JPH04173900A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH04173900A JPH04173900A JP2297239A JP29723990A JPH04173900A JP H04173900 A JPH04173900 A JP H04173900A JP 2297239 A JP2297239 A JP 2297239A JP 29723990 A JP29723990 A JP 29723990A JP H04173900 A JPH04173900 A JP H04173900A
- Authority
- JP
- Japan
- Prior art keywords
- polyoxyethylene
- alcohol
- turpentine
- fatty acid
- pinene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 7
- 239000003599 detergent Substances 0.000 title abstract description 3
- -1 polyoxyethylene Polymers 0.000 claims abstract description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 14
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- 241000779819 Syncarpia glomulifera Species 0.000 claims abstract description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 8
- 239000000194 fatty acid Substances 0.000 claims abstract description 8
- 229930195729 fatty acid Natural products 0.000 claims abstract description 8
- 239000001739 pinus spp. Substances 0.000 claims abstract description 8
- 229940036248 turpentine Drugs 0.000 claims abstract description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 6
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims abstract description 6
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 claims abstract description 5
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 claims abstract description 5
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960000686 benzalkonium chloride Drugs 0.000 claims abstract description 4
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 4
- 150000002334 glycols Chemical class 0.000 claims abstract description 4
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 claims abstract description 4
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 claims abstract description 3
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 claims abstract description 3
- 239000001293 FEMA 3089 Substances 0.000 claims abstract description 3
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims abstract description 3
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 claims abstract description 3
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 claims abstract description 3
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229930006722 beta-pinene Natural products 0.000 claims abstract description 3
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229940116411 terpineol Drugs 0.000 claims abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract 2
- 235000019441 ethanol Nutrition 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 9
- 239000003205 fragrance Substances 0.000 claims description 5
- 125000000545 (4R)-limonene group Chemical group 0.000 claims 1
- 229920001214 Polysorbate 60 Polymers 0.000 claims 1
- 239000012190 activator Substances 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 230000001877 deodorizing effect Effects 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 abstract description 5
- 239000002304 perfume Substances 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000005907 alkyl ester group Chemical group 0.000 abstract 1
- 229920000136 polysorbate Polymers 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 15
- 235000019645 odor Nutrition 0.000 description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 230000001954 sterilising effect Effects 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- AFSHUZFNMVJNKX-LLWMBOQKSA-N 1,2-dioleoyl-sn-glycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](CO)OC(=O)CCCCCCC\C=C/CCCCCCCC AFSHUZFNMVJNKX-LLWMBOQKSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- WFSMVVDJSNMRAR-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethanol Chemical compound CCOCCOCCOCCO WFSMVVDJSNMRAR-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- RUPBZQFQVRMKDG-UHFFFAOYSA-M Didecyldimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCC[N+](C)(C)CCCCCCCCCC RUPBZQFQVRMKDG-UHFFFAOYSA-M 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 241000293871 Salmonella enterica subsp. enterica serovar Typhi Species 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- UREZNYTWGJKWBI-UHFFFAOYSA-M benzethonium chloride Chemical compound [Cl-].C1=CC(C(C)(C)CC(C)(C)C)=CC=C1OCCOCC[N+](C)(C)CC1=CC=CC=C1 UREZNYTWGJKWBI-UHFFFAOYSA-M 0.000 description 1
- 229960001950 benzethonium chloride Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000012000 cholesterol Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 229960004670 didecyldimethylammonium chloride Drugs 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 description 1
- UJEZLFUVGBLKNJ-UHFFFAOYSA-N formaldehyde methanethiol Chemical compound C=O.CS UJEZLFUVGBLKNJ-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- JYVNDCLJHKQUHE-UHFFFAOYSA-N hydroxymethyl acetate Chemical compound CC(=O)OCO JYVNDCLJHKQUHE-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229930004725 sesquiterpene Natural products 0.000 description 1
- 150000004354 sesquiterpene derivatives Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000019265 sodium DL-malate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- LPSWFOCTMJQJIS-UHFFFAOYSA-N sulfanium;hydroxide Chemical compound [OH-].[SH3+] LPSWFOCTMJQJIS-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- NIUZJTWSUGSWJI-UHFFFAOYSA-M triethyl(methyl)azanium;chloride Chemical compound [Cl-].CC[N+](C)(CC)CC NIUZJTWSUGSWJI-UHFFFAOYSA-M 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はオレンジ、レモンなどのベースとなるターペン
ティン系香料、グ（従来の技術）
上記用途に使用する洗浄剤としては殆どはアルカリ性で
グリコール、アル酸化剤中心のものが常用されてきてい
る。Detailed Description of the Invention (Industrial Field of Application) The present invention is based on turpentine fragrances such as oranges and lemons (prior art).Most of the cleaning agents used for the above purpose are alkaline and glycol-based. , those based mainly on alkali oxidizing agents have been commonly used.
アルカリ性のものは界面活性剤と苛性ソーダ、苛性力１
ハアンモビア、その他のアルカリビルダーにてＰＨを１
２以上となしてそのアルカリ分解力と界面活性剤の乳化
分散力を利用したものとオレンジ系溶剤や水溶性の溶剤
を併用したものあるいはアルコール（エチル）主剤のア
ルコール消臭剤のものがよく使用されている。然し従来
のものは洗浄力、除菌力、除臭力、及び液の安定性、安
全性のすべてを完全に滴定したものはなく、夫々併用し
ているのが実状である。The alkaline ones are surfactant and caustic soda, caustic power 1
Adjust the pH to 1 with Hanmovia and other alkaline builders.
2 or higher, which utilizes the alkaline decomposition power and the emulsifying and dispersing power of surfactants, and those that use orange-based solvents or water-soluble solvents together, or alcohol deodorants that use alcohol (ethyl) as the main ingredient are often used. has been done. However, none of the conventional products has completely titrated all of the detergency, sterilizing power, deodorizing power, liquid stability, and safety, and the reality is that each is used in combination.
（発明の解決しようとする問題点）
このような実状に鑑みて、洗浄力、除菌力、除臭力、液
の安定性（温度、光、容器の耐久性、外観、におい、性
能の維持）及び安全性の高いしかも使い易い水系の洗浄
剤を開発する必要がある。(Problems to be solved by the invention) In view of the above-mentioned circumstances, cleaning power, sterilizing power, deodorizing power, stability of liquid (temperature, light, durability of container, appearance, odor, maintenance of performance) ) and a water-based cleaning agent that is both highly safe and easy to use.
（問題を解決する為の手段）
本発明者は以上の中から非イオン界面活性剤、カチオン
界面活性剤、低級アルコール類、グリコール及びターペ
ンティン系香料ベースを用いて水中心のＰＨが７以上１
２以下好ましくは８〜１２のアルカリ性の洗浄剤を用い
ることによって上記問題点を解決するのに成功したもの
である。(Means for solving the problem) The present inventor uses a nonionic surfactant, a cationic surfactant, a lower alcohol, a glycol, and a turpentine fragrance base from among the above to increase the pH of the water center from 7 to 1.
The above-mentioned problems have been successfully solved by using an alkaline detergent with a pH of 2 or less, preferably 8 to 12.
具体的には、水を主成分となした水系においてターペン
ティン系溶剤１例えば、Ｄ−リモネン、α−ピネン、β
−ピネン、タービノーレン、ジペンテン、セスキテルペ
ン、ミルセン、テルペンアルコール、ターピネオール、
テレビン油、その他テルペンポリマーなどを非イオン界
面活性剤に分散させる。Specifically, in an aqueous system containing water as a main component, turpentine solvent 1, for example, D-limonene, α-pinene, β
-pinene, terbinolene, dipentene, sesquiterpene, myrcene, terpene alcohol, terpineol,
Turpentine oil or other terpene polymers are dispersed in a nonionic surfactant.
非イオン界面活性剤としてはポリオキシエチレン（ＥＯ
ニア〜２５モル）アルキル（Ｃ８〜Ｃ１５）、エーテル
、フェノールエーテル、ポリオキシエチレン（ＥＯ：２
〜１０モル）、ヤシ油脂肪酸モノエタノールアミド、ポ
リオキシエチレン（Ｅｏ・７〜３０モル）、ソルビタン
脂肪酸エステル（Ｃ１０〜Ｃｌ８）、ポリオキシエチレ
ン（ＥＯ：５〜２０モル）、アルキル（Ｃ８〜Ｃ２２）
、アミン、ポリオキシエチレン（ＥＯ： ７〜２００モ
ル）、硬化ヒマシ油、などでＨＣＢが大体において７以
上のものが好ましい、又グリコール類としては、有機溶
剤としてエチルグリコール、エチルジグリコール、エチ
ルトリグリコール、ブチルグリコール、ブチルジグリコ
ール、ブチルトリグリコール、フェニルグリコール、ヘ
キシルグリコール、ジメチルグリコール、ジエチルグリ
コール、ジメチルジグリコール、ジブチルジグリコール
、メチル−ｔ−ブチルグリコール、メトキシプロパツー
ル、メチレングリコールアセテート、エチレングリコー
ルアセテート、などがあげられる。As a nonionic surfactant, polyoxyethylene (EO
(near to 25 mol) alkyl (C8 to C15), ether, phenol ether, polyoxyethylene (EO:2
~10 mol), coconut oil fatty acid monoethanolamide, polyoxyethylene (Eo: 7-30 mol), sorbitan fatty acid ester (C10-Cl8), polyoxyethylene (EO: 5-20 mol), alkyl (C8-C22) )
, amines, polyoxyethylene (EO: 7 to 200 moles), hydrogenated castor oil, etc., with an HCB of 7 or more are preferred.As glycols, organic solvents such as ethyl glycol, ethyl diglycol, and ethyl triglycol are preferred. Glycol, butyl glycol, butyl diglycol, butyl triglycol, phenyl glycol, hexyl glycol, dimethyl glycol, diethyl glycol, dimethyl diglycol, dibutyl diglycol, methyl-t-butyl glycol, methoxypropatol, methylene glycol acetate, ethylene glycol Examples include acetate.
然し最近安全性についてアルキルグリコール類は問題性
があり使用が懸念されるものもある。 （１９８８年
８月号化学経済 Ｐ、７２〜７７）更にアルコール類と
してはメチル７、）レコール、エチルアルコール、イソ
プロピルアルコール、ブチルアルコール、ベンジルアル
コール、ジアセトンアルコール、アミルアルコール、な
どあり、エチルアルコールが最適である。これらは２種
以上併用して混合溶剤として使用してもよい。However, recently, alkyl glycols have become problematic in terms of safety, and there are concerns about their use. (August 1988 Kagaku Keizai P, 72-77) Furthermore, alcohols include methyl 7), ethyl alcohol, isopropyl alcohol, butyl alcohol, benzyl alcohol, diacetone alcohol, amyl alcohol, and ethyl alcohol. Optimal. Two or more of these may be used in combination as a mixed solvent.
更にカチオン界面活性剤としては、塩化ベンザルコニウ
ム、塩化ベンゼトニウム、ジデシルジメチルアンモニウ
ムコロライド、トリエチルメチルアンモニウムクロライ
ド、ヤシアルキルアミン塩酸塩、ドデシルトリメチルア
ンモニウムクロライド、などトリメチル型、ジアルキル
型、ベンジル型アミン型、イミダシリン型などがあげら
れ、中でも塩化ベンザルコニウムは局方指定品として最
も適している。Further, as cationic surfactants, trimethyl type, dialkyl type, benzyl type amine type such as benzalkonium chloride, benzethonium chloride, didecyldimethylammonium chloride, triethylmethylammonium chloride, coconut alkylamine hydrochloride, dodecyltrimethylammonium chloride, etc. , imidacillin type, etc. Among them, benzalkonium chloride is the most suitable as a pharmacopeia-designated product.
この外にＰＨを７〜１２にキープする目的でＥＤＴＡ−
４Ｎａ、ＮＴＡ、ポリアクリル酸ソーダ（ＭＷ＝２００
０〜８０００）、珪酸ソーダ、クエン酸ソーダ、リン酸
ソーダ、炭酸ソーダ、リンゴ酸ソーダ、炭酸カリウム、
モノ、ジ、トｌへの各アルカノールアミン（エタノール
、又はプロパツールのアミン）、アンモニ乙アルカリ水
酸化物（ＮａＯＨ，ＫＯＨ）を加える。全体的に水分散
系又は水可溶性とするのがよい。In addition to this, add EDTA to keep the pH between 7 and 12.
4Na, NTA, sodium polyacrylate (MW=200
0-8000), sodium silicate, sodium citrate, sodium phosphate, soda carbonate, sodium malate, potassium carbonate,
Add each alkanolamine (ethanol or propatool amine) to mono-, di-, and tri-alkali, and ammonia alkali hydroxide (NaOH, KOH). It is preferable that the entire composition be water-dispersed or water-soluble.
この場合の配合割合は、
ターペンティン系溶剤が０２〜２０ω％グリコール系溶
剤が０５〜５０ω％
非イオン及びカチオン界面活性剤が０．２〜〕Ｏω％低
級アルコールが０．５〜２０ω％
でＰＨを７〜１２より好ましくは８〜」１を調整する。In this case, the blending proportions are: Turpentine solvent: 02-20ω% Glycol solvent: 05-50ω% Nonionic and cationic surfactants: 0.2-]Oω% Lower alcohol: 0.5-20ω% is adjusted to 7 to 12, more preferably 8 to 1.
その理由は、溶剤量の内ターペンティン系は水に不溶で
安定性が悪く、収納容器を侵食するおそれがあり、グリ
コール系との全量で０．５〜４０ω％を好適とする。The reason for this is that turpentine in the amount of solvent is insoluble in water, has poor stability, and may corrode the storage container, so the total amount with glycol is preferably 0.5 to 40 ω%.
今１つはこれ以上溶剤が多いと、ワンウェイ（そのまま
使用する；タイプでは使用機材を損傷するおそれもあり
、使用上のにおい１手肌への影響も不都合となるからで
ある。この配合系には勿論、その他の香料成分：界面活
性剤、殺菌剤、防腐剤、湿潤剤、各種防蝕剤、色素、キ
レート剤、有機溶剤などを加えることもできるわけで、
要は安全性、洗浄力、全体の液の安定性、除菌力、除臭
力を維持し、充填した場合の各種容器（多くはポリエチ
レン、ＰＶＣ、アクリル、ＰＥＴ、ＰＶＤＣ、ポリプロ
ピレンなどのプラスチック）への物理的、化学的影響を
与えないことである。One reason is that if there is more solvent than this, there is a risk of damaging the equipment used in the one-way (use as is) type, and the smell during use will also be inconvenient and affect the skin. Of course, other fragrance ingredients such as surfactants, bactericides, preservatives, wetting agents, various anticorrosive agents, pigments, chelating agents, and organic solvents can also be added.
The key is to maintain safety, cleaning power, overall liquid stability, sterilizing power, and deodorizing power, and to maintain various containers when filled (mostly plastics such as polyethylene, PVC, acrylic, PET, PVDC, and polypropylene). There should be no physical or chemical impact on the
本発明の具体的使用方法はスプレーガンやガス（ＬＰＧ
、フロン、ＣＣ）２ガスその他）充填式、あるいはＮＷ
Ｆやティッシュにしみこませてふく方法などが具体的で
ワンウェイ（そのまま使用する）方式が便利である。A specific method of using the present invention is to use a spray gun or gas (LPG).
, Freon, CC) 2 gases, etc.) Filling type, or NW
The one-way (use it as is) method is convenient, as there are specific methods such as soaking it in F or a tissue and wiping it off.
特に用途としてはＯＡ、ＦＡ、ＨＡなどのオートメーシ
ョンブームで各種事務用機具、通信機具、電化製品、住
居設備の油汚れ、手あか、塵埃、各種細菌汚染などのク
リーニングに極めて有効、且つ適切なものである。In particular, with the automation boom in OA, FA, HA, etc., it is extremely effective and suitable for cleaning oil stains, hand marks, dust, and various bacterial contamination from various office equipment, communication equipment, electrical appliances, and residential equipment. be.
以下実施例によって説明する。This will be explained below using examples.
（実施例）
（備考）
・非イオン界面活性剤
■ポリオキシエチレン（ＥＯ−９モル）ラウリルエーテ
ル■ポリオキシエチレン （ＥＯ−１２モル）メルビタ
ン脂肪酸エステｋ（ラウレート）（におい）
５人のモニターによって嗅覚法でにおいを官能テストし
て欧の評価をした。(Example) (Notes) - Nonionic surfactant ■Polyoxyethylene (EO-9 mol) Lauryl ether ■Polyoxyethylene (EO-12 mol) Melbitan fatty acid ester K (laurate) (odor) Based on 5 monitors We conducted a sensory evaluation of the smell using the olfactory method.
５人のｎ＝３ の内６０％の評価を下記によって示した
。The evaluation of 60% of the 5 people (n=3) was shown below.
◎：芳香
○：どちらともいえない
△：アルコール臭あり 、
×：アミン臭、アルコール臭あり
、 （低温安定性）
一１０℃で１ケ月放置して、ニゴリ、分離を観察し全く
ないものを◎とした。◎: Aromatic ○: Neutral △: Alcohol odor, ×: Amine odor, alcohol odor (Low temperature stability) Leave it at -10℃ for 1 month and observe no bitterness or separation. And so.
（洗浄力）
（イ）ＰＶ“Ｃ（硬質塩ビ）の上に市販のマジックイン
キでマーキングして放置後、夫々の液をふきつけて５秒
後の除去状況を観察した。(Cleaning power) (a) Marking was made on PV"C (rigid vinyl chloride) using a commercially available marker ink, and the marks were left to stand. After wiping each liquid, the removal status was observed after 5 seconds.
（ロ）ステンレス（ＳＵＳ−３０４）の上にコレステロ
ール／ジオレイン／タルク／カーボンブラック／ワセリ
ン／を１・１・１トリクロルエタンで５０００ＣＰの粘
液となし、これをマーキング（２０ＸＩＯＩＩＩＩ）
して１日放置して、 （イ）と同様に夫々の液をふきつ
けて５秒後、ウェス（コツトン）でふきとりその痕跡を
みた。(b) Cholesterol/diolein/talc/carbon black/vaseline/is made into a 5000CP slime on stainless steel (SUS-304) with 1.1.1 trichloroethane and marked (20XIOIII)
After leaving it for a day, I wiped it with each solution in the same way as in (a), and after 5 seconds, I wiped it off with a rag and looked for any traces.
（ハ）メタルアクリル硬質プレートの上に（ロ）の汚垢
をつけて同様のテストを行なった。(c) A similar test was conducted by applying the stain in (b) on a metal acrylic hard plate.
◎・はぼ完全に除去した
○、わずかに残る（１０％未満）
△：全全体４０％未滴しかとれない
×：全体の２０％未満しかとれない
（除菌力）
（イ）大腸菌（Ｅｓｃｈｅｒｉｃａｈｉａ Ｃｏ１１
０−１２５）（ロ）ブドウ球菌（Ｓｌｉｐｈｙｏｃｏ
ｃｃｕ＋ ｓｕ＋ｅｕＩ、 ５Ｔ−３３１）（ハ）チ
フス菌（Ｓａｌｎｏｎｅｌｌｅ、 １ｙｐｈｉ、Ｗｓ＋
Ｌｏｎ Ｖ）（除臭力）
（イ）硫化水素水（５ω％）をＰＶＣ（硬質塩ビ）の上
に散布し、その上にその３倍の量の配合試作品を散布し
て５分後のにおいを調べた。◎・Completely removed ○, slightly remaining (less than 10%) △: Only 40% of the total can be removed ×: Only less than 20% of the total can be removed (sterilization power) (a) Escherichia coli Co11
0-125) (b) Staphylococcus
ccu+ su+euI, 5T-331) (c) Salmonella typhi (Salnonelle, 1yphi, Ws+
Lon V) (Deodorizing power) (a) Hydrogen sulfide water (5ω%) was sprayed on PVC (hard PVC), and 5 minutes after spraying three times the amount of the blended prototype product on top of it, I investigated the smell.
（ロ）メチルメルカプタン士ホルムアルデヒドの１００
倍希釈（アセトン）をステンレス（ＳＩＪＳ−３０４＞
に散布しく３分後）の悪臭を確認してから夫々の配合試
作品を前」８散布量の約３倍（Ｖｏｌｕｍｅ）を調べた
。（消臭効果）
◎、殆ど感じない
Ｏ３かすかに残っている
△：どちらともいえない
１−×・かなり悪臭が残っている
（作用効果）
以上本発明によって、洗浄力、除菌力、除臭力を兼備し
、しかも人の嗅覚に快感を与える安全な水系の洗浄剤組
成物が得られるもので、特に洗浄目的に走りがちな当該
分野の商品において可視できない域の細菌類や悪臭を除
去できる衛生効果を有するものとして、電話、ファック
ス、コピー機、ワープロ、パソコン、キーボード、電卓
、その他のオフィス設備、ビデオデツキ、ＴＶ、などの
電化製品、住居設備（換気扇、厨房設備、調度品、イン
テリア用品、バス、トイレ）、スポーツグツズ、カーケ
アなどの巾広い用途を有する洗浄剤である。(b) Methyl mercaptan formaldehyde 100
Double diluted (acetone) with stainless steel (SIJS-304>
After confirming the odor after 3 minutes of spraying, the volume of each blended prototype product was examined at a volume approximately three times that of the previous spray. (Deodorizing effect) ◎, barely perceptible O3 remains △: neither 1-×, quite a bad odor remains (effects) As described above, the present invention has improved cleaning power, sterilization power, and odor removal. It is possible to obtain a safe water-based cleaning composition that is both effective and pleasant to the human sense of smell, and can remove bacteria and bad odors that cannot be seen in products in this field, which tend to be used for cleaning purposes. Items that have hygienic effects include electrical appliances such as telephones, fax machines, copy machines, word processors, personal computers, keyboards, calculators, other office equipment, video decks, TVs, and residential equipment (exhaust fans, kitchen equipment, furniture, interior goods, It is a cleaning agent that has a wide range of uses, including baths, toilets), sports goods, and car care.
以上”that's all"
Claims (2)
ペンテイン系香料、グリコール類、及び低級アルコール
を含んでなる水系のＰＨが７以上１２以下の洗浄剤組成
物(1) An aqueous cleaning composition with a pH of 7 or more and 12 or less, which comprises a nonionic surfactant and a cationic activator, a turpentein fragrance, glycols, and a lower alcohol.
ルエーテル、ポリオキシエチレンアルキルフェノールエ
ーテル、ポリオキシエチレン脂肪酸アルカノールアミド
、ポリオキシエチレンソルビタン脂肪酸エステル、ポリ
オキシエチレンアルキル脂肪酸エステル、であり、カチ
オン界面活性剤が塩化ベンザルコニウム、ジアルキルジ
メチルアンモニウムクロライド（アルキルはＣが１０〜
１５）であり、ターペンティン系香料が、Ｄ−リモネン
、α−ピネン、β−ピネン、ジペンテン、ミルセン、タ
ーピネオール、テレビン油であり、且つ、アルコール類
がエチルアルコール、ブチルアルコール、アミルアルコ
ールである第（１）項記載の洗浄剤組成物(2) The nonionic surfactant is polyoxyethylene alkyl ether, polyoxyethylene alkylphenol ether, polyoxyethylene fatty acid alkanolamide, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl fatty acid ester, and the cationic surfactant is Benzalkonium chloride, dialkyldimethylammonium chloride (alkyl has 10 to 10 carbon atoms)
15), and the turpentine fragrance is D-limonene, α-pinene, β-pinene, dipentene, myrcene, terpineol, or turpentine oil, and the alcohol is ethyl alcohol, butyl alcohol, or amyl alcohol. Cleaning composition described in section 1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2297239A JP2829887B2 (en) | 1990-11-05 | 1990-11-05 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2297239A JP2829887B2 (en) | 1990-11-05 | 1990-11-05 | Detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04173900A true JPH04173900A (en) | 1992-06-22 |
| JP2829887B2 JP2829887B2 (en) | 1998-12-02 |
Family
ID=17843968
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2297239A Expired - Fee Related JP2829887B2 (en) | 1990-11-05 | 1990-11-05 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2829887B2 (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05239492A (en) * | 1992-03-02 | 1993-09-17 | Kao Corp | Liquid detergent composition for head surface |
| JPH06264097A (en) * | 1993-01-26 | 1994-09-20 | T Paul Kk | Alkaline sterilizing detergent |
| WO1998030665A1 (en) * | 1997-01-06 | 1998-07-16 | Reckitt & Colman Inc. | Improved blooming type disinfecting cleaning compositions |
| EP0863971A4 (en) * | 1995-11-14 | 1999-06-09 | Reckitt & Colman Inc | Improved compositions containing organic compounds |
| WO1999053011A1 (en) * | 1998-04-14 | 1999-10-21 | Reckitt Benckiser Inc. | Botanical oils as blooming agents in hard surface cleaning compositions |
| WO2002008372A1 (en) * | 2000-07-21 | 2002-01-31 | Unilever Plc | Antimicrobial compositions |
| WO2002047883A1 (en) * | 2000-12-13 | 2002-06-20 | Asahi Kasei Kabushiki Kaisha | Detergent |
| WO2003040280A1 (en) * | 2001-11-08 | 2003-05-15 | Green & Clean, Inc. | Active natural cleaning material using soybean fatty acids and its manufacture |
| JP2003238996A (en) * | 2002-02-22 | 2003-08-27 | Kao Corp | Concentrated liquid cleaning agent for flush toilet |
| JP2006008801A (en) * | 2004-06-24 | 2006-01-12 | Johnson Professional Co Ltd | Detergent composition for hard surface |
| US7247607B2 (en) | 2001-11-08 | 2007-07-24 | Green & Clean, Inc. | Active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof |
| CN112680293A (en) * | 2019-10-18 | 2021-04-20 | 中国石油化工股份有限公司 | Emulsifier, preparation method and application thereof, and method for emulsifying butter in alkaline washing tower |
| WO2024135215A1 (en) * | 2022-12-23 | 2024-06-27 | 小林製薬株式会社 | Cleaning agent composition |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115717095A (en) * | 2022-11-28 | 2023-02-28 | 广东红日星实业有限公司 | Cleaning agent and preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05239492A (en) * | 1992-03-02 | 1993-09-17 | Kao Corp | Liquid detergent composition for head surface |
| JPH06264097A (en) * | 1993-01-26 | 1994-09-20 | T Paul Kk | Alkaline sterilizing detergent |
| EP0863971A4 (en) * | 1995-11-14 | 1999-06-09 | Reckitt & Colman Inc | Improved compositions containing organic compounds |
| US6030936A (en) * | 1997-01-06 | 2000-02-29 | Reckitt & Colman Inc. | Blooming type disinfecting cleaning compositions |
| WO1998030665A1 (en) * | 1997-01-06 | 1998-07-16 | Reckitt & Colman Inc. | Improved blooming type disinfecting cleaning compositions |
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| WO1999053011A1 (en) * | 1998-04-14 | 1999-10-21 | Reckitt Benckiser Inc. | Botanical oils as blooming agents in hard surface cleaning compositions |
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| WO2002008372A1 (en) * | 2000-07-21 | 2002-01-31 | Unilever Plc | Antimicrobial compositions |
| US7144847B2 (en) | 2000-12-13 | 2006-12-05 | Asahi Kasei Chemicals Corporation | Detergent |
| JPWO2002047883A1 (en) * | 2000-12-13 | 2004-04-15 | 旭化成株式会社 | Washing soap |
| WO2002047883A1 (en) * | 2000-12-13 | 2002-06-20 | Asahi Kasei Kabushiki Kaisha | Detergent |
| WO2003040280A1 (en) * | 2001-11-08 | 2003-05-15 | Green & Clean, Inc. | Active natural cleaning material using soybean fatty acids and its manufacture |
| US7247607B2 (en) | 2001-11-08 | 2007-07-24 | Green & Clean, Inc. | Active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof |
| JP2003238996A (en) * | 2002-02-22 | 2003-08-27 | Kao Corp | Concentrated liquid cleaning agent for flush toilet |
| JP2006008801A (en) * | 2004-06-24 | 2006-01-12 | Johnson Professional Co Ltd | Detergent composition for hard surface |
| JP4565321B2 (en) * | 2004-06-24 | 2010-10-20 | ディバーシー株式会社 | Detergent composition for cooking table, cooking equipment and surrounding floor |
| CN112680293A (en) * | 2019-10-18 | 2021-04-20 | 中国石油化工股份有限公司 | Emulsifier, preparation method and application thereof, and method for emulsifying butter in alkaline washing tower |
| CN112680293B (en) * | 2019-10-18 | 2022-07-08 | 中国石油化工股份有限公司 | Emulsifier, preparation method and application thereof, and method for emulsifying butter in alkaline washing tower |
| WO2024135215A1 (en) * | 2022-12-23 | 2024-06-27 | 小林製薬株式会社 | Cleaning agent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2829887B2 (en) | 1998-12-02 |
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