MX2013013195A - Liquid soap for removing alkidalic and reflecting paint, graffiti, enamel, engine grease and vegetable grease, with a dry cleaning action and bactericide power. - Google Patents

Abstract

The present invention refers to the development and formulation of a liquid remover soap having a dry cleaning action and bactericide power for removing the dirt present in different hard surfaces, such as: metals, ceramic, plastic, glass, inorganic and organic substrates including textiles and with a bactericide action. The present invention refers to the development and formulation of a liquid remover soap having a dry cleaning action and bactericide power for removing the dirt present in the surface of human and animal skin, having a bactericide action. The invention includes characteristics that turn it into a suitable product for performing cleaning and disinfecting operations at an industrial, domestic, institutional, commercial and service level in: plants for processing food and beverages, metal-mechanical industries, transformation industries. The product is useful for the domestic cleaning and disinfection of kitchens, bathrooms, garages, walls, tapestry, etc., for cleaning and disinfecting institutional bathrooms, kitchens and industrial dining areas; cleaning and disinfecting convenience stores, public markets and supply centers. In gas stations, bus stations, public and private schools, etc. One of the main characteristics of the invention is to reduce the consumption of water used for cleaning and rinsing the treated surfaces. The invention is environmentally friendly, harmless to humans and animals and represents a novel alternative for replacing products that have the same functionality, but which are formulated with compounds or ingredients that are corrosive, toxic, carcinogenic, volatile and aggressive to the environment and human and animal health. The invention allows cleaning and disinfection tasks to be performed in the same step, with the consequent saving of time, resources, water and energy, allowing the operations to be optimized.

Description

REMOVED LIQUID SOAP TO ELIMINATE ALKIDICAL AND REFLECTIVE PAINT, GRAFITI, VARNISH, ENGINE GREASE AND VEGETABLE GREASE, WITH DRY CLEANING ACTION AND BACTERICIDE POWER.

FIELD OF THE INVENTION: The composition of liquid soap remover to remove alkyd and reflective paint, graffiti, varnish, motor grease and vegetable grease, with dry cleaning action and bactericidal power that is a mixture of anionic surfactants, tertiary amine, thickener, orange terpenes, esters dibasic, emollients and / or humectants, fragrance, dyes, germicide based on extracts of citrus fruits, which exerts a cleaning and bactericidal action in dry, in addition to requiring little amount of water for rinsing.

OBJECT OF THE INVENTION: The composition of liquid soap remover to remove alkyd and reflective paint, graffiti, varnish, motor grease and vegetable fat, with dry cleansing action and bactericidal power with the properties of being non-irritating to human and animal skin, friendly to the environment environment, biodegradable, non-toxic, non-flammable, substitute for products formulated with volatile and flammable solvents, and chemical bactericidal agents, methanol-free formula and with low water consumption for rinsing.

For cleaning and disinfection: domestic, industrial, institutional, municipal and services. With emphasis on cleaning skin and hands to remove grease, oil-based paint, reflective paint, varnish, inks and dyes and eliminate bacteria present on skin and hands.

Cleaning and disinfection of surfaces of diverse nature such as varnished surfaces, metal surfaces, stainless steel surfaces, copper, aluminum, and galvanized, vivid tiles, terrazzo floors, marble floors, cement floors, textiles, vulcanized rubber cleaner, removes ink, marker, bearing grease, dyes, mascara, mustard, etc.

BACKGROUND: It was found that there is a patented invention with the number MX A / 2011/011583, consisting of a mixture of dibasic esters, one or more surfactants, optionally water or a solvent and reviewing the ingredients declared in said patent it was found that despite declare itself friendly to the environment and non-toxic, it contains methanol, a substance recognized for its dangerousness. It is found in a small percentage but is present in that formulation. Although they do not declare it, it is known that methanol is a risk to human health (it can cause vision problems until death). They emphasize that it has a percentage of .02 to 2.0% methanol and they try to mask it by referring to it as short chain alcohol and that is nothing but methanol.

A market investigation was carried out in the main self-service stores and no similar product was found, for the purpose of the invention.

DETAILED DESCRIPTION OF THE INVENTION: The composition of liquid detergent remover to eliminate alfalfa and reflective paint, graffiti, varnish, motor grease and vegetable grease, with dry cleaning action, which exerts a dry cleaning action in addition to requiring little water for rinsing, is composed by: a) 10 - 60% anionic surfactant b) 3- 20% tertiary amine c) 1 - 10% thickener i d) 0.5 - 5% Terpene e) 3 - 48% of dibasic esters f) 1 - 2% Emollients and / or humectants g) 0.5 - 5% of bactericidal citrus extracts h) 5 - 20% water The characteristics of the resulting product are: Liquid state . 100 - 500 centipoises Color . Pale yellow to colorless.

To Rome . Citric. pH. 4.00 - 10.0 Appearance . Opalescent.

Solubility Completely soluble in water.

The composition of liquid soap remover to remove alkyd and reflective paint, graffiti, varnish, motor grease and vegetable fat, with dry cleansing action and bactericidal power, in addition to requiring little water for rinsing, does not incorporate toxic substances its formulation.

The liquid soap composition is used for the dry removal of: ink stains, paint, grease, marker, graffiti, alkyd enamel, ketchup stains, blood, grass, dye, mascara, lipstick, carbon black, varnish Of nails.

The liquid soap composition is used for dry removal on surfaces such as; stainless steel, copper, aluminum, glass, porcelain, ceramic, carbon steel, chrome surfaces, cement, concrete, vindica and terrazzo tiles, brass, formica.

The liquid soap composition is used for the dry removal of; ink, dye, alkyd paint, varnish, grease on hands and skin.

The liquid soap composition is used for the removal of ink, gum, grease, blood stains, tomato sauce, cosmetic waste, lipstick, mascara, nail polish, ballpoint pen ink.

The liquid soap composition is used in textile materials such as; cotton, linen, polyester, cotton polyester, nylon.

The liquid soap composition is used for washing and disinfecting machinery; industrial, mechanical, electrical and electronic equipment such as; motors, gearmotors, transmission chain, belts, two and four stroke internal combustion engines, sprockets, pinions, crowns, transmission mechanisms and any lubricated component with the advantage of the invention of not being toxic, non-volatile, non-flammable, not corrosive The liquid soap composition includes: ANIONIC TENSIONING.

They consist of a linear or branched alkyl chain ranging from 10 to 14 carbon atoms, and an anion is found at its polar end of the molecule. Representatives of this group are derivatives of sulfate ion or sulphonates, carboxylic acids, acylamino acids, etc. with general formulas: In solution they ionize, but considering the behavior of their groups in solution, the hydrophobic group becomes negatively charged.

It consists of anionic surfactants which may be some of the following, but are not limited to: sodium lauryl sulfate, triethanolamine lauryl sulfate, disodium succinate lauryl sulfate, short chain acyl glutamate, N-methyl taurine, linear ADBS, ADBS branched, AMINA TERCIARY Amines are organic chemical compounds that are considered as derivatives of ammonia and result from the substitution of the hydrogens in the molecule with organic functional groups of the acyl or short chain alkyl, intermediate or long type. When three hydrogens are substituted, the amines will be tertiary, Ammonia tertiary amine The amines are simple when the alkyl groups are the same and mixed if they are different.

Amines are very polar compounds. Pure tertiary amines can not form hydrogen bonds, however they can accept hydrogen bonds with molecules that have O-H or N-H bonds. Since nitrogen is less electronegative than oxygen, the N-H bond is less polar than the O-H bond. Therefore, amines form weaker hydrogen bonds than alcohols of similar molecular weights.

As tertiary amines: but not limiting to Trimethyl amine, dimethyl propyl amine, triethanolamine, methyl diethyl amine. : THICKENERS Thickening agents are substances that, when added to a mixture, increase its viscosity without substantially modifying its other properties such as taste, smell and color. They provide body, increase stability and facilitate the formation of suspensions. Thickening agents are frequently food additives. Thickeners generally have a rather complex structure and are based on polysaccharides and cellulose derivatives. I '' , As a thickener: but not limited to carbomers, guar gum, tragacanth gum, xanthan gum, carboxymethyl cellulose, hydroxyethyl ethyl cellulose, methyl ethyl hydroxyethyl cellulose, modified corn starch.

TERPENOS Terpenes are organic solvents that often have a natural origin such as pine bark or citrus fruits. They usually have strong and characteristic odors and are good solvents. They can be used with immersion and ultrasonic systems, and usually work well at room temperature. In semi-aqueous systems it is usually possible to separate and reuse the terpene. Terpenes are considered biodegradable, As a biodegradable organic solvent, including but not limited to: Orange terpenes, pine terpenes, d-limonene.

DIBASIC ESTERS.

Esters are organic compounds derived from organic or inorganic oxygenated acids in which one or more protons are substituted by organic alkyl groups (symbolized by R '.) In the most common esters the acid in question is a carboxylic acid.

There is a group called generically as organic dibasic ester that combines excellent solvency power with a wide range of properties. Dibasic esters can function as solvents, ingredients and chemical intermediates; and they are non-flammable, easily biodegradable and non-corrosive with a mild fruit smell.

As dibasic esters, but not limited to: Dimethyl-2-methyl glutarate, dialkyl adipates, alkyl succinate adipates dialkyl methyl glutarates EMOLLIENTS / MOISTURIZERS They are agents that soften the skin and mucous membranes as well as retain moisture in the epidermis, thus avoiding dryness.

I - I - As emollients, the following are indicated, but not limited to: Hexyl laurate, diisopropyl adipate, isostearic neopentanonate, silicones.

As humectants, they are mentioned, but not limited to: Propylene glycol, glycerin, hyaluronic acid, polypropylene glycol.

As a fragrance, the following are indicated, without limitation: Floral, fruit and herbal.

As a natural dye, the following are mentioned but not limited to: Beta carotene, red cochineal, chlorophyll, betanin.

CITRUS EXTRACTS BACTERICIDES They are antimicrobial products of natural origin, derived from citrus fruits whose main function is to eliminate microorganisms that cause the decomposition of products and the transmission of diseases.

The incorporation of this bactericidal agent in the formulation of the product allows the surfaces to be cleaned and disinfected in a single step, in addition to preventing them from becoming a focus of microbial contamination of humans, animals, plants, food, objects of common use and staff, etc.

As citrus extracts with bactericidal action are indicated but not limited to: Grapefruit, orange and lemon extracts, alone or in combination: As a vehicle for the formulation, the following are mentioned but not limited to: Drinking water, demineralised water, chlorinated water, bidistilled water, purified water by reverse osmosis, distilled water, etc.

EXAMPLES OF THE INVENTION The following formulations corresponding to the present application were made of the present invention: FORMULA DX-135.

Rank Sodium lauryl sulphate 10% - 50% Triethanolamine 10% - 15% Guar gum 1% - 7% Terpenes 0.5% - 5% Dimethyl-2-methyl glutarate 3% - 40% Emollients and / or humectants 1.5% - 2% Citrus bactericidal extracts 0.5% - 4% Water 5% - 20% FORMULA ALFA-13.

Rank Anionic surfactant 15% - 30% Tertiary amine 5% - 17% Thickener 2% - 10% Terpenes 0.5% - 2.5% Dibasic ester 5% - 20% Emollients and / or humectants 1.25% - 1.75% Citrus bactericidal extracts 0.5% - 1% Water 8% - 20% FORMULA R-903.

Rank Anionic surfactant 15% - 45% Tertiary amine 11% - 19% Thickener 1% - 20% Terpenes 2% - 3.5% Ester dibasic 13% - 44% Emollients and / or humectants 1.5% - 1.60% Citrus extracts bactericides 0.5% - 1% Water 7.5% - 19% FORMULA AI-9016.

Rank Anionic surfactant 15% - 30% Tertiary amine 3% - 10% Thickener 2% - 5% Terpenes 0.7% - 4.5% Ester dibasic 10% - 25% Emollients and / or humectants 1% - 1.4% Citrus extracts bactericides 1% - 3% Water 5% - 18% FORMULA DK-W-230513 Range Anionic surfactant 17% - 47% Tertiary amines 11% - 13% Thickeners 1.3% - 4.8% Terpenes 1% - 4.7% Dibasic ester 6% - 19% Emollients and / or humectants 1.1% - 1.2% Citrus extracts bactericides 0.8% - 3.3% Water 5% - 20% FORMULA NSR- 3127-5 Rank Anionic surfactant 13% - 31% Tertiary amine 5% - 14% Thickening 1% - 8% Terpenes 2% - 4.2% Dibasic ester 5% - 24% Emollients and / or humectants 1.7% - 1.8% Bactericidal citrus extract 1.5% - 3.7% Water 8% - 20% Practical examples of the invention: 1. - As a practical example, the concentrated product of the formula identified as DK-W-230513 was applied, dry on the hands of a painter, containing residues of alkyd enamel, rubbed for approximately 2 minutes and then proceeded to rinse the residues with water and dried with a towel, after making the application, completely removing the residues of the enamel. Later it could be observed that the product had no negative or irritating effect on the skin. 2. As a practical example of the invention, the formula identified as R-903, in the proportion of one part of product per 10 of water, on different surfaces present in an industrial kitchen was tested as a degreaser. The diluted product was sprayed on the dry surfaces and allowed to act for 20 seconds to later pass a clean and damp cloth over the treated surface to remove the residues of the product. It was observed that with the application of the product the grease and cochambre residues were eliminated without major difficulty and no damage or attack to surface was observed by the use of the product. 3. - The diluted product of the formula identified as NSR - 3127-5 was applied in the proportion of one part of product to 5 of water on a surface of rustic finished cement, which presented accumulated dirt of oil, motor grease, dirt, dust , etc. Then the surface was carved with the help of a thick bristle brush and then rinsed with clean water. It was observed that the product completely removed the accumulated dirt giving it an optimum appearance without damaging the surface.

The 3 formulas mentioned above were tested to demonstrate their bactericidal effect on the treated surfaces, using the drag swab technique. Initial samples were taken to determine the bacterial load present before using the product and to show final samples after applying the formulas. The biological indicator used was the Aerobic Mesophilic Microorganisms.

PROOF OF BACTERICIDE EFFECTIVENESS * Values expressed in CFU / 100 cm2 The results found clearly demonstrate the bactericidal effect of the formulations tested.

In a complementary way, tests were carried out with the 3 formulations to evaluate the elimination power of organic matter in different surfaces.

A Clean Trace Luminometer was used for the determinations which measures the amount of residual organic matter present in a surface, after carrying out the cleaning, the values are expressed in Relative Units of Light, (URL).

CLEANING EFFECTIVENESS TEST The results obtained demonstrate the cleaning power of the formulations tested

Claims (19)

CLAIMS: Having described my invention sufficiently and clearly, I consider it as a novelty and therefore claim as my exclusive property what is contained in the following clauses:

1 The composition of the liquid detergent comprising: a) 10 - 60% anionic surfactant b) 10-20% tertiary amine c) 1 - 10% thickener d) 0.5 - 5% Terpene e) 3 -48% of dibasic esters f) 1 - 2% emollients / humectants g) 5 - 20% Water h) 0.5 - 5% of Bactericidal Citrus Extracts

2. - The liquid soap composition according to claim 1 further characterized in that: the anionic surfactants are selected from the group comprising anionic linear or branched alkyl chain anionic surfactants of 14 to 18 carbon atoms

3. - The liquid soap composition according to claim 2 further characterized in that the anionic surfactants are selected from the group comprising ammonium surfactants derived from the sulfate ion or sulphonate ion. :

4. The liquid soap composition according to one or any of the preceding Claims further characterized in that the selected tertiary amine corresponds to trimethyl amine and / or dimethylpropylamine and / or triethanolamine and / or methyldiethylamine.

5. The liquid soap composition according to one or any of the preceding Claims further characterized in that the selected thickener comprises natural gums of vegetable origin such as guar gum or tragacanth gum or gum arabic or xanthan gum including modified corn starch.

6. The liquid soap composition according to one or any of the preceding Claims further characterized in that the thickener selected comprises cellulose derivatives such as carboxymethyl cellulose, hydroxyethyl ethyl cellulose, methyl ethyl hydroxyethyl cellulose or thickeners derived from acrylic acid, generically referred to as carbomers

7. The liquid soap composition according to one or any of the preceding Claims further characterized in that the terpene is of citrus origin constituted primarily by d-limonene

8. The liquid soap composition according to one or any of the preceding Claims further characterized in that the selected dibasic ester comprises dimethyl-2-methyl glutarate or dialkyl adipates or adipates of alkyl succinate or dialkyl methylglutarates,

9. The liquid soap composition according to one or any of the preceding Claims further characterized in that the selected emollients / humectants comprise the hexyl laurate, diisopropyl adipate, isostearic neopentanonate, glycerin, emulsified silicones, propylene glycol, glycerin, hyaluronic acid, polypropylene glycol ,

10. The liquid soap composition according to one or any of the preceding Claims further characterized in that the water used as a diluent is selected from drinking water, chlorinated water, deionized water, distilled water, bidistilled water, water purified by reverse osmosis, ozonated water , soft water.

11. - The liquid soap composition according to one or any of the Claims; above, characterized in that the bactericidal agent is selected from a mixture of citrus extracts of grapefruit, orange and lemon.

12. - The use of the liquid soap remover composition with dry cleaning action and bactericidal power in accordance with one or any of the preceding Claims, for industrial, domestic, institutional and service cleaning.

13. - The use of the liquid soap remover composition according to Claim 12, comprises the removal of ink stains, paint, grease, marker, graffiti, alkyd enamel, alkyd and reflective paint, graffiti, varnish, motor grease and grease vegetable, mascara stains, lipstick, nail varnish, on hard surfaces such as stainless steel, copper, aluminum, glass, porcelain, ceramics, carbon steel, chrome surfaces, cement, concrete, vinyl and terrazzo tiles, brass, forma , plastic.

14. - The use of the liquid soap remover composition according to claim 12, comprises the elimination of ink stains, paint, grease, marker, graffiti, alkyd enamel, alkyd and reflective paint, varnish, motor grease and vegetable fat, dye, mascara, lipstick, nail varnish, on the surface of the skin.

15. - The use of the liquid soap remover composition according to Claim 12, comprises the removal of ink stains, paint, grease, marker, graffiti, alkyd enamel, alkyd and reflective paint, graffiti, varnish, motor grease and Vegetable fat, ketchup stains, blood, grass, dye, mascara, lipstick, nail varnish, on cotton garments, linen, polyester, polyester / cotton blend, nylon.

16. - The use of the liquid soap remover composition according to Claim 12, comprises the removal of ink stains, paint, grease, marker, graffiti, alkyd enamel, alkyd and reflective paint, graffiti, varnish, motor grease and grease vegetable, dye, 'mascara, lipstick, nail varnish, on metal surfaces of machinery and equipment.

17. - The use of the liquid soap remover composition in accordance with the claim 12, includes the removal of graffiti, motor grease and vegetable fat, oil, ink, enamel, on -different surfaces, with the properties of being biodegradable, non-toxic, non-corrosive, no. Flammable, non-volatile, methanol-free and safe to apply. :

18. - The use of the liquid soap remover composition according to Claim 12,, comprises the removal of graffiti, motor grease and vegetable fat, oil, ink, enamel, on different surfaces.

19. - The use of the liquid soap remover composition according to claim 12, comprises the removal of graffiti, motor grease and vegetable fat, oil, ink, enamel, on different surfaces.