JPH0349945A - Coated steel plate having uneven surface and preparation thereof - Google Patents

Coated steel plate having uneven surface and preparation thereof

Info

Publication number
JPH0349945A
JPH0349945A JP18457589A JP18457589A JPH0349945A JP H0349945 A JPH0349945 A JP H0349945A JP 18457589 A JP18457589 A JP 18457589A JP 18457589 A JP18457589 A JP 18457589A JP H0349945 A JPH0349945 A JP H0349945A
Authority
JP
Japan
Prior art keywords
steel plate
light
resin composition
cured
uncured
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP18457589A
Other languages
Japanese (ja)
Inventor
Kyoji Mizutani
水谷 京二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MIZUTANI PAINT KK
SILVER KOGYO KK
Silver Industries Inc
Original Assignee
MIZUTANI PAINT KK
SILVER KOGYO KK
Silver Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MIZUTANI PAINT KK, SILVER KOGYO KK, Silver Industries Inc filed Critical MIZUTANI PAINT KK
Priority to JP18457589A priority Critical patent/JPH0349945A/en
Publication of JPH0349945A publication Critical patent/JPH0349945A/en
Pending legal-status Critical Current

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  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

PURPOSE:To easily form a protruding part having a complicated shape by applying a photo-setting resin composition to the surface of a steel plate and partially irradiat ing the same with light to form the cured and uncured parts of the photo-setting resin composition and removing the uncured part to form a coating layer to the surface of the steel plate. CONSTITUTION:As a steel plate, a stainless steel plate is used and pretreated, for example, in such a way that said steel plate is degreased and subsequently treated with sand blasting or a coating type chromate solution and coated with epoxy resin paint as a primer. As a photo-setting resin composition, a photopolymerizable vinyl compound is used and a filler, a tixotripic agent, a photosensitizer and a diluent may be added and, as light to be applied, radioactive rays such as ultraviolet rays or elec tron beam are used. For example, when a filter having shadow is used as a method for partially irradiating the surface of the steel plate with light, the cured part irradiat ed with light at a transparent part and an uncured part not irradiated with light because of a dark color can be simultaneously formed and, when only the uncoated part is washed off by a solvent or washing, the cured part remains on the surface of the steel plate as a protruding part.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は1例えば、・浴槽、浴室ユニット等に使用する
ことができ、表面に光硬化性樹脂による凹凸部分を有す
る被覆鋼板及びその製造方法に関するものである。
[Detailed Description of the Invention] <Industrial Application Field> The present invention provides, for example, 1) a coated steel plate that can be used for bathtubs, bathroom units, etc. and has an uneven portion made of a photocurable resin on its surface, and a method for manufacturing the same; It is related to.

〈従来の技術〉 従来より表面に凹凸部分を形成した鋼板の製造方法とし
ては、(a)鋼板のエツチング、(b)エンボス加工用
ロールまたはプレス機械の使用、(c)模様塗料の塗装
、(d)加工されたシート類の貼着、(e)タイル材の
接着等があった。
<Prior art> Conventional methods for manufacturing steel plates with uneven parts formed on their surfaces include (a) etching of steel plates, (b) use of embossing rolls or press machines, (c) painting of pattern paints, ( d) Adhesion of processed sheets, (e) Adhesion of tile materials, etc.

) 〈発明が解決しようとする課題〉 しかし、上記したような方法ではそれぞれに欠点がある
) <Problem to be solved by the invention> However, each of the above methods has drawbacks.

例えば上記した(a)の方法によるエツチングでは鋼板
を腐食液により腐食して凹部を形成する方法であるため
、鋼板の厚さ以上の深さを形成することは不可能である
。この為、深い凹部を形成する場合には厚い鋼板を使用
する必要があり、重量増加及び価格上昇の問題を生ずる
ことになる。また、その工程において、マスク材の貼着
力によってはエツチング途中で剥離したり、エツチング
後の除去に手間取ったりする欠点をも有している。
For example, in the etching method (a) described above, since the recesses are formed by corroding the steel plate with a corrosive liquid, it is impossible to form a recess that is deeper than the thickness of the steel plate. For this reason, when forming deep recesses, it is necessary to use thick steel plates, resulting in problems of increased weight and price. Furthermore, in this process, depending on the adhesion strength of the mask material, it may peel off during etching, or it may take time to remove it after etching.

次に、上記した(b’)のエンボス加工法では、金型を
作り機械的に押圧変形して凹凸を形成する方法であるた
め、金型の作製に高い費用を要することになって多種の
凹凸形状に対応することができない。また、鋼板に変形
による歪みや反りを生じて外観を損なう問題をも有して
いる。
Next, in the above-mentioned embossing method (b'), a mold is made and mechanically pressed and deformed to form unevenness, so the manufacturing of the mold is expensive and there are many types of embossing. Unable to handle uneven shapes. Further, there is also the problem that the steel plate is distorted or warped due to deformation, which impairs its appearance.

また、(C)の模様塗料方法には、ハンマートーン塗料
やちぢみ塗料等を使用するのであるが、表現できる模様
が著しく制限され、形成される凹部もlll1m程度で
ある。また、概して堅牢性が低いので装飾等の使用に限
定される問題をも有している。
Further, in the pattern painting method (C), a hammer tone paint, a shrinking paint, etc. are used, but the patterns that can be expressed are severely limited, and the recesses formed are also about 1 m long. Additionally, since they generally have low robustness, they have the problem of being limited to use as decoration.

さらに、(dlのシート類を貼着する方法及び(e)の
タイル材を接着する方法、及びその他の成形部材を接着
したり貼着する方法では、接着剤、貼着剤の耐水性が課
題になるし、接着したり貼着する作業についても制限が
多く、且つ手間や時間が掛るという問題を有している。
Furthermore, the water resistance of adhesives and adhesives is an issue in the method of pasting sheets (dl), the method of gluing tiles (e), and the method of gluing or pasting other molded parts. Moreover, there are many restrictions on the work of gluing and pasting, and there are problems in that it takes time and effort.

従って、上記したような欠点のない凹凸表面を有する被
覆鋼材が嘱望されていた。
Therefore, a coated steel material having an uneven surface free from the above-mentioned defects has been desired.

(課題を解決するための手段) 本発明は上記に鑑み提案されたもので、鋼板の表面に光
硬化性樹脂組成物を塗布し、部分的に光を照射すること
により光硬化性樹脂組成物の硬化部分と未硬化部分とを
形成し、該未硬化部分を除去した後に、鋼板の表面に被
覆層を形成するようにしたことを特徴とする凹凸表面を
有する被覆鋼板及びその製造方法に関するものである。
(Means for Solving the Problems) The present invention has been proposed in view of the above, and the photocurable resin composition is formed by applying a photocurable resin composition to the surface of a steel plate and partially irradiating it with light. A coated steel sheet having an uneven surface and a method for producing the same, characterized in that a hardened portion and an unhardened portion are formed, and a coating layer is formed on the surface of the steel sheet after the unhardened portion is removed. It is.

まずζ本発明に使用する鋼板には、強度や耐腐食性の高
いステンレス鋼板等が使用されるが、通常塗装に供する
場合と同様に前処理を行うことが望ましい、この前処理
とは、例えば脱脂後サンドブラストまたは塗布形クロメ
ート液で処理した後、エポキシ樹脂系塗料をブライマー
(下塗り剤)として塗布するものである。
First, the steel plate used in the present invention is a stainless steel plate with high strength and corrosion resistance, but it is desirable to perform pretreatment in the same way as when applying it to normal painting.This pretreatment includes, for example, After degreasing, sandblasting or coating with a chromate solution, an epoxy resin paint is applied as a primer (undercoat).

また、本発明に使用する光硬化性樹脂組成物としては、
光重合性ビニル化合物を必須成分とし、その他には顔料
、充填剤、揺変性剤、光増感剤(光開始剤)、希釈剤等
を添加してもよい。ここで、光重合性ビニル化合物とは
、分子内に光重合性ビニル基を1以上有するものであ−
リ、通常光重合性ビニル基が1つのものと2つ以上のも
のとを併用して重合後には三次元架橋するように構成す
る。
In addition, the photocurable resin composition used in the present invention includes:
The photopolymerizable vinyl compound is an essential component, and pigments, fillers, thixotropic agents, photosensitizers (photoinitiators), diluents, etc. may also be added. Here, the photopolymerizable vinyl compound is one having one or more photopolymerizable vinyl groups in its molecule.
(2) Usually, one photopolymerizable vinyl group and two or more photopolymerizable vinyl groups are used in combination so that three-dimensional crosslinking occurs after polymerization.

なお、上記した光硬化性樹脂組成物に照射する光は、紫
外線若しくは電子線等の放射線でよく、選定した光に応
じて光源及び上記した光硬化性樹脂組成物を調整すれば
よい。
Note that the light irradiated onto the photocurable resin composition described above may be radiation such as ultraviolet rays or electron beams, and the light source and the photocurable resin composition described above may be adjusted according to the selected light.

紫外線照射を使用する場合は、照射エネルギーが低いの
で、光硬化性樹脂組成物として光重合性ビニル化合物と
光増感剤とを併用する必要がある。また、塗布膜が厚い
程、顔料や充填剤の混合量が制限されることとなる。こ
れは、顔料や充填剤が光重合性ビニル化合物を隠蔽した
り、光を吸収若しくは反射するためであり、隠蔽性の高
い顔料や金属顔料等を大量に使用する場合は乾燥不良を
生じやすい。
When using ultraviolet irradiation, since the irradiation energy is low, it is necessary to use a photopolymerizable vinyl compound and a photosensitizer together as a photocurable resin composition. Furthermore, the thicker the coating film, the more limited the amount of pigments and fillers to be mixed. This is because the pigment or filler hides the photopolymerizable vinyl compound or absorbs or reflects light, and if a large amount of pigments or metal pigments with high hiding properties are used, poor drying tends to occur.

一方、電子線等の放射線を使用して照射する場合は、照
射エネルギーが高く、通常は光増感剤の添加を必要とし
ない。また、上記したような顔料や充填剤の使用につい
ても特に制限されることもな(、乾燥不良を起しに(い
が、照射エネルギーが強すぎて他部材が老化する等の悪
影響を及ぼす虞れがあり、さらには照射装置が大型であ
るという課題を有している。
On the other hand, when irradiating with radiation such as an electron beam, the irradiation energy is high and the addition of a photosensitizer is usually not required. In addition, there are no particular restrictions on the use of pigments or fillers as described above (because they may cause poor drying), but there is a risk that the irradiation energy may be too strong and cause adverse effects such as aging of other components. Furthermore, there are problems in that the irradiation device is large.

従って、通常は最も技術的に成熟している紫外線を、水
銀ランプ或いはメタルハライドランプ等を光源として照
射すればよい。
Therefore, it is usually sufficient to irradiate ultraviolet rays, which are the most technologically mature, using a mercury lamp, a metal halide lamp, or the like as a light source.

上記した光硬化性樹脂組成物は前記した鋼板の表面にス
プレー装置や刷毛、ローラー等を用いて塗布する。
The photocurable resin composition described above is applied to the surface of the steel plate using a spray device, a brush, a roller, or the like.

なお、光硬化性樹脂組成物が高粘度の液体或いはチクソ
トロビック性の高い液体であれば、塗布後の流動性が殆
どなく、凸部の厚い成形に好適なものとなる。
Note that if the photocurable resin composition is a liquid with high viscosity or a liquid with high thixotropic properties, it will have almost no fluidity after application and will be suitable for molding thick convex portions.

本発明では、鋼板の表面に上記したように光硬化性樹脂
を塗布した後、部分的に光を照射して光硬化性樹脂の硬
化部分と未硬化部分とを形成するのであるが、部分的に
光を照射する方法として、例えば陰影を何する光フィル
ターを使用する。
In the present invention, after applying a photocurable resin to the surface of a steel plate as described above, light is partially irradiated to form a hardened portion and an uncured portion of the photocurable resin. For example, a light filter is used to create shadows.

このフィルターは、透明な板状材に陰影部分を設けて作
製するもので、この陰影部分は光を遮蔽して光硬化性樹
脂組成物の未硬化部分を形成させるために設けられるも
のである。
This filter is manufactured by providing a shaded portion on a transparent plate-like material, and this shaded portion is provided to block light and form an uncured portion of the photocurable resin composition.

上記した光フィルターの陰影部分は、写真や印刷、その
他の方法により容易に作製することができ、多種類の陰
影を有する光フィルターを使用することによって多種類
の凹凸形状を作製することができるものである。
The shaded areas of the above-mentioned optical filter can be easily created by photography, printing, or other methods, and by using an optical filter with many types of shading, many types of uneven shapes can be created. It is.

従って、上記したように作製した陰影を有する光フィル
ターを通して光硬化性樹脂組成物に光を照射すると、透
明部分で光が照射された硬化部分と、濃色で光が照射さ
れない未硬化部分とを同時に形成することができる。
Therefore, when light is irradiated on the photocurable resin composition through the light filter having a shade produced as described above, the cured portion that is transparent and is irradiated with light, and the uncured portion that is dark and is not irradiated with light. can be formed simultaneously.

また、光硬化性樹脂組成物の硬化部分は三次元架橋して
不溶性となっていて、未硬化部分は、前記したように光
重合性ビニル化合物とその他の添加剤から構成されて軟
質であるから、未硬化部分だけを溶剤や水洗などによっ
て容易に洗浄、除去することができ、硬化部分が凸部と
して鋼材表面に残存することになる。
In addition, the cured portion of the photocurable resin composition is three-dimensionally crosslinked and becomes insoluble, and the uncured portion is soft and composed of the photopolymerizable vinyl compound and other additives as described above. , only the unhardened portion can be easily cleaned and removed by solvent or washing with water, and the hardened portion remains as a convex portion on the surface of the steel material.

そして、上記したように形成される凹凸表面を有する鋼
板の全面若しくは一部に被覆層を形成する。
Then, a coating layer is formed on the entire surface or a part of the steel plate having the uneven surface formed as described above.

上記した被覆層は、例えば高耐候性塗料、スウエード調
塗料、ハードコート剤、通常の着色塗料、半透明または
透明塗料等を塗装したり、金属感を付与するためにメツ
キすることにより形成すす ることができ−る。
The above-mentioned coating layer is formed by, for example, coating with a highly weather-resistant paint, suede-like paint, hard coat agent, ordinary colored paint, translucent or transparent paint, or by plating to give a metallic feel. I can do that.

上記のようにして形成された硬化部分である凸部は、耐
候性、肌触り感、耐摩耗性、質感等の多様な要求に対し
て十分に対応できるとは限らないので、被覆層を設ける
ことによって上記した各種の要求に対応させるものであ
る。
The convex portion, which is the hardened portion formed as described above, cannot necessarily meet various requirements such as weather resistance, texture, abrasion resistance, texture, etc., so it is necessary to provide a coating layer. This is to meet the various demands mentioned above.

〈実施例〉 以下に本発明の詳細な説明する。<Example> The present invention will be explained in detail below.

実施例1 エポキシ樹脂系塗料がブライマーとして塗装済のステン
レス鋼板に光硬化性樹脂組成物を平均膜厚1.2+++
+++どなるように塗装した。次に、塗布面に黒色塗料
でタイル状模様を描いた厚さ約50μmのポリプロピレ
ンフィルムを密着させて、紫外線照射装置中を通過させ
た後、フィルムを剥すと黒色塗料で模様を付けた部分は
未硬化であったので、溶剤で洗浄、除去し、凹凸表面を
有するステンレス鋼板を得た。凹凸表面のうち凸部は黄
色を帯びた半透明層であり、凹部は白色のステンレス鋼
板である。この全面にフタロシアニングリーンを混入し
たパワーフロン#3000S I水谷ペイント株式会社
製の超耐候性フッ素樹脂塗料(以下同じ))を塗装して
単調のタイル状外観を呈する被覆ステンレス鋼板を得た
。凹部の深さは約1.211Imであった。
Example 1 A photocurable resin composition was applied to a stainless steel plate coated with an epoxy resin paint as a brimer to an average film thickness of 1.2+++.
+++ I painted it to look like it. Next, a polypropylene film with a thickness of approximately 50 μm with a tile-like pattern drawn with black paint is closely attached to the coated surface and passed through an ultraviolet irradiation device. When the film is peeled off, the area with the pattern painted with black paint is visible. Since it was uncured, it was removed by cleaning with a solvent to obtain a stainless steel plate with an uneven surface. The convex portions of the uneven surface are a yellowish semi-transparent layer, and the concave portions are a white stainless steel plate. The entire surface was coated with Power Flon #3000S I super weather-resistant fluororesin paint (manufactured by Mizutani Paint Co., Ltd. (the same applies hereinafter)) mixed with phthalocyanine green to obtain a coated stainless steel plate exhibiting a monotonous tile-like appearance. The depth of the recess was approximately 1.211 Im.

実施例2 実施例1で使用したタイル状模様を描いたフィルムの代
わりに花柄を描いたフィルムを使用した以外は同様に操
作を行って、花柄の凹凸表面を有するステンレス鋼板を
得た。次に、凸部である花柄にシルクスクリーン印刷で
着色した後、全面にパワーフロン#300OSクリヤー
を塗装し、タイルの組み合せでは得ることが難しい模様
の凹凸表面を有する被覆ステンレス鋼板を得た。
Example 2 A stainless steel plate having an uneven surface with a floral pattern was obtained in the same manner as in Example 1, except that a film with a floral pattern was used instead of the film with a tile-like pattern used in Example 1. Next, after coloring the flower pattern, which is a convex part, by silk screen printing, the entire surface was coated with Powerflon #300OS clear to obtain a coated stainless steel plate having an uneven surface with a pattern that is difficult to obtain with a combination of tiles.

実施例3 実施例1と同様にして凹凸表面を有するステンレス鋼板
を得た後、真空蒸着法でアルミニウムメツキし、次いで
、全面にパワーフロン#3000Sクリヤーを塗装して
、当ステンレス鋼板の厚みよりも深い凹部を有する金属
調被覆ステンレス鋼板を得た。
Example 3 After obtaining a stainless steel plate with an uneven surface in the same manner as in Example 1, it was plated with aluminum using a vacuum evaporation method, and then the entire surface was coated with Powerflon #3000S clear to make it thicker than the thickness of the stainless steel plate. A metallic coated stainless steel plate with deep recesses was obtained.

〈発明の効果〉 以上説明したように本発明の凹凸表面を有する被覆鋼板
は、凸部が硬化した光硬化性樹脂組成物であるので、鋼
板自体の厚みは薄いものでもよく、また軽量であるから
例λば建築物の浴室や洗面所の壁材、床材、または浴槽
、その他各種の用途に利用することができるものである
<Effects of the Invention> As explained above, the coated steel sheet having an uneven surface of the present invention is made of a photocurable resin composition in which the convex portions are hardened, so the steel sheet itself may be thin and lightweight. For example, λ can be used as wall materials, floor materials, bathtubs, and other various purposes in bathrooms and washrooms of buildings.

また、本発明の被覆鋼板は、従来の凹凸表面を有する鋼
板のように歪みや反りがな(、さらに従来の模様塗装で
は不可能であった複雑な形状の凸部を容易に形成するこ
とができ、且つ該凸部を著しく高く形成することができ
る。
In addition, the coated steel sheet of the present invention does not distort or warp like conventional steel sheets with uneven surfaces (in addition, it is possible to easily form convex portions with complex shapes that were impossible with conventional pattern painting). In addition, the convex portion can be formed extremely high.

さらに、本発明の被覆鋼板の製造方法では、陰影を有す
る光フィルターを変更するだけで多種の形状を有する凹
凸表面を形成することができ、さらには被覆1として種
々の塗料を塗布したりメツキをすることにより多種の外
観装飾を容易に且つ安価に表現することができる。
Furthermore, in the method for producing a coated steel sheet of the present invention, uneven surfaces having various shapes can be formed simply by changing the light filter with shading, and furthermore, various paints or plating can be applied as the coating 1. By doing so, various exterior decorations can be easily and inexpensively expressed.

Claims (2)

【特許請求の範囲】[Claims] (1)鋼板の表面に、硬化させた光硬化性樹脂組成物で
ある凸部が部分的に形成され、該凸部の表面に被覆層が
形成されていることを特徴とする凹凸表面を有する被覆
鋼板。
(1) The steel plate has an uneven surface characterized by partially forming protrusions made of a cured photocurable resin composition on the surface of the steel plate, and forming a coating layer on the surface of the protrusions. Coated steel plate.
(2)鋼板の表面に光硬化性樹脂組成物を塗布した後に
部分的に光を照射することにより、光が照射した硬化部
分と光が照射しない未硬化部分とを形成し、該未硬化部
分を除去して部分的に凸部を形成した後に、全面若しく
は一部に被覆層を形成するようにしたことを特徴とする
凹凸表面を有する被覆鋼板の製造方法。
(2) By applying a photocurable resin composition to the surface of a steel plate and then partially irradiating it with light, a cured part that is irradiated with light and an uncured part that is not irradiated with light are formed, and the uncured part 1. A method for manufacturing a coated steel sheet having an uneven surface, characterized in that after partially forming convex portions by removing the above, a coating layer is formed on the entire surface or a portion of the surface.
JP18457589A 1989-07-19 1989-07-19 Coated steel plate having uneven surface and preparation thereof Pending JPH0349945A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18457589A JPH0349945A (en) 1989-07-19 1989-07-19 Coated steel plate having uneven surface and preparation thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18457589A JPH0349945A (en) 1989-07-19 1989-07-19 Coated steel plate having uneven surface and preparation thereof

Publications (1)

Publication Number Publication Date
JPH0349945A true JPH0349945A (en) 1991-03-04

Family

ID=16155606

Family Applications (1)

Application Number Title Priority Date Filing Date
JP18457589A Pending JPH0349945A (en) 1989-07-19 1989-07-19 Coated steel plate having uneven surface and preparation thereof

Country Status (1)

Country Link
JP (1) JPH0349945A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4067256A4 (en) * 2019-11-26 2024-01-03 Okura Industrial Co., Ltd. Inner pouch for cylindrical container and composite container using same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4067256A4 (en) * 2019-11-26 2024-01-03 Okura Industrial Co., Ltd. Inner pouch for cylindrical container and composite container using same
US11932453B2 (en) 2019-11-26 2024-03-19 Okura Industrial Co., Ltd. Inner pouch for cylindrical container and composite container using same

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