JPH04112611U - Button with antibacterial properties - Google Patents

Button with antibacterial properties

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Publication number
JPH04112611U
JPH04112611U JP3778891U JP3778891U JPH04112611U JP H04112611 U JPH04112611 U JP H04112611U JP 3778891 U JP3778891 U JP 3778891U JP 3778891 U JP3778891 U JP 3778891U JP H04112611 U JPH04112611 U JP H04112611U
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Japan
Prior art keywords
button
antibacterial
effect
antibacterial agent
forming material
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Pending
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JP3778891U
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Japanese (ja)
Inventor
仲内弘和
Original Assignee
仲内株式会社
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Priority to JP3778891U priority Critical patent/JPH04112611U/en
Publication of JPH04112611U publication Critical patent/JPH04112611U/en
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Abstract

(57)【要約】 【目的】 ボタンの成形条件に耐えて抗菌効果が有効に
生じると共に長期間に亘りその効力を保持し、かつ利用
に安全な抗菌性能を有するボタンの提供にある。 【構成】 ボタン1の形成材2中に粒体状の抗菌剤3が
均一に分散された状態で含有保持せしめられてなる。 【効果】 有効な抗菌作用がボタン1の全表面に渡って
発揮されることにより衛生的に利用ができる。また抗菌
剤に基づく毒性による弊害も解消され、また抗菌効果が
長期に及ぶこと、また強度、着色状態も制限されないこ
とから、ボタンとしての機能も損なわれることなく使用
できる。
(57) [Summary] [Purpose] To provide a button that can withstand the molding conditions of the button, effectively produces an antibacterial effect, retains its effect for a long period of time, and has antibacterial properties that are safe for use. [Structure] A granular antibacterial agent 3 is contained and maintained in a uniformly dispersed state in a forming material 2 of a button 1. [Effect] An effective antibacterial effect is exerted over the entire surface of the button 1, allowing it to be used hygienically. In addition, the harmful effects of toxicity caused by antibacterial agents are eliminated, the antibacterial effect lasts for a long time, and there are no restrictions on strength or coloring, so it can be used as a button without impairing its function.

Description

【考案の詳細な説明】[Detailed explanation of the idea]

【0001】0001

【産業上の利用分野】[Industrial application field]

本考案は、抗菌性能を有する服飾用ボタンの構成に関する。 The present invention relates to the construction of a button for clothing having antibacterial properties.

【0002】0002

【従来の技術】[Conventional technology]

従来、服飾用ボタンは、衣服の開き留め又は装飾を目的として用いられてきた ものであり、天然材又は人造材を素材としてボタンが製造されてきた。 天然材としては貝殻、骨、角などが利用され、また人造材としては各種のプラ スチック材、ガラス材、金属材などが利用されてきた。 Conventionally, buttons for clothing have been used for the purpose of fastening clothes or for decoration. Buttons have been manufactured using natural or artificial materials. Shells, bones, horns, etc. are used as natural materials, and various plastics are used as artificial materials. Stick materials, glass materials, metal materials, etc. have been used.

【0003】 このような従来のボタンについては、その利用は衣服等の極めて限られた部分 を占めるに過ぎないことから、それ自体に抗菌性能を保持させることは全く考慮 されなかった。0003 Conventional buttons like this can only be used in extremely limited areas such as clothing. However, since it only accounts for 1% of the total It wasn't done.

【0004】0004

【考案が解決しようとする課題】[Problem that the idea aims to solve]

しかし、上記したボタンは、人の手が接触する機会が多く、また衣服に於いて は外部に露出して用いられる場合がほとんどであることから、実際上はカビ菌、 細菌などの各種の菌類が付着、繁殖することにもなる。また、この菌類の繁殖に つき、衣服が年間を通じて常時着装されることは少なく、タンスなどの暗所にて 保存される場合には、その繁殖の頻度は極めて大きくなる。 このように菌類が付着、繁殖したボタンとの接触はその伝染の直接的な原因と なり、また人の健康を害する原因ともなる。 However, the above-mentioned buttons are often touched by human hands, and are difficult to use when wearing clothes. In most cases, it is exposed to the outside and is used, so in reality, mold, bacteria, Various types of fungi such as bacteria can also attach and multiply. Also, the growth of this fungus Because of this, clothes are rarely worn all the time throughout the year, and are stored in dark places such as chests of drawers. If preserved, the frequency of reproduction will be extremely high. Contact with buttons on which fungi have attached and grown in this way is a direct cause of infection. It can also cause damage to human health.

【0005】 また、このボタンにつき、抗菌性能を保持させようとする試みには次のような 困難がある。即ち、従来、工業用のものとして利用されてきた特に有機系の抗菌 剤は、その効力について優れるが安全性に欠けるものが多くそのままでは人が直 接接触する機会が多いボタンとしての使用には適当でない。また食品衛法で許可 され防腐剤として利用されるような抗菌剤は、一般に溶媒中に溶解して使用され るものであるから、ボタンに利用する場合には短期的な効力しか期待できない。 従って、数年単位で利用されるボタンへの使用には適さない。また、ボタン材料 としての加工の際の耐熱性等の製造時の条件も考慮しなければならない。[0005] In addition, the following attempts have been made to maintain the antibacterial properties of this button. There are difficulties. In other words, especially organic antibacterial agents that have traditionally been used for industrial purposes, Although many drugs have excellent efficacy, they lack safety and cannot be used directly by humans. It is not suitable for use as a button with many opportunities for contact. Also permitted under the Food Sanitation Act Antibacterial agents used as preservatives are generally dissolved in a solvent. Therefore, when used for buttons, only short-term effectiveness can be expected. Therefore, it is not suitable for use in buttons that are used every few years. We also have button material Manufacturing conditions such as heat resistance during processing as a material must also be considered.

【0006】 本考案の目的は、成形条件に耐えて抗菌効果が有効に生じると共に、長期間に 亘ってその効力を保持し、かつ利用に安全な抗菌性能を有するボタンを提供する にある。[0006] The purpose of this invention is to withstand molding conditions, effectively produce antibacterial effects, and to last for a long time. To provide a button that maintains its effectiveness over time and has antibacterial properties that are safe for use. It is in.

【0007】[0007]

【課題を解決するための手段】[Means to solve the problem]

そこで、本考案は上記した目的を達成するために抗菌性能を有するボタンにつ き、次のように構成した。 即ち、ボタンの形成材中に粒体状の抗菌剤が均一に分散された状態で含有保持 せしめられてなることを特徴とする。 Therefore, in order to achieve the above-mentioned purpose, this invention was developed to develop a button with antibacterial properties. It was constructed as follows. In other words, the granular antibacterial agent is kept uniformly dispersed in the button forming material. It is characterized by being forced to become.

【0008】 上記した構成特徴に於いて、ボタンの形成材としての適材は、抗菌剤の粒体を ボタンとしての形成段階に於いて内部乃至表面に混入できるプラスチック材、金 属材などである。 このプラスチック材としては、ポリエステル樹脂、アクリル樹脂、ナイロン樹 脂、ラクトロイド樹脂、ABS樹脂などであり、また金属材としては、亜鉛と錫 との合金など低融点の材料を挙げることができる。[0008] Considering the above-mentioned structural characteristics, the suitable material for forming the button is antibacterial agent granules. Plastic materials and gold that can be mixed inside or on the surface during the button formation stage Materials, etc. This plastic material includes polyester resin, acrylic resin, and nylon resin. resin, lactroid resin, ABS resin, etc., and metal materials such as zinc and tin. Examples include materials with low melting points, such as alloys with

【0009】 また、抗菌剤としては、人体に対する毒性が少なく、またボタンの形成段階の 前後に於いてその当初の粒体状を維持するものであり、例えば、銅、銀、亜鉛な どの抗菌性を呈する金属粉材、若しくはリン酸カルシウムなどの耐熱性担体に抗 菌性の金属イオンを交換吸着せしめてなるものなどの適用が好ましい。[0009] In addition, as an antibacterial agent, it has low toxicity to the human body, and is effective at the button formation stage. It maintains its original granular shape before and after, for example, copper, silver, zinc, etc. Resistant to any antibacterial metal powder or heat-resistant carrier such as calcium phosphate. It is preferable to use a material obtained by exchanging and adsorbing bacterial metal ions.

【0010】 また、抗菌剤粒体のボタン形成材中に於ける均一分散構成は、プラスチック材 が形成材である場合には、そのボタンとしての形成段階に於いて、適当な分散剤 を添加する方法によって得られる。具体的にはポリエステル樹脂を形成材とする とき、N,N−ジメチルホルムアマイド又はナトリウムメチレートなどを分散剤 として用いることができる。なお、ボタン形成材が金属材である場合には、金属 材の熔融状態に於ける金属材原子又は分子の温度活性を利用することができる。 従って、抗菌剤粒体の単純混入によって上記同様の均一分散構成を得ることがで きる。0010 In addition, the uniform dispersion of antibacterial agent particles in the button forming material is similar to that of plastic materials. If it is a forming material, an appropriate dispersant is added during the process of forming it into a button. Obtained by adding . Specifically, polyester resin is used as the forming material. When using a dispersant such as N,N-dimethylformamide or sodium methylate, It can be used as In addition, if the button forming material is a metal material, the metal The temperature activity of metal material atoms or molecules in the molten state of the material can be utilized. Therefore, it is possible to obtain the same uniform dispersion structure as above by simply mixing antibacterial agent granules. Wear.

【0011】[0011]

【作用】[Effect]

本考案に係るボタン構成は次のような作用を生じさせる。 抗菌剤の粒体はボタン中に於いて均一に分散されているから、抗菌効力がボタ ンの表面全体に均等に及ぶ。 The button configuration according to the present invention produces the following effects. Since the antibacterial agent particles are uniformly dispersed within the button, the antibacterial effect is maintained throughout the button. Evenly spread over the entire surface of the tube.

【0012】 また、抗菌剤の粒体は、ボタンの表面付近に位置するものについて強くその抗 菌効果をボタン表面上に及ぼし、またその存在がボタン表面からの距離が長くな るのに従ってその効果を弱める。なお、ボタンの表面付近に存在しない抗菌剤に よる抗菌作用は、形成材がプラスチック材である場合にはその分子構造に応じて 発揮され、また形成材が金属材でてある場合にはその鋳造に際し生ずる微細孔を 介して発揮される。0012 In addition, antibacterial particles located near the surface of the button have a strong antibacterial effect. It has a fungal effect on the button surface, and its presence increases the distance from the button surface. The effect weakens as the temperature increases. Please note that antibacterial agents that are not present near the surface of the button When the forming material is plastic, the antibacterial effect depends on its molecular structure. In addition, if the forming material is a metal material, the micro pores that occur during casting. It is demonstrated through.

【0013】 また、この抗菌剤粒体の均一分散構成は抗菌剤をボタン表面には極く僅かしか 存在させないから、含有する抗菌剤の粒体のほとんどはボタンの形成材によって コーティング状態となっている。従って、ボタンに対する直接的な接触も、人体 にはその抗菌作用によって害を及ぼすことはない。[0013] In addition, the uniformly dispersed structure of this antibacterial agent granule allows the antibacterial agent to be deposited in a very small amount on the button surface. Most of the antibacterial particles contained in the button are absorbed by the material forming the button. It is in a coating state. Therefore, direct contact with the button is also harmful to the human body. does not cause any harm due to its antibacterial properties.

【0014】[0014]

【実施例】【Example】

(実施例1) 次の方法によりこの実施例のボタンを製造した。 先ず、40℃の温度下にて、ボタンの形成材原料を次の各成分の混合によって調 製した。 ポリエステル樹脂原料液 75重量% 抗菌剤 10重量% 分散剤(DMF) 5重量% なお、上記の抗菌剤は、リン酸カルシウム粉末に銀イオンを交換吸着したも のである。 次いで、この形成材原料を40〜50℃の温度下にてプレート状に硬化形成する。 次いで、この樹脂プレートを型抜きし、さらに切削、研磨加工、穴開け加工及び 艶出し加工を経てボタンを得た。 (Example 1) The button of this example was manufactured by the following method. First, the button forming material raw material was prepared by mixing the following ingredients at a temperature of 40℃. Manufactured. Polyester resin raw material liquid 75% by weight Antibacterial agent 10% by weight Dispersing agent (DMF) 5% by weight The above antibacterial agent is made by exchanging and adsorbing silver ions to calcium phosphate powder. It is. Next, this forming material raw material is cured and formed into a plate shape at a temperature of 40 to 50°C. Next, this resin plate is cut out, and further processed by cutting, polishing, drilling and Buttons were obtained after polishing.

【0015】 このようにして得られたボタン1を図1及び図2に示した。図示するように、 このボタン1は、その樹脂形成材2中に抗菌剤粒体3…を均一に分散した状態で 含有保持して構成されている。なお、4は前部表面、5は後部表面、また6は留 め付け糸用の開孔である。[0015] The button 1 thus obtained is shown in FIGS. 1 and 2. As shown, This button 1 has antibacterial agent particles 3 uniformly dispersed in its resin forming material 2. Contains and retains. Note that 4 is the front surface, 5 is the rear surface, and 6 is the clasp. This is an opening for the pinning thread.

【0016】 また、図3及び図4には、本考案には含まれない対照ボタンの構成を示した。 図示する対照ボタン11は抗菌剤粒体13…がその樹脂形成材12内部の中間部に凝集 状態で保持されてなる。また対照ボタン21は抗菌剤粒体23…がその樹脂形成材22 の表面部分に部分的に凝集した状態で偏在して保持されてなる。なお、14、24は 夫々の前部表面、15、25は夫々の後部表面であり、また16、26は夫々の開孔であ る。[0016] Further, FIGS. 3 and 4 show the configuration of a control button that is not included in the present invention. In the illustrated control button 11, antibacterial agent particles 13 aggregate in the middle part inside the resin forming material 12. It is maintained in the state. In addition, the control button 21 has antibacterial agent particles 23... and its resin forming material 22. It is held unevenly in a partially aggregated state on the surface of the . In addition, 14 and 24 are The respective front surfaces, 15, 25 are the respective rear surfaces, and 16, 26 are the respective apertures. Ru.

【0017】 対照ボタン11では、抗菌剤粒体13…のほとんどがその前部及び後部の表面14、 15からほぼ完全に隔離された状態にあることから、有効な抗菌効果は望み得ない と共に、ボタン内部に粒体物が集中的に存在することになるから、ボタンの構成 自体を弱体化するという欠点がある。[0017] In the control button 11, most of the antibacterial agent particles 13 are on its front and rear surfaces 14, Since it is almost completely isolated from 15, it is impossible to expect an effective antibacterial effect. At the same time, there will be a concentration of particles inside the button, so the structure of the button will be It has the disadvantage of weakening itself.

【0018】 また、対照ボタン21では、抗菌剤粒体23…が前部表面24又は後部表面25付近に 存在してその抗菌効果が有効に発揮されるが、その存在が表面部分に集中にする ために人が接触することにもなり、また抗菌剤粒体23自体の酸化変質化等の周囲 環境の影響により無効力化し、また表面摩耗によって抗菌剤粒体が容易に離脱す るおそれもあり、数年単位の長期に及ぶ有効な抗菌効果の持続は到底望めない。 またこのように抗菌剤粒体が表面付近に存在することは、ボタンに対する着色不 良の原因ともなる、等の欠点がある。[0018] In addition, in the control button 21, the antibacterial agent particles 23... are near the front surface 24 or the rear surface 25. When present, its antibacterial effect is effectively exerted, but its presence concentrates on the surface area. Therefore, people may come into contact with the antibacterial agent granules 23, and the surrounding area may be affected by oxidative deterioration of the antibacterial agent particles 23 itself. The antibacterial agent particles become ineffective due to environmental influences, and the antibacterial agent granules are easily released due to surface abrasion. There is a risk that the antibacterial effect will last for several years, so it is impossible to expect that the antibacterial effect will last for several years. In addition, the presence of antibacterial agent particles near the surface prevents coloring of buttons. There are drawbacks such as being the cause of poor performance.

【0019】 上記したような対照ボタン11及び21についての諸欠点は、本考案に係るボタン 1に於いては生じない。即ち、抗菌剤粒体3…は樹脂形成材2中に均一分散状態 にあり、その抗菌作用は後記するように、その表面4、5にも散在することから 有効に発揮される。なお、この抗菌作用はこのような表面4、5付近に存在する 抗菌剤粒体3…が主として担うとしても、その他の抗菌剤粒体3…も樹脂形成材 2の分子組成に応じてその抗菌作用を表面4、5上に及ぼす。また、この抗菌剤 粒体3…の均一散在構成によって、前記したボタン11に於ける弱体化と着色に対 する影響は解消され、また人が抗菌剤と接触する機会を減殺する。[0019] The various drawbacks of the contrast buttons 11 and 21 as described above are the same as those of the button according to the present invention. 1 does not occur. That is, the antibacterial agent particles 3 are uniformly dispersed in the resin forming material 2. , and its antibacterial action is also scattered on its surfaces 4 and 5, as described later. Effectively demonstrated. Furthermore, this antibacterial effect exists near such surfaces 4 and 5. Even if the antibacterial agent granules 3... are mainly responsible, other antibacterial agent granules 3... are also responsible for the resin forming material. Depending on the molecular composition of 2, it exerts its antibacterial action on surfaces 4, 5. Also, this antibacterial agent The uniform scattering structure of the particles 3 prevents the button 11 from becoming weakened and discolored. This eliminates the effects of antibacterial agents and reduces the chance of human contact with antimicrobial agents.

【0020】 次に、ボタン1についての抗菌効果を下記の手段によって試験した。 先ず、試験液の調製を次のように行った。 つまり、ハートインヒュージョン寒天培地で冷凍保存した大腸菌(Escherichi -a coli ; IFO 3301)を35℃で20時間培養し、この培養大腸菌を白金耳で2〜3 コロニー掻き取り、これをインヒュージョンブイヨン30mlで35℃、17時間、水平 振とう培養した。次いで、リン酸緩衡液にこの培養大腸菌を2000分の1容量に加 えて、菌数を5×105 個/mlとし、これを試験液とした。Next, the antibacterial effect of Button 1 was tested by the following means. First, a test solution was prepared as follows. In other words, Escherichia coli (IFO 3301) frozen and preserved on a heart infusion agar medium was cultured at 35°C for 20 hours, two to three colonies of this cultured E. coli were scraped off with a platinum loop, and this was added to 30 ml of infusion broth. The cells were cultured with horizontal shaking at 35°C for 17 hours. Next, this cultured E. coli was added to 1/2000 volume of the phosphoric acid buffer solution to give a bacterial count of 5×10 5 cells/ml, and this was used as a test solution.

【0021】 また、抗菌力測定を次のように行った。 先ず、被験ボタン1をキャップ付減菌容器内に収容し、このボタン1の表面4 上に前記した試験液を5ml塗布して、同容器内をキャップで密閉し試料とした。 次いで、この試料を25℃下で6時間、24時間及び48時間後に分けて夫々静置培 養した。 また、同一材で純粋に形成した同形同大のボタンに上記同様の操作を施してコ ントロールボタンとし、上記同様に静置培養した。[0021] In addition, antibacterial activity was measured as follows. First, the button 1 to be tested is placed in a sterilized container with a cap, and the surface 4 of the button 1 is 5 ml of the above-mentioned test solution was applied onto the container, and the inside of the container was sealed with a cap to serve as a sample. Next, this sample was divided into static cultures at 25°C for 6 hours, 24 hours, and 48 hours. fed. In addition, buttons of the same shape and size made purely from the same material can be used in the same manner as above. The cells were used as control buttons, and statically cultured in the same manner as above.

【0022】 次いで、被験ボタン1と上記コントロールボタン面上のコロニーをカウントし て大腸菌数を求めた。 なお、被験ボタンについては、抗菌剤粒体3の含有率が10重量%、20重量%及 び30重量%のものを作成し、夫々上記同様に処理して試料とし、同様に大腸菌数 を求めた。 これらの結果を次の表1に示した。[0022] Next, count the colonies on the test button 1 and the control button surface. The number of E. coli bacteria was determined. Regarding the test buttons, the content of antibacterial agent granules 3 was 10% by weight, 20% by weight, and 20% by weight. Prepare samples of 30% by weight and 30% by weight, process them in the same manner as above, and use them as samples. I asked for These results are shown in Table 1 below.

【表1】 [Table 1]

【0023】 この表1の結果によれば、本考案に係るボタンについては、当該抗菌剤によれ ばその含有量により限界があるものの、一定時間経過後に於いては有効な抗菌作 用が発揮されることを確認することができ、またコントロールボタンとの対比に 於いてもこの効果が有意であると判断される。[0023] According to the results in Table 1, the button according to the present invention is not affected by the antibacterial agent. Although there is a limit depending on the content of tobacco, effective antibacterial action is achieved after a certain period of time. You can confirm that the function is being used, and also compare it with the control button. This effect is also judged to be significant.

【0024】 (実施例2) この実施例でのボタンは次のような製造方法によって得た。 先ず、亜鉛と錫との合金材を約450 ℃の温度下で熔融状態とした。 次いで、この熔融物中にリン酸カルシウム粉末に銅イオンを交換吸着してなる 粒体状の抗菌剤を7重量%の割合で混入し、速やかにこの混入後の熔融物をボタ ン型内に流し込んだ。 次いで、自然放冷し、型内から取り出し、表面研磨加工を経て製品ボタンとし た。 この金属ボタンについても前記した樹脂製ボタン1と同様の抗菌効果を確認し 、またその効果が長期間に及ぶことも確認した。[0024] (Example 2) The button in this example was obtained by the following manufacturing method. First, an alloy material of zinc and tin was brought into a molten state at a temperature of approximately 450°C. Next, copper ions are exchanged and adsorbed to calcium phosphate powder in this melt. A granular antibacterial agent is mixed in at a ratio of 7% by weight, and the molten material after this mixing is immediately boiled. The mixture was poured into a mold. Next, it is left to cool naturally, taken out from the mold, and subjected to surface polishing to become a finished button. Ta. We confirmed that this metal button also has the same antibacterial effect as the resin button 1 mentioned above. It was also confirmed that the effect lasted for a long time.

【0025】[0025]

【考案の効果】[Effect of the idea]

上述したように本考案は構成されることから、次のような効果を奏する。 本考案に係るボタンに於いては、前記したように有効な抗菌作用が全表面に渡 って発揮され、各種の菌類に対してその繁殖を抑え又は死滅せしめることから、 衛生的な利用を図ることができる。 しかも、その作用は長期間に亘り、ボタンとしての利用期間に合致すること、 またボタンと接触する場合に於いても人を害することはないから、開き留め用の ボタンとしての機能も損なわれることはない。 Since the present invention is constructed as described above, it has the following effects. In the button according to the present invention, as mentioned above, the effective antibacterial action is spread over the entire surface. This is because it suppresses the proliferation or kills various types of fungi. It can be used hygienically. Moreover, its action lasts for a long time, matching the period of use as a button. Also, even if it comes into contact with the button, it will not cause any harm to people, so please use it for opening and closing. The function as a button is not impaired either.

【0026】 また、形成されたボタンにつき、一定の強度を保持し、また意図する着色のも のとして得られるから、従来どおりの多様なボタンを得ることができる。[0026] In addition, the formed button maintains a certain strength and has the desired coloring. Since it can be obtained as a button, a variety of buttons can be obtained as before.

【図面の簡単な説明】[Brief explanation of drawings]

【図1】本考案に係る実施例でのボタンの中央縦断面正
面図。
FIG. 1 is a front view of a central longitudinal cross-section of a button in an embodiment of the present invention.

【図2】同中央横断面平面図。FIG. 2 is a central cross-sectional plan view of the same.

【図3】対照ボタンの縦断面正面図。FIG. 3 is a vertical cross-sectional front view of a control button.

【図4】対照ボタンの縦断面正面図。FIG. 4 is a vertical cross-sectional front view of a control button.

【図面符号の説明】1 ボタン 2 形成材 3 抗菌剤粒体[Explanation of drawing symbols] 1 button 2 Forming material 3 Antibacterial agent granules

Claims (2)

【実用新案登録請求の範囲】[Scope of utility model registration request] 【請求項1】 ボタンの形成材中に粒体状の抗菌剤が均
一に分散された状態で含有保持されてなることを特徴と
する抗菌性能を有するボタン。
1. A button having antibacterial properties, characterized in that a granular antibacterial agent is contained and retained in a uniformly dispersed state in a material forming the button.
【請求項2】 抗菌剤が、リン酸カルシウムに抗菌性金
属イオンを交換吸着せしめてなる粉末粒状剤であること
を特徴とする請求項1の抗菌性能を有するボタン。
2. The button having antibacterial properties according to claim 1, wherein the antibacterial agent is a powdery granular agent made by exchanging and adsorbing antibacterial metal ions to calcium phosphate.
JP3778891U 1991-03-20 1991-03-20 Button with antibacterial properties Pending JPH04112611U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3778891U JPH04112611U (en) 1991-03-20 1991-03-20 Button with antibacterial properties

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3778891U JPH04112611U (en) 1991-03-20 1991-03-20 Button with antibacterial properties

Publications (1)

Publication Number Publication Date
JPH04112611U true JPH04112611U (en) 1992-09-30

Family

ID=31919441

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3778891U Pending JPH04112611U (en) 1991-03-20 1991-03-20 Button with antibacterial properties

Country Status (1)

Country Link
JP (1) JPH04112611U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100478931B1 (en) * 2002-05-02 2005-03-28 정호균 Manufacturing method of multi-function button

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01236008A (en) * 1988-03-16 1989-09-20 Dentaru Kagaku Kk Toothbrush
JPH02153723A (en) * 1988-12-05 1990-06-13 Lion Corp Viscose sponge having antibacterial property
JPH02264069A (en) * 1989-03-31 1990-10-26 Kuraray Co Ltd Production of antimicrobial molded product

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01236008A (en) * 1988-03-16 1989-09-20 Dentaru Kagaku Kk Toothbrush
JPH02153723A (en) * 1988-12-05 1990-06-13 Lion Corp Viscose sponge having antibacterial property
JPH02264069A (en) * 1989-03-31 1990-10-26 Kuraray Co Ltd Production of antimicrobial molded product

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100478931B1 (en) * 2002-05-02 2005-03-28 정호균 Manufacturing method of multi-function button

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