JPH038644B2 - - Google Patents
Info
- Publication number
- JPH038644B2 JPH038644B2 JP12799285A JP12799285A JPH038644B2 JP H038644 B2 JPH038644 B2 JP H038644B2 JP 12799285 A JP12799285 A JP 12799285A JP 12799285 A JP12799285 A JP 12799285A JP H038644 B2 JPH038644 B2 JP H038644B2
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- weight
- meth
- block copolymer
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 claims description 64
- 229920001400 block copolymer Polymers 0.000 claims description 47
- 239000000178 monomer Substances 0.000 claims description 37
- MMCOUVMKNAHQOY-UHFFFAOYSA-L oxido carbonate Chemical compound [O-]OC([O-])=O MMCOUVMKNAHQOY-UHFFFAOYSA-L 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical class 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 125000005037 alkyl phenyl group Chemical group 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 229920005989 resin Polymers 0.000 description 28
- 239000011347 resin Substances 0.000 description 28
- 239000000203 mixture Substances 0.000 description 23
- 238000000034 method Methods 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 16
- 238000006116 polymerization reaction Methods 0.000 description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 13
- -1 2-ethylhexyl Chemical group 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000011159 matrix material Substances 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- 150000002978 peroxides Chemical class 0.000 description 5
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 5
- BMPPHGZRHQWRFX-UHFFFAOYSA-N (1-tert-butylperoxy-2-carboxyoxyethyl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(COC(O)=O)OOC(C)(C)C BMPPHGZRHQWRFX-UHFFFAOYSA-N 0.000 description 4
- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- BEOXWOUYOVVTOU-UHFFFAOYSA-N 2-carboxyoxyethyl 3-(2-methylpentan-2-ylperoxy)prop-2-enoate Chemical compound CCCC(C)(C)OOC=CC(=O)OCCOC(O)=O BEOXWOUYOVVTOU-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- CVEISTHBPFIRKN-UHFFFAOYSA-N (1-butylperoxy-2-carboxyoxyethyl) 2-methylprop-2-enoate Chemical compound CCCCOOC(COC(O)=O)OC(=O)C(C)=C CVEISTHBPFIRKN-UHFFFAOYSA-N 0.000 description 1
- LGTYQJIJDFPOPA-UHFFFAOYSA-N (1-tert-butylperoxy-2-carboxyoxypropan-2-yl) 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(OC(O)=O)COOC(C)(C)C LGTYQJIJDFPOPA-UHFFFAOYSA-N 0.000 description 1
- LGDKZTWUKPJMHD-UHFFFAOYSA-N 2-(1-tert-butylperoxy-2-carboxyoxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOC(COC(=O)O)OOC(C)(C)C LGDKZTWUKPJMHD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- OQONQKYKMBUFLS-UHFFFAOYSA-N 2-[(2-methylpropan-2-yl)oxycarbonyloxy]ethyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)OCCOC(=O)C=C OQONQKYKMBUFLS-UHFFFAOYSA-N 0.000 description 1
- NZQYTVCGWJZBKK-UHFFFAOYSA-N 2-carboxyoxyethyl 3-(2,4,4-trimethylpentan-2-ylperoxy)prop-2-enoate Chemical compound CC(C)(C)CC(C)(C)OOC=CC(=O)OCCOC(O)=O NZQYTVCGWJZBKK-UHFFFAOYSA-N 0.000 description 1
- JTCDBWDDCRFJFF-UHFFFAOYSA-N 2-carboxyoxyethyl 3-[2-(4-propan-2-ylphenyl)propan-2-ylperoxy]prop-2-enoate Chemical compound CC(C)C1=CC=C(C=C1)C(C)(C)OOC=CC(=O)OCCOC(=O)O JTCDBWDDCRFJFF-UHFFFAOYSA-N 0.000 description 1
- YTEAHQIOWUNLTP-UHFFFAOYSA-N 2-carboxyoxyethyl 3-tert-butylperoxyprop-2-enoate Chemical compound CC(C)(C)OOC=CC(=O)OCCOC(O)=O YTEAHQIOWUNLTP-UHFFFAOYSA-N 0.000 description 1
- VYVRAXXYCTWZLO-UHFFFAOYSA-N 2-carboxyoxypropan-2-yl 3-(2,4,4-trimethylpentan-2-ylperoxy)prop-2-enoate Chemical compound CC(C)(C)CC(C)(C)OOC=CC(=O)OC(C)(C)OC(O)=O VYVRAXXYCTWZLO-UHFFFAOYSA-N 0.000 description 1
- IRSOWCFTLDBUHO-UHFFFAOYSA-N 2-carboxyoxypropan-2-yl 3-(2-methylpentan-2-ylperoxy)prop-2-enoate Chemical compound CCCC(C)(C)OOC=CC(=O)OC(C)(C)OC(O)=O IRSOWCFTLDBUHO-UHFFFAOYSA-N 0.000 description 1
- RVAKJVUONBGRJG-UHFFFAOYSA-N 2-carboxyoxypropan-2-yl 3-tert-butylperoxyprop-2-enoate Chemical compound CC(C)(C)OOC=CC(=O)OC(C)(C)OC(O)=O RVAKJVUONBGRJG-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OCDOXHMCBNUJJT-UHFFFAOYSA-N [2-carboxyoxy-1-(2,4,4-trimethylpentan-2-ylperoxy)ethyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(COC(O)=O)OOC(C)(C)CC(C)(C)C OCDOXHMCBNUJJT-UHFFFAOYSA-N 0.000 description 1
- GYAULSLYQCDSDD-UHFFFAOYSA-N [2-carboxyoxy-1-(2,4,4-trimethylpentan-2-ylperoxy)propan-2-yl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(OC(O)=O)COOC(C)(C)CC(C)(C)C GYAULSLYQCDSDD-UHFFFAOYSA-N 0.000 description 1
- NLWBSJAGYYEQDW-UHFFFAOYSA-N [2-carboxyoxy-1-(2-methylbutan-2-ylperoxy)ethyl] 2-methylprop-2-enoate Chemical compound CCC(C)(C)OOC(COC(O)=O)OC(=O)C(C)=C NLWBSJAGYYEQDW-UHFFFAOYSA-N 0.000 description 1
- MVPZHSCAJBECMG-UHFFFAOYSA-N [2-carboxyoxy-1-(2-methylbutan-2-ylperoxy)propan-2-yl] 2-methylprop-2-enoate Chemical compound CCC(C)(C)OOCC(C)(OC(O)=O)OC(=O)C(C)=C MVPZHSCAJBECMG-UHFFFAOYSA-N 0.000 description 1
- HCMDXMDZWCYFEG-UHFFFAOYSA-N [2-carboxyoxy-1-(2-methylpentan-2-ylperoxy)ethyl] 2-methylprop-2-enoate Chemical compound CCCC(C)(C)OOC(COC(O)=O)OC(=O)C(C)=C HCMDXMDZWCYFEG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- TXHIDIHEXDFONW-UHFFFAOYSA-N benzene;propan-2-one Chemical compound CC(C)=O.C1=CC=CC=C1 TXHIDIHEXDFONW-UHFFFAOYSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000005912 ethyl carbonate group Chemical group 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical compound CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000000045 pyrolysis gas chromatography Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12799285A JPS61287914A (ja) | 1985-06-14 | 1985-06-14 | ブロック共重合体を製造する方法 |
| US06/871,912 US4665131A (en) | 1985-06-14 | 1986-06-09 | Block copolymer |
| EP86304465A EP0206644B1 (fr) | 1985-06-14 | 1986-06-11 | Copolymère séquencé |
| DE8686304465T DE3676884D1 (de) | 1985-06-14 | 1986-06-11 | Blockmischpolymer. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12799285A JPS61287914A (ja) | 1985-06-14 | 1985-06-14 | ブロック共重合体を製造する方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61287914A JPS61287914A (ja) | 1986-12-18 |
| JPH038644B2 true JPH038644B2 (fr) | 1991-02-06 |
Family
ID=14973774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12799285A Granted JPS61287914A (ja) | 1985-06-14 | 1985-06-14 | ブロック共重合体を製造する方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61287914A (fr) |
-
1985
- 1985-06-14 JP JP12799285A patent/JPS61287914A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61287914A (ja) | 1986-12-18 |
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