JPH0339663B2 - - Google Patents
Info
- Publication number
- JPH0339663B2 JPH0339663B2 JP62150410A JP15041087A JPH0339663B2 JP H0339663 B2 JPH0339663 B2 JP H0339663B2 JP 62150410 A JP62150410 A JP 62150410A JP 15041087 A JP15041087 A JP 15041087A JP H0339663 B2 JPH0339663 B2 JP H0339663B2
- Authority
- JP
- Japan
- Prior art keywords
- fatty acid
- calcium
- oils
- fats
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 45
- 239000000194 fatty acid Substances 0.000 claims description 45
- 229930195729 fatty acid Natural products 0.000 claims description 45
- 150000004665 fatty acids Chemical class 0.000 claims description 44
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 25
- 239000011575 calcium Substances 0.000 claims description 25
- 229910052791 calcium Inorganic materials 0.000 claims description 25
- 239000003925 fat Substances 0.000 claims description 21
- 239000003921 oil Substances 0.000 claims description 20
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 19
- 239000011777 magnesium Substances 0.000 claims description 19
- 229910052749 magnesium Inorganic materials 0.000 claims description 19
- 241000282849 Ruminantia Species 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 235000019197 fats Nutrition 0.000 description 20
- 235000019198 oils Nutrition 0.000 description 19
- 239000003760 tallow Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 235000015278 beef Nutrition 0.000 description 9
- 210000004767 rumen Anatomy 0.000 description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
- 102000004169 proteins and genes Human genes 0.000 description 6
- 108090000623 proteins and genes Proteins 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 235000013365 dairy product Nutrition 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000015097 nutrients Nutrition 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000036760 body temperature Effects 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 235000014593 oils and fats Nutrition 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000021321 essential mineral Nutrition 0.000 description 3
- -1 first Substances 0.000 description 3
- 244000144972 livestock Species 0.000 description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 210000000214 mouth Anatomy 0.000 description 3
- 235000012424 soybean oil Nutrition 0.000 description 3
- 239000003549 soybean oil Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 206010003210 Arteriosclerosis Diseases 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 208000000913 Kidney Calculi Diseases 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 206010029148 Nephrolithiasis Diseases 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 210000003165 abomasum Anatomy 0.000 description 2
- 208000011775 arteriosclerosis disease Diseases 0.000 description 2
- 206010003246 arthritis Diseases 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 244000309466 calf Species 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 210000000813 small intestine Anatomy 0.000 description 2
- 239000008149 soap solution Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 210000004872 soft tissue Anatomy 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 208000004434 Calcinosis Diseases 0.000 description 1
- 244000020518 Carthamus tinctorius Species 0.000 description 1
- 235000003255 Carthamus tinctorius Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 208000008167 Magnesium Deficiency Diseases 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 239000003568 Sodium, potassium and calcium salts of fatty acids Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 235000013969 calcium salts of fatty acid Nutrition 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 235000019621 digestibility Nutrition 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 210000004051 gastric juice Anatomy 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000004764 magnesium deficiency Nutrition 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000022676 rumination Effects 0.000 description 1
- 208000015212 rumination disease Diseases 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000000626 ureter Anatomy 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は反芻動物用飼料原料の製造法に関する
ものである。
油脂は、蛋白質、炭水化物、無機物、ビタミン
などと共に家畜の生命の維持や畜産物の生産のた
めに極めて重要な役割を果す栄養素である。牛、
綿羊のような反芻家畜では、これらの栄養素が第
一胃中の微生物の栄養源として一部分解、吸収さ
れることが多い。ことに高能力牛の場合、エネル
ギー要求量は穀物のみでは充足できないことから
トウモロコシの2.25倍のエネルギーを含有する油
脂でトウモロコシを一部代替えし生産性を高めて
いる。
しかし、油脂は胃中の諸酵素の活性を阻害し、
飼料の消化率の低下、特にセルロールスの消化や
非蛋白態窒素化合物の利用を阻害するものともい
われ、油脂の給与には限界があつた。また、油脂
中の不飽和脂肪酸が微生物の作用によつて還元さ
れて一部飽和酸になる等の欠点があつた。
そのため、油脂の微生物による分解、吸収、諸
酵素への活性阻害、油脂の酸化が生じないように
直接第一胃から第三胃を通過させて(以下、バイ
パスという)、第四胃での消化を効率的に行う必
要がある。
(従来の技術)
栄養素をバイパスさせて有効利用をはかる従来
技術には、例えば牛脂を大豆油粕で保護する方法
としてK.S.Eng、Feedstuffs、49(47)、18
(1977);N.E.Smith et al、J.Dairy Sci.、61、
747(1978)があり、油脂を蛋白質で被覆し、該蛋
白質をホルムアルデヒドで保護する方法として
T.R.Wrenn et al、J.Dairy Sci.、60、521
(1977);W.Chalupa、Feed Management、33、
10(1982);A.M.Gaddenet al、J.Dairy Sci.、
67、1414(1948)等がある。
(発明が解決しようとする問題点)
しかしながら油脂を保護する従来技術は、例え
ば牛脂を大豆油粕で保護する方法においては、口
腔での荒噛み、第一胃での加温、撹拌、口腔への
反芻、第三胃での圧迫磨砕などにより油脂を保護
し得たかどうか疑問があり、また蛋白質のホルマ
リン処理による方法においては油脂を保護する目
的はかなえられたとしても、蛋白質自体が変性す
るために栄養源とならない欠点がある。
また、米国特許第4642317号公報と特公昭59−
10780号公報には、油脂を脂肪酸のカルシウム塩
の形で反芻動物に給与することが開示されてい
る。
この脂肪酸カルシウムは、口腔から第三胃を通
過するまでは、体温による融解や脂肪酸への分解
を受けることなくバイパスし、第四胃において強
い酸性の胃液によつて脂肪酸に分解し、分解に伴
う融点降下によつて体温で融解して、小腸で吸収
されるものであり、カルシウム分は反芻動物に必
要なミネラルとして利用される。
一般に動物飼料に有用なミネラルとしては、カ
ルシウム、マグネシウム、リン、亜鉛、マンガ
ン、銅、鉄、モリブデン等が知られているが、前
記従来技術のように脂肪酸カルシウムだけを給与
するときには、血液中のカルシウム値のみが高く
なつて、軟組織へのカルシウムの沈着が生じ、動
脈硬化症や関節炎、腎臓結石などを引き起す原因
となる一方、別途摂取されたマグネシウム分がカ
ルシウムと一緒に尿から排泄されるため、深刻な
マグネシウム欠乏を招くという問題がある。
本発明者はこれらの問題を解決するために種々
実験し研究を重ねた結果、油脂を脂肪酸カルシウ
ムおよび脂肪酸マグネシウムという脂肪酸金属塩
の形で保護することに加えて、脂肪酸カルシウム
と脂肪酸マグネシウムを併用することが、反芻動
物への油脂の効率良い給与と必須ミネラルのバラ
ンスのとれた補給に最良の方法であることを見出
し、本発明を完成させた。
(問題を解決するための手段)
本発明の反芻動物用飼料原料の製造法の要旨
は、油脂を脂肪酸カルシウムおよび脂肪酸マグネ
シウムとして保護すると共に、脂肪酸カルシウム
と脂肪酸マグネシウムを併用することにある。
ここで、脂肪酸の原料となる油脂としては、飽
和脂肪酸含量の多いヤシ油、パーム油や不飽和脂
肪酸含量の多いナタネ油、大豆油、サフラワー油
などの植物性油脂や牛脂、豚脂なとの動物性油脂
が用いられる。容易に入手できる脂肪酸を出発原
料とすることもできるが、脂肪酸はこれらの油脂
を通常水酸化ナトリウム水溶液でケン化分解した
ものである。
脂肪酸カルシウムおよび脂肪酸マグネシウムの
一般的な製法を述べると、まず、油脂を水酸化ナ
トリウム水溶液でケン化分解し、脂肪酸ナトリウ
ム水溶液(以下、石けん溶液という)とする。次
に、この石けん溶液にカルシウム塩化物水溶液お
よびマグネシウム塩化物水溶液をかきまぜながら
徐々に加えて複分解し、水不溶性の脂肪酸金属塩
として塩折させる。ろ布で過剰の水をろ過した
後、風乾し粉砕する。
脂肪酸マグネシウムはサフラワー脂肪酸のよう
に油脂の不飽和度が高くなるほど常温でペースト
状になり易く、他の飼料原料と混合しにくくなる
ものであるが、本発明者は脂肪酸金属塩の組成が
脂肪酸カルシウム99〜80%、脂肪酸マグネシウム
1〜20%となるように複分解時に塩化カルシウム
と塩化マグネシウムの混合水溶液を加えると、粉
末状の好ましい性状を示すことを見い出した。
(作用)
脂肪酸カルシウムと脂肪酸マグネシウムは、も
との脂肪酸よりはるかに高融点となり、中性PHで
は分解しない。そのため、反芻動物に給与された
脂肪酸カルシウムと脂肪酸マグネシウムは、口腔
から第三胃に至るまでの微アルカリ性から中性領
域では、体温での融解や脂肪酸への分解を受ける
ことなしにバイパスし、第四胃において強い酸性
の胃液で脂肪酸に分解し、分解に伴う融点降下に
よつて体温でも融解することになり、小腸で吸収
される。
油脂を保護するカルシウム塩とマグネシウム塩
は、反芻動物の必須ミネラルの補給源として有効
に利用される。
不飽和脂肪酸は上記バイパスにより酸化を受け
にくく、バターのソフト化にも役立つ。
(実施例)
牛脂2Kg(融点40.7℃)を70℃に加熱融解し、
これに10%水酸化ナトリウム溶液2.8Kgをかきま
ぜながら徐々に加え、ケン化分解して牛脂脂肪酸
ナトリウムとする。さらに、これに10%塩化カル
シウム3.5Kgおよび10%塩化マグネシウム0.3Kgの
混合水溶液を同様にかきまぜながら加えて複分解
した後、過剰の水をろ布でろ過し、水洗、ろ過、
風乾、粉砕して牛脂脂肪酸カルシウムおよび牛脂
脂肪酸マグネシウム混合物2.2Kg(水分8%)を
得た。
これらの供試試料による乳用系去勢子牛の育成
試験結果を表−1に示す。
表−1の乳用系去勢子牛の育成試験で、各添加
区の1Kg増体に要する試料の量を比較すると、牛
脂を保護せずに単に与えた場合(実験2)には対
照区(実験1)と差があるものの、牛脂を牛脂脂
肪酸カルシウムおよび牛脂脂肪酸マグネシウムと
して保護した場合(実験3)には著しい差があ
り、本発明の有用性は高いものである。
【表】
【表】
(発明の効果)
以上のように本発明は、油脂を脂肪酸カルシウ
ムおよび脂肪酸マグネシウムとして保護すること
に加えて、脂肪酸カルシウムと脂肪酸マグネシウ
ムを併用するものであるため、単にバイパス作用
によつて油脂分が第四胃で効率良く消化されるだ
けでなく、反芻動物にとつて必須ミネラルである
カルシウムとマグネシウムのバランスのとれた給
与が可能となり、充分に補給されたマグネシウム
が血管内壁や臓器内壁あるいは尿管内壁といつた
軟組織へのカルシウムの沈着を防ぐため、動脈硬
化症や関節炎、腎臓結石などのカルシウム過剰に
因る各種疾病を予防することができる。 DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for producing feed materials for ruminants. Oils and fats, along with proteins, carbohydrates, inorganic substances, vitamins, etc., are nutrients that play an extremely important role in maintaining the life of livestock and producing livestock products. Cow,
In ruminant livestock such as cotton sheep, these nutrients are often partially broken down and absorbed as nutrients for microorganisms in the rumen. In particular, in the case of high-performance cattle, the energy requirements cannot be met by grain alone, so corn is partially replaced with fat and oil, which contains 2.25 times the energy of corn, to increase productivity. However, fats and oils inhibit the activity of various enzymes in the stomach,
There was a limit to the feeding of fats and oils as it was said to reduce the digestibility of feed, especially inhibiting the digestion of cellulose and the utilization of non-protein nitrogen compounds. Additionally, there were drawbacks such as unsaturated fatty acids in fats and oils being reduced to partially saturated acids by the action of microorganisms. Therefore, in order to prevent the decomposition and absorption of fats and oils by microorganisms, inhibition of the activity of various enzymes, and oxidation of fats and oils, the oils and fats are passed directly from the rumen to the rumen (hereinafter referred to as bypass), and digested in the abomasum. needs to be done efficiently. (Conventional technology) Conventional technology that bypasses nutrients to effectively utilize them includes, for example, KSEng, Feedstuffs, 49 (47), 18, which is a method of protecting beef tallow with soybean oil cake.
(1977); NE Smith et al, J.Dairy Sci., 61 ,
747 (1978) as a method of coating fats and oils with proteins and protecting the proteins with formaldehyde.
TRWrenn et al, J.Dairy Sci., 60 , 521
(1977); W. Chalupa, Feed Management, 33 ,
10 (1982); AMGaddenet al, J.Dairy Sci.,
67, 1414 (1948), etc. (Problems to be Solved by the Invention) However, conventional techniques for protecting fats and oils, for example, in the method of protecting beef tallow with soybean oil cake, include rough chewing in the oral cavity, heating in the rumen, stirring, and There are doubts as to whether fats and oils could be protected by rumination, pressure grinding in the rumen, etc., and even if the method of treating proteins with formalin achieves the purpose of protecting fats and oils, the protein itself denatures. has the disadvantage that it is not a source of nutrients. Also, U.S. Patent No. 4,642,317 and Japanese Patent Publication No. 59-
Publication No. 10780 discloses feeding fats and oils to ruminants in the form of calcium salts of fatty acids. This fatty acid calcium bypasses the oral cavity until it passes through the rumen, without being melted by body temperature or decomposed into fatty acids. It melts at body temperature due to the lowering of its melting point and is absorbed in the small intestine, and the calcium content is used as a mineral necessary for ruminants. Calcium, magnesium, phosphorus, zinc, manganese, copper, iron, molybdenum, etc. are generally known as minerals useful in animal feed, but when only fatty acid calcium is fed as in the prior art, blood Calcium levels alone increase, causing calcium deposits in soft tissues, which can lead to arteriosclerosis, arthritis, kidney stones, etc., while magnesium, which is taken separately, is excreted in urine along with calcium. Therefore, there is a problem of serious magnesium deficiency. As a result of various experiments and researches to solve these problems, the inventor of the present invention discovered that in addition to protecting fats and oils in the form of fatty acid metal salts called fatty acid calcium and fatty acid magnesium, the present inventor uses fatty acid calcium and fatty acid magnesium in combination. The inventors have discovered that this is the best method for efficiently supplying fats and oils to ruminants and providing a well-balanced supply of essential minerals, and have completed the present invention. (Means for Solving the Problem) The gist of the method for producing feed materials for ruminants of the present invention is to protect fats and oils as fatty acid calcium and fatty acid magnesium, and to use fatty acid calcium and fatty acid magnesium in combination. Here, the oils and fats that are the raw materials for fatty acids include vegetable oils such as coconut oil, which has a high content of saturated fatty acids, palm oil, rapeseed oil, which has a high content of unsaturated fatty acids, soybean oil, and safflower oil, beef tallow, and pork fat. animal fats and oils are used. Although readily available fatty acids can be used as starting materials, fatty acids are usually obtained by saponifying and decomposing these oils and fats with an aqueous sodium hydroxide solution. To describe a general method for producing fatty acid calcium and fatty acid magnesium, first, fats and oils are saponified and decomposed with an aqueous sodium hydroxide solution to form an aqueous sodium fatty acid solution (hereinafter referred to as a soap solution). Next, an aqueous calcium chloride solution and an aqueous magnesium chloride solution are gradually added to this soap solution while stirring to cause double decomposition, and the resulting water-insoluble fatty acid metal salt is salted out. After filtering excess water with a filter cloth, air dry and grind. The higher the degree of unsaturation of fatty acids such as safflower fatty acids, the more likely fatty acid magnesium becomes paste-like at room temperature, making it difficult to mix with other feed ingredients. It has been found that when an aqueous mixed solution of calcium chloride and magnesium chloride is added during metathesis so that the calcium content is 99-80% and the fatty acid magnesium content is 1-20%, it exhibits favorable powdery properties. (Action) Fatty acid calcium and fatty acid magnesium have a much higher melting point than the original fatty acids, and do not decompose at neutral pH. Therefore, fatty acid calcium and fatty acid magnesium fed to ruminants bypass the slightly alkaline to neutral region from the oral cavity to the rumen without being melted at body temperature or decomposed into fatty acids. It is decomposed into fatty acids in the strong acidic gastric juices in the four stomachs, and as the melting point decreases with the decomposition, it melts at body temperature and is absorbed in the small intestine. Calcium and magnesium salts that protect fats and oils are effectively used as a source of essential minerals for ruminants. Unsaturated fatty acids are less susceptible to oxidation due to the above-mentioned bypass, and are also useful for softening butter. (Example) 2 kg of beef tallow (melting point 40.7°C) was heated and melted at 70°C,
2.8 kg of 10% sodium hydroxide solution is gradually added to this while stirring, and the mixture is saponified and decomposed into sodium beef tallow fatty acid. Furthermore, a mixed aqueous solution of 3.5 kg of 10% calcium chloride and 0.3 kg of 10% magnesium chloride was added to this while stirring in the same manner to cause double decomposition, and then excess water was filtered with a filter cloth, washed with water, filtered,
The mixture was air-dried and ground to obtain 2.2 kg (8% moisture) of a mixture of calcium tallow fatty acid and magnesium tallow fatty acid. Table 1 shows the results of a breeding test on dairy steer calves using these test samples. In the breeding test of dairy steer calves shown in Table 1, when comparing the amount of sample required to gain 1 kg in each addition group, it was found that when beef tallow was simply fed without protection (Experiment 2), the control group (Experiment 2) Although there is a difference from Experiment 1), there is a significant difference when beef tallow is protected as beef tallow fatty acid calcium and beef tallow fatty acid magnesium (Experiment 3), and the usefulness of the present invention is high. [Table] [Table] (Effects of the Invention) As described above, the present invention protects fats and oils as fatty acid calcium and fatty acid magnesium, and also uses fatty acid calcium and fatty acid magnesium in combination. This not only allows fats and oils to be efficiently digested in the abomasum, but also enables a well-balanced supply of calcium and magnesium, which are essential minerals for ruminants. By preventing the deposition of calcium in soft tissues such as the inner walls of organs and the inner walls of the ureters, various diseases caused by excess calcium, such as arteriosclerosis, arthritis, and kidney stones, can be prevented.
Claims (1)
シウムとして保護し、脂肪酸カルシウムと脂肪酸
マグネシウムを併用することを特徴とする反芻動
物用飼料原料の製造法。 2 脂肪酸カルシウムが99〜80%および脂肪酸マ
グネシウムが1〜20%である特許請求の範囲第1
項記載の反芻動物用飼料原料の製造法。[Scope of Claims] 1. A method for producing feed materials for ruminants, characterized in that fats and oils are protected as fatty acid calcium and fatty acid magnesium, and fatty acid calcium and fatty acid magnesium are used together. 2 Claim 1 in which fatty acid calcium is 99-80% and fatty acid magnesium is 1-20%
Method for producing feed ingredients for ruminants as described in Section 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62150410A JPS63313547A (en) | 1987-06-17 | 1987-06-17 | Production of feed raw material for ruminant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62150410A JPS63313547A (en) | 1987-06-17 | 1987-06-17 | Production of feed raw material for ruminant |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63313547A JPS63313547A (en) | 1988-12-21 |
JPH0339663B2 true JPH0339663B2 (en) | 1991-06-14 |
Family
ID=15496345
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62150410A Granted JPS63313547A (en) | 1987-06-17 | 1987-06-17 | Production of feed raw material for ruminant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63313547A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2761927B2 (en) * | 1989-07-10 | 1998-06-04 | 勲 堀内 | Dairy cattle feed additives and methods |
KR100864112B1 (en) * | 2006-12-13 | 2008-10-17 | 대한민국(관리부서:농촌진흥청) | Manufacture of ruminally protected fat supplemented with amino acids |
JP7093193B2 (en) * | 2018-02-09 | 2022-06-29 | 太陽油脂株式会社 | Vegetable oil saponified composition |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5910780A (en) * | 1982-07-09 | 1984-01-20 | Nippon Denso Co Ltd | Discontinuity detector for glow plug |
US4642317A (en) * | 1981-06-16 | 1987-02-10 | The Ohio Agricultural Research And Development Center | Process for feeding ruminant animals and composition for use therein |
-
1987
- 1987-06-17 JP JP62150410A patent/JPS63313547A/en active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4642317A (en) * | 1981-06-16 | 1987-02-10 | The Ohio Agricultural Research And Development Center | Process for feeding ruminant animals and composition for use therein |
US4642317B1 (en) * | 1981-06-16 | 1996-12-31 | Ohio Agricultural Res & Dev | Process for feeding ruminant animals and composition for use therein |
JPS5910780A (en) * | 1982-07-09 | 1984-01-20 | Nippon Denso Co Ltd | Discontinuity detector for glow plug |
Also Published As
Publication number | Publication date |
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JPS63313547A (en) | 1988-12-21 |
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