶²äœåœ¢æ ã§æ·»å ã
ããããããããã¹ãŠã®å Žåã«ãããŠãç²ç¶ç©åœ¢
æåã«çµåå€ãšåå¿çæç©ãšã®ç·å¯æ··åç©ã調補
ããããšããå¿ é ã§ããããã®çš®ã®ç²ç¶ç©ã®å¥œãŸ
ãã調補æ³ã¯ã1982幎11æ15æ¥åºé¡ã®ç±³åœç¹èš±ç¬¬
441978å·æ现æžã«é瀺ãããã€è«æ±ãããŠããã
æ¬çºæã®æ¹æ³ã®å¥œãŸããå
·äœäŸã«ãããŠã¯ã
C2ãC3ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã¯ã
ãšã¹ãã«äº€æåå¿ãçããããã®ã«äœ¿çšãããã®
ãšåäžã®åå¿åšå ã§çæããããããŠäž¡åå¿çšã®
ãã¹ãŠã®æåã¯ãäžç·ã«æ·»å ãããããã®ãã
ã«ãããšããŒã«ã¹ã«ãã³é žãããªãŠã ããã³C2
ãC3ã¢ã«ã«ã³é žç¡æ°Žç©ïŒéåžžçŽ20ïŒ ã¢ã«éå°ïŒ
ã¯ã液ç¶C6ãC18èèªæã«ã«ãã³é žïŒããšããŒã«
ã¹ã«ãããŒãã®ïŒåã¢ã«éã§ååšïŒã«æ·»å ããã
ãããŠç³»ã¯ãéæµäžã§çŽ160âãçŽ175âã®ç¯å²å
ã®åå¿åšæž©åºŠã«ãããŠçŽïŒãïŒæéå ç±ãããã
次ãã§ãéæµã¯åæ¢ããããããŠåå¿åšæž©åºŠã¯ã
45ã90åéã«ããã€ãŠ200âã220âã®ç¯å²å ã®å€
ã«ææž©ããããã®éã«éå°ã®æªåå¿C2ãC3ã¢ã«
ã«ã³é žç¡æ°Žç©ããã³å¯çç©C2ãC3ã¢ã«ã«ã³é žã¯ã
é€å»ããããã®åŸçæç©ããã³åå¿åªäœã®åé¢ã
ãã³ååã¯ãåèšã®ããã«å®æœãããã
C2ãC3ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãããŒãã¯ã
ãšã¹ãã«äº€æåå¿ãçããããã®ã«äœ¿çšãããã®
ãšåäžã®åå¿åšå ã§çæããããããŠäž¡åå¿çšã®
ãã¹ãŠã®æåã¯ãäžç·ã«æ·»å ãããããã®ãã
ã«ãããšããŒã«ã¹ã«ãã³é žãããªãŠã ããã³C2
ãC3ã¢ã«ã«ã³é žç¡æ°Žç©ïŒéåžžçŽ20ïŒ ã¢ã«éå°ïŒ
ã¯ã液ç¶C6ãC18èèªæã«ã«ãã³é žïŒããšããŒã«
ã¹ã«ãããŒãã®ïŒåã¢ã«éã§ååšïŒã«æ·»å ããã
ãããŠç³»ã¯ãéæµäžã§çŽ160âãçŽ175âã®ç¯å²å
ã®åå¿åšæž©åºŠã«ãããŠçŽïŒãïŒæéå ç±ãããã
次ãã§ãéæµã¯åæ¢ããããããŠåå¿åšæž©åºŠã¯ã
45ã90åéã«ããã€ãŠ200âã220âã®ç¯å²å ã®å€
ã«ææž©ããããã®éã«éå°ã®æªåå¿C2ãC3ã¢ã«
ã«ã³é žç¡æ°Žç©ããã³å¯çç©C2ãC3ã¢ã«ã«ã³é žã¯ã
é€å»ããããã®åŸçæç©ããã³åå¿åªäœã®åé¢ã
ãã³ååã¯ãåèšã®ããã«å®æœãããã
æ¬çºæã®ãšã¹ãã«äº€ææ³ã¯ããã®çš®ã®åå¿ã«é
垞䜿çšããã觊åªãèšåããã«èšèŒãããŠããã
åºé¡äººã¯ãé©ç°çãªããšã«ãæ·»å 觊åªãæ¬çºæã®
æ¹æ³ãå®æœããã®ã«å¿ é ã§ã¯ãªãããšãããã³è¯
奜ãªè²ã®çæç©ã®é«åçã觊åªã䜿çšããã«åèš
æ¡ä»¶äžã§åŸãããããšãèŠãåºããŠãããããã«
ãæãããé žæ§åããã³å¡©åºæ§åã®äž¡æ¹ã®è§Šåªã®
䜿çšã¯ãåå¿é床è«ãé«ãããšèããããã
垞䜿çšããã觊åªãèšåããã«èšèŒãããŠããã
åºé¡äººã¯ãé©ç°çãªããšã«ãæ·»å 觊åªãæ¬çºæã®
æ¹æ³ãå®æœããã®ã«å¿ é ã§ã¯ãªãããšãããã³è¯
奜ãªè²ã®çæç©ã®é«åçã觊åªã䜿çšããã«åèš
æ¡ä»¶äžã§åŸãããããšãèŠãåºããŠãããããã«
ãæãããé žæ§åããã³å¡©åºæ§åã®äž¡æ¹ã®è§Šåªã®
䜿çšã¯ãåå¿é床è«ãé«ãããšèããããã
奜é©ãªè§Šåªã¯ãäŸãã°ããã«ãã¿ããŒãããã«
ãšã³ã¹ã«ãã³é žãéå±ãã°ãã·ãŠã ïŒç²æ«ç¶ïŒã
ãããªãŠã ã¡ããã·ãããã³é ¢é žãããªãŠã ã§ã
ããããããæãå Žåã«ã¯ãC6ãC18ã¢ã·ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãããŒãçæç©å ã®è§Šåªã®ä¿æ
ã¯ããã«ãªãã·é žçºççšã®C6ãC18ã¢ã·ã«ãªãã·
ãã³ãŒã³ã¹ã«ãããŒãçæç©ã®äœ¿çšæã«åé¡ãç
ãããç¹ã«ãçæç©åºæºã§200ppm以äžã®ãã¿ã³
ã¯ãåé§ç©è³ªããçæããããã«ãªãã·é žã®é床
ã®å解ãçããããã觊åªæ±æç©ãäŸãã°ãã¿ã³
ã¯ãè¿œå ã®ä»äžæ®µéã§é€å»ããåŸããããã®ããš
ã¯åŠçã®è€éãããã³ã³ã¹ãã®å¢å€§ã®ãã補é èŠ
å°ããæãŸãããªãã
ãšã³ã¹ã«ãã³é žãéå±ãã°ãã·ãŠã ïŒç²æ«ç¶ïŒã
ãããªãŠã ã¡ããã·ãããã³é ¢é žãããªãŠã ã§ã
ããããããæãå Žåã«ã¯ãC6ãC18ã¢ã·ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãããŒãçæç©å ã®è§Šåªã®ä¿æ
ã¯ããã«ãªãã·é žçºççšã®C6ãC18ã¢ã·ã«ãªãã·
ãã³ãŒã³ã¹ã«ãããŒãçæç©ã®äœ¿çšæã«åé¡ãç
ãããç¹ã«ãçæç©åºæºã§200ppm以äžã®ãã¿ã³
ã¯ãåé§ç©è³ªããçæããããã«ãªãã·é žã®é床
ã®å解ãçããããã觊åªæ±æç©ãäŸãã°ãã¿ã³
ã¯ãè¿œå ã®ä»äžæ®µéã§é€å»ããåŸããããã®ããš
ã¯åŠçã®è€éãããã³ã³ã¹ãã®å¢å€§ã®ãã補é èŠ
å°ããæãŸãããªãã
åŸã€ãŠãå¡©åºæ§è§ŠåªãäŸãã°ãã°ãã·ãŠã ãã
ã³ãããªãŠã ã奜ãŸããããåŸè ã®ã¡ã¿ããŒã«æº¶
液ã®äœ¿çšã¯å¥œãŸãããã¯ã³ããããåå¿ã«ãããŠ
å€éã®C2ãC3ã¢ã«ã«ã³é žç¡æ°Žç©ãå¿ èŠãšããã
æã奜ãŸãã觊åªã¯ãåŒ±é žã®ã¢ã«ã«ãªéå±å¡©ãç¹
ã«ã¢ã«ã«ãªéå±ã¢ã«ãã«ã«ã«ãã³é žå¡©ã§ãããæ
ã奜ãŸããå¡©ã¯ãé«æ®çºæ§ãæããèèªé žã®å¡©ã
äŸãã°é ¢é žãããªãŠã ãããããªã³é žãããªãŠã
ãŸãã¯ããã³é žãããªãŠã ã§ããããã®çç±ã¯ã
ããããç³»ãã容æã«æé€ãããããã«ãã€ãŠç
æç©ã®æ±æãåé¿ããããã§ãããæ·»å 觊åªã¯ã
åºäœã¹ã«ãããŒãæåã®ééã®0.5ïŒ ãïŒïŒ ã®é
ã§äœ¿çšããããããŠç²ç¶ç©åæ£æ¶²ã調補ãããé
ã«ãããšäžç·ã«æ·»å ãããã
ã³ãããªãŠã ã奜ãŸããããåŸè ã®ã¡ã¿ããŒã«æº¶
液ã®äœ¿çšã¯å¥œãŸãããã¯ã³ããããåå¿ã«ãããŠ
å€éã®C2ãC3ã¢ã«ã«ã³é žç¡æ°Žç©ãå¿ èŠãšããã
æã奜ãŸãã觊åªã¯ãåŒ±é žã®ã¢ã«ã«ãªéå±å¡©ãç¹
ã«ã¢ã«ã«ãªéå±ã¢ã«ãã«ã«ã«ãã³é žå¡©ã§ãããæ
ã奜ãŸããå¡©ã¯ãé«æ®çºæ§ãæããèèªé žã®å¡©ã
äŸãã°é ¢é žãããªãŠã ãããããªã³é žãããªãŠã
ãŸãã¯ããã³é žãããªãŠã ã§ããããã®çç±ã¯ã
ããããç³»ãã容æã«æé€ãããããã«ãã€ãŠç
æç©ã®æ±æãåé¿ããããã§ãããæ·»å 觊åªã¯ã
åºäœã¹ã«ãããŒãæåã®ééã®0.5ïŒ ãïŒïŒ ã®é
ã§äœ¿çšããããããŠç²ç¶ç©åæ£æ¶²ã調補ãããé
ã«ãããšäžç·ã«æ·»å ãããã
æ¬çºæã®æ¹æ³ã¯ãC9èèªæã«ã«ãã³é
žãããš
ããŒã«ã¹ã«ãã³é žãããªãŠã ããã³ç¡æ°Žé ¢é žãšå
å¿ãããŠC9ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žã
ããªãŠã ãçæãã以äžã®äŸã«ãã€ãŠäŸç€ºããåŸ
ãã
ããŒã«ã¹ã«ãã³é žãããªãŠã ããã³ç¡æ°Žé ¢é žãšå
å¿ãããŠC9ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žã
ããªãŠã ãçæãã以äžã®äŸã«ãã€ãŠäŸç€ºããåŸ
ãã
äŸ ïŒ
ãããã€ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é
žãããªãŠ
ã ã®ïŒæ®µé觊åªäœçšçæ 500mlã®ïŒå£åå¿ãã©ã¹ã³ã«ã¯ãããã³é ž79.61
ïœïŒ0.5ã¢ã«ïŒãç¡æ°ŽããšããŒã«ã¹ã«ãã³é žãããª
ãŠã 19.62ïœïŒ0.1ã¢ã«ïŒããã³ç¡æ°Žé ¢é ž12.25ïœ
ïŒ0.12ã¢ã«ïŒãä»èŸŒãŸããããã©ã¹ã³ã«ã¯ãå ç±
ãžã€ã±ãããæ¹ææ©ãçªçŽ å ¥å£ããã³ãªãŒããŒã
ããå·åŽåšãšçåºç©æé容åšãšãèšãããã40cm
ã®å ç±ä¿æž©ãã°ã©ãŠã¯ã¹ïŒVigraauxïŒã«ã©ã ã
åãä»ããããŠãããä»èŸŒåŸããã©ã¹ã³ã¯çªçŽ ã§
ãã©ãã·ãŠãããçªçŽ äŸçµŠæ©ã¯ãã°ã©ãŠã¯ã¹ã«ã©
ã ã®é éšã«é£çµããããããŠåå¿æ··åç©ã®å ç±ã
ãã³æ¹æã¯éå§ããããæ··åç©ã®æž©åºŠã¯ã30ååŸ
ã«130âã«éãã40ååŸã«170âã«éãããã®ç¹ã§
æ·¡é»è²ãåãã泡ããããåå¿æ··åç©äžã«è¡šãã
ãã次ãã§ãç³»ã¯éæµäžã§å¹³åãã©ã¹ã³æž©åºŠ
172.5âã§115åéæäœããããã®åŸæ³¡ãããã¯æ¶
ããããã°ã©ãŠã¯ã«ã©ã ã®é éšãžã®çªçŽ 絊éæ©ã¯
åé¢ãããã«ã©ã å ç±åšã¯äœåããããããŠçªçŽ
ã¯åå¿ãã©ã¹ã³ã«ééãããŠèžçãä¿é²ãããã
åå¿æ··åç©ã®æž©åºŠã¯ã70åã«ããã€ãŠæ倧216â
ã«ææž©ããããã®æã«é ¢é žããã³ããã³é žãããª
ãçåºç©22.90ïœãæéããããçåºç©ã®GLCå
æã¯ãç¡æ°Žé ¢é žãååšããŠããªãããšã瀺ããã
åå¿ãã©ã¹ã³ã®æ®çå 容ç©ãå³ã¡æ·¡é»è²ããŠç¶ã
ãŒã¹ãã¯äžå€åžžæž©ã«å·åŽããã次ãã§ãžãšãã«ãš
ãŒãã«ïŒã«åæ£ããããããŠéãããããã®
æäœã¯ïŒåç¹°ãè¿ããããããŠæçµçæç©ã¯ç空
ãã·ã±ãŒã¿ãŒå ã§ä¹Ÿç¥ããããããŠåŸ®ç²æ«ã«ç²ç
ããããæçµåéã¯çœè²åºäœ28.74ïœã§ãããã
ã®NMRåæã¯ä»¥äžã®å€ïŒééïŒãäžããã
ã ã®ïŒæ®µé觊åªäœçšçæ 500mlã®ïŒå£åå¿ãã©ã¹ã³ã«ã¯ãããã³é ž79.61
ïœïŒ0.5ã¢ã«ïŒãç¡æ°ŽããšããŒã«ã¹ã«ãã³é žãããª
ãŠã 19.62ïœïŒ0.1ã¢ã«ïŒããã³ç¡æ°Žé ¢é ž12.25ïœ
ïŒ0.12ã¢ã«ïŒãä»èŸŒãŸããããã©ã¹ã³ã«ã¯ãå ç±
ãžã€ã±ãããæ¹ææ©ãçªçŽ å ¥å£ããã³ãªãŒããŒã
ããå·åŽåšãšçåºç©æé容åšãšãèšãããã40cm
ã®å ç±ä¿æž©ãã°ã©ãŠã¯ã¹ïŒVigraauxïŒã«ã©ã ã
åãä»ããããŠãããä»èŸŒåŸããã©ã¹ã³ã¯çªçŽ ã§
ãã©ãã·ãŠãããçªçŽ äŸçµŠæ©ã¯ãã°ã©ãŠã¯ã¹ã«ã©
ã ã®é éšã«é£çµããããããŠåå¿æ··åç©ã®å ç±ã
ãã³æ¹æã¯éå§ããããæ··åç©ã®æž©åºŠã¯ã30ååŸ
ã«130âã«éãã40ååŸã«170âã«éãããã®ç¹ã§
æ·¡é»è²ãåãã泡ããããåå¿æ··åç©äžã«è¡šãã
ãã次ãã§ãç³»ã¯éæµäžã§å¹³åãã©ã¹ã³æž©åºŠ
172.5âã§115åéæäœããããã®åŸæ³¡ãããã¯æ¶
ããããã°ã©ãŠã¯ã«ã©ã ã®é éšãžã®çªçŽ 絊éæ©ã¯
åé¢ãããã«ã©ã å ç±åšã¯äœåããããããŠçªçŽ
ã¯åå¿ãã©ã¹ã³ã«ééãããŠèžçãä¿é²ãããã
åå¿æ··åç©ã®æž©åºŠã¯ã70åã«ããã€ãŠæ倧216â
ã«ææž©ããããã®æã«é ¢é žããã³ããã³é žãããª
ãçåºç©22.90ïœãæéããããçåºç©ã®GLCå
æã¯ãç¡æ°Žé ¢é žãååšããŠããªãããšã瀺ããã
åå¿ãã©ã¹ã³ã®æ®çå 容ç©ãå³ã¡æ·¡é»è²ããŠç¶ã
ãŒã¹ãã¯äžå€åžžæž©ã«å·åŽããã次ãã§ãžãšãã«ãš
ãŒãã«ïŒã«åæ£ããããããŠéãããããã®
æäœã¯ïŒåç¹°ãè¿ããããããŠæçµçæç©ã¯ç空
ãã·ã±ãŒã¿ãŒå ã§ä¹Ÿç¥ããããããŠåŸ®ç²æ«ã«ç²ç
ããããæçµåéã¯çœè²åºäœ28.74ïœã§ãããã
ã®NMRåæã¯ä»¥äžã®å€ïŒééïŒãäžããã
ãããã€ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é
žãããªãŠ
ã 80.3ïŒ ã¢ã»ããã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã
16.3ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 3.4ïŒ ãããã€ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠ
ã ã®å šåçã¯ãçè«å€ã®69ïŒ ã§ãã€ãã
ã 80.3ïŒ ã¢ã»ããã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã
16.3ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 3.4ïŒ ãããã€ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠ
ã ã®å šåçã¯ãçè«å€ã®69ïŒ ã§ãã€ãã
äŸ ïŒ
ãã«ãšã³ã¹ã«ãã³é
žè§Šåªã䜿çšããŠã®ãããã€
ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã®ïŒæ®µ
çæ åèšã®ãã®ãšåæ§ã®æäœããã³è£ 眮ã䜿çšãã
ãã以äžã®å·®ããã€ããïœâãã«ãšã³ã¹ã«ãã³é ž
ïŒïœããåå¿éå§åã«ãã©ã¹ã³å 容ç©ã«æ·»å ã
ãããããŠéæµæ®µéã¯ããã©ã¹ã³æž©åºŠ170âã§95
åããã€ããèžç段éã¯50åãããããããŠæ倧
ãã©ã¹ã³æž©åºŠã¯202âã§ãã€ããåå¿ããã®å šå
éã¯ç°è²åºäœ28ïœã§ããããã®NMRåæã¯ä»¥äž
ã®å€ïŒééïŒã瀺ããã
ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã®ïŒæ®µ
çæ åèšã®ãã®ãšåæ§ã®æäœããã³è£ 眮ã䜿çšãã
ãã以äžã®å·®ããã€ããïœâãã«ãšã³ã¹ã«ãã³é ž
ïŒïœããåå¿éå§åã«ãã©ã¹ã³å 容ç©ã«æ·»å ã
ãããããŠéæµæ®µéã¯ããã©ã¹ã³æž©åºŠ170âã§95
åããã€ããèžç段éã¯50åãããããããŠæ倧
ãã©ã¹ã³æž©åºŠã¯202âã§ãã€ããåå¿ããã®å šå
éã¯ç°è²åºäœ28ïœã§ããããã®NMRåæã¯ä»¥äž
ã®å€ïŒééïŒã瀺ããã
ãããã€ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é
žãããªãŠ
ã 94.8ïŒ ïœâãã«ãšã³ã¹ã«ãã³é žãããªãŠã 3.6ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 1.6ïŒ å šåçã¯ãçè«å€ã®83.1ïŒ ã§ãã€ãã
ã 94.8ïŒ ïœâãã«ãšã³ã¹ã«ãã³é žãããªãŠã 3.6ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 1.6ïŒ å šåçã¯ãçè«å€ã®83.1ïŒ ã§ãã€ãã
äŸ ïŒ
ãã°ãã·ãŠã ç²æ«ã䜿çšããŠã®ãããã€ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã®ïŒæ®µçæ æäœããã³è£ 眮ã¯ãåèšã®éãã§ãã€ãããã°
ãã·ãŠã ç²æ«0.1ïœããåå¿éå§åã«ãã©ã¹ã³ã«
æ·»å ããããããŠéæµæž©åºŠ167âã115åé䜿çšã
ãããæ倧åå¿æ··åç©æž©åºŠ215âã䜿çšããŠãèž
çã¯65åããã€ããMg0.11ïŒ ïŒåååžå ã«ããïŒ
ãå«æããçœè²åºäœçæç©30.4ïœãåŸããããã
ãŠNMRåæã¯ä»¥äžã®å€ïŒééïŒã瀺ããã
ã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã®ïŒæ®µçæ æäœããã³è£ 眮ã¯ãåèšã®éãã§ãã€ãããã°
ãã·ãŠã ç²æ«0.1ïœããåå¿éå§åã«ãã©ã¹ã³ã«
æ·»å ããããããŠéæµæž©åºŠ167âã115åé䜿çšã
ãããæ倧åå¿æ··åç©æž©åºŠ215âã䜿çšããŠãèž
çã¯65åããã€ããMg0.11ïŒ ïŒåååžå ã«ããïŒ
ãå«æããçœè²åºäœçæç©30.4ïœãåŸããããã
ãŠNMRåæã¯ä»¥äžã®å€ïŒééïŒã瀺ããã
ãããã€ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é
žãããªãŠ
ã 91.4ïŒ ã¢ã»ããã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã
2.7ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 5.9ïŒ å šåçã¯ãçè«å€ã®82.7ïŒ ã§ãã€ãã
ã 91.4ïŒ ã¢ã»ããã·ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã
2.7ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 5.9ïŒ å šåçã¯ãçè«å€ã®82.7ïŒ ã§ãã€ãã
äŸ ïŒ
é
¢é
žãããªãŠã ã䜿çšããŠã®ãããã€ã«ãªãã·
ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã®ïŒæ®µçæ æäœããã³è£ 眮ã¯ãåèšã®éãã§ããããããŠ
é ¢é žãããªãŠã ïŒïœãã觊åªãšããŠäœ¿çšãããã
éæµã¯166âã§140åãããããããŠèžçã¯65åã
ãã€ãïŒæ倧ãã©ã¹ã³æž©åºŠ218âïŒãçœè²çæç©
32.7ïœãåŸããããã®NMRåæã¯ä»¥äžã®å€ã瀺
ããã
ãã³ãŒã³ã¹ã«ãã³é žãããªãŠã ã®ïŒæ®µçæ æäœããã³è£ 眮ã¯ãåèšã®éãã§ããããããŠ
é ¢é žãããªãŠã ïŒïœãã觊åªãšããŠäœ¿çšãããã
éæµã¯166âã§140åãããããããŠèžçã¯65åã
ãã€ãïŒæ倧ãã©ã¹ã³æž©åºŠ218âïŒãçœè²çæç©
32.7ïœãåŸããããã®NMRåæã¯ä»¥äžã®å€ã瀺
ããã
ãããã€ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é
žãããªãŠ
ã 99ïŒ é ¢é žãããªãŠã ïŒïŒ å šåçã¯ãçè«å€ã®96.3ïŒ ã§ãã€ãã
ã 99ïŒ é ¢é žãããªãŠã ïŒïŒ å šåçã¯ãçè«å€ã®96.3ïŒ ã§ãã€ãã
ãããã®å®éšãããæ¬çºæã®æ¹æ³ã¯ã蚱容å¯èœ
ãªçŽåºŠã®ç©è³ªã®æºè¶³ãªåçãåŸãã®ã«è§Šåªäœçšã
å¿ èŠãšããªãããšãããããåå¿æ¡ä»¶ã®æé©å
ã¯ããã®æ¹æ³ã䜿çšããŠåŸãããåçããã³çŽåºŠ
ãåäžããããšäºæããåŸããå®éšããé žæ§ãã
ã³ïŒãŸãã¯ïŒå¡©åºæ§è§Šåªäœçšãåå¿æéããã³
ïŒãŸãã¯ïŒæž©åºŠã®ççž®ãäœäžãäžããããšã瀺ã
ãŠãããããããé žæ§è§Šåªã¯ã貧匱ãªçæç©ã®è²
ãçããåŸåãããããããŠåèšã®ããã«çæç©
ã®è§Šåªéå±æ±æã¯ãç¡æ©éé žçŽ æŒçœå€ã§ã®éå æ°Ž
å解ã«ãã€ãŠçæãããææ©ãã«ãªãã·é žã®å®å®
æ§ã«æªåœ±é¿ãåãŒãããšããããå¡©åºæ§è§Šåªã¯ã
åäžã®äžå©ããããããªãããéå±ã¢ã«ã³ãã·ã
ã®äœ¿çšã¯ã倧éå°ã®ç¡æ°Žé ¢é žãå¿ èŠãšããããšã«
ãã€ãŠæåã³ã¹ããå¢å€§ãããã奜ãŸãã觊åª
ã¯ãåŒ±é žã®ãããªãŠã å¡©ãäŸãã°ã«ã«ãã³é žã®ã
ããªãŠã å¡©ã§ããããã®çç±ã¯ããããçæç©ã®
æ±æãæå°éã«ãããããŠæ¬æ³ãå®æœããã®ã«å¿
èŠãªåå¿äœã®éãå¢å€§ããªãããã§ããã
ãªçŽåºŠã®ç©è³ªã®æºè¶³ãªåçãåŸãã®ã«è§Šåªäœçšã
å¿ èŠãšããªãããšãããããåå¿æ¡ä»¶ã®æé©å
ã¯ããã®æ¹æ³ã䜿çšããŠåŸãããåçããã³çŽåºŠ
ãåäžããããšäºæããåŸããå®éšããé žæ§ãã
ã³ïŒãŸãã¯ïŒå¡©åºæ§è§Šåªäœçšãåå¿æéããã³
ïŒãŸãã¯ïŒæž©åºŠã®ççž®ãäœäžãäžããããšã瀺ã
ãŠãããããããé žæ§è§Šåªã¯ã貧匱ãªçæç©ã®è²
ãçããåŸåãããããããŠåèšã®ããã«çæç©
ã®è§Šåªéå±æ±æã¯ãç¡æ©éé žçŽ æŒçœå€ã§ã®éå æ°Ž
å解ã«ãã€ãŠçæãããææ©ãã«ãªãã·é žã®å®å®
æ§ã«æªåœ±é¿ãåãŒãããšããããå¡©åºæ§è§Šåªã¯ã
åäžã®äžå©ããããããªãããéå±ã¢ã«ã³ãã·ã
ã®äœ¿çšã¯ã倧éå°ã®ç¡æ°Žé ¢é žãå¿ èŠãšããããšã«
ãã€ãŠæåã³ã¹ããå¢å€§ãããã奜ãŸãã觊åª
ã¯ãåŒ±é žã®ãããªãŠã å¡©ãäŸãã°ã«ã«ãã³é žã®ã
ããªãŠã å¡©ã§ããããã®çç±ã¯ããããçæç©ã®
æ±æãæå°éã«ãããããŠæ¬æ³ãå®æœããã®ã«å¿
èŠãªåå¿äœã®éãå¢å€§ããªãããã§ããã
äŸ ïŒ
é
¢é
žãããªãŠã 觊åªã䜿çšããŠã®ïŒïŒïŒïŒïŒâ
ããªã¡ãã«ãããµãã€ã«ãªãã·ãã³ãŒã³ã¹ã«ã
ã³é žãããªãŠã ã®ïŒæ®µçæ äŸïŒã§äœ¿çšããããã®ãšåæ§ã®æäœããã³è£ 眮
ãã䜿çšãããã以äžã®éã®åå¿äœã䜿çšãã
ãã
ããªã¡ãã«ãããµãã€ã«ãªãã·ãã³ãŒã³ã¹ã«ã
ã³é žãããªãŠã ã®ïŒæ®µçæ äŸïŒã§äœ¿çšããããã®ãšåæ§ã®æäœããã³è£ 眮
ãã䜿çšãããã以äžã®éã®åå¿äœã䜿çšãã
ãã
ïŒïŒïŒïŒïŒâããªã¡ãã«ãããµã³é
žïŒã€ãœãã
ã³å¡©ïŒ 127.85ïœïŒ0.81ã¢ã«ïŒ ç¡æ°Žé ¢é ž 36.75ïœïŒ0.36ã¢ã«ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã
58.85ïœïŒ0.3ã¢ã«ïŒ é ¢é žãããªãŠã ïŒç¡æ°ŽïŒ 3.0ïœ ãã®æ··åç©ã¯ãæµåæ§æžæ¿æ¶²ãäžãããåå¿ã
ã©ã¹ã³å 容ç©ã¯ã160âã«å ç±ããããããŠè£ 眮
ãèžçæ¹åŒã«è»¢æãããåã«çªçŽ é°å²æ°äžã§ïŒ
ïŒïŒïŒæééæµããããããŠãã©ã¹ã³æž©åºŠã¯ã45å ã«ããã€ãŠ260âã«ææž©ããããã®éã«ã€ãœãã
ã³é žãé ¢é žããã³çè·¡éã®ç¡æ°Žé ¢é žã®æ··åç©
59.63ïœããçåºç©å容åšã«æéãããããã®éã
åå¿ãã©ã¹ã³ã®å 容ç©ã¯ãã¯ãªãŒã ç¶çœè²æµåæ§
æžæ¿æ¶²ããæ¹æç¶æ ã«ä¿ã€ããšã®å°é£ãªç²çš ãªçº
泡淡é»è²ã®å¡ã«å€åãããå ç±ã¯åæ¢ããããã
ãŠçªçŽ é°å²æ°ããã©ã¹ã³å ã«ç¶æããªãããå 容
ç©ã®æµåæ§ãåäžãããTAE8040ïœããã©ã¹ã³
ã«æ·»å ãããããã©ã¹ã³ã¯ãå·åŽããããããŠ45
ååŸã«åå¿ãã©ã¹ã³å 容ç©ã®æž©åºŠã¯ã70âã«äžã
ãããã®æ®µéã§ãã©ã¹ã³ã¯ç©ºã«ããããããŠæ··å
ç©ã¯å®€æž©ã«å·åŽãããã以äžã®åæå€ãæããç°
è²ããã€ãçœè²ã®ãããç²ç¶ç©ã®åœ¢æ ã®åå¿çæ
ç©156.83ïœãåŸãããã
ã³å¡©ïŒ 127.85ïœïŒ0.81ã¢ã«ïŒ ç¡æ°Žé ¢é ž 36.75ïœïŒ0.36ã¢ã«ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã
58.85ïœïŒ0.3ã¢ã«ïŒ é ¢é žãããªãŠã ïŒç¡æ°ŽïŒ 3.0ïœ ãã®æ··åç©ã¯ãæµåæ§æžæ¿æ¶²ãäžãããåå¿ã
ã©ã¹ã³å 容ç©ã¯ã160âã«å ç±ããããããŠè£ 眮
ãèžçæ¹åŒã«è»¢æãããåã«çªçŽ é°å²æ°äžã§ïŒ
ïŒïŒïŒæééæµããããããŠãã©ã¹ã³æž©åºŠã¯ã45å ã«ããã€ãŠ260âã«ææž©ããããã®éã«ã€ãœãã
ã³é žãé ¢é žããã³çè·¡éã®ç¡æ°Žé ¢é žã®æ··åç©
59.63ïœããçåºç©å容åšã«æéãããããã®éã
åå¿ãã©ã¹ã³ã®å 容ç©ã¯ãã¯ãªãŒã ç¶çœè²æµåæ§
æžæ¿æ¶²ããæ¹æç¶æ ã«ä¿ã€ããšã®å°é£ãªç²çš ãªçº
泡淡é»è²ã®å¡ã«å€åãããå ç±ã¯åæ¢ããããã
ãŠçªçŽ é°å²æ°ããã©ã¹ã³å ã«ç¶æããªãããå 容
ç©ã®æµåæ§ãåäžãããTAE8040ïœããã©ã¹ã³
ã«æ·»å ãããããã©ã¹ã³ã¯ãå·åŽããããããŠ45
ååŸã«åå¿ãã©ã¹ã³å 容ç©ã®æž©åºŠã¯ã70âã«äžã
ãããã®æ®µéã§ãã©ã¹ã³ã¯ç©ºã«ããããããŠæ··å
ç©ã¯å®€æž©ã«å·åŽãããã以äžã®åæå€ãæããç°
è²ããã€ãçœè²ã®ãããç²ç¶ç©ã®åœ¢æ ã®åå¿çæ
ç©156.83ïœãåŸãããã
ïŒïŒïŒïŒïŒâããªã¡ãã«ãããµãã€ã«ãªãã·ã
ã³ãŒã³ã¹ã«ãã³é žãããªãŠã 55.8ïŒ ïŒïŒïŒïŒïŒâããªã¡ãã«ãããµã³é žãããªãŠã
8.2ïŒ ïŒïŒïŒïŒïŒâããªã¡ãã«ãããµã³é ž 0.7ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 2.8ïŒ ã¿ããŒã¢ã«ã³ãŒã«ïŒEOïŒ80 26.7ïŒ æ°Žããã³åŸ®éæå 5.8ïŒ ããšããŒã«ã¹ã«ãã³é žå¡©è»¢åã«åºã¥ãåå¿åç
ã¯ã86.8ïŒ ã§ãã€ãã
ã³ãŒã³ã¹ã«ãã³é žãããªãŠã 55.8ïŒ ïŒïŒïŒïŒïŒâããªã¡ãã«ãããµã³é žãããªãŠã
8.2ïŒ ïŒïŒïŒïŒïŒâããªã¡ãã«ãããµã³é ž 0.7ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã 2.8ïŒ ã¿ããŒã¢ã«ã³ãŒã«ïŒEOïŒ80 26.7ïŒ æ°Žããã³åŸ®éæå 5.8ïŒ ããšããŒã«ã¹ã«ãã³é žå¡©è»¢åã«åºã¥ãåå¿åç
ã¯ã86.8ïŒ ã§ãã€ãã
äŸ ïŒ
é
¢é
žãããªãŠã 觊åªã䜿çšããŠã®ïŒâããšãã«
ããããªãã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããª
ãŠã ã®ïŒæ®µçæ äŸïŒã§äœ¿çšããããã®ãšåæ§ã®æäœããã³è£ 眮
ã䜿çšãããã以äžã®éã®åå¿äœã䜿çšãããã
ããããªãã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žãããª
ãŠã ã®ïŒæ®µçæ äŸïŒã§äœ¿çšããããã®ãšåæ§ã®æäœããã³è£ 眮
ã䜿çšãããã以äžã®éã®åå¿äœã䜿çšãããã
ïŒâããšãã«ããããªã³é
žïŒãããã±ã€ç®é
žïŒ
ïŒMWT150.2ïŒ 135.18ïœïŒ0.9ã¢ã«ïŒ ç¡æ°Žé ¢é ž 36.75ïœïŒ0.36ã¢ã«ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã
58.85ïœïŒ0.3ã¢ã«ïŒ é ¢é žãããªãŠã ïŒç¡æ°ŽïŒ 3.0ïœ ãããã±ã€ç®é žãç¡æ°Žé ¢é žããã³é ¢é žãããªãŠ
ã ããåå¿ãã©ã¹ã³ã«æ·»å ããããããŠ60âã§ç¡
è²æ¶²äœãçãããããšããŒã«ã¹ã«ãã³é žãããªãŠ
ã ããæ·»å ããããã€æ¹æã«ãã€ãŠåæ£ãããã
ããŠé žåé²æ¢çšçªçŽ ãã©ã³ã±ããã䜿çšããŠæž©åºŠ
ã65âã«ææž©ããããå 容ç©ã¯ãè£ çœ®ãèžçæ¹åŒ
ã«è»¢æãããåã«ïŒïŒïŒïŒæééæµããããèžçæ¹ åŒã«ãããŠããã©ã¹ã³å 容ç©ã¯ã45åã«ããã€ãŠ
260âã®æž©åºŠã«å°éããããããŠæ··åé ¢é žïŒãã
ãã±ã€ç®é ž80.2ïœããçåºç©ãšããŠãã©ã¹ã³ãã
é€å»ããããæ®çãã©ã¹ã³å 容ç©ã¯ãåžžæž©ã«å·åŽ
ããããžãšãã«ãšãŒãã«ã«åæ£ããããããŠé
ãããŠïŒâããšãã«ããããªãã«ãªãã·ãã³ãŒã³
ã¹ã«ãã³é žãããªãŠã 90ééïŒ ããã³ããšããŒã«
ã¹ã«ãã³é žãããªãŠã 1.2ïŒ ïŒæ®éšã¯ïŒâããšã
ã«ããããªã³é žãšãã®ãããªãŠã å¡©ãšã®æ··åç©ã§
ããïŒãå«æããçœè²çµæ¶æ§çæç©97.88ïœãäž
ããã
ïŒMWT150.2ïŒ 135.18ïœïŒ0.9ã¢ã«ïŒ ç¡æ°Žé ¢é ž 36.75ïœïŒ0.36ã¢ã«ïŒ ããšããŒã«ã¹ã«ãã³é žãããªãŠã
58.85ïœïŒ0.3ã¢ã«ïŒ é ¢é žãããªãŠã ïŒç¡æ°ŽïŒ 3.0ïœ ãããã±ã€ç®é žãç¡æ°Žé ¢é žããã³é ¢é žãããªãŠ
ã ããåå¿ãã©ã¹ã³ã«æ·»å ããããããŠ60âã§ç¡
è²æ¶²äœãçãããããšããŒã«ã¹ã«ãã³é žãããªãŠ
ã ããæ·»å ããããã€æ¹æã«ãã€ãŠåæ£ãããã
ããŠé žåé²æ¢çšçªçŽ ãã©ã³ã±ããã䜿çšããŠæž©åºŠ
ã65âã«ææž©ããããå 容ç©ã¯ãè£ çœ®ãèžçæ¹åŒ
ã«è»¢æãããåã«ïŒïŒïŒïŒæééæµããããèžçæ¹ åŒã«ãããŠããã©ã¹ã³å 容ç©ã¯ã45åã«ããã€ãŠ
260âã®æž©åºŠã«å°éããããããŠæ··åé ¢é žïŒãã
ãã±ã€ç®é ž80.2ïœããçåºç©ãšããŠãã©ã¹ã³ãã
é€å»ããããæ®çãã©ã¹ã³å 容ç©ã¯ãåžžæž©ã«å·åŽ
ããããžãšãã«ãšãŒãã«ã«åæ£ããããããŠé
ãããŠïŒâããšãã«ããããªãã«ãªãã·ãã³ãŒã³
ã¹ã«ãã³é žãããªãŠã 90ééïŒ ããã³ããšããŒã«
ã¹ã«ãã³é žãããªãŠã 1.2ïŒ ïŒæ®éšã¯ïŒâããšã
ã«ããããªã³é žãšãã®ãããªãŠã å¡©ãšã®æ··åç©ã§
ããïŒãå«æããçœè²çµæ¶æ§çæç©97.88ïœãäž
ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (a) 液ç¶çœ®æãŸãã¯é眮æC6ãC18èèªæã«
ã«ãã³é žåªäœäžã®C2ãC3ã¢ã·ã«ãªãã·ãã³ãŒ
ã³ã¹ã«ãã³é žå¡©ã®åäžåæ£æ··åç©ã調補ããã€
ç¶æãïŒã«ã«ãã³é žå¯Ÿã¹ã«ãã³é žå¡©ã®ã¢ã«æ¯ã¯
ïŒïŒïŒãè¶ ãããããŠã¹ã«ãã³é žå¡©ã¯ç²ç¶åœ¢æ
ã§ããïŒã (b) æ··åç©ã®æž©åºŠããã¢ã·ããªã·ã¹åå¿ãçãã
ããã€å¯çç©C2ãC3ã¢ã«ã«ã³é žã®æ®çºããã³
é€å»ãå¯èœãšãããã®ã«ååãªå€ã«ææž©ããã
ãã㊠(c) C6ãC18ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©
ãååãã ããšãç¹åŸŽãšãããC6ãC18ã¢ã·ã«ãªãã·ãã³ãŒ
ã³ã¹ã«ãã³é žå¡©ã®è£œæ³ã ïŒ ã«ã«ãã³é žå¯Ÿã¹ã«ãã³é žå¡©ã®ã¢ã«æ¯ããå°ãª
ããšãïŒïŒïŒã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒ
ã®æ¹æ³ã ïŒ ã«ã«ãã³é žå¯Ÿã¹ã«ãã³é žå¡©ã®ã¢ã«æ¯ããå°ãª
ããšãïŒïŒïŒã奜ãŸããã¯å°ãªããšãïŒïŒïŒã§ã
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ããã³ç¬¬ïŒé ã®ãããã
ïŒã€ã«èšèŒã®æ¹æ³ã ïŒ èèªæã«ã«ãã³é žåªäœããã«ã«ããã«ççŽ ã
ãã®ã³ãã€ã«ã«ããã«ççŽ ãå å«ããççŽ æ°å°ãª
ããšãïŒã®ç·ç¶éãå«æããéç·ç¶ã«ã«ãã³é žã§
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®ããããïŒ
ã€ã«èšèŒã®æ¹æ³ã ïŒ éç·ç¶èèªæã«ã«ãã³é žãã1.9ã4.1ã®ç¯å²
å ã®log POCTãæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èš
èŒã®æ¹æ³ã ïŒ éç·ç¶èèªæã«ã«ãã³é žããççŽ æ°ïŒã12ã
奜ãŸããã¯ïŒãïŒãæããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
ããã³ç¬¬ïŒé ã®ããããïŒã€ã«èšèŒã®æ¹æ³ã ïŒ ãšã¹ãã«äº€æ觊åªããã¢ã«ã«ã³é žåªäœã«é
åãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®ããã
ãïŒã€ã«èšèŒã®æ¹æ³ã ïŒ è§Šåªããå¡©åºæ§è§Šåªã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã«èšèŒã®æ¹æ³ã ïŒ å¡©åºæ§è§ŠåªããåŒ±é žã®ã¢ã«ã«ãªéå±å¡©ã奜ãŸ
ããã¯ã¢ã«ã«ãªéå±ã«ã«ãã³é žå¡©ã§ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒïŒ ããšããŒã«ã¹ã«ãã³é žå¡©ããã¢ã«ã«ãªéå±
å¡©ã奜ãŸããã¯ãããªãŠã å¡©ã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé ã第ïŒé ã®ããããïŒã€ã«èšèŒã®æ¹æ³ã ïŒïŒ C2ãC3ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é ž
å¡©ãããã®å Žã§çæãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
ã第ïŒïŒé ã®ããããïŒã€ã«èšèŒã®æ¹æ³ã ïŒïŒ (a) 液ç¶çœ®æãŸãã¯é眮æC6ãC12èèªæ
ã«ã«ãã³é žåªäœäžã®ããšããŒã«ã¹ã«ãã³é žå¡©ã
ãã³C2ãC3ã¢ã«ã«ã³é žç¡æ°Žç©ã®æ··åç©ã調補
ãïŒã«ã«ãã³é žå¯Ÿã¹ã«ãã³é žå¡©ã®ã¢ã«æ¯ã¯ïŒïŒ
ïŒãè¶ ããç¡æ°Žç©å¯Ÿã¹ã«ãã³é žå¡©ã®ã¢ã«æ¯ã¯
ïŒïŒïŒãè¶ ãããããŠã¹ã«ãã³é žå¡©ã¯ç²ç¶åœ¢æ
ã§ããïŒã (b) ããšããŒã«ã¹ã«ãã³é žå¡©ãåå¿ããŠC2ãC3
ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ãçæãã
ãŸã§ãæ··åç©ãéæµäžã§140ã180âã®ç¯å²å ã®
枩床ã«å ç±ãã (c) æ··åç©ã®æž©åºŠãã¢ã·ããªã·ã¹ãçããããã€
å¯çç©C2ãC3ã¢ã«ã«ã³é žã®æ®çºããã³é€å»ã
å¯èœãšãããã®ã«ååãªå€ã«ææž©ããã (d) C6ãC12ã¢ã·ã«ãªãã·ãã³ãŒã³ã¹ã«ãã³é žå¡©
ãååããããšãããªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒ
é ã«èšèŒã®æ¹æ³ã ïŒïŒ ååããçæ°Žæ§æº¶åªäžã®å®å šåå¿æ··åç©ã®
åæ£æ¶²ã調補ãããã®åŸæ²æ®¿C6ãC18ã¢ã·ã«ãªã
ã·ãã³ãŒã³ã¹ã«ãã³é žå¡©ãäžæŸã¿æ¶²ããåé¢ãã
ããšãããªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®
ããããïŒã€ã«èšèŒã®æ¹æ³ã ïŒïŒ äžæŸã¿æ¶²ãå ç±ãããŠæº¶åªãæ®çºãããã
ããŠéå°ã®C6ãC18ã¢ã«ã«ã³é žãå·¥çš(a)ã«å埪ç°
ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®æ¹æ³ã ïŒïŒ ååãã (a) 40âãããé«ãèç¹ã®æ¶²åããéåžžåºäœã®æ°Ž
溶æ§ãŸãã¯æ°Žåæ£æ§ææ©çµåå€åºäœäžã®å®å šå
å¿æ··åç©ã®ç·å¯åæ£æ¶²ã調補ãïŒåèšåæ£ã¯äž
掻æ§ã¬ã¹é°å²æ°äžã§çããïŒã (b) åèšåæ£æ¶²ãå·åŽãããã㊠(c) åèšå·åŽåæ£æ¶²ãåºäœç²ç¶ç©ã«ãã ããšãããªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®
ããããïŒã€ã«èšèŒã®æ¹æ³ã ïŒïŒ éåžžåºäœã®æ°Žæº¶æ§ãŸãã¯æ°Žåæ£æ§ææ©åºäœ
ããã¢ã«ã³ãŒã«ïŒã¢ã«åœããå¹³å20ã100ã¢ã«ã®
ãšãã¬ã³ãªãã·ããšçž®åãããC8ãC18èèªæã¢
ã«ã³ãŒã«ãååé2000ã15000ã®ããªãšãã¬ã³ã°
ãªã³ãŒã«ãC12ãC18èèªé žãŸãã¯åèšååç©ïŒçš®
以äžãšé°ã€ãªã³çé¢æŽ»æ§å€ãšã®æ··åç©ãããªãç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé ã«èšèŒã®æ¹æ³ã
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB8227675 | 1982-09-28 | ||
GB8227675 | 1982-09-28 | ||
GB8311497 | 1983-04-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59134774A JPS59134774A (ja) | 1984-08-02 |
JPH041739B2 true JPH041739B2 (ja) | 1992-01-14 |
Family
ID=10533223
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18009283A Granted JPS59134774A (ja) | 1982-09-28 | 1983-09-28 | ã¹ã«ãã³åææ©ååç©ã®åææ³ |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59134774A (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4916219A (en) * | 1985-03-28 | 1990-04-10 | University Of Iowa Research Foundation | Oligosaccharide heparin fragments as inhibitors of complement cascade |
-
1983
- 1983-09-28 JP JP18009283A patent/JPS59134774A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS59134774A (ja) | 1984-08-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0105672B1 (en) | Synthesis of sulphonated organic compounds | |
EP0105673B1 (en) | Synthesis of hydrophilic phenol ester derivatives | |
EP0227194B1 (en) | Preparation of sulphonated aromatic esters | |
EP3292097A1 (en) | Process for the decarboxylative ketonization of fatty acids or fatty acid derivatives | |
EP0262895B1 (en) | Diperoxyacid precursors process for production thereof and use in bleaching compositions | |
JPH0321541B2 (ja) | ||
EP0859756B1 (en) | Preparation of amido ester compounds | |
JPS636056B2 (ja) | ||
US11702386B2 (en) | Processes for the manufacture of secondary fatty alcohols, internal olefins and internal olefin sulfonates | |
EP0719249A1 (en) | Synthesis of amido acids from carboxylic acid esters and amino acid salts | |
KR870000451B1 (ko) | ì€ëŠ¬ìŒìŽíž ìì€í 륎ì ì ì¡°ë°©ë² | |
GB2081266A (en) | Production of sucrose-fatty acid esters | |
JPH041739B2 (ja) | ||
US6271410B1 (en) | Higher alkyl esters of cyanoacetic acid | |
JPH04273837A (ja) | ïŒâããããã·ã¹ãã¬ã³ã®å¡©ã®è£œé æ¹æ³ | |
EP1212282B1 (en) | Production of aryl carboxylate esters | |
EP0333373B1 (en) | Method for synthesizing acyloxycarboxylic acids | |
US3051748A (en) | Organometallic compounds | |
US3917662A (en) | Preparation of fatty acid esters | |
GB1565663A (en) | Production of esters in the presence of amphoteric catalysts and oxalic acid | |
JPH0623160B2 (ja) | αâã¯ããâαâãªãã·ã€ããâïŒãŒããããã·ã¢ã»ããã§ãã³ã®è£œé | |
US5304690A (en) | Process for the preparation of salts of 4-hydroxystyrene | |
EP3950663A1 (en) | New method for obtaining diester compounds useful for the manufacture of new quaternary ammonium compounds | |
GB2102421A (en) | Process for the preparation of cyclopropane derivatives | |
JPH0212472B2 (ja) |